JPH0437094B2 - - Google Patents
Info
- Publication number
- JPH0437094B2 JPH0437094B2 JP12503087A JP12503087A JPH0437094B2 JP H0437094 B2 JPH0437094 B2 JP H0437094B2 JP 12503087 A JP12503087 A JP 12503087A JP 12503087 A JP12503087 A JP 12503087A JP H0437094 B2 JPH0437094 B2 JP H0437094B2
- Authority
- JP
- Japan
- Prior art keywords
- fluorine
- containing elastomer
- vulcanized
- present
- vulcanization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001971 elastomer Polymers 0.000 claims description 32
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 26
- 229910052731 fluorine Inorganic materials 0.000 claims description 26
- 239000011737 fluorine Substances 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 24
- 239000000806 elastomer Substances 0.000 claims description 23
- 150000001875 compounds Chemical class 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 5
- 238000012986 modification Methods 0.000 claims description 4
- 230000004048 modification Effects 0.000 claims description 4
- 238000004073 vulcanization Methods 0.000 description 15
- 238000004381 surface treatment Methods 0.000 description 11
- 230000001070 adhesive effect Effects 0.000 description 10
- 239000000853 adhesive Substances 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- ZFVMWEVVKGLCIJ-UHFFFAOYSA-N bisphenol AF Chemical compound C1=CC(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C=C1 ZFVMWEVVKGLCIJ-UHFFFAOYSA-N 0.000 description 4
- 229920001973 fluoroelastomer Polymers 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- -1 magnesium oxide Chemical class 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910000000 metal hydroxide Inorganic materials 0.000 description 2
- 150000004692 metal hydroxides Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000002715 modification method Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- HHVIBTZHLRERCL-UHFFFAOYSA-N sulfonyldimethane Chemical compound CS(C)(=O)=O HHVIBTZHLRERCL-UHFFFAOYSA-N 0.000 description 2
- LLOXZCFOAUCDAE-UHFFFAOYSA-N 2-diphenylphosphorylbenzene-1,4-diol Chemical compound OC1=CC=C(O)C(P(=O)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 LLOXZCFOAUCDAE-UHFFFAOYSA-N 0.000 description 1
- GPAPPPVRLPGFEQ-UHFFFAOYSA-N 4,4'-dichlorodiphenyl sulfone Chemical compound C1=CC(Cl)=CC=C1S(=O)(=O)C1=CC=C(Cl)C=C1 GPAPPPVRLPGFEQ-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- OMFMOEOGTAYVMW-UHFFFAOYSA-N CC=C.C=C.C=C(F)F.F.F.F.F.F.F.F.F.F.F Chemical compound CC=C.C=C.C=C(F)F.F.F.F.F.F.F.F.F.F.F OMFMOEOGTAYVMW-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- USFRYJRPHFMVBZ-UHFFFAOYSA-M benzyl(triphenyl)phosphanium;chloride Chemical compound [Cl-].C=1C=CC=CC=1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)CC1=CC=CC=C1 USFRYJRPHFMVBZ-UHFFFAOYSA-M 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- CCAFPWNGIUBUSD-UHFFFAOYSA-N diethyl sulfoxide Chemical compound CCS(=O)CC CCAFPWNGIUBUSD-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- ULYZAYCEDJDHCC-UHFFFAOYSA-N isopropyl chloride Chemical compound CC(C)Cl ULYZAYCEDJDHCC-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- NIQQIJXGUZVEBB-UHFFFAOYSA-N methanol;propan-2-one Chemical compound OC.CC(C)=O NIQQIJXGUZVEBB-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62125030A JPS63291930A (ja) | 1987-05-23 | 1987-05-23 | 含フツ素エラストマ−成形品の表面改質方法 |
| DE3886818T DE3886818T2 (de) | 1987-05-23 | 1988-05-04 | Aus einem vernetzten Elastomer geformter Gegenstand. |
| EP88107173A EP0292747B1 (en) | 1987-05-23 | 1988-05-04 | A shaped article of a crosslinked elastomer |
| US07/191,063 US4981912A (en) | 1987-05-23 | 1988-05-06 | Shaped article of a crosslinked elastomer |
| CA000567375A CA1325507C (en) | 1987-05-23 | 1988-05-20 | Shaped article of a crosslinked elastomer |
| KR1019880006024A KR910003958B1 (ko) | 1987-05-23 | 1988-05-21 | 표면 개질된 엘라스토머-가류성형체 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62125030A JPS63291930A (ja) | 1987-05-23 | 1987-05-23 | 含フツ素エラストマ−成形品の表面改質方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63291930A JPS63291930A (ja) | 1988-11-29 |
| JPH0437094B2 true JPH0437094B2 (enExample) | 1992-06-18 |
Family
ID=14900109
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62125030A Granted JPS63291930A (ja) | 1987-05-23 | 1987-05-23 | 含フツ素エラストマ−成形品の表面改質方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63291930A (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007080681A1 (ja) | 2006-01-11 | 2007-07-19 | Nok Corporation | フッ素ゴム架橋体の製造方法 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0816174B2 (ja) * | 1991-01-17 | 1996-02-21 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 加硫成形体の製造方法 |
| JP6001274B2 (ja) | 2012-02-15 | 2016-10-05 | スリーエム イノベイティブ プロパティズ カンパニー | フルオロポリマー組成物 |
| WO2019126298A1 (en) * | 2017-12-22 | 2019-06-27 | 3M Innovative Properties Company | Peroxide-cured halogenated elastomers having a silicon-containing superficial layer |
-
1987
- 1987-05-23 JP JP62125030A patent/JPS63291930A/ja active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007080681A1 (ja) | 2006-01-11 | 2007-07-19 | Nok Corporation | フッ素ゴム架橋体の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63291930A (ja) | 1988-11-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1189210A (en) | Fluoroelastomer film compositions containing silane compounds and method for the preparation thereof | |
| JP5336051B2 (ja) | パーフルオロエラストマー組成物及びシール材 | |
| EP0292747B1 (en) | A shaped article of a crosslinked elastomer | |
| JP4168480B2 (ja) | フッ素ゴム水性塗料組成物および被覆物品 | |
| JPS6142955B2 (enExample) | ||
| WO2001085858A1 (en) | Fluororubber coating composition | |
| JPH0437094B2 (enExample) | ||
| JPH0335032A (ja) | 表面改質含フッ素エラストマー加硫成形体の製造法 | |
| Gu et al. | Effect of sequence structure on wetting behaviors of fluorinated methacrylate polymers based on perfluorohexylethyl methacrylate and stearyl acrylate | |
| JPH04236232A (ja) | 加硫成形体の製造方法 | |
| JPH04209633A (ja) | 非粘着性シリコンゴム材料およびその製造法 | |
| JPH01131255A (ja) | 表面改質エラストマー加硫成形体 | |
| JPH02215839A (ja) | 表面改質含フッ素エラストマー加硫成形体 | |
| JPH0124810B2 (enExample) | ||
| JPS61247744A (ja) | 加硫ゴム成形品の表面処理方法 | |
| Guerrouani et al. | Fluorinated-plasma coating on polyhydroxyalcanoate PHBV: Effect on the biodegradation | |
| JPH0260901A (ja) | 高耐油性ゴム成形品 | |
| JPS63295647A (ja) | 加硫ゴム成形品の表面処理方法 | |
| JPH07133464A (ja) | フッ素ゴム用表面処理液及びこれを用いた処理方法並びにこの表面処理液で表面処理されたフッ素ゴム成型体 | |
| JPH0598055A (ja) | 表面改質含フツ素エラストマー加硫成形体の製造方法 | |
| Hwang et al. | Diffusion and sorption behavior of glycidyl methacrylate in styrene butadiene rubber | |
| JP2000080190A (ja) | 加硫ゴム成形品の表面処理方法 | |
| JP3682255B2 (ja) | ゴム用添加剤、ゴム組成物およびゴム製品 | |
| JPH10195405A (ja) | ブチルゴム粘着剤組成物及びそれを用いた粘着テープ又はシート | |
| JPS63120744A (ja) | 加硫ゴム成形品の表面処理方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |