JPH0452940B2 - - Google Patents
Info
- Publication number
- JPH0452940B2 JPH0452940B2 JP59092661A JP9266184A JPH0452940B2 JP H0452940 B2 JPH0452940 B2 JP H0452940B2 JP 59092661 A JP59092661 A JP 59092661A JP 9266184 A JP9266184 A JP 9266184A JP H0452940 B2 JPH0452940 B2 JP H0452940B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- type
- oxazole
- compound
- charge
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 108091008695 photoreceptors Proteins 0.000 claims description 25
- 239000000126 substance Substances 0.000 claims description 23
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 22
- 150000007978 oxazole derivatives Chemical group 0.000 claims description 19
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 239000002131 composite material Substances 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 49
- 150000001875 compounds Chemical class 0.000 description 37
- 238000004519 manufacturing process Methods 0.000 description 23
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
- 238000006243 chemical reaction Methods 0.000 description 21
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 18
- 239000000203 mixture Substances 0.000 description 18
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- 238000000354 decomposition reaction Methods 0.000 description 14
- 238000010521 absorption reaction Methods 0.000 description 13
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 12
- 238000010992 reflux Methods 0.000 description 12
- 239000002904 solvent Substances 0.000 description 12
- 238000000862 absorption spectrum Methods 0.000 description 11
- 239000013078 crystal Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 9
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- -1 phthalocyanine nitrogen isomer Chemical class 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 239000011230 binding agent Substances 0.000 description 7
- 238000002844 melting Methods 0.000 description 7
- 230000008018 melting Effects 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 230000035945 sensitivity Effects 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- 229920001225 polyester resin Polymers 0.000 description 5
- 239000004645 polyester resin Substances 0.000 description 5
- 229920002050 silicone resin Polymers 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 4
- WTDHULULXKLSOZ-UHFFFAOYSA-N Hydroxylamine hydrochloride Chemical compound Cl.ON WTDHULULXKLSOZ-UHFFFAOYSA-N 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 4
- 150000001555 benzenes Chemical class 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 239000004014 plasticizer Substances 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 238000001953 recrystallisation Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 125000001424 substituent group Chemical group 0.000 description 4
- PSZNEXCIYHTTND-UHFFFAOYSA-N 1-[4-(dimethylamino)phenyl]-2-(2-fluorophenyl)-2-hydroxyethanone Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C(O)C1=CC=CC=C1F PSZNEXCIYHTTND-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 3
- KMLGFOAKCYHXCQ-UHFFFAOYSA-N 4-(diethylamino)benzonitrile Chemical compound CCN(CC)C1=CC=C(C#N)C=C1 KMLGFOAKCYHXCQ-UHFFFAOYSA-N 0.000 description 3
- JYMNQRQQBJIMCV-UHFFFAOYSA-N 4-(dimethylamino)benzonitrile Chemical compound CN(C)C1=CC=C(C#N)C=C1 JYMNQRQQBJIMCV-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000002835 absorbance Methods 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000000921 elemental analysis Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 235000019253 formic acid Nutrition 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
- 229910052753 mercury Inorganic materials 0.000 description 3
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 150000003384 small molecules Chemical class 0.000 description 3
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 3
- 235000019254 sodium formate Nutrition 0.000 description 3
- DXBHBZVCASKNBY-UHFFFAOYSA-N 1,2-Benz(a)anthracene Chemical compound C1=CC=C2C3=CC4=CC=CC=C4C=C3C=CC2=C1 DXBHBZVCASKNBY-UHFFFAOYSA-N 0.000 description 2
- QNLZIZAQLLYXTC-UHFFFAOYSA-N 1,2-dimethylnaphthalene Chemical compound C1=CC=CC2=C(C)C(C)=CC=C21 QNLZIZAQLLYXTC-UHFFFAOYSA-N 0.000 description 2
- DGPBVJWCIDNDPN-UHFFFAOYSA-N 2-(dimethylamino)benzaldehyde Chemical compound CN(C)C1=CC=CC=C1C=O DGPBVJWCIDNDPN-UHFFFAOYSA-N 0.000 description 2
- NUTUBCIAQHTQRN-UHFFFAOYSA-N 2-(dipropylamino)benzaldehyde Chemical compound CCCN(CCC)C1=CC=CC=C1C=O NUTUBCIAQHTQRN-UHFFFAOYSA-N 0.000 description 2
- ZWDVQMVZZYIAHO-UHFFFAOYSA-N 2-fluorobenzaldehyde Chemical compound FC1=CC=CC=C1C=O ZWDVQMVZZYIAHO-UHFFFAOYSA-N 0.000 description 2
- TURIHPLQSRVWHU-UHFFFAOYSA-N 2-phenylnaphthalene Chemical compound C1=CC=CC=C1C1=CC=C(C=CC=C2)C2=C1 TURIHPLQSRVWHU-UHFFFAOYSA-N 0.000 description 2
- PYBOHBWNACIEDV-UHFFFAOYSA-N 4-(dipropylamino)benzonitrile Chemical compound CCCN(CCC)C1=CC=C(C#N)C=C1 PYBOHBWNACIEDV-UHFFFAOYSA-N 0.000 description 2
- QXCYIDFEZSITMW-UHFFFAOYSA-N 4-[2-[4-(diethylamino)phenyl]-5-(2-fluorophenyl)-1,3-oxazol-4-yl]-n,n-dimethylaniline Chemical compound C1=CC(N(CC)CC)=CC=C1C1=NC(C=2C=CC(=CC=2)N(C)C)=C(C=2C(=CC=CC=2)F)O1 QXCYIDFEZSITMW-UHFFFAOYSA-N 0.000 description 2
- YQVFRCFHXGQGNI-UHFFFAOYSA-N 4-[2-[4-(dipropylamino)phenyl]-5-(2-fluorophenyl)-1,3-oxazol-4-yl]-n,n-dimethylaniline Chemical compound C1=CC(N(CCC)CCC)=CC=C1C1=NC(C=2C=CC(=CC=2)N(C)C)=C(C=2C(=CC=CC=2)F)O1 YQVFRCFHXGQGNI-UHFFFAOYSA-N 0.000 description 2
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 2
- 239000004280 Sodium formate Substances 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- WDECIBYCCFPHNR-UHFFFAOYSA-N chrysene Chemical compound C1=CC=CC2=CC=C3C4=CC=CC=C4C=CC3=C21 WDECIBYCCFPHNR-UHFFFAOYSA-N 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 239000002612 dispersion medium Substances 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- MMFBQHXDINNBMW-UHFFFAOYSA-N n,n-dipropylaniline Chemical compound CCCN(CCC)C1=CC=CC=C1 MMFBQHXDINNBMW-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 150000002923 oximes Chemical class 0.000 description 2
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 2
- NNFCIKHAZHQZJG-UHFFFAOYSA-N potassium cyanide Chemical compound [K+].N#[C-] NNFCIKHAZHQZJG-UHFFFAOYSA-N 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 238000005292 vacuum distillation Methods 0.000 description 2
- HYGLETVERPVXOS-UHFFFAOYSA-N 1-bromopyrene Chemical compound C1=C2C(Br)=CC=C(C=C3)C2=C2C3=CC=CC2=C1 HYGLETVERPVXOS-UHFFFAOYSA-N 0.000 description 1
- VHQGURIJMFPBKS-UHFFFAOYSA-N 2,4,7-trinitrofluoren-9-one Chemical compound [O-][N+](=O)C1=CC([N+]([O-])=O)=C2C3=CC=C([N+](=O)[O-])C=C3C(=O)C2=C1 VHQGURIJMFPBKS-UHFFFAOYSA-N 0.000 description 1
- OFJBYLCQNJHFMI-UHFFFAOYSA-N 2,5-dihydro-1,2-oxazole Chemical class C1ONC=C1 OFJBYLCQNJHFMI-UHFFFAOYSA-N 0.000 description 1
- HDVGAFBXTXDYIB-UHFFFAOYSA-N 2,7-dinitrofluoren-9-one Chemical compound C1=C([N+]([O-])=O)C=C2C(=O)C3=CC([N+](=O)[O-])=CC=C3C2=C1 HDVGAFBXTXDYIB-UHFFFAOYSA-N 0.000 description 1
- FLCWJWNCSHIREG-UHFFFAOYSA-N 2-(diethylamino)benzaldehyde Chemical compound CCN(CC)C1=CC=CC=C1C=O FLCWJWNCSHIREG-UHFFFAOYSA-N 0.000 description 1
- KLLLJCACIRKBDT-UHFFFAOYSA-N 2-phenyl-1H-indole Chemical compound N1C2=CC=CC=C2C=C1C1=CC=CC=C1 KLLLJCACIRKBDT-UHFFFAOYSA-N 0.000 description 1
- CCIRWPQIFNLNMJ-UHFFFAOYSA-N 2-phenylpyrene Chemical compound C1=CC=CC=C1C1=CC2=CC=C(C=CC=C3C=C4)C3=C2C4=C1 CCIRWPQIFNLNMJ-UHFFFAOYSA-N 0.000 description 1
- AEFDIOODLJMOML-UHFFFAOYSA-N 3,7-dinitrodibenzothiophene 5-oxide Chemical compound C1=C([N+]([O-])=O)C=C2S(=O)C3=CC([N+](=O)[O-])=CC=C3C2=C1 AEFDIOODLJMOML-UHFFFAOYSA-N 0.000 description 1
- IAWRFMPNMXEJCK-UHFFFAOYSA-N 3-phenyl-9h-carbazole Chemical compound C1=CC=CC=C1C1=CC=C(NC=2C3=CC=CC=2)C3=C1 IAWRFMPNMXEJCK-UHFFFAOYSA-N 0.000 description 1
- MLEBCZSWVARRML-UHFFFAOYSA-N 4-(2,5-diphenyl-1,3-oxazol-4-yl)-n,n-diethylaniline Chemical compound C1=CC(N(CC)CC)=CC=C1C1=C(C=2C=CC=CC=2)OC(C=2C=CC=CC=2)=N1 MLEBCZSWVARRML-UHFFFAOYSA-N 0.000 description 1
- BGNGWHSBYQYVRX-UHFFFAOYSA-N 4-(dimethylamino)benzaldehyde Chemical compound CN(C)C1=CC=C(C=O)C=C1 BGNGWHSBYQYVRX-UHFFFAOYSA-N 0.000 description 1
- BZKRKPGZABEOSM-XMHGGMMESA-N 4-[(e)-2-[3-[4-(diethylamino)phenyl]-2-phenyl-3,4-dihydropyrazol-5-yl]ethenyl]-n,n-diethylaniline Chemical compound C1=CC(N(CC)CC)=CC=C1\C=C\C1=NN(C=2C=CC=CC=2)C(C=2C=CC(=CC=2)N(CC)CC)C1 BZKRKPGZABEOSM-XMHGGMMESA-N 0.000 description 1
- DPZNJTUKKZBXAP-UHFFFAOYSA-N 4-[2-[4-(dimethylamino)phenyl]-5-(2-fluorophenyl)-1,3-oxazol-4-yl]-n,n-dimethylaniline Chemical compound C1=CC(N(C)C)=CC=C1C1=NC(C=2C=CC(=CC=2)N(C)C)=C(C=2C(=CC=CC=2)F)O1 DPZNJTUKKZBXAP-UHFFFAOYSA-N 0.000 description 1
- ZOZONPMSKMOZIG-UHFFFAOYSA-N 4-[5-(2-chlorophenyl)-1,3-oxazol-2-yl]-N,N-dimethylaniline Chemical compound CN(C1=CC=C(C=C1)C=1OC(=CN=1)C1=C(C=CC=C1)Cl)C ZOZONPMSKMOZIG-UHFFFAOYSA-N 0.000 description 1
- BDQMFBXOQYLWQE-UHFFFAOYSA-N 4-[5-(2-chlorophenyl)-2-[4-(diethylamino)phenyl]-1,3-oxazol-4-yl]-n,n-dimethylaniline Chemical compound C1=CC(N(CC)CC)=CC=C1C1=NC(C=2C=CC(=CC=2)N(C)C)=C(C=2C(=CC=CC=2)Cl)O1 BDQMFBXOQYLWQE-UHFFFAOYSA-N 0.000 description 1
- OVYWSSPXKUPBRQ-UHFFFAOYSA-N 4-[5-(2-chlorophenyl)-2-[4-(dimethylamino)phenyl]-1,3-oxazol-4-yl]-n,n-dimethylaniline Chemical compound C1=CC(N(C)C)=CC=C1C1=NC(C=2C=CC(=CC=2)N(C)C)=C(C=2C(=CC=CC=2)Cl)O1 OVYWSSPXKUPBRQ-UHFFFAOYSA-N 0.000 description 1
- LLBZPESJRQGYMB-UHFFFAOYSA-N 4-one Natural products O1C(C(=O)CC)CC(C)C11C2(C)CCC(C3(C)C(C(C)(CO)C(OC4C(C(O)C(O)C(COC5C(C(O)C(O)CO5)OC5C(C(OC6C(C(O)C(O)C(CO)O6)O)C(O)C(CO)O5)OC5C(C(O)C(O)C(C)O5)O)O4)O)CC3)CC3)=C3C2(C)CC1 LLBZPESJRQGYMB-UHFFFAOYSA-N 0.000 description 1
- 229920005789 ACRONAL® acrylic binder Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical class [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 244000028419 Styrax benzoin Species 0.000 description 1
- 235000000126 Styrax benzoin Nutrition 0.000 description 1
- 235000008411 Sumatra benzointree Nutrition 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229960002130 benzoin Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- YLQWCDOCJODRMT-UHFFFAOYSA-N fluoren-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C2=C1 YLQWCDOCJODRMT-UHFFFAOYSA-N 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 235000019382 gum benzoic Nutrition 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- WCPAKWJPBJAGKN-UHFFFAOYSA-N oxadiazole Chemical compound C1=CON=N1 WCPAKWJPBJAGKN-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 238000006303 photolysis reaction Methods 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001470 polyketone Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- OVARTBFNCCXQKS-UHFFFAOYSA-N propan-2-one;hydrate Chemical compound O.CC(C)=O OVARTBFNCCXQKS-UHFFFAOYSA-N 0.000 description 1
- MHZDONKZSXBOGL-UHFFFAOYSA-N propyl dihydrogen phosphate Chemical compound CCCOP(O)(O)=O MHZDONKZSXBOGL-UHFFFAOYSA-N 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- ODHXBMXNKOYIBV-UHFFFAOYSA-N triphenylamine Chemical compound C1=CC=CC=C1N(C=1C=CC=CC=1)C1=CC=CC=C1 ODHXBMXNKOYIBV-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/0664—Dyes
- G03G5/0696—Phthalocyanines
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/0622—Heterocyclic compounds
- G03G5/0624—Heterocyclic compounds containing one hetero ring
- G03G5/0627—Heterocyclic compounds containing one hetero ring being five-membered
- G03G5/0631—Heterocyclic compounds containing one hetero ring being five-membered containing two hetero atoms
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Photoreceptors In Electrophotography (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Description
ïŒç£æ¥äžã®å©çšåéïŒ
æ¬çºæã¯ãé»ååçã«ããç»åäœæã«æå¹ãªæ
å äœã«ä¿ããç¹ã«é·æ³¢é·ã®å ã«å¯ŸããŠãé«æ床ã
æããé»è·çºçç©è³ªãšååŠçã«å®å®ãªæ°èŠãªãªã
ãµãŸãŒã«èªå°äœãšããæ§æãããé»ååççšæå
äœã«é¢ããã ïŒåŸæ¥æè¡ïŒ åŸæ¥ãé·æ³¢é·ã®å ã«å¯ŸããŠé«æ床ãæããé»å
åçæå äœã«ãããŠãé»è·çºçç©è³ªãšããŠÏåã
Ïâ²åãηåããã³Î·â²åç¡éå±ãã¿ãã·ã¢ãã³ã®ã
ã¡å°ãªããšãäžçš®é¡ã䜿çšããé»è·æ¬éç©è³ªãšã
ãŠïŒâïŒïŒâãžãããã«ã¢ããããšãã«ïŒâïŒâ
ïŒïŒâãžã¡ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâã¯ã
ãããšãã«ïŒâïŒïŒïŒâãªããµãŸãŒã«ãååç©
ïŒïŒããïŒâïŒïŒâãžãšãã«ã¢ããããšãã«ïŒâïŒ
âïŒïŒâïŒãžã¡ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâã¯
ããããšãã«ïŒâïŒïŒïŒâãªããµãŸãŒã«ãååç©
ïŒïŒããïŒâïŒïŒâãžã¡ãã«ã¢ããããšãã«ïŒâïŒ
âïŒïŒâãžã¡ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâã¯
ããããšãã«ïŒâïŒïŒïŒâãªããµãŸãŒã«ãååç©
ïŒïŒããªã©ã®ãªããµãŸãŒã«èªå°äœã®ãã¡å°ãªããš
ãäžçš®é¡ããæ§æãããã¬ãŒã¶ãŒããŒã ããªã³ã¿
ãŒçšé»ååçæå äœãïŒç¹éæ58â182639å·å ¬
å ±ãç¹éæ58â182640å·å ¬å ±ïŒç¥ãããŠãããã
ãããäžèšãªããµãŸãŒã«èªå°äœã¯ç¹ã«ã溶液ç¶æ
ã«ãããŠçŽ«å€ç·ã®ç §å°ã«ãããèãã容æã«å解
ããå解çæç©ãšããŠäž»ã«ïŒâïŒïŒâãžãããã«
ã¢ããããšãã«ïŒâïŒâãžã¡ãã«ã¢ããããšãã³
ãããïŒïŒ10âïœããªããµãŸãŒã«ãçæãããã®
ç¹æ§ãå£å€±ããããåãæ±ãã«æ³šæãèŠããç¹
ã«ãé»ååçæå äœã®è£œé äžã«ãã®ç¹æ§ãå£å€±ã
ããããšããæ¬ ç¹ãæããã æ¬çºæã¯ããã®ãããªåé¡ç¹ã解決ãããã®ã§
ãããæ°èŠãªååç©ã§ãã€ãŠçŽ«å€ç·ã®ç §å°ã«å¯Ÿã
ãŠå®å®ãªæ§è³ªãæãããªããµãŸãŒã«èªå°äœãå«æ
ããé·æ³¢é·ã®å ã«å¯ŸããŠé«æ床ã瀺ãåªããé»å
åçç¹æ§ãæããé»ååçæå äœãæäŸãããã®
ã§ãããç¹ã«ãã®è£œé äžã«ããã®ç¹æ§ãå£å€±ããª
ãé»ååçæå äœãæäŸãããã®ã§ããã ïŒçºæã®æ§æïŒ å°é»æ§æ¯æäœäžã«ãé»è·çºçç©è³ªãå«ãé»è·çº
çå±€åã³é»è·æ¬éç©è³ªãå«ãé»è·æ¬éå±€ãæãã
è€ååã®é»ååçæå äœã«ãããŠãåèšé»è·çºç
ç©è³ªããÏåãÏâ²åãηååã³Î·â²åç¡éå±ãã¿ã
ã·ã¢ãã³ã®ãã¡å°ãªããšãäžçš®é¡ãå«ã¿ãé»è·æ¬
éç©è³ªããäžè¬åŒïŒïŒ ïŒãã ããåŒäžR1ïŒR2ïŒR3ããã³R4ã¯ãã¢ã«
ãã«åºã瀺ããããã¯åäžã§ãç°ãªã€ãŠãããïŒ
ã§è¡šããããªããµãŸãŒã«èªå°äœã§ããããšãç¹åŸŽ
ãšããé»ååçæå äœã«é¢ããã äžèšäžè¬åŒïŒïŒã§è¡šããããååç©ã¯ãäžèš
ååç©ïŒïŒïŒïŒïŒããã³ïŒïŒã«ãããClåå
ã®ãããã«ïŒŠååãæãããã®ã§ãããããã«ã
ãã玫å€ç·ã«å¯ŸããŠãå®å®æ§ãéåžžã«å€§ããã玫
å€ç·ãç §å°ãããŠãå解ããããšããªããé»åå
çæå äœã«å®å®ãªåªããç¹æ§ãäžãããã®ã§ã
ãã äžè¬åŒïŒïŒã§è¡šãããããªããµãŸãŒã«èªå°äœ
ã¯ãäž»ã«é»è·æ¬éç©è³ªãšããŠæ©èœããããã®åå
ç©ã¯ä»ã®é»è·æ¬éç©è³ªãäŸãã°é«ååååç©ã®ã
ã®ã§ã¯ããªââããã«ã«ã«ããŸãŒã«ãããã²ã³
åããªââããã«ã«ã«ããŸãŒã«ãããªããã«ã
ã¬ã³ãããªããã«ã€ã³ããããããµãªã³ãããªã
ãã«ãã³ãŸããªããšã³ãããªããã«ã¢ã³ãã©ã»
ã³ãããªããã«ã¢ã¯ãªãžã³ãããªããã«ãã©ãŸãª
ã³çããäœååååç©ã®ãã®ã§ã¯ãã«ãªã¬ã³ãã
ã«ãªã¬ãã³ãïŒïŒïŒâãžãããâïŒâãã«ãªã¬ã
ã³ãïŒïŒïŒïŒïŒâããªãããâïŒâãã«ãªã¬ã
ã³ã4Hâã€ã³ããïŒïŒïŒïŒïŒïŒïŒããªããšã³â
ïŒâãªã³ãïŒïŒïŒâãžãããâãžãã³ãŸããªããš
ã³âïŒâãªããµã€ããïŒâããã ãã¬ã³ãïŒâã
ãšãã«ãã¬ã³ãã«ã«ããŸãŒã«ãïŒâããšãã«ã«ã«
ããŸãŒã«ãïŒâããšãã«ã€ã³ããŒã«ãïŒâããšã
ã«ããã¿ã¬ã³ããªããµãžã¢ãŸãŒã«ãããªã¢ãŸãŒ
ã«ãïŒâããšãã«âïŒâïŒïŒâãžãšãã«ã¢ããã¹
ããªã«ïŒâïŒâïŒïŒâãžãšãã«ã¢ããããšãã«ïŒã
ã©ãŸãªã³ãïŒâããšãã«âïŒâïŒïŒâãžãšãã«ã¢
ããããšãã«ïŒâïŒâããšãã«ãªããµãŸãŒã«ãã
ãªããšãã«ã¢ãã³ãã€ãããŸãŒã«ãã¯ãªã»ã³ãã
ãã©ããšã³ãã¢ã¯ãªãã³ããããã®èªå°äœçãšäœµ
çšããããšãã§ãããä»ã®é»è·æ¬éç©è³ªã®é åå²
åã¯ãäžè¬åŒïŒïŒã§è¡šãããããªããµãŸãŒã«èª
å°äœã«ããé»ååçç¹æ§ã®åäžãæããªãããã«
該èªå°äœïŒéééšã«å¯ŸããŠïŒéééšä»¥äžã奜ãŸã
ããç¹ã«0.25éééšä»¥äžã奜ãŸããã æ¬çºæã«ãããŠäœ¿çšãããé»è·çºçææã§ãã
ÏïŒÏâ²ïŒÎ·åã³Î·â²åç¡éå±ãã¿ãã·ã¢ãã³ã¯ãç¹
é58â182640å·å ¬å ±åã³ãšãŒãããç¹èš±å ¬é第
92255å·å ¬å ±ã«èšèŒããããã®ã§ããã Ïåç¡éå±ãã¿ãã·ã¢ãã³ã¯ããã©ãã°è§åºŠ
ïŒ2Ξ±0.2床ïŒã7.6ïŒ9.2ïŒ16.8ïŒ17.4ïŒ20.4åã³
20.9ã«ç¹åŸŽçãªããŒã¯ãæããç·åæãã¿ãŒã³
ãæããç¹ã«ãèµ€å€ç·åžåã¹ãã«ãã«ã700ã760
cm-1ã®éã«751±ïŒcm-1ãæã匷ãïŒæ¬ã®åžå垯
ãã1320ã1340cm-1ã®éã«ã»ãŒåã匷ãã®ïŒæ¬ã®
åžå垯ãã3288±ïŒcm-1ã«ç¹åŸŽçãªåžåãæãã
ãã®ã奜ãŸããã Ïâ²åç¡éå±ãã¿ãã·ã¢ãã³ã¯ããã©ãã°è§åºŠ
ïŒ2Ξ±0.2床ïŒã7.5ïŒ9.1ïŒ16.8ïŒ17.3ïŒ20.3ïŒ20.8ïŒ
21.4åã³27.4ã«åŒ·ãããŒã¯ãæããç·åæãã¿
ãŒã³ãæããèµ€å€ç·åžåã¹ãã¯ãã«ã700ã760cm
âïŒã®éã«753ïŒÂ±ïŒïŒcm-1ãæã匷ãïŒæ¬ã®åžå垯
ãã1320ã1340cm-1ã®éã«ïŒæ¬ã®ã»ãŒåã匷ãã®
åžå垯ãã3297±ïŒcm-1ã«ç¹åŸŽçãªåžåãæãã
ãã®ãæãŸããã ηååã³Î·â²åç¡éå±ãã¿ãã·ã¢ãã³ã¯ãç¡éå±
ãã¿ãã·ã¢ãã³100éééšãšãã³ãŒã³æ žã«çœ®æåº
ãæããç¡éå±ãã¿ãã·ã¢ãã³ããã³ãŒã³æ žã«çœ®
æåºãæããŠããŠããããã¿ãã·ã¢ãã³çªçŽ åæ§
äœè¥ããã¯éå±ãã¿ãã·ã¢ãã³ã®äžçš®è¥ããã¯äº
皮以äž50éééšä»¥äžãšã®æ··åç©çµæ¶ã§ãããηã
ãã³Î·â²åã¯ãåã ãäºçš®é¡ãã€ååšããã ηåç¡éå±ãã¿ãã·ã¢ãã³ã¯ãèµ€å€ç·åžåã¹ã
ã¯ãã«ã700ã760cm-1ã®éã«753±ïŒcm-1ãæã
匷ãïŒæ¬ã®åžå垯ãã1320ã1340cm-1ã®éã«ïŒæ¬
ã®ã»ãŒåã匷ãã®åžå垯ãã3285±ïŒcm-1ã«ç¹åŸŽ
çãªåžåãæãããηåç¡éå±ãã¿ãã·ã¢ãã³ã®
ãã¡äžçš®ã¯ããã©ãã°è§åºŠïŒ2Ξ±0.2床ïŒãã
7.6ïŒ9.2ïŒ16.8ïŒ17.4åã³28.5ã«ç¹åŸŽçãªããŒã¯ã
æããç·åæãã¿ãŒã³ãæããä»ã®äžçš®ã¯ã
7.6ïŒ9.2ïŒ16.8ïŒ17.4ïŒ21.5åã³27.5ã«ç¹åŸŽçãªã
ãŒã¯ãæããç·åæãã¿ãŒã³ãæããã ηâ²åç¡éå±ãã¿ãã·ã¢ãã³ã¯ãèµ€å€ç·åžåã¹ã
ã¯ãã«ã700ã760cm-1ã®éã«ã753±ïŒcm-1ãæ
ã匷ãïŒæ¬ã®åžå垯ãã1320ã1340cm-1ã«ïŒæ¬ã®
ã»ãŒåã匷ãã®åžå垯ãã3297±ïŒcm-1ã«ç¹åŸŽç
ãªåžåãæãããηâ²åç¡éå±ãã¿ãã·ã¢ãã³ã®äž
çš®ã¯ããã©ãã°è§åºŠïŒ2Ξ±ïŒåºŠïŒã7.5ïŒ9.1ïŒ
16.8ïŒ17.3ïŒ20.3ïŒ20.8ïŒ21.4åã³27.4ã«ç¹åŸŽçãª
ããŒã¯ãæããåç·åæãã¿ãŒã³ãæããä»ã®äž
çš®ã¯ã7.5ïŒ9.1ïŒ16.8ïŒ17.3ïŒ20.3ïŒ20.8ïŒ21.4ïŒ
22.1ïŒ27.4åã³28.5ã«ç¹åŸŽçãªããŒã¯ãæãã
ç·åæãã¿ãŒã³ãæããã Ïåã³Ïâ²åç¡éå±ãã¿ãã·ã¢ãã³ã¯ãäŸãã°Î±
åç¡éå±ãã¿ãã·ã¢ãã³ã液äœåæ£åªã«åæ£ãã
磚ç å©å€ã®ååšäžã«50ã180âã奜ãŸããã¯60ã
130âã®æž©åºŠã§çµæ¶å€æããã®ã«ååãªæéãæª
æè¥ããã¯æ©æ¢°çæªåããã€ãŠããªã³ã°ããããš
ã«ãã補é ããããšãã§ããã ηåã³Î·â²åç¡éå±ãã¿ãã·ã¢ãã³ã¯ãäŸãã¯ã
αåç¡éå±ãã¿ãã·ã¢ãã³100éééšãšãã³ãŒã³
æ žã«çœ®æåºãæããç¡éå±ãã¿ãã·ã¢ãã³ããã«
ãã€ã³ååç©çã®ãã³ãŒã³æ žã«çœ®æåºãæããŠã
ãŠããããã¿ãã·ã¢ãã³çªçŽ åæ§äœè¥ããã¯éå±
ãã¿ãã·ã¢ãã³50éééšä»¥äžã奜ãŸããã¯0.1ã
30éééšãšã液äœåæ£åªã«åæ£ãã磚ç å©å€ã®å
åšäžã«30ã220âã奜ãŸããã¯60ã130âã§çµæ¶å€
æããã®ã«ååãªæéãæªæè¥ããã¯æ©æ¢°çæªå
ããã€ãŠããªã³ã°ããããšã«ãã補é ããããšã
ã§ããã å å°é»äœå±€ã«ã¯ãæ¢ç¥ã®çµåå€ãå¯å¡å€ãæµå
æ§ä»äžå€ããã³ããŒã«æå¶å€çã®æ·»å å€ã䜿çšã
ãããšãã§ãããçµåå€ãšããŠã¯ãç·ç¶é£œåããª
ãšã¹ãã«æš¹èãããªã«ãŒãããŒãæš¹èãã¢ã¯ãªã«
系暹èãããã©ãŒã«æš¹èãããªã±ãã³æš¹èãããª
ãŠã¬ã¿ã³æš¹èãããªââããã«ã«ã«ããŸãŒã«ã
ããªâïŒïœâããã«ããšãã«ïŒã¢ã»ãã©ã»ã³ãã·
ãªã³ãŒã³æš¹èãããªã¢ããæš¹èããšããã·æš¹èã
ããªã¹ãã¬ã³æš¹èãªã©ãéžã°ããã ãŸããç±åã³ïŒãŸãã¯å ã«ãã€ãŠæ¶æ©ããç±ç¡¬
åååã³å 硬ååæš¹èã䜿çšã§ããããããã«ã
ãŠã絶çžæ§ã§éåžžã®ç¶æ ã§ç®è圢æèœãæããæš¹
èåã³ïŒãŸãã¯å ã«ãã€ãŠç¡¬åãç®èã圢æãã
æš¹èã§ããã°ç¹ã«å¶éã¯ãªããå¯å¡å€ãšããŠãã
ã²ã³åãã©ãã€ã³ããžã¡ãã«ããã¿ã¬ã³ããžãã
ã«ãã¿ã¬ãŒãçãæãããããæµåæ§ä»äžå€ãšã
ãŠã¯ã¢ããããŒïŒã¢ã³ãµã³ãã±ãã«ã«ç€Ÿè£œïŒãã¢
ã¯ãããŒã«4FïŒãã¹ã瀟補ïŒçããã³ããŒã«æå¶
å€ãšããŠã¯ãã³ãŸã€ã³ããžã¡ãã«ãã¬ãã¿ã¬ãŒã
çãæããããããããã¯é©å®éžæããŠäœ¿çšã
ãããã®éãé©å®æ±ºå®ãããã°ããã äžæ¹ãïŒå±€æ§é ãæ¡ãå Žåãé»è·çºçå±€ã¯ãå
èšÏåãÏâ²åãηååã³Î·â²åç¡éå±ãã¿ãã·ã¢ã
ã³ã®ãã¡å°ãªããšãäžçš®é¡ãé»è·çºçç©è³ªãšããŠ
䜿çšããã®ã§è圢æã®ããã«äžèšçµåå€ã䜿çšã
ãå¿ èŠãããããã®äœ¿çšéã¯ãé»è·çºçç©è³ªïŒé
ééšåœãïŒãïŒéééšã§ãããïŒéééšãè¶ãã
ãšé»ååçç¹æ§ãäœäžããããã®ä»ãäžèšå¯å¡
å€ãæ·»å å€ã¯ãé»è·çºçç©è³ªã«å¯ŸããŠæ°ééïŒ ä»¥
äžã§é©å®äœ¿çšãããããŸããé»è·æ¬éå±€ã¯ãäžè¬
åŒïŒïŒã§è¡šãããããªããµãŸãŒã«èªå°äœãé»è·
æ¬éç©è³ªãšããŠåç¬ã§çšããå Žåã«ã¯ãäžèšã®çµ
åå€ãé»è·æ¬éç©è³ªïŒéééšåœãïŒãïŒéééšçš
ããã®ãäžè¬çã§ããããŸããä»ã®é»è·æ¬éç©è³ª
ã䜵çšããå Žåã該é»è·æ¬éç©è³ªãé«ååååç©
ã®ãšãã«ã¯ãçµåå€ãçšããªããŠããããã該é«
ååååç©ïŒéééšã«å¯Ÿãçµåå€ãïŒéééšä»¥äž
ã§äœ¿çšããŠããããïŒéééšãè¶ãããšé»ååç
ç¹æ§ãäœäžããããŸããäžèšé»è·æ¬éæ§ç©è³ªãšã
ãŠäœååååç©ã䜵çšãããšãã¯ãçµåå€ã¯äžè¬
åŒïŒïŒã®ãªããµãŸãŒã«èªå°äœåã³è©²äœåååå
ç©ã®ç·éïŒéééšã«å¯ŸããŠ0.3ãïŒéééšäœ¿çšã
ããã0.3éééšæªæºã§ã¯é»è·æ¬éå±€ã®åœ¢æãå°
é£ã«ãªããïŒéééšãè¶ãããšé»ååçç¹æ§ãäœ
äžããããã®ä»äžèšå¯å¡å€ãæ·»å å€ã¯äžèšé»è·æ¬
éæ§ç©è³ªïŒéééšã«å¯ŸããŠ0.05éééšä»¥äžã§é©å®
䜿çšããããé»è·çºçå±€ã®åãã¯0.01ã10ÎŒïœã
奜ãŸããã¯0.2ã5ÎŒïœãæãŸããã0.01ÎŒïœæªæºã§
ã¯ãé»è·çºçå±€ãåäžã«åœ¢æããã®ãå°é£ã«ãª
ãã10ÎŒïœãè¶ãããšé»ååçç¹æ§ãäœäžããã
ãŸããé»è·æ¬éå±€ã®åãã¯ïŒã50ÎŒïœã奜ãŸãã
ã¯ïŒã25ÎŒïœã§ããã5ÎŒïœæªæºã§ã¯åæé»äœãäœ
äžãã50ÎŒïœãè¶ãããšæ床ãäœäžããã ãããããããã®å Žåãæçµçã«ã¯å æ床å³ã¡
垯é»ç¹æ§ãæããªãããã«é æ ®ããŠæ±ºå®ããã®ã
æãŸãããå å°é»å±€ã®åããããŸãåããªããã
ããšå±€èªäœã®å¯ææ§ãäœäžããæ§ããããã®ã§æ³š
æãèŠããã æ¬çºæã®é»ååçæå äœããé»è·çºçå±€ãé»è·
æ¬éå±€ããã€äºå±€æ§é ãšããå Žåãå°é»æ§æ¯æäœ
ã®äžã«é»è·çºçå±€ã圢æãããã®äžã«é»è·æ¬éå±€
ã圢æãããã®ããé»ååçç¹æ§äžå¥œãŸãããã
é»è·çºçå±€ãšé»è·æ¬éå±€ãéã«ãªã€ãŠããŠãã
ããå°é»æ§æ¯æäœã«ã¯ã¢ã«ãããŠã ãçã¡ããã
é ãéãªã©ãçšããããã å°é»æ§æ¯æäœäžã«é»è·çºçå±€ããã³é»è·æ¬éå±€
ãããªãäºå±€ã圢æããã«ã¯ãåå±€ã®æåãã¢ã»
ãã³ãã¡ãã«ãšãã«ã±ãã³çã®ã±ãã³ç³»æº¶å€ãã
ãã©ããããã©ã³çã®ãšãŒãã«ç³»æº¶å€ããã«ãš
ã³ããã·ã¬ã³çã®è³éŠæ系溶å€çã®æº¶å€ã«åäžã«
溶解ãŸãã¯åæ£ãããã®ã¡ãå°é»æ§æ¯æäœäžã«å¡
åžä¹Ÿç¥ããããšãã§ããããã®ãã¡ãé»è·çºçå±€
ãŸãã¯é»è·æ¬éå±€ã圢æãããã®ã¡ããã®äžã«é»
è·æ¬éå±€ãŸãã¯é»è·çºçå±€ãåæ§ã«å¡åžä¹Ÿç¥ããŠ
äºå±€æ§é ãšããããšãã§ããã å¡åžä¹Ÿç¥ã¯ãäŸãã°ãã¯ã¿ãŒãã¬ãŒããçšããŠ
æå®ã®èåã«å¡å·¥ãã15åéèªç¶ä¹Ÿç¥ãããåŸã
80ã110âã§40åé也ç¥ããŠè¡ãªãããšãã§ããã æ¬çºæã«ä¿ãé»ååçæå äœã¯ãããã«å°é»æ§
æ¯æäœã®ããäžã«èãæ¥çå±€ãããªã€å±€ãæããŠ
ããŠãããããŸããè¡šé¢ã«ã·ãªã³ã³çã®ä¿è·å±€ã
èšããããšãã§ããã æ¬çºæã«ãªãé»ååçæå äœãçšããè€åæ³ã¯
åŸæ¥ãšåæ§ãè¡šé¢ã«åž¯é»ãé²å ãæœããåŸãçŸå
ãè¡ãªããæ®éçŽäžã«ç»åã転åãå®çããã°ã
ãã æ¬çºæã«ãªãé»ååçæå äœã¯ãé«ãæ床ãæ
ããäžã€ææžè¡°ãå°ãããå ç²åŽãå°ãªããªã©åª
ããå©ç¹ãæããŠããã äžè¬åŒïŒïŒã§è¡šãããããªããµãŸãŒã«èªå°äœ
ãšããŠã¯ãïŒâïŒïŒâãžãããã«ã¢ããããšãã«ïŒ
âïŒâïŒïŒâãžã¡ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒ
âãã«ãªã«ããšãã«ïŒâïŒïŒïŒâãªããµãŸãŒã«ã
ïŒâïŒïŒâãžãšãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâ
ãžã¡ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâãã«ãªã«ã
ãšãã«ïŒâïŒïŒïŒâãªããµãŸãŒã«ãïŒâïŒïŒâãžã¡
ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâãžã¡ãã«ã¢ãã
ããšãã«ïŒâïŒâïŒïŒâãã«ãªã«ããšãã«ïŒâïŒïŒ
ïŒâãªããµãŸãŒã«ãïŒâïŒïŒâãžãããã«ã¢ãã
ããšãã«ïŒâïŒâïŒïŒâãžãšãã«ã¢ããããšãã«ïŒ
âïŒâïŒïŒâãã«ãªã«ããšãã«ïŒâïŒïŒïŒâãªããµ
ãŸãŒã«ãïŒâïŒïŒâãžãšãã«ã¢ããããšãã«ïŒâïŒ
âïŒïŒâãžãšãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâã
ã«ãªã«ããšãã«ïŒâïŒïŒïŒâãªããµãŸãŒã«ãïŒâ
ïŒïŒâãžã¡ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâãžãš
ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâãã«ãªã«ããšã
ã«ïŒâïŒïŒïŒâãªããµãŸãŒã«ãïŒâïŒïŒâãžã¡ãã«
ã¢ããããšãã«ïŒâïŒâïŒïŒâãžãããã«ã¢ããã
ãšãã«ïŒâïŒâïŒïŒâãã«ãªã«ããšãã«ïŒâïŒïŒïŒ
âãªããµãŸãŒã«çãããã äžè¬åŒïŒïŒã§è¡šãããããªããµãŸãŒã«èªå°äœ
ã¯ã ïŒãã ããåŒäžãR1ããã³R2ã¯ã¡ãã«åºããš
ãã«åºããããã«åºçã®ã¢ã«ãã«åºã瀺ãããã
ãã¯åäžã§ãç°ãªã€ãŠããŠãããïŒã§è¡šãããã
ååç©ãšãäžè¬åŒ(B) ïŒãã ããåŒäžãR3ããã³R4ã¯ãã¡ãã«åºã
ãšãã«åºããããã«åºçã®ã¢ã«ãã«åºã瀺ããã
ããã¯åäžã§ãç°ãªã€ãŠããŠãããïŒã§è¡šããã
ãååç©ãåå¿ãããããšã«ãã€ãŠåŸãããšãã§
ããã åŒ(A)ã§è¡šããããååç©ã¯ãäŸãã°ãïŒâãžã¡
ãã«ã¢ãããã³ãºã¢ã«ããããïŒâãã«ãªããã³
ãºã¢ã«ãããããã³KCNããããããïŒã¢ã«ã
ïŒã¢ã«ããã³0.1ã1.5ã¢ã«ã®å²åã§50ïŒ ãšã¿ããŒ
ã«æ°Žæº¶æ¶²äžã«å ã1.5ãïŒæéå ç±éæµãããã
ãšã«ãã補é ã§ããã äžè¬åŒ(B)ã§è¡šããããååç©ã¯ãäŸãã°äžèšã®
åŒïŒïŒã§è¡šããããåå¿åŸè·¯ã«ããåæã§ã
ããããªãã¡ãã¢ããªã³ïŒã¢ã«ãšäžè¬åŒ(C) ïŒROïŒ3PO (C) ïŒãã ãåŒäžïŒ²ã¯ãã¡ãã«åºããšãã«åºããã
ãã«åºçã®ã¢ã«ãã«åºã瀺ããäžã€ã®ïŒ²ã¯åäžã§
ãç°ãªã€ãŠããŠãããïŒã§è¡šããããååç©0.67
ã¢ã«ãïŒæéå ç±éæµããŠåå¿ãããæžå§èžçã
ãŠãžã¢ã«ãã«ã¢ããªã³ïŒããã§ãã¢ã«ãã«åºãšã
ãŠã¯ã¡ãã«ããšãã«åºããããã«åºçãããã以
äžåãïŒãåŸããç¶ããŠãïŒïŒ®âãžã¡ãã«ãã«
ã ã¢ããïŒã¢ã«ã«ãžã¢ã«ãã«ã¢ããªã³0.3ã0.4ã¢
ã«ã19ã22âã§æ»Žäžãã滎äžçµäºåŸ90ã95âã§ïŒ
æéåå¿ããæžå§èžçããŠãžã¢ã«ãã«ã¢ãããã³
ãºã¢ã«ããããåŸãããžã¢ã«ãã«ã¢ãããã³ãºã¢
ã«ãããïŒã¢ã«ã«å¯ŸããŠå¡©é žããããã·ã¢ãã³
1.0ã1.3ã¢ã«ã宀枩ã§20åéåå¿ãããåå¿æ¶²ã
å·èµåº«äžã«æŸçœ®ããŠãžã¢ã«ãã«ã¢ãããã³ãºã¢ã«
ãããã»ãªãã·ã ãæåºããããæåŸã«ãžã¢ã«ã
ã«ã¢ãããã³ãºã¢ã«ãããã»ãªãã·ã ïŒã¢ã«ã«å¯Ÿ
ããŠç¡æ°Žé ¢é žïŒãïŒã¢ã«ã20åéå ç±éæµããŠè±
æ°Žåå¿ããäžè¬åŒ(B)ã§è¡šããããååç©ã補é ã
ãããšãã§ããã äžèšã«ãããŠããžã¢ã«ãã«ã¢ãããã³ãºã¢ã«ã
ãããããžã¢ã«ãã«ã¢ãããã³ãŸãããªã«ãçæ
ãããããã«ã¯ãäžèšåŒïŒïŒ¹ïŒã®åŸè·¯ã«ãã€ãŠè¡
ãªãããšãã§ããã ããªãã¡ããžã¢ã«ãã«ã¢ãããã³ãºã¢ã«ããã
ïŒã¢ã«ã«å¯ŸããŠNH2OHã»HCl1.15ã¢ã«ã
HCOONa倧éå°ããã³ã®é žçŽ1500c.c.ãæ··åãã
éæµäžã«ïŒæéåå¿ããããã®åŸãçŽã¡ã«åå¿æ¶²
ãæ°Žäžã«å ãããšãžã¢ã«ãã«ã¢ãããã³ãŸãããª
ã«ã®æ²æ®¿ãæåºããããã®æ²æ®¿ãæ°Žã§åçµæ¶ãã
ã°ããã äžè¬åŒïŒïŒã§è¡šããããååç©ã¯ãåŒ(A)ãã
ã³äžè¬åŒ(B)ã§è¡šããããååç©ãæ¿ç¡«é žã«æº¶è§£ã
ããææã§åå¿ãããããšã«ããåŸããããåå¿
枩床ã¯20ã70âã奜ãŸãããåå¿æž©åºŠã50ã70â
ã«ãããš0.5ãïŒæéã§åå¿ã¯çµäºãããåå¿ç©
ã®ç²Ÿè£œã¯ã¡ã¿ããŒã«ã«ããåçµæ¶ã«ãã€ãŠãããª
ãããšãã§ããã äžè¬åŒ(A)ããã³äžè¬åŒ(B)ã§è¡šããããååç©
ã¯ãåå¿åã«äºãæ··åããŠããã®ã奜ãŸãããäž
è¬åŒ(A)ã®ååç©ãåç¬ã§æ¿ç¡«é žã«æ·»å ãããšæ¿ç¡«
é žã«ããäžè¬åŒ(B)ã§è¡šããããååç©ãšåå¿ãã
åã«è±æ°Žåå¿ããããŠããŸãã ïŒå®æœäŸïŒ 以äžã«æ¬çºæã®å®æœäŸã瀺ãã å®æœäŸ ïŒãïŒ Ïåç¡éå±ãã¿ãã·ã¢ãã³ïŒæ±æŽã€ã³ã補é (æ ª)
補ïŒïŒéééšãšã·ãªã³ãŒã³æš¹èïŒä¿¡è¶ååŠå·¥æ¥(æ ª)
åååïŒKR255ïŒ6.7éééšãããã©ããããã©
ã³ã溶å€ãšããïŒééïŒ ã®æº¶æ¶²ã«ãªãããã«ã
ãŠãããŒã«ãã«ïŒæ¥æ¬ååŠé¶æ¥è£œïŒå¯žãããã
ã«ïŒã§ïŒæéæ··ç·ŽãããåŸãããé¡æåæ£æ¶²ãã¢
ããªã±ãŒã¿ã«ããã¢ã«ãããŠã æ¿ïŒå°é»äœïŒäžã«
å¡å·¥ãã90âã§40åé也ç¥ããŠåã1ÎŒïœã®é»è·
çºçå±€ã圢æããã 次ã«äžèšç¬¬ïŒè¡šã«ç€ºãããªããµãŸãŒã«èªå°äœïŒ
éééšãããªãšã¹ãã«æš¹èïŒæ±æŽçŽ¡çžŸ(æ ª)åååã
ãã€ãã³200ïŒ2.4éééšããã³ã¹ãã¬ã³æš¹èïŒãš
ããœç€Ÿè£œããã³ããã¯ã¹100ïŒ0.6éééšãããã©
ããããã©ã³ã溶å€ãšãã27ééïŒ ã®æº¶æ¶²ãšãã
äžèšé»è·çºçå±€ã®äžã«ã¢ããªã±ãŒã¿ã«ããå¡å·¥ã
90âã§40åé也ç¥ããŠåã30ÎŒïœã®é»è·æ¬éå±€ã
圢æããŠé»ååçæå äœãåŸãã ãã®ããã«ããŠäœæããé»ååçæå äœã«ã€
ããéé»èšé²çŽè©Šéšè£ 眮ïŒå·å£é»æ©(æ ª)åååSP
â428ïŒãçšããŠé»ååçç¹æ§ã枬å®ããããã®
å Žåãè² 5KVã®ã³ããæŸé»ã10ç§éè¡ãªã€ãŠåž¯
é»ããïŒ10ç§é垯é»åŸã®è¡šé¢é»äœV0ïŒïŒ¶ïŒãåæ
é»äœãšããïŒã30ç§éææã«æŸçœ®åŸïŒãã®æå»ã®
è¡šé¢é»äœãV30ïŒïŒ¶ïŒã§è¡šãããV30ïŒV0Ã100ã
ææžè¡°ïŒïŒ ïŒãšããïŒãã¿ã³ã°ã¹ãã³ç¯ã§ãè¡šé¢
ãïŒã«ã¯ã¹ã«ãªãããã«é²å ãããã®æã®è¡šé¢é»
äœã®æžè¡°åã³æéãèšé²ããV30ã1/2ã«ãªããŸ
ã§ã®æéïœïŒç§ïŒãšç §åºŠïŒã«ã¯ã¹ïŒã®ç©ã§æ床
ïŒåæžé²å éE50ãã«ã¯ã¹ã»ç§åäœïŒãè¡šãããã
ãŸããåå æ床ã¯ãã¿ã³ã°ã¹ãã³ã©ã³ãã®æ¿ã
ã«ãåå åšããã®åã ã®æ³¢é·ãå æºãšããV30ã
ïŒïŒïŒã«ãªããŸã§ã«èŠããæéïœïŒç§ïŒãšåæ³¢é·ã®ãš
ãã«ã®ãŒïŒÎŒWïŒcm2ïŒãšã®ç©ã®éæ°ã§æ床ïŒm2ïŒ
ïœïŒªïŒãšããããããã®çµæãäžèšç¬¬ïŒè¡šã«ç€ºã
ãã å®æœäŸ ïŒãïŒ Ïâ²åç¡éå±ãã¿ãã·ã¢ãã³ïŒæ±æŽã€ã³ã補é
(æ ª)ïŒïŒéééšãšã·ãªã³ãŒã³æš¹èïŒä¿¡è¶ååŠå·¥æ¥(æ ª)
åååãKB255ïŒ6.7éééšãããã©ããããã©
ã³ã溶å€ãšããŠïŒééïŒ ã®æº¶æ¶²ã«ãªãããã«ã
ãŠãããŒã«ãã«ïŒæ¥æ¬ååŠé¶æ¥è£œãïŒå¯žãããã
ã«ïŒã§ïŒæéåæ£ããåŸãããåæ£æ¶²ãå®æœäŸïŒ
ãïŒãšåæ§ã®æ¹æ³ã§å¡å·¥ã也ç¥ããåã1ÎŒïœã®
é»è·çºçå±€ã圢æããã 次ã«äžèšç¬¬ïŒè¡šã«ç€ºãããªããµãŸãŒã«èªå°äœïŒ
éééšãšããªãšã¹ãã«æš¹èïŒæ±æŽçŽ¡çžŸ(æ ª)åååã
ãã€ãã³200ïŒ2.4éééšããã³ã¹ãã¬ã³æš¹èïŒãš
ããœç€Ÿè£œããã³ããã¯ã¹100ïŒ0.6éééšãããã©
ããããã©ã³ã溶å€ãšãã27ééïŒ ã®æº¶æ¶²ãšãã
äžèšé»è·çºçå±€ã®äžã«ã¢ããªã±ãŒã¿ã«ããå¡å·¥ã
90âã§40åé也ç¥ããŠåã15ÎŒïœã®é»è·æ¬éå±€ã
圢æããŠé»ååçæå äœãåŸãã ãã®ããã«ããŠäœæããé»ååçæå äœã®ç¹æ§
ãå®æœäŸïŒãïŒãšåæ§ã«æž¬å®ããçµæã第ïŒè¡šã«
èšããã å®æœäŸ ïŒãïŒ Î·åç¡éå±ãã¿ãã·ã¢ãã³ïŒæ±æŽã€ã³ã補é (æ ª)
補ïŒïŒéééšãšã·ãªã³ãŒã³æš¹èïŒä¿¡è¶ååŠå·¥æ¥(æ ª)
åååãKR255ïŒ6.7éééšãããã©ããããã©
ã³ã溶å€ãšããŠïŒééïŒ ã®æº¶æ¶²ã«ãªãããã«ã
ãŠãããŒã«ãã«ïŒæ¥æ¬ååŠé¶æ¥è£œãïŒå¯žãããã
ã«ïŒã§ïŒæéåæ£ããåŸãããåæ£æ¶²ãå®æœäŸïŒ
ãïŒãšåæ§ã®æ¹æ³ã§å¡å·¥ã也ç¥ããåã1ÎŒïœã®
é»è·çºçå±€ã圢æããã 次ã«äžèšç¬¬ïŒè¡šã«ç€ºãããªããµãŸãŒã«èªå°äœïŒ
éééšãšããªãšã¹ãã«æš¹èïŒæ±æŽçŽ¡çžŸ(æ ª)åååã
ãã€ãã³200ïŒ2.4éééšããã³ã¹ãã¬ã³æš¹èïŒãš
ããœç€Ÿè£œããã³ããã¯ã¹100ïŒ0.6éééšãããã©
ããããã©ã³ã溶å€ãšãã27ééïŒ ã®æº¶æ¶²ãšãã
äžèšé»è·çºçå±€ã®äžã«ã¢ããªã±ãŒã¿ã«ããå¡å·¥ã
90âã§40åé也ç¥ããŠåã15ÎŒïœã®é»è·æ¬éå±€ã
圢æããŠé»ååçæå äœãåŸãã ãã®ããã«ããŠäœæããé»ååçæå äœã®ç¹æ§
ãå®æœäŸïŒãïŒãšåæ§ã«æž¬å®ããçµæã第ïŒè¡šã«
èšããã å®æœäŸ 10ã12 ηâ²åç¡éå±ãã¿ãã·ã¢ãã³ïŒæ±æŽã€ã³ã補é (æ ª)
補ïŒïŒéééšãšã·ãªã³ãŒã³æš¹èïŒä¿¡è¶ååŠå·¥æ¥(æ ª)
åååãKR255ïŒ6.7éééšãããã©ããããã©
ã³ã溶å€ãšããŠïŒééïŒ ã®æº¶æ¶²ã«ãªãããã«ã
ãŠãããŒã«ãã«ïŒæ¥æ¬ååŠé¶æ¥è£œãïŒå¯žãããã
ã«ïŒã§ïŒæéåæ£ããåŸãããåæ£æ¶²ãå®æœäŸïŒ
ãïŒãšåæ§ã®æ¹æ³ã§å¡å·¥ã也ç¥ããåã1ÎŒïœã®
é»è·çºçå±€ã圢æããã 次ã«äžèšç¬¬ïŒè¡šã«ç€ºãããªããµãŸãŒã«èªå°äœïŒ
éééšãšããªãšã¹ãã«æš¹èïŒæ±æŽçŽ¡çžŸ(æ ª)åååã
ãã€ãã³200ïŒ2.4éééšããã³ã¹ãã¬ã³æš¹èïŒãš
ããœç€Ÿè£œããã³ããã¯ã¹100ïŒ0.6éééšãããã©
ããããã©ã³ã溶å€ãšãã27ééïŒ ã®æº¶æ¶²ãšãã
äžèšé»è·çºçå±€ã®äžã«ã¢ããªã±ãŒã¿ã«ããå¡å·¥ã
90âã§40åé也ç¥ããŠåã15ÎŒïœã®é»è·æ¬éå±€ã
圢æããŠé»ååçæå äœãåŸãã ãã®ããã«ããŠäœæããé»ååçæå äœã®ç¹æ§
ãå®æœäŸïŒãïŒãšåæ§ã«æž¬å®ããçµæã第ïŒè¡šã«
èšããã
å äœã«ä¿ããç¹ã«é·æ³¢é·ã®å ã«å¯ŸããŠãé«æ床ã
æããé»è·çºçç©è³ªãšååŠçã«å®å®ãªæ°èŠãªãªã
ãµãŸãŒã«èªå°äœãšããæ§æãããé»ååççšæå
äœã«é¢ããã ïŒåŸæ¥æè¡ïŒ åŸæ¥ãé·æ³¢é·ã®å ã«å¯ŸããŠé«æ床ãæããé»å
åçæå äœã«ãããŠãé»è·çºçç©è³ªãšããŠÏåã
Ïâ²åãηåããã³Î·â²åç¡éå±ãã¿ãã·ã¢ãã³ã®ã
ã¡å°ãªããšãäžçš®é¡ã䜿çšããé»è·æ¬éç©è³ªãšã
ãŠïŒâïŒïŒâãžãããã«ã¢ããããšãã«ïŒâïŒâ
ïŒïŒâãžã¡ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâã¯ã
ãããšãã«ïŒâïŒïŒïŒâãªããµãŸãŒã«ãååç©
ïŒïŒããïŒâïŒïŒâãžãšãã«ã¢ããããšãã«ïŒâïŒ
âïŒïŒâïŒãžã¡ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâã¯
ããããšãã«ïŒâïŒïŒïŒâãªããµãŸãŒã«ãååç©
ïŒïŒããïŒâïŒïŒâãžã¡ãã«ã¢ããããšãã«ïŒâïŒ
âïŒïŒâãžã¡ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâã¯
ããããšãã«ïŒâïŒïŒïŒâãªããµãŸãŒã«ãååç©
ïŒïŒããªã©ã®ãªããµãŸãŒã«èªå°äœã®ãã¡å°ãªããš
ãäžçš®é¡ããæ§æãããã¬ãŒã¶ãŒããŒã ããªã³ã¿
ãŒçšé»ååçæå äœãïŒç¹éæ58â182639å·å ¬
å ±ãç¹éæ58â182640å·å ¬å ±ïŒç¥ãããŠãããã
ãããäžèšãªããµãŸãŒã«èªå°äœã¯ç¹ã«ã溶液ç¶æ
ã«ãããŠçŽ«å€ç·ã®ç §å°ã«ãããèãã容æã«å解
ããå解çæç©ãšããŠäž»ã«ïŒâïŒïŒâãžãããã«
ã¢ããããšãã«ïŒâïŒâãžã¡ãã«ã¢ããããšãã³
ãããïŒïŒ10âïœããªããµãŸãŒã«ãçæãããã®
ç¹æ§ãå£å€±ããããåãæ±ãã«æ³šæãèŠããç¹
ã«ãé»ååçæå äœã®è£œé äžã«ãã®ç¹æ§ãå£å€±ã
ããããšããæ¬ ç¹ãæããã æ¬çºæã¯ããã®ãããªåé¡ç¹ã解決ãããã®ã§
ãããæ°èŠãªååç©ã§ãã€ãŠçŽ«å€ç·ã®ç §å°ã«å¯Ÿã
ãŠå®å®ãªæ§è³ªãæãããªããµãŸãŒã«èªå°äœãå«æ
ããé·æ³¢é·ã®å ã«å¯ŸããŠé«æ床ã瀺ãåªããé»å
åçç¹æ§ãæããé»ååçæå äœãæäŸãããã®
ã§ãããç¹ã«ãã®è£œé äžã«ããã®ç¹æ§ãå£å€±ããª
ãé»ååçæå äœãæäŸãããã®ã§ããã ïŒçºæã®æ§æïŒ å°é»æ§æ¯æäœäžã«ãé»è·çºçç©è³ªãå«ãé»è·çº
çå±€åã³é»è·æ¬éç©è³ªãå«ãé»è·æ¬éå±€ãæãã
è€ååã®é»ååçæå äœã«ãããŠãåèšé»è·çºç
ç©è³ªããÏåãÏâ²åãηååã³Î·â²åç¡éå±ãã¿ã
ã·ã¢ãã³ã®ãã¡å°ãªããšãäžçš®é¡ãå«ã¿ãé»è·æ¬
éç©è³ªããäžè¬åŒïŒïŒ ïŒãã ããåŒäžR1ïŒR2ïŒR3ããã³R4ã¯ãã¢ã«
ãã«åºã瀺ããããã¯åäžã§ãç°ãªã€ãŠãããïŒ
ã§è¡šããããªããµãŸãŒã«èªå°äœã§ããããšãç¹åŸŽ
ãšããé»ååçæå äœã«é¢ããã äžèšäžè¬åŒïŒïŒã§è¡šããããååç©ã¯ãäžèš
ååç©ïŒïŒïŒïŒïŒããã³ïŒïŒã«ãããClåå
ã®ãããã«ïŒŠååãæãããã®ã§ãããããã«ã
ãã玫å€ç·ã«å¯ŸããŠãå®å®æ§ãéåžžã«å€§ããã玫
å€ç·ãç §å°ãããŠãå解ããããšããªããé»åå
çæå äœã«å®å®ãªåªããç¹æ§ãäžãããã®ã§ã
ãã äžè¬åŒïŒïŒã§è¡šãããããªããµãŸãŒã«èªå°äœ
ã¯ãäž»ã«é»è·æ¬éç©è³ªãšããŠæ©èœããããã®åå
ç©ã¯ä»ã®é»è·æ¬éç©è³ªãäŸãã°é«ååååç©ã®ã
ã®ã§ã¯ããªââããã«ã«ã«ããŸãŒã«ãããã²ã³
åããªââããã«ã«ã«ããŸãŒã«ãããªããã«ã
ã¬ã³ãããªããã«ã€ã³ããããããµãªã³ãããªã
ãã«ãã³ãŸããªããšã³ãããªããã«ã¢ã³ãã©ã»
ã³ãããªããã«ã¢ã¯ãªãžã³ãããªããã«ãã©ãŸãª
ã³çããäœååååç©ã®ãã®ã§ã¯ãã«ãªã¬ã³ãã
ã«ãªã¬ãã³ãïŒïŒïŒâãžãããâïŒâãã«ãªã¬ã
ã³ãïŒïŒïŒïŒïŒâããªãããâïŒâãã«ãªã¬ã
ã³ã4Hâã€ã³ããïŒïŒïŒïŒïŒïŒïŒããªããšã³â
ïŒâãªã³ãïŒïŒïŒâãžãããâãžãã³ãŸããªããš
ã³âïŒâãªããµã€ããïŒâããã ãã¬ã³ãïŒâã
ãšãã«ãã¬ã³ãã«ã«ããŸãŒã«ãïŒâããšãã«ã«ã«
ããŸãŒã«ãïŒâããšãã«ã€ã³ããŒã«ãïŒâããšã
ã«ããã¿ã¬ã³ããªããµãžã¢ãŸãŒã«ãããªã¢ãŸãŒ
ã«ãïŒâããšãã«âïŒâïŒïŒâãžãšãã«ã¢ããã¹
ããªã«ïŒâïŒâïŒïŒâãžãšãã«ã¢ããããšãã«ïŒã
ã©ãŸãªã³ãïŒâããšãã«âïŒâïŒïŒâãžãšãã«ã¢
ããããšãã«ïŒâïŒâããšãã«ãªããµãŸãŒã«ãã
ãªããšãã«ã¢ãã³ãã€ãããŸãŒã«ãã¯ãªã»ã³ãã
ãã©ããšã³ãã¢ã¯ãªãã³ããããã®èªå°äœçãšäœµ
çšããããšãã§ãããä»ã®é»è·æ¬éç©è³ªã®é åå²
åã¯ãäžè¬åŒïŒïŒã§è¡šãããããªããµãŸãŒã«èª
å°äœã«ããé»ååçç¹æ§ã®åäžãæããªãããã«
該èªå°äœïŒéééšã«å¯ŸããŠïŒéééšä»¥äžã奜ãŸã
ããç¹ã«0.25éééšä»¥äžã奜ãŸããã æ¬çºæã«ãããŠäœ¿çšãããé»è·çºçææã§ãã
ÏïŒÏâ²ïŒÎ·åã³Î·â²åç¡éå±ãã¿ãã·ã¢ãã³ã¯ãç¹
é58â182640å·å ¬å ±åã³ãšãŒãããç¹èš±å ¬é第
92255å·å ¬å ±ã«èšèŒããããã®ã§ããã Ïåç¡éå±ãã¿ãã·ã¢ãã³ã¯ããã©ãã°è§åºŠ
ïŒ2Ξ±0.2床ïŒã7.6ïŒ9.2ïŒ16.8ïŒ17.4ïŒ20.4åã³
20.9ã«ç¹åŸŽçãªããŒã¯ãæããç·åæãã¿ãŒã³
ãæããç¹ã«ãèµ€å€ç·åžåã¹ãã«ãã«ã700ã760
cm-1ã®éã«751±ïŒcm-1ãæã匷ãïŒæ¬ã®åžå垯
ãã1320ã1340cm-1ã®éã«ã»ãŒåã匷ãã®ïŒæ¬ã®
åžå垯ãã3288±ïŒcm-1ã«ç¹åŸŽçãªåžåãæãã
ãã®ã奜ãŸããã Ïâ²åç¡éå±ãã¿ãã·ã¢ãã³ã¯ããã©ãã°è§åºŠ
ïŒ2Ξ±0.2床ïŒã7.5ïŒ9.1ïŒ16.8ïŒ17.3ïŒ20.3ïŒ20.8ïŒ
21.4åã³27.4ã«åŒ·ãããŒã¯ãæããç·åæãã¿
ãŒã³ãæããèµ€å€ç·åžåã¹ãã¯ãã«ã700ã760cm
âïŒã®éã«753ïŒÂ±ïŒïŒcm-1ãæã匷ãïŒæ¬ã®åžå垯
ãã1320ã1340cm-1ã®éã«ïŒæ¬ã®ã»ãŒåã匷ãã®
åžå垯ãã3297±ïŒcm-1ã«ç¹åŸŽçãªåžåãæãã
ãã®ãæãŸããã ηååã³Î·â²åç¡éå±ãã¿ãã·ã¢ãã³ã¯ãç¡éå±
ãã¿ãã·ã¢ãã³100éééšãšãã³ãŒã³æ žã«çœ®æåº
ãæããç¡éå±ãã¿ãã·ã¢ãã³ããã³ãŒã³æ žã«çœ®
æåºãæããŠããŠããããã¿ãã·ã¢ãã³çªçŽ åæ§
äœè¥ããã¯éå±ãã¿ãã·ã¢ãã³ã®äžçš®è¥ããã¯äº
皮以äž50éééšä»¥äžãšã®æ··åç©çµæ¶ã§ãããηã
ãã³Î·â²åã¯ãåã ãäºçš®é¡ãã€ååšããã ηåç¡éå±ãã¿ãã·ã¢ãã³ã¯ãèµ€å€ç·åžåã¹ã
ã¯ãã«ã700ã760cm-1ã®éã«753±ïŒcm-1ãæã
匷ãïŒæ¬ã®åžå垯ãã1320ã1340cm-1ã®éã«ïŒæ¬
ã®ã»ãŒåã匷ãã®åžå垯ãã3285±ïŒcm-1ã«ç¹åŸŽ
çãªåžåãæãããηåç¡éå±ãã¿ãã·ã¢ãã³ã®
ãã¡äžçš®ã¯ããã©ãã°è§åºŠïŒ2Ξ±0.2床ïŒãã
7.6ïŒ9.2ïŒ16.8ïŒ17.4åã³28.5ã«ç¹åŸŽçãªããŒã¯ã
æããç·åæãã¿ãŒã³ãæããä»ã®äžçš®ã¯ã
7.6ïŒ9.2ïŒ16.8ïŒ17.4ïŒ21.5åã³27.5ã«ç¹åŸŽçãªã
ãŒã¯ãæããç·åæãã¿ãŒã³ãæããã ηâ²åç¡éå±ãã¿ãã·ã¢ãã³ã¯ãèµ€å€ç·åžåã¹ã
ã¯ãã«ã700ã760cm-1ã®éã«ã753±ïŒcm-1ãæ
ã匷ãïŒæ¬ã®åžå垯ãã1320ã1340cm-1ã«ïŒæ¬ã®
ã»ãŒåã匷ãã®åžå垯ãã3297±ïŒcm-1ã«ç¹åŸŽç
ãªåžåãæãããηâ²åç¡éå±ãã¿ãã·ã¢ãã³ã®äž
çš®ã¯ããã©ãã°è§åºŠïŒ2Ξ±ïŒåºŠïŒã7.5ïŒ9.1ïŒ
16.8ïŒ17.3ïŒ20.3ïŒ20.8ïŒ21.4åã³27.4ã«ç¹åŸŽçãª
ããŒã¯ãæããåç·åæãã¿ãŒã³ãæããä»ã®äž
çš®ã¯ã7.5ïŒ9.1ïŒ16.8ïŒ17.3ïŒ20.3ïŒ20.8ïŒ21.4ïŒ
22.1ïŒ27.4åã³28.5ã«ç¹åŸŽçãªããŒã¯ãæãã
ç·åæãã¿ãŒã³ãæããã Ïåã³Ïâ²åç¡éå±ãã¿ãã·ã¢ãã³ã¯ãäŸãã°Î±
åç¡éå±ãã¿ãã·ã¢ãã³ã液äœåæ£åªã«åæ£ãã
磚ç å©å€ã®ååšäžã«50ã180âã奜ãŸããã¯60ã
130âã®æž©åºŠã§çµæ¶å€æããã®ã«ååãªæéãæª
æè¥ããã¯æ©æ¢°çæªåããã€ãŠããªã³ã°ããããš
ã«ãã補é ããããšãã§ããã ηåã³Î·â²åç¡éå±ãã¿ãã·ã¢ãã³ã¯ãäŸãã¯ã
αåç¡éå±ãã¿ãã·ã¢ãã³100éééšãšãã³ãŒã³
æ žã«çœ®æåºãæããç¡éå±ãã¿ãã·ã¢ãã³ããã«
ãã€ã³ååç©çã®ãã³ãŒã³æ žã«çœ®æåºãæããŠã
ãŠããããã¿ãã·ã¢ãã³çªçŽ åæ§äœè¥ããã¯éå±
ãã¿ãã·ã¢ãã³50éééšä»¥äžã奜ãŸããã¯0.1ã
30éééšãšã液äœåæ£åªã«åæ£ãã磚ç å©å€ã®å
åšäžã«30ã220âã奜ãŸããã¯60ã130âã§çµæ¶å€
æããã®ã«ååãªæéãæªæè¥ããã¯æ©æ¢°çæªå
ããã€ãŠããªã³ã°ããããšã«ãã補é ããããšã
ã§ããã å å°é»äœå±€ã«ã¯ãæ¢ç¥ã®çµåå€ãå¯å¡å€ãæµå
æ§ä»äžå€ããã³ããŒã«æå¶å€çã®æ·»å å€ã䜿çšã
ãããšãã§ãããçµåå€ãšããŠã¯ãç·ç¶é£œåããª
ãšã¹ãã«æš¹èãããªã«ãŒãããŒãæš¹èãã¢ã¯ãªã«
系暹èãããã©ãŒã«æš¹èãããªã±ãã³æš¹èãããª
ãŠã¬ã¿ã³æš¹èãããªââããã«ã«ã«ããŸãŒã«ã
ããªâïŒïœâããã«ããšãã«ïŒã¢ã»ãã©ã»ã³ãã·
ãªã³ãŒã³æš¹èãããªã¢ããæš¹èããšããã·æš¹èã
ããªã¹ãã¬ã³æš¹èãªã©ãéžã°ããã ãŸããç±åã³ïŒãŸãã¯å ã«ãã€ãŠæ¶æ©ããç±ç¡¬
åååã³å 硬ååæš¹èã䜿çšã§ããããããã«ã
ãŠã絶çžæ§ã§éåžžã®ç¶æ ã§ç®è圢æèœãæããæš¹
èåã³ïŒãŸãã¯å ã«ãã€ãŠç¡¬åãç®èã圢æãã
æš¹èã§ããã°ç¹ã«å¶éã¯ãªããå¯å¡å€ãšããŠãã
ã²ã³åãã©ãã€ã³ããžã¡ãã«ããã¿ã¬ã³ããžãã
ã«ãã¿ã¬ãŒãçãæãããããæµåæ§ä»äžå€ãšã
ãŠã¯ã¢ããããŒïŒã¢ã³ãµã³ãã±ãã«ã«ç€Ÿè£œïŒãã¢
ã¯ãããŒã«4FïŒãã¹ã瀟補ïŒçããã³ããŒã«æå¶
å€ãšããŠã¯ãã³ãŸã€ã³ããžã¡ãã«ãã¬ãã¿ã¬ãŒã
çãæããããããããã¯é©å®éžæããŠäœ¿çšã
ãããã®éãé©å®æ±ºå®ãããã°ããã äžæ¹ãïŒå±€æ§é ãæ¡ãå Žåãé»è·çºçå±€ã¯ãå
èšÏåãÏâ²åãηååã³Î·â²åç¡éå±ãã¿ãã·ã¢ã
ã³ã®ãã¡å°ãªããšãäžçš®é¡ãé»è·çºçç©è³ªãšããŠ
䜿çšããã®ã§è圢æã®ããã«äžèšçµåå€ã䜿çšã
ãå¿ èŠãããããã®äœ¿çšéã¯ãé»è·çºçç©è³ªïŒé
ééšåœãïŒãïŒéééšã§ãããïŒéééšãè¶ãã
ãšé»ååçç¹æ§ãäœäžããããã®ä»ãäžèšå¯å¡
å€ãæ·»å å€ã¯ãé»è·çºçç©è³ªã«å¯ŸããŠæ°ééïŒ ä»¥
äžã§é©å®äœ¿çšãããããŸããé»è·æ¬éå±€ã¯ãäžè¬
åŒïŒïŒã§è¡šãããããªããµãŸãŒã«èªå°äœãé»è·
æ¬éç©è³ªãšããŠåç¬ã§çšããå Žåã«ã¯ãäžèšã®çµ
åå€ãé»è·æ¬éç©è³ªïŒéééšåœãïŒãïŒéééšçš
ããã®ãäžè¬çã§ããããŸããä»ã®é»è·æ¬éç©è³ª
ã䜵çšããå Žåã該é»è·æ¬éç©è³ªãé«ååååç©
ã®ãšãã«ã¯ãçµåå€ãçšããªããŠããããã該é«
ååååç©ïŒéééšã«å¯Ÿãçµåå€ãïŒéééšä»¥äž
ã§äœ¿çšããŠããããïŒéééšãè¶ãããšé»ååç
ç¹æ§ãäœäžããããŸããäžèšé»è·æ¬éæ§ç©è³ªãšã
ãŠäœååååç©ã䜵çšãããšãã¯ãçµåå€ã¯äžè¬
åŒïŒïŒã®ãªããµãŸãŒã«èªå°äœåã³è©²äœåååå
ç©ã®ç·éïŒéééšã«å¯ŸããŠ0.3ãïŒéééšäœ¿çšã
ããã0.3éééšæªæºã§ã¯é»è·æ¬éå±€ã®åœ¢æãå°
é£ã«ãªããïŒéééšãè¶ãããšé»ååçç¹æ§ãäœ
äžããããã®ä»äžèšå¯å¡å€ãæ·»å å€ã¯äžèšé»è·æ¬
éæ§ç©è³ªïŒéééšã«å¯ŸããŠ0.05éééšä»¥äžã§é©å®
䜿çšããããé»è·çºçå±€ã®åãã¯0.01ã10ÎŒïœã
奜ãŸããã¯0.2ã5ÎŒïœãæãŸããã0.01ÎŒïœæªæºã§
ã¯ãé»è·çºçå±€ãåäžã«åœ¢æããã®ãå°é£ã«ãª
ãã10ÎŒïœãè¶ãããšé»ååçç¹æ§ãäœäžããã
ãŸããé»è·æ¬éå±€ã®åãã¯ïŒã50ÎŒïœã奜ãŸãã
ã¯ïŒã25ÎŒïœã§ããã5ÎŒïœæªæºã§ã¯åæé»äœãäœ
äžãã50ÎŒïœãè¶ãããšæ床ãäœäžããã ãããããããã®å Žåãæçµçã«ã¯å æ床å³ã¡
垯é»ç¹æ§ãæããªãããã«é æ ®ããŠæ±ºå®ããã®ã
æãŸãããå å°é»å±€ã®åããããŸãåããªããã
ããšå±€èªäœã®å¯ææ§ãäœäžããæ§ããããã®ã§æ³š
æãèŠããã æ¬çºæã®é»ååçæå äœããé»è·çºçå±€ãé»è·
æ¬éå±€ããã€äºå±€æ§é ãšããå Žåãå°é»æ§æ¯æäœ
ã®äžã«é»è·çºçå±€ã圢æãããã®äžã«é»è·æ¬éå±€
ã圢æãããã®ããé»ååçç¹æ§äžå¥œãŸãããã
é»è·çºçå±€ãšé»è·æ¬éå±€ãéã«ãªã€ãŠããŠãã
ããå°é»æ§æ¯æäœã«ã¯ã¢ã«ãããŠã ãçã¡ããã
é ãéãªã©ãçšããããã å°é»æ§æ¯æäœäžã«é»è·çºçå±€ããã³é»è·æ¬éå±€
ãããªãäºå±€ã圢æããã«ã¯ãåå±€ã®æåãã¢ã»
ãã³ãã¡ãã«ãšãã«ã±ãã³çã®ã±ãã³ç³»æº¶å€ãã
ãã©ããããã©ã³çã®ãšãŒãã«ç³»æº¶å€ããã«ãš
ã³ããã·ã¬ã³çã®è³éŠæ系溶å€çã®æº¶å€ã«åäžã«
溶解ãŸãã¯åæ£ãããã®ã¡ãå°é»æ§æ¯æäœäžã«å¡
åžä¹Ÿç¥ããããšãã§ããããã®ãã¡ãé»è·çºçå±€
ãŸãã¯é»è·æ¬éå±€ã圢æãããã®ã¡ããã®äžã«é»
è·æ¬éå±€ãŸãã¯é»è·çºçå±€ãåæ§ã«å¡åžä¹Ÿç¥ããŠ
äºå±€æ§é ãšããããšãã§ããã å¡åžä¹Ÿç¥ã¯ãäŸãã°ãã¯ã¿ãŒãã¬ãŒããçšããŠ
æå®ã®èåã«å¡å·¥ãã15åéèªç¶ä¹Ÿç¥ãããåŸã
80ã110âã§40åé也ç¥ããŠè¡ãªãããšãã§ããã æ¬çºæã«ä¿ãé»ååçæå äœã¯ãããã«å°é»æ§
æ¯æäœã®ããäžã«èãæ¥çå±€ãããªã€å±€ãæããŠ
ããŠãããããŸããè¡šé¢ã«ã·ãªã³ã³çã®ä¿è·å±€ã
èšããããšãã§ããã æ¬çºæã«ãªãé»ååçæå äœãçšããè€åæ³ã¯
åŸæ¥ãšåæ§ãè¡šé¢ã«åž¯é»ãé²å ãæœããåŸãçŸå
ãè¡ãªããæ®éçŽäžã«ç»åã転åãå®çããã°ã
ãã æ¬çºæã«ãªãé»ååçæå äœã¯ãé«ãæ床ãæ
ããäžã€ææžè¡°ãå°ãããå ç²åŽãå°ãªããªã©åª
ããå©ç¹ãæããŠããã äžè¬åŒïŒïŒã§è¡šãããããªããµãŸãŒã«èªå°äœ
ãšããŠã¯ãïŒâïŒïŒâãžãããã«ã¢ããããšãã«ïŒ
âïŒâïŒïŒâãžã¡ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒ
âãã«ãªã«ããšãã«ïŒâïŒïŒïŒâãªããµãŸãŒã«ã
ïŒâïŒïŒâãžãšãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâ
ãžã¡ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâãã«ãªã«ã
ãšãã«ïŒâïŒïŒïŒâãªããµãŸãŒã«ãïŒâïŒïŒâãžã¡
ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâãžã¡ãã«ã¢ãã
ããšãã«ïŒâïŒâïŒïŒâãã«ãªã«ããšãã«ïŒâïŒïŒ
ïŒâãªããµãŸãŒã«ãïŒâïŒïŒâãžãããã«ã¢ãã
ããšãã«ïŒâïŒâïŒïŒâãžãšãã«ã¢ããããšãã«ïŒ
âïŒâïŒïŒâãã«ãªã«ããšãã«ïŒâïŒïŒïŒâãªããµ
ãŸãŒã«ãïŒâïŒïŒâãžãšãã«ã¢ããããšãã«ïŒâïŒ
âïŒïŒâãžãšãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâã
ã«ãªã«ããšãã«ïŒâïŒïŒïŒâãªããµãŸãŒã«ãïŒâ
ïŒïŒâãžã¡ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâãžãš
ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâãã«ãªã«ããšã
ã«ïŒâïŒïŒïŒâãªããµãŸãŒã«ãïŒâïŒïŒâãžã¡ãã«
ã¢ããããšãã«ïŒâïŒâïŒïŒâãžãããã«ã¢ããã
ãšãã«ïŒâïŒâïŒïŒâãã«ãªã«ããšãã«ïŒâïŒïŒïŒ
âãªããµãŸãŒã«çãããã äžè¬åŒïŒïŒã§è¡šãããããªããµãŸãŒã«èªå°äœ
ã¯ã ïŒãã ããåŒäžãR1ããã³R2ã¯ã¡ãã«åºããš
ãã«åºããããã«åºçã®ã¢ã«ãã«åºã瀺ãããã
ãã¯åäžã§ãç°ãªã€ãŠããŠãããïŒã§è¡šãããã
ååç©ãšãäžè¬åŒ(B) ïŒãã ããåŒäžãR3ããã³R4ã¯ãã¡ãã«åºã
ãšãã«åºããããã«åºçã®ã¢ã«ãã«åºã瀺ããã
ããã¯åäžã§ãç°ãªã€ãŠããŠãããïŒã§è¡šããã
ãååç©ãåå¿ãããããšã«ãã€ãŠåŸãããšãã§
ããã åŒ(A)ã§è¡šããããååç©ã¯ãäŸãã°ãïŒâãžã¡
ãã«ã¢ãããã³ãºã¢ã«ããããïŒâãã«ãªããã³
ãºã¢ã«ãããããã³KCNããããããïŒã¢ã«ã
ïŒã¢ã«ããã³0.1ã1.5ã¢ã«ã®å²åã§50ïŒ ãšã¿ããŒ
ã«æ°Žæº¶æ¶²äžã«å ã1.5ãïŒæéå ç±éæµãããã
ãšã«ãã補é ã§ããã äžè¬åŒ(B)ã§è¡šããããååç©ã¯ãäŸãã°äžèšã®
åŒïŒïŒã§è¡šããããåå¿åŸè·¯ã«ããåæã§ã
ããããªãã¡ãã¢ããªã³ïŒã¢ã«ãšäžè¬åŒ(C) ïŒROïŒ3PO (C) ïŒãã ãåŒäžïŒ²ã¯ãã¡ãã«åºããšãã«åºããã
ãã«åºçã®ã¢ã«ãã«åºã瀺ããäžã€ã®ïŒ²ã¯åäžã§
ãç°ãªã€ãŠããŠãããïŒã§è¡šããããååç©0.67
ã¢ã«ãïŒæéå ç±éæµããŠåå¿ãããæžå§èžçã
ãŠãžã¢ã«ãã«ã¢ããªã³ïŒããã§ãã¢ã«ãã«åºãšã
ãŠã¯ã¡ãã«ããšãã«åºããããã«åºçãããã以
äžåãïŒãåŸããç¶ããŠãïŒïŒ®âãžã¡ãã«ãã«
ã ã¢ããïŒã¢ã«ã«ãžã¢ã«ãã«ã¢ããªã³0.3ã0.4ã¢
ã«ã19ã22âã§æ»Žäžãã滎äžçµäºåŸ90ã95âã§ïŒ
æéåå¿ããæžå§èžçããŠãžã¢ã«ãã«ã¢ãããã³
ãºã¢ã«ããããåŸãããžã¢ã«ãã«ã¢ãããã³ãºã¢
ã«ãããïŒã¢ã«ã«å¯ŸããŠå¡©é žããããã·ã¢ãã³
1.0ã1.3ã¢ã«ã宀枩ã§20åéåå¿ãããåå¿æ¶²ã
å·èµåº«äžã«æŸçœ®ããŠãžã¢ã«ãã«ã¢ãããã³ãºã¢ã«
ãããã»ãªãã·ã ãæåºããããæåŸã«ãžã¢ã«ã
ã«ã¢ãããã³ãºã¢ã«ãããã»ãªãã·ã ïŒã¢ã«ã«å¯Ÿ
ããŠç¡æ°Žé ¢é žïŒãïŒã¢ã«ã20åéå ç±éæµããŠè±
æ°Žåå¿ããäžè¬åŒ(B)ã§è¡šããããååç©ã補é ã
ãããšãã§ããã äžèšã«ãããŠããžã¢ã«ãã«ã¢ãããã³ãºã¢ã«ã
ãããããžã¢ã«ãã«ã¢ãããã³ãŸãããªã«ãçæ
ãããããã«ã¯ãäžèšåŒïŒïŒ¹ïŒã®åŸè·¯ã«ãã€ãŠè¡
ãªãããšãã§ããã ããªãã¡ããžã¢ã«ãã«ã¢ãããã³ãºã¢ã«ããã
ïŒã¢ã«ã«å¯ŸããŠNH2OHã»HCl1.15ã¢ã«ã
HCOONa倧éå°ããã³ã®é žçŽ1500c.c.ãæ··åãã
éæµäžã«ïŒæéåå¿ããããã®åŸãçŽã¡ã«åå¿æ¶²
ãæ°Žäžã«å ãããšãžã¢ã«ãã«ã¢ãããã³ãŸãããª
ã«ã®æ²æ®¿ãæåºããããã®æ²æ®¿ãæ°Žã§åçµæ¶ãã
ã°ããã äžè¬åŒïŒïŒã§è¡šããããååç©ã¯ãåŒ(A)ãã
ã³äžè¬åŒ(B)ã§è¡šããããååç©ãæ¿ç¡«é žã«æº¶è§£ã
ããææã§åå¿ãããããšã«ããåŸããããåå¿
枩床ã¯20ã70âã奜ãŸãããåå¿æž©åºŠã50ã70â
ã«ãããš0.5ãïŒæéã§åå¿ã¯çµäºãããåå¿ç©
ã®ç²Ÿè£œã¯ã¡ã¿ããŒã«ã«ããåçµæ¶ã«ãã€ãŠãããª
ãããšãã§ããã äžè¬åŒ(A)ããã³äžè¬åŒ(B)ã§è¡šããããååç©
ã¯ãåå¿åã«äºãæ··åããŠããã®ã奜ãŸãããäž
è¬åŒ(A)ã®ååç©ãåç¬ã§æ¿ç¡«é žã«æ·»å ãããšæ¿ç¡«
é žã«ããäžè¬åŒ(B)ã§è¡šããããååç©ãšåå¿ãã
åã«è±æ°Žåå¿ããããŠããŸãã ïŒå®æœäŸïŒ 以äžã«æ¬çºæã®å®æœäŸã瀺ãã å®æœäŸ ïŒãïŒ Ïåç¡éå±ãã¿ãã·ã¢ãã³ïŒæ±æŽã€ã³ã補é (æ ª)
補ïŒïŒéééšãšã·ãªã³ãŒã³æš¹èïŒä¿¡è¶ååŠå·¥æ¥(æ ª)
åååïŒKR255ïŒ6.7éééšãããã©ããããã©
ã³ã溶å€ãšããïŒééïŒ ã®æº¶æ¶²ã«ãªãããã«ã
ãŠãããŒã«ãã«ïŒæ¥æ¬ååŠé¶æ¥è£œïŒå¯žãããã
ã«ïŒã§ïŒæéæ··ç·ŽãããåŸãããé¡æåæ£æ¶²ãã¢
ããªã±ãŒã¿ã«ããã¢ã«ãããŠã æ¿ïŒå°é»äœïŒäžã«
å¡å·¥ãã90âã§40åé也ç¥ããŠåã1ÎŒïœã®é»è·
çºçå±€ã圢æããã 次ã«äžèšç¬¬ïŒè¡šã«ç€ºãããªããµãŸãŒã«èªå°äœïŒ
éééšãããªãšã¹ãã«æš¹èïŒæ±æŽçŽ¡çžŸ(æ ª)åååã
ãã€ãã³200ïŒ2.4éééšããã³ã¹ãã¬ã³æš¹èïŒãš
ããœç€Ÿè£œããã³ããã¯ã¹100ïŒ0.6éééšãããã©
ããããã©ã³ã溶å€ãšãã27ééïŒ ã®æº¶æ¶²ãšãã
äžèšé»è·çºçå±€ã®äžã«ã¢ããªã±ãŒã¿ã«ããå¡å·¥ã
90âã§40åé也ç¥ããŠåã30ÎŒïœã®é»è·æ¬éå±€ã
圢æããŠé»ååçæå äœãåŸãã ãã®ããã«ããŠäœæããé»ååçæå äœã«ã€
ããéé»èšé²çŽè©Šéšè£ 眮ïŒå·å£é»æ©(æ ª)åååSP
â428ïŒãçšããŠé»ååçç¹æ§ã枬å®ããããã®
å Žåãè² 5KVã®ã³ããæŸé»ã10ç§éè¡ãªã€ãŠåž¯
é»ããïŒ10ç§é垯é»åŸã®è¡šé¢é»äœV0ïŒïŒ¶ïŒãåæ
é»äœãšããïŒã30ç§éææã«æŸçœ®åŸïŒãã®æå»ã®
è¡šé¢é»äœãV30ïŒïŒ¶ïŒã§è¡šãããV30ïŒV0Ã100ã
ææžè¡°ïŒïŒ ïŒãšããïŒãã¿ã³ã°ã¹ãã³ç¯ã§ãè¡šé¢
ãïŒã«ã¯ã¹ã«ãªãããã«é²å ãããã®æã®è¡šé¢é»
äœã®æžè¡°åã³æéãèšé²ããV30ã1/2ã«ãªããŸ
ã§ã®æéïœïŒç§ïŒãšç §åºŠïŒã«ã¯ã¹ïŒã®ç©ã§æ床
ïŒåæžé²å éE50ãã«ã¯ã¹ã»ç§åäœïŒãè¡šãããã
ãŸããåå æ床ã¯ãã¿ã³ã°ã¹ãã³ã©ã³ãã®æ¿ã
ã«ãåå åšããã®åã ã®æ³¢é·ãå æºãšããV30ã
ïŒïŒïŒã«ãªããŸã§ã«èŠããæéïœïŒç§ïŒãšåæ³¢é·ã®ãš
ãã«ã®ãŒïŒÎŒWïŒcm2ïŒãšã®ç©ã®éæ°ã§æ床ïŒm2ïŒ
ïœïŒªïŒãšããããããã®çµæãäžèšç¬¬ïŒè¡šã«ç€ºã
ãã å®æœäŸ ïŒãïŒ Ïâ²åç¡éå±ãã¿ãã·ã¢ãã³ïŒæ±æŽã€ã³ã補é
(æ ª)ïŒïŒéééšãšã·ãªã³ãŒã³æš¹èïŒä¿¡è¶ååŠå·¥æ¥(æ ª)
åååãKB255ïŒ6.7éééšãããã©ããããã©
ã³ã溶å€ãšããŠïŒééïŒ ã®æº¶æ¶²ã«ãªãããã«ã
ãŠãããŒã«ãã«ïŒæ¥æ¬ååŠé¶æ¥è£œãïŒå¯žãããã
ã«ïŒã§ïŒæéåæ£ããåŸãããåæ£æ¶²ãå®æœäŸïŒ
ãïŒãšåæ§ã®æ¹æ³ã§å¡å·¥ã也ç¥ããåã1ÎŒïœã®
é»è·çºçå±€ã圢æããã 次ã«äžèšç¬¬ïŒè¡šã«ç€ºãããªããµãŸãŒã«èªå°äœïŒ
éééšãšããªãšã¹ãã«æš¹èïŒæ±æŽçŽ¡çžŸ(æ ª)åååã
ãã€ãã³200ïŒ2.4éééšããã³ã¹ãã¬ã³æš¹èïŒãš
ããœç€Ÿè£œããã³ããã¯ã¹100ïŒ0.6éééšãããã©
ããããã©ã³ã溶å€ãšãã27ééïŒ ã®æº¶æ¶²ãšãã
äžèšé»è·çºçå±€ã®äžã«ã¢ããªã±ãŒã¿ã«ããå¡å·¥ã
90âã§40åé也ç¥ããŠåã15ÎŒïœã®é»è·æ¬éå±€ã
圢æããŠé»ååçæå äœãåŸãã ãã®ããã«ããŠäœæããé»ååçæå äœã®ç¹æ§
ãå®æœäŸïŒãïŒãšåæ§ã«æž¬å®ããçµæã第ïŒè¡šã«
èšããã å®æœäŸ ïŒãïŒ Î·åç¡éå±ãã¿ãã·ã¢ãã³ïŒæ±æŽã€ã³ã補é (æ ª)
補ïŒïŒéééšãšã·ãªã³ãŒã³æš¹èïŒä¿¡è¶ååŠå·¥æ¥(æ ª)
åååãKR255ïŒ6.7éééšãããã©ããããã©
ã³ã溶å€ãšããŠïŒééïŒ ã®æº¶æ¶²ã«ãªãããã«ã
ãŠãããŒã«ãã«ïŒæ¥æ¬ååŠé¶æ¥è£œãïŒå¯žãããã
ã«ïŒã§ïŒæéåæ£ããåŸãããåæ£æ¶²ãå®æœäŸïŒ
ãïŒãšåæ§ã®æ¹æ³ã§å¡å·¥ã也ç¥ããåã1ÎŒïœã®
é»è·çºçå±€ã圢æããã 次ã«äžèšç¬¬ïŒè¡šã«ç€ºãããªããµãŸãŒã«èªå°äœïŒ
éééšãšããªãšã¹ãã«æš¹èïŒæ±æŽçŽ¡çžŸ(æ ª)åååã
ãã€ãã³200ïŒ2.4éééšããã³ã¹ãã¬ã³æš¹èïŒãš
ããœç€Ÿè£œããã³ããã¯ã¹100ïŒ0.6éééšãããã©
ããããã©ã³ã溶å€ãšãã27ééïŒ ã®æº¶æ¶²ãšãã
äžèšé»è·çºçå±€ã®äžã«ã¢ããªã±ãŒã¿ã«ããå¡å·¥ã
90âã§40åé也ç¥ããŠåã15ÎŒïœã®é»è·æ¬éå±€ã
圢æããŠé»ååçæå äœãåŸãã ãã®ããã«ããŠäœæããé»ååçæå äœã®ç¹æ§
ãå®æœäŸïŒãïŒãšåæ§ã«æž¬å®ããçµæã第ïŒè¡šã«
èšããã å®æœäŸ 10ã12 ηâ²åç¡éå±ãã¿ãã·ã¢ãã³ïŒæ±æŽã€ã³ã補é (æ ª)
補ïŒïŒéééšãšã·ãªã³ãŒã³æš¹èïŒä¿¡è¶ååŠå·¥æ¥(æ ª)
åååãKR255ïŒ6.7éééšãããã©ããããã©
ã³ã溶å€ãšããŠïŒééïŒ ã®æº¶æ¶²ã«ãªãããã«ã
ãŠãããŒã«ãã«ïŒæ¥æ¬ååŠé¶æ¥è£œãïŒå¯žãããã
ã«ïŒã§ïŒæéåæ£ããåŸãããåæ£æ¶²ãå®æœäŸïŒ
ãïŒãšåæ§ã®æ¹æ³ã§å¡å·¥ã也ç¥ããåã1ÎŒïœã®
é»è·çºçå±€ã圢æããã 次ã«äžèšç¬¬ïŒè¡šã«ç€ºãããªããµãŸãŒã«èªå°äœïŒ
éééšãšããªãšã¹ãã«æš¹èïŒæ±æŽçŽ¡çžŸ(æ ª)åååã
ãã€ãã³200ïŒ2.4éééšããã³ã¹ãã¬ã³æš¹èïŒãš
ããœç€Ÿè£œããã³ããã¯ã¹100ïŒ0.6éééšãããã©
ããããã©ã³ã溶å€ãšãã27ééïŒ ã®æº¶æ¶²ãšãã
äžèšé»è·çºçå±€ã®äžã«ã¢ããªã±ãŒã¿ã«ããå¡å·¥ã
90âã§40åé也ç¥ããŠåã15ÎŒïœã®é»è·æ¬éå±€ã
圢æããŠé»ååçæå äœãåŸãã ãã®ããã«ããŠäœæããé»ååçæå äœã®ç¹æ§
ãå®æœäŸïŒãïŒãšåæ§ã«æž¬å®ããçµæã第ïŒè¡šã«
èšããã
ãè¡šã
ãè¡šã
ãè¡šã
ãžã¡ãã«ã¢ãããã³ãºã¢ã«ããã14.9ïœãïŒâ
ãã«ãªã«ãã³ãºã¢ã«ããã12.4ïœããã³ã·ã¢ã³å
ã«ãªãŠã 8.0ïœã50ïŒ ãšã¿ããŒã«æº¶æ¶²150mlã«æº¶è§£
ããïŒæé30åå ç±éæµãããå ç±éæµåŸæŸå·ã
æåºããæ·¡é»è²çµæ¶ããéãã80âã§ä¹Ÿç¥ããã
çµæ¶ãã¡ã¿ããŒã«500mlã§åçµæ¶ããŠèç¹168ã
170âã®ïŒâãžã¡ãã«ã¢ããâ2â²âãã«ãªã«ãã³
ãŸã€ã³ïŒåç45ïŒ ïŒãåŸãã 補é äŸ ïŒ ãïŒâãžãããã«ã¢ãããã³ãŸãããªã«ã®è£œ
é ã ã¢ããªã³62ïœãšïœâãããã«ãã¹ããšã€ã100
ïœãïŒæéå ç±éæµããåŸæŸå·ãã溶液枩床ã55
ã60âã«éäžãããšãã«ãæ°Žé žåãããªãŠã 氎溶
液ïŒ56.3ïœïŒ225mlãå ããïŒæéå ç±éæµããã
å ç±éæµçµäºåŸçŽã¡ã«åå¿æº¶æ¶²ãïŒâããŒã«ãŒ
ã«ç§»ãæŸçœ®ãããåå¿æ¶²ã¯äºå±€ã«åé¢ããäžå±€ã¯
é»è²ãåããäžå±€ã¯çœè²åºäœãšãªã€ããçœè²åºäœ
ããšãŒãã«100mlã§ïŒåæœåºããäžå±€ãšæœåºæ¶²ã
ç¡æ°Žç¡«é žãããªãŠã ã§ä¹Ÿç¥ããããšãŒãã«ãçå»
åŸãåäœç©ã®ç¡æ°Žé ¢é žãå ãäžæ©æŸçœ®ãããåå¿
液ã«å¡©é žæ°Žæº¶æ¶²ïŒ45mlïŒ67.5mlïŒãå ãæŸå·åŸã
25ïŒ æ°Žé žåãããªãŠã 溶液ãå ãããšãªã€ã«å±€ãš
æ°Žå±€ã«åé¢ãããæ°Žå±€ããšãŒãã«100mlã§ïŒåæœ
åºãããªã€ã«å±€ãšãšãã«ç¡æ°Žç¡«é žãããªãŠã ã§ä¹Ÿ
ç¥ããããšãŒãã«ãçå»åŸæžå§èžçïŒb.p130ã
140âïŒ18mmHgïŒããŠããžãããã«ã¢ããªã³ïŒå
ç69ïŒ ïŒãåŸãã 次ã«ãïŒïŒ®âãžã¡ãã«ãã«ã ã¢ãã54ïœã20
â以äžã«ä¿æãããªãã·å¡©åãªã³44.5ïœã30åé
ã§æ»Žäžããã äžèšã§åŸããããžãããã«ã¢ããªã³35ïœãïŒæ
éã§æ»Žäžããã滎äžçµäºåŸ90ã95âã§ïŒæéå ç±
æªæããããã®åŸãåå¿æ¶²ãæ°·æ°Žã«å ã飜åé ¢é ž
ãããªãŠã 溶液ã§äžåããããšãŒãã«100mlã§ïŒ
åæœåºããç¡æ°Žç¡«é žãããªãŠã ã§ä¹Ÿç¥ããããšãŒ
ãã«ãçå»åŸãæžå§èžçïŒb.p155ã163âïŒïŒmm
HgïŒããŠãžãããã«ã¢ãããã³ãºã¢ã«ããã
ïŒåç46ïŒ ïŒãåŸãã ãã®ãžãããã«ã¢ãããã³ãºã¢ã«ããã11.6ïœ
ã95ïŒ ãšã¿ããŒã«23mlã«æº¶è§£ããããã«å¡©é žãã
ããã·ã¢ãã³æ°Žæº¶æ¶²ïŒ4.7ïœïŒ5.7mlïŒãå ã20å
éæªæãããåå¿æ¶²ã«æ°Žé žåãããªãŠã 氎溶液
ïŒ3.4ïœïŒ4.5mlïŒãå ãïŒæé30å宀枩ã§æŸçœ®ã
ããæ°·29ïœãå ãåå¿ç³»å ãCO2ã¬ã¹ã§çœ®æãã
åŸãå·èµåº«äžã§äžæ©æŸçœ®ãããæåºããçœè²çµæ¶
ãåžåŒãéããçµæ¶ãæ°ŽæŽããåŸä¹Ÿç¥ããã åŸãããååç©ã«ç¡æ°Žé ¢é ž12.4ïœãå ã20åé
å ç±éæµããããã®åŸãå·æ°Ž35mlã«åå¿æ¶²ãå ã
æ°Žé žåãããªãŠã 溶液ã§äžåããããšãŒãã«40ml
ã§ïŒåæœåºããæœåºæ¶²ãç¡æ°Žç¡«é žãããªãŠã ã§ä¹Ÿ
ç¥ããããšãŒãã«çå»åŸæžå§èžçïŒb.p180âïŒïŒ
mmHgïŒããŠïŒâãžãããã«ã¢ãããã³ãŸãããª
ã«ïŒåç79ïŒ ïŒãåŸãããããæŸçœ®ããŠãããšçµ
æ¶åããèç¹39ã41âã®é»è²çµæ¶ãšãªã€ãã 補é äŸ ïŒ ãïŒâãžã¡ãã«ã¢ãããã³ãŸãããªã«ã®è£œé ã 補é äŸïŒã®æé ã«åŸã€ãŠåæãããžã¡ãã«ã¢ã
ããã³ãºã¢ã«ããã29.8ïœãå¡©é žããããã·ã¢ã
ã³15.9ïœãã®é žãããªãŠã 25ïœããã³ã®é ž333ml
ãïŒæéå ç±éæµãããåå¿æ¶²ãæ°Ž800mlã«æªæ
ããªãã滎äžãããšæ·¡ç·è²ã®çµæ¶ãæåºãããã
éåŸä¹Ÿç¥ããã¢ã»ãã³ã§åçµæ¶ããèç¹67ã69â
ã®ïŒâãžã¡ãã«ã¢ãããã³ãŸãããªã«ïŒåç50
ïŒ ïŒãåŸãã 補é äŸ ïŒ ãïŒâãžãšãã«ã¢ãããã³ãŸãããªã«ã®è£œé ã 補é äŸïŒã®æé ã«åŸã€ãŠåæãããžãšãã«ã¢ã
ããã³ãºã¢ã«ããã25ïœãå¡©é žããããã·ã¢ãã³
10.5ïœãã®é žãããªãŠã 16.5ïœããã³ã®é ž220ml
ãïŒæéå ç±éæµãããåå¿æ¶²ãæ°Ž400mlã«æªæ
ããªããæ·»å ãããšçœè²ã®çµæ¶ãæåºããããé
åŸä¹Ÿç¥ãæ°Žâã¢ã»ãã³ã§åçµæ¶ããèç¹66ã67â
ã®ïŒâãžãšãã«ã¢ãããã³ãŸãããªã«ïŒåç50
ïŒ ïŒãåŸãã 補é äŸ ïŒ ãååç©ïŒïŒã®è£œé ã ææã§æ¿ç¡«é ž35ïœã60âã«ä¿æããããã«è£œé
äŸïŒã§åŸãïŒâãžã¡ãã«ã¢ããâ2â²âãã«ãªã«ã
ã³ãŸã€ã³2.4ïœã補é äŸïŒã§åŸãïŒâãžãããã«
ã¢ãããã³ãŸãããªã«2.1ïœã®æ··åç©ãå ãïŒæ
éæªæãããåå¿æ¶²ãæ°Ž900mlã«å ãããšé»ç·ã®
æ²æ®¿ãæåºããããéåŸãé液ã3Næ°Žé žåãã
ãªãŠã 溶液ã§ã¢ã«ã«ãªæ§ã«ãããšæ·¡é»è²ã®çµæ¶ã
æåºããããããåžåŒãéã颚也ãããã¡ã¿ããŒ
ã«ã§åçµæ¶ããŠæ·¡é»è²åºäœ1.73ïœïŒåç43ïŒ ïŒã
åŸãããã®æ·¡é»è²åºäœã¯äžèšã®åæçµæããïŒâ
ïŒïŒâãžãããã«ã¢ããããšãã«ïŒâïŒâïŒïŒâãž
ã¡ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâãã«ãªã«ããš
ãã«ïŒâïŒïŒïŒâãªããµãŸãŒã«ïŒååç©ïŒã§ã
ãããšã確èªããã (1) èç¹ïŒ134ã135â (2) å çŽ åæå€ïŒC29H32N3OF    èšç®å€(%) 76.15 7.00 9.19 å®æž¬å€(%) 76.07 7.11 9.15 補é äŸ ïŒ ãååç©ïŒïŒã®è£œé ã ææã§æ¿ç¡«é ž35ïœã60âã«ä¿æããããã«è£œé
äŸïŒã§åŸãïŒâãžã¡ãã«ã¢ããâ2â²âãã«ãªã«ã
ã³ãŸã€ã³2.4ïœã補é äŸïŒã§åŸãïŒâãžã¡ãã«ã¢
ãããã³ãŸãããªã«1.5ïœã®æ··åç©ãå ã30åé
æªæãããåå¿æ¶²ãæ°Ž900mlã«å ãããšé»ç·ã®æ²
殿ãæåºããããéåŸã液ã3Næ°Žé žåãããªãŠ
ã 溶液ã§ã¢ã«ã«ãªæ§ã«ãããšæ·¡é»è²ã®çµæ¶ãæåº
ããããããåžåŒãéã颚也ãããã¡ã¿ããŒã«ã§
åçµæ¶ããŠæ·¡é»è²åºäœ1.56ïœïŒåç44ïŒ ïŒãåŸ
ãããã®æ·¡é»è²åºäœã¯äžèšã®åæçµæããïŒâ
ïŒïŒâãžã¡ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâãžã¡
ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâãã«ãªã«ããšã
ã«ïŒâïŒïŒïŒâãªããµãŸãŒã«ïŒååç©ïŒã§ã
ãããšã確èªããã (1) èç¹ïŒ172ã173â (2) å çŽ åæå€ïŒC25H24N3OF    èšç®å€(%) 74.79 6.03 10.47 å®æž¬å€(%) 74.53 6.04 10.47 補é äŸ ïŒ ãååç©ïŒïŒã®è£œé ã ææã§æ¿ç¡«é ž32ïœã60âã«ä¿æããããã«è£œé
äŸïŒã§åŸãïŒâãžãšãã«ã¢ããâ2â²âãã«ãªã«ã
ã³ãŸã€ã³2.2ïœã補é äŸïŒã§åŸãïŒâãžãšãã«ã¢
ãããã³ãŸãããªã«1.64ïœã®æ··åç©ãå ãïŒæé
æªæãããåå¿æ¶²ãæ°Ž800mlã«å ãããšé»ç·ã®æ²
殿ãæåºããããéåŸã液ã3Næ°Žé žåãããªãŠ
ã 溶液ã§ã¢ã«ã«ãªæ§ã«ãããšãæ·¡é»è²ã®çµæ¶ãæ
åºããããããåžåŒãéã颚也ãããã¡ã¿ããŒã«
ã§åçµæ¶ããŠæ·¡é»è²åºäœ1.39ïœïŒåç40ïŒ ïŒãåŸ
ãããã®æ·¡é»è²åºäœã¯äžèšã®åæçµæããïŒâ
ïŒïŒâãžãšãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâãžã¡
ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâãã«ãªã«ããšã
ã«ïŒâïŒïŒïŒâãªããµãŸãŒã«ïŒååç©ïŒã§ãã
ããšã確èªããã (1) èç¹ïŒ102ã105â (2) å çŽ åæå€ïŒC27H28N3OF    èšç®å€(%) 75.35 6.51 9.77 å®æž¬å€(%) 75.25 6.53 9.72 å®æœäŸïŒãïŒã§çšãããªããµãŸãŒã«èªå°äœ
ãïŒïŒïŒïŒïŒããã³ïŒïŒãããã³æ¯èŒãšããŠåŸ
æ¥çšããããŠãããªããµãŸãŒã«èªå°äœãšããŠïŒâ
ïŒïŒâãžãšãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâãžã¡
ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâã¯ããããšã
ã«ïŒâïŒïŒïŒâãªããµãŸãŒã«ïŒïŒã®çŽ«å€ç·ç §å°
ã«å¯Ÿããå®å®æ§ã®è©Šéšã次ã®ããã«ããŠè¡ãªã€
ãã ååç©ïŒïŒïŒïŒïŒïŒïŒïŒããã³ïŒïŒãå¥ã
ã«ïŒÃ10-4molïŒã®æ¿åºŠã§æº¶è§£ããŠãªãã¢ã»ã
ãããªã«æº¶æ¶²ã«ãããããçªçŽ ã¬ã¹ãäžæééæ°
ããåŸçªçŽ ã¬ãŠãéæ°ããªãã150Wé«å§æ°Žéç
ã§ç §å°ãããç §å°éå§åŸïŒåééã§è©Šæãæ¡å
ããã¢ã»ããããªã«æº¶æ¶²ã§äžå®çã§åžéããåŸã
玫å€åå å 床èšãçšããŠåžåã¹ãã¯ãã«ã®å€åã
調ã¹ãã æ¯èŒã«çšããååç©ïŒïŒã¯ãæ°Žéçç §å°ïŒå
åŸã«ã¯ãåæã®åžåã¹ãã¯ãã«ïŒÎ»maxïŒ
363.0nm εïŒ4.8Ã104ïŒmolã»cmïŒ310nm
shoulderãšã¯éã€ãåžåã¹ãã¯ãã«ïŒÎ»maxïŒ
370.0nmïŒ258.0nmïŒ245.0nmïŒã«å€åããŠããã
åŸè ã®åžåã¹ãã¯ãã«ã¯ãååç©ïŒïŒãå解ã
ãŠçããïŒâïŒïŒâãžãšãã«ã¢ããããšãã«ïŒâïŒ
âãžã¡ãã«ã¢ããããšãã³ãããïŒïŒ10âïœããª
ããµãŸãŒã«ã«ãããã®ã§ãããæ¯èŒã«çšããåå
ç©ïŒïŒã®å解çã¯ãåæéã«ãããåžåã¹ãã¯
ãã«ã®å解ã«ããçŸããã258.0nmã®åžå 床枬å®
ããLambartâBeerã®æ³æž¬ãçšããŠå解ç©ã®ç
ææ¿åºŠããæ±ããã æ¬çºæã®é»ååçæå äœã«çšããé»è·æ¬éç©è³ª
ïŒïŒïŒïŒïŒããã³ïŒïŒã¯ãç §å°60ååŸã«ãã
ãŠãåæã®ã¹ãã¯ãã«ïŒïŒ¶ïŒÎ»maxïŒ363.0nm ε
ïŒ4.9Ã104ïŒmolã»cmïŒ310.0nm shoulderïŒ
ïŒÎ»maxïŒ359.0nm εïŒ4.5Ã104ïŒmolã»cmïŒ
310.0nm shoulderïŒïŒÎ»maxïŒ363.0nm εïŒ
4.5Ã104ïŒmolã»cmïŒ310.0nm shoulderïŒãšåž
åã¹ãã¯ãã«ã®ãã¿ãŒã³ã¯å€åããªãããããã®
ååç©ã®å解çã¯ãåæéã«ãããåžåã¹ãã¯ã
ã«ã®310.0nmã®åžå 床ïŒA310.0ïŒãšÎ»maxã®åžå 床
ïŒAλmaxïŒã®æ¯ïŒA310.0ïŒAλmaxïŒããè©äŸ¡ã
ãã ååç©ïŒïŒïŒïŒïŒããã³ïŒïŒã®ã¢ã»ããã
ãªã«æº¶æ¶²ã®é«å§æ°Žéçç §å°ã«ããå å解çã®çµæ
å€åã第ïŒå³ã«ç€ºãã第ïŒå³äžæ²ç·ïŒã¯ãååç©
ïŒïŒã®å解çã瀺ããæ²ç·ïŒã¯ãååç©ïŒïŒ
ã®å解çã瀺ããæ²ç·ïŒã¯ãååç©ïŒïŒã®å解
çã瀺ãããã³æ²ç·ïŒã¯ååç©ïŒïŒã®å解çã
瀺ãã ïŒçºæã®å¹æïŒ ä»¥äžããæãããªããã«ãæ¬çºæã«ä¿ãé»åå
çæå äœã¯ã玫å€ç·ç §å°ã«å¯ŸããŠå®å®ã§ãããè¯
奜ãªé»ååçç¹æ§ãæããé»ååçæå äœã§ã
ãã
ãã«ãªã«ãã³ãºã¢ã«ããã12.4ïœããã³ã·ã¢ã³å
ã«ãªãŠã 8.0ïœã50ïŒ ãšã¿ããŒã«æº¶æ¶²150mlã«æº¶è§£
ããïŒæé30åå ç±éæµãããå ç±éæµåŸæŸå·ã
æåºããæ·¡é»è²çµæ¶ããéãã80âã§ä¹Ÿç¥ããã
çµæ¶ãã¡ã¿ããŒã«500mlã§åçµæ¶ããŠèç¹168ã
170âã®ïŒâãžã¡ãã«ã¢ããâ2â²âãã«ãªã«ãã³
ãŸã€ã³ïŒåç45ïŒ ïŒãåŸãã 補é äŸ ïŒ ãïŒâãžãããã«ã¢ãããã³ãŸãããªã«ã®è£œ
é ã ã¢ããªã³62ïœãšïœâãããã«ãã¹ããšã€ã100
ïœãïŒæéå ç±éæµããåŸæŸå·ãã溶液枩床ã55
ã60âã«éäžãããšãã«ãæ°Žé žåãããªãŠã 氎溶
液ïŒ56.3ïœïŒ225mlãå ããïŒæéå ç±éæµããã
å ç±éæµçµäºåŸçŽã¡ã«åå¿æº¶æ¶²ãïŒâããŒã«ãŒ
ã«ç§»ãæŸçœ®ãããåå¿æ¶²ã¯äºå±€ã«åé¢ããäžå±€ã¯
é»è²ãåããäžå±€ã¯çœè²åºäœãšãªã€ããçœè²åºäœ
ããšãŒãã«100mlã§ïŒåæœåºããäžå±€ãšæœåºæ¶²ã
ç¡æ°Žç¡«é žãããªãŠã ã§ä¹Ÿç¥ããããšãŒãã«ãçå»
åŸãåäœç©ã®ç¡æ°Žé ¢é žãå ãäžæ©æŸçœ®ãããåå¿
液ã«å¡©é žæ°Žæº¶æ¶²ïŒ45mlïŒ67.5mlïŒãå ãæŸå·åŸã
25ïŒ æ°Žé žåãããªãŠã 溶液ãå ãããšãªã€ã«å±€ãš
æ°Žå±€ã«åé¢ãããæ°Žå±€ããšãŒãã«100mlã§ïŒåæœ
åºãããªã€ã«å±€ãšãšãã«ç¡æ°Žç¡«é žãããªãŠã ã§ä¹Ÿ
ç¥ããããšãŒãã«ãçå»åŸæžå§èžçïŒb.p130ã
140âïŒ18mmHgïŒããŠããžãããã«ã¢ããªã³ïŒå
ç69ïŒ ïŒãåŸãã 次ã«ãïŒïŒ®âãžã¡ãã«ãã«ã ã¢ãã54ïœã20
â以äžã«ä¿æãããªãã·å¡©åãªã³44.5ïœã30åé
ã§æ»Žäžããã äžèšã§åŸããããžãããã«ã¢ããªã³35ïœãïŒæ
éã§æ»Žäžããã滎äžçµäºåŸ90ã95âã§ïŒæéå ç±
æªæããããã®åŸãåå¿æ¶²ãæ°·æ°Žã«å ã飜åé ¢é ž
ãããªãŠã 溶液ã§äžåããããšãŒãã«100mlã§ïŒ
åæœåºããç¡æ°Žç¡«é žãããªãŠã ã§ä¹Ÿç¥ããããšãŒ
ãã«ãçå»åŸãæžå§èžçïŒb.p155ã163âïŒïŒmm
HgïŒããŠãžãããã«ã¢ãããã³ãºã¢ã«ããã
ïŒåç46ïŒ ïŒãåŸãã ãã®ãžãããã«ã¢ãããã³ãºã¢ã«ããã11.6ïœ
ã95ïŒ ãšã¿ããŒã«23mlã«æº¶è§£ããããã«å¡©é žãã
ããã·ã¢ãã³æ°Žæº¶æ¶²ïŒ4.7ïœïŒ5.7mlïŒãå ã20å
éæªæãããåå¿æ¶²ã«æ°Žé žåãããªãŠã 氎溶液
ïŒ3.4ïœïŒ4.5mlïŒãå ãïŒæé30å宀枩ã§æŸçœ®ã
ããæ°·29ïœãå ãåå¿ç³»å ãCO2ã¬ã¹ã§çœ®æãã
åŸãå·èµåº«äžã§äžæ©æŸçœ®ãããæåºããçœè²çµæ¶
ãåžåŒãéããçµæ¶ãæ°ŽæŽããåŸä¹Ÿç¥ããã åŸãããååç©ã«ç¡æ°Žé ¢é ž12.4ïœãå ã20åé
å ç±éæµããããã®åŸãå·æ°Ž35mlã«åå¿æ¶²ãå ã
æ°Žé žåãããªãŠã 溶液ã§äžåããããšãŒãã«40ml
ã§ïŒåæœåºããæœåºæ¶²ãç¡æ°Žç¡«é žãããªãŠã ã§ä¹Ÿ
ç¥ããããšãŒãã«çå»åŸæžå§èžçïŒb.p180âïŒïŒ
mmHgïŒããŠïŒâãžãããã«ã¢ãããã³ãŸãããª
ã«ïŒåç79ïŒ ïŒãåŸãããããæŸçœ®ããŠãããšçµ
æ¶åããèç¹39ã41âã®é»è²çµæ¶ãšãªã€ãã 補é äŸ ïŒ ãïŒâãžã¡ãã«ã¢ãããã³ãŸãããªã«ã®è£œé ã 補é äŸïŒã®æé ã«åŸã€ãŠåæãããžã¡ãã«ã¢ã
ããã³ãºã¢ã«ããã29.8ïœãå¡©é žããããã·ã¢ã
ã³15.9ïœãã®é žãããªãŠã 25ïœããã³ã®é ž333ml
ãïŒæéå ç±éæµãããåå¿æ¶²ãæ°Ž800mlã«æªæ
ããªãã滎äžãããšæ·¡ç·è²ã®çµæ¶ãæåºãããã
éåŸä¹Ÿç¥ããã¢ã»ãã³ã§åçµæ¶ããèç¹67ã69â
ã®ïŒâãžã¡ãã«ã¢ãããã³ãŸãããªã«ïŒåç50
ïŒ ïŒãåŸãã 補é äŸ ïŒ ãïŒâãžãšãã«ã¢ãããã³ãŸãããªã«ã®è£œé ã 補é äŸïŒã®æé ã«åŸã€ãŠåæãããžãšãã«ã¢ã
ããã³ãºã¢ã«ããã25ïœãå¡©é žããããã·ã¢ãã³
10.5ïœãã®é žãããªãŠã 16.5ïœããã³ã®é ž220ml
ãïŒæéå ç±éæµãããåå¿æ¶²ãæ°Ž400mlã«æªæ
ããªããæ·»å ãããšçœè²ã®çµæ¶ãæåºããããé
åŸä¹Ÿç¥ãæ°Žâã¢ã»ãã³ã§åçµæ¶ããèç¹66ã67â
ã®ïŒâãžãšãã«ã¢ãããã³ãŸãããªã«ïŒåç50
ïŒ ïŒãåŸãã 補é äŸ ïŒ ãååç©ïŒïŒã®è£œé ã ææã§æ¿ç¡«é ž35ïœã60âã«ä¿æããããã«è£œé
äŸïŒã§åŸãïŒâãžã¡ãã«ã¢ããâ2â²âãã«ãªã«ã
ã³ãŸã€ã³2.4ïœã補é äŸïŒã§åŸãïŒâãžãããã«
ã¢ãããã³ãŸãããªã«2.1ïœã®æ··åç©ãå ãïŒæ
éæªæãããåå¿æ¶²ãæ°Ž900mlã«å ãããšé»ç·ã®
æ²æ®¿ãæåºããããéåŸãé液ã3Næ°Žé žåãã
ãªãŠã 溶液ã§ã¢ã«ã«ãªæ§ã«ãããšæ·¡é»è²ã®çµæ¶ã
æåºããããããåžåŒãéã颚也ãããã¡ã¿ããŒ
ã«ã§åçµæ¶ããŠæ·¡é»è²åºäœ1.73ïœïŒåç43ïŒ ïŒã
åŸãããã®æ·¡é»è²åºäœã¯äžèšã®åæçµæããïŒâ
ïŒïŒâãžãããã«ã¢ããããšãã«ïŒâïŒâïŒïŒâãž
ã¡ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâãã«ãªã«ããš
ãã«ïŒâïŒïŒïŒâãªããµãŸãŒã«ïŒååç©ïŒã§ã
ãããšã確èªããã (1) èç¹ïŒ134ã135â (2) å çŽ åæå€ïŒC29H32N3OF    èšç®å€(%) 76.15 7.00 9.19 å®æž¬å€(%) 76.07 7.11 9.15 補é äŸ ïŒ ãååç©ïŒïŒã®è£œé ã ææã§æ¿ç¡«é ž35ïœã60âã«ä¿æããããã«è£œé
äŸïŒã§åŸãïŒâãžã¡ãã«ã¢ããâ2â²âãã«ãªã«ã
ã³ãŸã€ã³2.4ïœã補é äŸïŒã§åŸãïŒâãžã¡ãã«ã¢
ãããã³ãŸãããªã«1.5ïœã®æ··åç©ãå ã30åé
æªæãããåå¿æ¶²ãæ°Ž900mlã«å ãããšé»ç·ã®æ²
殿ãæåºããããéåŸã液ã3Næ°Žé žåãããªãŠ
ã 溶液ã§ã¢ã«ã«ãªæ§ã«ãããšæ·¡é»è²ã®çµæ¶ãæåº
ããããããåžåŒãéã颚也ãããã¡ã¿ããŒã«ã§
åçµæ¶ããŠæ·¡é»è²åºäœ1.56ïœïŒåç44ïŒ ïŒãåŸ
ãããã®æ·¡é»è²åºäœã¯äžèšã®åæçµæããïŒâ
ïŒïŒâãžã¡ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâãžã¡
ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâãã«ãªã«ããšã
ã«ïŒâïŒïŒïŒâãªããµãŸãŒã«ïŒååç©ïŒã§ã
ãããšã確èªããã (1) èç¹ïŒ172ã173â (2) å çŽ åæå€ïŒC25H24N3OF    èšç®å€(%) 74.79 6.03 10.47 å®æž¬å€(%) 74.53 6.04 10.47 補é äŸ ïŒ ãååç©ïŒïŒã®è£œé ã ææã§æ¿ç¡«é ž32ïœã60âã«ä¿æããããã«è£œé
äŸïŒã§åŸãïŒâãžãšãã«ã¢ããâ2â²âãã«ãªã«ã
ã³ãŸã€ã³2.2ïœã補é äŸïŒã§åŸãïŒâãžãšãã«ã¢
ãããã³ãŸãããªã«1.64ïœã®æ··åç©ãå ãïŒæé
æªæãããåå¿æ¶²ãæ°Ž800mlã«å ãããšé»ç·ã®æ²
殿ãæåºããããéåŸã液ã3Næ°Žé žåãããªãŠ
ã 溶液ã§ã¢ã«ã«ãªæ§ã«ãããšãæ·¡é»è²ã®çµæ¶ãæ
åºããããããåžåŒãéã颚也ãããã¡ã¿ããŒã«
ã§åçµæ¶ããŠæ·¡é»è²åºäœ1.39ïœïŒåç40ïŒ ïŒãåŸ
ãããã®æ·¡é»è²åºäœã¯äžèšã®åæçµæããïŒâ
ïŒïŒâãžãšãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâãžã¡
ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâãã«ãªã«ããšã
ã«ïŒâïŒïŒïŒâãªããµãŸãŒã«ïŒååç©ïŒã§ãã
ããšã確èªããã (1) èç¹ïŒ102ã105â (2) å çŽ åæå€ïŒC27H28N3OF    èšç®å€(%) 75.35 6.51 9.77 å®æž¬å€(%) 75.25 6.53 9.72 å®æœäŸïŒãïŒã§çšãããªããµãŸãŒã«èªå°äœ
ãïŒïŒïŒïŒïŒããã³ïŒïŒãããã³æ¯èŒãšããŠåŸ
æ¥çšããããŠãããªããµãŸãŒã«èªå°äœãšããŠïŒâ
ïŒïŒâãžãšãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâãžã¡
ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâã¯ããããšã
ã«ïŒâïŒïŒïŒâãªããµãŸãŒã«ïŒïŒã®çŽ«å€ç·ç §å°
ã«å¯Ÿããå®å®æ§ã®è©Šéšã次ã®ããã«ããŠè¡ãªã€
ãã ååç©ïŒïŒïŒïŒïŒïŒïŒïŒããã³ïŒïŒãå¥ã
ã«ïŒÃ10-4molïŒã®æ¿åºŠã§æº¶è§£ããŠãªãã¢ã»ã
ãããªã«æº¶æ¶²ã«ãããããçªçŽ ã¬ã¹ãäžæééæ°
ããåŸçªçŽ ã¬ãŠãéæ°ããªãã150Wé«å§æ°Žéç
ã§ç §å°ãããç §å°éå§åŸïŒåééã§è©Šæãæ¡å
ããã¢ã»ããããªã«æº¶æ¶²ã§äžå®çã§åžéããåŸã
玫å€åå å 床èšãçšããŠåžåã¹ãã¯ãã«ã®å€åã
調ã¹ãã æ¯èŒã«çšããååç©ïŒïŒã¯ãæ°Žéçç §å°ïŒå
åŸã«ã¯ãåæã®åžåã¹ãã¯ãã«ïŒÎ»maxïŒ
363.0nm εïŒ4.8Ã104ïŒmolã»cmïŒ310nm
shoulderãšã¯éã€ãåžåã¹ãã¯ãã«ïŒÎ»maxïŒ
370.0nmïŒ258.0nmïŒ245.0nmïŒã«å€åããŠããã
åŸè ã®åžåã¹ãã¯ãã«ã¯ãååç©ïŒïŒãå解ã
ãŠçããïŒâïŒïŒâãžãšãã«ã¢ããããšãã«ïŒâïŒ
âãžã¡ãã«ã¢ããããšãã³ãããïŒïŒ10âïœããª
ããµãŸãŒã«ã«ãããã®ã§ãããæ¯èŒã«çšããåå
ç©ïŒïŒã®å解çã¯ãåæéã«ãããåžåã¹ãã¯
ãã«ã®å解ã«ããçŸããã258.0nmã®åžå 床枬å®
ããLambartâBeerã®æ³æž¬ãçšããŠå解ç©ã®ç
ææ¿åºŠããæ±ããã æ¬çºæã®é»ååçæå äœã«çšããé»è·æ¬éç©è³ª
ïŒïŒïŒïŒïŒããã³ïŒïŒã¯ãç §å°60ååŸã«ãã
ãŠãåæã®ã¹ãã¯ãã«ïŒïŒ¶ïŒÎ»maxïŒ363.0nm ε
ïŒ4.9Ã104ïŒmolã»cmïŒ310.0nm shoulderïŒ
ïŒÎ»maxïŒ359.0nm εïŒ4.5Ã104ïŒmolã»cmïŒ
310.0nm shoulderïŒïŒÎ»maxïŒ363.0nm εïŒ
4.5Ã104ïŒmolã»cmïŒ310.0nm shoulderïŒãšåž
åã¹ãã¯ãã«ã®ãã¿ãŒã³ã¯å€åããªãããããã®
ååç©ã®å解çã¯ãåæéã«ãããåžåã¹ãã¯ã
ã«ã®310.0nmã®åžå 床ïŒA310.0ïŒãšÎ»maxã®åžå 床
ïŒAλmaxïŒã®æ¯ïŒA310.0ïŒAλmaxïŒããè©äŸ¡ã
ãã ååç©ïŒïŒïŒïŒïŒããã³ïŒïŒã®ã¢ã»ããã
ãªã«æº¶æ¶²ã®é«å§æ°Žéçç §å°ã«ããå å解çã®çµæ
å€åã第ïŒå³ã«ç€ºãã第ïŒå³äžæ²ç·ïŒã¯ãååç©
ïŒïŒã®å解çã瀺ããæ²ç·ïŒã¯ãååç©ïŒïŒ
ã®å解çã瀺ããæ²ç·ïŒã¯ãååç©ïŒïŒã®å解
çã瀺ãããã³æ²ç·ïŒã¯ååç©ïŒïŒã®å解çã
瀺ãã ïŒçºæã®å¹æïŒ ä»¥äžããæãããªããã«ãæ¬çºæã«ä¿ãé»åå
çæå äœã¯ã玫å€ç·ç §å°ã«å¯ŸããŠå®å®ã§ãããè¯
奜ãªé»ååçç¹æ§ãæããé»ååçæå äœã§ã
ãã
第ïŒå³ã¯ãååç©ïŒïŒïŒïŒïŒïŒïŒïŒããã³
ïŒïŒã®ã¢ã»ããããªã«æº¶æ¶²ã®é«å§æ°Žéçç §å°ã«
ããå解çã®çµæå€åã§ããã 笊å·ã®èª¬æãïŒâŠâŠå®æœäŸïŒã§çšãããªããµãŸ
ãŒã«èªå°äœïŒïŒã®å解çã瀺ãæ²ç·ãïŒâŠâŠå®
æœäŸïŒã§çšãããªããµãŸãŒã«èªå°äœïŒïŒã®å解
çã瀺ãæ²ç·ãïŒâŠâŠå®æœäŸïŒã§çšãããªããµãŸ
ãŒã«èªå°äœïŒïŒã®å解çã瀺ãæ²ç·ãïŒâŠâŠæ¯
èŒã«çšãããªããµãŸãŒã«èªå°äœïŒïŒã®å解çã
瀺ãæ²ç·ã
ïŒïŒã®ã¢ã»ããããªã«æº¶æ¶²ã®é«å§æ°Žéçç §å°ã«
ããå解çã®çµæå€åã§ããã 笊å·ã®èª¬æãïŒâŠâŠå®æœäŸïŒã§çšãããªããµãŸ
ãŒã«èªå°äœïŒïŒã®å解çã瀺ãæ²ç·ãïŒâŠâŠå®
æœäŸïŒã§çšãããªããµãŸãŒã«èªå°äœïŒïŒã®å解
çã瀺ãæ²ç·ãïŒâŠâŠå®æœäŸïŒã§çšãããªããµãŸ
ãŒã«èªå°äœïŒïŒã®å解çã瀺ãæ²ç·ãïŒâŠâŠæ¯
èŒã«çšãããªããµãŸãŒã«èªå°äœïŒïŒã®å解çã
瀺ãæ²ç·ã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ å°é»æ§æ¯æäœäžã«ãé»è·çºçç©è³ªãå«ãé»è·
çºçå±€åã³é»è·æ¬éç©è³ªãå«ãé»è·æ¬éå±€ãæã
ãè€ååã®é»ååçæå äœã«ãããŠãåèšé»è·çº
çç©è³ªããÏåÏâ²åãηååã³Î·â²åç¡éå±ãã¿ã
ã·ã¢ãã³ã®ãã¡å°ãªããšãäžçš®é¡ãå«ã¿ãé»è·æ¬
éç©è³ªããäžè¬åŒïŒïŒ ïŒãã ãåŒäžãR1ïŒR2ïŒR3ããã³R4ã¯ãã¢ã«
ãã«åºã瀺ãããããã¯åäžã§ãç°ãªã€ãŠãã
ãïŒã§è¡šããããªããµãŸãŒã«èªå°äœã§ããããšã
ç¹åŸŽãšããé»ååçæå äœã
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9266184A JPS60237454A (ja) | 1984-05-09 | 1984-05-09 | é»ååçæå äœ |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9266184A JPS60237454A (ja) | 1984-05-09 | 1984-05-09 | é»ååçæå äœ |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS60237454A JPS60237454A (ja) | 1985-11-26 |
JPH0452940B2 true JPH0452940B2 (ja) | 1992-08-25 |
Family
ID=14060654
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP9266184A Granted JPS60237454A (ja) | 1984-05-09 | 1984-05-09 | é»ååçæå äœ |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60237454A (ja) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62111257A (ja) * | 1985-07-02 | 1987-05-22 | Dainippon Ink & Chem Inc | é»ååççšæå äœ |
JP2564875B2 (ja) * | 1988-02-26 | 1996-12-18 | æ¥ç«åæå·¥æ¥æ ªåŒäŒç€Ÿ | é»ååçæå äœ |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3257203A (en) * | 1958-08-20 | 1966-06-21 | Azoplate Corp | Electrophotographic reproduction material |
JPS56123544A (en) * | 1980-03-03 | 1981-09-28 | Hitachi Ltd | Composite type electrophotographic plate and electrophotographic method using it |
-
1984
- 1984-05-09 JP JP9266184A patent/JPS60237454A/ja active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3257203A (en) * | 1958-08-20 | 1966-06-21 | Azoplate Corp | Electrophotographic reproduction material |
JPS56123544A (en) * | 1980-03-03 | 1981-09-28 | Hitachi Ltd | Composite type electrophotographic plate and electrophotographic method using it |
Also Published As
Publication number | Publication date |
---|---|
JPS60237454A (ja) | 1985-11-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4869988A (en) | Photoconductive imaging members with N,N-bis(biarylyl)aniline, or tris(biarylyl)amine charge transporting components | |
EP0277039A2 (en) | Electrophotograhic plate by use of metal naphthalocyanine derivative | |
JPH08211636A (ja) | é»ååççšæå äœ | |
JPH0229208B2 (ja) | ||
JPH0452940B2 (ja) | ||
JPH09138512A (ja) | é»ååçæå äœ | |
JPH0727245B2 (ja) | é»ååçæå äœ | |
JPH05100456A (ja) | é»ååççšæå äœ | |
JPH0416851A (ja) | é»ååççšæå äœ | |
JP2988055B2 (ja) | é»ååççšæå äœ | |
US5753393A (en) | Electrophotographic photoreceptor | |
JP2748497B2 (ja) | ãªãã·ãã¿ããŠã ãã¿ãã·ã¢ãã³çµæ¶ã®è£œé æ³ | |
JP2748736B2 (ja) | é»ååçæå äœ | |
JP3232738B2 (ja) | ãã¿ãã·ã¢ãã³çµæç©ããã®è£œé æ³ããã³ãããçšããé»ååçæå äœãªãã³ã«é»è·çºçå±€çšå¡å·¥æ¶² | |
JP2875360B2 (ja) | é»ååçæå äœ | |
JPH04362653A (ja) | é»ååçæå äœ | |
JP3551395B2 (ja) | é»ååçæå äœ | |
KR900006391B1 (ko) | ì ìì¬ì§ì© ê°êŽì²Ž | |
JPH09297415A (ja) | é»ååççšæå äœ | |
JP3290875B2 (ja) | é»ååçæå äœã䞊ã³ã«ããã¹ã¢ãŸååç©ãäžéäœåã³ãã¹ã¢ãŸååç©ã®è£œé æ¹æ³ | |
JPS6219746B2 (ja) | ||
JPH09216877A (ja) | ïŒïŒïŒâãžã¡ãã«ããµã³ãã³ååç©åã³è©²ååç©ãçšããé»ååççšæå äœ | |
JP2890876B2 (ja) | æå äœ | |
JPH0373961A (ja) | é»ååçæå äœ | |
JPH0644160B2 (ja) | é»ååççšæå ææã®è£œé æ¹æ³ |