JPH038358B2 - - Google Patents

Info

Publication number
JPH038358B2
JPH038358B2 JP1042033A JP4203389A JPH038358B2 JP H038358 B2 JPH038358 B2 JP H038358B2 JP 1042033 A JP1042033 A JP 1042033A JP 4203389 A JP4203389 A JP 4203389A JP H038358 B2 JPH038358 B2 JP H038358B2
Authority
JP
Japan
Prior art keywords
solution
phosphine
catalysts
added
mmol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP1042033A
Other languages
English (en)
Japanese (ja)
Other versions
JPH02183A (ja
Inventor
Chaaruzu Kurisutopufueru Uiriamu
Sutandeitsushu Noruzu Uiriamu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of JPH02183A publication Critical patent/JPH02183A/ja
Publication of JPH038358B2 publication Critical patent/JPH038358B2/ja
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C07F15/008—Rhodium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5004—Acyclic saturated phosphines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5022—Aromatic phosphines (P-C aromatic linkage)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
    • C07F9/5304—Acyclic saturated phosphine oxides or thioxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
    • C07F9/5325—Aromatic phosphine oxides or thioxides (P-C aromatic linkage)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6527—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07F9/6533—Six-membered rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP1042033A 1980-12-05 1989-02-23 光学活性ホスフィン化合物 Granted JPH02183A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/213,272 US4376870A (en) 1980-12-05 1980-12-05 Optically active phosphine compounds
US213272 1980-12-05

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
JP56194664A Division JPS57120596A (en) 1980-12-05 1981-12-04 Catalytic asymmetric hydrogenation

Publications (2)

Publication Number Publication Date
JPH02183A JPH02183A (ja) 1990-01-05
JPH038358B2 true JPH038358B2 (cs) 1991-02-05

Family

ID=22794423

Family Applications (4)

Application Number Title Priority Date Filing Date
JP56194664A Granted JPS57120596A (en) 1980-12-05 1981-12-04 Catalytic asymmetric hydrogenation
JP1042033A Granted JPH02183A (ja) 1980-12-05 1989-02-23 光学活性ホスフィン化合物
JP1042032A Granted JPH02190A (ja) 1980-12-05 1989-02-23 光学活性ホスフィン化合物
JP2225473A Granted JPH04159288A (ja) 1980-12-05 1990-08-29 光学活性ホスフィン化合物

Family Applications Before (1)

Application Number Title Priority Date Filing Date
JP56194664A Granted JPS57120596A (en) 1980-12-05 1981-12-04 Catalytic asymmetric hydrogenation

Family Applications After (2)

Application Number Title Priority Date Filing Date
JP1042032A Granted JPH02190A (ja) 1980-12-05 1989-02-23 光学活性ホスフィン化合物
JP2225473A Granted JPH04159288A (ja) 1980-12-05 1990-08-29 光学活性ホスフィン化合物

Country Status (6)

Country Link
US (1) US4376870A (cs)
JP (4) JPS57120596A (cs)
CA (1) CA1162542A (cs)
DE (2) DE3153690C2 (cs)
FR (3) FR2497204A1 (cs)
GB (1) GB2089349B (cs)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4668809A (en) * 1982-05-03 1987-05-26 Exxon Research And Engineering Transition metal complex catalysts
US4595753A (en) * 1982-05-03 1986-06-17 Exxon Research And Engineering Co. Heterocycle-substituted alkyl diaryl phosphine rhodium caronyl hydride complex hydroformylation catalyst compositions
JPS59157094A (ja) * 1983-02-28 1984-09-06 Takasago Corp ２，２′−ビス（ジフエニルホスフイノ）−１，１′−ビナフチルジオキサイドのラセミ体を光学分割する方法
FR2550202B1 (fr) * 1983-08-03 1986-03-21 Rhone Poulenc Rech Procede de preparation de tri(m-sulfophenyl) phosphine
US4556720A (en) * 1983-10-12 1985-12-03 Minnesota Mining And Manufacturing Company Fluorochemical rhodium compounds
US4625069A (en) * 1983-10-12 1986-11-25 Minnesota Mining And Manufacturing Fluorochemical rhodium compounds
US8471067B2 (en) * 2004-06-01 2013-06-25 University College Dublin Chiral phosphorus compounds
CN100434368C (zh) * 2004-06-16 2008-11-19 耿建平 纳米净水器
JP4904413B2 (ja) 2010-04-26 2012-03-28 古河電気工業株式会社 半導体レーザ素子および半導体レーザ素子の製造方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3849480A (en) * 1968-09-09 1974-11-19 Monsanto Co Catalytic asymmetric hydrogenation
NL155004B (nl) 1970-05-11 1977-11-15 Monsanto Co Werkwijze voor het asymmetrisch hydrogeneren van een eventieel beta-gesubstitueerd alfa-acylaminoacrylzuur en/of een zout daarvan, alsmede werkwijze voor de bereiding van een katalysatoroplossing.
US4008280A (en) * 1970-12-29 1977-02-15 Mitsubishi Petrochemical Company Limited Process for production of acrolein
NL7202928A (cs) * 1971-03-08 1972-09-12
US4294989A (en) * 1971-03-08 1981-10-13 Monsanto Company Methylcyclohexyl-O-anisylphosphine
FR2230654B1 (cs) * 1973-05-21 1975-11-21 Rhone Poulenc Ind
US4008281A (en) * 1973-12-03 1977-02-15 Monsanto Company Asymmetric catalysis
US4119652A (en) * 1974-08-29 1978-10-10 Monsanto Company Catalytic asymmetric hydrogenation
US4166824A (en) * 1977-06-14 1979-09-04 American Cyanamid Company Chiral rhodium-diphosphine catalyst capable of catalytic reduction of a tetramisole precursor to give a significant excess of the desired S-(-)isomer, levamisole
US4201714A (en) * 1977-08-19 1980-05-06 Celanese Corporation Stabilized catalyst complex of rhodium metal, bidentate ligand and monodentate ligand

Also Published As

Publication number Publication date
JPH039118B2 (cs) 1991-02-07
JPH02190A (ja) 1990-01-05
CA1162542A (en) 1984-02-21
JPH02183A (ja) 1990-01-05
FR2510562A1 (fr) 1983-02-04
FR2497204B1 (cs) 1984-04-13
JPH0476996B2 (cs) 1992-12-07
DE3148098A1 (de) 1982-07-08
JPH029598B2 (cs) 1990-03-02
GB2089349A (en) 1982-06-23
JPH04159288A (ja) 1992-06-02
FR2510562B1 (cs) 1984-04-06
GB2089349B (en) 1985-02-27
DE3153690C2 (cs) 1991-08-08
FR2497204A1 (fr) 1982-07-02
FR2510579B1 (cs) 1984-04-13
JPS57120596A (en) 1982-07-27
DE3148098C2 (cs) 1991-05-16
US4376870A (en) 1983-03-15
FR2510579A1 (fr) 1983-02-04

Similar Documents

Publication Publication Date Title
HU217368B (hu) Királis 2,5-dialkil- foszfolánok, előállításuk és a vegyületeket ligandumként tartalmazó enantioszelektív hidrogénezőkatalizátorok
JPH038358B2 (cs)
Van de Weghe et al. Synthesis of a new asymmetric cyclopentadienyl ligand: application to the preparation of a trivalent samarium complex
CN113896674B (zh) 一种阿普斯特的合成方法
CN113402553B (zh) 一种2-烷基-吲哚骨架的膦配体及其制备方法和应用
CN108558927B (zh) 一种硅立体中心手性化合物及其合成方法
CN113549062A (zh) 一种金鸡纳碱衍生的大位阻手性季铵盐相转移催化剂及其合成方法
US6288279B1 (en) 6′,6-bis-(1-phosphanorbornadiene) diphosphines
CN101676293B (zh) 一种联咪唑有机膦化合物及其制备方法
JPH08245664A (ja) 光学活性非対称ジホスフィン及び該化合物の存在下にて光学活性体を得る方法
US7094725B2 (en) Biphenyldiphosphine compounds
CN115819258A (zh) 一种利用含膦氧双键催化剂的西格列汀中间体的制备方法
CN115108937A (zh) 含三级立体中心的α-叠氮酮的合成方法
JP5407332B2 (ja) クォータピリジン誘導体の製造方法及びその中間体
CN109251227B (zh) 一类包含二茂铁骨架和刚性螺环结构的手性化合物及合成与应用
US4565892A (en) Process for the preparation of bisphosphine dioxides
US4464306A (en) Coordination complexes of optically active phosphine compounds
EP1389174A1 (en) Preparation and use of diols
CN114630712A (zh) 新型过渡金属催化剂
JP2855221B2 (ja) 光学活性３，４―ビスホスフィノピロリジン化合物
US5849961A (en) Optically active 1,1'-biphenanthryl-2,2'-diol, process for preparing the same, and resolving reagent comprising the same
CN108264526A (zh) 一类o,o,n配位三价双环磷化物、合成方法及其催化应用
JP4282788B2 (ja) 新規なジフェニルアルシン類
CN117903195A (zh) 一种制备（2-氧代-2-芳基乙基）（苯基）膦酸烷基酯类化合物的方法
CN118637983A (zh) 一种手性顺式邻二醇的制备方法