JPH0352425B2 - - Google Patents
Info
- Publication number
- JPH0352425B2 JPH0352425B2 JP58035990A JP3599083A JPH0352425B2 JP H0352425 B2 JPH0352425 B2 JP H0352425B2 JP 58035990 A JP58035990 A JP 58035990A JP 3599083 A JP3599083 A JP 3599083A JP H0352425 B2 JPH0352425 B2 JP H0352425B2
- Authority
- JP
- Japan
- Prior art keywords
- sintered body
- ceo
- zro
- tetragonal
- sintered
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 24
- 239000013078 crystal Substances 0.000 claims description 20
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 238000001308 synthesis method Methods 0.000 claims description 4
- 239000011812 mixed powder Substances 0.000 claims description 2
- 238000005245 sintering Methods 0.000 claims 1
- 239000000843 powder Substances 0.000 description 18
- 239000002994 raw material Substances 0.000 description 13
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 7
- 229910002077 partially stabilized zirconia Inorganic materials 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 239000003381 stabilizer Substances 0.000 description 7
- 238000005259 measurement Methods 0.000 description 6
- 238000007373 indentation Methods 0.000 description 5
- CMOAHYOGLLEOGO-UHFFFAOYSA-N oxozirconium;dihydrochloride Chemical compound Cl.Cl.[Zr]=O CMOAHYOGLLEOGO-UHFFFAOYSA-N 0.000 description 5
- 150000000703 Cerium Chemical class 0.000 description 4
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000011259 mixed solution Substances 0.000 description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- 229910052684 Cerium Inorganic materials 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- 238000005452 bending Methods 0.000 description 3
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 3
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 3
- 238000010304 firing Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000013001 point bending Methods 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- 150000003754 zirconium Chemical class 0.000 description 3
- NGDQQLAVJWUYSF-UHFFFAOYSA-N 4-methyl-2-phenyl-1,3-thiazole-5-sulfonyl chloride Chemical compound S1C(S(Cl)(=O)=O)=C(C)N=C1C1=CC=CC=C1 NGDQQLAVJWUYSF-UHFFFAOYSA-N 0.000 description 2
- 229910052772 Samarium Inorganic materials 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 150000001785 cerium compounds Chemical class 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 2
- 230000036961 partial effect Effects 0.000 description 2
- 229910052761 rare earth metal Inorganic materials 0.000 description 2
- 150000002910 rare earth metals Chemical class 0.000 description 2
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 150000003755 zirconium compounds Chemical class 0.000 description 2
- OERNJTNJEZOPIA-UHFFFAOYSA-N zirconium nitrate Chemical compound [Zr+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O OERNJTNJEZOPIA-UHFFFAOYSA-N 0.000 description 2
- 229910021193 La 2 O 3 Inorganic materials 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- -1 etc. Inorganic materials 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000012770 industrial material Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910002076 stabilized zirconia Inorganic materials 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
- C04B35/486—Fine ceramics
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Composite Materials (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58035990A JPS59162173A (ja) | 1983-03-07 | 1983-03-07 | ジルコニア焼結体 |
DE19843408096 DE3408096A1 (de) | 1983-03-07 | 1984-03-05 | Zirkoniumdioxidsinterprodukt und verfahren zu seiner herstellung |
AU25314/84A AU567328B2 (en) | 1983-03-07 | 1984-03-06 | Zirconia-cerium oxide ceramic |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58035990A JPS59162173A (ja) | 1983-03-07 | 1983-03-07 | ジルコニア焼結体 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS59162173A JPS59162173A (ja) | 1984-09-13 |
JPH0352425B2 true JPH0352425B2 (fi) | 1991-08-09 |
Family
ID=12457279
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP58035990A Granted JPS59162173A (ja) | 1983-03-07 | 1983-03-07 | ジルコニア焼結体 |
Country Status (3)
Country | Link |
---|---|
JP (1) | JPS59162173A (fi) |
AU (1) | AU567328B2 (fi) |
DE (1) | DE3408096A1 (fi) |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60108367A (ja) * | 1983-11-16 | 1985-06-13 | 日立化成工業株式会社 | ジルコニア質焼結体 |
JPS60137870A (ja) * | 1983-12-26 | 1985-07-22 | 日立化成工業株式会社 | ジルコニア焼結体 |
JPS60141671A (ja) * | 1983-12-27 | 1985-07-26 | 日立化成工業株式会社 | ジルコニア焼結体の製造方法 |
JPS6177665A (ja) * | 1984-09-22 | 1986-04-21 | 株式会社ノリタケカンパニーリミテド | 高靭性ジルコニア焼結体 |
JPH0764631B2 (ja) * | 1985-03-22 | 1995-07-12 | 株式会社ノリタケカンパニ−リミテド | 耐熱水安定性に優れた高靭性ジルコニア焼結体 |
JPH0710746B2 (ja) * | 1985-07-08 | 1995-02-08 | 株式会社ノリタケカンパニーリミテド | 高靭性ジルコニア質焼結体 |
JPS61291458A (ja) * | 1985-06-20 | 1986-12-22 | 東ソー株式会社 | ジルコニア焼結体およびその製造法 |
JPH0818164B1 (fi) * | 1985-09-27 | 1996-02-28 | ||
GB8524140D0 (en) * | 1985-10-01 | 1985-11-06 | Tioxide Group Plc | Stabilised metallic oxides |
DE3608854A1 (de) * | 1986-03-17 | 1987-09-24 | Leitz Ernst Gmbh | Verwendung eines oxidkeramik-werkstoffs fuer presswerkzeuge zum ausformen von bauteilen aus glas oder einer glashaltigen keramik hoher oberflaechenguete und massgenauigkeit |
JPS63139050A (ja) * | 1986-11-28 | 1988-06-10 | 住友化学工業株式会社 | ジルコニア質セラミツクス |
GB8709515D0 (en) * | 1987-04-22 | 1987-05-28 | Tioxide Group Plc | Stabilised metallic oxides |
GB2206111B (en) * | 1987-06-24 | 1991-08-14 | Council Scient Ind Res | Sintered ceramic product |
EP0328041B1 (en) * | 1988-02-08 | 1994-09-07 | Mitsubishi Chemical Corporation | Ceramic implant and process for its production |
JPH0672049B2 (ja) * | 1990-10-05 | 1994-09-14 | 株式会社東芝 | ボンディングキャピラリおよび光コネクタ用部品 |
GB9123280D0 (en) * | 1991-11-02 | 1991-12-18 | Tioxide Group Services Ltd | Metallic oxides |
DE4237272A1 (de) * | 1992-11-04 | 1994-05-05 | Nukem Gmbh | Verfahren zur Herstellung von stabilisiertem Hafniumoxidpulver oder Hafniumoxid enthaltendem Pulver |
FR2699524B1 (fr) * | 1992-12-21 | 1995-02-10 | Rhone Poulenc Chimie | Composition à base d'un oxyde mixte de cérium et de zirconium, préparation et utilisation. |
FR2701472B1 (fr) * | 1993-02-10 | 1995-05-24 | Rhone Poulenc Chimie | Procédé de préparation de compositions à base d'oxydes mixtes de zirconium et de cérium. |
FR2701471B1 (fr) * | 1993-02-10 | 1995-05-24 | Rhone Poulenc Chimie | Procédé de synthèse de compositions à base d'oxydes mixtes de zirconium et de cérium, compositions ainsi obtenues et utilisations de ces dernières. |
JPH06219831A (ja) * | 1993-04-05 | 1994-08-09 | Noritake Co Ltd | 高靱性ジルコニア質焼結体 |
FR2714370B1 (fr) * | 1993-12-24 | 1996-03-08 | Rhone Poulenc Chimie | Précurseur d'une composition et composition à base d'un oxyde mixte de cérium et de zirconium, procédé de préparation et utilisation. |
JP2774782B2 (ja) * | 1995-09-21 | 1998-07-09 | 株式会社東芝 | 光コネクタ用部品 |
FR2882749B1 (fr) * | 2005-03-01 | 2007-04-27 | Saint Gobain Ct Recherches | Bille frittee a base de zircone et d'oxyde de cerium |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3514252A (en) * | 1967-07-07 | 1970-05-26 | Grace W R & Co | Process for the preparation of stabilized zirconia powders |
US4316969A (en) * | 1979-07-02 | 1982-02-23 | Nippon Kynol Incorporated | Cured novolak fiber-reinforced, chlorinated rubber molded articles having excellent flame-proofness, and process for the preparation thereof |
US4360598A (en) * | 1980-03-26 | 1982-11-23 | Ngk Insulators, Ltd. | Zirconia ceramics and a method of producing the same |
JPS601827B2 (ja) * | 1980-03-31 | 1985-01-17 | 工業技術院長 | Mhd発電機用材料 |
-
1983
- 1983-03-07 JP JP58035990A patent/JPS59162173A/ja active Granted
-
1984
- 1984-03-05 DE DE19843408096 patent/DE3408096A1/de not_active Ceased
- 1984-03-06 AU AU25314/84A patent/AU567328B2/en not_active Ceased
Also Published As
Publication number | Publication date |
---|---|
DE3408096A1 (de) | 1984-10-04 |
AU2531484A (en) | 1984-09-13 |
JPS59162173A (ja) | 1984-09-13 |
AU567328B2 (en) | 1987-11-19 |
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