JPH0415469B2 - - Google Patents
Info
- Publication number
- JPH0415469B2 JPH0415469B2 JP10233385A JP10233385A JPH0415469B2 JP H0415469 B2 JPH0415469 B2 JP H0415469B2 JP 10233385 A JP10233385 A JP 10233385A JP 10233385 A JP10233385 A JP 10233385A JP H0415469 B2 JPH0415469 B2 JP H0415469B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- formula
- photoreceptor
- carrier
- dialkylamino
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 108091008695 photoreceptors Proteins 0.000 claims description 85
- 239000000126 substance Substances 0.000 claims description 36
- -1 azo compound Chemical class 0.000 claims description 35
- 125000004663 dialkyl amino group Chemical group 0.000 claims description 16
- 125000000217 alkyl group Chemical group 0.000 claims description 14
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 13
- 125000003545 alkoxy group Chemical group 0.000 claims description 8
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 8
- 125000004986 diarylamino group Chemical group 0.000 claims description 8
- 125000005843 halogen group Chemical group 0.000 claims description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 8
- 125000004185 ester group Chemical group 0.000 claims description 7
- 125000001424 substituent group Chemical group 0.000 claims description 7
- 125000002252 acyl group Chemical group 0.000 claims description 5
- 125000003277 amino group Chemical group 0.000 claims description 2
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims 1
- 239000010410 layer Substances 0.000 description 69
- 150000001875 compounds Chemical class 0.000 description 40
- 239000010408 film Substances 0.000 description 19
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 17
- 230000035945 sensitivity Effects 0.000 description 16
- 238000005259 measurement Methods 0.000 description 12
- 238000001035 drying Methods 0.000 description 11
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 9
- 239000006185 dispersion Substances 0.000 description 8
- 239000004419 Panlite Substances 0.000 description 7
- 239000011230 binding agent Substances 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 239000004065 semiconductor Substances 0.000 description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 239000004417 polycarbonate Substances 0.000 description 5
- 229920000515 polycarbonate Polymers 0.000 description 5
- 229920006267 polyester film Polymers 0.000 description 5
- 229910052711 selenium Inorganic materials 0.000 description 5
- 239000011669 selenium Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000004431 polycarbonate resin Substances 0.000 description 4
- 229920005668 polycarbonate resin Polymers 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000003595 spectral effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- UBOXGVDOUJQMTN-UHFFFAOYSA-N 1,1,2-trichloroethane Chemical compound ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 2
- ZXBSSAFKXWFUMF-UHFFFAOYSA-N 1,2,3-trinitrofluoren-9-one Chemical compound C12=CC=CC=C2C(=O)C2=C1C=C([N+](=O)[O-])C([N+]([O-])=O)=C2[N+]([O-])=O ZXBSSAFKXWFUMF-UHFFFAOYSA-N 0.000 description 2
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 2
- VOPISUYJMWWTCD-UHFFFAOYSA-N 9-(4-methoxyphenyl)-3-[2-(4-methoxyphenyl)ethenyl]carbazole Chemical compound C1=CC(OC)=CC=C1C=CC1=CC=C(N(C=2C=CC(OC)=CC=2)C=2C3=CC=CC=2)C3=C1 VOPISUYJMWWTCD-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 description 2
- 239000012790 adhesive layer Substances 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 239000002612 dispersion medium Substances 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 229920006158 high molecular weight polymer Polymers 0.000 description 2
- 239000000113 methacrylic resin Substances 0.000 description 2
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- DNXIASIHZYFFRO-UHFFFAOYSA-N pyrazoline Chemical compound C1CN=NC1 DNXIASIHZYFFRO-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 1
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- JOERSAVCLPYNIZ-UHFFFAOYSA-N 2,4,5,7-tetranitrofluoren-9-one Chemical compound O=C1C2=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C2C2=C1C=C([N+](=O)[O-])C=C2[N+]([O-])=O JOERSAVCLPYNIZ-UHFFFAOYSA-N 0.000 description 1
- IKOKHHBZFDFMJW-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-3-(2-morpholin-4-ylethoxy)pyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C=1C(=NN(C=1)CC(=O)N1CC2=C(CC1)NN=N2)OCCN1CCOCC1 IKOKHHBZFDFMJW-UHFFFAOYSA-N 0.000 description 1
- GMGDWNYWMLZUEF-UHFFFAOYSA-N 2-hydroxy-n-(4-methoxy-2-methylphenyl)-11h-benzo[a]carbazole-3-carboxamide Chemical compound CC1=CC(OC)=CC=C1NC(=O)C1=CC2=CC=C(C=3C(=CC=CC=3)N3)C3=C2C=C1O GMGDWNYWMLZUEF-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- HSABKLSZLQDFEE-UHFFFAOYSA-N 3-(4-methylphenyl)-5-[2-(4-methylphenyl)ethenyl]-2-phenyl-1,3-dihydropyrazole Chemical compound C1=CC(C)=CC=C1C=CC1=CC(C=2C=CC(C)=CC=2)N(C=2C=CC=CC=2)N1 HSABKLSZLQDFEE-UHFFFAOYSA-N 0.000 description 1
- KIGTXAWIOISJOG-UHFFFAOYSA-N 4-methoxy-n,n-diphenylaniline Chemical compound C1=CC(OC)=CC=C1N(C=1C=CC=CC=1)C1=CC=CC=C1 KIGTXAWIOISJOG-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229920005497 Acrypet® Polymers 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 239000004420 Iupilon Substances 0.000 description 1
- OALZJTDPAJELTH-UHFFFAOYSA-N N-[1-(1-ethyl-9H-carbazol-4-yl)-3,4-dihydro-2H-quinolin-2-yl]methanimine Chemical compound C12=CC=CC=C2NC2=C1C(N1C3=CC=CC=C3CCC1N=C)=CC=C2CC OALZJTDPAJELTH-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 1
- 150000001716 carbazoles Chemical class 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000000434 field desorption mass spectrometry Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 150000007857 hydrazones Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 229910003437 indium oxide Inorganic materials 0.000 description 1
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 229940079865 intestinal antiinfectives imidazole derivative Drugs 0.000 description 1
- 229940102253 isopropanolamine Drugs 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- UHEPMPUUNDWUGP-UHFFFAOYSA-N n,n-diethyl-4-[1-[2-(4-methoxyphenyl)ethenyl]-2-phenyl-3h-pyrazol-3-yl]aniline Chemical compound C1=CC(N(CC)CC)=CC=C1C1N(C=2C=CC=CC=2)N(C=CC=2C=CC(OC)=CC=2)C=C1 UHEPMPUUNDWUGP-UHFFFAOYSA-N 0.000 description 1
- CVKIMZDUDFGOLC-UHFFFAOYSA-N n,n-diphenyl-2-(2-phenylethenyl)aniline Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1N(C=1C=CC=CC=1)C1=CC=CC=C1 CVKIMZDUDFGOLC-UHFFFAOYSA-N 0.000 description 1
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 150000004866 oxadiazoles Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 125000001484 phenothiazinyl group Chemical class C1(=CC=CC=2SC3=CC=CC=C3NC12)* 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 150000003219 pyrazolines Chemical class 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 239000001119 stannous chloride Substances 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical class C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 229940066767 systemic antihistamines phenothiazine derivative Drugs 0.000 description 1
- 229940042055 systemic antimycotics triazole derivative Drugs 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 125000005259 triarylamine group Chemical group 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/0664—Dyes
- G03G5/0675—Azo dyes
- G03G5/0679—Disazo dyes
- G03G5/0681—Disazo dyes containing hetero rings in the part of the molecule between the azo-groups
Landscapes
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Photoreceptors In Electrophotography (AREA)
Description
ïŒç£æ¥äžã®å©çšåéïŒ
æ¬èæ¡ã¯æå
äœã«é¢ãã詳ããã¯ç¹å®ã®ã¢ãŸå
åç©ãå«æããæå å±€ãæããæ°èŠãªæå äœã«é¢
ããã ïŒåŸæ¥ã®æè¡ïŒ åŸæ¥ãé»ååçæå äœãšããŠã¯ãã»ã¬ã³ãé žå
äºéãç¡«åã«ãããŠã ãã·ãªã³ã³çã®ç¡æ©å å°é»
æ§ååç©ãäž»æåãšããæå å±€ãæããç¡æ©æå
äœãåºãçšããããŠããããããããããã¯æ
床ãç±å®å®æ§ãè湿æ§ãèä¹ æ§çã«ãããŠå¿ ãã
ãæºè¶³ãåŸããã®ã§ã¯ãªããäŸãã°ãã»ã¬ã³ã¯çµ
æ¶åãããšæå äœãšããŠã®ç¹æ§ãå£åããŠããŸã
ããã補é äžãé£ããããŸãç±ãæçµçãåå ãš
ãªãçµæ¶åããæå äœãšããŠã®æ§èœãå£åããŠã
ãŸãããŸãç¡«åã«ãããŠã ã§ã¯è湿æ§ãèä¹ æ§ã
é žåäºéã§ãèä¹ æ§çã«åé¡ãããã ãããç¡æ©æå äœã®æã€æ¬ ç¹ãå æããç®çã§
æ§ã ãªææ©å å°é»æ§ååç©ãäž»æåãšããæå å±€
ãæããææ©æå äœã®éçºã»ç 究ãè¿å¹Žçãã«è¡
ãªãããŠãããäŸãã°ç¹å ¬æ50â10496å·å ¬å ±ã«
ã¯ããªââããã«ã«ã«ããŸãŒã«ãšïŒïŒïŒïŒïŒâ
ããªãããâïŒâãã«ãªã¬ãã³ãå«æããæå å±€
ãæããææ©æå äœã®èšèŒããããããããã®æ
å äœã¯ãæ床åã³èä¹ æ§ã«ãããŠå¿ ãããæºè¶³ã§
ãããã®ã§ã¯ãªãããã®ãããªæ¬ ç¹ãæ¹è¯ããã
ãã«ãã€ãªã¢çºçæ©èœãšãã€ãªã¢èŒžéæ©èœãšãç°
ãªãç©è³ªã«åæ ãããããé«æ§èœã®ææ©æå äœã
éçºããè©Šã¿ããªãããŠããããã®ãããªããã
ãæ©èœåé¢åã®æå äœã¯ãããããã®ææãåºã
ç¯å²ããéžæããããšãã§ããä»»æã®æ§èœãæã
ãæå äœãæ¯èŒç容æã«äœæãåŸãããšããå€ã
ã®ç 究ããªãããŠããã ãçºæã解決ããããšããåé¡ç¹ã äžèšã®ãããªæ©èœåé¢åã®æå äœã«ãããŠãã
ã®ãã€ãªã¢çºçç©è³ªãšããŠãæ°å€ãã®ååç©ãæ
æ¡ãããŠãããç¡æ©ååç©ããã€ãªã¢çºçç©è³ªãš
ããŠçšããäŸãšããŠã¯ãäŸãã°ãç¹å ¬æ43â
16198å·å ¬å ±ã«èšèŒãããç¡å®åœ¢ã»ã¬ã³ãããã
ããã¯ææ©å å°é»æ§ååç©ãšçµã¿åãããŠäœ¿çšã
ããããç¡å®åœ¢ã»ã¬ã³ãããªããã€ãªã¢çºçå±€ã¯
ç±ã«ããçµæ¶åããŠæå äœãšããŠã®ç¹æ§ãå£åã
ãŠããŸããšããæ¬ ç¹ã¯æ¹è¯ãããŠã¯ããªãã ãŸãææ©ææãææ©é¡æããã€ãªã¢çºçç©è³ªãš
ããŠçšããé»ååçæå äœãæ°å€ãææ¡ãããŠã
ããäŸãã°ããã¹ã¢ãŸååç©ãæå å±€äžã«å«æã
ãé»ååçæå äœãšããŠãç¹éæ54â22834å·å ¬
å ±ãç¹éæ55â73057å·å ¬å ±ãç¹éæ55â117151
å·å ¬å ±ãç¹éæ56â46237å·å ¬å ±çããã§ã«å ¬ç¥
ã§ãããããããããã®ãã¹ã¢ãŸååç©ã¯ãæ
床ãæ®çé»äœãããã¯ãç¹°ãè¿ã䜿çšæã®å®å®æ§
ã®ç¹æ§ã«ãããŠãå¿ ãããæºè¶³ãåŸããã®ã§ã¯ãª
ãããŸãããã€ãªã¢èŒžéç©è³ªã®éžæç¯å²ãéå®ã
ãããªã©ãé»ååçããã»ã¹ã®å¹ åºãèŠæ±ãåå
æºè¶³ããããã®ã§ã¯ãªãã ããã«è¿å¹Žæå äœã®å æºãšããŠArã¬ãŒã¶ãŒã
HeâNeã¬ãŒã¶ãŒçã®æ°äœã¬ãŒã¶ãŒãåå°äœã¬ãŒ
ã¶ãŒã䜿çšããå§ããŠããããããã®ã¬ãŒã¶ãŒã¯
ãã®ç¹åŸŽãšããŠæç³»åã§ONâOFFãå¯èœã§ã
ããã€ã³ããªãžãšã³ãè€åæ©ãã¯ãããšããç»å
åŠçæ©èœãæããè€åæ©ãã³ã³ããŠãŒã¿ãŒã®ã¢ãŠ
ããããçšã®ããªã³ã¿ãŒã®å æºãšããŠç¹ã«ææèŠ
ãããŠãããäžã§ãåå°äœã¬ãŒã¶ãŒã¯ãã®æ§è³ªäž
é³é¿å·¥åŠçŽ åçã®é»æ°ä¿¡å·ïŒå ä¿¡å·ã®å€æçŽ åã
äžèŠã§ããããšãå°åã»è»œéåãå¯èœã§ããããš
ãªã©ãã泚ç®ãéããŠãããããããã®åå°äœã¬
ãŒã¶ãŒã¯æ°äœã¬ãŒã¶ãŒã«æ¯èŒããŠäœåºåã§ããã
ãŸãçºæ¯æ³¢é·ãé·æ³¢é·ïŒçŽ780nm以äžïŒã§ããã
ãšããåŸæ¥ã®æå äœã§ã¯åå æ床ãçæ³¢é·åŽã«ã
ãéããŠããããã®ãŸãŸã§ã¯åå°äœã¬ãŒã¶ãŒãå
æºãšããæå äœãšããŠã®äœ¿çšã¯äžå¯èœã§ããã æ¬çºæã®ç®çã¯ãã€ãªã¢çºçèœã«åªããç¹å®ã®
ã¢ãŸååç©ãå«æããæå äœãæäŸããããšã«ã
ãã æ¬çºæã®ä»ã®ç®çã¯ãé«æ床ã«ããŠãã€æ®çé»
äœãå°ããããŸãç¹°ãè¿ã䜿çšããŠããããã®ç¹
æ§ãå€åããªãèä¹ æ§ã®åªããæå äœãæäŸãã
ããšã«ããã æ¬çºæã®æŽã«ä»ã®ç®çã¯ãåºç¯ãªãã€ãªã¢èŒžé
ç©è³ªãšã®çµã¿åããã«ãããŠããæå¹ã«ãã€ãªã¢
çºçç©è³ªãšããŠäœçšãåŸãã¢ãŸååç©ãå«æãã
æå äœãæäŸããããšã«ããã æ¬çºæã®æŽã«ä»ã®ç®çã¯ãåå°äœã¬ãŒã¶ãŒçã®
é·æ³¢é·å æºã«å¯ŸããŠãååã®å®çšæ床ãæããæ
å äœãæäŸããããšã«ããã æ¬çºæã®æŽã«ä»ã®ç®çã¯ãæ现æžäžã®èšèŒãã
ããããã«ãªãã§ãããã ãåé¡ç¹ã解決ããããã®æ段ã æ¬çºæè çã¯ã以äžã®ç®çãéæãã¹ãéæç
究ãéããçµæãäžèšäžè¬åŒããã§ç€ºãããã¢
ãŸååç©ãæå äœã®æå¹æåãšããŠåãåŸãããš
ãèŠåºããæ¬çºæãå®æãããã®ã§ããã äžè¬åŒãã åŒäžY1ïŒY2ã¯ããããæ°ŽçŽ ååãããã²ã³å
åãã¢ã«ãã«åºïŒå¥œãŸããã¯ççŽ ååæ°ïŒãïŒã®
ãã®ïŒã¢ã«ã³ãã·åºïŒå¥œãŸããã¯ççŽ ååæ°ïŒã
ïŒã®ãã®ïŒåã¯ããããã·åºãè¡šãã ã¯ã
åç©ãå«æããæå å±€ãæããæ°èŠãªæå äœã«é¢
ããã ïŒåŸæ¥ã®æè¡ïŒ åŸæ¥ãé»ååçæå äœãšããŠã¯ãã»ã¬ã³ãé žå
äºéãç¡«åã«ãããŠã ãã·ãªã³ã³çã®ç¡æ©å å°é»
æ§ååç©ãäž»æåãšããæå å±€ãæããç¡æ©æå
äœãåºãçšããããŠããããããããããã¯æ
床ãç±å®å®æ§ãè湿æ§ãèä¹ æ§çã«ãããŠå¿ ãã
ãæºè¶³ãåŸããã®ã§ã¯ãªããäŸãã°ãã»ã¬ã³ã¯çµ
æ¶åãããšæå äœãšããŠã®ç¹æ§ãå£åããŠããŸã
ããã補é äžãé£ããããŸãç±ãæçµçãåå ãš
ãªãçµæ¶åããæå äœãšããŠã®æ§èœãå£åããŠã
ãŸãããŸãç¡«åã«ãããŠã ã§ã¯è湿æ§ãèä¹ æ§ã
é žåäºéã§ãèä¹ æ§çã«åé¡ãããã ãããç¡æ©æå äœã®æã€æ¬ ç¹ãå æããç®çã§
æ§ã ãªææ©å å°é»æ§ååç©ãäž»æåãšããæå å±€
ãæããææ©æå äœã®éçºã»ç 究ãè¿å¹Žçãã«è¡
ãªãããŠãããäŸãã°ç¹å ¬æ50â10496å·å ¬å ±ã«
ã¯ããªââããã«ã«ã«ããŸãŒã«ãšïŒïŒïŒïŒïŒâ
ããªãããâïŒâãã«ãªã¬ãã³ãå«æããæå å±€
ãæããææ©æå äœã®èšèŒããããããããã®æ
å äœã¯ãæ床åã³èä¹ æ§ã«ãããŠå¿ ãããæºè¶³ã§
ãããã®ã§ã¯ãªãããã®ãããªæ¬ ç¹ãæ¹è¯ããã
ãã«ãã€ãªã¢çºçæ©èœãšãã€ãªã¢èŒžéæ©èœãšãç°
ãªãç©è³ªã«åæ ãããããé«æ§èœã®ææ©æå äœã
éçºããè©Šã¿ããªãããŠããããã®ãããªããã
ãæ©èœåé¢åã®æå äœã¯ãããããã®ææãåºã
ç¯å²ããéžæããããšãã§ããä»»æã®æ§èœãæã
ãæå äœãæ¯èŒç容æã«äœæãåŸãããšããå€ã
ã®ç 究ããªãããŠããã ãçºæã解決ããããšããåé¡ç¹ã äžèšã®ãããªæ©èœåé¢åã®æå äœã«ãããŠãã
ã®ãã€ãªã¢çºçç©è³ªãšããŠãæ°å€ãã®ååç©ãæ
æ¡ãããŠãããç¡æ©ååç©ããã€ãªã¢çºçç©è³ªãš
ããŠçšããäŸãšããŠã¯ãäŸãã°ãç¹å ¬æ43â
16198å·å ¬å ±ã«èšèŒãããç¡å®åœ¢ã»ã¬ã³ãããã
ããã¯ææ©å å°é»æ§ååç©ãšçµã¿åãããŠäœ¿çšã
ããããç¡å®åœ¢ã»ã¬ã³ãããªããã€ãªã¢çºçå±€ã¯
ç±ã«ããçµæ¶åããŠæå äœãšããŠã®ç¹æ§ãå£åã
ãŠããŸããšããæ¬ ç¹ã¯æ¹è¯ãããŠã¯ããªãã ãŸãææ©ææãææ©é¡æããã€ãªã¢çºçç©è³ªãš
ããŠçšããé»ååçæå äœãæ°å€ãææ¡ãããŠã
ããäŸãã°ããã¹ã¢ãŸååç©ãæå å±€äžã«å«æã
ãé»ååçæå äœãšããŠãç¹éæ54â22834å·å ¬
å ±ãç¹éæ55â73057å·å ¬å ±ãç¹éæ55â117151
å·å ¬å ±ãç¹éæ56â46237å·å ¬å ±çããã§ã«å ¬ç¥
ã§ãããããããããã®ãã¹ã¢ãŸååç©ã¯ãæ
床ãæ®çé»äœãããã¯ãç¹°ãè¿ã䜿çšæã®å®å®æ§
ã®ç¹æ§ã«ãããŠãå¿ ãããæºè¶³ãåŸããã®ã§ã¯ãª
ãããŸãããã€ãªã¢èŒžéç©è³ªã®éžæç¯å²ãéå®ã
ãããªã©ãé»ååçããã»ã¹ã®å¹ åºãèŠæ±ãåå
æºè¶³ããããã®ã§ã¯ãªãã ããã«è¿å¹Žæå äœã®å æºãšããŠArã¬ãŒã¶ãŒã
HeâNeã¬ãŒã¶ãŒçã®æ°äœã¬ãŒã¶ãŒãåå°äœã¬ãŒ
ã¶ãŒã䜿çšããå§ããŠããããããã®ã¬ãŒã¶ãŒã¯
ãã®ç¹åŸŽãšããŠæç³»åã§ONâOFFãå¯èœã§ã
ããã€ã³ããªãžãšã³ãè€åæ©ãã¯ãããšããç»å
åŠçæ©èœãæããè€åæ©ãã³ã³ããŠãŒã¿ãŒã®ã¢ãŠ
ããããçšã®ããªã³ã¿ãŒã®å æºãšããŠç¹ã«ææèŠ
ãããŠãããäžã§ãåå°äœã¬ãŒã¶ãŒã¯ãã®æ§è³ªäž
é³é¿å·¥åŠçŽ åçã®é»æ°ä¿¡å·ïŒå ä¿¡å·ã®å€æçŽ åã
äžèŠã§ããããšãå°åã»è»œéåãå¯èœã§ããããš
ãªã©ãã泚ç®ãéããŠãããããããã®åå°äœã¬
ãŒã¶ãŒã¯æ°äœã¬ãŒã¶ãŒã«æ¯èŒããŠäœåºåã§ããã
ãŸãçºæ¯æ³¢é·ãé·æ³¢é·ïŒçŽ780nm以äžïŒã§ããã
ãšããåŸæ¥ã®æå äœã§ã¯åå æ床ãçæ³¢é·åŽã«ã
ãéããŠããããã®ãŸãŸã§ã¯åå°äœã¬ãŒã¶ãŒãå
æºãšããæå äœãšããŠã®äœ¿çšã¯äžå¯èœã§ããã æ¬çºæã®ç®çã¯ãã€ãªã¢çºçèœã«åªããç¹å®ã®
ã¢ãŸååç©ãå«æããæå äœãæäŸããããšã«ã
ãã æ¬çºæã®ä»ã®ç®çã¯ãé«æ床ã«ããŠãã€æ®çé»
äœãå°ããããŸãç¹°ãè¿ã䜿çšããŠããããã®ç¹
æ§ãå€åããªãèä¹ æ§ã®åªããæå äœãæäŸãã
ããšã«ããã æ¬çºæã®æŽã«ä»ã®ç®çã¯ãåºç¯ãªãã€ãªã¢èŒžé
ç©è³ªãšã®çµã¿åããã«ãããŠããæå¹ã«ãã€ãªã¢
çºçç©è³ªãšããŠäœçšãåŸãã¢ãŸååç©ãå«æãã
æå äœãæäŸããããšã«ããã æ¬çºæã®æŽã«ä»ã®ç®çã¯ãåå°äœã¬ãŒã¶ãŒçã®
é·æ³¢é·å æºã«å¯ŸããŠãååã®å®çšæ床ãæããæ
å äœãæäŸããããšã«ããã æ¬çºæã®æŽã«ä»ã®ç®çã¯ãæ现æžäžã®èšèŒãã
ããããã«ãªãã§ãããã ãåé¡ç¹ã解決ããããã®æ段ã æ¬çºæè çã¯ã以äžã®ç®çãéæãã¹ãéæç
究ãéããçµæãäžèšäžè¬åŒããã§ç€ºãããã¢
ãŸååç©ãæå äœã®æå¹æåãšããŠåãåŸãããš
ãèŠåºããæ¬çºæãå®æãããã®ã§ããã äžè¬åŒãã åŒäžY1ïŒY2ã¯ããããæ°ŽçŽ ååãããã²ã³å
åãã¢ã«ãã«åºïŒå¥œãŸããã¯ççŽ ååæ°ïŒãïŒã®
ãã®ïŒã¢ã«ã³ãã·åºïŒå¥œãŸããã¯ççŽ ååæ°ïŒã
ïŒã®ãã®ïŒåã¯ããããã·åºãè¡šãã ã¯ã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
ãåŒãåã¯
ãåŒãã§ãã€ãŠãQ1ïŒQ2ïŒQ3ïŒ
Q4ïŒQ5åã³Q6ã¯ã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
R11ïŒR12ïŒR13ïŒR14ïŒR15ïŒR16ïŒR17ïŒR18å
ã³R19ã¯ãæ°ŽçŽ ååãã¢ã«ãã«åºïŒå¥œãŸããã¯ç
çŽ ååïŒãïŒïŒãã¢ã«ã³ãã·åºïŒå¥œãŸããã¯ççŽ
ååïŒãïŒïŒãããã²ã³ååãã·ã¢ãåºããšã¹ã
ã«åºïŒäŸãã°ã¢ã»ããã·åºãããããªãããã·åº
çïŒãã¢ã·ã«åºïŒäŸãã°ã¢ã»ãã«åºããã³ãŸã€ã«
åºçïŒããžã¢ã«ãã«ã¢ããåºããžã¢ã©ã«ãã«ã¢ã
ãåºããžã¢ãªãŒã«ã¢ããåºãåã¯ããããã·åºã
ãããåºãè¡šãããã ããn1ïŒn4åã³n7ã¯ãïŒã
ïŒã®æŽæ°ãè¡šããn1ïŒn4åã³n7ãïŒä»¥äžã®æã¯ã
R11ïŒR14åã³R17ã¯ãããããç°ãªã眮æåºã§ã
ããŸããªãããŸããn2ïŒn3ïŒn5ïŒn6ïŒn8åã³n9
ã¯ãïŒãïŒã®æŽæ°ãè¡šããn2ïŒn3ïŒn5ïŒn6ïŒn8å
ã³n9ãïŒä»¥äžã®æã¯ãR12ïŒR13ïŒR15ïŒR16ïŒR18
åã³R19ã¯ãããããç°ãªã眮æåºã§ãããŸããª
ãããŸããããããïŒã€ã®R11ïŒR12ïŒR13ïŒR14ïŒ
R15ïŒR16ïŒR17ïŒR18åã³R19ã§èèªæççŽ ç°å
ã¯ãèèªæè€çŽ ç°ã圢æããŠãããã R21ïŒR22åã³R23ã¯ãæ°ŽçŽ ååãã¢ã«ãã«åº
ïŒå¥œãŸããã¯ççŽ ååæ°ïŒãïŒïŒåã¯ã¢ãªãŒã«åº
ïŒäŸãã°ããšãã«åºïŒãè¡šãã Q7ã¯ã
ã³R19ã¯ãæ°ŽçŽ ååãã¢ã«ãã«åºïŒå¥œãŸããã¯ç
çŽ ååïŒãïŒïŒãã¢ã«ã³ãã·åºïŒå¥œãŸããã¯ççŽ
ååïŒãïŒïŒãããã²ã³ååãã·ã¢ãåºããšã¹ã
ã«åºïŒäŸãã°ã¢ã»ããã·åºãããããªãããã·åº
çïŒãã¢ã·ã«åºïŒäŸãã°ã¢ã»ãã«åºããã³ãŸã€ã«
åºçïŒããžã¢ã«ãã«ã¢ããåºããžã¢ã©ã«ãã«ã¢ã
ãåºããžã¢ãªãŒã«ã¢ããåºãåã¯ããããã·åºã
ãããåºãè¡šãããã ããn1ïŒn4åã³n7ã¯ãïŒã
ïŒã®æŽæ°ãè¡šããn1ïŒn4åã³n7ãïŒä»¥äžã®æã¯ã
R11ïŒR14åã³R17ã¯ãããããç°ãªã眮æåºã§ã
ããŸããªãããŸããn2ïŒn3ïŒn5ïŒn6ïŒn8åã³n9
ã¯ãïŒãïŒã®æŽæ°ãè¡šããn2ïŒn3ïŒn5ïŒn6ïŒn8å
ã³n9ãïŒä»¥äžã®æã¯ãR12ïŒR13ïŒR15ïŒR16ïŒR18
åã³R19ã¯ãããããç°ãªã眮æåºã§ãããŸããª
ãããŸããããããïŒã€ã®R11ïŒR12ïŒR13ïŒR14ïŒ
R15ïŒR16ïŒR17ïŒR18åã³R19ã§èèªæççŽ ç°å
ã¯ãèèªæè€çŽ ç°ã圢æããŠãããã R21ïŒR22åã³R23ã¯ãæ°ŽçŽ ååãã¢ã«ãã«åº
ïŒå¥œãŸããã¯ççŽ ååæ°ïŒãïŒïŒåã¯ã¢ãªãŒã«åº
ïŒäŸãã°ããšãã«åºïŒãè¡šãã Q7ã¯ã
ãåŒããè¡šããR31ã¯ã
æ°ŽçŽ ååãã¢ã«ãã«åºïŒå¥œãŸããã¯ççŽ ååæ°ïŒ
ãïŒïŒãã¢ã«ã³ãã·åºïŒå¥œãŸããã¯ççŽ ååæ°ïŒ
ãïŒïŒãããã²ã³ååãã·ã¢ãåºããšã¹ãã«åº
ïŒäŸãã°ã¢ã»ããã·åºãããããªãããã·åºçïŒã
ãžã¢ã«ãã«ã¢ããåºããžã¢ã©ã«ãã«ã¢ããåºããž
ã¢ãªãŒã«ã¢ããåºãåã¯ããããã·åºãè¡šããã
ã ããn11ã¯ïŒãïŒã®æŽæ°ãè¡šããn11ãïŒä»¥äžã®
æã¯ãR31ã¯ç°ãªã眮æåºã§ãããŸããªãã R1ã¯ãæ°ŽçŽ ååãã¢ã«ãã«åºãã¢ããåºããž
ã¢ã«ãã«ã¢ããåºããžã¢ãªãŒã«ã¢ããåºããžã¢ã©
ã«ãã«ã¢ããåºãã«ã«ãã¢ã€ã«åºãã«ã«ããã·ã«
åºåã³ãã®ãšã¹ãã«åºãŸãã¯ã·ã¢ãåºãè¡šãã R2åã³R3ã¯ãã¢ã«ãã«åºãã¢ã©ã«ãã«åºãå
ã¯
ãïŒïŒãã¢ã«ã³ãã·åºïŒå¥œãŸããã¯ççŽ ååæ°ïŒ
ãïŒïŒãããã²ã³ååãã·ã¢ãåºããšã¹ãã«åº
ïŒäŸãã°ã¢ã»ããã·åºãããããªãããã·åºçïŒã
ãžã¢ã«ãã«ã¢ããåºããžã¢ã©ã«ãã«ã¢ããåºããž
ã¢ãªãŒã«ã¢ããåºãåã¯ããããã·åºãè¡šããã
ã ããn11ã¯ïŒãïŒã®æŽæ°ãè¡šããn11ãïŒä»¥äžã®
æã¯ãR31ã¯ç°ãªã眮æåºã§ãããŸããªãã R1ã¯ãæ°ŽçŽ ååãã¢ã«ãã«åºãã¢ããåºããž
ã¢ã«ãã«ã¢ããåºããžã¢ãªãŒã«ã¢ããåºããžã¢ã©
ã«ãã«ã¢ããåºãã«ã«ãã¢ã€ã«åºãã«ã«ããã·ã«
åºåã³ãã®ãšã¹ãã«åºãŸãã¯ã·ã¢ãåºãè¡šãã R2åã³R3ã¯ãã¢ã«ãã«åºãã¢ã©ã«ãã«åºãå
ã¯
ãåŒããè¡šããR41ã¯ãæ°ŽçŽ å
åãã¢ã«ãã«åºãã¢ã«ã³ãã·åºãããã²ã³ååã
ã·ã¢ãåºããšã¹ãã«åºãã¢ã·ã«åºããžã¢ã«ãã«ã¢
ããåºããžã¢ã©ã«ãã«ã¢ããåºããžã¢ãªãŒã«ã¢ã
ãåºãåã¯ãã€ãããã·åºãè¡šãããã ããn21
ã¯ãïŒãïŒã®æŽæ°ãè¡šããn21ãïŒä»¥äžã®æã¯ã
R41ã¯ç°ãªã眮æåºã§ãããŸããªãã æ¬çºæã®æå äœã«ãããŠã¯åèšäžè¬åŒããã§
è¡šãããäžèšã®ããšãååç©ã®ãã¥ãããçšãã
ããšãã§ããããç¹ã«å¥œãŸãããã®ãšããŠã¯äžèš
äžè¬åŒãïœããæãããã®ãæããããã äžè¬åŒãïœã ãŸãY1ïŒY2ãšããŠæ°ŽçŽ ååãã¡ãã«åºãåã³
ã¡ããã·åºãæãããã®ãç¹ã«å¥œãŸããçšããã
ãã åèšäžè¬åŒããã§ç€ºãããæ¬çºæã«æçšãªå
åç©ã®å ·äœäŸãäžèšã«ç€ºãããããã«ãã€ãŠæ¬çº
æã®ã¢ãŸååç©ãéå®ããããã®ã§ã¯ãªãã ïŒäŸç€ºååç©ïŒ (1) äžè¬åŒããã§è¡šããããã®äžäžè¬åŒãã
ã®æ§é ãæãããã® äžè¬åŒãã X1ã¯
ã·ã¢ãåºããšã¹ãã«åºãã¢ã·ã«åºããžã¢ã«ãã«ã¢
ããåºããžã¢ã©ã«ãã«ã¢ããåºããžã¢ãªãŒã«ã¢ã
ãåºãåã¯ãã€ãããã·åºãè¡šãããã ããn21
ã¯ãïŒãïŒã®æŽæ°ãè¡šããn21ãïŒä»¥äžã®æã¯ã
R41ã¯ç°ãªã眮æåºã§ãããŸããªãã æ¬çºæã®æå äœã«ãããŠã¯åèšäžè¬åŒããã§
è¡šãããäžèšã®ããšãååç©ã®ãã¥ãããçšãã
ããšãã§ããããç¹ã«å¥œãŸãããã®ãšããŠã¯äžèš
äžè¬åŒãïœããæãããã®ãæããããã äžè¬åŒãïœã ãŸãY1ïŒY2ãšããŠæ°ŽçŽ ååãã¡ãã«åºãåã³
ã¡ããã·åºãæãããã®ãç¹ã«å¥œãŸããçšããã
ãã åèšäžè¬åŒããã§ç€ºãããæ¬çºæã«æçšãªå
åç©ã®å ·äœäŸãäžèšã«ç€ºãããããã«ãã€ãŠæ¬çº
æã®ã¢ãŸååç©ãéå®ããããã®ã§ã¯ãªãã ïŒäŸç€ºååç©ïŒ (1) äžè¬åŒããã§è¡šããããã®äžäžè¬åŒãã
ã®æ§é ãæãããã® äžè¬åŒãã X1ã¯
ãåŒã
åã¯
ãåŒããè¡šãã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
(2) äžè¬åŒããã®æ§é ãæãããã®
äžè¬åŒãã
X1ã¯äžè¬åŒããã«åã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
(3) äžè¬åŒããã®æ§é ãæãããã®
äžè¬åŒãã
X2ã¯
ãåŒã
ãåŒãåã¯
ãåŒããè¡šãã
ãè¡šã
ãè¡šã
ãè¡šã
(4) äžè¬åŒããã®æ§é ãæãããã®ã
äžè¬åŒãã
X2ã¯äžè¬åŒããã«åã
ãè¡šã
ãè¡šã
ãè¡šã
(5) äžè¬åŒããã®æ§é ãæãããã®
äžè¬åŒãã
X1ã¯äžè¬åŒããã«åã
ãè¡šã
ãè¡šã
(6) äžè¬åŒããã®æ§é ãæãããã®
äžè¬åŒãã
X1ã¯äžè¬åŒããã«åã
ãè¡šã
ãè¡šã
ãè¡šã
(7) äžè¬åŒããã®æ§é ãæãããã®
äžè¬åŒãã
X1ã¯äžè¬åŒããã«åã
ãè¡šã
ãè¡šã
(8) äžè¬åŒããã®æ§é ãæãããã®
äžè¬åŒãã
X1ã¯äžè¬åŒããã«åã
ãè¡šã
ãè¡šã
(9) ãã®ä»ã®æ§é ã®ãã®
äžè¬åŒããã§è¡šããããæ¬çºæã®ã¢ãŸååç©
ã¯ä»¥äžã«è¿°ã¹ããããªåææ³ã«ãã€ãŠå®¹æã«åæ
ããããšãã§ããã ãŸããäžèšäžè¬åŒïŒ»ïŒ³âïŒïŒœã§è¡šãããããžã
ããååç©ããå¡©é žäžã§å¡©å第äžã¹ãºïŒäžæ°Žå
ç©ïŒãçšããŠéå ããŠãäžèšäžè¬åŒïŒ»ïŒ³âïŒïŒœã§
è¡šãããããžã¢ããååç©ãšããã 次ã«ããžã¢ããååç©ïŒ»ïŒ³âïŒïŒœ2.3ïœïŒ0.01
ã¢ã«ïŒãæ¿å¡©é ž18mlãæ°Ž12mlãæ··åããæªæãã€
ã€ãïŒâ以äžã«ä¿ã¡ãªããäºç¡é žãœãŒã1.5ïœ
ïŒ0.022ã¢ã«ïŒã®æ°ŽïŒml溶液ã滎äžããŠã15åéæª
æããåžåŒããããŠäžæº¶ç©ãé€å»ãããæ¯æ¶²ã«
HBF4ãå ããæåºç©ããåããHBF4æŽæµããŠã
ããã©ãŸããŠã å¡©ãåŸããåŸãããããã©ãŸããŠ
ã å¡©ã¯ã100mlã®å·DMFã«æº¶è§£ããïŒâ以äžã«ä¿
ã¡ã€ã€ãïŒâããããã·âïŒâïŒïŒâã¡ãã«âïŒ
âã¡ããã·ããšãã«ã«ã«ãã¢ã€ã«ïŒâ11Hâãã³
ãŸïŒ»ïœïŒœã«ã«ããŸãŒã«9.5ïœïŒ0.024ã¢ã«ïŒã®å·
DMF200ml溶液ãå ãããç¶ããŠãé ¢é žãœãŒãïŒ
æ°Žåç©5.4ïœïŒ0.04ã¢ã«ïŒã®æ°Ž20ml溶液ã滎äžãã
ïŒâ以äžã§ïŒæéæªæããåŸã宀枩ã§ïŒæéæªæ
ããã çµæ¶ããåããDMF300mlã§ïŒåæŽæµãæ°Ž300
mlã§ïŒåæŽæµã次ãã§ã¡ã¿ããŒã«300mlã§æŽæµã
ãåŸã也ç¥ããŠãäŸç€ºååç©ïŒ¢â26ã®6.5ïœïŒ63
ïŒ ïŒãåŸãã â26ã®æ§é ã¯ãIRã¹ãã¯ãã«ïŒKBrïŒã§ã
1710cm-1ã«ã©ã¯ãã³ã®åžåã瀺ãããšãFDâMS
ã¹ãã¯ãã«ã§ãïœïŒïœïŒ1040ã«M+ã®ããŒã¯ã瀺
ãããšãåã³ãå çŽ åæå€ããèšç®å€ãšããäžèŽ
ããããšïŒäžèšïŒãã確èªãããïŒæž¬å®å€ïŒïŒ£ïŒ
72.54ãïŒ4.32ãïŒ10.70ãèšç®å€ïŒïŒ£ïŒ
72.68ãïŒ4.26ãïŒ10.77ïŒãªãèç¹ã¯300â以
äžã§ãã€ãã æ¬çºæã®åèšã¢ãŸååç©ã¯åªããå å°é»æ§ãæ
ãããããçšããŠæå äœã補é ããå Žåãå°é»æ§
æ¯æäœäžã«æ¬çºæã®ã¢ãŸååç©ãçµçå€äžã«åæ£
ããæå å±€ãèšããããšã«ãã補é ãããšãã§ã
ãããæ¬çºæã®ã¢ãŸååç©ã®æã€å å°é»æ§ã®ã
ã¡ãç¹ã«åªãããã€ãªã¢çºçèœãå©çšããŠãã€ãª
ã¢çºçç©è³ªãšããŠçšãããããšçµã¿åãããŠæå¹
ã«äœçšãåŸããã€ãªã¢èŒžéç©è³ªãšå ±ã«çšããããš
ã«ãããããããæ©èœåé¢åã®æå äœãæ§æãã
å Žåç¹ã«åªããçµæãåŸããããåèšæ©èœåé¢å
æå äœã¯åæ£åã®ãã®ã§ãã€ãŠããããããã€ãª
ã¢çºçç©è³ªãå«ããã€ãªã¢çºçå±€ãšãã€ãªã¢èŒžé
ç©è³ªãå«ããã€ãªã¢èŒžéå±€ãç©å±€ããç©å±€åæå
äœãšããããšããã奜ãŸããã æ¬çºæã®ã¢ãŸååç©ããã€ãªã¢çºçç©è³ªãšããŠ
çšããå Žåããããšçµã¿åãããŠçšãããããã€
ãªã¢èŒžéç©è³ªãšããŠã¯ãããªããããã«ãªã¬ãã³
ãããã¯ããã©ããããã«ãªã¬ãã³ãªã©ã®é»åã
茞éããããé»åå容æ§ç©è³ªã®ã»ããããªââ
ããã«ã«ã«ããŸãŒã«ã«ä»£è¡šããããããªè€çŽ ç°å
åç©ãåŽéã«æããéåäœãããªã¢ãŸãŒã«èªå°
äœããªããµãžã¢ãŸãŒã«èªå°äœãã€ãããŸãŒã«èªå°
äœããã©ãŸãªã³èªå°äœãããªã¢ãªãŒã«ã¢ã«ã«ã³èª
å°äœãããšãã¬ã³ãžã¢ãã³èªå°äœãããã©ãŸã³èª
å°äœãã¢ãã眮æã«ã«ã³ã³èªå°äœãããªã¢ãªãŒã«
ã¢ãã³èªå°äœãã«ã«ããŸãŒã«èªå°äœãã¹ãã«ãã³
èªå°äœãããšããã¢ãžã³èªå°äœçã®æ£åã茞éã
ãããé»åäŸäžæ§ç©è³ªãæããããããæ¬çºæã«
çšãããããã€ãªã¢èŒžéç©è³ªã¯ãããã«éå®ãã
ããã®ã§ã¯ãªãã æå äœã®æ©æ¢°çæ§æã¯çš®ã ã®åœ¢æ ãç¥ãããŠã
ãããæ¬çºæã®æå äœã¯ãããã®ãããã®åœ¢æ ã
ããšãåŸãã éåžžã¯ã第ïŒå³ã第ïŒå³ã®åœ¢æ ã§ããã第ïŒå³
åã³ç¬¬ïŒå³ã§ã¯ãå°é»æ§æ¯æäœïŒäžã«åè¿°ã®ã¢ãŸ
ååç©ãäž»æåãšãããã€ãªã¢çºçå±€ïŒãšããã€
ãªã¢èŒžéç©è³ªãäž»æåãšããŠå«æãããã€ãªã¢èŒž
éå±€ïŒãšã®ç©å±€äœããæãæå å±€ïŒãèšããã第
ïŒå³åã³ç¬¬ïŒå³ã«ç€ºãããã«ãã®æå å±€ïŒã¯ãå°
é»æ§æ¯æäœäžã«èšããäžéå±€ïŒãä»ããŠèšããŠã
ããããã®ããã«æå å±€ïŒãäºå±€æ§æãšãããšã
ã«æãåªããé»ååçç¹æ§ãæããæå äœãåŸã
ããããŸãæ¬çºæã«ãããŠã¯ã第ïŒå³ããã³ç¬¬ïŒ
å³ã«ç€ºãããã«åèšãã€ãªã¢çºçç©è³ªïŒããã€ãª
ã¢èŒžéç©è³ªãäž»æåãšããå±€ïŒäžã«åæ£ããããŠ
æãæå å±€ïŒãå°é»æ§æ¯æäœïŒäžã«çŽæ¥ãããã
ã¯äžéå±€ïŒãä»ããŠèšããŠãããã äºå±€æ§æã®æå å±€ïŒãæ§æãããã€ãªã¢çºçå±€
ïŒã¯å°é»æ§æ¯æäœïŒããããã¯ãã€ãªã¢èŒžéå±€ïŒ
äžã«çŽæ¥ããããã¯å¿ èŠã«å¿ããŠæ¥çå±€ãããã¯
ããªã€ãŒå±€ãªã©ã®äžéå±€ãèšããäžã«äŸãã°æ¬¡ã®
æ¹æ³ã«ãã€ãŠåœ¢æããããšãã§ããã ïŒâïŒ ã¢ãŸååç©ãé©åœãªæº¶åªã«æº¶è§£ãã溶液
ãããããã¯å¿ èŠã«å¿ããŠçµçå€ãå ãæ··å溶
解ãã溶液ãå¡åžããæ¹æ³ã ïŒâïŒ ã¢ãŸååç©ãããŒã«ãã«ããã¢ãããµãŒ
çã«ãã€ãŠåæ£åªäžã§åŸ®çŽ°ç²åãšããå¿ èŠã«å¿
ããŠçµçå€ããããæ··ååæ£ããåæ£æ¶²ãå¡åž
ããæ¹æ³ã ãã€ãªã¢çºçå±€ã®åœ¢æã«äœ¿çšããã溶åªããã
ã¯åæ£åªãšããŠã¯ãïœâããã«ã¢ãã³ããžãšãã«
ã¢ãã³ããšãã¬ã³ãžã¢ãã³ãã€ãœãããããŒã«ã¢
ãã³ãããªãšã¿ããŒã«ã¢ãã³ãããªãšãã¬ã³ãžã¢
ãã³ãïŒïŒ®âãžã¡ãã«ãã«ã ã¢ãããã¢ã»ã
ã³ãã¡ãã«ãšãã«ã±ãã³ãã·ã¯ããããµãã³ãã
ã³ãŒã³ããã«ãšã³ããã·ã¬ã³ãã¯ãããã«ã ã
ïŒïŒïŒâãžã¯ãããšã¿ã³ãïŒïŒïŒïŒïŒâããªã¯ã
ããšã¿ã³ãïŒïŒïŒïŒïŒïŒâããªã¯ãããšã¿ã³ãã
ãªã¯ãããšã¿ã³ããšãã©ã¯ãããšã¿ã³ããžã¯ãã
ã¡ã¿ã³ãããã©ããããã©ã³ããžãªããµã³ãã¡ã¿
ããŒã«ããšã¿ããŒã«ãã€ãœãããããŒã«ãé ¢é žãš
ãã«ãé ¢é žããã«ããžã¡ãã«ã¹ã«ããã·ãçãæ
ããããã ãã€ãªã¢çºçå±€ãããã¯ãã€ãªã¢èŒžéå±€ã«çµç
å€ãçšããå Žåã¯ä»»æã®ãã®ãçšããããšãã§ã
ãããçæ°Žæ§ã§ããã€èªé»çãé«ããé»æ°çµ¶çžæ§
ã®ãã€ã«ã 圢ææ§é«ååéåäœãçšããã®ã奜ãŸ
ããããã®ãããªé«ååéåäœãšããŠã¯ãäŸãã°
次ã®ãã®ãæããããšãã§ãããããããã«éå®
ããããã®ã§ã¯ãªãã âïŒ ããªã«ãŒãããŒã âïŒ ããªãšã¹ã㫠âïŒ ã¡ã¿ã¯ãªã«æš¹è âïŒ ã¢ã¯ãªã«æš¹è âïŒ ããªå¡©åãã㫠âïŒ ããªå¡©åãããªã㳠âïŒ ããªã¹ãã¬ã³ âïŒ ããªããã«ã¢ã»ããŒã âïŒ ã¹ãã¬ã³âãã¿ãžãšã³å ±éåäœ ïŒ°â10 å¡©åãããªãã³âã¢ã¯ãªããããªã«å ±é
åäœ ïŒ°â11 å¡©åããã«âé ¢é žããã«å ±éåäœ ïŒ°â12 å¡©åããã«âé ¢é žããã«âç¡æ°Žãã¬ã€ã³
é žå ±éåäœ ïŒ°â13 ã·ãªã³ã³æš¹è â14 ã·ãªã³ã³âã¢ã«ãããæš¹è â15 ããšããŒã«ãã«ã ã¢ã«ãããæš¹è â16 ã¹ãã¬ã³âã¢ã«ãããæš¹è â17 ããªââããã«ã«ã«ããŸãŒã« â18 ããªããã«ããã©ãŒã« â19 ããªããã«ããªã«ããŒã« ãããã®çµçå€ã¯ãåç¬ã§ãããã¯ïŒçš®ä»¥äžã®
æ··åç©ãšããŠçšããããšãã§ããã ãã®ããã«ããŠåœ¢æããããã€ãªã¢çºçå±€ïŒã®
åãã¯ã0.01ÎŒïœã20ÎŒïœã§ããããšã奜ãŸãã
ããæŽã«å¥œãŸããã¯0.05ÎŒïœã5ÎŒïœã§ããããŸã
ãã€ãªã¢çºçå±€ãããã¯æå å±€ãåæ£ç³»ã®å Žåã¢
ãŸååç©ã®ç²äœã¯5ÎŒïœä»¥äžã§ããããšã奜ãŸã
ããæŽã«å¥œãŸããã¯1ÎŒïœä»¥äžã§ããã æ¬çºæã®æå äœã«çšããããå°é»æ§æ¯æäœãšã
ãŠã¯ãåéãå«ããéå±æ¿ãéå±ãã©ã ãŸãã¯å°
é»æ§ããªããŒãé žåã€ã³ãžãŠã çã®å°é»æ§ååç©
ãåéãå«ããã¢ã«ãããŠã ããã©ãžãŠã ãéç
ã®éå±èå±€ãå¡åžãèžçãããã¯ã©ãããŒãã
ãŠãå°é»æ§åãéæããçŽããã©ã¹ããã¯ãã€ã«
ã çãæãããããæ¥çå±€ãããã¯ããªã€ãŒå±€ãª
ã©ã®äžéå±€ãšããŠã¯ãåèšçµçå€ãšããŠçšããã
ãé«ååéåäœã®ã»ããããªããã«ã¢ã«ã³ãŒã«ã
ãšãã«ã»ã«ããŒã¹ãã«ã«ããã·ã¡ãã«ã»ã«ããŒã¹
ãªã©ã®ææ©é«ååç©è³ªãŸãã¯é žåã¢ã«ãããŠã ãª
ã©ãçšããããã æ¬çºæã®æå äœã¯ä»¥äžã®ãããªæ§æã§ãã€ãŠã
åŸè¿°ãããããªå®æœäŸãããæãããªããã«ã垯
é»ç¹æ§ãæ床ç¹æ§ç»å圢æç¹æ§ã«åªããŠãããç¹
ã«ç¹°ãè¿ã䜿çšãããšãã«ãç²åŽå£åãå°ãªãã
èä¹ æ§ãåªãããã®ã§ããã 以äžãæ¬çºæã®å®æœäŸã§å ·äœçã«èª¬æãããã
ããã«ããæ¬çºæã®å®æœæ æ§ãéå®ããããã®ã§
ã¯ãªãã ãå®æœäŸã å®æœäŸ ïŒ äŸç€ºååç©ïŒ¢â90.2ïœãšããªã«ãŒãããŒãæš¹è
ããã³ã©ã€ãâ1250ãïŒåžäººåæ瀟補ïŒïŒïœãšã
1.ããªãªãïŒâãžã¯ãããšã¿ã³110mlã«å ããã
ãŒã«ãã«ã§12æéåæ£ããããã®åæ£æ¶²ãã¢ã«ã
ããŠã ãèžçããããªãšã¹ãã«ãã€ã«ã äžã«ã也
ç¥æã®èåã1ÎŒïœã«ãªãããã«å¡åžãããã€ãª
ã¢çºçå±€ãšããæŽã«ãã®äžã«ããã€ãªã¢èŒžéå±€ãš
ããŠãïŒâããšãã«âïŒïœâã¡ãã«ã¹ããªã«ïŒâïŒ
âïŒïœâã¡ããã·ããšãã«ïŒãã©ãŸãªã³ïŒäžèšæ§
é åŒïŒ«â(1)ïŒïŒïœãããªã«ãŒãããŒãæš¹èããã³
ã©ã€ãâ1250ã10ïœãšãïŒïŒïŒâãžã¯ãããšã¿
ã³110mlã«æº¶è§£ãã液ã也ç¥åŸã®èåã15ÎŒïœã«
ãªãããã«å¡åžããŠããã€ãªã¢èŒžéå±€ã圢æãã
æ¬çºæã®æå äœãäœæããã 以äžã®ããã«ããŠåŸãããæå äœã(æ ª)å·å£é»æ©
補äœæ補SPâ428åéé»çŽè©Šéšæ©ãçšããŠã以äž
ã®ç¹æ§è©äŸ¡ãè¡ã€ãã垯é»å§â6KVã§ïŒç§é垯
é»ããåŸãïŒç§éææŸçœ®ãã次ãã§æå äœè¡šé¢ã§
ã®ç §åºŠã35luxã«ãªãããã«ããã²ã³ã©ã³ãå ã
ç §å°ããŠãè¡šé¢é»äœãååã«æžè¡°ãããã®ã«èŠã
ãé²å éïŒåæžé²å éïŒïŒ¥1/2ãæ±ããããŸã
30luxã»secã®é²å éã§é²å ããåŸã®è¡šé¢é»äœïŒæ®
çé»äœïŒVRãæ±ãããæŽã«åæ§ã®æž¬å®ã100åç¹°
ãè¿ããŠè¡ã€ããçµæã¯ç¬¬ïŒè¡šã«ç€ºãéãã§ã
ãã
ã¯ä»¥äžã«è¿°ã¹ããããªåææ³ã«ãã€ãŠå®¹æã«åæ
ããããšãã§ããã ãŸããäžèšäžè¬åŒïŒ»ïŒ³âïŒïŒœã§è¡šãããããžã
ããååç©ããå¡©é žäžã§å¡©å第äžã¹ãºïŒäžæ°Žå
ç©ïŒãçšããŠéå ããŠãäžèšäžè¬åŒïŒ»ïŒ³âïŒïŒœã§
è¡šãããããžã¢ããååç©ãšããã 次ã«ããžã¢ããååç©ïŒ»ïŒ³âïŒïŒœ2.3ïœïŒ0.01
ã¢ã«ïŒãæ¿å¡©é ž18mlãæ°Ž12mlãæ··åããæªæãã€
ã€ãïŒâ以äžã«ä¿ã¡ãªããäºç¡é žãœãŒã1.5ïœ
ïŒ0.022ã¢ã«ïŒã®æ°ŽïŒml溶液ã滎äžããŠã15åéæª
æããåžåŒããããŠäžæº¶ç©ãé€å»ãããæ¯æ¶²ã«
HBF4ãå ããæåºç©ããåããHBF4æŽæµããŠã
ããã©ãŸããŠã å¡©ãåŸããåŸãããããã©ãŸããŠ
ã å¡©ã¯ã100mlã®å·DMFã«æº¶è§£ããïŒâ以äžã«ä¿
ã¡ã€ã€ãïŒâããããã·âïŒâïŒïŒâã¡ãã«âïŒ
âã¡ããã·ããšãã«ã«ã«ãã¢ã€ã«ïŒâ11Hâãã³
ãŸïŒ»ïœïŒœã«ã«ããŸãŒã«9.5ïœïŒ0.024ã¢ã«ïŒã®å·
DMF200ml溶液ãå ãããç¶ããŠãé ¢é žãœãŒãïŒ
æ°Žåç©5.4ïœïŒ0.04ã¢ã«ïŒã®æ°Ž20ml溶液ã滎äžãã
ïŒâ以äžã§ïŒæéæªæããåŸã宀枩ã§ïŒæéæªæ
ããã çµæ¶ããåããDMF300mlã§ïŒåæŽæµãæ°Ž300
mlã§ïŒåæŽæµã次ãã§ã¡ã¿ããŒã«300mlã§æŽæµã
ãåŸã也ç¥ããŠãäŸç€ºååç©ïŒ¢â26ã®6.5ïœïŒ63
ïŒ ïŒãåŸãã â26ã®æ§é ã¯ãIRã¹ãã¯ãã«ïŒKBrïŒã§ã
1710cm-1ã«ã©ã¯ãã³ã®åžåã瀺ãããšãFDâMS
ã¹ãã¯ãã«ã§ãïœïŒïœïŒ1040ã«M+ã®ããŒã¯ã瀺
ãããšãåã³ãå çŽ åæå€ããèšç®å€ãšããäžèŽ
ããããšïŒäžèšïŒãã確èªãããïŒæž¬å®å€ïŒïŒ£ïŒ
72.54ãïŒ4.32ãïŒ10.70ãèšç®å€ïŒïŒ£ïŒ
72.68ãïŒ4.26ãïŒ10.77ïŒãªãèç¹ã¯300â以
äžã§ãã€ãã æ¬çºæã®åèšã¢ãŸååç©ã¯åªããå å°é»æ§ãæ
ãããããçšããŠæå äœã補é ããå Žåãå°é»æ§
æ¯æäœäžã«æ¬çºæã®ã¢ãŸååç©ãçµçå€äžã«åæ£
ããæå å±€ãèšããããšã«ãã補é ãããšãã§ã
ãããæ¬çºæã®ã¢ãŸååç©ã®æã€å å°é»æ§ã®ã
ã¡ãç¹ã«åªãããã€ãªã¢çºçèœãå©çšããŠãã€ãª
ã¢çºçç©è³ªãšããŠçšãããããšçµã¿åãããŠæå¹
ã«äœçšãåŸããã€ãªã¢èŒžéç©è³ªãšå ±ã«çšããããš
ã«ãããããããæ©èœåé¢åã®æå äœãæ§æãã
å Žåç¹ã«åªããçµæãåŸããããåèšæ©èœåé¢å
æå äœã¯åæ£åã®ãã®ã§ãã€ãŠããããããã€ãª
ã¢çºçç©è³ªãå«ããã€ãªã¢çºçå±€ãšãã€ãªã¢èŒžé
ç©è³ªãå«ããã€ãªã¢èŒžéå±€ãç©å±€ããç©å±€åæå
äœãšããããšããã奜ãŸããã æ¬çºæã®ã¢ãŸååç©ããã€ãªã¢çºçç©è³ªãšããŠ
çšããå Žåããããšçµã¿åãããŠçšãããããã€
ãªã¢èŒžéç©è³ªãšããŠã¯ãããªããããã«ãªã¬ãã³
ãããã¯ããã©ããããã«ãªã¬ãã³ãªã©ã®é»åã
茞éããããé»åå容æ§ç©è³ªã®ã»ããããªââ
ããã«ã«ã«ããŸãŒã«ã«ä»£è¡šããããããªè€çŽ ç°å
åç©ãåŽéã«æããéåäœãããªã¢ãŸãŒã«èªå°
äœããªããµãžã¢ãŸãŒã«èªå°äœãã€ãããŸãŒã«èªå°
äœããã©ãŸãªã³èªå°äœãããªã¢ãªãŒã«ã¢ã«ã«ã³èª
å°äœãããšãã¬ã³ãžã¢ãã³èªå°äœãããã©ãŸã³èª
å°äœãã¢ãã眮æã«ã«ã³ã³èªå°äœãããªã¢ãªãŒã«
ã¢ãã³èªå°äœãã«ã«ããŸãŒã«èªå°äœãã¹ãã«ãã³
èªå°äœãããšããã¢ãžã³èªå°äœçã®æ£åã茞éã
ãããé»åäŸäžæ§ç©è³ªãæããããããæ¬çºæã«
çšãããããã€ãªã¢èŒžéç©è³ªã¯ãããã«éå®ãã
ããã®ã§ã¯ãªãã æå äœã®æ©æ¢°çæ§æã¯çš®ã ã®åœ¢æ ãç¥ãããŠã
ãããæ¬çºæã®æå äœã¯ãããã®ãããã®åœ¢æ ã
ããšãåŸãã éåžžã¯ã第ïŒå³ã第ïŒå³ã®åœ¢æ ã§ããã第ïŒå³
åã³ç¬¬ïŒå³ã§ã¯ãå°é»æ§æ¯æäœïŒäžã«åè¿°ã®ã¢ãŸ
ååç©ãäž»æåãšãããã€ãªã¢çºçå±€ïŒãšããã€
ãªã¢èŒžéç©è³ªãäž»æåãšããŠå«æãããã€ãªã¢èŒž
éå±€ïŒãšã®ç©å±€äœããæãæå å±€ïŒãèšããã第
ïŒå³åã³ç¬¬ïŒå³ã«ç€ºãããã«ãã®æå å±€ïŒã¯ãå°
é»æ§æ¯æäœäžã«èšããäžéå±€ïŒãä»ããŠèšããŠã
ããããã®ããã«æå å±€ïŒãäºå±€æ§æãšãããšã
ã«æãåªããé»ååçç¹æ§ãæããæå äœãåŸã
ããããŸãæ¬çºæã«ãããŠã¯ã第ïŒå³ããã³ç¬¬ïŒ
å³ã«ç€ºãããã«åèšãã€ãªã¢çºçç©è³ªïŒããã€ãª
ã¢èŒžéç©è³ªãäž»æåãšããå±€ïŒäžã«åæ£ããããŠ
æãæå å±€ïŒãå°é»æ§æ¯æäœïŒäžã«çŽæ¥ãããã
ã¯äžéå±€ïŒãä»ããŠèšããŠãããã äºå±€æ§æã®æå å±€ïŒãæ§æãããã€ãªã¢çºçå±€
ïŒã¯å°é»æ§æ¯æäœïŒããããã¯ãã€ãªã¢èŒžéå±€ïŒ
äžã«çŽæ¥ããããã¯å¿ èŠã«å¿ããŠæ¥çå±€ãããã¯
ããªã€ãŒå±€ãªã©ã®äžéå±€ãèšããäžã«äŸãã°æ¬¡ã®
æ¹æ³ã«ãã€ãŠåœ¢æããããšãã§ããã ïŒâïŒ ã¢ãŸååç©ãé©åœãªæº¶åªã«æº¶è§£ãã溶液
ãããããã¯å¿ èŠã«å¿ããŠçµçå€ãå ãæ··å溶
解ãã溶液ãå¡åžããæ¹æ³ã ïŒâïŒ ã¢ãŸååç©ãããŒã«ãã«ããã¢ãããµãŒ
çã«ãã€ãŠåæ£åªäžã§åŸ®çŽ°ç²åãšããå¿ èŠã«å¿
ããŠçµçå€ããããæ··ååæ£ããåæ£æ¶²ãå¡åž
ããæ¹æ³ã ãã€ãªã¢çºçå±€ã®åœ¢æã«äœ¿çšããã溶åªããã
ã¯åæ£åªãšããŠã¯ãïœâããã«ã¢ãã³ããžãšãã«
ã¢ãã³ããšãã¬ã³ãžã¢ãã³ãã€ãœãããããŒã«ã¢
ãã³ãããªãšã¿ããŒã«ã¢ãã³ãããªãšãã¬ã³ãžã¢
ãã³ãïŒïŒ®âãžã¡ãã«ãã«ã ã¢ãããã¢ã»ã
ã³ãã¡ãã«ãšãã«ã±ãã³ãã·ã¯ããããµãã³ãã
ã³ãŒã³ããã«ãšã³ããã·ã¬ã³ãã¯ãããã«ã ã
ïŒïŒïŒâãžã¯ãããšã¿ã³ãïŒïŒïŒïŒïŒâããªã¯ã
ããšã¿ã³ãïŒïŒïŒïŒïŒïŒâããªã¯ãããšã¿ã³ãã
ãªã¯ãããšã¿ã³ããšãã©ã¯ãããšã¿ã³ããžã¯ãã
ã¡ã¿ã³ãããã©ããããã©ã³ããžãªããµã³ãã¡ã¿
ããŒã«ããšã¿ããŒã«ãã€ãœãããããŒã«ãé ¢é žãš
ãã«ãé ¢é žããã«ããžã¡ãã«ã¹ã«ããã·ãçãæ
ããããã ãã€ãªã¢çºçå±€ãããã¯ãã€ãªã¢èŒžéå±€ã«çµç
å€ãçšããå Žåã¯ä»»æã®ãã®ãçšããããšãã§ã
ãããçæ°Žæ§ã§ããã€èªé»çãé«ããé»æ°çµ¶çžæ§
ã®ãã€ã«ã 圢ææ§é«ååéåäœãçšããã®ã奜ãŸ
ããããã®ãããªé«ååéåäœãšããŠã¯ãäŸãã°
次ã®ãã®ãæããããšãã§ãããããããã«éå®
ããããã®ã§ã¯ãªãã âïŒ ããªã«ãŒãããŒã âïŒ ããªãšã¹ã㫠âïŒ ã¡ã¿ã¯ãªã«æš¹è âïŒ ã¢ã¯ãªã«æš¹è âïŒ ããªå¡©åãã㫠âïŒ ããªå¡©åãããªã㳠âïŒ ããªã¹ãã¬ã³ âïŒ ããªããã«ã¢ã»ããŒã âïŒ ã¹ãã¬ã³âãã¿ãžãšã³å ±éåäœ ïŒ°â10 å¡©åãããªãã³âã¢ã¯ãªããããªã«å ±é
åäœ ïŒ°â11 å¡©åããã«âé ¢é žããã«å ±éåäœ ïŒ°â12 å¡©åããã«âé ¢é žããã«âç¡æ°Žãã¬ã€ã³
é žå ±éåäœ ïŒ°â13 ã·ãªã³ã³æš¹è â14 ã·ãªã³ã³âã¢ã«ãããæš¹è â15 ããšããŒã«ãã«ã ã¢ã«ãããæš¹è â16 ã¹ãã¬ã³âã¢ã«ãããæš¹è â17 ããªââããã«ã«ã«ããŸãŒã« â18 ããªããã«ããã©ãŒã« â19 ããªããã«ããªã«ããŒã« ãããã®çµçå€ã¯ãåç¬ã§ãããã¯ïŒçš®ä»¥äžã®
æ··åç©ãšããŠçšããããšãã§ããã ãã®ããã«ããŠåœ¢æããããã€ãªã¢çºçå±€ïŒã®
åãã¯ã0.01ÎŒïœã20ÎŒïœã§ããããšã奜ãŸãã
ããæŽã«å¥œãŸããã¯0.05ÎŒïœã5ÎŒïœã§ããããŸã
ãã€ãªã¢çºçå±€ãããã¯æå å±€ãåæ£ç³»ã®å Žåã¢
ãŸååç©ã®ç²äœã¯5ÎŒïœä»¥äžã§ããããšã奜ãŸã
ããæŽã«å¥œãŸããã¯1ÎŒïœä»¥äžã§ããã æ¬çºæã®æå äœã«çšããããå°é»æ§æ¯æäœãšã
ãŠã¯ãåéãå«ããéå±æ¿ãéå±ãã©ã ãŸãã¯å°
é»æ§ããªããŒãé žåã€ã³ãžãŠã çã®å°é»æ§ååç©
ãåéãå«ããã¢ã«ãããŠã ããã©ãžãŠã ãéç
ã®éå±èå±€ãå¡åžãèžçãããã¯ã©ãããŒãã
ãŠãå°é»æ§åãéæããçŽããã©ã¹ããã¯ãã€ã«
ã çãæãããããæ¥çå±€ãããã¯ããªã€ãŒå±€ãª
ã©ã®äžéå±€ãšããŠã¯ãåèšçµçå€ãšããŠçšããã
ãé«ååéåäœã®ã»ããããªããã«ã¢ã«ã³ãŒã«ã
ãšãã«ã»ã«ããŒã¹ãã«ã«ããã·ã¡ãã«ã»ã«ããŒã¹
ãªã©ã®ææ©é«ååç©è³ªãŸãã¯é žåã¢ã«ãããŠã ãª
ã©ãçšããããã æ¬çºæã®æå äœã¯ä»¥äžã®ãããªæ§æã§ãã€ãŠã
åŸè¿°ãããããªå®æœäŸãããæãããªããã«ã垯
é»ç¹æ§ãæ床ç¹æ§ç»å圢æç¹æ§ã«åªããŠãããç¹
ã«ç¹°ãè¿ã䜿çšãããšãã«ãç²åŽå£åãå°ãªãã
èä¹ æ§ãåªãããã®ã§ããã 以äžãæ¬çºæã®å®æœäŸã§å ·äœçã«èª¬æãããã
ããã«ããæ¬çºæã®å®æœæ æ§ãéå®ããããã®ã§
ã¯ãªãã ãå®æœäŸã å®æœäŸ ïŒ äŸç€ºååç©ïŒ¢â90.2ïœãšããªã«ãŒãããŒãæš¹è
ããã³ã©ã€ãâ1250ãïŒåžäººåæ瀟補ïŒïŒïœãšã
1.ããªãªãïŒâãžã¯ãããšã¿ã³110mlã«å ããã
ãŒã«ãã«ã§12æéåæ£ããããã®åæ£æ¶²ãã¢ã«ã
ããŠã ãèžçããããªãšã¹ãã«ãã€ã«ã äžã«ã也
ç¥æã®èåã1ÎŒïœã«ãªãããã«å¡åžãããã€ãª
ã¢çºçå±€ãšããæŽã«ãã®äžã«ããã€ãªã¢èŒžéå±€ãš
ããŠãïŒâããšãã«âïŒïœâã¡ãã«ã¹ããªã«ïŒâïŒ
âïŒïœâã¡ããã·ããšãã«ïŒãã©ãŸãªã³ïŒäžèšæ§
é åŒïŒ«â(1)ïŒïŒïœãããªã«ãŒãããŒãæš¹èããã³
ã©ã€ãâ1250ã10ïœãšãïŒïŒïŒâãžã¯ãããšã¿
ã³110mlã«æº¶è§£ãã液ã也ç¥åŸã®èåã15ÎŒïœã«
ãªãããã«å¡åžããŠããã€ãªã¢èŒžéå±€ã圢æãã
æ¬çºæã®æå äœãäœæããã 以äžã®ããã«ããŠåŸãããæå äœã(æ ª)å·å£é»æ©
補äœæ補SPâ428åéé»çŽè©Šéšæ©ãçšããŠã以äž
ã®ç¹æ§è©äŸ¡ãè¡ã€ãã垯é»å§â6KVã§ïŒç§é垯
é»ããåŸãïŒç§éææŸçœ®ãã次ãã§æå äœè¡šé¢ã§
ã®ç §åºŠã35luxã«ãªãããã«ããã²ã³ã©ã³ãå ã
ç §å°ããŠãè¡šé¢é»äœãååã«æžè¡°ãããã®ã«èŠã
ãé²å éïŒåæžé²å éïŒïŒ¥1/2ãæ±ããããŸã
30luxã»secã®é²å éã§é²å ããåŸã®è¡šé¢é»äœïŒæ®
çé»äœïŒVRãæ±ãããæŽã«åæ§ã®æž¬å®ã100åç¹°
ãè¿ããŠè¡ã€ããçµæã¯ç¬¬ïŒè¡šã«ç€ºãéãã§ã
ãã
ãè¡šã
æ¯èŒäŸ ïŒ
ãã€ãªã¢çºçç©è³ªãšããŠäžèšãã¹ã¢ãŸååç©ïŒ§
â(1)ãçšããä»ã¯ãå®æœäŸïŒãšåæ§ã«ããŠæ¯èŒçš
æå äœãäœæããã ãã®æ¯èŒçšæå äœã«ã€ããŠãå®æœäŸïŒãšåæ§ã«
ããŠæž¬å®ãè¡ã€ããšããã第ïŒè¡šã«ç€ºãçµæãåŸ
ãã
â(1)ãçšããä»ã¯ãå®æœäŸïŒãšåæ§ã«ããŠæ¯èŒçš
æå äœãäœæããã ãã®æ¯èŒçšæå äœã«ã€ããŠãå®æœäŸïŒãšåæ§ã«
ããŠæž¬å®ãè¡ã€ããšããã第ïŒè¡šã«ç€ºãçµæãåŸ
ãã
ãè¡šã
以äžã®çµæããæãããªããã«ãæ¬çºæã®æå
äœã¯ãæ¯èŒçšæå äœã«æ¯ã¹ãæ床ãæ®çé»äœåã³
ç¹°ãè¿ãã®å®å®æ§ã«ãããŠæ¥µããŠåªãããã®ã§ã
ãã å®æœäŸïŒâïŒ ãã€ãªã¢çºçç©è³ªãšããŠäŸç€ºååç©ïŒ¢â68ã
â81ãåã³ïŒ¢â104ãçšãããã€ãªã¢èŒžéç©è³ªãš
ããŠããããããïŒâã¡ãã«âïŒâïŒïŒâãšãã«
âïŒâã«ã«ããŸãªã«ïŒã¡ããªãã³ã¢ãã³âïŒïŒ
ïŒïŒïŒïŒïŒâããã©ããããããªã³ïŒäžèšååç©
â(2)ïŒãïŒâïŒïŒâãšãã«âïŒâã«ã«ããŸãªã«ïŒ
ã¡ããªãã³ã¢ããâïŒïŒïŒïŒïŒïŒïŒâããã©ãã
ããããªã³ïŒäžèšååç©ïŒ«â(3)ïŒãåã³ïŒïŒ4â²â
ã¡ãã«â4â³âïŒïŒâã¯ãã«ïŒâã¹ããªã«ããªããšã
ã«ã¢ãã³ïŒäžèšååç©ïŒ«â(4)ïŒãçšããä»ã¯å®æœ
äŸïŒãšåæ§ã«ããŠãæ¬çºæã®æå äœãäœæããå
æ§ã®æž¬å®ãè¡ã€ããšãã第ïŒè¡šã«ç€ºãçµæãåŸ
ãã
äœã¯ãæ¯èŒçšæå äœã«æ¯ã¹ãæ床ãæ®çé»äœåã³
ç¹°ãè¿ãã®å®å®æ§ã«ãããŠæ¥µããŠåªãããã®ã§ã
ãã å®æœäŸïŒâïŒ ãã€ãªã¢çºçç©è³ªãšããŠäŸç€ºååç©ïŒ¢â68ã
â81ãåã³ïŒ¢â104ãçšãããã€ãªã¢èŒžéç©è³ªãš
ããŠããããããïŒâã¡ãã«âïŒâïŒïŒâãšãã«
âïŒâã«ã«ããŸãªã«ïŒã¡ããªãã³ã¢ãã³âïŒïŒ
ïŒïŒïŒïŒïŒâããã©ããããããªã³ïŒäžèšååç©
â(2)ïŒãïŒâïŒïŒâãšãã«âïŒâã«ã«ããŸãªã«ïŒ
ã¡ããªãã³ã¢ããâïŒïŒïŒïŒïŒïŒïŒâããã©ãã
ããããªã³ïŒäžèšååç©ïŒ«â(3)ïŒãåã³ïŒïŒ4â²â
ã¡ãã«â4â³âïŒïŒâã¯ãã«ïŒâã¹ããªã«ããªããšã
ã«ã¢ãã³ïŒäžèšååç©ïŒ«â(4)ïŒãçšããä»ã¯å®æœ
äŸïŒãšåæ§ã«ããŠãæ¬çºæã®æå äœãäœæããå
æ§ã®æž¬å®ãè¡ã€ããšãã第ïŒè¡šã«ç€ºãçµæãåŸ
ãã
ãè¡šã
å®æœäŸ ïŒ
ããªãšã¹ãã«ãã€ã«ã äžã«ã¢ã«ãããŠã ç®ãã©
ãããŒãããŠæãå°é»æ§æ¯æäœäžã«ãå¡©åããã«
âé ¢é žããã«âç¡æ°Žãã¬ã€ã³é žå ±éåäœããšã¹ã¬
ãã¯MFâ10ãïŒç©æ°ŽååŠç€Ÿè£œïŒããæãåã
0.05ÎŒïœã®äžéå±€ãèšãããã®äžã«äŸç€ºååç©ïŒ¢
â10.2ïœãïŒïŒïŒâãžã¯ãããšã¿ã³110mlã«æ··å
ããããŒã«ãã«ã§24æéåæ£ããåæ£æ¶²ã也ç¥åŸ
ã®èåã0.5ÎŒïœã«ãªãããã«ããŠå¡åžãããã€ãª
ã¢çºçå±€ã圢æããããã®ãã€ãªã¢çºçå±€ã®äžã«
ïŒïŒ3â²ïŒïŒâããªã¡ãã«âããªããšãã«ã¢ãã³ïŒ
ïœãšã¡ã¿ã¯ãªã«æš¹èãã¢ã¯ãªããããïŒäžè±ã¬ã€
ãšã³ç€Ÿè£œïŒ10ïœãšãïŒïŒïŒâãžã¯ãããšã¿ã³70ml
ã«æº¶è§£ãã液ãã也ç¥åŸã®èåã10ÎŒïœã«ãªãã
ãã«å¡åžããŠãã€ãªã¢èŒžéå±€ã圢æããæ¬çºæã®
æå äœãäœæããã ãã®æå äœã«ã€ããŠå®æœäŸïŒãšåæ§ã®æž¬å®ãè¡
ãªã€ããšãã第ïŒåç®ã«ã€ããŠïŒ¥1/2ïŒ4.1luxã»
secãVRïŒ10vã®çµæãåŸãã å®æœäŸ ïŒ å®æœäŸïŒã§çšããäžéå±€ãèšããå°é»æ§æ¯æäœ
äžã«ãäŸç€ºååç©ïŒ¢â37ã®ïŒïŒ ãšãã¬ã³ãžã¢ãã³
溶液ã也ç¥åŸã®èåã1.3ÎŒïœã«ãªãããã«å¡åž
ãããã€ãªã¢çºçå±€ãäœæããã 次ãã§ãã®äžã«ãïŒâã¡ããã·â4â²âã¹ããªã«
ããªããšãã«ã¢ãã³ïŒäžèšååç©ïŒ«â(5)ïŒ ïŒïœãšããªãšã¹ãã«æš¹èããã€ãã³200ãïŒæ±æŽ
玡瞟瀟補ïŒ10ïœãšãïŒïŒïŒãžã¯ãããšã¿ã³70mlã«
溶解ãããã®æº¶æ¶²ã也ç¥åŸã®èåã12ÎŒïœã«ãªã
ããã«å¡åžããŠãã€ãªã¢èŒžéå±€ã圢æããæ¬çºæ
ã®æå äœãäœæããã ãã®æå äœã«ã€ããŠå®æœäŸïŒãšåæ§ã®æž¬å®ãè¡
ã€ããšãã第ïŒè¡šã«ç€ºãçµæãåŸãã æ¯èŒäŸ ïŒ å®æœäŸïŒã«ãããŠäŸç€ºååç©ïŒ¢âïŒãäžèšã®æ§
é åŒã§è¡šããããã¹ã¢ãŸååç©ïŒ§â(2)ã«ä»£ããä»
ã¯åæ§ã«ããŠæ¯èŒçšã®æå äœãäœæããã ãã®æå äœã«ã€ããŠå®æœäŸïŒãšåæ§ã®æž¬å®ãè¡
ã€ãçµæã第ïŒè¡šã«ç€ºãã
ãããŒãããŠæãå°é»æ§æ¯æäœäžã«ãå¡©åããã«
âé ¢é žããã«âç¡æ°Žãã¬ã€ã³é žå ±éåäœããšã¹ã¬
ãã¯MFâ10ãïŒç©æ°ŽååŠç€Ÿè£œïŒããæãåã
0.05ÎŒïœã®äžéå±€ãèšãããã®äžã«äŸç€ºååç©ïŒ¢
â10.2ïœãïŒïŒïŒâãžã¯ãããšã¿ã³110mlã«æ··å
ããããŒã«ãã«ã§24æéåæ£ããåæ£æ¶²ã也ç¥åŸ
ã®èåã0.5ÎŒïœã«ãªãããã«ããŠå¡åžãããã€ãª
ã¢çºçå±€ã圢æããããã®ãã€ãªã¢çºçå±€ã®äžã«
ïŒïŒ3â²ïŒïŒâããªã¡ãã«âããªããšãã«ã¢ãã³ïŒ
ïœãšã¡ã¿ã¯ãªã«æš¹èãã¢ã¯ãªããããïŒäžè±ã¬ã€
ãšã³ç€Ÿè£œïŒ10ïœãšãïŒïŒïŒâãžã¯ãããšã¿ã³70ml
ã«æº¶è§£ãã液ãã也ç¥åŸã®èåã10ÎŒïœã«ãªãã
ãã«å¡åžããŠãã€ãªã¢èŒžéå±€ã圢æããæ¬çºæã®
æå äœãäœæããã ãã®æå äœã«ã€ããŠå®æœäŸïŒãšåæ§ã®æž¬å®ãè¡
ãªã€ããšãã第ïŒåç®ã«ã€ããŠïŒ¥1/2ïŒ4.1luxã»
secãVRïŒ10vã®çµæãåŸãã å®æœäŸ ïŒ å®æœäŸïŒã§çšããäžéå±€ãèšããå°é»æ§æ¯æäœ
äžã«ãäŸç€ºååç©ïŒ¢â37ã®ïŒïŒ ãšãã¬ã³ãžã¢ãã³
溶液ã也ç¥åŸã®èåã1.3ÎŒïœã«ãªãããã«å¡åž
ãããã€ãªã¢çºçå±€ãäœæããã 次ãã§ãã®äžã«ãïŒâã¡ããã·â4â²âã¹ããªã«
ããªããšãã«ã¢ãã³ïŒäžèšååç©ïŒ«â(5)ïŒ ïŒïœãšããªãšã¹ãã«æš¹èããã€ãã³200ãïŒæ±æŽ
玡瞟瀟補ïŒ10ïœãšãïŒïŒïŒãžã¯ãããšã¿ã³70mlã«
溶解ãããã®æº¶æ¶²ã也ç¥åŸã®èåã12ÎŒïœã«ãªã
ããã«å¡åžããŠãã€ãªã¢èŒžéå±€ã圢æããæ¬çºæ
ã®æå äœãäœæããã ãã®æå äœã«ã€ããŠå®æœäŸïŒãšåæ§ã®æž¬å®ãè¡
ã€ããšãã第ïŒè¡šã«ç€ºãçµæãåŸãã æ¯èŒäŸ ïŒ å®æœäŸïŒã«ãããŠäŸç€ºååç©ïŒ¢âïŒãäžèšã®æ§
é åŒã§è¡šããããã¹ã¢ãŸååç©ïŒ§â(2)ã«ä»£ããä»
ã¯åæ§ã«ããŠæ¯èŒçšã®æå äœãäœæããã ãã®æå äœã«ã€ããŠå®æœäŸïŒãšåæ§ã®æž¬å®ãè¡
ã€ãçµæã第ïŒè¡šã«ç€ºãã
ãè¡šã
å®æœäŸïŒã®è©Šæã¯æ¯èŒäŸã«å¯Ÿã100åç¹°è¿ã䜿
çšåŸã®ç¹æ§ã«ãããŠç¹ã«ããããŠããã å®æœäŸ ïŒ å®æœäŸïŒã«ãããŠäŸç€ºååç©ïŒ¢â10ãäŸç€ºåå
ç©ïŒ¢âïŒã«ä»£ããä»ã¯åæ§ã«ããŠãã€ãªã¢çºçå±€
ã圢æããããã®äžã«ãïŒâïŒïœâã¡ããã·ã¹ã
ãªã«ïŒïŒâïŒïœâã¡ããã·ããšãã«ïŒã«ã«ããŸãŒ
ã«ïŒïœãšããªã«ãŒãããŒãããã³ã©ã€ãâ
1250ãïŒåžäººåæ瀟補ïŒ10ïœãšãïŒïŒïŒâãžã¯ã
ããšã¿ã³70mlã«æº¶è§£ãã液ã也ç¥åŸã®èåã10ÎŒ
ïœã«ãªãããã«å¡åžããŠãã€ãªã¢èŒžéå±€ã圢æ
ããæ¬çºæã®æå äœãäœæããã ãã®æå äœã«ã€ããŠãå®æœäŸïŒãšåæ§ã«ããŠæž¬
å®ãè¡ã€ããšãã1/2ïŒ4.7luxã»secåã³VRïŒ0v
ã§ãã€ãã å®æœäŸ ïŒ çŽåŸ100mmã®ã¢ã«ãããŠã 補ãã©ã ã®è¡šé¢ã«å¡©
åããã«âé ¢é žããã«âç¡æ°Žãã¬ã€ã³é žå ±éåäœ
ããšã¹ã¬ãã¯MFâ10ãïŒç©æ°ŽååŠç€Ÿè£œïŒããæã
åã0.05ÎŒïœã®äžéå±€ãèšãããã®äžã«äŸç€ºåå
ç©ïŒ¢â82.4ïœãïŒïŒïŒâãžã¯ãããšã¿ã³400mlã«
æ··åããããŒã«ãã«åæ£æ©ã§24æéåæ£ããåæ£
液ã也ç¥åŸã®èåã0.6ÎŒïœã«ãªãããã«ããŠå¡åž
ãããã€ãªã¢çºçå±€ã圢æããã ããã«ãã®äžã«ãïŒâïŒïœâã¡ããã·ã¹ããªã«ïŒ
âïŒâïŒïœâã¡ããã·ããšãã«ïŒã«ã«ããŸãŒã«
ïŒäžèšååç©ïŒ«â(6)ïŒ30ïœãšããªã«ãŒãããŒãæš¹
èããŠãŒããã³ïŒ³â1000ãïŒäžè±ã¬ã¹ååŠç€Ÿè£œïŒ
50ïœãšãïŒïŒïŒâãžã¯ãããšã¿ã³ 400mlã«æº¶è§£ãã也ç¥åŸã®èåã13ÎŒïœã«ãªã
ããã«å¡åžããŠãã€ãªã¢èŒžéå±€ã圢æãããã©ã
ç¶ã®æå äœãäœæããã ãã®ããã«ããŠäœæããæå äœãé»ååçè€å
æ©ãâBix1600MRãïŒå°è¥¿å åçå·¥æ¥ç€Ÿè£œïŒã®
æ¹é æ©ã«è£ çããç»åãè€åãããšããã³ã³ãã©
ã¹ããé«ããåç»ã«å¿ å®ã§ãã€é®®æãªè€åç»åã
åŸãããŸããããã¯10000åç¹°ãè¿ããŠãå€ãã
ããšã¯ãªãã€ãã æ¯èŒäŸ ïŒ å®æœäŸïŒã«ãããŠäŸç€ºååç©ïŒ¢â82ãäžèšæ§é
åŒã§è¡šãããããªã¹ã¢ãŸååç©ïŒïŒ§â(3)ïŒã«ä»£ã
ãä»ã¯ãå®æœäŸïŒãšåæ§ã«ããŠãã©ã ç¶ã®æ¯èŒçš
æå äœãäœæããå®æœäŸïŒãšåæ§ã«ããŠè€åç»å
ãè©äŸ¡ãããšãããã«ããªãå€ãç»åããåŸãã
ãªãã€ããåãè€åãç¹°ãè¿ããŠããã«åŸããè€
åç»åã®ã³ã³ãã©ã¹ããäœäžãã2000åç¹°ãè¿ã
ãšãã»ãšãã©è€åç»åã¯åŸãããªãã€ãã å®æœäŸ ïŒ ããªãšã¹ãã«ãã€ã«ã äžã«ã¢ã«ãããŠã ç®ãã©
ãããŒãããŠæãå°é»æ§æ¯æäœäžã«ãå¡©åããã«
âé ¢é žããã«âç¡æ°Žãã¬ã€ã³é žå ±éåäœããšã¹ã¬
ãã¯MFâ10ãïŒç©æ°ŽååŠç€Ÿè£œïŒãããªãåã
0.05ÎŒã®äžéå±€ãèšãããã®äžã«äŸç€ºååç©ïŒ¢â
1.5ïœãšããªã«ãŒãããŒãæš¹èããã³ã©ã€ãâ
1250ãïŒåžäººåæ瀟補ïŒ3.3ïœãšããžã¯ããã¡ã¿ã³
100mlã«å ããããŒã«ãã«ã§24æéåæ£ããåæ£
液ã也ç¥æã®èåã10ÎŒïœã«ãªãããã«å¡åžãã
æå äœãäœæããã 以äžã®ããã«ããŠåŸãããæå äœã垯é»å§ãïŒ
6Kvã«ä»£ããä»ã¯å®æœäŸïŒãšåæ§ã«ããŠïŒ¥1/2ãš
VRã枬å®ãããïŒåç®ã®çµæã¯ïŒ¥1/2ïŒ4.8luxã»
secåã³VRïŒ0vã§ãã€ãã å®æœäŸ 10 ã¢ã«ãããŠã ãèžçããããªãšã¹ãã«ãã€ã«ã
äžã«ãã€ãªã¢èŒžéå±€ãšããŠãïŒâã¡ããã·ããªã
ãšãã«ã¢ãã³ïŒïœãšããªãšã¹ãã«æš¹èããã€ãã³
200ãïŒæ±æŽçŽ¡çžŸç€Ÿè£œïŒ10ïœãšãïŒïŒïŒâãžã¯ãã
ãšã¿ã³70mlã«æº¶è§£ãããã®æº¶æ¶²ã也ç¥åŸã®èåã
10ÎŒïœã«ãªãããã«å¡åžããã 次ã«ããã®äžã«äŸç€ºååç©ïŒ¢â82.1ïœãšïŒ¢â
991ïœãšãïŒïŒïŒâãžã¯ãããšã¿ã³110mlã«æ··å
ããããŒã«ãã«ã§24æéåæ£ããåæ£æ¶²ã也ç¥åŸ
ã®èåã0.5ÎŒïœã«ãªãããã«å¡åžãããã€ãªã¢çº
çå±€ãšããæ¬çºæã®æå äœã圢æããã ãã®ããã«ããŠåŸãããæå äœãå®æœäŸïŒãšå
æ§ã«ããŠè©äŸ¡ãããšãã1/2ïŒ4.8luxã»secåã³
VRïŒ0vã§ãã€ãã å®æœäŸ 11 äŸç€ºååç©ååç©ïŒ¢âïŒã®ïŒïŒ ãšãã¬ã³ãžã¢ã
ã³æº¶æ¶²ããã¢ã«ãããŠã ãã©ãããŒãããããªãš
ã¹ãã«ãã€ã«ã äžã«ä¹Ÿç¥æã®èåã0.5ÎŒïœã«ãªã
ããã«å¡åžãããã€ãªã¢çºçå±€ã圢æãããæŽã«
ãã®äžã«ãã€ãªã¢èŒžéå±€ãšããŠãïŒâã¡ãã«âïŒ
âïŒïœâãžãšãã«ã¢ããããšãã«ïŒâïŒâïŒïœâãž
ãšãã«ã¢ããããšãã«ïŒãã©ãŸãªã³ïŒäžèšååç©
â(7)ïŒãïŒâããšãã«ïŒïœâã¡ããã·ã¹ããªã«ïŒ
âïŒâïŒïœâãžãšãã«ã¢ããããšãã«ïŒãã©ãŸãª
ã³äžèšååç©ïŒ«â(8)ããŸãã¯ãïŒâããšãã«âïŒ
âïŒïœâã¡ãã«ã¹ããªã«ïŒâïŒâïŒïœâã¡ãã«ããš
ãã«ïŒãã©ãŸãªã³ïŒäžèšååç©ïŒ«â(9)ïŒãå¥ã ã«
ããããçŽ10ïœãšããªã«ãŒãããŒã æš¹èïŒåžäººåæ瀟補ããã³ã©ã€ãâ1250ïŒ14ïœ
ãïŒïŒïŒâãžã¯ãããšã¿ã³140mlã«æº¶è§£ãã溶液
ãã也ç¥åŸã®èåã12ÎŒïœãšãªãããã«å¡åžã也
ç¥ããããããïŒçš®ã®ãã€ãªã¢èŒžéç©è³ªã®ç°ãªã
æå äœãåŸãã ãã®ïŒçš®ã®æå äœããå®æœäŸïŒãšåæ§ã®æž¬å®ã
è¡ã€ããçµæã¯ç¬¬ïŒè¡šã«ç€ºãéããããã®ãã€ãª
ã¢èŒžéç©è³ªãšã®çµã¿åããã«ãããŠãè¯å¥œã§ãã€
ãã
çšåŸã®ç¹æ§ã«ãããŠç¹ã«ããããŠããã å®æœäŸ ïŒ å®æœäŸïŒã«ãããŠäŸç€ºååç©ïŒ¢â10ãäŸç€ºåå
ç©ïŒ¢âïŒã«ä»£ããä»ã¯åæ§ã«ããŠãã€ãªã¢çºçå±€
ã圢æããããã®äžã«ãïŒâïŒïœâã¡ããã·ã¹ã
ãªã«ïŒïŒâïŒïœâã¡ããã·ããšãã«ïŒã«ã«ããŸãŒ
ã«ïŒïœãšããªã«ãŒãããŒãããã³ã©ã€ãâ
1250ãïŒåžäººåæ瀟補ïŒ10ïœãšãïŒïŒïŒâãžã¯ã
ããšã¿ã³70mlã«æº¶è§£ãã液ã也ç¥åŸã®èåã10ÎŒ
ïœã«ãªãããã«å¡åžããŠãã€ãªã¢èŒžéå±€ã圢æ
ããæ¬çºæã®æå äœãäœæããã ãã®æå äœã«ã€ããŠãå®æœäŸïŒãšåæ§ã«ããŠæž¬
å®ãè¡ã€ããšãã1/2ïŒ4.7luxã»secåã³VRïŒ0v
ã§ãã€ãã å®æœäŸ ïŒ çŽåŸ100mmã®ã¢ã«ãããŠã 補ãã©ã ã®è¡šé¢ã«å¡©
åããã«âé ¢é žããã«âç¡æ°Žãã¬ã€ã³é žå ±éåäœ
ããšã¹ã¬ãã¯MFâ10ãïŒç©æ°ŽååŠç€Ÿè£œïŒããæã
åã0.05ÎŒïœã®äžéå±€ãèšãããã®äžã«äŸç€ºåå
ç©ïŒ¢â82.4ïœãïŒïŒïŒâãžã¯ãããšã¿ã³400mlã«
æ··åããããŒã«ãã«åæ£æ©ã§24æéåæ£ããåæ£
液ã也ç¥åŸã®èåã0.6ÎŒïœã«ãªãããã«ããŠå¡åž
ãããã€ãªã¢çºçå±€ã圢æããã ããã«ãã®äžã«ãïŒâïŒïœâã¡ããã·ã¹ããªã«ïŒ
âïŒâïŒïœâã¡ããã·ããšãã«ïŒã«ã«ããŸãŒã«
ïŒäžèšååç©ïŒ«â(6)ïŒ30ïœãšããªã«ãŒãããŒãæš¹
èããŠãŒããã³ïŒ³â1000ãïŒäžè±ã¬ã¹ååŠç€Ÿè£œïŒ
50ïœãšãïŒïŒïŒâãžã¯ãããšã¿ã³ 400mlã«æº¶è§£ãã也ç¥åŸã®èåã13ÎŒïœã«ãªã
ããã«å¡åžããŠãã€ãªã¢èŒžéå±€ã圢æãããã©ã
ç¶ã®æå äœãäœæããã ãã®ããã«ããŠäœæããæå äœãé»ååçè€å
æ©ãâBix1600MRãïŒå°è¥¿å åçå·¥æ¥ç€Ÿè£œïŒã®
æ¹é æ©ã«è£ çããç»åãè€åãããšããã³ã³ãã©
ã¹ããé«ããåç»ã«å¿ å®ã§ãã€é®®æãªè€åç»åã
åŸãããŸããããã¯10000åç¹°ãè¿ããŠãå€ãã
ããšã¯ãªãã€ãã æ¯èŒäŸ ïŒ å®æœäŸïŒã«ãããŠäŸç€ºååç©ïŒ¢â82ãäžèšæ§é
åŒã§è¡šãããããªã¹ã¢ãŸååç©ïŒïŒ§â(3)ïŒã«ä»£ã
ãä»ã¯ãå®æœäŸïŒãšåæ§ã«ããŠãã©ã ç¶ã®æ¯èŒçš
æå äœãäœæããå®æœäŸïŒãšåæ§ã«ããŠè€åç»å
ãè©äŸ¡ãããšãããã«ããªãå€ãç»åããåŸãã
ãªãã€ããåãè€åãç¹°ãè¿ããŠããã«åŸããè€
åç»åã®ã³ã³ãã©ã¹ããäœäžãã2000åç¹°ãè¿ã
ãšãã»ãšãã©è€åç»åã¯åŸãããªãã€ãã å®æœäŸ ïŒ ããªãšã¹ãã«ãã€ã«ã äžã«ã¢ã«ãããŠã ç®ãã©
ãããŒãããŠæãå°é»æ§æ¯æäœäžã«ãå¡©åããã«
âé ¢é žããã«âç¡æ°Žãã¬ã€ã³é žå ±éåäœããšã¹ã¬
ãã¯MFâ10ãïŒç©æ°ŽååŠç€Ÿè£œïŒãããªãåã
0.05ÎŒã®äžéå±€ãèšãããã®äžã«äŸç€ºååç©ïŒ¢â
1.5ïœãšããªã«ãŒãããŒãæš¹èããã³ã©ã€ãâ
1250ãïŒåžäººåæ瀟補ïŒ3.3ïœãšããžã¯ããã¡ã¿ã³
100mlã«å ããããŒã«ãã«ã§24æéåæ£ããåæ£
液ã也ç¥æã®èåã10ÎŒïœã«ãªãããã«å¡åžãã
æå äœãäœæããã 以äžã®ããã«ããŠåŸãããæå äœã垯é»å§ãïŒ
6Kvã«ä»£ããä»ã¯å®æœäŸïŒãšåæ§ã«ããŠïŒ¥1/2ãš
VRã枬å®ãããïŒåç®ã®çµæã¯ïŒ¥1/2ïŒ4.8luxã»
secåã³VRïŒ0vã§ãã€ãã å®æœäŸ 10 ã¢ã«ãããŠã ãèžçããããªãšã¹ãã«ãã€ã«ã
äžã«ãã€ãªã¢èŒžéå±€ãšããŠãïŒâã¡ããã·ããªã
ãšãã«ã¢ãã³ïŒïœãšããªãšã¹ãã«æš¹èããã€ãã³
200ãïŒæ±æŽçŽ¡çžŸç€Ÿè£œïŒ10ïœãšãïŒïŒïŒâãžã¯ãã
ãšã¿ã³70mlã«æº¶è§£ãããã®æº¶æ¶²ã也ç¥åŸã®èåã
10ÎŒïœã«ãªãããã«å¡åžããã 次ã«ããã®äžã«äŸç€ºååç©ïŒ¢â82.1ïœãšïŒ¢â
991ïœãšãïŒïŒïŒâãžã¯ãããšã¿ã³110mlã«æ··å
ããããŒã«ãã«ã§24æéåæ£ããåæ£æ¶²ã也ç¥åŸ
ã®èåã0.5ÎŒïœã«ãªãããã«å¡åžãããã€ãªã¢çº
çå±€ãšããæ¬çºæã®æå äœã圢æããã ãã®ããã«ããŠåŸãããæå äœãå®æœäŸïŒãšå
æ§ã«ããŠè©äŸ¡ãããšãã1/2ïŒ4.8luxã»secåã³
VRïŒ0vã§ãã€ãã å®æœäŸ 11 äŸç€ºååç©ååç©ïŒ¢âïŒã®ïŒïŒ ãšãã¬ã³ãžã¢ã
ã³æº¶æ¶²ããã¢ã«ãããŠã ãã©ãããŒãããããªãš
ã¹ãã«ãã€ã«ã äžã«ä¹Ÿç¥æã®èåã0.5ÎŒïœã«ãªã
ããã«å¡åžãããã€ãªã¢çºçå±€ã圢æãããæŽã«
ãã®äžã«ãã€ãªã¢èŒžéå±€ãšããŠãïŒâã¡ãã«âïŒ
âïŒïœâãžãšãã«ã¢ããããšãã«ïŒâïŒâïŒïœâãž
ãšãã«ã¢ããããšãã«ïŒãã©ãŸãªã³ïŒäžèšååç©
â(7)ïŒãïŒâããšãã«ïŒïœâã¡ããã·ã¹ããªã«ïŒ
âïŒâïŒïœâãžãšãã«ã¢ããããšãã«ïŒãã©ãŸãª
ã³äžèšååç©ïŒ«â(8)ããŸãã¯ãïŒâããšãã«âïŒ
âïŒïœâã¡ãã«ã¹ããªã«ïŒâïŒâïŒïœâã¡ãã«ããš
ãã«ïŒãã©ãŸãªã³ïŒäžèšååç©ïŒ«â(9)ïŒãå¥ã ã«
ããããçŽ10ïœãšããªã«ãŒãããŒã æš¹èïŒåžäººåæ瀟補ããã³ã©ã€ãâ1250ïŒ14ïœ
ãïŒïŒïŒâãžã¯ãããšã¿ã³140mlã«æº¶è§£ãã溶液
ãã也ç¥åŸã®èåã12ÎŒïœãšãªãããã«å¡åžã也
ç¥ããããããïŒçš®ã®ãã€ãªã¢èŒžéç©è³ªã®ç°ãªã
æå äœãåŸãã ãã®ïŒçš®ã®æå äœããå®æœäŸïŒãšåæ§ã®æž¬å®ã
è¡ã€ããçµæã¯ç¬¬ïŒè¡šã«ç€ºãéããããã®ãã€ãª
ã¢èŒžéç©è³ªãšã®çµã¿åããã«ãããŠãè¯å¥œã§ãã€
ãã
ãè¡šã
æ¯èŒäŸ ïŒ
äŸç€ºååç©ïŒ¢âïŒãäžèšã®ãã¹ã¢ãŸååç©ïŒïŒ§
â(4)ïŒã«ä»£ããä»ã¯å®æœäŸ11ãšåæ§ã«ããŠæ¯èŒçš
æå äœãäœæããç¹æ§è©äŸ¡ãè¡ã€ãçµæã 第ïŒè¡šã«ç€ºãéãããã€ãªã¢èŒžéç©è³ªã«ãã€ãŠ
çµæã«ã°ãã€ããåºãã
â(4)ïŒã«ä»£ããä»ã¯å®æœäŸ11ãšåæ§ã«ããŠæ¯èŒçš
æå äœãäœæããç¹æ§è©äŸ¡ãè¡ã€ãçµæã 第ïŒè¡šã«ç€ºãéãããã€ãªã¢èŒžéç©è³ªã«ãã€ãŠ
çµæã«ã°ãã€ããåºãã
ãè¡šã
å®æœäŸ 12
å®æœäŸïŒã§çšããäžéå±€ãèšããå°é»æ§æ¯æäœ
äžã«ãäŸç€ºååç©ïŒ¢â54.2ïœãšïŒïŒïŒâãžã¯ãã
ãšã¿ã³100mlãšãããåæ£æ··åãã也ç¥åŸã®èå
ã0.3ÎŒïœã«ãªãããã«å¡åžããã€ãªã¢çºçå±€ãäœ
æããã 次ãã§ãã®äžã«ãã€ãªã¢èŒžéç©è³ªãšããŠãïŒâ
ã¡ãã«â4â²ã¹ããªã«âããªããšãã«ã¢ãã³ïŒäžèš
ååç©ïŒ«â(10)ïŒïŒïœãšããªã«ãŒãããŒãããã³ã©
ã€ãâ1250ãïŒåžäººåæç€Ÿè£œïŒ 10ïœãšãïŒïŒïŒâãžã¯ãããšã¿ã³90ïœã«æº¶è§£ãã
液ã也ç¥åŸã®èåã10ÎŒïœã«ãªãããã«å¡åžããŠ
ãã€ãªã¢èŒžéå±€ã圢æããæ¬çºæã®æå äœãäœæ
ããã ãã®æå äœã«ã€ããŠã25âåã³60âã®å®€å 枩床
ã«ãããé»ååçç¹æ§ããå®æœäŸïŒãšåæ§ã«ããŠ
枬å®ããã çµæã第ïŒè¡šã«ç€ºãã
äžã«ãäŸç€ºååç©ïŒ¢â54.2ïœãšïŒïŒïŒâãžã¯ãã
ãšã¿ã³100mlãšãããåæ£æ··åãã也ç¥åŸã®èå
ã0.3ÎŒïœã«ãªãããã«å¡åžããã€ãªã¢çºçå±€ãäœ
æããã 次ãã§ãã®äžã«ãã€ãªã¢èŒžéç©è³ªãšããŠãïŒâ
ã¡ãã«â4â²ã¹ããªã«âããªããšãã«ã¢ãã³ïŒäžèš
ååç©ïŒ«â(10)ïŒïŒïœãšããªã«ãŒãããŒãããã³ã©
ã€ãâ1250ãïŒåžäººåæç€Ÿè£œïŒ 10ïœãšãïŒïŒïŒâãžã¯ãããšã¿ã³90ïœã«æº¶è§£ãã
液ã也ç¥åŸã®èåã10ÎŒïœã«ãªãããã«å¡åžããŠ
ãã€ãªã¢èŒžéå±€ã圢æããæ¬çºæã®æå äœãäœæ
ããã ãã®æå äœã«ã€ããŠã25âåã³60âã®å®€å 枩床
ã«ãããé»ååçç¹æ§ããå®æœäŸïŒãšåæ§ã«ããŠ
枬å®ããã çµæã第ïŒè¡šã«ç€ºãã
ãè¡šã
以äžã®çµæããæãããªããã«ãæ¬çºæã®æå
äœã¯é«æž©ã«ãããŠãæ床ãæ®çé»äœç¹æ§ãè¯å¥œã§
ãããç±ã«å¯ŸããŠå®å®ã§ããããšããããã å®æœäŸ 13 å®æœäŸïŒã§çšããäžéå±€ãèšããå°é»æ§æ¯æäœ
äžã«äŸç€ºååç©ïŒ¢â12.2ïœãšïŒïŒïŒâãžã¯ãã«ãš
ã¿ã³110mlãšãããåæ£æ··åã也ç¥åŸã®èåã
0.3ÎŒïœã«ãªãããã«å¡åžããŠãã€ãªã¢çºçå±€ãäœ
æããã ãã®ãã€ãªã¢çºçå±€ã®UVå ã«å¯Ÿããèä¹ æ§ã
è©Šéšããããã30cmé¢ããäœçœ®ã«è¶ é«å§æ°Žéã©ã³
ãïŒæ±äº¬è浊é»æ©ç€Ÿè£œïŒã眮ãã10åé
1500cdïŒcm2ã®UVå ãç §å°ããã次ã«ãã®UVå
ç §å°æžã¿ã®ãã€ãªã¢çºçå±€ã®äžã«ãã€ãªã¢èŒžéç©
質ãšããŠãïŒâã¡ããã·â4â²âïŒïŒâã¡ãã«ã¹ã
ãªã«ïŒâããªããšãã«ã¢ãã³ïŒäžèšååç©ïŒ«â
ïŒ11ïŒïŒïŒïœãšããªã«ãŒãããŒãããã³ã©ã€ãâ
1250ãïŒåžäººåæ瀟補ïŒ10ïœãšããïŒïŒïŒâãžã¯
ãã«ãšã¿ã³90ïœã«æº¶è§£ããã 液ã也ç¥åŸã®èåã12ÎŒïœã«ãªãããã«å¡åžããŠ
ãã€ãªã¢èŒžéå±€ã圢æããæ¬çºæã®æå äœãäœæ
ããã ãã®æå äœã«ã€ããŠãå®æœäŸïŒãšåæ§ã®æž¬å®ã
è¡ã€ããçµæã第ïŒè¡šã«ç€ºãã å®æœäŸ 14 ãã€ãªã¢çºç局圢æåŸã«UVå ãç §å°ããªãä»
ã¯ãå®æœäŸ13ãšåæ§ã«ããŠæ¬çºæã®æå äœãäœæ
ããå®æœäŸïŒãšåæ§ã®æž¬å®ãè¡ã€ããçµæã第ïŒ
è¡šã«ç€ºãã
äœã¯é«æž©ã«ãããŠãæ床ãæ®çé»äœç¹æ§ãè¯å¥œã§
ãããç±ã«å¯ŸããŠå®å®ã§ããããšããããã å®æœäŸ 13 å®æœäŸïŒã§çšããäžéå±€ãèšããå°é»æ§æ¯æäœ
äžã«äŸç€ºååç©ïŒ¢â12.2ïœãšïŒïŒïŒâãžã¯ãã«ãš
ã¿ã³110mlãšãããåæ£æ··åã也ç¥åŸã®èåã
0.3ÎŒïœã«ãªãããã«å¡åžããŠãã€ãªã¢çºçå±€ãäœ
æããã ãã®ãã€ãªã¢çºçå±€ã®UVå ã«å¯Ÿããèä¹ æ§ã
è©Šéšããããã30cmé¢ããäœçœ®ã«è¶ é«å§æ°Žéã©ã³
ãïŒæ±äº¬è浊é»æ©ç€Ÿè£œïŒã眮ãã10åé
1500cdïŒcm2ã®UVå ãç §å°ããã次ã«ãã®UVå
ç §å°æžã¿ã®ãã€ãªã¢çºçå±€ã®äžã«ãã€ãªã¢èŒžéç©
質ãšããŠãïŒâã¡ããã·â4â²âïŒïŒâã¡ãã«ã¹ã
ãªã«ïŒâããªããšãã«ã¢ãã³ïŒäžèšååç©ïŒ«â
ïŒ11ïŒïŒïŒïœãšããªã«ãŒãããŒãããã³ã©ã€ãâ
1250ãïŒåžäººåæ瀟補ïŒ10ïœãšããïŒïŒïŒâãžã¯
ãã«ãšã¿ã³90ïœã«æº¶è§£ããã 液ã也ç¥åŸã®èåã12ÎŒïœã«ãªãããã«å¡åžããŠ
ãã€ãªã¢èŒžéå±€ã圢æããæ¬çºæã®æå äœãäœæ
ããã ãã®æå äœã«ã€ããŠãå®æœäŸïŒãšåæ§ã®æž¬å®ã
è¡ã€ããçµæã第ïŒè¡šã«ç€ºãã å®æœäŸ 14 ãã€ãªã¢çºç局圢æåŸã«UVå ãç §å°ããªãä»
ã¯ãå®æœäŸ13ãšåæ§ã«ããŠæ¬çºæã®æå äœãäœæ
ããå®æœäŸïŒãšåæ§ã®æž¬å®ãè¡ã€ããçµæã第ïŒ
è¡šã«ç€ºãã
ãè¡šã
以äžã®çµæããæãããªããã«ãæ¬çºæã®æå
äœã¯UVå ç §å°ã«å¯ŸããŠæ床ã»æ®çé»äœç¹æ§ã«åª
ããå容é»äœã®å€åéãå°ãããå ã«å¯ŸããŠå®å®
ã§ããããšãç解ã§ããã æ¯èŒäŸ ïŒ ååç©ïŒ¢â10ãäžèšã®ãã¹ã¢ãŸååç©ïŒïŒ§â
(5)ïŒã«å€ããä»ã¯å®æœäŸ13åã³å®æœäŸ14ãšåæ§ã« ããŠæå äœãäœæããå®æœäŸïŒãšåæ§ã®æž¬å®ãè¡
ãªã€ããçµæã第ïŒè¡šã«ç€ºãã
äœã¯UVå ç §å°ã«å¯ŸããŠæ床ã»æ®çé»äœç¹æ§ã«åª
ããå容é»äœã®å€åéãå°ãããå ã«å¯ŸããŠå®å®
ã§ããããšãç解ã§ããã æ¯èŒäŸ ïŒ ååç©ïŒ¢â10ãäžèšã®ãã¹ã¢ãŸååç©ïŒïŒ§â
(5)ïŒã«å€ããä»ã¯å®æœäŸ13åã³å®æœäŸ14ãšåæ§ã« ããŠæå äœãäœæããå®æœäŸïŒãšåæ§ã®æž¬å®ãè¡
ãªã€ããçµæã第ïŒè¡šã«ç€ºãã
ãè¡šã
以äžã®çµæããæãããªããã«ãäžèšååç©ã
çšããŠäœæããååç©ã¯ãUVå ç §å°ã«ãã€ãŠæ
床ã»æ®çé»äœç¹æ§ã¯å£åããå容é»äœã®å€åéã
倧ããã å®æœäŸ 15 å®æœäŸïŒã«ãããŠäŸç€ºååç©ïŒ¢â10ãâ27ã«
å€ããä»ã¯åæ§ã«ããŠãã©ã ç¶ã®æå äœãäœæã
ãããã®æå äœã®790nmã«ãããåå æ床ã¯
0.67ÎŒJïŒcm2ïŒåæžé²åºéïŒã§ãã€ãããã®æ¬çºæ
ã®æå äœãæå äœè¡šé¢ã§ã®ã¬ãŒã¶ãŒå 匷床ã
0.85mWãšãªãåå°äœã¬ãŒã¶ãŒïŒ790nmïŒãè£ ç
ããå®éšæ©ã«ããå®åãã¹ããè¡ã€ãã æå äœã®è¡šé¢ãâ6KVã«åž¯é»ããåŸãã¬ãŒã¶
ãŒå é²å ãâ250Vã®ãã€ã¢ã¹é»å§ã§å転çŸåã
ããšãããã«ããªã®ãªãè¯å¥œãªç»åãåŸãããã æ¯èŒäŸ ïŒ å®æœäŸ15ã«ãããŠäŸç€ºååç©ïŒ¢â27ã«ä»£ããŠäž
èšã®æ¯èŒäŸãã¹ã¢ãŸååç©ãçšããä»ã¯åæ§ã«ã
ãŠæ¯èŒçšæå äœãåŸãã ãã®æå äœã®790nmã«ãããåå æ床ã¯
6.8ÎŒJïŒcm2ïŒåæžé²å éïŒã§ãã€ãããã®æ¯èŒçš
æå äœãçšããŠå®æœäŸ15ãšåæ§ã«åå°äœã¬ãŒã¶ãŒ
ã«ããå®åãã¹ããè¡ã€ããã«ããªãå€ãè¯å¥œãª
ç»åã¯åŸãããªãã€ãã 以äžã®å®æœäŸãæ¯èŒäŸã®çµæããæãããªãã
ã«æ¬çºæã®æå äœã¯æ¯èŒçšæå äœã«æ¯ã¹ãå®å®
æ§ãæ床ãèä¹ æ§ãåºç¯ãªãã€ãªã¢èŒžéç©è³ªãšã®
çµã¿åããçã®ç¹æ§ã«ãããŠèããåªãããã®ã§
ããã ïŒçºæã®å¹æïŒ æ¬çºæã«ãã€ãŠãæå äœã®æå å±€ãæ§æããå
å°é»æ§ç©è³ªãšããŠåèšäžè¬åŒããã§è¡šãããã¢
ãŸååç©ã䜿çšããããšã«ãããæ¬çºæã®ç®çã§
ããç±åã³å ã«å¯ŸããŠå®å®ã§ããããŸãé»è·ä¿æ
åãæ床ãæ®çé»äœçã®é»ååçç¹æ§ã«ãããŠåª
ããŠããããã€ç¹°è¿ã䜿çšããæã«ãç²åŽå£åã
å°ãªããããã«780nm以äžã®é·æ³¢é·é åã«ãããŠ
ãååãªæ床ãæããåªããæå äœãäœæããã
ãšãã§ããã
çšããŠäœæããååç©ã¯ãUVå ç §å°ã«ãã€ãŠæ
床ã»æ®çé»äœç¹æ§ã¯å£åããå容é»äœã®å€åéã
倧ããã å®æœäŸ 15 å®æœäŸïŒã«ãããŠäŸç€ºååç©ïŒ¢â10ãâ27ã«
å€ããä»ã¯åæ§ã«ããŠãã©ã ç¶ã®æå äœãäœæã
ãããã®æå äœã®790nmã«ãããåå æ床ã¯
0.67ÎŒJïŒcm2ïŒåæžé²åºéïŒã§ãã€ãããã®æ¬çºæ
ã®æå äœãæå äœè¡šé¢ã§ã®ã¬ãŒã¶ãŒå 匷床ã
0.85mWãšãªãåå°äœã¬ãŒã¶ãŒïŒ790nmïŒãè£ ç
ããå®éšæ©ã«ããå®åãã¹ããè¡ã€ãã æå äœã®è¡šé¢ãâ6KVã«åž¯é»ããåŸãã¬ãŒã¶
ãŒå é²å ãâ250Vã®ãã€ã¢ã¹é»å§ã§å転çŸåã
ããšãããã«ããªã®ãªãè¯å¥œãªç»åãåŸãããã æ¯èŒäŸ ïŒ å®æœäŸ15ã«ãããŠäŸç€ºååç©ïŒ¢â27ã«ä»£ããŠäž
èšã®æ¯èŒäŸãã¹ã¢ãŸååç©ãçšããä»ã¯åæ§ã«ã
ãŠæ¯èŒçšæå äœãåŸãã ãã®æå äœã®790nmã«ãããåå æ床ã¯
6.8ÎŒJïŒcm2ïŒåæžé²å éïŒã§ãã€ãããã®æ¯èŒçš
æå äœãçšããŠå®æœäŸ15ãšåæ§ã«åå°äœã¬ãŒã¶ãŒ
ã«ããå®åãã¹ããè¡ã€ããã«ããªãå€ãè¯å¥œãª
ç»åã¯åŸãããªãã€ãã 以äžã®å®æœäŸãæ¯èŒäŸã®çµæããæãããªãã
ã«æ¬çºæã®æå äœã¯æ¯èŒçšæå äœã«æ¯ã¹ãå®å®
æ§ãæ床ãèä¹ æ§ãåºç¯ãªãã€ãªã¢èŒžéç©è³ªãšã®
çµã¿åããçã®ç¹æ§ã«ãããŠèããåªãããã®ã§
ããã ïŒçºæã®å¹æïŒ æ¬çºæã«ãã€ãŠãæå äœã®æå å±€ãæ§æããå
å°é»æ§ç©è³ªãšããŠåèšäžè¬åŒããã§è¡šãããã¢
ãŸååç©ã䜿çšããããšã«ãããæ¬çºæã®ç®çã§
ããç±åã³å ã«å¯ŸããŠå®å®ã§ããããŸãé»è·ä¿æ
åãæ床ãæ®çé»äœçã®é»ååçç¹æ§ã«ãããŠåª
ããŠããããã€ç¹°è¿ã䜿çšããæã«ãç²åŽå£åã
å°ãªããããã«780nm以äžã®é·æ³¢é·é åã«ãããŠ
ãååãªæ床ãæããåªããæå äœãäœæããã
ãšãã§ããã
第ïŒå³ã第ïŒå³ã¯ããããæ¬çºæã®æå
äœã®æ©
械çæ§æäŸã«ã€ããŠç€ºãæé¢å³ã§ãã€ãŠå³äžã®ïŒ
ãïŒã¯ãããã以äžã®äºãè¡šãã ïŒâŠâŠå°é»æ¯æäœãïŒâŠâŠãã€ãªã¢çºçå±€ãïŒ
âŠâŠãã€ãªã¢èŒžéå±€ãïŒâŠâŠæå å±€ãïŒâŠâŠäžé
å±€ãïŒâŠâŠãã€ãªã¢èŒžéç©è³ªãå«æããå±€ãïŒâŠ
âŠãã€ãªã¢çºçç©è³ªã
械çæ§æäŸã«ã€ããŠç€ºãæé¢å³ã§ãã€ãŠå³äžã®ïŒ
ãïŒã¯ãããã以äžã®äºãè¡šãã ïŒâŠâŠå°é»æ¯æäœãïŒâŠâŠãã€ãªã¢çºçå±€ãïŒ
âŠâŠãã€ãªã¢èŒžéå±€ãïŒâŠâŠæå å±€ãïŒâŠâŠäžé
å±€ãïŒâŠâŠãã€ãªã¢èŒžéç©è³ªãå«æããå±€ãïŒâŠ
âŠãã€ãªã¢çºçç©è³ªã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ å°é»æ§æ¯æäœäžã«äžèšäžè¬åŒããã§è¡šãã
ãã¢ãŸååç©ãå«æããæå å±€ãæããããšãç¹
城ãšããæå äœã äžè¬åŒãã ãåŒäžY1åã³Y2ã¯ããããæ°ŽçŽ ååãããã²
ã³ååãã¢ã«ãã«åºãã¢ã«ã³ãã·åºåã¯ãããã
ã·åºãè¡šãã ã¯ããåŒããåŒã ãåŒããåŒã ãåŒã ãåŒã ãåŒããåŒãå㯠ãåŒãã§ãã€ãŠãQ1ïŒQ2ïŒQ3ïŒ Q4ïŒQ5åã³Q6ã¯ããåŒã ãåŒã ãåŒã ãåŒã ãåŒã ãåŒã ãåŒã ãåŒã R11ïŒR12ïŒR13ïŒR14ïŒR15ïŒR16ïŒR17ïŒR18åã³
R19ã¯ãæ°ŽçŽ ååãã¢ã«ãã«åºãã¢ã«ã³ãã·åºã
ããã²ã³ååãã·ã¢ãåºããšã¹ãã«åºãã¢ã·ã«
åºããžã¢ã«ãã«ã¢ããåºããžã¢ã©ã«ãã«ã¢ãã
åºããžã¢ãªãŒã«ã¢ããåºãåã¯ããããã·åºãè¡š
ãããã ããn1ïŒn4åã³n7ã¯ãïŒãïŒã®æŽæ°ãè¡š
ããn1ïŒn4ãåã³ïœãïŒä»¥äžã®ãšãã¯ãR11ïŒ
R14ãåã³R17ã¯ãããããç°ãªã眮æåºã§ãã
ãŸããªãããŸããn2ïŒn3ïŒn5ïŒn6ïŒn8ããã³n9
ã¯ãïŒãïŒã®æŽæ°ãè¡šããn2ïŒn3ïŒn5ïŒn6ïŒn8ã
ãã³n9ãïŒä»¥äžã®ãšãã¯ãR12ïŒR13ïŒR15ïŒR16ïŒ
R18ãåã³R19ã¯ãããããåãã§ãç°ãªã€ãŠã
ãŠãããã R21ãR22åã³R23ã¯ãæ°ŽçŽ ååãã¢ã«ãã«åºå
ã¯ã¢ãªãŒã«åºãè¡šãã Q8ã¯ããåŒããè¡šããR31ã¯ã æ°ŽçŽ ååãã¢ã«ãã«åºãã¢ã«ã³ãã·åºãããã²ã³
ååãã·ã¢ãåºããšã¹ãã«åºãã¢ã·ã«åºããžã¢ã«
ãã«ã¢ããåºããžã¢ã©ã«ãã«ã¢ããåºããžã¢ãªãŒ
ã«ã¢ããåºåã¯ããããã·åºãè¡šãããã ãã
n11ã¯ãïŒãïŒã®æŽæ°ãè¡šããn11ãïŒä»¥äžã®ãšã
ã¯ãR31ã¯ç°ãªã眮æåºã§ãããŸããªãã R1ã¯ãæ°ŽçŽ ååãã¢ã«ãã«åºãã¢ããåºããž
ã¢ã«ãã«ã¢ããåºããžã¢ãªãŒã«ã¢ããåºããžã¢ã©
ã«ãã«ã¢ããåºãã«ã«ãã¢ã€ã«åºãã«ã«ããã·ã«
åºãããã¯ãã®ãšã¹ãã«åºãŸãã¯ã·ã¢ãåºãè¡š
ãã R2åã³R3ã¯ãã¢ã«ãã«åºãã¢ã©ã«ãã«åºãå
ã¯ãåŒããè¡šããR41ã¯ãæ°ŽçŽ å åãã¢ã«ãã«åºãã¢ã«ã³ãã·åºãããã²ã³ååã
ã·ã¢ãåºããšã¹ãã«åºãã¢ã·ã«åºããžã¢ã«ãã«ã¢
ããåºããžã¢ã©ã«ãã«ã¢ããåºããžã¢ãªãŒã«ã¢ã
ãåºãåã¯ããããã·åºãè¡šãããã ããn21ã¯ã
ïŒãïŒã®æŽæ°ãè¡šããn21ãïŒä»¥äžã®ãšãã¯ãR41
ã¯ç°ãªã眮æåºã§ãããŸããªããã ïŒ åèšæå å±€ããã€ãªã¢èŒžéç©è³ªãšãã€ãªã¢çº
çç©è³ªãšãå«æãã該ãã€ãªã¢çºçç©è³ªãåèšäž
è¬åŒããã§è¡šãããã¢ãŸååç©ã§ããç¹èš±è«æ±
ã®ç¯å²ç¬¬ïŒé èšèŒã®æå äœã ïŒ åèšæå å±€ããã€ãªã¢çºçç©è³ªãå«æããã
ã€ãªã¢çºçå±€ãšããã€ãªã¢èŒžéç©è³ªãå«æããã
ã€ãªã¢èŒžéå±€ãšã®ç©å±€äœã§æ§æãããŠããç¹èš±è«
æ±ã®ç¯å²ç¬¬ïŒé åã¯ç¬¬ïŒé èšèŒã®æå äœã
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10233385A JPS61259258A (ja) | 1985-05-13 | 1985-05-13 | æå äœ |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10233385A JPS61259258A (ja) | 1985-05-13 | 1985-05-13 | æå äœ |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS61259258A JPS61259258A (ja) | 1986-11-17 |
JPH0415469B2 true JPH0415469B2 (ja) | 1992-03-18 |
Family
ID=14324588
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP10233385A Granted JPS61259258A (ja) | 1985-05-13 | 1985-05-13 | æå äœ |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS61259258A (ja) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4994672B2 (ja) * | 2006-01-27 | 2012-08-08 | æ°æ¥éµååŠæ ªåŒäŒç€Ÿ | è³éŠæããªã¢ããé žåã³è³éŠæããªã€ãã |
-
1985
- 1985-05-13 JP JP10233385A patent/JPS61259258A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS61259258A (ja) | 1986-11-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPH026050B2 (ja) | ||
JPH0251502B2 (ja) | ||
JPH0210413B2 (ja) | ||
JPH0272372A (ja) | é»ååçæå äœ | |
JPH0415469B2 (ja) | ||
JPH037943B2 (ja) | ||
JPH0251503B2 (ja) | ||
JPS60197764A (ja) | æå äœ | |
JPH0220974B2 (ja) | ||
JPH0331256B2 (ja) | ||
JPH037942B2 (ja) | ||
JPS6135548B2 (ja) | ||
JPH0414343B2 (ja) | ||
JP2652679B2 (ja) | æå äœ | |
JPH0220972B2 (ja) | ||
JPH0220977B2 (ja) | ||
JPH0415467B2 (ja) | ||
JPH037941B2 (ja) | ||
JPH01230059A (ja) | æå äœ | |
JPH0220973B2 (ja) | ||
JPH0220976B2 (ja) | ||
JPH0210412B2 (ja) | ||
JPH0220979B2 (ja) | ||
JPH037940B2 (ja) | ||
JPH0220975B2 (ja) |