JPH0482021B2 - - Google Patents
Info
- Publication number
- JPH0482021B2 JPH0482021B2 JP60261479A JP26147985A JPH0482021B2 JP H0482021 B2 JPH0482021 B2 JP H0482021B2 JP 60261479 A JP60261479 A JP 60261479A JP 26147985 A JP26147985 A JP 26147985A JP H0482021 B2 JPH0482021 B2 JP H0482021B2
- Authority
- JP
- Japan
- Prior art keywords
- copolymer
- acrylic acid
- ethylene
- acid ester
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920001577 copolymer Polymers 0.000 claims description 88
- 239000000203 mixture Substances 0.000 claims description 66
- 229920001400 block copolymer Polymers 0.000 claims description 54
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 50
- 239000000178 monomer Substances 0.000 claims description 41
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 33
- 229910052760 oxygen Inorganic materials 0.000 claims description 33
- 239000001301 oxygen Substances 0.000 claims description 33
- 229920006226 ethylene-acrylic acid Polymers 0.000 claims description 27
- 238000004519 manufacturing process Methods 0.000 claims description 17
- MMCOUVMKNAHQOY-UHFFFAOYSA-L oxido carbonate Chemical compound [O-]OC([O-])=O MMCOUVMKNAHQOY-UHFFFAOYSA-L 0.000 claims description 17
- -1 acrylic ester Chemical class 0.000 claims description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 7
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical group CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 6
- 230000008018 melting Effects 0.000 claims description 6
- BMPPHGZRHQWRFX-UHFFFAOYSA-N (1-tert-butylperoxy-2-carboxyoxyethyl) 2-methylprop-2-enoate Chemical group CC(=C)C(=O)OC(COC(O)=O)OOC(C)(C)C BMPPHGZRHQWRFX-UHFFFAOYSA-N 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 4
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000005977 Ethylene Substances 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pentâ4âenâ2âone Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 125000000753 cycloalkyl group Chemical class 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 34
- 238000006116 polymerization reaction Methods 0.000 description 31
- 238000006243 chemical reaction Methods 0.000 description 23
- 125000002081 peroxide group Chemical group 0.000 description 23
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 16
- 230000000903 blocking effect Effects 0.000 description 15
- 238000011282 treatment Methods 0.000 description 15
- 239000011342 resin composition Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 10
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 9
- 238000004898 kneading Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 150000002978 peroxides Chemical class 0.000 description 8
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 3
- YTEAHQIOWUNLTP-UHFFFAOYSA-N 2-carboxyoxyethyl 3-tert-butylperoxyprop-2-enoate Chemical compound CC(C)(C)OOC=CC(=O)OCCOC(O)=O YTEAHQIOWUNLTP-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- ANHMUEBVHTUWHS-UHFFFAOYSA-N 2-(2-carboxyoxyethoxy)ethyl 3-tert-butylperoxyprop-2-enoate Chemical compound CC(C)(C)OOC=CC(=O)OCCOCCOC(=O)O ANHMUEBVHTUWHS-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
- BEOXWOUYOVVTOU-UHFFFAOYSA-N 2-carboxyoxyethyl 3-(2-methylpentan-2-ylperoxy)prop-2-enoate Chemical compound CCCC(C)(C)OOC=CC(=O)OCCOC(O)=O BEOXWOUYOVVTOU-UHFFFAOYSA-N 0.000 description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- HCMDXMDZWCYFEG-UHFFFAOYSA-N [2-carboxyoxy-1-(2-methylpentan-2-ylperoxy)ethyl] 2-methylprop-2-enoate Chemical compound CCCC(C)(C)OOC(COC(O)=O)OC(=O)C(C)=C HCMDXMDZWCYFEG-UHFFFAOYSA-N 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 150000001451 organic peroxides Chemical class 0.000 description 2
- 150000004978 peroxycarbonates Chemical group 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229920006249 styrenic copolymer Polymers 0.000 description 2
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 2
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 2
- CVEISTHBPFIRKN-UHFFFAOYSA-N (1-butylperoxy-2-carboxyoxyethyl) 2-methylprop-2-enoate Chemical compound CCCCOOC(COC(O)=O)OC(=O)C(C)=C CVEISTHBPFIRKN-UHFFFAOYSA-N 0.000 description 1
- LGTYQJIJDFPOPA-UHFFFAOYSA-N (1-tert-butylperoxy-2-carboxyoxypropan-2-yl) 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(OC(O)=O)COOC(C)(C)C LGTYQJIJDFPOPA-UHFFFAOYSA-N 0.000 description 1
- MBMAEXJAHORIGF-UHFFFAOYSA-N (2-carboxyoxy-1-pentylperoxypropan-2-yl) 2-methylprop-2-enoate Chemical compound CCCCCOOCC(C)(OC(O)=O)OC(=O)C(C)=C MBMAEXJAHORIGF-UHFFFAOYSA-N 0.000 description 1
- RXMNFWAHGZIZJV-UHFFFAOYSA-N 2-carboxyoxyethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOC(O)=O RXMNFWAHGZIZJV-UHFFFAOYSA-N 0.000 description 1
- NZQYTVCGWJZBKK-UHFFFAOYSA-N 2-carboxyoxyethyl 3-(2,4,4-trimethylpentan-2-ylperoxy)prop-2-enoate Chemical compound CC(C)(C)CC(C)(C)OOC=CC(=O)OCCOC(O)=O NZQYTVCGWJZBKK-UHFFFAOYSA-N 0.000 description 1
- IRSOWCFTLDBUHO-UHFFFAOYSA-N 2-carboxyoxypropan-2-yl 3-(2-methylpentan-2-ylperoxy)prop-2-enoate Chemical compound CCCC(C)(C)OOC=CC(=O)OC(C)(C)OC(O)=O IRSOWCFTLDBUHO-UHFFFAOYSA-N 0.000 description 1
- RVAKJVUONBGRJG-UHFFFAOYSA-N 2-carboxyoxypropan-2-yl 3-tert-butylperoxyprop-2-enoate Chemical compound CC(C)(C)OOC=CC(=O)OC(C)(C)OC(O)=O RVAKJVUONBGRJG-UHFFFAOYSA-N 0.000 description 1
- BIISIZOQPWZPPS-UHFFFAOYSA-N 2-tert-butylperoxypropan-2-ylbenzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=CC=C1 BIISIZOQPWZPPS-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- ROPFPVGMLGHSNB-UHFFFAOYSA-N CCCC(C)(C)OOC=CC(=O)OCCOCCOC(=O)O Chemical compound CCCC(C)(C)OOC=CC(=O)OCCOCCOC(=O)O ROPFPVGMLGHSNB-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- OCDOXHMCBNUJJT-UHFFFAOYSA-N [2-carboxyoxy-1-(2,4,4-trimethylpentan-2-ylperoxy)ethyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(COC(O)=O)OOC(C)(C)CC(C)(C)C OCDOXHMCBNUJJT-UHFFFAOYSA-N 0.000 description 1
- GYAULSLYQCDSDD-UHFFFAOYSA-N [2-carboxyoxy-1-(2,4,4-trimethylpentan-2-ylperoxy)propan-2-yl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(OC(O)=O)COOC(C)(C)CC(C)(C)C GYAULSLYQCDSDD-UHFFFAOYSA-N 0.000 description 1
- NLWBSJAGYYEQDW-UHFFFAOYSA-N [2-carboxyoxy-1-(2-methylbutan-2-ylperoxy)ethyl] 2-methylprop-2-enoate Chemical compound CCC(C)(C)OOC(COC(O)=O)OC(=O)C(C)=C NLWBSJAGYYEQDW-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005502 peroxidation Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
- C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C08G81/021—Block or graft polymers containing only sequences of polymers of C08C or C08F
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/941—Polymer mixture containing block copolymer is mixed or reacted with chemical treating agent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
Description
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0.002ééïŒ ä»¥äžã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ãª
ãã第ïŒé ã®ããããã«èšèŒã®ã°ã©ããåãšãã¬
ã³âã¢ã¯ãªã«é žãšã¹ãã«å ±éåäœã®è£œé æ³ã
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60261479A JPS62121716A (ja) | 1985-11-22 | 1985-11-22 | ã°ã©ããåãšãã¬ã³âã¢ã¯ãªã«é žãšã¹ãã«å ±éåäœã®è£œé æ³ |
| US06/928,555 US4753990A (en) | 1985-11-22 | 1986-11-10 | Method for producing a grafted ethylene-acrylic acid ester copolymer |
| EP86308957A EP0225102B1 (en) | 1985-11-22 | 1986-11-17 | Method for producing a grafted ethylene-acrylic acid ester copolymer |
| DE8686308957T DE3672967D1 (de) | 1985-11-22 | 1986-11-17 | Verfahren zur herstellung eines gepfropften aethylen-acrylsaeure-ester-copolymerisats. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60261479A JPS62121716A (ja) | 1985-11-22 | 1985-11-22 | ã°ã©ããåãšãã¬ã³âã¢ã¯ãªã«é žãšã¹ãã«å ±éåäœã®è£œé æ³ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62121716A JPS62121716A (ja) | 1987-06-03 |
| JPH0482021B2 true JPH0482021B2 (ja) | 1992-12-25 |
Family
ID=17362474
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60261479A Granted JPS62121716A (ja) | 1985-11-22 | 1985-11-22 | ã°ã©ããåãšãã¬ã³âã¢ã¯ãªã«é žãšã¹ãã«å ±éåäœã®è£œé æ³ |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4753990A (ja) |
| EP (1) | EP0225102B1 (ja) |
| JP (1) | JPS62121716A (ja) |
| DE (1) | DE3672967D1 (ja) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4665131A (en) * | 1985-06-14 | 1987-05-12 | Nippon Oil And Fats Company, Ltd. | Block copolymer |
| US4665132A (en) * | 1985-06-14 | 1987-05-12 | Nippon Oil & Fats Co., Ltd. | Block copolymer |
| US5187235A (en) * | 1986-10-08 | 1993-02-16 | Avery Dennison Corporation | Energy-curable acrylic pressure-sensitive adhesives |
| KR910004490B1 (ko) * | 1987-01-31 | 1991-06-29 | ëíŒì ì ê°ë¶ìêž°ê°ìŽì€ | ê·žëŒííží ì 구첎 ë° ê·ž ì ì¡°ë°©ë² |
| EP0294062B1 (en) * | 1987-06-03 | 1993-09-01 | Ube Industries, Ltd. | Resin compositions and molded products thereof |
| EP0295821B1 (en) * | 1987-06-16 | 1994-01-05 | Nippon Oil And Fats Company, Limited | Method for production of graft resin composition |
| EP0307802B1 (en) * | 1987-09-09 | 1995-01-11 | Nippon Petrochemicals Company, Limited | Thermoplastic resin composition and method for preparing the same |
| WO1991000300A1 (en) * | 1989-06-28 | 1991-01-10 | Akzo N.V. | (CO)POLYMER MODIFICATION EMPLOYING UNSATURATED t-ALKYL PEROXY ALKENES |
| FR2649111B1 (fr) * | 1989-06-29 | 1991-09-13 | Poudres & Explosifs Ste Nale | Procede de fabrication de revetements par radioreticulation, nouvelles compositions radioreticulables et nouveaux carbonates |
| US5206298A (en) * | 1989-12-19 | 1993-04-27 | Tomei Sangyo Kabushiki Kaisha | Graft copolymer, solution containing the graft copolymer for treating contact lens, and method of treating contact lens with the solution and making hydrophilic lens surface |
| EP0872539A4 (en) * | 1995-11-07 | 2002-07-03 | Nof Corp | VISCOSITY INDEX IMPROVERS, PRODUCTION OF THE SAME AND LUBRICATING OIL COMPOSITION |
| DE602007009792D1 (de) * | 2007-03-30 | 2010-11-25 | Kemira Oyj | Gepfropfter Interpolymerlatex und Herstellungsverfahren dafÃŒr |
| KR102420906B1 (ko) * | 2014-11-18 | 2022-07-13 | ëì¹ì ê°ë¶ìí€ê°ìŽì€ | ìížë -ììžížì°ë¹ë ê³µì€í©ì²Ž ìì§ ì¡°ì±ë¬Œ, ê·žëííž ê³µì€í©ì²Ž, ìŽê°ìì± ìì§ ì¡°ì±ë¬Œ, ë° ìì§ ì±íí |
| TWI839457B (zh) * | 2019-02-07 | 2024-04-21 | æ¥åæ¥æ²¹è¡ä»œæéå ¬åž | æš¹èçµåç©ãç±å¡æ§æš¹èçµåç©åç±å¡æ§æš¹èæåé« |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5610538A (en) * | 1979-07-06 | 1981-02-03 | Nippon Oil & Fats Co Ltd | Styrene resin composition |
| US4658001A (en) * | 1984-10-12 | 1987-04-14 | Nippon Oils & Fats Co., Ltd. | Peroxycarbonate group-containing copolymer and method for manufacture thereof |
| US4665132A (en) * | 1985-06-14 | 1987-05-12 | Nippon Oil & Fats Co., Ltd. | Block copolymer |
| US4665131A (en) * | 1985-06-14 | 1987-05-12 | Nippon Oil And Fats Company, Ltd. | Block copolymer |
-
1985
- 1985-11-22 JP JP60261479A patent/JPS62121716A/ja active Granted
-
1986
- 1986-11-10 US US06/928,555 patent/US4753990A/en not_active Expired - Fee Related
- 1986-11-17 EP EP86308957A patent/EP0225102B1/en not_active Expired
- 1986-11-17 DE DE8686308957T patent/DE3672967D1/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62121716A (ja) | 1987-06-03 |
| DE3672967D1 (de) | 1990-08-30 |
| EP0225102B1 (en) | 1990-07-25 |
| EP0225102A1 (en) | 1987-06-10 |
| US4753990A (en) | 1988-06-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |