JPH0251498B2 - - Google Patents
Info
- Publication number
- JPH0251498B2 JPH0251498B2 JP58043860A JP4386083A JPH0251498B2 JP H0251498 B2 JPH0251498 B2 JP H0251498B2 JP 58043860 A JP58043860 A JP 58043860A JP 4386083 A JP4386083 A JP 4386083A JP H0251498 B2 JPH0251498 B2 JP H0251498B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- dye
- silver
- acid
- groups
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 silver halide Chemical class 0.000 claims description 100
- 239000000126 substance Substances 0.000 claims description 61
- 239000000463 material Substances 0.000 claims description 60
- 229910052709 silver Inorganic materials 0.000 claims description 55
- 239000004332 silver Substances 0.000 claims description 55
- 125000000217 alkyl group Chemical group 0.000 claims description 38
- 239000002243 precursor Substances 0.000 claims description 30
- 125000003118 aryl group Chemical group 0.000 claims description 25
- 238000010438 heat treatment Methods 0.000 claims description 21
- 239000011230 binding agent Substances 0.000 claims description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 12
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 11
- 125000000623 heterocyclic group Chemical group 0.000 claims description 11
- 125000002252 acyl group Chemical group 0.000 claims description 9
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 9
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 7
- 125000003342 alkenyl group Chemical group 0.000 claims description 4
- 125000001841 imino group Chemical group [H]N=* 0.000 claims description 4
- 125000003107 substituted aryl group Chemical group 0.000 claims description 4
- 239000000975 dye Substances 0.000 description 105
- 239000010410 layer Substances 0.000 description 53
- 230000015572 biosynthetic process Effects 0.000 description 52
- 238000003786 synthesis reaction Methods 0.000 description 52
- 150000003378 silver Chemical class 0.000 description 43
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 39
- 239000002585 base Substances 0.000 description 38
- 238000000034 method Methods 0.000 description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 35
- 229910001868 water Inorganic materials 0.000 description 35
- 239000000243 solution Substances 0.000 description 34
- 150000001875 compounds Chemical class 0.000 description 32
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 30
- 238000006243 chemical reaction Methods 0.000 description 25
- 239000013078 crystal Substances 0.000 description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 24
- 239000000203 mixture Substances 0.000 description 24
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 23
- 108010010803 Gelatin Proteins 0.000 description 22
- 229920000159 gelatin Polymers 0.000 description 22
- 235000019322 gelatine Nutrition 0.000 description 22
- 235000011852 gelatine desserts Nutrition 0.000 description 22
- 239000008273 gelatin Substances 0.000 description 21
- 239000000758 substrate Substances 0.000 description 21
- 239000007800 oxidant agent Substances 0.000 description 19
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 18
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 17
- 239000000839 emulsion Substances 0.000 description 17
- 238000011161 development Methods 0.000 description 16
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 15
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 15
- 229920000642 polymer Polymers 0.000 description 15
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 14
- 125000005843 halogen group Chemical group 0.000 description 14
- 125000003545 alkoxy group Chemical group 0.000 description 13
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 12
- 238000000576 coating method Methods 0.000 description 12
- 239000006185 dispersion Substances 0.000 description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 11
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 11
- 125000004432 carbon atom Chemical group C* 0.000 description 11
- 125000001424 substituent group Chemical group 0.000 description 11
- 125000004442 acylamino group Chemical group 0.000 description 10
- 125000003277 amino group Chemical group 0.000 description 10
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- 238000003756 stirring Methods 0.000 description 10
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 9
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- 239000002202 Polyethylene glycol Substances 0.000 description 9
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 9
- 239000002253 acid Substances 0.000 description 9
- 238000009835 boiling Methods 0.000 description 9
- 239000003638 chemical reducing agent Substances 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 9
- 239000005457 ice water Substances 0.000 description 9
- 229920001223 polyethylene glycol Polymers 0.000 description 9
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 8
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 8
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 8
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 8
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 8
- 239000004094 surface-active agent Substances 0.000 description 8
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 7
- 229910021612 Silver iodide Inorganic materials 0.000 description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 7
- 125000004414 alkyl thio group Chemical group 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 7
- 239000003960 organic solvent Substances 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- 238000011160 research Methods 0.000 description 7
- 229940045105 silver iodide Drugs 0.000 description 7
- 238000012546 transfer Methods 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- WTDHULULXKLSOZ-UHFFFAOYSA-N Hydroxylamine hydrochloride Chemical compound Cl.ON WTDHULULXKLSOZ-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 125000004093 cyano group Chemical group *C#N 0.000 description 6
- 230000007062 hydrolysis Effects 0.000 description 6
- 238000006460 hydrolysis reaction Methods 0.000 description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 6
- 239000002736 nonionic surfactant Substances 0.000 description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 6
- 239000000049 pigment Substances 0.000 description 6
- 230000001235 sensitizing effect Effects 0.000 description 6
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 5
- IBWXIFXUDGADCV-UHFFFAOYSA-N 2h-benzotriazole;silver Chemical compound [Ag].C1=CC=C2NN=NC2=C1 IBWXIFXUDGADCV-UHFFFAOYSA-N 0.000 description 5
- 230000002378 acidificating effect Effects 0.000 description 5
- 125000005110 aryl thio group Chemical group 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 125000004657 aryl sulfonyl amino group Chemical group 0.000 description 4
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 4
- 125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 239000000084 colloidal system Substances 0.000 description 4
- 150000002430 hydrocarbons Chemical group 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- DWLVWMUCHSLGSU-UHFFFAOYSA-M n,n-dimethylcarbamate Chemical compound CN(C)C([O-])=O DWLVWMUCHSLGSU-UHFFFAOYSA-M 0.000 description 4
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
- 238000006479 redox reaction Methods 0.000 description 4
- HBROZNQEVUILML-UHFFFAOYSA-N salicylhydroxamic acid Chemical compound ONC(=O)C1=CC=CC=C1O HBROZNQEVUILML-UHFFFAOYSA-N 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 4
- 235000010215 titanium dioxide Nutrition 0.000 description 4
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 description 4
- MOCMBTHPKMYRRK-UHFFFAOYSA-N 2-amino-4-tert-butyl-5-hexadecoxyphenol;hydrochloride Chemical compound Cl.CCCCCCCCCCCCCCCCOC1=CC(O)=C(N)C=C1C(C)(C)C MOCMBTHPKMYRRK-UHFFFAOYSA-N 0.000 description 3
- RZKJWYDRDBVDJJ-UHFFFAOYSA-N 2-methyl-1,3-benzoxazol-6-ol Chemical compound C1=C(O)C=C2OC(C)=NC2=C1 RZKJWYDRDBVDJJ-UHFFFAOYSA-N 0.000 description 3
- BSKHPKMHTQYZBB-UHFFFAOYSA-N 2-methylpyridine Chemical compound CC1=CC=CC=N1 BSKHPKMHTQYZBB-UHFFFAOYSA-N 0.000 description 3
- RHTIMXFFOVWNLX-UHFFFAOYSA-N 5-bromo-n,2-dihydroxybenzamide Chemical compound ONC(=O)C1=CC(Br)=CC=C1O RHTIMXFFOVWNLX-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 3
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 3
- 241001061127 Thione Species 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 3
- HOLVRJRSWZOAJU-UHFFFAOYSA-N [Ag].ICl Chemical compound [Ag].ICl HOLVRJRSWZOAJU-UHFFFAOYSA-N 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 3
- 125000004656 alkyl sulfonylamino group Chemical group 0.000 description 3
- 125000004104 aryloxy group Chemical group 0.000 description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical class C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 3
- 239000012964 benzotriazole Substances 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- HPNKKTVEGUKEEG-UHFFFAOYSA-N n-(4-hexadecoxy-2-hydroxyphenyl)acetamide Chemical compound CCCCCCCCCCCCCCCCOC1=CC=C(NC(C)=O)C(O)=C1 HPNKKTVEGUKEEG-UHFFFAOYSA-N 0.000 description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 150000002923 oximes Chemical class 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 3
- 229910001961 silver nitrate Inorganic materials 0.000 description 3
- 239000001632 sodium acetate Substances 0.000 description 3
- 235000017281 sodium acetate Nutrition 0.000 description 3
- 235000011121 sodium hydroxide Nutrition 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- HUWSZNZAROKDRZ-RRLWZMAJSA-N (3r,4r)-3-azaniumyl-5-[[(2s,3r)-1-[(2s)-2,3-dicarboxypyrrolidin-1-yl]-3-methyl-1-oxopentan-2-yl]amino]-5-oxo-4-sulfanylpentane-1-sulfonate Chemical compound OS(=O)(=O)CC[C@@H](N)[C@@H](S)C(=O)N[C@@H]([C@H](C)CC)C(=O)N1CCC(C(O)=O)[C@H]1C(O)=O HUWSZNZAROKDRZ-RRLWZMAJSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical compound C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 description 2
- HNTGIJLWHDPAFN-UHFFFAOYSA-N 1-bromohexadecane Chemical compound CCCCCCCCCCCCCCCCBr HNTGIJLWHDPAFN-UHFFFAOYSA-N 0.000 description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- SULYEHHGGXARJS-UHFFFAOYSA-N 2',4'-dihydroxyacetophenone Chemical compound CC(=O)C1=CC=C(O)C=C1O SULYEHHGGXARJS-UHFFFAOYSA-N 0.000 description 2
- ATCRIUVQKHMXSH-UHFFFAOYSA-N 2,4-dichlorobenzoic acid Chemical compound OC(=O)C1=CC=C(Cl)C=C1Cl ATCRIUVQKHMXSH-UHFFFAOYSA-N 0.000 description 2
- OISVCGZHLKNMSJ-UHFFFAOYSA-N 2,6-dimethylpyridine Chemical compound CC1=CC=CC(C)=N1 OISVCGZHLKNMSJ-UHFFFAOYSA-N 0.000 description 2
- NEAQRZUHTPSBBM-UHFFFAOYSA-N 2-hydroxy-3,3-dimethyl-7-nitro-4h-isoquinolin-1-one Chemical compound C1=C([N+]([O-])=O)C=C2C(=O)N(O)C(C)(C)CC2=C1 NEAQRZUHTPSBBM-UHFFFAOYSA-N 0.000 description 2
- XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 2
- LAQYHRQFABOIFD-UHFFFAOYSA-N 2-methoxyhydroquinone Chemical compound COC1=CC(O)=CC=C1O LAQYHRQFABOIFD-UHFFFAOYSA-N 0.000 description 2
- DQSHFKPKFISSNM-UHFFFAOYSA-N 2-methylbenzoxazole Chemical compound C1=CC=C2OC(C)=NC2=C1 DQSHFKPKFISSNM-UHFFFAOYSA-N 0.000 description 2
- VYNUATGQEAAPAQ-UHFFFAOYSA-N 2-sulfonylacetic acid Chemical compound OC(=O)C=S(=O)=O VYNUATGQEAAPAQ-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- UYEMGAFJOZZIFP-UHFFFAOYSA-N 3,5-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC(O)=CC(O)=C1 UYEMGAFJOZZIFP-UHFFFAOYSA-N 0.000 description 2
- WQVIJCIUQDVDHJ-UHFFFAOYSA-N 5-amino-n-(5-tert-butyl-4-hexadecoxy-2-hydroxyphenyl)-2-(2-methoxyethoxy)benzenesulfonamide Chemical compound C1=C(C(C)(C)C)C(OCCCCCCCCCCCCCCCC)=CC(O)=C1NS(=O)(=O)C1=CC(N)=CC=C1OCCOC WQVIJCIUQDVDHJ-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical class C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 229910015900 BF3 Inorganic materials 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical class CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- JGFZNNIVVJXRND-UHFFFAOYSA-N N,N-Diisopropylethylamine (DIPEA) Chemical compound CCN(C(C)C)C(C)C JGFZNNIVVJXRND-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- 206010070834 Sensitisation Diseases 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical class OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical class OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 2
- 125000004390 alkyl sulfonyl group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 125000004202 aminomethyl group Chemical group [H]N([H])C([H])([H])* 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 150000004982 aromatic amines Chemical class 0.000 description 2
- 125000005160 aryl oxy alkyl group Chemical group 0.000 description 2
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 2
- 150000001565 benzotriazoles Chemical class 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 150000001767 cationic compounds Chemical class 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical class CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical class CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical class OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical class CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 150000002460 imidazoles Chemical class 0.000 description 2
- 125000005462 imide group Chemical group 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N isopropyl alcohol Natural products CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- FBSFWRHWHYMIOG-UHFFFAOYSA-N methyl 3,4,5-trihydroxybenzoate Chemical compound COC(=O)C1=CC(O)=C(O)C(O)=C1 FBSFWRHWHYMIOG-UHFFFAOYSA-N 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- BOMDYWWCQBJGDU-UHFFFAOYSA-N n-(5-tert-butyl-4-hexadecoxy-2-hydroxyphenyl)acetamide Chemical compound CCCCCCCCCCCCCCCCOC1=CC(O)=C(NC(C)=O)C=C1C(C)(C)C BOMDYWWCQBJGDU-UHFFFAOYSA-N 0.000 description 2
- 125000001624 naphthyl group Chemical group 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 239000012038 nucleophile Substances 0.000 description 2
- 230000000269 nucleophilic effect Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical class CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 150000007530 organic bases Chemical class 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluic acid Chemical compound CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 description 2
- RZXMPPFPUUCRFN-UHFFFAOYSA-N p-toluidine Chemical compound CC1=CC=C(N)C=C1 RZXMPPFPUUCRFN-UHFFFAOYSA-N 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 description 2
- 235000011181 potassium carbonates Nutrition 0.000 description 2
- 235000011118 potassium hydroxide Nutrition 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical class OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical class OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 230000008313 sensitization Effects 0.000 description 2
- 238000010898 silica gel chromatography Methods 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 125000005504 styryl group Chemical group 0.000 description 2
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 description 2
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical class OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
- 125000003396 thiol group Chemical group [H]S* 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 229940066528 trichloroacetate Drugs 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- QNRQQUSFAXCSQM-UHFFFAOYSA-N (2-methylphenyl)methanol;hydrate Chemical compound O.CC1=CC=CC=C1CO QNRQQUSFAXCSQM-UHFFFAOYSA-N 0.000 description 1
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- LUMLZKVIXLWTCI-NSCUHMNNSA-N (e)-2,3-dichloro-4-oxobut-2-enoic acid Chemical compound OC(=O)C(\Cl)=C(/Cl)C=O LUMLZKVIXLWTCI-NSCUHMNNSA-N 0.000 description 1
- NMIRPMWNPFPQAX-UHFFFAOYSA-N 1,1'-biphenyl;octanedioic acid Chemical compound C1=CC=CC=C1C1=CC=CC=C1.OC(=O)CCCCCCC(O)=O NMIRPMWNPFPQAX-UHFFFAOYSA-N 0.000 description 1
- 150000000178 1,2,4-triazoles Chemical class 0.000 description 1
- XBYRMPXUBGMOJC-UHFFFAOYSA-N 1,2-dihydropyrazol-3-one Chemical class OC=1C=CNN=1 XBYRMPXUBGMOJC-UHFFFAOYSA-N 0.000 description 1
- 150000005206 1,2-dihydroxybenzenes Chemical class 0.000 description 1
- QUKGLNCXGVWCJX-UHFFFAOYSA-N 1,3,4-thiadiazol-2-amine Chemical compound NC1=NN=CS1 QUKGLNCXGVWCJX-UHFFFAOYSA-N 0.000 description 1
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
- ODIRBFFBCSTPTO-UHFFFAOYSA-N 1,3-selenazole Chemical class C1=C[se]C=N1 ODIRBFFBCSTPTO-UHFFFAOYSA-N 0.000 description 1
- YLVACWCCJCZITJ-UHFFFAOYSA-N 1,4-dioxane-2,3-diol Chemical compound OC1OCCOC1O YLVACWCCJCZITJ-UHFFFAOYSA-N 0.000 description 1
- SIQZJFKTROUNPI-UHFFFAOYSA-N 1-(hydroxymethyl)-5,5-dimethylhydantoin Chemical compound CC1(C)N(CO)C(=O)NC1=O SIQZJFKTROUNPI-UHFFFAOYSA-N 0.000 description 1
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 1
- FYBFGAFWCBMEDG-UHFFFAOYSA-N 1-[3,5-di(prop-2-enoyl)-1,3,5-triazinan-1-yl]prop-2-en-1-one Chemical compound C=CC(=O)N1CN(C(=O)C=C)CN(C(=O)C=C)C1 FYBFGAFWCBMEDG-UHFFFAOYSA-N 0.000 description 1
- YZUPZGFPHUVJKC-UHFFFAOYSA-N 1-bromo-2-methoxyethane Chemical compound COCCBr YZUPZGFPHUVJKC-UHFFFAOYSA-N 0.000 description 1
- WDRZVZVXHZNSFG-UHFFFAOYSA-N 1-ethenylpyridin-1-ium Chemical compound C=C[N+]1=CC=CC=C1 WDRZVZVXHZNSFG-UHFFFAOYSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- KPVMVJXYXFUVLR-UHFFFAOYSA-N 12-ethyltetradecan-1-amine Chemical compound CCC(CC)CCCCCCCCCCCN KPVMVJXYXFUVLR-UHFFFAOYSA-N 0.000 description 1
- KJUGUADJHNHALS-UHFFFAOYSA-N 1H-tetrazole Chemical class C=1N=NNN=1 KJUGUADJHNHALS-UHFFFAOYSA-N 0.000 description 1
- HAZJTCQWIDBCCE-UHFFFAOYSA-N 1h-triazine-6-thione Chemical compound SC1=CC=NN=N1 HAZJTCQWIDBCCE-UHFFFAOYSA-N 0.000 description 1
- LLCOQBODWBFTDD-UHFFFAOYSA-N 1h-triazol-1-ium-4-thiolate Chemical class SC1=CNN=N1 LLCOQBODWBFTDD-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- DBCKMJVEAUXWJJ-UHFFFAOYSA-N 2,3-dichlorobenzene-1,4-diol Chemical compound OC1=CC=C(O)C(Cl)=C1Cl DBCKMJVEAUXWJJ-UHFFFAOYSA-N 0.000 description 1
- SNTWKPAKVQFCCF-UHFFFAOYSA-N 2,3-dihydro-1h-triazole Chemical compound N1NC=CN1 SNTWKPAKVQFCCF-UHFFFAOYSA-N 0.000 description 1
- 150000001473 2,4-thiazolidinediones Chemical class 0.000 description 1
- GPASWZHHWPVSRG-UHFFFAOYSA-N 2,5-dimethylbenzene-1,4-diol Chemical compound CC1=CC(O)=C(C)C=C1O GPASWZHHWPVSRG-UHFFFAOYSA-N 0.000 description 1
- YKUDHBLDJYZZQS-UHFFFAOYSA-N 2,6-dichloro-1h-1,3,5-triazin-4-one Chemical compound OC1=NC(Cl)=NC(Cl)=N1 YKUDHBLDJYZZQS-UHFFFAOYSA-N 0.000 description 1
- ZUHJONSUZIRGOH-UHFFFAOYSA-N 2-(2-methoxyethoxy)-5-nitrobenzenesulfonyl chloride Chemical compound COCCOC1=CC=C([N+]([O-])=O)C=C1S(Cl)(=O)=O ZUHJONSUZIRGOH-UHFFFAOYSA-N 0.000 description 1
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 1
- VASHPRAPVHERFM-UHFFFAOYSA-N 2-amino-4-tert-butyl-5-hexadecoxyphenol Chemical compound CCCCCCCCCCCCCCCCOC1=CC(O)=C(N)C=C1C(C)(C)C VASHPRAPVHERFM-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- AFENDNXGAFYKQO-UHFFFAOYSA-N 2-hydroxybutyric acid Chemical compound CCC(O)C(O)=O AFENDNXGAFYKQO-UHFFFAOYSA-N 0.000 description 1
- FLFWJIBUZQARMD-UHFFFAOYSA-N 2-mercapto-1,3-benzoxazole Chemical compound C1=CC=C2OC(S)=NC2=C1 FLFWJIBUZQARMD-UHFFFAOYSA-N 0.000 description 1
- VWFUDKCJVNWDPI-UHFFFAOYSA-N 2-methyl-1,3-benzoxazol-5-ol Chemical compound OC1=CC=C2OC(C)=NC2=C1 VWFUDKCJVNWDPI-UHFFFAOYSA-N 0.000 description 1
- SRJCJJKWVSSELL-UHFFFAOYSA-N 2-methylnaphthalen-1-ol Chemical compound C1=CC=CC2=C(O)C(C)=CC=C21 SRJCJJKWVSSELL-UHFFFAOYSA-N 0.000 description 1
- FTCOWMWIZNVSPP-UHFFFAOYSA-N 2-phenyl-4h-pyrazol-3-one Chemical compound O=C1CC=NN1C1=CC=CC=C1 FTCOWMWIZNVSPP-UHFFFAOYSA-N 0.000 description 1
- WLJVXDMOQOGPHL-PPJXEINESA-N 2-phenylacetic acid Chemical class O[14C](=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-PPJXEINESA-N 0.000 description 1
- ILYSAKHOYBPSPC-UHFFFAOYSA-N 2-phenylbenzoic acid Chemical class OC(=O)C1=CC=CC=C1C1=CC=CC=C1 ILYSAKHOYBPSPC-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- UGWULZWUXSCWPX-UHFFFAOYSA-N 2-sulfanylideneimidazolidin-4-one Chemical class O=C1CNC(=S)N1 UGWULZWUXSCWPX-UHFFFAOYSA-N 0.000 description 1
- RVBUGGBMJDPOST-UHFFFAOYSA-N 2-thiobarbituric acid Chemical class O=C1CC(=O)NC(=S)N1 RVBUGGBMJDPOST-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- KZFMGQGVVIBTIH-UHFFFAOYSA-N 3-(4-methyl-2-sulfanylidene-1,3-thiazol-3-yl)propanoic acid Chemical compound CC1=CSC(=S)N1CCC(O)=O KZFMGQGVVIBTIH-UHFFFAOYSA-N 0.000 description 1
- IYOANCSJLXHUOU-UHFFFAOYSA-N 3-[[5-hydroxy-8-[(2-methylsulfonyl-4-nitrophenyl)diazenyl]naphthalen-1-yl]sulfamoyl]benzenesulfonyl chloride Chemical compound CS(=O)(=O)C1=CC([N+]([O-])=O)=CC=C1N=NC1=CC=C(O)C2=CC=CC(NS(=O)(=O)C=3C=C(C=CC=3)S(Cl)(=O)=O)=C12 IYOANCSJLXHUOU-UHFFFAOYSA-N 0.000 description 1
- UEGFKFNFTYLWMM-UHFFFAOYSA-N 3-azaniumylbutan-2-ylazanium;dichloride Chemical compound Cl.Cl.CC(N)C(C)N UEGFKFNFTYLWMM-UHFFFAOYSA-N 0.000 description 1
- NQJATJCXKYZVEL-UHFFFAOYSA-N 3-benzylsulfanyl-1h-1,2,4-triazol-5-amine Chemical compound N1C(N)=NC(SCC=2C=CC=CC=2)=N1 NQJATJCXKYZVEL-UHFFFAOYSA-N 0.000 description 1
- YLNKRLLYLJYWEN-UHFFFAOYSA-N 4-(2,2-dibutoxyethoxy)-4-oxobutanoic acid Chemical compound CCCCOC(OCCCC)COC(=O)CCC(O)=O YLNKRLLYLJYWEN-UHFFFAOYSA-N 0.000 description 1
- DSVIHYOAKPVFEH-UHFFFAOYSA-N 4-(hydroxymethyl)-4-methyl-1-phenylpyrazolidin-3-one Chemical compound N1C(=O)C(C)(CO)CN1C1=CC=CC=C1 DSVIHYOAKPVFEH-UHFFFAOYSA-N 0.000 description 1
- FQPRUMXSHZSJGM-UITAMQMPSA-N 4-[(Z)-N-hydroxy-C-methylcarbonimidoyl]benzene-1,3-diol Chemical compound O/N=C(/C)C1=CC=C(O)C=C1O FQPRUMXSHZSJGM-UITAMQMPSA-N 0.000 description 1
- MLCZOHLVCQVKPI-UHFFFAOYSA-N 4-methyl-2h-benzotriazole;silver Chemical compound [Ag].CC1=CC=CC2=C1N=NN2 MLCZOHLVCQVKPI-UHFFFAOYSA-N 0.000 description 1
- GLESMLFTZHDPLQ-UHFFFAOYSA-N 5-[(3-cyano-5-oxo-1-phenyl-4H-pyrazol-4-yl)diazenyl]-2-(2-methoxyethoxy)benzenesulfonic acid Chemical compound C(#N)C1=NN(C(C1N=NC1=CC=C(C(=C1)S(=O)(=O)O)OCCOC)=O)C1=CC=CC=C1 GLESMLFTZHDPLQ-UHFFFAOYSA-N 0.000 description 1
- JNDPCOZHIGHGJP-UHFFFAOYSA-N 5-bromo-n,2-dihydroxybenzamide;dimethylcarbamic acid Chemical compound CN(C)C(O)=O.ONC(=O)C1=CC(Br)=CC=C1O JNDPCOZHIGHGJP-UHFFFAOYSA-N 0.000 description 1
- IARUBKVHIIBDEN-UHFFFAOYSA-N 5-oxo-1-phenyl-4h-pyrazole-3-carbonitrile Chemical compound O=C1CC(C#N)=NN1C1=CC=CC=C1 IARUBKVHIIBDEN-UHFFFAOYSA-N 0.000 description 1
- SLXKOJJOQWFEFD-UHFFFAOYSA-N 6-aminohexanoic acid Chemical compound NCCCCCC(O)=O SLXKOJJOQWFEFD-UHFFFAOYSA-N 0.000 description 1
- MCWZWCWOKFQFBZ-UHFFFAOYSA-N 6-hexadecoxy-2-methyl-1,3-benzoxazole Chemical compound CCCCCCCCCCCCCCCCOC1=CC=C2N=C(C)OC2=C1 MCWZWCWOKFQFBZ-UHFFFAOYSA-N 0.000 description 1
- CJUFCZXDOQHQCT-UHFFFAOYSA-N 6-tert-butyl-2-methyl-1,3-benzoxazol-5-ol Chemical compound OC1=C(C(C)(C)C)C=C2OC(C)=NC2=C1 CJUFCZXDOQHQCT-UHFFFAOYSA-N 0.000 description 1
- JCZZKBKPYWKTRP-UHFFFAOYSA-N 6-tert-butyl-5-hexadecoxy-2-methyl-1,3-benzoxazole Chemical compound C1=C(C(C)(C)C)C(OCCCCCCCCCCCCCCCC)=CC2=C1OC(C)=N2 JCZZKBKPYWKTRP-UHFFFAOYSA-N 0.000 description 1
- JXSRRBVHLUJJFC-UHFFFAOYSA-N 7-amino-2-methylsulfanyl-[1,2,4]triazolo[1,5-a]pyrimidine-6-carbonitrile Chemical compound N1=CC(C#N)=C(N)N2N=C(SC)N=C21 JXSRRBVHLUJJFC-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- LSPHULWDVZXLIL-UHFFFAOYSA-N Camphoric acid Natural products CC1(C)C(C(O)=O)CCC1(C)C(O)=O LSPHULWDVZXLIL-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241001070941 Castanea Species 0.000 description 1
- 235000014036 Castanea Nutrition 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- 206010073306 Exposure to radiation Diseases 0.000 description 1
- 239000001263 FEMA 3042 Substances 0.000 description 1
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical class OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 description 1
- 150000000996 L-ascorbic acids Chemical class 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- QSACCXVHEVWNMX-UHFFFAOYSA-N N-acetylanthranilic acid Chemical compound CC(=O)NC1=CC=CC=C1C(O)=O QSACCXVHEVWNMX-UHFFFAOYSA-N 0.000 description 1
- AFBPFSWMIHJQDM-UHFFFAOYSA-N N-methyl-N-phenylamine Natural products CNC1=CC=CC=C1 AFBPFSWMIHJQDM-UHFFFAOYSA-N 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- 229930192627 Naphthoquinone Natural products 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- XOAAWQZATWQOTB-UHFFFAOYSA-N Taurine Natural products NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N Tetrahydrothiophene-1,1-dioxide, Natural products O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- DTQVDTLACAAQTR-UHFFFAOYSA-M Trifluoroacetate Chemical compound [O-]C(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-M 0.000 description 1
- AKZWRTCWNXHHFR-PDIZUQLASA-N [(3S)-oxolan-3-yl] N-[(2S,3S)-4-[(5S)-5-benzyl-3-[(2R)-2-carbamoyloxy-2,3-dihydro-1H-inden-1-yl]-4-oxo-3H-pyrrol-5-yl]-3-hydroxy-1-phenylbutan-2-yl]carbamate Chemical compound NC(=O)O[C@@H]1Cc2ccccc2C1C1C=N[C@](C[C@H](O)[C@H](Cc2ccccc2)NC(=O)O[C@H]2CCOC2)(Cc2ccccc2)C1=O AKZWRTCWNXHHFR-PDIZUQLASA-N 0.000 description 1
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 1
- XCFIVNQHHFZRNR-UHFFFAOYSA-N [Ag].Cl[IH]Br Chemical compound [Ag].Cl[IH]Br XCFIVNQHHFZRNR-UHFFFAOYSA-N 0.000 description 1
- PIBQGZLFBAQMLH-UHFFFAOYSA-N [amino(sulfanyl)methylidene]-(2-hydroxyethyl)azanium;2,2,2-trichloroacetate Chemical compound NC(S)=[NH+]CCO.[O-]C(=O)C(Cl)(Cl)Cl PIBQGZLFBAQMLH-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- FPWNQPQTICPCOM-UHFFFAOYSA-N acetonitrile;propan-2-ol Chemical compound CC#N.CC(C)O FPWNQPQTICPCOM-UHFFFAOYSA-N 0.000 description 1
- 125000005041 acyloxyalkyl group Chemical group 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 125000003172 aldehyde group Chemical group 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000005083 alkoxyalkoxy group Chemical group 0.000 description 1
- 125000005078 alkoxycarbonylalkyl group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229960002684 aminocaproic acid Drugs 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 125000005428 anthryl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C(*)=C([H])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical group 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- SLUNEGLMXGHOLY-UHFFFAOYSA-N benzene;hexane Chemical compound CCCCCC.C1=CC=CC=C1 SLUNEGLMXGHOLY-UHFFFAOYSA-N 0.000 description 1
- BNZXJGMVVSASQT-UHFFFAOYSA-N benzenesulfonyl acetate Chemical compound CC(=O)OS(=O)(=O)C1=CC=CC=C1 BNZXJGMVVSASQT-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- GQCYXEOBZQXHPO-UHFFFAOYSA-N benzoic acid;silver Chemical class [Ag].OC(=O)C1=CC=CC=C1 GQCYXEOBZQXHPO-UHFFFAOYSA-N 0.000 description 1
- 150000001559 benzoic acids Chemical class 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 1
- COPHVUDURPSYBO-UHFFFAOYSA-N butyl dioctyl phosphate Chemical compound CCCCCCCCOP(=O)(OCCCC)OCCCCCCCC COPHVUDURPSYBO-UHFFFAOYSA-N 0.000 description 1
- 150000001661 cadmium Chemical class 0.000 description 1
- LSPHULWDVZXLIL-QUBYGPBYSA-N camphoric acid Chemical class CC1(C)[C@H](C(O)=O)CC[C@]1(C)C(O)=O LSPHULWDVZXLIL-QUBYGPBYSA-N 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000001768 cations Chemical group 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000012320 chlorinating reagent Substances 0.000 description 1
- 125000004965 chloroalkyl group Chemical group 0.000 description 1
- SKCNIGRBPJIUBQ-UHFFFAOYSA-N chloroform;ethyl acetate Chemical compound ClC(Cl)Cl.CCOC(C)=O SKCNIGRBPJIUBQ-UHFFFAOYSA-N 0.000 description 1
- AJPXTSMULZANCB-UHFFFAOYSA-N chlorohydroquinone Chemical compound OC1=CC=C(O)C(Cl)=C1 AJPXTSMULZANCB-UHFFFAOYSA-N 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- WYYQVWLEPYFFLP-UHFFFAOYSA-K chromium(3+);triacetate Chemical compound [Cr+3].CC([O-])=O.CC([O-])=O.CC([O-])=O WYYQVWLEPYFFLP-UHFFFAOYSA-K 0.000 description 1
- 125000000490 cinnamyl group Chemical group C(C=CC1=CC=CC=C1)* 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 1
- 238000004440 column chromatography Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000002508 contact lithography Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 125000004966 cyanoalkyl group Chemical group 0.000 description 1
- FOTKYAAJKYLFFN-UHFFFAOYSA-N decane-1,10-diol Chemical compound OCCCCCCCCCCO FOTKYAAJKYLFFN-UHFFFAOYSA-N 0.000 description 1
- 238000011033 desalting Methods 0.000 description 1
- 125000004663 dialkyl amino group Chemical group 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- HPYNZHMRTTWQTB-UHFFFAOYSA-N dimethylpyridine Natural products CC1=CC=CN=C1C HPYNZHMRTTWQTB-UHFFFAOYSA-N 0.000 description 1
- XWVQUJDBOICHGH-UHFFFAOYSA-N dioctyl nonanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCC(=O)OCCCCCCCC XWVQUJDBOICHGH-UHFFFAOYSA-N 0.000 description 1
- 150000002012 dioxanes Chemical class 0.000 description 1
- ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 150000002023 dithiocarboxylic acids Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- ZEUUVJSRINKECZ-UHFFFAOYSA-N ethanedithioic acid Chemical class CC(S)=S ZEUUVJSRINKECZ-UHFFFAOYSA-N 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000000834 fixative Substances 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 239000012458 free base Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 125000002541 furyl group Chemical group 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- CZLCEPVHPYKDPJ-UHFFFAOYSA-N guanidine;2,2,2-trichloroacetic acid Chemical compound NC(N)=N.OC(=O)C(Cl)(Cl)Cl CZLCEPVHPYKDPJ-UHFFFAOYSA-N 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000005113 hydroxyalkoxy group Chemical group 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 150000002443 hydroxylamines Chemical class 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- 125000001041 indolyl group Chemical group 0.000 description 1
- 229940079865 intestinal antiinfectives imidazole derivative Drugs 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- GPSDUZXPYCFOSQ-UHFFFAOYSA-N m-toluic acid Chemical compound CC1=CC=CC(C(O)=O)=C1 GPSDUZXPYCFOSQ-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- UKVIEHSSVKSQBA-UHFFFAOYSA-N methane;palladium Chemical compound C.[Pd] UKVIEHSSVKSQBA-UHFFFAOYSA-N 0.000 description 1
- HNQIVZYLYMDVSB-UHFFFAOYSA-N methanesulfonimidic acid Chemical compound CS(N)(=O)=O HNQIVZYLYMDVSB-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- IBKQQKPQRYUGBJ-UHFFFAOYSA-N methyl gallate Natural products CC(=O)C1=CC(O)=C(O)C(O)=C1 IBKQQKPQRYUGBJ-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- DDIZAANNODHTRB-UHFFFAOYSA-N methyl p-anisate Chemical compound COC(=O)C1=CC=C(OC)C=C1 DDIZAANNODHTRB-UHFFFAOYSA-N 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- ZAKLKBFCSHJIRI-UHFFFAOYSA-N mucochloric acid Natural products OC1OC(=O)C(Cl)=C1Cl ZAKLKBFCSHJIRI-UHFFFAOYSA-N 0.000 description 1
- ZHFBNFIXRMDULI-UHFFFAOYSA-N n,n-bis(2-ethoxyethyl)hydroxylamine Chemical compound CCOCCN(O)CCOCC ZHFBNFIXRMDULI-UHFFFAOYSA-N 0.000 description 1
- XBECFEJUQZXMFE-UHFFFAOYSA-N n-(4-aminobutyl)acetamide;hydrochloride Chemical compound Cl.CC(=O)NCCCCN XBECFEJUQZXMFE-UHFFFAOYSA-N 0.000 description 1
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- UMBBGOALZMAJSF-UHFFFAOYSA-N n-benzylethenamine;hydrochloride Chemical compound [Cl-].C=C[NH2+]CC1=CC=CC=C1 UMBBGOALZMAJSF-UHFFFAOYSA-N 0.000 description 1
- 150000002791 naphthoquinones Chemical class 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 239000001005 nitro dye Substances 0.000 description 1
- 125000000018 nitroso group Chemical group N(=O)* 0.000 description 1
- 239000012434 nucleophilic reagent Substances 0.000 description 1
- ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- VECVSKFWRQYTAL-UHFFFAOYSA-N octyl benzoate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1 VECVSKFWRQYTAL-UHFFFAOYSA-N 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- BIAGWOZIXODKKS-UHFFFAOYSA-N oxadiazole-4-thiol;silver Chemical compound [Ag].SC1=CON=N1 BIAGWOZIXODKKS-UHFFFAOYSA-N 0.000 description 1
- 150000002916 oxazoles Chemical class 0.000 description 1
- 150000002918 oxazolines Chemical class 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- QUBQYFYWUJJAAK-UHFFFAOYSA-N oxymethurea Chemical compound OCNC(=O)NCO QUBQYFYWUJJAAK-UHFFFAOYSA-N 0.000 description 1
- 229950005308 oxymethurea Drugs 0.000 description 1
- KLAKIAVEMQMVBT-UHFFFAOYSA-N p-hydroxy-phenacyl alcohol Natural products OCC(=O)C1=CC=C(O)C=C1 KLAKIAVEMQMVBT-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical class N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 description 1
- IRDJLIBTYFENSX-UHFFFAOYSA-N phenyl 5-bromo-2-hydroxybenzoate Chemical compound OC1=CC=C(Br)C=C1C(=O)OC1=CC=CC=C1 IRDJLIBTYFENSX-UHFFFAOYSA-N 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- UHZYTMXLRWXGPK-UHFFFAOYSA-N phosphorus pentachloride Chemical compound ClP(Cl)(Cl)(Cl)Cl UHZYTMXLRWXGPK-UHFFFAOYSA-N 0.000 description 1
- 239000001007 phthalocyanine dye Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 125000006239 protecting group Chemical group 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 150000003232 pyrogallols Chemical class 0.000 description 1
- 150000003233 pyrroles Chemical class 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 150000003236 pyrrolines Chemical class 0.000 description 1
- 125000000168 pyrrolyl group Chemical group 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000012260 resinous material Substances 0.000 description 1
- KIWUVOGUEXMXSV-UHFFFAOYSA-N rhodanine Chemical class O=C1CSC(=S)N1 KIWUVOGUEXMXSV-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical class C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 1
- 229940081974 saccharin Drugs 0.000 description 1
- 235000019204 saccharin Nutrition 0.000 description 1
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 235000017709 saponins Nutrition 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical compound [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 description 1
- 229910001488 sodium perchlorate Inorganic materials 0.000 description 1
- VQIQPNAYDOXKST-UHFFFAOYSA-M sodium;4-(2-ethylhexoxy)-4-oxobutanoate Chemical compound [Na+].CCCCC(CC)COC(=O)CCC([O-])=O VQIQPNAYDOXKST-UHFFFAOYSA-M 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 150000003431 steroids Chemical class 0.000 description 1
- 125000005415 substituted alkoxy group Chemical group 0.000 description 1
- 229960002317 succinimide Drugs 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 125000004964 sulfoalkyl group Chemical group 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 125000006296 sulfonyl amino group Chemical group [H]N(*)S(*)(=O)=O 0.000 description 1
- 230000006103 sulfonylation Effects 0.000 description 1
- 238000005694 sulfonylation reaction Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000003115 supporting electrolyte Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical class OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 1
- 150000003536 tetrazoles Chemical class 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 150000003557 thiazoles Chemical class 0.000 description 1
- 150000003549 thiazolines Chemical class 0.000 description 1
- 125000001544 thienyl group Chemical group 0.000 description 1
- 150000003556 thioamides Chemical class 0.000 description 1
- 125000000101 thioether group Chemical group 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 238000010023 transfer printing Methods 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- NJPOTNJJCSJJPJ-UHFFFAOYSA-N tributyl benzene-1,3,5-tricarboxylate Chemical compound CCCCOC(=O)C1=CC(C(=O)OCCCC)=CC(C(=O)OCCCC)=C1 NJPOTNJJCSJJPJ-UHFFFAOYSA-N 0.000 description 1
- 150000003639 trimesic acids Chemical class 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- INDZTCRIYSRWOH-UHFFFAOYSA-N undec-10-enyl carbamimidothioate;hydroiodide Chemical compound I.NC(=N)SCCCCCCCCCC=C INDZTCRIYSRWOH-UHFFFAOYSA-N 0.000 description 1
- 229920003176 water-insoluble polymer Polymers 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 239000001043 yellow dye Substances 0.000 description 1
- DGVVWUTYPXICAM-UHFFFAOYSA-N βâMercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/494—Silver salt compositions other than silver halide emulsions; Photothermographic systems ; Thermographic systems using noble metal compounds
- G03C1/498—Photothermographic systems, e.g. dry silver
- G03C1/49836—Additives
- G03C1/49845—Active additives, e.g. toners, stabilisers, sensitisers
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
- G03C8/40—Development by heat ; Photo-thermographic processes
- G03C8/4013—Development by heat ; Photo-thermographic processes using photothermographic silver salt systems, e.g. dry silver
- G03C8/408—Additives or processing agents not provided for in groups G03C8/402Â -Â G03C8/4046
- G03C8/4086—Base precursors
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/156—Precursor compound
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Description
æ¬çºæã¯å®è³ªçã«æ°Žãå«ãŸãªãç¶æ
ã§å ç±ã«ã
ã€ãŠæå æ§ããã²ã³åéãšåå¿ããŠèŠªæ°Žæ§è²çŽ ã
æŸåºããè²çŽ äŸäžæ§ç©è³ªãå«ãæ°ããæå ææã«
é¢ãããã®ã§ããã æ¬çºæã¯æŽã«å¡©åºãã¬ã«ãŒãµãŒãå«ãç±çŸåã«
ã©ãŒæå ææã«é¢ãããã®ã§ããã ããã§ããå¡©åºãã¬ã«ãŒãµãŒãšã¯ç±å解ã«ãã
å¡©åºæ§æåãæŸåºãããã®ã§ããã ããã²ã³åéãçšããåçæ³ã¯ãä»ã®åçæ³ã
ãšãã°é»ååçæ³ããžã¢ãŸåçæ³ã«æ¯ã¹ãŠãæ床
ãé調調ç¯ãªã©ã®åçç¹æ§ã«ããããŠããã®ã§ã
åŸæ¥ããæãåºç¯ã«çšããããŠãããè¿å¹Žã«ãªã€
ãŠããã²ã³åéãçšããæå ææã®ç»å圢æåŠç
æ³ãåŸæ¥ã®çŸå液çã«ãã湿åŒåŠçãããå ç±ç
ã«ãã也åŒåŠçã«ãããããšã«ããç°¡æã§è¿ éã«
ç»åãåŸãããšã®ã§ããæè¡ãéçºãããŠããã ç±çŸåæå ææã¯åœè©²æè¡åéã§ã¯å ¬ç¥ã§ãã
ç±çŸåæå ææãšãã®ããã»ã¹ã«ã€ããŠã¯ããã
ãšãã°åçå·¥æ¥ã®åºç€ïŒ1979幎ã³ãã瀟çºè¡ïŒã®
553é ã555é ã1978幎ïŒæçºè¡æ åæ å ±40é ã
Nebletts Handbook of Photography and
Reprography 7th Ed.ïŒVan Nostrand Reinhold
CompanyïŒã®32é ã33é ãç±³åœç¹èš±ç¬¬3152904
å·ã第3301678å·ã第3392020å·ã第3457075å·ã
è±åœç¹èš±ç¬¬1131108å·ã第1167777å·ããã³ããªãµ
ãŒããã€ã¹ã¯ããŒãžã€ãŒèª1978幎ïŒæå·ïŒã15ã
ãŒãžïŒRDâ17029ïŒã«èšèŒãããŠããã 也åŒã§è²ç»åïŒã«ã©ãŒç»åïŒãåŸãæ¹æ³ã«ã€ã
ãŠã¯ãå€ãã®æ¹æ³ãææ¡ãããŠãããçŸå液ã®é ž
åäœãšã«ãã©ãŒãšã®çµåã«ããè²ç»åã圢æãã
æ¹æ³ã«ã€ããŠã¯ãç±³åœç¹èš±ç¬¬3531286å·ã§ã¯ïœâ
ããšãã¬ã³ãžã¢ãã³é¡éå å€ãšããšããŒã«æ§åã¯
掻æ§ã¡ãã¬ã³ã«ãã©ãŒããç±³åœç¹èš±ç¬¬3761270ã§
ã¯ãïœâã¢ããããšããŒã«ç³»éå å€ãããã«ã®ãŒ
ç¹èš±ç¬¬802519å·ããã³ãªãµãŒããã€ã¹ã¯ããŒãžã€
ãŒèª1975幎ïŒæå·31ïŒ32ããŒãžã§ã¯ãã¹ã«ãã³ã¢
ããããšããŒã«ç³»éå å€ãããŸãç±³åœç¹èš±ç¬¬
4021240å·ã§ã¯ãã¹ã«ãã³ã¢ããããšããŒã«ç³»é
å å€ãšïŒåœéã«ãã©ãŒãšã®çµã¿åããææ¡ãããŠ
ããã ãããããã®ãããªæ¹æ³ã«ãããŠã¯ãç±çŸååŸ
é²å éšåã«éå éã®åãšè²ç»åãšãåæã«çãã
ãããè²ç»åãæ¿ããšããæ¬ ç¹ããã€ãããã®æ¬
ç¹ã解決ããæ¹æ³ãšããŠãéåã液äœåŠçã«ãã
åãã®ããããè²çŽ ã®ã¿ãä»ã®å±€ãããšãã°åå
å±€ãæããã·ãŒãã«è»¢åããæ¹æ³ãããããæªå
å¿ç©ãšè²çŽ ãšãåºå¥ããŠè²çŽ ã®ã¿ã転åããããš
ã¯å®¹æã§ãªããšããæ¬ ç¹ãæããã ãŸãè²çŽ ã«å«çªçŽ ãããç°åºãå°å ¥ããéå¡©ã
圢æãããç±çŸåã«ããè²çŽ ãéé¢ãããæ¹æ³ã
ãªãµãŒããã€ã¹ã¯ããŒãžã€ãŒèª1978幎ïŒæå·54ã
58ããŒãžRDâ16966ã«èšèŒãããŠããããã®æ¹
æ³ã§ã¯ãå ã®ããã€ãŠããªãéšåã§ã®è²çŽ ã®éé¢
ãæå¶ããããšãå°é£ã§ãé®®æãªç»åãåŸãããš
ãã§ãããäžè¬çãªæ¹æ³ã§ãªãã ãŸãæç±éè²çŽ æŒçœæ³ã«ãããããžã®è²ç»åã
圢æããæ¹æ³ã«ã€ããŠã¯ãããšãã°ãªãµãŒããã€
ã¹ã¯ããŒãžã€ãŒèª1976幎ïŒæå·30ã32ããŒãž
ïŒRDâ14433ïŒãåèª1976幎12æå·14ã15ããŒãž
ïŒRDâ15227ïŒãç±³åœç¹èš±ç¬¬4235957å·ãªã©ã«æçš
ãªè²çŽ ãšæŒçœã®æ¹æ³ãèšèŒãããŠããã ãããããã®æ¹æ³ã«ãããŠã¯ãè²çŽ ã®æŒçœãæ©
ããããã®æŽ»æ§åå€ã·ãŒããéããŠå ç±ãããªã©
ã®äœåãªå·¥çšãšææãå¿ èŠã§ããããŸãåŸããã
è²ç»åãé·æã®ä¿åäžã«ãå ±åããéé¢éãªã©ã«
ããåŸã ã«éå æŒçœããããšããæ¬ ç¹ãæããŠã
ãã ãŸããã€ã³è²çŽ ãå©çšããŠè²ç»åã圢æããæ¹
æ³ã«ã€ããŠã¯ãããšãã°ç±³åœç¹èš±ç¬¬3985565å·ã
第4022617å·ã«èšèŒãããŠããããããããã®æ¹
æ³ã§ã¯ãã€ã³è²çŽ ãå®å®ã«åçææã«å èµããã
ãšã¯å°é£ã§ãä¿åæã«åŸã ã«çè²ãããšããæ¬ ç¹
ãæããŠããã ããã«ã以äžã®è«žæ¹æ³ã§ã¯äžè¬ã«çŸåã«æ¯èŒç
é·æéãèŠããåŸãããç»åãé«ãã«ããªãšäœã
æ¿åºŠããåŸãããªããšããæ¬ ç¹ãæããŠããã æ¬çºæã¯å®è³ªçã«æ°Žãå«ãŸãªãç¶æ ã§å ç±ã«ã
ãè²çŽ ç»åã圢æããæ°ããã«ã©ãŒæå ææãæ
äŸãããã®ã§ããããã€ãããŸã§å ¬ç¥ã®ææãæ
ããŠããæ¬ ç¹ã解決ãããã®ã§ããã å³ã¡ãæ¬çºæã®ç®çã¯ãçæéã§é«æ¿åºŠã®ã«ã©
ãŒç»åãåŸãæå ææãæäŸãããã®ã§ããã æ¬çºæã®ç®çã¯ãé«æ¿åºŠã§ãããã«ããªã®äœã
ã«ã©ãŒç»åãåŸãæå ææãæäŸãããã®ã§ã
ãã æ¬çºæã®ç®çã¯ãçµæå®å®æ§ã®åªããç±çŸåã«
ã©ãŒæå ææãæäŸãããã®ã§ãããããã§ãã
ãçµæçã«å®å®ããšã¯ãç±çŸååŠçåã®æå ææ
ã®ä¿åäžã«ãããŠãæé«æ¿åºŠãæäœæ¿åºŠãæ床ç
ã®åçæ§èœã®å€åãå°ãªãããšã§ããã ãããè«žç®çã¯ãæ¯æäœäžã«å°ãªããšãæå æ§
ããã²ã³åéããã€ã³ããŒãæå æ§ããã²ã³åé
ã«å¯ŸããŠéå æ§ãããããã€æå æ§ããã²ã³åé
ãšå ç±ã«ããåå¿ããŠèŠªæ°Žæ§è²çŽ ãæŸåºããè²çŽ
äŸäžæ§ç©è³ªäžŠã³ã«äžèšäžè¬åŒ(A)ããã³ïŒãŸãã¯äž
è¬åŒ(B)ã§ç€ºãå¡©åºãã¬ã«ãŒãµãŒãæããç±çŸåã«
ã©ãŒæå ææã«ããéæãããã äžè¬åŒ(A)
ã€ãŠæå æ§ããã²ã³åéãšåå¿ããŠèŠªæ°Žæ§è²çŽ ã
æŸåºããè²çŽ äŸäžæ§ç©è³ªãå«ãæ°ããæå ææã«
é¢ãããã®ã§ããã æ¬çºæã¯æŽã«å¡©åºãã¬ã«ãŒãµãŒãå«ãç±çŸåã«
ã©ãŒæå ææã«é¢ãããã®ã§ããã ããã§ããå¡©åºãã¬ã«ãŒãµãŒãšã¯ç±å解ã«ãã
å¡©åºæ§æåãæŸåºãããã®ã§ããã ããã²ã³åéãçšããåçæ³ã¯ãä»ã®åçæ³ã
ãšãã°é»ååçæ³ããžã¢ãŸåçæ³ã«æ¯ã¹ãŠãæ床
ãé調調ç¯ãªã©ã®åçç¹æ§ã«ããããŠããã®ã§ã
åŸæ¥ããæãåºç¯ã«çšããããŠãããè¿å¹Žã«ãªã€
ãŠããã²ã³åéãçšããæå ææã®ç»å圢æåŠç
æ³ãåŸæ¥ã®çŸå液çã«ãã湿åŒåŠçãããå ç±ç
ã«ãã也åŒåŠçã«ãããããšã«ããç°¡æã§è¿ éã«
ç»åãåŸãããšã®ã§ããæè¡ãéçºãããŠããã ç±çŸåæå ææã¯åœè©²æè¡åéã§ã¯å ¬ç¥ã§ãã
ç±çŸåæå ææãšãã®ããã»ã¹ã«ã€ããŠã¯ããã
ãšãã°åçå·¥æ¥ã®åºç€ïŒ1979幎ã³ãã瀟çºè¡ïŒã®
553é ã555é ã1978幎ïŒæçºè¡æ åæ å ±40é ã
Nebletts Handbook of Photography and
Reprography 7th Ed.ïŒVan Nostrand Reinhold
CompanyïŒã®32é ã33é ãç±³åœç¹èš±ç¬¬3152904
å·ã第3301678å·ã第3392020å·ã第3457075å·ã
è±åœç¹èš±ç¬¬1131108å·ã第1167777å·ããã³ããªãµ
ãŒããã€ã¹ã¯ããŒãžã€ãŒèª1978幎ïŒæå·ïŒã15ã
ãŒãžïŒRDâ17029ïŒã«èšèŒãããŠããã 也åŒã§è²ç»åïŒã«ã©ãŒç»åïŒãåŸãæ¹æ³ã«ã€ã
ãŠã¯ãå€ãã®æ¹æ³ãææ¡ãããŠãããçŸå液ã®é ž
åäœãšã«ãã©ãŒãšã®çµåã«ããè²ç»åã圢æãã
æ¹æ³ã«ã€ããŠã¯ãç±³åœç¹èš±ç¬¬3531286å·ã§ã¯ïœâ
ããšãã¬ã³ãžã¢ãã³é¡éå å€ãšããšããŒã«æ§åã¯
掻æ§ã¡ãã¬ã³ã«ãã©ãŒããç±³åœç¹èš±ç¬¬3761270ã§
ã¯ãïœâã¢ããããšããŒã«ç³»éå å€ãããã«ã®ãŒ
ç¹èš±ç¬¬802519å·ããã³ãªãµãŒããã€ã¹ã¯ããŒãžã€
ãŒèª1975幎ïŒæå·31ïŒ32ããŒãžã§ã¯ãã¹ã«ãã³ã¢
ããããšããŒã«ç³»éå å€ãããŸãç±³åœç¹èš±ç¬¬
4021240å·ã§ã¯ãã¹ã«ãã³ã¢ããããšããŒã«ç³»é
å å€ãšïŒåœéã«ãã©ãŒãšã®çµã¿åããææ¡ãããŠ
ããã ãããããã®ãããªæ¹æ³ã«ãããŠã¯ãç±çŸååŸ
é²å éšåã«éå éã®åãšè²ç»åãšãåæã«çãã
ãããè²ç»åãæ¿ããšããæ¬ ç¹ããã€ãããã®æ¬
ç¹ã解決ããæ¹æ³ãšããŠãéåã液äœåŠçã«ãã
åãã®ããããè²çŽ ã®ã¿ãä»ã®å±€ãããšãã°åå
å±€ãæããã·ãŒãã«è»¢åããæ¹æ³ãããããæªå
å¿ç©ãšè²çŽ ãšãåºå¥ããŠè²çŽ ã®ã¿ã転åããããš
ã¯å®¹æã§ãªããšããæ¬ ç¹ãæããã ãŸãè²çŽ ã«å«çªçŽ ãããç°åºãå°å ¥ããéå¡©ã
圢æãããç±çŸåã«ããè²çŽ ãéé¢ãããæ¹æ³ã
ãªãµãŒããã€ã¹ã¯ããŒãžã€ãŒèª1978幎ïŒæå·54ã
58ããŒãžRDâ16966ã«èšèŒãããŠããããã®æ¹
æ³ã§ã¯ãå ã®ããã€ãŠããªãéšåã§ã®è²çŽ ã®éé¢
ãæå¶ããããšãå°é£ã§ãé®®æãªç»åãåŸãããš
ãã§ãããäžè¬çãªæ¹æ³ã§ãªãã ãŸãæç±éè²çŽ æŒçœæ³ã«ãããããžã®è²ç»åã
圢æããæ¹æ³ã«ã€ããŠã¯ãããšãã°ãªãµãŒããã€
ã¹ã¯ããŒãžã€ãŒèª1976幎ïŒæå·30ã32ããŒãž
ïŒRDâ14433ïŒãåèª1976幎12æå·14ã15ããŒãž
ïŒRDâ15227ïŒãç±³åœç¹èš±ç¬¬4235957å·ãªã©ã«æçš
ãªè²çŽ ãšæŒçœã®æ¹æ³ãèšèŒãããŠããã ãããããã®æ¹æ³ã«ãããŠã¯ãè²çŽ ã®æŒçœãæ©
ããããã®æŽ»æ§åå€ã·ãŒããéããŠå ç±ãããªã©
ã®äœåãªå·¥çšãšææãå¿ èŠã§ããããŸãåŸããã
è²ç»åãé·æã®ä¿åäžã«ãå ±åããéé¢éãªã©ã«
ããåŸã ã«éå æŒçœããããšããæ¬ ç¹ãæããŠã
ãã ãŸããã€ã³è²çŽ ãå©çšããŠè²ç»åã圢æããæ¹
æ³ã«ã€ããŠã¯ãããšãã°ç±³åœç¹èš±ç¬¬3985565å·ã
第4022617å·ã«èšèŒãããŠããããããããã®æ¹
æ³ã§ã¯ãã€ã³è²çŽ ãå®å®ã«åçææã«å èµããã
ãšã¯å°é£ã§ãä¿åæã«åŸã ã«çè²ãããšããæ¬ ç¹
ãæããŠããã ããã«ã以äžã®è«žæ¹æ³ã§ã¯äžè¬ã«çŸåã«æ¯èŒç
é·æéãèŠããåŸãããç»åãé«ãã«ããªãšäœã
æ¿åºŠããåŸãããªããšããæ¬ ç¹ãæããŠããã æ¬çºæã¯å®è³ªçã«æ°Žãå«ãŸãªãç¶æ ã§å ç±ã«ã
ãè²çŽ ç»åã圢æããæ°ããã«ã©ãŒæå ææãæ
äŸãããã®ã§ããããã€ãããŸã§å ¬ç¥ã®ææãæ
ããŠããæ¬ ç¹ã解決ãããã®ã§ããã å³ã¡ãæ¬çºæã®ç®çã¯ãçæéã§é«æ¿åºŠã®ã«ã©
ãŒç»åãåŸãæå ææãæäŸãããã®ã§ããã æ¬çºæã®ç®çã¯ãé«æ¿åºŠã§ãããã«ããªã®äœã
ã«ã©ãŒç»åãåŸãæå ææãæäŸãããã®ã§ã
ãã æ¬çºæã®ç®çã¯ãçµæå®å®æ§ã®åªããç±çŸåã«
ã©ãŒæå ææãæäŸãããã®ã§ãããããã§ãã
ãçµæçã«å®å®ããšã¯ãç±çŸååŠçåã®æå ææ
ã®ä¿åäžã«ãããŠãæé«æ¿åºŠãæäœæ¿åºŠãæ床ç
ã®åçæ§èœã®å€åãå°ãªãããšã§ããã ãããè«žç®çã¯ãæ¯æäœäžã«å°ãªããšãæå æ§
ããã²ã³åéããã€ã³ããŒãæå æ§ããã²ã³åé
ã«å¯ŸããŠéå æ§ãããããã€æå æ§ããã²ã³åé
ãšå ç±ã«ããåå¿ããŠèŠªæ°Žæ§è²çŽ ãæŸåºããè²çŽ
äŸäžæ§ç©è³ªäžŠã³ã«äžèšäžè¬åŒ(A)ããã³ïŒãŸãã¯äž
è¬åŒ(B)ã§ç€ºãå¡©åºãã¬ã«ãŒãµãŒãæããç±çŸåã«
ã©ãŒæå ææã«ããéæãããã äžè¬åŒ(A)
ãåŒã
äžè¬åŒ(B)
ãåŒã
ããã§ãA1ïŒA2ïŒA5ïŒA6ïŒA7ïŒA8ã¯ããã
ãæ°ŽçŽ ååãã¢ã«ãã«åºã眮æã¢ã«ãã«åºãã·ã¯
ãã¢ã«ãã«åºãã¢ã«ã±ãã«åºãã¢ã©ã«ãã«åºãã¢
ãªãŒã«åºã眮æã¢ãªãŒã«åºãã¢ã·ã«åºåã³è€çŽ ç°
åŒåºã®äžããéžã°ãã眮æåºãè¡šããããŸãA1
ãšA2ã¯é£çµããŠç°ã圢æããŠããŠãããããã
ã«A5ïŒA6ïŒA7ïŒA8ã¯ãäžã®ïŒã€ãé£çµããŠç°ã
圢æããŠããŠãããã A3ïŒA4ã¯ããããæ°ŽçŽ ååãã¢ã«ãã«åºã眮
æã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºãã¢ã©ã«ãã«åº
ãè¡šããããŸãA3ãšA4ã¯é£çµããŠç°ã圢æããŠ
ããŠããããã
ãæ°ŽçŽ ååãã¢ã«ãã«åºã眮æã¢ã«ãã«åºãã·ã¯
ãã¢ã«ãã«åºãã¢ã«ã±ãã«åºãã¢ã©ã«ãã«åºãã¢
ãªãŒã«åºã眮æã¢ãªãŒã«åºãã¢ã·ã«åºåã³è€çŽ ç°
åŒåºã®äžããéžã°ãã眮æåºãè¡šããããŸãA1
ãšA2ã¯é£çµããŠç°ã圢æããŠããŠãããããã
ã«A5ïŒA6ïŒA7ïŒA8ã¯ãäžã®ïŒã€ãé£çµããŠç°ã
圢æããŠããŠãããã A3ïŒA4ã¯ããããæ°ŽçŽ ååãã¢ã«ãã«åºã眮
æã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºãã¢ã©ã«ãã«åº
ãè¡šããããŸãA3ãšA4ã¯é£çµããŠç°ã圢æããŠ
ããŠããããã
ãåŒããäºéçµåãšãªã€ãŠã€ããåºã圢æã
ãŠããŠãããã
ã¯æ±æ žæ§åºãè¡šããã
A1ãªããA8ã«æããããŠããã¢ã«ãã«åºã®äŸ
ãšããŠã¯ççŽ æ°ïŒã18ã®çŽéãŸãã¯åå²ã¢ã«ãã«
åºïŒçœ®æã¢ã«ãã«åºã®çœ®æåºã®äŸãšããŠã¯æ°Žé ž
åºãã¢ã«ã³ãã·åºãã·ã¢ãåºãã«ã«ããã·ã«åºã
ã«ã«ãã¢ã«ã³ãã·åºãã«ã«ãã¢ã€ã«åºãããã²ã³
ååçãæããããã A1ãªããA8ã«æããããŠããã·ã¯ãã¢ã«ãã«
åºã®äŸãšããŠã¯ççŽ æ°ïŒã10ã®ïŒãªããïŒå¡ã·ã¯
ãã¢ã«ãã«åºããããã¢ã«ã±ãã«åºã®äŸãšããŠã¯
ã¢ãªã«åºãã¯ããã«åºãã·ã³ããã«åºçãæãã
ããã A1ãªããA8ã«æããããŠããã¢ã©ã«ãã«åºã®
äŸãšããŠã¯ãã³ãžã«åºãβâããšããã«åºããã³
ãºãããªã«åºçããããã¢ãªãŒã«åºã®äŸãšããŠã¯
ããšãã«åºããããã«åºãã¢ã³ã¹ãªã«åºçãã
ãã眮æã¢ãªãŒã«åºã®çœ®æåºã®äŸãšããŠã¯ã¢ã«ã
ã«åºãã¢ã«ã³ãã·åºããžã¢ã«ãã«ã¢ããåºãã·ã¢
ãåºããããåºãããã²ã³ååçããããA1ãª
ããA8ã«æããããŠããè€çŽ ç°åºã®äŸãšããŠã¯
ããªãžã«åºãããªã«åºãããšãã«åºããããŒã«
åºãã€ã³ããªã«åºçãæããããã¢ã·ã«åºã®äŸãš
ããŠã¯èèªæãŸãã¯è³éŠæã«ã«ãã³é žããèªå°ã
ããççŽ æ°ïŒã18ã®ã¢ã·ã«åºãæãããããA3
ãšA4ãçµåããŠç°ã圢æããäŸãšããŠã¯
ãšããŠã¯ççŽ æ°ïŒã18ã®çŽéãŸãã¯åå²ã¢ã«ãã«
åºïŒçœ®æã¢ã«ãã«åºã®çœ®æåºã®äŸãšããŠã¯æ°Žé ž
åºãã¢ã«ã³ãã·åºãã·ã¢ãåºãã«ã«ããã·ã«åºã
ã«ã«ãã¢ã«ã³ãã·åºãã«ã«ãã¢ã€ã«åºãããã²ã³
ååçãæããããã A1ãªããA8ã«æããããŠããã·ã¯ãã¢ã«ãã«
åºã®äŸãšããŠã¯ççŽ æ°ïŒã10ã®ïŒãªããïŒå¡ã·ã¯
ãã¢ã«ãã«åºããããã¢ã«ã±ãã«åºã®äŸãšããŠã¯
ã¢ãªã«åºãã¯ããã«åºãã·ã³ããã«åºçãæãã
ããã A1ãªããA8ã«æããããŠããã¢ã©ã«ãã«åºã®
äŸãšããŠã¯ãã³ãžã«åºãβâããšããã«åºããã³
ãºãããªã«åºçããããã¢ãªãŒã«åºã®äŸãšããŠã¯
ããšãã«åºããããã«åºãã¢ã³ã¹ãªã«åºçãã
ãã眮æã¢ãªãŒã«åºã®çœ®æåºã®äŸãšããŠã¯ã¢ã«ã
ã«åºãã¢ã«ã³ãã·åºããžã¢ã«ãã«ã¢ããåºãã·ã¢
ãåºããããåºãããã²ã³ååçããããA1ãª
ããA8ã«æããããŠããè€çŽ ç°åºã®äŸãšããŠã¯
ããªãžã«åºãããªã«åºãããšãã«åºããããŒã«
åºãã€ã³ããªã«åºçãæããããã¢ã·ã«åºã®äŸãš
ããŠã¯èèªæãŸãã¯è³éŠæã«ã«ãã³é žããèªå°ã
ããççŽ æ°ïŒã18ã®ã¢ã·ã«åºãæãããããA3
ãšA4ãçµåããŠç°ã圢æããäŸãšããŠã¯
ãåŒã
ãåŒã
ãåŒã
ãåŒã
çãããããŸã
ãåŒããã€ããåºãšãªãäŸãšã
ãŠã¯
ãåŒã
ãåŒã
ãåŒãçãããã
ã§ç€ºãæ±æ žæ§åºãšããŠã¯ãäŸãã°æ°Žé
žåºãã
ãããã·ã¡ãã«åºãã¢ããåºã眮æã¢ããåºãã¢
ããã¡ãã«åºã眮æã¢ããã¡ãã«åºãã¡ã«ã«ãã
åºãã¡ã«ã«ããã¡ãã«åºãã«ã«ããã·ã«åºãã«ã«
ãã¢ã€ã«åºã眮æã«ã«ãã¢ã€ã«åºãã¹ã«ãã¢ã¢ã€
ã«åºã眮æã¹ã«ãã¢ã¢ã€ã«åºãªã©ãããã äžèšäžè¬åŒã§ç€ºãããå¡©åºãã¬ã«ãŒãµãŒã®ã
ã¡ã奜ãŸããã¯äžè¬åŒ(A)ã®ååç©ã§ãããã«å¥œãŸ
ããã¯äžè¬åŒ(A)ã§A1ãšA2ãè³éŠç°ãŸãã¯è€çŽ ç°
ã圢æããŠããååç©ã§ãããæã奜ãŸããã¯æ¬¡
ã®äžè¬åŒ(C)ã§ç€ºããããµãªãã«ãããããµã é žã«
ã«ãã¡ãŒãèªå°äœã§ããã äžè¬åŒ(C) äžåŒã«ãããŠãã¯ãã¢ã«ãã«åºã眮æã¢ã«ã
ã«åºãã·ã¯ãã¢ã«ãã«åºãã¢ã«ã±ãã«åºãã¢ã©ã«
ãã«åºãã¢ãªãŒã«åºãã¢ã«ã³ãã·åºã眮æã¢ã«ã³
ãã·åºãã¢ããåºã眮æã¢ããåºãã¢ã·ã«ã¢ãã
åºãã¹ã«ããã«ã¢ããåºãã¢ã·ã«åºããããåºã
ã·ã¢ãåºãããã²ã³ååãã¢ãªãŒã«ãªãã·åºãã«
ã«ãã¢ã€ã«åºã眮æã«ã«ãã¢ã€ã«åºãã¹ã«ãã¢ã¢
ã€ã«åºã眮æã¹ã«ãã¢ã¢ã€ã«åºã®äžããéžã°ãã
眮æåºãè¡šãããïœã¯ïŒãïŒã®æŽæ°ãè¡šãããïœ
ãïŒä»¥äžã®ãšãã¯åãã§ãç°ãªã€ãŠããŠãã
ããã®å ·äœäŸã¯A1ãªããA8ã«ãããŠèšèŒãã
ã®ãšåãã§ããã 奜ãŸããå ·äœäŸã以äžã«ç€ºããã 次ã«æ¬çºæã®å¡©åºãã¬ã«ãŒãµãŒã®åæäŸã«ã€ã
ãŠè¿°ã¹ãã åæäŸ ãµãªãã«ããããã·ãµã é žïŒ®ïŒïŒ®âãžã¡ãã«
ã«ã«ãã¡ãŒã(1) ãµãªãã«ãããããµã é ž15.3ïœãïŒïŒ®âãž
ã¡ãã«ã«ã«ããã«ã¯ããªã10mlã®ãžã¡ãã«ãã«
ã ã¢ãã溶液äžã«å®€æž©äžåŸã ã«ããªãšãã«ã¢ã
ã³14mlãæ·»å ã10æéæ¹æããããããåŒ±é žæ§
æ°·æ°Žäžã«æ³šãæ²ç©ç©ãåã也ç¥ããã åé18ïœ mp.95âïŒâïŒdecïŒ ïŒâããã¢ãµãªãã«ãããããµã é žïŒ®ïŒïŒ®â
ãžã¡ãã«ã«ã«ãã¡ãŒã(7) ïŒâïŒ ïŒâããã¢ãµãªãã«é žããšãã« ïŒâããã¢ãµãªãã«é ž217ïœãããšããŒã«
113ïœã®ãã³ãŒã³æžæ¿æ¶²ã«å¡©åããªãã«80ml
ãåŸã ã«æ·»å ãã10æéå ç±éæµããããã³
ãŒã³ãçå»åŸæ°·æ°Žã泚ãã§æ²ç©ç©ãåã也
ç¥ããã åé210ïœ ïŒâïŒ ïŒâããã¢ãµãªãã«ãããããµã é ž ïŒâïŒ 210ïœãããããã·ã«ã¢ãã³å¡©é ž
å¡©105ïœã®ã¡ã¿ããŒã«æº¶æ¶²ã«æ°Žé žåã«ãªãŠã
127ïœã®ã¡ã¿ããŒã«æº¶æ¶²ãåŸã ã«æ·»å ããã ïŒæéæ¹æåŸæ²ç©ç©ãåããããããæ°Ž
ã«æžæ¿ãããå¡©é žå¡©60mlãæ·»å åŸïŒæéæ¹æ
ãæ²ç©ç©ãåã也ç¥ããã åé136ïœ ïŒâïŒ ïŒâããã¢ãµãªãã«ãããããµã é žïŒ®ïŒ
âãžã¡ãã«ã«ã«ãã¡ãŒã ïŒâïŒ 136ïœãïŒïŒ®âãžã¡ãã«ã«ã«ã
ãã«ã¯ããªã54mlã®ãžã¡ãã«ãã«ã ã¢ãã溶
液äžã«å®€æž©äžåŸã ã«ããªãšãã«ã¢ãã³81mlã
泚ãã10æéæ¹æããããããæ°·æ°Žäžã«æ³šã
æ²ç©ç©ãåã也ç¥ããã åé102ïœ mp.118âïŒâïŒdecïŒ ãµãªãã«ãããããµã é ž ïŒïŒ®âãžããã«
ã«ã«ãã¡ãŒãïŒ38ïŒ ïŒâïŒ ïŒ®ïŒïŒ®âãžããã«ã«ã«ããã«ã¯ããªã ãã¹ã²ã³20ïœãâ40âã«å·åŽãããžã¯ãã
ã¡ã¿ã³æº¶æ¶²ãšããããã«ãžããã«ã¢ãã³8.4
ïœãåŸã ã«æ·»å ãã宀枩æžå§äžéå°ã®ãã¹ã²
ã³ããžã¯ããã¡ã¿ã³ãçå»ããæ°Žâãããµã³
ã§æœåºåŸä¹Ÿç¥ããããµã³ãçå»ããã å
é7.5ïœ ïŒâïŒ ãµãªãã«ãããããµã é žïŒ®ïŒïŒ®âãžãã
ã«ã«ã«ãã¡ãŒã ã®æ¹æ³ã«åŸãããµãªãã«ãããããµã é ž
6.0ïœïŒâïŒã7.5ïœãããªãšãã«ã¢ãã³5.4ml
ãçšãåå¿ããããããæ°·æ°Žäžã«æ³šãé ¢é žãš
ãã«ã§æœåºã也ç¥åŸã«ã©ã ã¯ãããã°ã©ãã€
ãŒã§ç²Ÿè£œããã åé11.2ïœïŒoilïŒ æ¬çºæã®å¡©åºãã¬ã«ãŒãµãŒã¯ãåºãç¯å²ã§çšã
ãããšãã§ãããå¡åžèãééã«æç®ããŠ40éé
ïŒ ä»¥äžã奜ãŸããã¯30ééïŒ ä»¥äžã®ç¯å²ã§çšãã
ã®ãæå©ã§ããã æ¬çºæã®å¡©åºãã¬ã«ãŒãµãŒã¯ãåç¬ã§ããŸãïŒ
皮以äžã®æ··åç©ãšããŠçšããŠããããããã«å ¬ç¥
ã®å¡©åºãã¬ã«ãŒãµãŒãšçµã¿åãããŠçšããŠãã
ããå ¬ç¥ã®å¡©åºãã¬ã«ãŒãµãŒã®äŸã¯ãè±åœç¹èš±ç¬¬
998949å·ãç±³åœç¹èš±ç¬¬3220846å·ãç¹éæ50â
22625å·çã«èšèŒãããŠããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã§ã¯ç»åé²å åŸ
å®è³ªçã«æ°Žãå«ãŸãªãç¶æ ã§å ç±ããã ãã§éç»
åãšéç»åã«å¯Ÿå¿ããéšåã«æŒãŠå¯åæ§è²çŽ ãšã
åæã«äžããããšãã§ããïŒãããç±çŸåãšã
ããïŒã å³ã¡ãæ¬çºæã®ç±çŸåã«ã©ãŒæå ææãç»åé²
å ããå®è³ªçã«æ°Žãå«ãŸãªãç¶æ ã§å ç±çŸåãã
ãšé²å ãããæå æ§ããã²ã³åéã觊åªãšããŠæ
å æ§ããã²ã³åéãšéå æ§ã®è²çŽ äŸäžæ§ç©è³ªã®é
ã§é žåéå åå¿ãèµ·ãããé²å éšã«éç»åãçã
ãããã®ã¹ãããã«ãããŠè²çŽ äŸäžæ§ç©è³ªã¯ãæ
å æ§ããã²ã³åéã«ããé žåãããé žåäœãšãª
ãããã®çµæ芪氎æ§ã®å¯åæ§è²çŽ ãæŸåºãããé²
å éšã«ãããŠã¯ãéç»åãšå¯åæ§è²çŽ ãšãåŸãã
ãããã®æãå¡©åºãååšãããšäžèšã®åå¿ãä¿é²
ãããããã®å¯åæ§è²çŽ ããäŸãã°è²çŽ åºå®å±€ã«
移åãããããšã«ããè²çŽ åãåŸãããã®ã§ã
ããããããªãããå¡©åºãçŽæ¥æå ææäžã«å«æ
ããããšçµæå®å®æ§ãæªããæ¬çºæã®å¡©åºãã¬ã«
ãŒãµãŒãçšãããšãå ç±ã«ããé«æž©äžã§çŸåãã
éã«ã¯ãããŠå¡©åºãæŸåºããã®ã§ãæå ææã®çµ
æå®å®æ§ãæ¹è¯ããããšãã§ããã 以äžã¯ãã¬åã®ä¹³å€ãçšããå Žåã§ãããããª
ãŒãããžä¹³å€ãçšããå Žåã«ã¯ãæªé²å éšã«éç»
åãšå¯åæ§è²çŽ ãšãåŸããã以å€ã¯ãã¬åä¹³å€ã
çšããå Žåãšåæ§ã§ããã æ¬çºæã®æå æ§ããã²ã³åéãšè²çŽ äŸäžæ§ç©è³ª
ãšã®é žåéå åå¿ããã³åŒãç¶ããŠèµ·ããè²çŽ æŸ
åºåå¿ã¯ãé«æž©äžã§ããããå®è³ªçã«æ°Žãå«ãŸãª
ã也ç¥ç¶æ ã§èµ·ããããšãç¹åŸŽã§ãããããã§é«
æž©äžãšã¯80â以äžã®æž©åºŠæ¡ä»¶ãèšããå®è³ªçã«æ°Ž
ãå«ãŸãªã也ç¥ç¶æ ãšã¯ç©ºæ°äžã®æ°Žåãšã¯å¹³è¡¡ç¶
æ ã«ããããç³»å€ããã®æ°Žã®äŸçµŠã®ãªãç¶æ ãäº
ãããã®ãããªç¶æ âThe theory of the
photographic processâ4th Ed.ïŒEdited by T.
H.JamesïŒMacmillanïŒ374é ã«èšèŒãããŠã
ããå®è³ªçã«æ°Žãå«ãŸãªã也ç¥ç¶æ ã§ãå åãªå
å¿çã瀺ãããšã¯10-3Hgã§ïŒæ¥ç空也ç¥ããè©Š
æã®åå¿çãäœäžããªãããšããã確èªã§ããã åŸæ¥ãè²çŽ æŸåºåå¿ã¯ãããããæ±æ žè©Šè¬ã®æ»
æã«ãããã®ãšèããããPH10以以äžã®é«PHã®æ¶²
äœäžã§è¡ãããã®ãéåžžã§ããããããã«æ¬çºæ
ã®ããã«ãé«æž©äžã§ãããå®è³ªçã«æ°Žãå«ãŸãªã
也ç¥ç¶æ ã§é«ãåå¿çããããããšã¯äºæ³å€ã®ã
ãšã§ããããŸããæ¬çºæã®è²çŽ äŸäžæ§ç©è³ªã¯ãã
ãããè£å©çŸåè¬ã®å©ããåããã«ãããã²ã³å
éãšé žåéå åå¿ãè¡ãããšãã§ãããããã¯æ¹¿
åŒçŸåã§åžžæž©ä»è¿ã®æž©åºŠã§ã®ãããŸã§ã®ç¥èŠãã
ã¯äºæ³å€ã®çµæã§ããã 以äžã®åå¿ã¯ææ©éå¡©é žåå€ãååšãããšç¹ã«
ããé²è¡ããé«ãç»åæ¿åºŠã瀺ãããããã€ãŠæ
æ©éå¡©é žåå€ã䜵åãããããšã¯ç¹ã«å¥œãŸããå®
æœæ æ§ãšãããã æ¬çºæã«çšãããã芪氎æ§æ¡æ£æ§è²çŽ ãæŸåºã
ãéå æ§ã®è²çŽ äŸäžæ§ç©è³ªã¯æ¬¡ã®äžè¬åŒ RaâSO2â ãã ã§è¡šããããã ããã§Raã¯ãããã²ã³åéã«ããé žåããã
ãéå æ§åºè³ªããããããã¯èŠªæ°Žæ§åºããã€ã
ç»å圢æçšè²çŽ éšãããããã è²çŽ äŸäžæ§ç©è³ªRaâSO2âäžã®éå æ§åºè³ª
ïŒRaïŒã¯ãã¢ã»ããããªã«ã溶åªãšããæ¯æé»è§£
質ãšããŠéå¡©çŽ é žãœãŒããçšããããŒã©ãã°ã©ã
åæ³¢é»äœæž¬å®ã«ãããŠé£œåã«ãã¡ã«é»æ¥µã«å¯Ÿãã
é žåéå é»äœã1.2V以äžã§ãããã®ã奜ãŸããã
奜ãŸããéå æ§åºè³ªïŒRaïŒã¯æ¬¡ã®äžè¬åŒïŒïŒ
ãïŒïŒã§ããã ããã§R1 aãR2 aãR3 aãR4 aã¯åã æ°ŽçŽ ååãã¢ã«
ãã«åºãã·ã¯ãã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ã«ã³
ãã·åºãã¢ãªãŒã«ãªãã·åºãã¢ã©ã«ãã«åºãã¢ã·
ã«åºãã¢ã·ã«ã¢ããåºãã¢ã«ãã«ã¹ã«ããã«ã¢ã
ãåºãã¢ãªãŒã«ã¹ã«ããã«ã¢ããåºãã¢ãªãŒã«ãª
ãã·ã¢ã«ãã«åºãã¢ã«ã³ãã·ã¢ã«ãã«åºãâ眮
æã«ã«ãã¢ã€ã«åºãâ眮æã¹ã«ãã¢ã¢ã€ã«åºã
ããã²ã³ååãã¢ã«ãã«ããªåºãã¢ãªãŒã«ããªåº
ã®äžããéžã°ããåºãè¡šããããããã®åºäžã®ã¢
ã«ãã«åºããã³ã¢ãªãŒã«åºéšåã¯ããã«ã¢ã«ã³ã
ã·åºãããã²ã³ååãæ°Žé žåºãã·ã¢ãåºãã¢ã·ã«
åºãã¢ã·ã«ã¢ããåºã眮æã«ã«ãã¢ã€ã«åºã眮æ
ã¹ã«ãã¢ã¢ã€ã«åºãã¢ã«ãã«ã¹ã«ããã«ã¢ãã
åºãã¢ãªãŒã«ã¹ã«ããã«ã¢ããåºã眮æãŠã¬ã€ã
åºãŸãã¯ã«ã«ãã¢ã«ã³ãã·åºã§çœ®æãããŠããŠã
ããã ãŸããRaäžã®æ°Žé žåºããã³ã¢ããåºã¯æ±æ žè©Š
è¬ã®äœçšã«ããåçå¯èœãªä¿è·åºã§ä¿è·ãããŠã
ãŠãããã æ¬çºæã®æŽã«å¥œãŸããæ æ§ã«ãããŠã¯éå æ§åº
質Raã¯æ¬¡åŒïŒïŒã§è¡šããããã ããã§ãã¯æ°Žé žåºåã¯å æ°Žå解ã«ããæ°Žé žåº
ãäžããåºããããããR10 aã¯ã¢ã«ãã«åºåã¯è³
éŠæåºããããããïœã¯ïŒãªããïŒã®æŽæ°ããã
ããã X10ã¯ãïœïŒïŒã®æã¯é»åäŸäžæ§ã®çœ®æåºãã
ããããïœïŒïŒåã¯ïŒã®æã¯ããããåäžã§ãç°
ãªã€ã眮æåºã§ãããããã®ïŒã€ãé»åäŸäžæ§åº
ã®æ第ïŒãããã¯ç¬¬ïŒã®ãã®ã¯ãé»åäŸäžæ§åºå
ã¯ããã²ã³ååã§ãããX10èªèº«ã§çž®åç°ã圢æ
ããŠããŠããOR10 aãšç°ã圢æããŠãŠããããR10 a
ãšX10ã®äž¡è ã®ç·ççŽ æ°ã®åèšã¯ïŒä»¥äžã§ããã æ¬çºæã®åŒïŒïŒã«å«ãŸãããã®ã®ãã¡ããã
ã«å¥œãŸããæ æ§ã«ãããŠã¯ãéå æ§åºè³ªRaã¯æ¬¡
åŒïŒïœïŒããã³ïŒïœïŒã§è¡šããããã ããã§Gaã¯æ°Žé žåºåã¯å æ°Žå解ã«ããæ°Žé žåº
ãäžããåºããããããR11 aåã³R12 aã¯åãã§ã
ç°ã€ãŠããŠããããããããã¢ã«ãã«åºã§ãã
ããåã¯R11 aãšR12 aãé£çµããŠç°ã圢æããŠãã
ããR13 aã¯æ°ŽçŽ åååã¯ã¢ã«ãã«åºããR10 aã¯ã¢
ã«ãã«åºåã¯è³éŠæåºãè¡šãããX11åã³X12ã¯
åãã§ãç°ã€ãŠããããããããæ°ŽçŽ ååãã¢ã«
ãã«åºãã¢ã«ãã«ãªãã·åºãããã²ã³ååãã¢ã·
ã«ã¢ããåºåã¯ã¢ã«ãã«ããªåºãè¡šãããããã«
R10 aãšX12åã¯R10 aãšR13 aãšãé£çµããŠç°ã圢æã
ãŠãããã ããã§Gaã¯æ°Žé žåºããããã¯å æ°Žå解ã«ãã
æ°Žé žåºãäžããåºãR10 aã¯ã¢ã«ãã«ãããã¯è³éŠ
æåºãX2ã¯æ°ŽçŽ ååãã¢ã«ãã«åºãã¢ã«ãã«ãª
ãã·åºãããã²ã³ååãã¢ã·ã«ã¢ããåºåã¯ã¢ã«
ãã«ããªåºãè¡šãããX2ãšR10 aãšãé£çµããŠç°ã
圢æããŠããŠãããã ïŒïŒïŒïŒïœïŒãããã³ïŒïœïŒã«å å«ããã
å ·äœäŸã¯ãUS4055428ãç¹éæ56â12642å·ãã
ãã³å56â16130å·ã«ããããèšèŒãããŠããã æ¬çºæã®ããã«å¥œãŸããå¥ã®æ æ§ã«ãããŠã¯ã
éå æ§åºè³ªïŒRaïŒã¯æ¬¡åŒïŒXIïŒã§è¡šããããã ïŒãã ãã笊å·GaïŒX10ïŒR10 aããã³ïœã¯ãåŒ
ïŒïŒã®GaïŒX10ïŒR10 aïœãšå矩ã§ãããïŒ æ¬çºæã®ïŒXIïŒã«å«ãŸãããã®ã®ãã¡ãããã«
奜ãŸããæ æ§ã«ãããŠã¯ãéå æ§åºè³ªïŒRaïŒã¯
次åŒïŒXIïœïŒãïŒXIïœïŒã§è¡šããããã ãã ã Gaã¯æ°Žé žåºããŸãã¯å æ°Žå解ã«ããæ°Žé žåºã
äžããåºïŒ R21 aããã³R22 aã¯ãåãã§ãç°ãªã€ãŠããŠãã
ããããããã¢ã«ãã«åºãŸãã¯è³éŠæåºãè¡šã
ãïŒR21 aãšR22 aãšãçµåããŠç°ã圢æããŠãã
ãïŒ R25 aã¯ãæ°ŽçŽ ååãã¢ã«ãã«åºãŸãã¯è³éŠæåº
ãè¡šããïŒ R24 aã¯ãã¢ã«ãã«åºãŸãã¯è³éŠæåºãè¡šããïŒ R25 aã¯ãã¢ã«ãã«åºãã¢ã«ã³ãã·åºãã¢ã«ãã«
ããªåºãã¢ãªãŒã«ããªåºãããã²ã³ååããŸãã¯
ã¢ã·ã«ã¢ããåºãè¡šããïŒ ïœã¯ïŒãïŒãŸãã¯ïŒã§ããïŒ R24 aãšR25 aãšãçµåããŠçž®åç°ã圢æããŠããŠ
ãããïŒR21 aãšR24 aãšãçµåããŠçž®åç°ã圢æã
ãŠããŠãããïŒR21 aãšR25 aãšãçµåããŠçž®åç°ã
圢æããŠããŠãããããã€R21 aãR22 aãR23 aãR24 a
ããã³ïŒR25 aïŒpã®åèšççŽ æ°ã¯ïŒãã倧ããã ãã ããGaã¯æ°Žé žåºãŸãã¯å æ°Žå解ã«ããæ°Ž
é žåºãäžããåºïŒ R31 aã¯ã¢ã«ãã«åºãŸãã¯è³éŠæåºãè¡šããïŒ R32 aã¯ã¢ã«ãã«åºãŸãã¯è³éŠæåºãè¡šããïŒ R33 aã¯ã¢ã«ãã«åºãã¢ã«ã³ãã·åºãã¢ã«ãã«ã
ãªåºãã¢ãªãŒã«ããªåºãããã²ã³ååãŸãã¯ã¢ã·
ã«ã¢ããåºãè¡šããïŒ ïœã¯ïŒãïŒãŸãã¯ïŒã§ããïŒ R32 aãšR33 aãšãçµåããŠçž®åç°ã圢æããŠãã
ãïŒR31 aãšR32 aãçµåããŠçž®åç°ã圢æããŠãã
ãïŒR31 aãšR33 aãšãçµåããŠçž®åç°ã圢æããŠã
ãŠãããïŒãã€R31 aãR32 aãïŒR33 aïŒqã®åèšççŽ æ°ã¯
ïŒãã倧ããã åŒäžãGaã¯æ°Žé žåºãåã¯å æ°Žå解ã«ããæ°Žé ž
åºãäžããåºãè¡šããïŒ R41 aã¯ã¢ã«ãã«åºãåã¯è³éŠæåºãè¡šããïŒ R42 aã¯ã¢ã«ãã«åºãã¢ã«ã³ãã·åºãã¢ã«ãã«ã
ãªåºãã¢ãªãŒã«ããªåºãããã²ã³ååããŸãã¯ã¢
ã·ã«ã¢ããåºãè¡šããïŒ ïœã¯ïŒãïŒãŸãã¯ïŒã§ããïŒ
ãããã·ã¡ãã«åºãã¢ããåºã眮æã¢ããåºãã¢
ããã¡ãã«åºã眮æã¢ããã¡ãã«åºãã¡ã«ã«ãã
åºãã¡ã«ã«ããã¡ãã«åºãã«ã«ããã·ã«åºãã«ã«
ãã¢ã€ã«åºã眮æã«ã«ãã¢ã€ã«åºãã¹ã«ãã¢ã¢ã€
ã«åºã眮æã¹ã«ãã¢ã¢ã€ã«åºãªã©ãããã äžèšäžè¬åŒã§ç€ºãããå¡©åºãã¬ã«ãŒãµãŒã®ã
ã¡ã奜ãŸããã¯äžè¬åŒ(A)ã®ååç©ã§ãããã«å¥œãŸ
ããã¯äžè¬åŒ(A)ã§A1ãšA2ãè³éŠç°ãŸãã¯è€çŽ ç°
ã圢æããŠããååç©ã§ãããæã奜ãŸããã¯æ¬¡
ã®äžè¬åŒ(C)ã§ç€ºããããµãªãã«ãããããµã é žã«
ã«ãã¡ãŒãèªå°äœã§ããã äžè¬åŒ(C) äžåŒã«ãããŠãã¯ãã¢ã«ãã«åºã眮æã¢ã«ã
ã«åºãã·ã¯ãã¢ã«ãã«åºãã¢ã«ã±ãã«åºãã¢ã©ã«
ãã«åºãã¢ãªãŒã«åºãã¢ã«ã³ãã·åºã眮æã¢ã«ã³
ãã·åºãã¢ããåºã眮æã¢ããåºãã¢ã·ã«ã¢ãã
åºãã¹ã«ããã«ã¢ããåºãã¢ã·ã«åºããããåºã
ã·ã¢ãåºãããã²ã³ååãã¢ãªãŒã«ãªãã·åºãã«
ã«ãã¢ã€ã«åºã眮æã«ã«ãã¢ã€ã«åºãã¹ã«ãã¢ã¢
ã€ã«åºã眮æã¹ã«ãã¢ã¢ã€ã«åºã®äžããéžã°ãã
眮æåºãè¡šãããïœã¯ïŒãïŒã®æŽæ°ãè¡šãããïœ
ãïŒä»¥äžã®ãšãã¯åãã§ãç°ãªã€ãŠããŠãã
ããã®å ·äœäŸã¯A1ãªããA8ã«ãããŠèšèŒãã
ã®ãšåãã§ããã 奜ãŸããå ·äœäŸã以äžã«ç€ºããã 次ã«æ¬çºæã®å¡©åºãã¬ã«ãŒãµãŒã®åæäŸã«ã€ã
ãŠè¿°ã¹ãã åæäŸ ãµãªãã«ããããã·ãµã é žïŒ®ïŒïŒ®âãžã¡ãã«
ã«ã«ãã¡ãŒã(1) ãµãªãã«ãããããµã é ž15.3ïœãïŒïŒ®âãž
ã¡ãã«ã«ã«ããã«ã¯ããªã10mlã®ãžã¡ãã«ãã«
ã ã¢ãã溶液äžã«å®€æž©äžåŸã ã«ããªãšãã«ã¢ã
ã³14mlãæ·»å ã10æéæ¹æããããããåŒ±é žæ§
æ°·æ°Žäžã«æ³šãæ²ç©ç©ãåã也ç¥ããã åé18ïœ mp.95âïŒâïŒdecïŒ ïŒâããã¢ãµãªãã«ãããããµã é žïŒ®ïŒïŒ®â
ãžã¡ãã«ã«ã«ãã¡ãŒã(7) ïŒâïŒ ïŒâããã¢ãµãªãã«é žããšãã« ïŒâããã¢ãµãªãã«é ž217ïœãããšããŒã«
113ïœã®ãã³ãŒã³æžæ¿æ¶²ã«å¡©åããªãã«80ml
ãåŸã ã«æ·»å ãã10æéå ç±éæµããããã³
ãŒã³ãçå»åŸæ°·æ°Žã泚ãã§æ²ç©ç©ãåã也
ç¥ããã åé210ïœ ïŒâïŒ ïŒâããã¢ãµãªãã«ãããããµã é ž ïŒâïŒ 210ïœãããããã·ã«ã¢ãã³å¡©é ž
å¡©105ïœã®ã¡ã¿ããŒã«æº¶æ¶²ã«æ°Žé žåã«ãªãŠã
127ïœã®ã¡ã¿ããŒã«æº¶æ¶²ãåŸã ã«æ·»å ããã ïŒæéæ¹æåŸæ²ç©ç©ãåããããããæ°Ž
ã«æžæ¿ãããå¡©é žå¡©60mlãæ·»å åŸïŒæéæ¹æ
ãæ²ç©ç©ãåã也ç¥ããã åé136ïœ ïŒâïŒ ïŒâããã¢ãµãªãã«ãããããµã é žïŒ®ïŒ
âãžã¡ãã«ã«ã«ãã¡ãŒã ïŒâïŒ 136ïœãïŒïŒ®âãžã¡ãã«ã«ã«ã
ãã«ã¯ããªã54mlã®ãžã¡ãã«ãã«ã ã¢ãã溶
液äžã«å®€æž©äžåŸã ã«ããªãšãã«ã¢ãã³81mlã
泚ãã10æéæ¹æããããããæ°·æ°Žäžã«æ³šã
æ²ç©ç©ãåã也ç¥ããã åé102ïœ mp.118âïŒâïŒdecïŒ ãµãªãã«ãããããµã é ž ïŒïŒ®âãžããã«
ã«ã«ãã¡ãŒãïŒ38ïŒ ïŒâïŒ ïŒ®ïŒïŒ®âãžããã«ã«ã«ããã«ã¯ããªã ãã¹ã²ã³20ïœãâ40âã«å·åŽãããžã¯ãã
ã¡ã¿ã³æº¶æ¶²ãšããããã«ãžããã«ã¢ãã³8.4
ïœãåŸã ã«æ·»å ãã宀枩æžå§äžéå°ã®ãã¹ã²
ã³ããžã¯ããã¡ã¿ã³ãçå»ããæ°Žâãããµã³
ã§æœåºåŸä¹Ÿç¥ããããµã³ãçå»ããã å
é7.5ïœ ïŒâïŒ ãµãªãã«ãããããµã é žïŒ®ïŒïŒ®âãžãã
ã«ã«ã«ãã¡ãŒã ã®æ¹æ³ã«åŸãããµãªãã«ãããããµã é ž
6.0ïœïŒâïŒã7.5ïœãããªãšãã«ã¢ãã³5.4ml
ãçšãåå¿ããããããæ°·æ°Žäžã«æ³šãé ¢é žãš
ãã«ã§æœåºã也ç¥åŸã«ã©ã ã¯ãããã°ã©ãã€
ãŒã§ç²Ÿè£œããã åé11.2ïœïŒoilïŒ æ¬çºæã®å¡©åºãã¬ã«ãŒãµãŒã¯ãåºãç¯å²ã§çšã
ãããšãã§ãããå¡åžèãééã«æç®ããŠ40éé
ïŒ ä»¥äžã奜ãŸããã¯30ééïŒ ä»¥äžã®ç¯å²ã§çšãã
ã®ãæå©ã§ããã æ¬çºæã®å¡©åºãã¬ã«ãŒãµãŒã¯ãåç¬ã§ããŸãïŒ
皮以äžã®æ··åç©ãšããŠçšããŠããããããã«å ¬ç¥
ã®å¡©åºãã¬ã«ãŒãµãŒãšçµã¿åãããŠçšããŠãã
ããå ¬ç¥ã®å¡©åºãã¬ã«ãŒãµãŒã®äŸã¯ãè±åœç¹èš±ç¬¬
998949å·ãç±³åœç¹èš±ç¬¬3220846å·ãç¹éæ50â
22625å·çã«èšèŒãããŠããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã§ã¯ç»åé²å åŸ
å®è³ªçã«æ°Žãå«ãŸãªãç¶æ ã§å ç±ããã ãã§éç»
åãšéç»åã«å¯Ÿå¿ããéšåã«æŒãŠå¯åæ§è²çŽ ãšã
åæã«äžããããšãã§ããïŒãããç±çŸåãšã
ããïŒã å³ã¡ãæ¬çºæã®ç±çŸåã«ã©ãŒæå ææãç»åé²
å ããå®è³ªçã«æ°Žãå«ãŸãªãç¶æ ã§å ç±çŸåãã
ãšé²å ãããæå æ§ããã²ã³åéã觊åªãšããŠæ
å æ§ããã²ã³åéãšéå æ§ã®è²çŽ äŸäžæ§ç©è³ªã®é
ã§é žåéå åå¿ãèµ·ãããé²å éšã«éç»åãçã
ãããã®ã¹ãããã«ãããŠè²çŽ äŸäžæ§ç©è³ªã¯ãæ
å æ§ããã²ã³åéã«ããé žåãããé žåäœãšãª
ãããã®çµæ芪氎æ§ã®å¯åæ§è²çŽ ãæŸåºãããé²
å éšã«ãããŠã¯ãéç»åãšå¯åæ§è²çŽ ãšãåŸãã
ãããã®æãå¡©åºãååšãããšäžèšã®åå¿ãä¿é²
ãããããã®å¯åæ§è²çŽ ããäŸãã°è²çŽ åºå®å±€ã«
移åãããããšã«ããè²çŽ åãåŸãããã®ã§ã
ããããããªãããå¡©åºãçŽæ¥æå ææäžã«å«æ
ããããšçµæå®å®æ§ãæªããæ¬çºæã®å¡©åºãã¬ã«
ãŒãµãŒãçšãããšãå ç±ã«ããé«æž©äžã§çŸåãã
éã«ã¯ãããŠå¡©åºãæŸåºããã®ã§ãæå ææã®çµ
æå®å®æ§ãæ¹è¯ããããšãã§ããã 以äžã¯ãã¬åã®ä¹³å€ãçšããå Žåã§ãããããª
ãŒãããžä¹³å€ãçšããå Žåã«ã¯ãæªé²å éšã«éç»
åãšå¯åæ§è²çŽ ãšãåŸããã以å€ã¯ãã¬åä¹³å€ã
çšããå Žåãšåæ§ã§ããã æ¬çºæã®æå æ§ããã²ã³åéãšè²çŽ äŸäžæ§ç©è³ª
ãšã®é žåéå åå¿ããã³åŒãç¶ããŠèµ·ããè²çŽ æŸ
åºåå¿ã¯ãé«æž©äžã§ããããå®è³ªçã«æ°Žãå«ãŸãª
ã也ç¥ç¶æ ã§èµ·ããããšãç¹åŸŽã§ãããããã§é«
æž©äžãšã¯80â以äžã®æž©åºŠæ¡ä»¶ãèšããå®è³ªçã«æ°Ž
ãå«ãŸãªã也ç¥ç¶æ ãšã¯ç©ºæ°äžã®æ°Žåãšã¯å¹³è¡¡ç¶
æ ã«ããããç³»å€ããã®æ°Žã®äŸçµŠã®ãªãç¶æ ãäº
ãããã®ãããªç¶æ âThe theory of the
photographic processâ4th Ed.ïŒEdited by T.
H.JamesïŒMacmillanïŒ374é ã«èšèŒãããŠã
ããå®è³ªçã«æ°Žãå«ãŸãªã也ç¥ç¶æ ã§ãå åãªå
å¿çã瀺ãããšã¯10-3Hgã§ïŒæ¥ç空也ç¥ããè©Š
æã®åå¿çãäœäžããªãããšããã確èªã§ããã åŸæ¥ãè²çŽ æŸåºåå¿ã¯ãããããæ±æ žè©Šè¬ã®æ»
æã«ãããã®ãšèããããPH10以以äžã®é«PHã®æ¶²
äœäžã§è¡ãããã®ãéåžžã§ããããããã«æ¬çºæ
ã®ããã«ãé«æž©äžã§ãããå®è³ªçã«æ°Žãå«ãŸãªã
也ç¥ç¶æ ã§é«ãåå¿çããããããšã¯äºæ³å€ã®ã
ãšã§ããããŸããæ¬çºæã®è²çŽ äŸäžæ§ç©è³ªã¯ãã
ãããè£å©çŸåè¬ã®å©ããåããã«ãããã²ã³å
éãšé žåéå åå¿ãè¡ãããšãã§ãããããã¯æ¹¿
åŒçŸåã§åžžæž©ä»è¿ã®æž©åºŠã§ã®ãããŸã§ã®ç¥èŠãã
ã¯äºæ³å€ã®çµæã§ããã 以äžã®åå¿ã¯ææ©éå¡©é žåå€ãååšãããšç¹ã«
ããé²è¡ããé«ãç»åæ¿åºŠã瀺ãããããã€ãŠæ
æ©éå¡©é žåå€ã䜵åãããããšã¯ç¹ã«å¥œãŸããå®
æœæ æ§ãšãããã æ¬çºæã«çšãããã芪氎æ§æ¡æ£æ§è²çŽ ãæŸåºã
ãéå æ§ã®è²çŽ äŸäžæ§ç©è³ªã¯æ¬¡ã®äžè¬åŒ RaâSO2â ãã ã§è¡šããããã ããã§Raã¯ãããã²ã³åéã«ããé žåããã
ãéå æ§åºè³ªããããããã¯èŠªæ°Žæ§åºããã€ã
ç»å圢æçšè²çŽ éšãããããã è²çŽ äŸäžæ§ç©è³ªRaâSO2âäžã®éå æ§åºè³ª
ïŒRaïŒã¯ãã¢ã»ããããªã«ã溶åªãšããæ¯æé»è§£
質ãšããŠéå¡©çŽ é žãœãŒããçšããããŒã©ãã°ã©ã
åæ³¢é»äœæž¬å®ã«ãããŠé£œåã«ãã¡ã«é»æ¥µã«å¯Ÿãã
é žåéå é»äœã1.2V以äžã§ãããã®ã奜ãŸããã
奜ãŸããéå æ§åºè³ªïŒRaïŒã¯æ¬¡ã®äžè¬åŒïŒïŒ
ãïŒïŒã§ããã ããã§R1 aãR2 aãR3 aãR4 aã¯åã æ°ŽçŽ ååãã¢ã«
ãã«åºãã·ã¯ãã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ã«ã³
ãã·åºãã¢ãªãŒã«ãªãã·åºãã¢ã©ã«ãã«åºãã¢ã·
ã«åºãã¢ã·ã«ã¢ããåºãã¢ã«ãã«ã¹ã«ããã«ã¢ã
ãåºãã¢ãªãŒã«ã¹ã«ããã«ã¢ããåºãã¢ãªãŒã«ãª
ãã·ã¢ã«ãã«åºãã¢ã«ã³ãã·ã¢ã«ãã«åºãâ眮
æã«ã«ãã¢ã€ã«åºãâ眮æã¹ã«ãã¢ã¢ã€ã«åºã
ããã²ã³ååãã¢ã«ãã«ããªåºãã¢ãªãŒã«ããªåº
ã®äžããéžã°ããåºãè¡šããããããã®åºäžã®ã¢
ã«ãã«åºããã³ã¢ãªãŒã«åºéšåã¯ããã«ã¢ã«ã³ã
ã·åºãããã²ã³ååãæ°Žé žåºãã·ã¢ãåºãã¢ã·ã«
åºãã¢ã·ã«ã¢ããåºã眮æã«ã«ãã¢ã€ã«åºã眮æ
ã¹ã«ãã¢ã¢ã€ã«åºãã¢ã«ãã«ã¹ã«ããã«ã¢ãã
åºãã¢ãªãŒã«ã¹ã«ããã«ã¢ããåºã眮æãŠã¬ã€ã
åºãŸãã¯ã«ã«ãã¢ã«ã³ãã·åºã§çœ®æãããŠããŠã
ããã ãŸããRaäžã®æ°Žé žåºããã³ã¢ããåºã¯æ±æ žè©Š
è¬ã®äœçšã«ããåçå¯èœãªä¿è·åºã§ä¿è·ãããŠã
ãŠãããã æ¬çºæã®æŽã«å¥œãŸããæ æ§ã«ãããŠã¯éå æ§åº
質Raã¯æ¬¡åŒïŒïŒã§è¡šããããã ããã§ãã¯æ°Žé žåºåã¯å æ°Žå解ã«ããæ°Žé žåº
ãäžããåºããããããR10 aã¯ã¢ã«ãã«åºåã¯è³
éŠæåºããããããïœã¯ïŒãªããïŒã®æŽæ°ããã
ããã X10ã¯ãïœïŒïŒã®æã¯é»åäŸäžæ§ã®çœ®æåºãã
ããããïœïŒïŒåã¯ïŒã®æã¯ããããåäžã§ãç°
ãªã€ã眮æåºã§ãããããã®ïŒã€ãé»åäŸäžæ§åº
ã®æ第ïŒãããã¯ç¬¬ïŒã®ãã®ã¯ãé»åäŸäžæ§åºå
ã¯ããã²ã³ååã§ãããX10èªèº«ã§çž®åç°ã圢æ
ããŠããŠããOR10 aãšç°ã圢æããŠãŠããããR10 a
ãšX10ã®äž¡è ã®ç·ççŽ æ°ã®åèšã¯ïŒä»¥äžã§ããã æ¬çºæã®åŒïŒïŒã«å«ãŸãããã®ã®ãã¡ããã
ã«å¥œãŸããæ æ§ã«ãããŠã¯ãéå æ§åºè³ªRaã¯æ¬¡
åŒïŒïœïŒããã³ïŒïœïŒã§è¡šããããã ããã§Gaã¯æ°Žé žåºåã¯å æ°Žå解ã«ããæ°Žé žåº
ãäžããåºããããããR11 aåã³R12 aã¯åãã§ã
ç°ã€ãŠããŠããããããããã¢ã«ãã«åºã§ãã
ããåã¯R11 aãšR12 aãé£çµããŠç°ã圢æããŠãã
ããR13 aã¯æ°ŽçŽ åååã¯ã¢ã«ãã«åºããR10 aã¯ã¢
ã«ãã«åºåã¯è³éŠæåºãè¡šãããX11åã³X12ã¯
åãã§ãç°ã€ãŠããããããããæ°ŽçŽ ååãã¢ã«
ãã«åºãã¢ã«ãã«ãªãã·åºãããã²ã³ååãã¢ã·
ã«ã¢ããåºåã¯ã¢ã«ãã«ããªåºãè¡šãããããã«
R10 aãšX12åã¯R10 aãšR13 aãšãé£çµããŠç°ã圢æã
ãŠãããã ããã§Gaã¯æ°Žé žåºããããã¯å æ°Žå解ã«ãã
æ°Žé žåºãäžããåºãR10 aã¯ã¢ã«ãã«ãããã¯è³éŠ
æåºãX2ã¯æ°ŽçŽ ååãã¢ã«ãã«åºãã¢ã«ãã«ãª
ãã·åºãããã²ã³ååãã¢ã·ã«ã¢ããåºåã¯ã¢ã«
ãã«ããªåºãè¡šãããX2ãšR10 aãšãé£çµããŠç°ã
圢æããŠããŠãããã ïŒïŒïŒïŒïœïŒãããã³ïŒïœïŒã«å å«ããã
å ·äœäŸã¯ãUS4055428ãç¹éæ56â12642å·ãã
ãã³å56â16130å·ã«ããããèšèŒãããŠããã æ¬çºæã®ããã«å¥œãŸããå¥ã®æ æ§ã«ãããŠã¯ã
éå æ§åºè³ªïŒRaïŒã¯æ¬¡åŒïŒXIïŒã§è¡šããããã ïŒãã ãã笊å·GaïŒX10ïŒR10 aããã³ïœã¯ãåŒ
ïŒïŒã®GaïŒX10ïŒR10 aïœãšå矩ã§ãããïŒ æ¬çºæã®ïŒXIïŒã«å«ãŸãããã®ã®ãã¡ãããã«
奜ãŸããæ æ§ã«ãããŠã¯ãéå æ§åºè³ªïŒRaïŒã¯
次åŒïŒXIïœïŒãïŒXIïœïŒã§è¡šããããã ãã ã Gaã¯æ°Žé žåºããŸãã¯å æ°Žå解ã«ããæ°Žé žåºã
äžããåºïŒ R21 aããã³R22 aã¯ãåãã§ãç°ãªã€ãŠããŠãã
ããããããã¢ã«ãã«åºãŸãã¯è³éŠæåºãè¡šã
ãïŒR21 aãšR22 aãšãçµåããŠç°ã圢æããŠãã
ãïŒ R25 aã¯ãæ°ŽçŽ ååãã¢ã«ãã«åºãŸãã¯è³éŠæåº
ãè¡šããïŒ R24 aã¯ãã¢ã«ãã«åºãŸãã¯è³éŠæåºãè¡šããïŒ R25 aã¯ãã¢ã«ãã«åºãã¢ã«ã³ãã·åºãã¢ã«ãã«
ããªåºãã¢ãªãŒã«ããªåºãããã²ã³ååããŸãã¯
ã¢ã·ã«ã¢ããåºãè¡šããïŒ ïœã¯ïŒãïŒãŸãã¯ïŒã§ããïŒ R24 aãšR25 aãšãçµåããŠçž®åç°ã圢æããŠããŠ
ãããïŒR21 aãšR24 aãšãçµåããŠçž®åç°ã圢æã
ãŠããŠãããïŒR21 aãšR25 aãšãçµåããŠçž®åç°ã
圢æããŠããŠãããããã€R21 aãR22 aãR23 aãR24 a
ããã³ïŒR25 aïŒpã®åèšççŽ æ°ã¯ïŒãã倧ããã ãã ããGaã¯æ°Žé žåºãŸãã¯å æ°Žå解ã«ããæ°Ž
é žåºãäžããåºïŒ R31 aã¯ã¢ã«ãã«åºãŸãã¯è³éŠæåºãè¡šããïŒ R32 aã¯ã¢ã«ãã«åºãŸãã¯è³éŠæåºãè¡šããïŒ R33 aã¯ã¢ã«ãã«åºãã¢ã«ã³ãã·åºãã¢ã«ãã«ã
ãªåºãã¢ãªãŒã«ããªåºãããã²ã³ååãŸãã¯ã¢ã·
ã«ã¢ããåºãè¡šããïŒ ïœã¯ïŒãïŒãŸãã¯ïŒã§ããïŒ R32 aãšR33 aãšãçµåããŠçž®åç°ã圢æããŠãã
ãïŒR31 aãšR32 aãçµåããŠçž®åç°ã圢æããŠãã
ãïŒR31 aãšR33 aãšãçµåããŠçž®åç°ã圢æããŠã
ãŠãããïŒãã€R31 aãR32 aãïŒR33 aïŒqã®åèšççŽ æ°ã¯
ïŒãã倧ããã åŒäžãGaã¯æ°Žé žåºãåã¯å æ°Žå解ã«ããæ°Žé ž
åºãäžããåºãè¡šããïŒ R41 aã¯ã¢ã«ãã«åºãåã¯è³éŠæåºãè¡šããïŒ R42 aã¯ã¢ã«ãã«åºãã¢ã«ã³ãã·åºãã¢ã«ãã«ã
ãªåºãã¢ãªãŒã«ããªåºãããã²ã³ååããŸãã¯ã¢
ã·ã«ã¢ããåºãè¡šããïŒ ïœã¯ïŒãïŒãŸãã¯ïŒã§ããïŒ
ãåŒãåºã¯ïŒãïŒåã®é£œåçåæ°ŽçŽ ç°ãçž®
åãããã®ãè¡šããããããããšããŒã«ïŒåã¯ã
ã®åé§äœïŒæ¯æ žãžã®çµåã«ããããçž®åç°äžã®ç
ååå
ã®åé§äœïŒæ¯æ žãžã®çµåã«ããããçž®åç°äžã®ç
ååå
ãåŒãã¯çž®åç°ã®äžã€ã®èŠçŽ ãæ§æ
ããäžçŽççŽ ååã§ããããŸã該çåæ°ŽçŽ ç°äžã®
ççŽ ååïŒäœããåèšã®äžçŽççŽ ååã¯é€ãïŒã®
äžéšã¯é žçŽ ååã§çœ®æãããŠããŠããããæãã¯
該çåæ°ŽçŽ é¡ã«ã¯çœ®æåºãã€ããŠããŠããããã
åæŽã«è³éŠæç°ãçž®åããŠããŠãããïŒ R41 aåã¯R42 aãšåèšã®
ççŽ ååïŒäœããåèšã®äžçŽççŽ ååã¯é€ãïŒã®
äžéšã¯é žçŽ ååã§çœ®æãããŠããŠããããæãã¯
該çåæ°ŽçŽ é¡ã«ã¯çœ®æåºãã€ããŠããŠããããã
åæŽã«è³éŠæç°ãçž®åããŠããŠãããïŒ R41 aåã¯R42 aãšåèšã®
ãåŒãåºãšã¯çž®åç°
ã圢æããŠããããäœããR41 aãïŒR42 aïŒrãš
ãåŒãåºã®åèšççŽ æ°ã¯ïŒä»¥äžã§ããã
äžèšïŒXIïŒïŒïŒXIïœïŒãïŒXIïœïŒã«å
å«ãããå
·
äœäŸã¯ç¹é¡æ56â16131ãå57â650ãå57â4043
ã«èšèŒãããŠããã åŒïŒïŒããã³åŒïŒïŒã®æ¬è³ªçãªéšåã¯ãã©
âïŒã¹ã«ããã«ïŒã¢ããããšããŒã«éšåã§ããã
å ·äœçãªäŸãšããŠã¯ãUS3928312ãUS4076529ã
US Published Patent Application  351673ã
US4135929ãUS4258120ã«é瀺ãããéå æ§åºè³ª
ããããããããããããæ¬çºæã®éå æ§åºè³ª
ïŒRaïŒãšããŠæå¹ã§ããã æ¬çºæã®ããã«å¥œãŸããå¥ã®æ æ§ã«ãããŠã¯ã
éå æ§åºè³ªïŒRaïŒã¯æ¬¡åŒïŒïŒã§è¡šããããã ããã§ãBallastã¯èæ¡æ£æ§åºãããããã Gaã¯ãæ°Žé žåºåã¯æ°Žé žåºã®ãã¬ã«ãŒãµãŒãè¡š
ããã G1 aã¯ãè³éŠæç°ããããããã³ãŒã³ç°ãšãšã
ã«ããã¿ã¬ã³ç°ã圢æããåºããããããïœãã
ã³ïœã¯ïŒåã¯ïŒã®ããšãªã€ãæŽæ°ãããããã äžèšXIIã«å å«ãããå ·äœäŸã¯US4053312ã«èšèŒ
ãããŠããã åŒïŒïŒïŒïŒïŒïŒïŒïŒããã³ïŒïŒã®éå æ§åº
質ã¯ããããç°ãå«ãããšãç¹åŸŽã§ãããå ·äœç
ãªäŸãšããŠã¯ãUS4198235ãç¹éæ53â46730ã
US4273855ã«èšèŒãããŠãããã®ããããããã
åŒïŒïŒã§è¡šããããéå æ§åºè³ªã®å ·äœäŸã¯
US4149892ã«èšèŒãããã éå æ§åºè³ªRaã«èŠæ±ãããç¹æ§ãšããŠæ¬¡ã®ã
ã®ãæããããã ïŒ ããã²ã³åéã«ããéãã«é žåãããè²çŽ æŸ
åºå©å€ã®äœçšã«ãã€ãŠå¹çããç»å圢æçšã®æ¡
æ£æ§è²çŽ ãæŸåºããããšã ïŒ è²çŽ äŸäžæ§ç©è³ªã¯èŠªæ°Žæ§ãªããçæ°Žæ§ãã€ã³
ããŒäžã§èæ¡æ£æ§ã§ãããæŸåºãããè²çŽ ã®ã¿
ãæ¡æ£æ§ãæããããšãå¿ èŠã§ããããã®ã
ããéå æ§åºè³ªïŒ²ã¯å€§ããªçæ°Žæ§ãæããã
ãšã ïŒ ç±ããã³è²çŽ æŸåºå©å€ã«å¯Ÿããå®å®æ§ãåª
ããé žåããããŸã§ã¯ç»å圢æçšè²çŽ ãæŸåºã
ãªãããšã ïŒ åæã容æãªããš ãªã©ãæããããã 次ã«ãããã®æ¡ä»¶ãæºããRaã«ã€ããŠã®å¥œãŸ
ããå ·äœäŸã瀺ããäŸäžãNHâã¯è²çŽ éšãšã®é£
çµãè¡šããã ç»å圢æçšè²çŽ ã«å©çšã§ããè²çŽ ã«ã¯ã¢ãŸè²
çŽ ãã¢ãŸã¡ãã³è²çŽ ãã¢ã³ãã«ããã³è²çŽ ããã
ãããã³è²çŽ ãã¹ããªã«è²çŽ ããããè²çŽ ããã
ãªã³è²çŽ ãã«ã«ããã«è²çŽ ããã¿ãã·ã¢ãã³è²çŽ
ãªã©ãããããã®ä»£è¡šäŸãè²çŽ å¥ã«ç€ºãããªãã
ãããã®è²çŽ ã¯çŸååŠçæã«è€è²å¯èœãªãäžæç
ã«çæ³¢åãã圢ã§çšãããšãã§ããã äžåŒã«ãããŠR51 aãR56 aã¯ãåã æ°ŽçŽ ååãã¢
ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºãã¢ã©ã«ãã«åºãã¢
ã«ã³ãã·åºãã¢ãªãŒã«ãªãã·åºãã¢ãªãŒã«åºãã¢
ã·ã«ã¢ããåºãã¢ã·ã«åºãã·ã¢ãåºãæ°Žé žåºãã¢
ã«ãã«ã¹ã«ããã«ã¢ããåºãã¢ãªãŒã«ã¹ã«ããã«
ã¢ããåºãã¢ã«ãã«ã¹ã«ããã«åºãããããã·ã¢
ã«ãã«åºãã·ã¢ãã¢ã«ãã«åºãã¢ã«ã³ãã·ã«ã«ã
ãã«ã¢ã«ãã«åºãã¢ã«ã³ãã·ã¢ã«ãã«åºãã¢ãªãŒ
ã«ãªãã·ã¢ã«ãã«åºããããåºãããã²ã³ãã¹ã«
ãã¢ã¢ã€ã«åºãâ眮æã¹ã«ãã¢ã¢ã€ã«åºãã«ã«
ãã¢ã€ã«åºãâ眮æã«ã«ãã¢ã€ã«åºãã¢ã·ãŒã«
ãªãã·ã¢ã«ãã«åºãã¢ããåºã眮æã¢ããåºãã¢
ã«ãã«ããªåºãã¢ãªãŒã«ããªåºãã®äžããéžã°ã
ã眮æåºãè¡šããããããã®çœ®æåºäžã®ã¢ã«ãã«
åºããã³ã¢ãªãŒã«åºéšåã¯ããã«ããã²ã³ååã
æ°Žé žåºãã·ã¢ãåºãã¢ã·ã«åºãã¢ã·ã«ã¢ããåºã
ã¢ã«ã³ãã·åºãã«ã«ãã¢ã€ã«åºã眮æã«ã«ãã¢ã€
ã«åºãã¹ã«ãã¢ã¢ã€ã«åºã眮æã¹ã«ãã¢ã¢ã€ã«
åºãã«ã«ããã·ã«åºãã¢ã«ãã«ã¹ã«ããã«ã¢ãã
åºãã¢ãªãŒã«ã¹ã«ããã«ã¢ããåºãŸãã¯ãŠã¬ã€ã
åºã§çœ®æãããŠããŠãããã 芪氎æ§åºãšããŠã¯æ°Žé žåºãã«ã«ããã·ã«åºãã¹
ã«ãåºããªã³é žåºãã€ããåºããããããµã é ž
åºãåçŽã¢ã³ã¢ããŠã åºãã«ã«ãã¢ã€ã«åºã眮æ
ã«ã«ãã¢ã€ã«åºãã¹ã«ãã¢ã¢ã€ã«åºã眮æã¹ã«ã
ã¢ã¢ã€ã«åºãã¹ã«ãã¢ã¢ã€ã«ã¢ããåºã眮æã¹ã«
ãã¢ã¢ã€ã«ã¢ããåºããŠã¬ã€ãåºã眮æãŠã¬ã€ã
åºãã¢ã«ã³ãã·åºãããããã·ã¢ã«ã³ãã·åºãã¢
ã«ã³ãã·ã¢ã«ã³ãã·åºãªã©ãæããããã æ¬çºæã«ãããŠã¯ç¹ã«å¡©åºæ§æ¡ä»¶äžã§ãããã³
解é¢ããããšã«ãã芪氎æ§ãèããå¢å€§ãããã®
ã奜ãŸãããã®äžã«ã¯ããšããŒã«æ§æ°Žé žåºãã«ã«
ããã·ã«åºãã¹ã«ãåºããªã³é žåºãã€ããåºãã
ããããµã é žåºãïŒçœ®æïŒã¹ã«ãã¢ã¢ã€ã«åºãïŒçœ®
æïŒã¹ã«ãã¢ã¢ã€ã«ã¢ããåºãªã©ãå«ãŸããã ç»å圢æçšè²çŽ ã«èŠæ±ãããç¹æ§ã¯ãïŒïŒè²å
çŸã«é©ããè²çžãæããããšãïŒïŒåååžå ä¿æ°
ã倧ããããšãïŒïŒå ãç±ããã³ç³»äžã«å«ãŸãã
è²çŽ æŸåºå©å€ãã®ä»ã®æ·»å å€ã«å¯ŸããŠå®å®ãªã
ãšãïŒïŒåæã容æãªããšããªã©ãæããããã
ãããã®è«žæ¡ä»¶ãæºãã奜ãŸããç»å圢æçšè²çŽ
ã®å ·äœäŸã次ã«ç€ºããããã§H2NâSO2ã¯éå æ§
åºè³ªãšã®çµåéšãè¡šããã 次ã«å¥œãŸããè²çŽ äŸäžæ§ç©è³ªã®å ·äœäŸã瀺ãã æ¬çºæã®è²çŽ äŸäžæ§ç©è³ªãšããŠãäžèšã®å ·äœäŸ
ã®ã»ãã«ãUS4055428ãç¹éæ56â12642ãå56
â16130ãå56â16131ãå57â650ãå57â4043ã
US3928312ãUS4076529ãUS Published Patent
Application B351673ãUS4135929ã
US4198235ãç¹éæ53â46730ãUS4273855ã
US4149892ãUS4142891ãUS4258120ãªã©ã«èšèŒ
ãããŠããååç©ãæå¹ã§ããã ããã«ãUS4013633ãUS4156609ã
US4148641ãUS4165987ãUS4148643ã
US4183755ãUS4246414ãUS4268625ã
US4245028ãç¹éæ56â71072ãå56â25737ãå
55â138744ãå55â134849ãå52â109727ãå51
â114930ãªã©ã«èšèŒãããã€ãšããŒè²çŽ ãæŸåºã
ãè²çŽ äŸäžæ§ç©è³ªãæ¬çºæã«æå¹ã§ããããŸã
US3954476ãUS4932380ãUS3931144ã
US3932381ãUS4268624ãUS4255509ãç¹éæ56
â73057ãå56â71060ãå55â134850ãå55â
40402ãå55â36804ãå53â23628ãå52â
106727ãå55â33142ãå55â53329ãªã©ãããã
ããããŒã³ã¿è²çŽ ãæŸåºããè²çŽ äŸäžæ§ç©è³ªãæ¬
çºæã«æå¹ã§ããããŸãUS3929760ã
US4013635ãUS3942987ãUS4273708ã
US4148642ãUS4183754ãUS4147544ã
US4165238ãUS4246414ãUS4268625ãç¹éæ56
â71061ãå53â47823ãå52â8827ãå53â
143323ãªã©ã«ãããããã·ã¢ã³è²çŽ ãæŸåºããè²
çŽ äŸäžæ§ç©è³ªãæ¬çºæã«æå¹ã§ããã è²çŽ äŸäžæ§ç©è³ªã¯ãïŒçš®ä»¥äžäœµçšããŠãããã
ãã®å Žåãåäžè²çŽ ãããããæã«ïŒçš®ä»¥äžäœµçš
ããŠããããïŒçš®ä»¥äžã䜵çšããŠé»ãããããå Ž
åãå«ãŸããã è²çŽ äŸäžæ§ç©è³ªã¯åèšãšããŠã10mgïŒm2ãã15
ïœïŒm2ã®ç¯å²ã§çšããã®ãé©åœã§ããã奜ãŸãã
ã¯20mgïŒm2ãã10ïœïŒm2ã®ç¯å²ã§çšããã®ãæå©
ã§ããã 次ã«è²çŽ äŸäžæ§ç©è³ªã®åææ³ã«ã€ããŠè¿°ã¹ãã äžè¬ã«æ¬çºæã®è²çŽ äŸäžæ§ç©è³ªã¯éå æ§åºè³ª
Raã®ã¢ããåºãšç»å圢æçšè²çŽ éšã®ã¯ããã¹ã«
ããã«åºãçž®åãããããšã«ãã€ãŠåŸãããã éå æ§åºè³ªRaã®ã¢ããåºã¯åºè³ªã®çš®é¡ã«å¿ã
ãŠããããããããœãã¢ãŸåºã®éå ãããã¯ãã³
ãŸãªããµãŸãŒã«ã®éç°ã«ãã€ãŠå°å ¥ããããšãã§
ããéé¢å¡©åºãšããŠããç¡æ©é žã®å¡©ãšããŠã䜿çš
ã§ãããäžæ¹ãç»å圢æçšè²çŽ éšã®ã¯ããã¹ã«ã
ãã«åºã¯è©²è²çŽ ã®ã¹ã«ãã³é žãªããã¹ã«ãã³é žå¡©
ããåžžæ³ããªãã¡ããªãã·å¡©åãªã³ãäºå¡©åãª
ã³ãå¡©åããªãã«çã®ã¯ããåå€ã®äœçšã«ããèª
å°ã§ããã éå æ§åºè³ªRaãšç»å圢æçšè²çŽ éšïŒ€ãšã®çž®å
åå¿ã¯ãäžè¬ã«ãžã¡ãã«ãã«ã ã¢ããããžã¡ãã«
ã¢ã»ãã¢ããããžã¡ãã«ã¹ã«ããã·ããâã¡ã
ã«ãããªãã³ãã¢ã»ããããªã«çã®éãããã³æ§
極æ§æº¶åªäžãããªãžã³ããã³ãªã³ãã«ããžã³ãã
ãªãšãã«ã¢ãã³ããžã€ãœãããã«ãšãã«ã¢ãã³ç
ã®ææ©å¡©åºã®ååšäžãïŒã50âã®æž©åºŠã è¡ãããš
ãã§ããéåžžã極ããŠåçè¯ãç®çãšããè²çŽ äŸ
äžæ§ç©è³ªãåŸãããšãã§ããã 以äžã«ãã®åæäŸã瀺ãã åæäŸ ïŒ ïŒâããããã·âïŒâã¡ãã«ãã³ãŸãªããµãŸãŒ
ã«ã®åæ ïŒïŒïŒâãžããããã·ã¢ã»ãããšãã³306ïœã
ããããã·ã«ã¢ãã³å¡©é žå¡©164ïœãé ¢é žãããªãŠ
ã 328ïœããšã¿ããŒã«1000mlãããã³æ°Ž500mlãæ··
åããïŒæéå ç±éæµãããåå¿æ¶²ãæ°Ž10ã«ã
ããæåºããçµæ¶ãåããŠãïŒïŒïŒâãžããã
ãã·ã¢ã»ãããšãã³ãªãã·ã 314ïœãåŸãã ãã®ãªãã·ã 30ïœãé ¢é ž400mlã«æº¶è§£ãã120â
ã«ãŠå ç±æ¹æããªãããïŒæéå¡©åæ°ŽçŽ ã¬ã¹ãå¹
蟌ãã ãå·åŽåŸæåºããçµæ¶ãåãã次ãã§æ°Ž
ã§æŽæµããŠãïŒâããããã·âïŒâã¡ãã«ãã³ãº
ãªããµãŸãŒã«17ïœãåŸãã åæå ïŒ ïŒâãããµãã·ã«ãªãã·âïŒâã¡ãã«ãã³ãŸãª
ããµãŸãŒã«ã®åæ åæäŸïŒã§åæããïŒâããããã·âïŒâã¡ã
ã«ãã³ãºãªããµãŸãŒã«18.0ïœãïŒâããã¢ãããµ
ãã«ã³36.9ïœãçé žã«ãªãŠã 24.0ïœãïŒïŒ®âãž
ã¡ãã«ãã«ã ã¢ãã120mlã90âã§4.5æéæ¹æã
ããåå¿æ¶²ãããåºäœãå¥ãã液ãã¡ã¿ããŒ
ã«500mlã«ããããæåºããçµæ¶ãåããŠãïŒ
âãããµãã·ã«ãªãã·âïŒâã¡ãã«ãã³ãºãªããµ
ãŸãŒã«45.0ïœãåŸãã åæäŸ ïŒ ïŒâã¢ã»ãã«ã¢ããâïŒâãããµãã·ã«ãªãã·
ããšããŒã«ã®åæ åæäŸïŒã§åŸãïŒâãããµãã·ã«ãªãã·âïŒâ
ã¡ãã«ãã³ãºãªããµãŸãŒã«111ïœããšã¿ããŒã«
1300mlã33ïŒ å¡©é ž110mlãæ°Ž550mlãæ··åãã55ã
60âã§ïŒæéæ¹æãããå·åŽåŸæåºããçµæ¶ã
åãïŒâã¢ã»ãã«ã¢ããâïŒâãããµãã·ã«ãªã
ã·ããšããŒã«113ïœãåŸãã åæäŸ ïŒ ïŒâã¢ã»ãã«ã¢ããâïŒâïœâããã«âïŒâã
ããµãã·ã«ãªãã·ããšããŒã«ã®åæ åæäŸïŒã§åŸãïŒâã¢ã»ãã«ã¢ããâïŒâãã
ãµãã·ã«ãªãã·ããšããŒã«30.0ïœãã¢ã³ããŒãªã¹
ã15ïŒç±³åœã»ããŒã ã»ã¢ã³ãã»ããŒã¹ç€Ÿç»é²åæšïŒ
20.0ïœããã«ãšã³300mlãæ··åãã80ã90âã§å
ç±æ¹æããªãããã€ãœããã³ãïŒæéå¹ã蟌ã
ã ãåºäœãå»ããã®ã¡ã液ãæ¿çž®ããæ®æž£ã«
ïœâãããµã³350mlãå ãããšçµæ¶ãæåºããã
åããŠãïŒâã¢ã»ãã«ã¢ããâïŒâïœâããã«
âïŒâãããµãã·ã«ãªãã·ããšããŒã«23.5ïœãåŸ
ãã åæäŸ ïŒ ïŒâã¢ããâïŒâïœâããã«âïŒâãããµãã·
ã«ãªãã·ããšããŒã«ã®åæ åæäŸïŒã§åŸãïŒâã¢ã»ãã«ã¢ããâïŒâïœâ
ããã«âïŒâãããµãã·ã«ãªãã·ããšããŒã«23.0
ïœããšã¿ããŒã«120mlã35ïŒ å¡©é ž96mlãæ··åãã
ïŒæéæ¹æéæµãããåå¿æ¶²ãå·åŽããã®ã¡ãæ
åºããçµæ¶ãåããŠãïŒâã¢ããâïŒâïœâã
ãã«âïŒâãããµãã·ã«ãªãã·ããšããŒã«å¡©é žå¡©
23.2ïœãåŸãã åæäŸ ïŒ ïŒâïœâããã«âïŒâãããµãã·ã«ãªãã·âïŒ
âãïŒâïŒïŒâã¡ããã·ãšããã·ïŒâïŒâãã
ããã³ãŒã³ã¹ã«ããã«ã¢ãããããšããŒã«ã®å
æ åæäŸïŒã§åŸãïŒâã¢ããâïŒâïœâããã«â
ïŒâãããµãã·ã«ãªãã·ããšããŒã«å¡©é žå¡©4.4ïœ
ããã³ïŒâïŒïŒâã¡ããã·ãšããã·ïŒâïŒâãã
ããã³ãŒã³ã¹ã«ããã«ã¯ããªã3.18ïœãïŒïŒ®â
ãžã¡ãã«ã¢ã»ãã¢ãã12mlã«æº¶è§£ããããªãžã³
2.5mlãå ããã®ã¡ãïŒæé25âã§æ¹æãããå
å¿æ¶²ãçšå¡©é žã«ãããå ¥ãããšæ²¹ç¶ç©ãæåºã
ãããã®æ²¹ç¶ç©ã«ã¡ã¿ããŒã«30mlãå ãããšçµæ¶
åããã®ã§ãããåããã åé4.5ïœã åæäŸ ïŒ ïŒâãïŒâã¢ããâïŒâïŒïŒâã¡ããã·ãšãã
ã·ïŒãã³ãŒã³ã¹ã«ããã«ã¢ãããâïŒâïœâã
ãã«âïŒâãããµãã·ã«ãªãã·ããšããŒã«ã®å
æ äžèšåæäŸïŒã§åŸãååç©10ïœããšã¿ããŒã«60
mlã«æº¶è§£ãã10ïŒ ãã©ãžãŠã âççŽ è§ŠåªçŽ0.5ïœ
ãæ·»å ããã®ã¡ãæ°ŽçŽ ã55KgïŒcm2ãŸã§å§å ¥ãã60
âã§ïŒæéæ¹æããã次ãã§ã觊åªãç±æå»
ããæŸå·ãããšçµæ¶ãæåºããã®ã§åããã åé7.5ïœã åæäŸ ïŒ ïŒâã·ã¢ãâïŒâãïŒâïŒïŒâã¡ããã·ãšãã
ã·ïŒâïŒâã¹ã«ãããšãã«ã¢ãŸãâïŒâããšã
ã«âïŒâãã©ãŸãã³ã®åæ æ°Žé žåãããªãŠã 8.0ïœãšæ°Ž200mlã®æº¶æ¶²ã«ïŒâ
ã¢ããâïŒâïŒïŒâã¡ããã·ãšããã·ïŒãã³ãŒã³
ã¹ã«ãã³é ž49.4ïœãå ããããã«äºç¡é žãœãŒã
13.8ïœã®æ°Žæº¶æ¶²ïŒ50mlïŒãå ãããå¥ã«æ¿å¡©é ž60
mlãšæ°Ž400mlã®æº¶æ¶²ã調補ãããããïŒâ以äžã§
äžèšæº¶æ¶²ã滎äžããããã®åŸïŒâ以äžã§30åéæ¹
æãåå¿ãå®çµãããã å¥ã«æ°Žé žåãããªãŠã 16.0ïœãæ°Ž200mlãé ¢é ž
ãããªãŠã 33.0ïœããã³ã¡ã¿ããŒã«200mlã®æº¶æ¶²
ã調åããïŒâã·ã¢ãâïŒâããšãã«âïŒâãã©
ãŸãã³37.0ïœãå ãã10â以äžã§äžèšèª¿è£œæžã®ãž
ã¢ãŸæ¶²ã滎äžããã滎äžçµäºåŸ10â以äžã§30åé
æ¹æããã€ãã§å®€æž©ã§ïŒæéæ¹æããåŸãæåºã
ãçµæ¶ãåããã¢ã»ãã³200mlã§æŽæµãã颚也
ããã åé52.0ïœ m.p.263ã265â åæäŸ ïŒ ïŒâã·ã¢ãâïŒâãïŒâïŒïŒâã¡ããã·ãšãã
ã·ïŒâïŒâã¯ããã¹ã«ãããšãã«ã¢ãŸãâïŒâ
ããšãã«âïŒâãã©ãŸãã³ã®åæ äžèšåæäŸïŒã§åŸãïŒâã·ã¢ãâïŒâãïŒïŒâ
ã¡ããã·ãšããã·âïŒâã¹ã«ãããšãã«ã¢ãŸãâ
ïŒâããšãã«âïŒâãã©ãŸãã³51.0ïœãã¢ã»ãã³
250mlããã³ãªãã·å¡©åãªã³50mlã®æ··å溶液ã«ïŒ®ïŒ
âãžã¡ãã«ã¢ã»ãã¢ãã50mlã50â以äžã§æ»Žäž
ããã滎äžåŸçŽïŒæéæ¹æããæ°·æ°Ž1.0ã®äžã«
åŸã ã«æ³šãã ãæåºããçµæ¶ãå¥åŸãã¢ã»ãã
ããªã«100mlã§æŽæµãã颚也ããã åé46.7ïœ m.p.181ã183â åæäŸ 10 è²çŽ äŸäžæ§ç©è³ª(1)ã®åæ åæäŸïŒã§åŸãïŒâãïŒâã¢ããâïŒâïŒïŒâ
ã¡ããã·ãšããã·ïŒãã³ãŒã³ã¹ã«ããã«ã¢ããïŒ
âïœâããã«âïŒâãããµãã·ã«ãªãã·ããšããŒ
ã«6.3ïœãïŒïŒ®âãžã¡ãã«ã¢ã»ãã¢ãã30mlã«
溶解ããåæäŸïŒã§åŸãïŒâã·ã¢ãâïŒâãïŒâ
ïŒïŒâã¡ããã·ãšããã·ïŒâïŒâã¯ããã¹ã«ãã
ã«ããšãã«ã¢ãŸãâïŒâããšãã«âïŒâãã©ãŸã
ã³4.6ïœãå ããããã«ããªãžã³ïŒmlãå ããã
宀枩ã§ïŒæéæ¹æããã®ã¡ãåå¿æ¶²ãçšå¡©é žã«æ³š
ããæåºããçµæ¶ãåãããïŒïŒ®âãžã¡ãã«
ã¢ã»ãã¢ããâã¡ã¿ããŒã«ããåçµæ¶ããŠ7.5ïœ
ãåŸãã m.p.189ã191â åæäŸ 11 è²çŽ äŸäžæ§ç©è³ª(2)ã®åæ åæäŸïŒã§åŸãïŒâãïŒâã¢ããâïŒâïŒïŒâ
ã¡ããã·ãšããã·ïŒãã³ãŒã³ã¹ã«ããã«ã¢ããâ
ïŒâïœâããã«âïŒâãããµãã·ã«ãªãã·ããšã
ãŒã«6.3ïœãïŒïŒ®âãžã¡ãã«ã¢ã»ãã¢ãã30ml
ã«æº¶è§£ããïŒâã·ã¢ãâïŒâïŒïŒâã¯ããâïŒâ
ã¡ãã«ã¹ã«ããã«ããšãã«ã¢ãŸïŒâïŒâïŒïŒâã¯
ããã¹ã«ããã«ããšãã«ïŒâïŒâãã©ãŸãã³5.0
ïœãå ããããã«ããªãžã³ïŒmlãå ããã宀枩ã§
ïŒæéæ¹æããã®ã¡ãåå¿æ¶²ãçšå¡©é žã«æ³šããæ
åºããçµæ¶ãåãããã¢ã»ããããªã«ã§åçµæ¶
ããŠ8.4ïœãåŸãã m.p.144ã149â åæäŸ 12 è²çŽ äŸäžæ§ç©è³ª(10)ã®åæ ïŒâã¢ããâïŒâïœâããã«âïŒâãããµãã·
ã«ãªãã·ããšããŒã«å¡©é žå¡©4.4ïœããã³ïŒâãïŒ
âã¯ããã¹ã«ããã«âïŒâïŒïŒâã¡ããã·ãšãã
ã·ïŒããšãã«ã¢ãŸãâïŒâïŒïŒ®ïŒïŒ®âãžãšãã«ã¹
ã«ãã¢ã¢ã€ã«ïŒâïŒâã¡ãã«ã¹ã«ããã«ã¢ããâ
ïŒâããããŒã«6.5ïœãïŒïŒ®âãžã¡ãã«ã¢ã»ã
ã¢ãã20mlã«æº¶è§£ãããªãžã³4.2mlãå ãããïŒ
æé25âã§æ¹æããã®ã¡ãåå¿æ¶²ãçšå¡©é žäžã«æ³š
ãå ¥ãããæåºããåºäœãåããã·ãªã«ã²ã«ã«
ã©ã ã¯ãããã°ã©ãã€ãŒïŒã¯ãããã«ã âé ¢é žãš
ãã«ïŒïŒïŒïŒïŒæ··å溶åªã§æº¶åºïŒã«ãã€ãŠç²Ÿè£œã
ãã åé5.2ïœã åæäŸ 13 è²çŽ äŸäžæ§ç©è³ªïŒ17ïŒã®åæ ïŒâã¢ããâïŒâïœâããã«âïŒâãããµãã·
ã«ãªãã·ããšããŒã«å¡©é žå¡©11.6ïœãïŒïŒ®âãžã¡
ãã«ã¢ã»ãã¢ãã100mlã«æº¶è§£ããããªãžã³12ml
ãå ãããããã«ïŒâïŒïŒâã¯ããã¹ã«ããã«ã
ã³ãŒã³ã¹ã«ããã«ã¢ããïŒâïŒâïŒïŒ®âïœâãã
ã«ã¹ã«ãã¢ã¢ã€ã«ïŒâïŒâïŒïŒâã¡ãã«ã¹ã«ãã
ã«âïŒâãããããšãã«ã¢ãŸïŒâïŒâããããŒã«
20ïœãå ãããïŒæéæ¹æåŸãæ°·æ°Ž500mlã«ããã
æåºç©ãã€ãœãããã«ã¢ã«ã³ãŒã«âã¢ã»ããããª
ã«ïŒïŒïŒïŒïŒã§åçµæ¶ããŠ6.8ïœãåŸãã åæäŸ 14 è²çŽ äŸäžæ§ç©è³ªïŒ19ïŒã®åæ ïŒâãïŒâã¢ããâïŒâïŒïŒâã¡ããã·ãšãã
ã·ïŒãã³ãŒã³ã¹ã«ããã«ã¢ãããâïŒâïœâãã
ã«âïŒâãããµãã·ã«ãªãã·ããšããŒã«31.5ïœã
ïŒâïŒïŒâã¯ããã¹ã«ããã«ãã³ãŒã³ã¹ã«ããã«
ã¢ããïŒâïŒâïŒïŒâã¡ãã«ã¹ã«ããã«âïŒâã
ããããšãã«ã¢ãŸïŒâïŒâããããŒã«39.1ïœã
ïŒïŒ®âãžã¡ãã«ã¢ã»ãã¢ãã100mlã«æº¶è§£ãã
ããªãžã³21mlãå ããã80åæ¹æåŸãã¡ã¿ããŒã«
250mlãæ°Ž100mlãå ãããæåºããæš¹èç¶ç©ã¯ã
ã°ãããããšåºåããã®ã§åãããããããã«
ãšã³âã¡ã¿ããŒã«âæ°ŽïŒ16ïŒïŒïŒïŒïŒæ··åç³»ãã
åçµæ¶ããŠ41.5ïœåŸãã åæäŸ 15 ååç©40ã®åæ ïœïŒ ïŒïŒïŒâãžããããã·âïŒâïœâããã«ã¢
ã»ãããšãã³ã®åæ ïœâããã«ãããããã³83ïœãé ¢é ž400mlã«
溶解ãã80ã90âã«å ç±ããªããäžããåããŠ
çŽ ïŒBF3ïŒãçŽïŒæéå°å ¥ãããåå¿çµäºåŸïŒ
ã®æ°·æ°Žäžã«æ³šãæåºããç²èª¿ãªåºäœãåã
ãããã®åºäœã2NâNaOH600mlã«æº¶è§£ããäž
溶éšãå»ããã液ãçšå¡©é žã«ããé žæ§ãš
ããæåºããçµæ¶ãåããŠæ°ŽæŽããåŸãå«æ°Ž
ã¡ã¿ããŒã«ããåçµæ¶ããã åé68ïœïŒ65ïŒ ïŒ ïœïŒ ïŒïŒïŒâãžããããã·âïŒâïœâããã«ã¢
ã»ãããšãã³ããªãã·ã ã®åæ äžèšïœïŒã§åŸãããã±ãã³21ïœããšã¿ããŒã«
70mlãé ¢é žãããªãŠã 24ïœãšãšãã«å ç±æº¶è§£ã
ããæ¹æããªããå¡©é žããããã·ã«ã¢ãã³12ïœ
ãæ°Ž70mlã«æº¶è§£ããã液ãå ãçŽïŒæééæµã
ããåå¿çµäºåŸ500mlã®æ°·æ°Žã«æ³šãæåºçµæ¶ã
åããã³ãŒã³âãããµã³ããåçµæ¶ããã åé17ïœïŒ76ïŒ ïŒ ïœïŒ ïŒâïœâããã«âïŒâããããã·âïŒâã¡
ãã«ãã³ãºãªããµãŸãŒã«ã®åæ äžèšïœïŒã§åŸããªãã·ã 14ïœãé ¢é ž100mläž
ã«æº¶è§£ããå ç±ããªãã也ç¥å¡©é žã¬ã¹ãå°å ¥
ãã1.5æééæµãããåå¿çµäºåŸ500mlã®æ°·æ°Ž
äžã«æ³šãæåºçµæ¶ãåãæ°ŽæŽããã åéïŒïœïŒ70ïŒ ïŒ ïœïŒ ïŒâïœâããã«âïŒâãããµãã·ã«ãªãã·
âïŒâã¡ãã«ãã³ãºãªããµãŸãŒã«ã®åæ äžèšïœïŒã§åŸããã³ãºãªããµãŸãŒã«6.9ïœã
ãžã¡ãã«ãã«ã ã¢ãã50mlã«æº¶è§£ãããç¡æ°Žç
é žã«ãªãŠã ïŒïœãšãããµãã·ã«ãããã11ïœãš
å ±ã«80ã90âã«ãŠïŒæéæ¹æãããåå¿çµäº
åŸãç¡æ©ç©ãå»ããŠæ¶²ãã¡ã¿ããŒã«150ml
å ãæ°·å·ãããšçµæ¶ãæåºããããããåã
ãããšã«ããæšèšååç©ãåŸãã åé8.8ïœïŒ62ïŒ ïŒ ïœ ïŒ ïŒâã¢ããâïŒâïœâããã«âïŒâãããµ
ãã·ã«ãªãã·ããšããŒã«å¡©é žå¡©ã®åæ äžèšïœïŒã§åŸããã³ãºãªããµãŸãŒã«ååç©
7.3ïœããšã¿ããŒã«30mlãæ¿å¡©é ž20mlãšå ±ã«ïŒ
æééæµãããåå¿çµäºåŸãæŸå·ãæåºããçµ
æ¶ãåãæ°ŽæŽããåŸã¢ã»ãã³ã§æŽæµããã åé6.9ïœïŒ92ïŒ ïŒ ïœïŒ ååç©40ã®åæ äžèšïœ ïŒã§åŸãå¡©é žå¡©ïŒïœãšäžèšæ§é åŒã®è²
çŽ ã®ã¹ã«ããã«ã¯ããªã8.8ïœããžã¡ãã«ã¢ã»
ãã¢ãã50mlã«æº¶è§£ãããããªãžã³ïŒmlãå ã
ãŠå®€æž©ã§ïŒæéæ¹æãããåå¿çµäºåŸãçšå¡©é ž
äžã«æ³šãæåºããçµæ¶ãåããæ°ŽæŽããã也
ç¥åŸã·ãªã«ã²ã«ã¯ãããã°ã©ãã€ãŒã«ãŠç²Ÿè£œã
å®è³ªçã«ïŒæåã®æšèšååç©ã2.2ïœåŸãã è²çŽ ã¹ã«ããã«ã¯ããªãïŒ åæäŸ 16 è²çŽ äŸäžæ§ç©è³ªïŒ42ïŒã®åæ äžèšåæäŸ15dïŒã«ãããŠãïŒâïœâããã«â
ïŒâããããã·âïŒâã¡ãã«ãã³ãºãªããµãŸãŒã«
ã®ãããã«ïŒâïœâãªã¯ãã«âïŒâããããã·â
ïŒâã¡ãã«ãã³ãºãªããµãŸãŒã«ãçšããŠãâã
ããµãã·ã«åãè¡ã€ãã次ãã§åæäŸ15eïŒãã
ã³ïœïŒãšåæ§ã®åŠçã«ãã€ãŠè²çŽ äŸäžæ§ç©è³ª
ïŒ42ïŒãåŸãã æ¬çºæã®è²çŽ äŸäžæ§ç©è³ªã¯ãç±³åœç¹èš±2322027
å·èšèŒã®æ¹æ³ãªã©ã®å ¬ç¥ã®æ¹æ³ã«ããæå ææã®
å±€äžã«å°å ¥ããããšãã§ããããã®å Žåäžèšã®åŠ
ãé«æ²žç¹ææ©æº¶åªïŒäœæ²žç¹ææ©æº¶åªãçšããããš
ãã§ããã ããšãã°ãã¿ãŒã«é žã¢ã«ãã«ãšã¹ãã«ïŒãžãã
ã«ãã¿ã¬ãŒãïŒãžãªã¯ãã«ãã¿ã¬ãŒããªã©ïŒïŒãª
ã³é žãšã¹ãã«ïŒãžããšãã«ãã¹ããšãŒãïŒããªã
ãšãã«ãã¹ããšãŒãïŒããªã¯ã¬ãžã«ãã¹ããšãŒ
ãïŒãžãªã¯ãã«ããã«ãã¹ããšãŒãïŒïŒã¯ãšã³é ž
ãšã¹ãã«ïŒäŸãã°ã¢ã»ãã«ã¯ãšã³é žããªããã«ïŒïŒ
å®æ¯éŠé žãšã¹ãã«ïŒå®æ¯éŠé žãªã¯ãã«ïŒïŒã¢ã«ã
ã«ã¢ããïŒäŸãã°ãžãšãã«ã©ãŠãªã«ã¢ããïŒïŒè
èªé žãšã¹ãã«é¡ïŒäŸãã°ãžãããã·ãšãã«ãµã¯ã·
ããŒãïŒãžãªã¯ãã«ã¢ãŒã¬ãŒãïŒïŒããªã¡ã·ã³é ž
ãšã¹ãã«é¡ïŒäŸãã°ããªã¡ã·ã³é žããªããã«ïŒãª
ã©ã®é«æ²žç¹ææ©æº¶åªïŒãŸãã¯æ²žç¹çŽ30âä¹è³160
âã®ææ©æº¶åªïŒäŸãã°é ¢é žãšãã«ïŒé ¢é žããã«ã®
åŠãäœçŽã¢ã«ãã«ã¢ã»ããŒãïŒããããªã³é žãšã
ã«ïŒäºçŽããã«ã¢ã«ã³ãŒã«ïŒã¡ãã«ã€ãœããã«ã±
ãã³ïŒÎ²âãšããã·ãšãã«ã¢ã»ããŒãïŒã¡ãã«ã»
ããœã«ãã¢ã»ããŒãïŒã·ã¯ããããµãã³ãªã©ã«æº¶
解ããã®ã¡ã芪氎æ§ã³ãã€ãã«åæ£ããããäžèš
ã®é«æ²žç¹ææ©æº¶åªãšäœæ²žç¹ææ©æº¶åªãšãæ··åããŠ
çšããŠãããã ãŸãç¹å ¬æ51â39853å·ïŒç¹éæ51â59943å·ã«
èšèŒãããŠããéåç©ã«ããåæ£æ³ã䜿çšã§ã
ãããŸãè²çŽ äŸäžæ§ç©è³ªã芪氎æ§ã³ãã€ãã«åæ£
ããéã«ãçš®ã ã®çé¢æŽ»æ§å€ãçšããããšãã§
ãããããã®çé¢æŽ»æ§å€ãšããŠã¯ãã®æ现æžã®äž
ã®å¥ã®ãšããã§çé¢æŽ»æ§å€ãšããŠæãããã®ã䜿
ãããšãã§ããã æ¬çºæã§çšããããé«æ²žç¹ææ©æº¶åªã®éã¯çšã
ãããè²çŽ äŸäžæ§ç©è³ªïŒïœã«å¯ŸããŠ10ïœä»¥äžã奜
ãŸããã¯ïŒïœä»¥äžã§ããã æ¬çºæã«ãããŠã¯ãå¿ èŠã«å¿ããŠéå å€ãçšã
ãããšãã§ããããã®å Žåã®éå å€ãšã¯æè¬è£å©
çŸåè¬ã§ãããããã²ã³åéããã³ïŒãŸãã¯ææ©
éå¡©é žåå€ã«ãã€ãŠé žåããããã®é žåäœããè²
çŽ äŸäžæ§ç©è³ªäžã®éå æ§åºè³ªRaãé žåããèœå
ãæãããã®ã§ããã æçšãªè£å©çŸåè¬ã«ã¯ãã€ããããã³ïŒïœâã
ãã«ãã€ããããã³ïŒïŒïŒïŒâãžã¡ãã«ãã€ãã
ããã³ãªã©ã®ã¢ã«ãã«çœ®æãã€ããããã³é¡ïŒã«
ãã³ãŒã«é¡ïŒããã¬ããŒã«é¡ïŒã¯ãããã€ããã
ãã³ããžã¯ãããã€ããããã³ãªã©ã®ããã²ã³çœ®
æãã€ããããã³é¡ïŒã¡ããã·ãã€ããããã³ãª
ã©ã®ã¢ã«ã³ãã·çœ®æãã€ããããã³é¡ïŒã¡ãã«ã
ãããã·ããã¿ã¬ã³ãªã©ã®ããªããããã·ãã³ãŒ
ã³èªå°äœããããæŽã«ãã¡ãã«ã¬ã¬ãŒãïŒã¢ã¹ã³
ã«ãã³é žïŒã¢ã«ã³ã«ãã³é žèªå°äœé¡ïŒïŒ®ïŒNâ²â
ãžâïŒïŒâãšããã·ãšãã«ïŒããããã·ã«ã¢ãã³
ãªã©ã®ããããã·ã«ã¢ãã³é¡ïŒïŒâããšãã«âïŒ
âãã©ãŸãªãã³ïŒïŒâã¡ãã«âïŒâããããã·ã¡
ãã«âïŒâããšãã«âïŒâãã©ãŸãªãã³ãªã©ã®ã
ã©ãŸãªãã³é¡ïŒã¬ãã¯ãã³é¡ïŒããããã·ããã©
é žé¡ãæçšã§ããã è£å©çŸåè¬ã¯äžå®ã®æ¿åºŠç¯å²ã§çšããããšãã§
ãããæçšãªæ¿åºŠç¯å²ã¯éã«å¯ŸããŠ0.0005åã¢ã«
ã20åã¢ã«ãç¹ã«æçšãªæ¿åºŠç¯å²ãšããŠã¯ã
0.001åã¢ã«ãïŒåã¢ã«ã§ããã æ¬çºæã§çšããããããã²ã³åéãšããŠã¯å¡©å
éãå¡©èåéãå¡©æ²åéãèåéãæ²èåéãå¡©
æ²èåéãæ²åéãªã©ãããã æ¬çºæã«ãããŠãææ©éå¡©é žåå€ã䜵çšããã«
ããã²ã³åéãåç¬ã«çšããå Žåã¯ãšãã«å¥œãŸã
ãããã²ã³åéãšããŠã¯ç²åã®äžéšã«æ²åéçµæ¶
ãå«ãã§ãããã®ã§ãããããªãã¡ããã²ã³åé
ã®ïŒžç·åæããšã€ããšãã«çŽæ²åéã®ãã¿ãŒã³ã®
ããããããã®ãç¹ã«å¥œãŸããã åçæå ææã«ã¯ïŒçš®ä»¥äžã®ããã²ã³ååãå«
ãããã²ã³åéãçšããããããéåžžã®ããã²ã³
åéä¹³å€ã§ã¯ããã²ã³åéç²åã¯å®å šãªæ··æ¶ãäœ
ã€ãŠãããäŸãã°æ²èåéä¹³å€ã§ã¯ãã®ç²åã®ïŒž
ç·åæã枬å®ãããšæ²åéçµæ¶ãèåéçµæ¶ã®ã
ã¿ãŒã³ã¯ããããããæ··åæ¯ã«å¿ããäœçœ®ã«ïŒžç·
ãã¿ãŒã³ããããããã æ¬é¡ã«ãããŠç¹ã«å¥œãŸããããã²ã³åéã¯æ²å
éçµæ¶ãç²åäžã«å«ãã§ãããåŸã€ãŠæ²åéçµæ¶
ã®ïŒžç·ãã¿ãŒã³ãçŸãããå¡©æ²åéãæ²èåéã
å¡©æ²åéã§ããã ãã®ãããªããã²ã³åéã¯äŸãã°æ²èåéã§ã¯
èåã«ãªãŠã 溶液äžã«ç¡é žé溶液ãæ·»å ããŠãŸã
èåéç²åãäœãããã®åŸã«æ²åã«ãªãŠã ãæ·»å
ããããšã«ãã€ãŠåŸãããã ããã²ã³åéã¯ããµã€ãºããã³ïŒåã¯ããã²ã³
çµæã®ç°ãªãïŒçš®ä»¥äžã䜵çšããŠãããã æ¬çºæã§çšããããããã²ã³åéç²åã®ãµã€ãº
ã¯å¹³åç²åŸã0.001ÎŒmãã10ÎŒmã®ãã®ã奜ãŸã
ããæŽã«å¥œãŸããã¯0.001ÎŒmãã5ÎŒmã§ããã æ¬çºæã§äœ¿çšãããããã²ã³åéã¯ãã®ãŸãŸäœ¿
çšãããŠããããæŽã«ç¡«é»ãã»ã¬ã³ããã«ã«çã®
ååç©ãéãçœéããã©ãžãŠã ãããžãŠã ãã€ãª
ãžãŠã ãªã©ã®ååç©ã®ãããªååŠå¢æå€ãããã²
ã³åé«ãªã©ã®éå å€ãŸãã¯ãããã®çµåãã®äœ¿çš
ã«ãã€ãŠååŠå¢æãããŠãããã詳ããã¯âThe
Theory of tho Photographic ProcessâïŒçã
T.H.Jamesèã®ç¬¬ïŒç« 149é ã169é ã«èšèŒãã
ãŠããã æ¬çºæã«ãããŠç¹ã«å¥œãŸããå®æœæ æ§ã¯ææ©é
å¡©é žåå€ã䜵åããããã®ã§ããããæå ããã
ãã²ã³åéã®ååšäžã§æž©åºŠ80â以äžã奜ãŸããã¯
100â以äžã«å ç±ããããšãã«ãäžèšç»å圢æç©
質ãŸãã¯å¿ èŠã«å¿ããŠç»å圢æç©è³ªãšå ±åããã
éå å€ãšåå¿ããŠéåã圢æãããã®ã§ãããæ
æ©éå¡©é žåå€ã䜵åãããããšã«ãããããé«æ¿
床ã«çºè²ããæå ææãåŸãããšãã§ããã ãã®å Žåã«çšããããããã²ã³åéã¯ãããã²
ã³åéåç¬ã§äœ¿çšããå Žåã®çŽæ²åéçµæ¶ãå«ã
ãšãç¹åŸŽãæããããšãå¿ ãããå¿ èŠã§ãªãåœæ¥
çã«ãããŠç¥ãããããã²ã³åéå šãŠã䜿çšãã
ããšãã§ããã ãã®ãããªææ©éå¡©é žåå€ã®äŸãšããŠã¯ä»¥äžã®
ãããªãã®ãããã ã«ã«ããã·ã«åºãæããææ©ååç©ã®éå¡©ã§ã
ãããã®äžã«ã¯ä»£è¡šçãªãã®ãšããŠèèªæã«ã«ã
ã³é žã®éå¡©ãè³éŠæã«ã«ãã³é žã®éå¡©ãªã©ãã
ãã èèªæã«ã«ãã³é žã®äŸãšããŠã¯ããã³é žã®é
å¡©ãã¹ãã¢ãªã³é žã®éå¡©ããªã¬ã€ã³é žã®éå¡©ãã©
ãŠãªã³é žã®éå¡©ãã«ããªã³é žã®éå¡©ãããªã¹ãã³
é žã®éå¡©ããã«ããã³é žã®éå¡©ããã¬ã€ã³é žã®é
å¡©ãããã«é žã®éå¡©ãé ç³é žã®éå¡©ãããã€ã³é ž
ã®éå¡©ããªããŒã«é žã®éå¡©ããªã¬ã€ã³é žã®éå¡©ã
ã¢ãžãã³é žã®éå¡©ãã»ãã·ã³é žã®éå¡©ããã¯ãé ž
ã®éå¡©ãé ¢é žã®éå¡©ãé ªé žã®éå¡©ãæšè³é žã®éå¡©
ãªã©ãããããŸããããã®éå¡©ã®ããã²ã³ååã
ããããã·ã«åºã§çœ®æããããã®ãæå¹ã§ããã è³éŠæã«ã«ãã³é žããã³ãã®ä»ã®ã«ã«ããã·ã«
åºå«æååç©ã®éå¡©ãšããŠã¯å®æ¯éŠé žã®éå¡©ã
ïŒïŒïŒâãžããããã·å®æ¯éŠé žã®éå¡©ãïœâã¡ã
ã«å®æ¯éŠé žã®éå¡©ãïœâã¡ãã«å®æ¯éŠé žã®éå¡©ã
ïœâã¡ãã«å®æ¯éŠé žã®éå¡©ãïŒïŒïŒâãžã¯ãã«å®
æ¯éŠé žã®éå¡©ãã¢ã»ãã¢ããå®æ¯éŠé žã®éå¡©ãïœ
âããšãã«å®æ¯éŠé žã®éå¡©ãªã©ã®çœ®æå®æ¯éŠé žã®
éå¡©ã没é£åé žã®éå¡©ãã¿ã³ãã³é žã®éå¡©ããã¿
ã«é žã®éå¡©ããã¬ãã¿ã«é žã®éå¡©ããµãªãã«é žã®
éå¡©ãããšãã«é ¢é žã®éå¡©ãããã¡ãªããé žã®é
å¡©ãç±³åœç¹èš±ç¬¬3785830å·æ现æžèšèŒã®ïŒâã«ã«
ããã·ã¡ãã«âïŒâã¡ãã«âïŒâãã¢ãŸãªã³âïŒ
âããªã³ãªã©ã®éå¡©ãç±³åœç¹èš±ç¬¬3330663å·æ现
æžã«èšèŒãããŠããããªãšãŒãã«åºãæããèèª
æã«ã«ãã³é žã®éå¡©ãªã©ãããã ãã®ä»ã«ã¡ã«ã«ããåºãŸãã¯ããªã³åºãæãã
ååç©ããã³ãã®èªå°äœã®éå¡©ãããã äŸãã°ïŒâã¡ã«ã«ããâïŒâããšãã«âïŒïŒ
ïŒïŒïŒâããªã¢ãŸãŒã«ã®éå¡©ãïŒâã¡ã«ã«ããã
ã³ãŸã€ãããŸãŒã«ã®éå¡©ãïŒâã¡ã«ã«ããâïŒâ
ã¢ãããã¢ãžã¢ãŸãŒã«ã®éå¡©ãïŒâã¡ã«ã«ããã
ã³ããã¢ãŸãŒã«ã®éå¡©ãïŒâïŒïœâãšãã«ã°ãªã³
ãŒã«ã¢ããïŒãã³ãºãã¢ãŸãŒã«ã®éå¡©ãïœâã¢ã«
ãã«ïŒççŽ æ°12ã22ã®ã¢ã«ãã«åºïŒããªã°ãªã³ãŒ
ã«é ¢é žãªã©ã®ç¹éæ48â28221å·ã«èšèŒã®ããªã°
ãªã³ãŒã«é žã®éå¡©ããžããªé ¢é žã®éå¡©ã®ãããªãž
ããªã«ã«ãã³é žã®éå¡©ãããªã¢ããã®éå¡©ãïŒâ
ã«ã«ããã·âïŒâã¡ãã«âïŒâããšãã«âïŒâã
ãªããªãžã³ã®éå¡©ãã¡ã«ã«ããããªã¢ãžã³ã®é
å¡©ãïŒâã¡ã«ã«ãããã³ãŸãªããµãŸãŒã«ã®éå¡©ã
ã¡ã«ã«ãããªããµãžã¢ãŸãŒã«ã®éå¡©ãç±³åœç¹èš±
4123274å·æ现æžèšèŒã®éå¡©ãããšãã°ïŒïŒïŒïŒ
ïŒâã¡ã«ã«ããããªã¢ãŸãŒã«èªå°äœã§ããïŒâã¢
ããâïŒâãã³ãžã«ããªïŒïŒïŒïŒïŒâããªã¢ãŸãŒ
ã«ã®éå¡©ãç±³åœç¹èš±3301678å·æ现æžèšèŒã®ïŒâ
ïŒïŒã«ã«ããã·ãšãã«ïŒâïŒâã¡ãã«âïŒâãã¢
ãŸãªã³âïŒããªã³ã®éå¡©ãªã©ã®ããªã³ååç©ã®é
å¡©ã§ããã ãã®ä»ã«ãã€ããåºãæããååç©ã®éå¡©ãã
ããäŸãã°ç¹å ¬æ44â30270ãå45â18416å ¬å ±èš
èŒã®ãã³ãŸããªã¢ãŸãŒã«ããã³ãã®èªå°äœã®é
å¡©ãäŸãã°ãã³ãŸããªã¢ãŸãŒã«ã®éå¡©ãã¡ãã«ã
ã³ãŸããªã¢ãŸãŒã«ã®éå¡©ãªã©ã®ã¢ã«ãã«çœ®æãã³
ãŸããªã¢ãŸãŒã«ã®éå¡©ãïŒâã¯ãããã³ãŸããªã¢
ãŸãŒã«ã®éå¡©ã®ãããªããã²ã³çœ®æãã³ãŸããªã¢
ãŸãŒã«ã®éå¡©ãããã«ã«ã«ãã€ãããã³ãŸããªã¢
ãŸãŒã«ã®éå¡©ã®ãããªã«ã«ãã€ãããã³ãŸããªã¢
ãŸãŒã«ã®éå¡©ãç±³åœç¹èš±4220709å·æ现æžèšèŒã®
ïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«ãïŒââããã©ãŸãŒ
ã«ã®éå¡©ãã«ã«ããŸãŒã«ã®éå¡©ããµãã«ãªã³ã®é
å¡©ãã€ãããŸãŒã«ãã€ãããŸãŒã«èªå°äœã®éå¡©ãª
ã©ãããã ãŸããªãµãŒããã€ã¹ã¯ããŒãžã€ãŒVol170ã
1978幎ïŒæã®No.17029å·ã«èšèŒãããŠããéå¡©ã
ã¹ãã¢ãªã³é žé ãªã©ã®ææ©éå±å¡©ãæ¬çºæã«äœ¿çš
ã§ããææ©éå±å¡©é žåå€ã§ããã ææ©éå¡©é žåå€ã¯ãïŒçš®ä»¥äžäœ¿çšããããšãã§
ããã æ¬çºæã®å ç±äžã§ã®ç±çŸåéçšã¯ååæããã«
ãªã€ãŠããªãã以äžã®ããã«èããããšãã§ã
ãã æå ææã«å ãç §å°ãããšæå æ§ãæã€ããã²
ã³åéã«æœåã圢æããããããã«ã€ããŠã¯ã
T.H.Jamesèã®âThe Theory of the
Photographic Processâ3rd Editionã®105é ã
148é ã«èšèŒãããŠããã æå ææãå ç±ããããšã«ãããéå å€ãæ¬çº
æã®å Žåã¯è²çŽ äŸäžæ§ç©è³ªããæœåæ žã觊åªãšã
ãŠãããã²ã³åéãŸãã¯ããã²ã³éãšææ©éå¡©é ž
åå€ãéå ããéãçæããããèªèº«ã¯é žåãã
ãããã®é žåãããè²çŽ äŸäžæ§ç©è³ªã¯éè£ããŠè²
çŽ ãæŸåºãããã ãããã®ããã²ã³åéãææ©éå¡©é žåå€ã®äœã
æ¹ãäž¡æ¹ã®æ··åã®ãæ¹ãªã©ã«ã€ããŠã¯ããªãµãŒã
ãã€ã¹ã¯ããŒãžã€17029å·ãç¹éæ50â32928ãç¹
éæ51â42529ãç±³åœç¹èš±3700458ãç¹éæ49â
13244å·ãç¹éæ50â17216å·ã«èšèŒãããŠããã æ¬çºæã«ãããŠæå æ§ããã²ã³åéããã³ææ©
éå¡©é žåå€ã®å¡åžéã¯éã«æç®ããŠåèšã§50mgã
10ïœïŒm2ãé©åœã§ããã æ¬çºæã®æå æ§ããã²ã³åéãææ©éå¡©é žåå€
ã¯äžèšã®ãã€ã³ããŒäžã§èª¿æŽãããããŸãè²çŽ äŸ
äžæ§ç©è³ªãäžèšã®ãã€ã³ããŒäžã«åæ£ãããã æ¬çºæã«çšãããããã€ã³ããŒã¯ãåç¬ã§ãã
ããã¯çµã¿åããŠå«æããããšãã§ããããã®ã
ã€ã³ããŒã«ã¯ã芪氎æ§ã®ãã®ãçšããããšãã§ã
ãã芪氎æ§ãã€ã³ããŒãšããŠã¯ãéæãåéæã®
芪氎æ§ã³ãã€ãã代衚çã§ãããäŸãã°ãŒã©ã
ã³ããŒã©ãã³èªå°äœãã»ã«ããŒã¹èªå°äœçã®ã¿ã³
ãã¯è³ªãããã³ãã³ãã¢ã©ãã¢ãŽã çã®å€ç³é¡ã®
ãããªå€©ç¶ç©è³ªãšãããªããã«ãããªãã³ãã¢ã¯
ãªã«ã¢ããéåäœçã®æ°Žæº¶æ§ããªããã«ååç©ã®
ãããªåæéåç©è³ªãå«ããä»ã®åæéåååç©
ã«ã¯ãã©ããã¯ã¹ã®åœ¢ã§ãç¹ã«åçææã®å¯žåºŠå®
å®æ§ãå¢å ãããåæ£ç¶ããã«ååç©ãããã æ¬çºæã«çšããããããã²ã³åéã¯ãã¡ãã³è²
çŽ é¡ãã®ä»ã«ãã€ãŠåå å¢æãããŠããããçšã
ãããè²çŽ ã«ã¯ãã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ãã³è²
çŽ ãè€åã·ã¢ãã³è²çŽ ãè€åã¡ãã·ã¢ãã³è²çŽ ã
ããããŒã©ãŒã·ã¢ãã³è²çŽ ãããã·ã¢ãã³è²çŽ ã
ã¹ããªã«è²çŽ ããã³ãããªããœããŒã«è²çŽ ãå å«
ããããç¹ã«æçšãªè²çŽ ã¯ãã·ã¢ãã³è²çŽ ãã¡ã
ã·ã¢ãã³è²çŽ ãããã³è€åã¡ãã·ã¢ãã³è²çŽ ã«å±
ããè²çŽ ã§ããããããã®è²çŽ é¡ã«ã¯ãå¡©åºæ§ç°
ç¯ç°æ žãšããŠã·ã¢ãã³è²çŽ é¡ã«éåžžå©çšãããæ ž
ã®ãããããé©çšã§ã©ãããããªãã¡ããããªã³
æ žããªããµãŸãªã³æ žããã¢ãŸãªã³æ žããããŒã«
æ žããªããµãŸãŒã«æ žããã¢ãŸãŒã«æ žãã»ã¬ããŸãŒ
ã«æ žãã€ãããŸãŒã«æ žãããã©ãŸãŒã«æ žãããªãž
ã³æ žãªã©ïŒãããã®æ žã«èç°åŒçåæ°ŽçŽ ç°ãèå
ããæ žïŒåã³ãããã®æ žã«è³éŠæçåæ°ŽçŽ ç°ãè
åããæ žãå³ã¡ãã€ã³ãã¬ãã³æ žããã³ãŸã€ã³ã
ã¬ãã³æ žãã€ã³ããŒã«æ žããã³ãºãªããµããŒã«
æ žãããããªããµãŸãŒã«æ žããã³ãºãã¢ãŸãŒã«
æ žãããããã¢ãŸãŒã«æ žããã³ãŸã»ã¬ããŸãŒã«
æ žããã³ãºã€ãããŸãŒã«æ žããããªã³æ žãªã©ãé©
çšã§ããããããã®æ žã¯ççŽ ååäžã«çœ®æãããŠ
ããŠãããã ã¡ãã·ã¢ãã³è²çŽ ãŸãã¯è€åã¡ãã·ã¢ãã³è²çŽ
ã«ã¯ã±ãã¡ãã¬ã³æ§é ãæããæ žãšããŠããã©ãŸ
ãªã³âïŒâãªã³æ žãããªããã³ãã€ã³æ žãïŒâã
ãªãªããµãŸãªãžã³âïŒïŒïŒâãžãªã³æ žããã¢ãŸãª
ãžã³âïŒïŒïŒâãžãªã³æ žãããŒããã³æ žãããªã
ã«ãããŒã«é žæ žãªã©ã®ïŒãïŒå¡ç°ç¯ç°æ žãé©çšã
ãããšãã§ããã æçšãªå¢æè²çŽ ãšããŠã¯äŸãã°ããã€ãç¹èš±
929050å·ãç±³åœç¹èš±2231658å·ãå2493748å·ãå
2503776å·ãå2519001å·ãå2912329å·ãå
3656959å·ãå3672897å·ãå3694217å·ãå
4025349å·ãå4046572å·ãè±åœç¹èš±1242588å·ã
ç¹å ¬æ44â14030å·ãå52â24844å·ã«èšèŒããã
ãã®ãæããããšãåºæ¥ãã ãããã®å¢æè²çŽ ã¯åç¬ã«çšããŠãããããã
ããã®çµåããçšããŠããããå¢æè²çŽ ã®çµåã
ã¯ç¹ã«ã匷è²å¢æã®ç®çã§ãã°ãã°çšããããã
ãã®ä»£è¡šäŸã¯ç±³åœç¹èš±2688545å·ãå2977229å·ã
å3397060å·ãå3522052å·ãå3527641å·ãå
3617293å·ãå3628964å·ãå3666480å·ãå
3672898å·ãå3679428å·ãå3703377å·ãå
3769301å·ãå3814609å·ãå3837862å·ãå
4026707å·ãè±åœç¹èš±1344281å·ãå1507803å·ã
ç¹å ¬æ43â4936å·ãå53â12375å·ãç¹éæ52â
110618å·ãå52â109925å·ã«èšèŒãããŠããã å¢æè²çŽ ãšãšãã«ãããèªèº«åå å¢æäœçšãã
ããªãè²çŽ ãããã¯å¯èŠå ãå®è³ªçã«åžåããªã
ç©è³ªã§ãã€ãŠã匷è²å¢æã瀺ãç©è³ªãä¹³å€äžã«å«
ãã§ããããäŸãã°ãå«çªçŽ ç°ç¯ç°åºã§çœ®æãã
ãã¢ããã¹ãã«ååç©ïŒããšãã°ç±³åœç¹èš±
2933390å·ãå3635721å·ã«èšèŒã®ãã®ïŒãè³éŠæ
ææ©é žãã«ã ã¢ã«ãããçž®åç©ïŒããšãã°ç±³åœç¹
èš±3743510å·ã«èšèŒã®ãã®ïŒãã«ãããŠã å¡©ãã¢ã¶
ã€ã³ãã³ååç©ãªã©ãå«ãã§ããããç±³åœç¹èš±
3615613å·ãå3615641å·ãå3617295å·ãå
3635721å·ã«èšèŒã®çµåãã¯ç¹ã«æçšã§ããã æ¬çºæã§çšããããæ¯æäœã¯ãåŠç枩床ã«èã
ãããšã®ã§ãããã®ã§ãããäžè¬çãªæ¯æäœãšã
ãŠã¯ãã¬ã©ã¹ïŒçŽïŒéå±ããã³ãã®é¡äŒŒäœãçšã
ãããã°ããã§ãªããã¢ã»ãã«ã»ã«ããŒãºãã€ã«
ã ïŒã»ã«ããŒãºãšã¹ãã«ãã€ã«ã ïŒããªããã«ã¢
ã»ã¿ãŒã«ãã€ã«ã ïŒããªã¹ãã¬ã³ãã€ã«ã ïŒããª
ã«ãŒãããŒããã€ã«ã ïŒããªãšãã¬ã³ãã¬ãã¿ã¬
ãŒããã€ã«ã åã³ãããã«é¢é£ãããã€ã«ã ãŸã
ã¯æš¹èææãå«ãŸãããç±³åœç¹èš±3634089å·ïŒå
第3725070å·èšèŒã®ããªãšã¹ãã«ã¯å¥œãŸããçšã
ãããã æ¬çºæã«æŒããŠã¯çš®ã ã®è²çŽ æŸåºå©å€ãçšãã
ããšãã§ãããè²çŽ æŸåºå©å€ãšã¯æå æ§ããã²ã³
åéããã³ïŒãŸãã¯ææ©éå¡©é žåå€ãšè²çŽ äŸäžæ§
ç©è³ªãšã®é žåéå åå¿ãä¿é²ããåŒãç¶ããŠèµ·ã
ãè²çŽ ã®æŸåºåå¿ã§é žåãããè²çŽ äŸäžæ§ç©è³ªã«
æ±æ žçã«äœçšããŠè²çŽ æŸåºãä¿é²ããããšã®ã§ã
ããã®ã§ãå¡©åºãŸãã¯å¡©åºåé§äœãçšããããã
æ¬çºæã«ãããŠã¯åå¿ã®ä¿é²ã®ãããããã®è²çŽ
æŸåºå©å€ãçšããããšã¯ç¹ã«æå©ã§ããã 奜ãŸããå¡©åºã®äŸãšããŠã¯ãã¢ãã³é¡ãããã
ããšãã§ããããªã¢ã«ãã«ã¢ãã³é¡ãããããã·
ã«ã¢ãã³é¡ãèèªæããªã¢ãã³é¡ãâã¢ã«ãã«
眮æè³éŠæã¢ãã³é¡ãâããããã·ã«ã¢ã«ãã«
眮æè³éŠæã¢ãã³é¡ããã³ãïœâïŒãžã¢ã«ãã«ã¢
ããïŒããšãã«ãã¡ã¿ã³é¡ããããããšãã§ã
ãããŸãç±³åœç¹èš±ç¬¬2410644å·ã«ã¯ããã¿ã€ã³ãš
ãŠåããã©ã¡ãã«ã¢ã³ã¢ããŠã ããžã¢ãããã¿ã³
ãžãããã¯ãã©ã€ãããç±³åœç¹èš±ç¬¬3506444å·ã«
ã¯ãŠã¬ã¢ãïŒâã¢ããã«ããã³é žã®ãããªã¢ãã
é žãå«ãææ©ååç©ãèšèŒããæçšã§ãããå¡©åº
åé§äœã¯ãå ç±ã«ããå¡©åºæ§æåãæŸåºãããã®
ã§ãããå žåçãªå¡©åºåé§äœã®äŸã¯è±åœç¹èš±ç¬¬
998949å·ã«èšèŒãããŠããã奜ãŸããå¡©åºåé§äœ
ã¯ãã«ã«ãã³é žãšææ©å¡©åºã®å¡©ã§ããæçšãªã«ã«
ãã³é žãšããŠã¯ããªã¯ããé ¢é žãããªã¯ããé ¢
é žãæçšãªå¡©åºãšããŠã¯ã°ã¢ããžã³ããããªãž
ã³ãã¢ã«ããªã³ãïœâãã«ã€ãžã³ãïŒâãã³ãªã³
ãªã©ããããç±³åœç¹èš±ç¬¬3220846å·èšèŒã®ã°ã¢ã
ãžã³ããªã¯ããé ¢é žã¯ç¹ã«æçšã§ããããŸãç¹é
æ50â22625å·å ¬å ±ã«èšèŒãããŠããã¢ã«ãã³ã¢
ããé¡ã¯é«æž©ã§å解ãå¡©åºãçæãããã®ã§å¥œãŸ
ããçšããããã ãããã®è²çŽ æŸåºå©å€ã¯åºãç¯å²ã§çšããããš
ãã§ãããæçšãªç¯å²ã¯æå ææã®å¡åžä¹Ÿèãé
éã«æç®ãããã®ã®50ééããŒã»ã³ã以äžãæŽã«
奜ãŸããã¯ã0.01ééããŒã»ã³ããã40ééããŒ
ã»ã³ãã®ç¯å²ã§ããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã§ã¯äžèšäžè¬åŒ
ã§ç€ºãããååç©ãçšãããšçŸåãä¿é²ãããè²
çŽ ã®æŸåºãä¿é²ããæå©ã§ããã ãäžè¬åŒã äžåŒã«ãããŠA1ïŒA2ïŒA3ïŒA4ã¯åäžããŸãã¯
ç°ãªã€ãŠããŠãè¯ããããããæ°ŽçŽ ååãã¢ã«ã
ã«åºã眮æã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºãã¢ã©
ã«ãã«åºãã¢ãªãŒã«åºã眮æã¢ãªãŒã«åºããã³è€
çŽ ç°æ®åºã®äžããéžã°ãã眮æåºãè¡šããããŸã
A1ãšA2ãããã¯A3ãšA4ãé£çµããŠç°ã圢æããŠ
ããŠãããã å ·äœäŸãšããŠã¯ãH2NSO2NH2ïŒH2NSO2N
ïŒCH3ïŒ2ïŒH2NSO2NïŒC2H5ïŒ2ïŒH2NSO2NHCH3ïŒ
H2NSO2NïŒC2H4OHïŒ2ïŒCH3NHSO2NHCH3ïŒ
äœäŸã¯ç¹é¡æ56â16131ãå57â650ãå57â4043
ã«èšèŒãããŠããã åŒïŒïŒããã³åŒïŒïŒã®æ¬è³ªçãªéšåã¯ãã©
âïŒã¹ã«ããã«ïŒã¢ããããšããŒã«éšåã§ããã
å ·äœçãªäŸãšããŠã¯ãUS3928312ãUS4076529ã
US Published Patent Application  351673ã
US4135929ãUS4258120ã«é瀺ãããéå æ§åºè³ª
ããããããããããããæ¬çºæã®éå æ§åºè³ª
ïŒRaïŒãšããŠæå¹ã§ããã æ¬çºæã®ããã«å¥œãŸããå¥ã®æ æ§ã«ãããŠã¯ã
éå æ§åºè³ªïŒRaïŒã¯æ¬¡åŒïŒïŒã§è¡šããããã ããã§ãBallastã¯èæ¡æ£æ§åºãããããã Gaã¯ãæ°Žé žåºåã¯æ°Žé žåºã®ãã¬ã«ãŒãµãŒãè¡š
ããã G1 aã¯ãè³éŠæç°ããããããã³ãŒã³ç°ãšãšã
ã«ããã¿ã¬ã³ç°ã圢æããåºããããããïœãã
ã³ïœã¯ïŒåã¯ïŒã®ããšãªã€ãæŽæ°ãããããã äžèšXIIã«å å«ãããå ·äœäŸã¯US4053312ã«èšèŒ
ãããŠããã åŒïŒïŒïŒïŒïŒïŒïŒïŒããã³ïŒïŒã®éå æ§åº
質ã¯ããããç°ãå«ãããšãç¹åŸŽã§ãããå ·äœç
ãªäŸãšããŠã¯ãUS4198235ãç¹éæ53â46730ã
US4273855ã«èšèŒãããŠãããã®ããããããã
åŒïŒïŒã§è¡šããããéå æ§åºè³ªã®å ·äœäŸã¯
US4149892ã«èšèŒãããã éå æ§åºè³ªRaã«èŠæ±ãããç¹æ§ãšããŠæ¬¡ã®ã
ã®ãæããããã ïŒ ããã²ã³åéã«ããéãã«é žåãããè²çŽ æŸ
åºå©å€ã®äœçšã«ãã€ãŠå¹çããç»å圢æçšã®æ¡
æ£æ§è²çŽ ãæŸåºããããšã ïŒ è²çŽ äŸäžæ§ç©è³ªã¯èŠªæ°Žæ§ãªããçæ°Žæ§ãã€ã³
ããŒäžã§èæ¡æ£æ§ã§ãããæŸåºãããè²çŽ ã®ã¿
ãæ¡æ£æ§ãæããããšãå¿ èŠã§ããããã®ã
ããéå æ§åºè³ªïŒ²ã¯å€§ããªçæ°Žæ§ãæããã
ãšã ïŒ ç±ããã³è²çŽ æŸåºå©å€ã«å¯Ÿããå®å®æ§ãåª
ããé žåããããŸã§ã¯ç»å圢æçšè²çŽ ãæŸåºã
ãªãããšã ïŒ åæã容æãªããš ãªã©ãæããããã 次ã«ãããã®æ¡ä»¶ãæºããRaã«ã€ããŠã®å¥œãŸ
ããå ·äœäŸã瀺ããäŸäžãNHâã¯è²çŽ éšãšã®é£
çµãè¡šããã ç»å圢æçšè²çŽ ã«å©çšã§ããè²çŽ ã«ã¯ã¢ãŸè²
çŽ ãã¢ãŸã¡ãã³è²çŽ ãã¢ã³ãã«ããã³è²çŽ ããã
ãããã³è²çŽ ãã¹ããªã«è²çŽ ããããè²çŽ ããã
ãªã³è²çŽ ãã«ã«ããã«è²çŽ ããã¿ãã·ã¢ãã³è²çŽ
ãªã©ãããããã®ä»£è¡šäŸãè²çŽ å¥ã«ç€ºãããªãã
ãããã®è²çŽ ã¯çŸååŠçæã«è€è²å¯èœãªãäžæç
ã«çæ³¢åãã圢ã§çšãããšãã§ããã äžåŒã«ãããŠR51 aãR56 aã¯ãåã æ°ŽçŽ ååãã¢
ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºãã¢ã©ã«ãã«åºãã¢
ã«ã³ãã·åºãã¢ãªãŒã«ãªãã·åºãã¢ãªãŒã«åºãã¢
ã·ã«ã¢ããåºãã¢ã·ã«åºãã·ã¢ãåºãæ°Žé žåºãã¢
ã«ãã«ã¹ã«ããã«ã¢ããåºãã¢ãªãŒã«ã¹ã«ããã«
ã¢ããåºãã¢ã«ãã«ã¹ã«ããã«åºãããããã·ã¢
ã«ãã«åºãã·ã¢ãã¢ã«ãã«åºãã¢ã«ã³ãã·ã«ã«ã
ãã«ã¢ã«ãã«åºãã¢ã«ã³ãã·ã¢ã«ãã«åºãã¢ãªãŒ
ã«ãªãã·ã¢ã«ãã«åºããããåºãããã²ã³ãã¹ã«
ãã¢ã¢ã€ã«åºãâ眮æã¹ã«ãã¢ã¢ã€ã«åºãã«ã«
ãã¢ã€ã«åºãâ眮æã«ã«ãã¢ã€ã«åºãã¢ã·ãŒã«
ãªãã·ã¢ã«ãã«åºãã¢ããåºã眮æã¢ããåºãã¢
ã«ãã«ããªåºãã¢ãªãŒã«ããªåºãã®äžããéžã°ã
ã眮æåºãè¡šããããããã®çœ®æåºäžã®ã¢ã«ãã«
åºããã³ã¢ãªãŒã«åºéšåã¯ããã«ããã²ã³ååã
æ°Žé žåºãã·ã¢ãåºãã¢ã·ã«åºãã¢ã·ã«ã¢ããåºã
ã¢ã«ã³ãã·åºãã«ã«ãã¢ã€ã«åºã眮æã«ã«ãã¢ã€
ã«åºãã¹ã«ãã¢ã¢ã€ã«åºã眮æã¹ã«ãã¢ã¢ã€ã«
åºãã«ã«ããã·ã«åºãã¢ã«ãã«ã¹ã«ããã«ã¢ãã
åºãã¢ãªãŒã«ã¹ã«ããã«ã¢ããåºãŸãã¯ãŠã¬ã€ã
åºã§çœ®æãããŠããŠãããã 芪氎æ§åºãšããŠã¯æ°Žé žåºãã«ã«ããã·ã«åºãã¹
ã«ãåºããªã³é žåºãã€ããåºããããããµã é ž
åºãåçŽã¢ã³ã¢ããŠã åºãã«ã«ãã¢ã€ã«åºã眮æ
ã«ã«ãã¢ã€ã«åºãã¹ã«ãã¢ã¢ã€ã«åºã眮æã¹ã«ã
ã¢ã¢ã€ã«åºãã¹ã«ãã¢ã¢ã€ã«ã¢ããåºã眮æã¹ã«
ãã¢ã¢ã€ã«ã¢ããåºããŠã¬ã€ãåºã眮æãŠã¬ã€ã
åºãã¢ã«ã³ãã·åºãããããã·ã¢ã«ã³ãã·åºãã¢
ã«ã³ãã·ã¢ã«ã³ãã·åºãªã©ãæããããã æ¬çºæã«ãããŠã¯ç¹ã«å¡©åºæ§æ¡ä»¶äžã§ãããã³
解é¢ããããšã«ãã芪氎æ§ãèããå¢å€§ãããã®
ã奜ãŸãããã®äžã«ã¯ããšããŒã«æ§æ°Žé žåºãã«ã«
ããã·ã«åºãã¹ã«ãåºããªã³é žåºãã€ããåºãã
ããããµã é žåºãïŒçœ®æïŒã¹ã«ãã¢ã¢ã€ã«åºãïŒçœ®
æïŒã¹ã«ãã¢ã¢ã€ã«ã¢ããåºãªã©ãå«ãŸããã ç»å圢æçšè²çŽ ã«èŠæ±ãããç¹æ§ã¯ãïŒïŒè²å
çŸã«é©ããè²çžãæããããšãïŒïŒåååžå ä¿æ°
ã倧ããããšãïŒïŒå ãç±ããã³ç³»äžã«å«ãŸãã
è²çŽ æŸåºå©å€ãã®ä»ã®æ·»å å€ã«å¯ŸããŠå®å®ãªã
ãšãïŒïŒåæã容æãªããšããªã©ãæããããã
ãããã®è«žæ¡ä»¶ãæºãã奜ãŸããç»å圢æçšè²çŽ
ã®å ·äœäŸã次ã«ç€ºããããã§H2NâSO2ã¯éå æ§
åºè³ªãšã®çµåéšãè¡šããã 次ã«å¥œãŸããè²çŽ äŸäžæ§ç©è³ªã®å ·äœäŸã瀺ãã æ¬çºæã®è²çŽ äŸäžæ§ç©è³ªãšããŠãäžèšã®å ·äœäŸ
ã®ã»ãã«ãUS4055428ãç¹éæ56â12642ãå56
â16130ãå56â16131ãå57â650ãå57â4043ã
US3928312ãUS4076529ãUS Published Patent
Application B351673ãUS4135929ã
US4198235ãç¹éæ53â46730ãUS4273855ã
US4149892ãUS4142891ãUS4258120ãªã©ã«èšèŒ
ãããŠããååç©ãæå¹ã§ããã ããã«ãUS4013633ãUS4156609ã
US4148641ãUS4165987ãUS4148643ã
US4183755ãUS4246414ãUS4268625ã
US4245028ãç¹éæ56â71072ãå56â25737ãå
55â138744ãå55â134849ãå52â109727ãå51
â114930ãªã©ã«èšèŒãããã€ãšããŒè²çŽ ãæŸåºã
ãè²çŽ äŸäžæ§ç©è³ªãæ¬çºæã«æå¹ã§ããããŸã
US3954476ãUS4932380ãUS3931144ã
US3932381ãUS4268624ãUS4255509ãç¹éæ56
â73057ãå56â71060ãå55â134850ãå55â
40402ãå55â36804ãå53â23628ãå52â
106727ãå55â33142ãå55â53329ãªã©ãããã
ããããŒã³ã¿è²çŽ ãæŸåºããè²çŽ äŸäžæ§ç©è³ªãæ¬
çºæã«æå¹ã§ããããŸãUS3929760ã
US4013635ãUS3942987ãUS4273708ã
US4148642ãUS4183754ãUS4147544ã
US4165238ãUS4246414ãUS4268625ãç¹éæ56
â71061ãå53â47823ãå52â8827ãå53â
143323ãªã©ã«ãããããã·ã¢ã³è²çŽ ãæŸåºããè²
çŽ äŸäžæ§ç©è³ªãæ¬çºæã«æå¹ã§ããã è²çŽ äŸäžæ§ç©è³ªã¯ãïŒçš®ä»¥äžäœµçšããŠãããã
ãã®å Žåãåäžè²çŽ ãããããæã«ïŒçš®ä»¥äžäœµçš
ããŠããããïŒçš®ä»¥äžã䜵çšããŠé»ãããããå Ž
åãå«ãŸããã è²çŽ äŸäžæ§ç©è³ªã¯åèšãšããŠã10mgïŒm2ãã15
ïœïŒm2ã®ç¯å²ã§çšããã®ãé©åœã§ããã奜ãŸãã
ã¯20mgïŒm2ãã10ïœïŒm2ã®ç¯å²ã§çšããã®ãæå©
ã§ããã 次ã«è²çŽ äŸäžæ§ç©è³ªã®åææ³ã«ã€ããŠè¿°ã¹ãã äžè¬ã«æ¬çºæã®è²çŽ äŸäžæ§ç©è³ªã¯éå æ§åºè³ª
Raã®ã¢ããåºãšç»å圢æçšè²çŽ éšã®ã¯ããã¹ã«
ããã«åºãçž®åãããããšã«ãã€ãŠåŸãããã éå æ§åºè³ªRaã®ã¢ããåºã¯åºè³ªã®çš®é¡ã«å¿ã
ãŠããããããããœãã¢ãŸåºã®éå ãããã¯ãã³
ãŸãªããµãŸãŒã«ã®éç°ã«ãã€ãŠå°å ¥ããããšãã§
ããéé¢å¡©åºãšããŠããç¡æ©é žã®å¡©ãšããŠã䜿çš
ã§ãããäžæ¹ãç»å圢æçšè²çŽ éšã®ã¯ããã¹ã«ã
ãã«åºã¯è©²è²çŽ ã®ã¹ã«ãã³é žãªããã¹ã«ãã³é žå¡©
ããåžžæ³ããªãã¡ããªãã·å¡©åãªã³ãäºå¡©åãª
ã³ãå¡©åããªãã«çã®ã¯ããåå€ã®äœçšã«ããèª
å°ã§ããã éå æ§åºè³ªRaãšç»å圢æçšè²çŽ éšïŒ€ãšã®çž®å
åå¿ã¯ãäžè¬ã«ãžã¡ãã«ãã«ã ã¢ããããžã¡ãã«
ã¢ã»ãã¢ããããžã¡ãã«ã¹ã«ããã·ããâã¡ã
ã«ãããªãã³ãã¢ã»ããããªã«çã®éãããã³æ§
極æ§æº¶åªäžãããªãžã³ããã³ãªã³ãã«ããžã³ãã
ãªãšãã«ã¢ãã³ããžã€ãœãããã«ãšãã«ã¢ãã³ç
ã®ææ©å¡©åºã®ååšäžãïŒã50âã®æž©åºŠã è¡ãããš
ãã§ããéåžžã極ããŠåçè¯ãç®çãšããè²çŽ äŸ
äžæ§ç©è³ªãåŸãããšãã§ããã 以äžã«ãã®åæäŸã瀺ãã åæäŸ ïŒ ïŒâããããã·âïŒâã¡ãã«ãã³ãŸãªããµãŸãŒ
ã«ã®åæ ïŒïŒïŒâãžããããã·ã¢ã»ãããšãã³306ïœã
ããããã·ã«ã¢ãã³å¡©é žå¡©164ïœãé ¢é žãããªãŠ
ã 328ïœããšã¿ããŒã«1000mlãããã³æ°Ž500mlãæ··
åããïŒæéå ç±éæµãããåå¿æ¶²ãæ°Ž10ã«ã
ããæåºããçµæ¶ãåããŠãïŒïŒïŒâãžããã
ãã·ã¢ã»ãããšãã³ãªãã·ã 314ïœãåŸãã ãã®ãªãã·ã 30ïœãé ¢é ž400mlã«æº¶è§£ãã120â
ã«ãŠå ç±æ¹æããªãããïŒæéå¡©åæ°ŽçŽ ã¬ã¹ãå¹
蟌ãã ãå·åŽåŸæåºããçµæ¶ãåãã次ãã§æ°Ž
ã§æŽæµããŠãïŒâããããã·âïŒâã¡ãã«ãã³ãº
ãªããµãŸãŒã«17ïœãåŸãã åæå ïŒ ïŒâãããµãã·ã«ãªãã·âïŒâã¡ãã«ãã³ãŸãª
ããµãŸãŒã«ã®åæ åæäŸïŒã§åæããïŒâããããã·âïŒâã¡ã
ã«ãã³ãºãªããµãŸãŒã«18.0ïœãïŒâããã¢ãããµ
ãã«ã³36.9ïœãçé žã«ãªãŠã 24.0ïœãïŒïŒ®âãž
ã¡ãã«ãã«ã ã¢ãã120mlã90âã§4.5æéæ¹æã
ããåå¿æ¶²ãããåºäœãå¥ãã液ãã¡ã¿ããŒ
ã«500mlã«ããããæåºããçµæ¶ãåããŠãïŒ
âãããµãã·ã«ãªãã·âïŒâã¡ãã«ãã³ãºãªããµ
ãŸãŒã«45.0ïœãåŸãã åæäŸ ïŒ ïŒâã¢ã»ãã«ã¢ããâïŒâãããµãã·ã«ãªãã·
ããšããŒã«ã®åæ åæäŸïŒã§åŸãïŒâãããµãã·ã«ãªãã·âïŒâ
ã¡ãã«ãã³ãºãªããµãŸãŒã«111ïœããšã¿ããŒã«
1300mlã33ïŒ å¡©é ž110mlãæ°Ž550mlãæ··åãã55ã
60âã§ïŒæéæ¹æãããå·åŽåŸæåºããçµæ¶ã
åãïŒâã¢ã»ãã«ã¢ããâïŒâãããµãã·ã«ãªã
ã·ããšããŒã«113ïœãåŸãã åæäŸ ïŒ ïŒâã¢ã»ãã«ã¢ããâïŒâïœâããã«âïŒâã
ããµãã·ã«ãªãã·ããšããŒã«ã®åæ åæäŸïŒã§åŸãïŒâã¢ã»ãã«ã¢ããâïŒâãã
ãµãã·ã«ãªãã·ããšããŒã«30.0ïœãã¢ã³ããŒãªã¹
ã15ïŒç±³åœã»ããŒã ã»ã¢ã³ãã»ããŒã¹ç€Ÿç»é²åæšïŒ
20.0ïœããã«ãšã³300mlãæ··åãã80ã90âã§å
ç±æ¹æããªãããã€ãœããã³ãïŒæéå¹ã蟌ã
ã ãåºäœãå»ããã®ã¡ã液ãæ¿çž®ããæ®æž£ã«
ïœâãããµã³350mlãå ãããšçµæ¶ãæåºããã
åããŠãïŒâã¢ã»ãã«ã¢ããâïŒâïœâããã«
âïŒâãããµãã·ã«ãªãã·ããšããŒã«23.5ïœãåŸ
ãã åæäŸ ïŒ ïŒâã¢ããâïŒâïœâããã«âïŒâãããµãã·
ã«ãªãã·ããšããŒã«ã®åæ åæäŸïŒã§åŸãïŒâã¢ã»ãã«ã¢ããâïŒâïœâ
ããã«âïŒâãããµãã·ã«ãªãã·ããšããŒã«23.0
ïœããšã¿ããŒã«120mlã35ïŒ å¡©é ž96mlãæ··åãã
ïŒæéæ¹æéæµãããåå¿æ¶²ãå·åŽããã®ã¡ãæ
åºããçµæ¶ãåããŠãïŒâã¢ããâïŒâïœâã
ãã«âïŒâãããµãã·ã«ãªãã·ããšããŒã«å¡©é žå¡©
23.2ïœãåŸãã åæäŸ ïŒ ïŒâïœâããã«âïŒâãããµãã·ã«ãªãã·âïŒ
âãïŒâïŒïŒâã¡ããã·ãšããã·ïŒâïŒâãã
ããã³ãŒã³ã¹ã«ããã«ã¢ãããããšããŒã«ã®å
æ åæäŸïŒã§åŸãïŒâã¢ããâïŒâïœâããã«â
ïŒâãããµãã·ã«ãªãã·ããšããŒã«å¡©é žå¡©4.4ïœ
ããã³ïŒâïŒïŒâã¡ããã·ãšããã·ïŒâïŒâãã
ããã³ãŒã³ã¹ã«ããã«ã¯ããªã3.18ïœãïŒïŒ®â
ãžã¡ãã«ã¢ã»ãã¢ãã12mlã«æº¶è§£ããããªãžã³
2.5mlãå ããã®ã¡ãïŒæé25âã§æ¹æãããå
å¿æ¶²ãçšå¡©é žã«ãããå ¥ãããšæ²¹ç¶ç©ãæåºã
ãããã®æ²¹ç¶ç©ã«ã¡ã¿ããŒã«30mlãå ãããšçµæ¶
åããã®ã§ãããåããã åé4.5ïœã åæäŸ ïŒ ïŒâãïŒâã¢ããâïŒâïŒïŒâã¡ããã·ãšãã
ã·ïŒãã³ãŒã³ã¹ã«ããã«ã¢ãããâïŒâïœâã
ãã«âïŒâãããµãã·ã«ãªãã·ããšããŒã«ã®å
æ äžèšåæäŸïŒã§åŸãååç©10ïœããšã¿ããŒã«60
mlã«æº¶è§£ãã10ïŒ ãã©ãžãŠã âççŽ è§ŠåªçŽ0.5ïœ
ãæ·»å ããã®ã¡ãæ°ŽçŽ ã55KgïŒcm2ãŸã§å§å ¥ãã60
âã§ïŒæéæ¹æããã次ãã§ã觊åªãç±æå»
ããæŸå·ãããšçµæ¶ãæåºããã®ã§åããã åé7.5ïœã åæäŸ ïŒ ïŒâã·ã¢ãâïŒâãïŒâïŒïŒâã¡ããã·ãšãã
ã·ïŒâïŒâã¹ã«ãããšãã«ã¢ãŸãâïŒâããšã
ã«âïŒâãã©ãŸãã³ã®åæ æ°Žé žåãããªãŠã 8.0ïœãšæ°Ž200mlã®æº¶æ¶²ã«ïŒâ
ã¢ããâïŒâïŒïŒâã¡ããã·ãšããã·ïŒãã³ãŒã³
ã¹ã«ãã³é ž49.4ïœãå ããããã«äºç¡é žãœãŒã
13.8ïœã®æ°Žæº¶æ¶²ïŒ50mlïŒãå ãããå¥ã«æ¿å¡©é ž60
mlãšæ°Ž400mlã®æº¶æ¶²ã調補ãããããïŒâ以äžã§
äžèšæº¶æ¶²ã滎äžããããã®åŸïŒâ以äžã§30åéæ¹
æãåå¿ãå®çµãããã å¥ã«æ°Žé žåãããªãŠã 16.0ïœãæ°Ž200mlãé ¢é ž
ãããªãŠã 33.0ïœããã³ã¡ã¿ããŒã«200mlã®æº¶æ¶²
ã調åããïŒâã·ã¢ãâïŒâããšãã«âïŒâãã©
ãŸãã³37.0ïœãå ãã10â以äžã§äžèšèª¿è£œæžã®ãž
ã¢ãŸæ¶²ã滎äžããã滎äžçµäºåŸ10â以äžã§30åé
æ¹æããã€ãã§å®€æž©ã§ïŒæéæ¹æããåŸãæåºã
ãçµæ¶ãåããã¢ã»ãã³200mlã§æŽæµãã颚也
ããã åé52.0ïœ m.p.263ã265â åæäŸ ïŒ ïŒâã·ã¢ãâïŒâãïŒâïŒïŒâã¡ããã·ãšãã
ã·ïŒâïŒâã¯ããã¹ã«ãããšãã«ã¢ãŸãâïŒâ
ããšãã«âïŒâãã©ãŸãã³ã®åæ äžèšåæäŸïŒã§åŸãïŒâã·ã¢ãâïŒâãïŒïŒâ
ã¡ããã·ãšããã·âïŒâã¹ã«ãããšãã«ã¢ãŸãâ
ïŒâããšãã«âïŒâãã©ãŸãã³51.0ïœãã¢ã»ãã³
250mlããã³ãªãã·å¡©åãªã³50mlã®æ··å溶液ã«ïŒ®ïŒ
âãžã¡ãã«ã¢ã»ãã¢ãã50mlã50â以äžã§æ»Žäž
ããã滎äžåŸçŽïŒæéæ¹æããæ°·æ°Ž1.0ã®äžã«
åŸã ã«æ³šãã ãæåºããçµæ¶ãå¥åŸãã¢ã»ãã
ããªã«100mlã§æŽæµãã颚也ããã åé46.7ïœ m.p.181ã183â åæäŸ 10 è²çŽ äŸäžæ§ç©è³ª(1)ã®åæ åæäŸïŒã§åŸãïŒâãïŒâã¢ããâïŒâïŒïŒâ
ã¡ããã·ãšããã·ïŒãã³ãŒã³ã¹ã«ããã«ã¢ããïŒ
âïœâããã«âïŒâãããµãã·ã«ãªãã·ããšããŒ
ã«6.3ïœãïŒïŒ®âãžã¡ãã«ã¢ã»ãã¢ãã30mlã«
溶解ããåæäŸïŒã§åŸãïŒâã·ã¢ãâïŒâãïŒâ
ïŒïŒâã¡ããã·ãšããã·ïŒâïŒâã¯ããã¹ã«ãã
ã«ããšãã«ã¢ãŸãâïŒâããšãã«âïŒâãã©ãŸã
ã³4.6ïœãå ããããã«ããªãžã³ïŒmlãå ããã
宀枩ã§ïŒæéæ¹æããã®ã¡ãåå¿æ¶²ãçšå¡©é žã«æ³š
ããæåºããçµæ¶ãåãããïŒïŒ®âãžã¡ãã«
ã¢ã»ãã¢ããâã¡ã¿ããŒã«ããåçµæ¶ããŠ7.5ïœ
ãåŸãã m.p.189ã191â åæäŸ 11 è²çŽ äŸäžæ§ç©è³ª(2)ã®åæ åæäŸïŒã§åŸãïŒâãïŒâã¢ããâïŒâïŒïŒâ
ã¡ããã·ãšããã·ïŒãã³ãŒã³ã¹ã«ããã«ã¢ããâ
ïŒâïœâããã«âïŒâãããµãã·ã«ãªãã·ããšã
ãŒã«6.3ïœãïŒïŒ®âãžã¡ãã«ã¢ã»ãã¢ãã30ml
ã«æº¶è§£ããïŒâã·ã¢ãâïŒâïŒïŒâã¯ããâïŒâ
ã¡ãã«ã¹ã«ããã«ããšãã«ã¢ãŸïŒâïŒâïŒïŒâã¯
ããã¹ã«ããã«ããšãã«ïŒâïŒâãã©ãŸãã³5.0
ïœãå ããããã«ããªãžã³ïŒmlãå ããã宀枩ã§
ïŒæéæ¹æããã®ã¡ãåå¿æ¶²ãçšå¡©é žã«æ³šããæ
åºããçµæ¶ãåãããã¢ã»ããããªã«ã§åçµæ¶
ããŠ8.4ïœãåŸãã m.p.144ã149â åæäŸ 12 è²çŽ äŸäžæ§ç©è³ª(10)ã®åæ ïŒâã¢ããâïŒâïœâããã«âïŒâãããµãã·
ã«ãªãã·ããšããŒã«å¡©é žå¡©4.4ïœããã³ïŒâãïŒ
âã¯ããã¹ã«ããã«âïŒâïŒïŒâã¡ããã·ãšãã
ã·ïŒããšãã«ã¢ãŸãâïŒâïŒïŒ®ïŒïŒ®âãžãšãã«ã¹
ã«ãã¢ã¢ã€ã«ïŒâïŒâã¡ãã«ã¹ã«ããã«ã¢ããâ
ïŒâããããŒã«6.5ïœãïŒïŒ®âãžã¡ãã«ã¢ã»ã
ã¢ãã20mlã«æº¶è§£ãããªãžã³4.2mlãå ãããïŒ
æé25âã§æ¹æããã®ã¡ãåå¿æ¶²ãçšå¡©é žäžã«æ³š
ãå ¥ãããæåºããåºäœãåããã·ãªã«ã²ã«ã«
ã©ã ã¯ãããã°ã©ãã€ãŒïŒã¯ãããã«ã âé ¢é žãš
ãã«ïŒïŒïŒïŒïŒæ··å溶åªã§æº¶åºïŒã«ãã€ãŠç²Ÿè£œã
ãã åé5.2ïœã åæäŸ 13 è²çŽ äŸäžæ§ç©è³ªïŒ17ïŒã®åæ ïŒâã¢ããâïŒâïœâããã«âïŒâãããµãã·
ã«ãªãã·ããšããŒã«å¡©é žå¡©11.6ïœãïŒïŒ®âãžã¡
ãã«ã¢ã»ãã¢ãã100mlã«æº¶è§£ããããªãžã³12ml
ãå ãããããã«ïŒâïŒïŒâã¯ããã¹ã«ããã«ã
ã³ãŒã³ã¹ã«ããã«ã¢ããïŒâïŒâïŒïŒ®âïœâãã
ã«ã¹ã«ãã¢ã¢ã€ã«ïŒâïŒâïŒïŒâã¡ãã«ã¹ã«ãã
ã«âïŒâãããããšãã«ã¢ãŸïŒâïŒâããããŒã«
20ïœãå ãããïŒæéæ¹æåŸãæ°·æ°Ž500mlã«ããã
æåºç©ãã€ãœãããã«ã¢ã«ã³ãŒã«âã¢ã»ããããª
ã«ïŒïŒïŒïŒïŒã§åçµæ¶ããŠ6.8ïœãåŸãã åæäŸ 14 è²çŽ äŸäžæ§ç©è³ªïŒ19ïŒã®åæ ïŒâãïŒâã¢ããâïŒâïŒïŒâã¡ããã·ãšãã
ã·ïŒãã³ãŒã³ã¹ã«ããã«ã¢ãããâïŒâïœâãã
ã«âïŒâãããµãã·ã«ãªãã·ããšããŒã«31.5ïœã
ïŒâïŒïŒâã¯ããã¹ã«ããã«ãã³ãŒã³ã¹ã«ããã«
ã¢ããïŒâïŒâïŒïŒâã¡ãã«ã¹ã«ããã«âïŒâã
ããããšãã«ã¢ãŸïŒâïŒâããããŒã«39.1ïœã
ïŒïŒ®âãžã¡ãã«ã¢ã»ãã¢ãã100mlã«æº¶è§£ãã
ããªãžã³21mlãå ããã80åæ¹æåŸãã¡ã¿ããŒã«
250mlãæ°Ž100mlãå ãããæåºããæš¹èç¶ç©ã¯ã
ã°ãããããšåºåããã®ã§åãããããããã«
ãšã³âã¡ã¿ããŒã«âæ°ŽïŒ16ïŒïŒïŒïŒïŒæ··åç³»ãã
åçµæ¶ããŠ41.5ïœåŸãã åæäŸ 15 ååç©40ã®åæ ïœïŒ ïŒïŒïŒâãžããããã·âïŒâïœâããã«ã¢
ã»ãããšãã³ã®åæ ïœâããã«ãããããã³83ïœãé ¢é ž400mlã«
溶解ãã80ã90âã«å ç±ããªããäžããåããŠ
çŽ ïŒBF3ïŒãçŽïŒæéå°å ¥ãããåå¿çµäºåŸïŒ
ã®æ°·æ°Žäžã«æ³šãæåºããç²èª¿ãªåºäœãåã
ãããã®åºäœã2NâNaOH600mlã«æº¶è§£ããäž
溶éšãå»ããã液ãçšå¡©é žã«ããé žæ§ãš
ããæåºããçµæ¶ãåããŠæ°ŽæŽããåŸãå«æ°Ž
ã¡ã¿ããŒã«ããåçµæ¶ããã åé68ïœïŒ65ïŒ ïŒ ïœïŒ ïŒïŒïŒâãžããããã·âïŒâïœâããã«ã¢
ã»ãããšãã³ããªãã·ã ã®åæ äžèšïœïŒã§åŸãããã±ãã³21ïœããšã¿ããŒã«
70mlãé ¢é žãããªãŠã 24ïœãšãšãã«å ç±æº¶è§£ã
ããæ¹æããªããå¡©é žããããã·ã«ã¢ãã³12ïœ
ãæ°Ž70mlã«æº¶è§£ããã液ãå ãçŽïŒæééæµã
ããåå¿çµäºåŸ500mlã®æ°·æ°Žã«æ³šãæåºçµæ¶ã
åããã³ãŒã³âãããµã³ããåçµæ¶ããã åé17ïœïŒ76ïŒ ïŒ ïœïŒ ïŒâïœâããã«âïŒâããããã·âïŒâã¡
ãã«ãã³ãºãªããµãŸãŒã«ã®åæ äžèšïœïŒã§åŸããªãã·ã 14ïœãé ¢é ž100mläž
ã«æº¶è§£ããå ç±ããªãã也ç¥å¡©é žã¬ã¹ãå°å ¥
ãã1.5æééæµãããåå¿çµäºåŸ500mlã®æ°·æ°Ž
äžã«æ³šãæåºçµæ¶ãåãæ°ŽæŽããã åéïŒïœïŒ70ïŒ ïŒ ïœïŒ ïŒâïœâããã«âïŒâãããµãã·ã«ãªãã·
âïŒâã¡ãã«ãã³ãºãªããµãŸãŒã«ã®åæ äžèšïœïŒã§åŸããã³ãºãªããµãŸãŒã«6.9ïœã
ãžã¡ãã«ãã«ã ã¢ãã50mlã«æº¶è§£ãããç¡æ°Žç
é žã«ãªãŠã ïŒïœãšãããµãã·ã«ãããã11ïœãš
å ±ã«80ã90âã«ãŠïŒæéæ¹æãããåå¿çµäº
åŸãç¡æ©ç©ãå»ããŠæ¶²ãã¡ã¿ããŒã«150ml
å ãæ°·å·ãããšçµæ¶ãæåºããããããåã
ãããšã«ããæšèšååç©ãåŸãã åé8.8ïœïŒ62ïŒ ïŒ ïœ ïŒ ïŒâã¢ããâïŒâïœâããã«âïŒâãããµ
ãã·ã«ãªãã·ããšããŒã«å¡©é žå¡©ã®åæ äžèšïœïŒã§åŸããã³ãºãªããµãŸãŒã«ååç©
7.3ïœããšã¿ããŒã«30mlãæ¿å¡©é ž20mlãšå ±ã«ïŒ
æééæµãããåå¿çµäºåŸãæŸå·ãæåºããçµ
æ¶ãåãæ°ŽæŽããåŸã¢ã»ãã³ã§æŽæµããã åé6.9ïœïŒ92ïŒ ïŒ ïœïŒ ååç©40ã®åæ äžèšïœ ïŒã§åŸãå¡©é žå¡©ïŒïœãšäžèšæ§é åŒã®è²
çŽ ã®ã¹ã«ããã«ã¯ããªã8.8ïœããžã¡ãã«ã¢ã»
ãã¢ãã50mlã«æº¶è§£ãããããªãžã³ïŒmlãå ã
ãŠå®€æž©ã§ïŒæéæ¹æãããåå¿çµäºåŸãçšå¡©é ž
äžã«æ³šãæåºããçµæ¶ãåããæ°ŽæŽããã也
ç¥åŸã·ãªã«ã²ã«ã¯ãããã°ã©ãã€ãŒã«ãŠç²Ÿè£œã
å®è³ªçã«ïŒæåã®æšèšååç©ã2.2ïœåŸãã è²çŽ ã¹ã«ããã«ã¯ããªãïŒ åæäŸ 16 è²çŽ äŸäžæ§ç©è³ªïŒ42ïŒã®åæ äžèšåæäŸ15dïŒã«ãããŠãïŒâïœâããã«â
ïŒâããããã·âïŒâã¡ãã«ãã³ãºãªããµãŸãŒã«
ã®ãããã«ïŒâïœâãªã¯ãã«âïŒâããããã·â
ïŒâã¡ãã«ãã³ãºãªããµãŸãŒã«ãçšããŠãâã
ããµãã·ã«åãè¡ã€ãã次ãã§åæäŸ15eïŒãã
ã³ïœïŒãšåæ§ã®åŠçã«ãã€ãŠè²çŽ äŸäžæ§ç©è³ª
ïŒ42ïŒãåŸãã æ¬çºæã®è²çŽ äŸäžæ§ç©è³ªã¯ãç±³åœç¹èš±2322027
å·èšèŒã®æ¹æ³ãªã©ã®å ¬ç¥ã®æ¹æ³ã«ããæå ææã®
å±€äžã«å°å ¥ããããšãã§ããããã®å Žåäžèšã®åŠ
ãé«æ²žç¹ææ©æº¶åªïŒäœæ²žç¹ææ©æº¶åªãçšããããš
ãã§ããã ããšãã°ãã¿ãŒã«é žã¢ã«ãã«ãšã¹ãã«ïŒãžãã
ã«ãã¿ã¬ãŒãïŒãžãªã¯ãã«ãã¿ã¬ãŒããªã©ïŒïŒãª
ã³é žãšã¹ãã«ïŒãžããšãã«ãã¹ããšãŒãïŒããªã
ãšãã«ãã¹ããšãŒãïŒããªã¯ã¬ãžã«ãã¹ããšãŒ
ãïŒãžãªã¯ãã«ããã«ãã¹ããšãŒãïŒïŒã¯ãšã³é ž
ãšã¹ãã«ïŒäŸãã°ã¢ã»ãã«ã¯ãšã³é žããªããã«ïŒïŒ
å®æ¯éŠé žãšã¹ãã«ïŒå®æ¯éŠé žãªã¯ãã«ïŒïŒã¢ã«ã
ã«ã¢ããïŒäŸãã°ãžãšãã«ã©ãŠãªã«ã¢ããïŒïŒè
èªé žãšã¹ãã«é¡ïŒäŸãã°ãžãããã·ãšãã«ãµã¯ã·
ããŒãïŒãžãªã¯ãã«ã¢ãŒã¬ãŒãïŒïŒããªã¡ã·ã³é ž
ãšã¹ãã«é¡ïŒäŸãã°ããªã¡ã·ã³é žããªããã«ïŒãª
ã©ã®é«æ²žç¹ææ©æº¶åªïŒãŸãã¯æ²žç¹çŽ30âä¹è³160
âã®ææ©æº¶åªïŒäŸãã°é ¢é žãšãã«ïŒé ¢é žããã«ã®
åŠãäœçŽã¢ã«ãã«ã¢ã»ããŒãïŒããããªã³é žãšã
ã«ïŒäºçŽããã«ã¢ã«ã³ãŒã«ïŒã¡ãã«ã€ãœããã«ã±
ãã³ïŒÎ²âãšããã·ãšãã«ã¢ã»ããŒãïŒã¡ãã«ã»
ããœã«ãã¢ã»ããŒãïŒã·ã¯ããããµãã³ãªã©ã«æº¶
解ããã®ã¡ã芪氎æ§ã³ãã€ãã«åæ£ããããäžèš
ã®é«æ²žç¹ææ©æº¶åªãšäœæ²žç¹ææ©æº¶åªãšãæ··åããŠ
çšããŠãããã ãŸãç¹å ¬æ51â39853å·ïŒç¹éæ51â59943å·ã«
èšèŒãããŠããéåç©ã«ããåæ£æ³ã䜿çšã§ã
ãããŸãè²çŽ äŸäžæ§ç©è³ªã芪氎æ§ã³ãã€ãã«åæ£
ããéã«ãçš®ã ã®çé¢æŽ»æ§å€ãçšããããšãã§
ãããããã®çé¢æŽ»æ§å€ãšããŠã¯ãã®æ现æžã®äž
ã®å¥ã®ãšããã§çé¢æŽ»æ§å€ãšããŠæãããã®ã䜿
ãããšãã§ããã æ¬çºæã§çšããããé«æ²žç¹ææ©æº¶åªã®éã¯çšã
ãããè²çŽ äŸäžæ§ç©è³ªïŒïœã«å¯ŸããŠ10ïœä»¥äžã奜
ãŸããã¯ïŒïœä»¥äžã§ããã æ¬çºæã«ãããŠã¯ãå¿ èŠã«å¿ããŠéå å€ãçšã
ãããšãã§ããããã®å Žåã®éå å€ãšã¯æè¬è£å©
çŸåè¬ã§ãããããã²ã³åéããã³ïŒãŸãã¯ææ©
éå¡©é žåå€ã«ãã€ãŠé žåããããã®é žåäœããè²
çŽ äŸäžæ§ç©è³ªäžã®éå æ§åºè³ªRaãé žåããèœå
ãæãããã®ã§ããã æçšãªè£å©çŸåè¬ã«ã¯ãã€ããããã³ïŒïœâã
ãã«ãã€ããããã³ïŒïŒïŒïŒâãžã¡ãã«ãã€ãã
ããã³ãªã©ã®ã¢ã«ãã«çœ®æãã€ããããã³é¡ïŒã«
ãã³ãŒã«é¡ïŒããã¬ããŒã«é¡ïŒã¯ãããã€ããã
ãã³ããžã¯ãããã€ããããã³ãªã©ã®ããã²ã³çœ®
æãã€ããããã³é¡ïŒã¡ããã·ãã€ããããã³ãª
ã©ã®ã¢ã«ã³ãã·çœ®æãã€ããããã³é¡ïŒã¡ãã«ã
ãããã·ããã¿ã¬ã³ãªã©ã®ããªããããã·ãã³ãŒ
ã³èªå°äœããããæŽã«ãã¡ãã«ã¬ã¬ãŒãïŒã¢ã¹ã³
ã«ãã³é žïŒã¢ã«ã³ã«ãã³é žèªå°äœé¡ïŒïŒ®ïŒNâ²â
ãžâïŒïŒâãšããã·ãšãã«ïŒããããã·ã«ã¢ãã³
ãªã©ã®ããããã·ã«ã¢ãã³é¡ïŒïŒâããšãã«âïŒ
âãã©ãŸãªãã³ïŒïŒâã¡ãã«âïŒâããããã·ã¡
ãã«âïŒâããšãã«âïŒâãã©ãŸãªãã³ãªã©ã®ã
ã©ãŸãªãã³é¡ïŒã¬ãã¯ãã³é¡ïŒããããã·ããã©
é žé¡ãæçšã§ããã è£å©çŸåè¬ã¯äžå®ã®æ¿åºŠç¯å²ã§çšããããšãã§
ãããæçšãªæ¿åºŠç¯å²ã¯éã«å¯ŸããŠ0.0005åã¢ã«
ã20åã¢ã«ãç¹ã«æçšãªæ¿åºŠç¯å²ãšããŠã¯ã
0.001åã¢ã«ãïŒåã¢ã«ã§ããã æ¬çºæã§çšããããããã²ã³åéãšããŠã¯å¡©å
éãå¡©èåéãå¡©æ²åéãèåéãæ²èåéãå¡©
æ²èåéãæ²åéãªã©ãããã æ¬çºæã«ãããŠãææ©éå¡©é žåå€ã䜵çšããã«
ããã²ã³åéãåç¬ã«çšããå Žåã¯ãšãã«å¥œãŸã
ãããã²ã³åéãšããŠã¯ç²åã®äžéšã«æ²åéçµæ¶
ãå«ãã§ãããã®ã§ãããããªãã¡ããã²ã³åé
ã®ïŒžç·åæããšã€ããšãã«çŽæ²åéã®ãã¿ãŒã³ã®
ããããããã®ãç¹ã«å¥œãŸããã åçæå ææã«ã¯ïŒçš®ä»¥äžã®ããã²ã³ååãå«
ãããã²ã³åéãçšããããããéåžžã®ããã²ã³
åéä¹³å€ã§ã¯ããã²ã³åéç²åã¯å®å šãªæ··æ¶ãäœ
ã€ãŠãããäŸãã°æ²èåéä¹³å€ã§ã¯ãã®ç²åã®ïŒž
ç·åæã枬å®ãããšæ²åéçµæ¶ãèåéçµæ¶ã®ã
ã¿ãŒã³ã¯ããããããæ··åæ¯ã«å¿ããäœçœ®ã«ïŒžç·
ãã¿ãŒã³ããããããã æ¬é¡ã«ãããŠç¹ã«å¥œãŸããããã²ã³åéã¯æ²å
éçµæ¶ãç²åäžã«å«ãã§ãããåŸã€ãŠæ²åéçµæ¶
ã®ïŒžç·ãã¿ãŒã³ãçŸãããå¡©æ²åéãæ²èåéã
å¡©æ²åéã§ããã ãã®ãããªããã²ã³åéã¯äŸãã°æ²èåéã§ã¯
èåã«ãªãŠã 溶液äžã«ç¡é žé溶液ãæ·»å ããŠãŸã
èåéç²åãäœãããã®åŸã«æ²åã«ãªãŠã ãæ·»å
ããããšã«ãã€ãŠåŸãããã ããã²ã³åéã¯ããµã€ãºããã³ïŒåã¯ããã²ã³
çµæã®ç°ãªãïŒçš®ä»¥äžã䜵çšããŠãããã æ¬çºæã§çšããããããã²ã³åéç²åã®ãµã€ãº
ã¯å¹³åç²åŸã0.001ÎŒmãã10ÎŒmã®ãã®ã奜ãŸã
ããæŽã«å¥œãŸããã¯0.001ÎŒmãã5ÎŒmã§ããã æ¬çºæã§äœ¿çšãããããã²ã³åéã¯ãã®ãŸãŸäœ¿
çšãããŠããããæŽã«ç¡«é»ãã»ã¬ã³ããã«ã«çã®
ååç©ãéãçœéããã©ãžãŠã ãããžãŠã ãã€ãª
ãžãŠã ãªã©ã®ååç©ã®ãããªååŠå¢æå€ãããã²
ã³åé«ãªã©ã®éå å€ãŸãã¯ãããã®çµåãã®äœ¿çš
ã«ãã€ãŠååŠå¢æãããŠãããã詳ããã¯âThe
Theory of tho Photographic ProcessâïŒçã
T.H.Jamesèã®ç¬¬ïŒç« 149é ã169é ã«èšèŒãã
ãŠããã æ¬çºæã«ãããŠç¹ã«å¥œãŸããå®æœæ æ§ã¯ææ©é
å¡©é žåå€ã䜵åããããã®ã§ããããæå ããã
ãã²ã³åéã®ååšäžã§æž©åºŠ80â以äžã奜ãŸããã¯
100â以äžã«å ç±ããããšãã«ãäžèšç»å圢æç©
質ãŸãã¯å¿ èŠã«å¿ããŠç»å圢æç©è³ªãšå ±åããã
éå å€ãšåå¿ããŠéåã圢æãããã®ã§ãããæ
æ©éå¡©é žåå€ã䜵åãããããšã«ãããããé«æ¿
床ã«çºè²ããæå ææãåŸãããšãã§ããã ãã®å Žåã«çšããããããã²ã³åéã¯ãããã²
ã³åéåç¬ã§äœ¿çšããå Žåã®çŽæ²åéçµæ¶ãå«ã
ãšãç¹åŸŽãæããããšãå¿ ãããå¿ èŠã§ãªãåœæ¥
çã«ãããŠç¥ãããããã²ã³åéå šãŠã䜿çšãã
ããšãã§ããã ãã®ãããªææ©éå¡©é žåå€ã®äŸãšããŠã¯ä»¥äžã®
ãããªãã®ãããã ã«ã«ããã·ã«åºãæããææ©ååç©ã®éå¡©ã§ã
ãããã®äžã«ã¯ä»£è¡šçãªãã®ãšããŠèèªæã«ã«ã
ã³é žã®éå¡©ãè³éŠæã«ã«ãã³é žã®éå¡©ãªã©ãã
ãã èèªæã«ã«ãã³é žã®äŸãšããŠã¯ããã³é žã®é
å¡©ãã¹ãã¢ãªã³é žã®éå¡©ããªã¬ã€ã³é žã®éå¡©ãã©
ãŠãªã³é žã®éå¡©ãã«ããªã³é žã®éå¡©ãããªã¹ãã³
é žã®éå¡©ããã«ããã³é žã®éå¡©ããã¬ã€ã³é žã®é
å¡©ãããã«é žã®éå¡©ãé ç³é žã®éå¡©ãããã€ã³é ž
ã®éå¡©ããªããŒã«é žã®éå¡©ããªã¬ã€ã³é žã®éå¡©ã
ã¢ãžãã³é žã®éå¡©ãã»ãã·ã³é žã®éå¡©ããã¯ãé ž
ã®éå¡©ãé ¢é žã®éå¡©ãé ªé žã®éå¡©ãæšè³é žã®éå¡©
ãªã©ãããããŸããããã®éå¡©ã®ããã²ã³ååã
ããããã·ã«åºã§çœ®æããããã®ãæå¹ã§ããã è³éŠæã«ã«ãã³é žããã³ãã®ä»ã®ã«ã«ããã·ã«
åºå«æååç©ã®éå¡©ãšããŠã¯å®æ¯éŠé žã®éå¡©ã
ïŒïŒïŒâãžããããã·å®æ¯éŠé žã®éå¡©ãïœâã¡ã
ã«å®æ¯éŠé žã®éå¡©ãïœâã¡ãã«å®æ¯éŠé žã®éå¡©ã
ïœâã¡ãã«å®æ¯éŠé žã®éå¡©ãïŒïŒïŒâãžã¯ãã«å®
æ¯éŠé žã®éå¡©ãã¢ã»ãã¢ããå®æ¯éŠé žã®éå¡©ãïœ
âããšãã«å®æ¯éŠé žã®éå¡©ãªã©ã®çœ®æå®æ¯éŠé žã®
éå¡©ã没é£åé žã®éå¡©ãã¿ã³ãã³é žã®éå¡©ããã¿
ã«é žã®éå¡©ããã¬ãã¿ã«é žã®éå¡©ããµãªãã«é žã®
éå¡©ãããšãã«é ¢é žã®éå¡©ãããã¡ãªããé žã®é
å¡©ãç±³åœç¹èš±ç¬¬3785830å·æ现æžèšèŒã®ïŒâã«ã«
ããã·ã¡ãã«âïŒâã¡ãã«âïŒâãã¢ãŸãªã³âïŒ
âããªã³ãªã©ã®éå¡©ãç±³åœç¹èš±ç¬¬3330663å·æ现
æžã«èšèŒãããŠããããªãšãŒãã«åºãæããèèª
æã«ã«ãã³é žã®éå¡©ãªã©ãããã ãã®ä»ã«ã¡ã«ã«ããåºãŸãã¯ããªã³åºãæãã
ååç©ããã³ãã®èªå°äœã®éå¡©ãããã äŸãã°ïŒâã¡ã«ã«ããâïŒâããšãã«âïŒïŒ
ïŒïŒïŒâããªã¢ãŸãŒã«ã®éå¡©ãïŒâã¡ã«ã«ããã
ã³ãŸã€ãããŸãŒã«ã®éå¡©ãïŒâã¡ã«ã«ããâïŒâ
ã¢ãããã¢ãžã¢ãŸãŒã«ã®éå¡©ãïŒâã¡ã«ã«ããã
ã³ããã¢ãŸãŒã«ã®éå¡©ãïŒâïŒïœâãšãã«ã°ãªã³
ãŒã«ã¢ããïŒãã³ãºãã¢ãŸãŒã«ã®éå¡©ãïœâã¢ã«
ãã«ïŒççŽ æ°12ã22ã®ã¢ã«ãã«åºïŒããªã°ãªã³ãŒ
ã«é ¢é žãªã©ã®ç¹éæ48â28221å·ã«èšèŒã®ããªã°
ãªã³ãŒã«é žã®éå¡©ããžããªé ¢é žã®éå¡©ã®ãããªãž
ããªã«ã«ãã³é žã®éå¡©ãããªã¢ããã®éå¡©ãïŒâ
ã«ã«ããã·âïŒâã¡ãã«âïŒâããšãã«âïŒâã
ãªããªãžã³ã®éå¡©ãã¡ã«ã«ããããªã¢ãžã³ã®é
å¡©ãïŒâã¡ã«ã«ãããã³ãŸãªããµãŸãŒã«ã®éå¡©ã
ã¡ã«ã«ãããªããµãžã¢ãŸãŒã«ã®éå¡©ãç±³åœç¹èš±
4123274å·æ现æžèšèŒã®éå¡©ãããšãã°ïŒïŒïŒïŒ
ïŒâã¡ã«ã«ããããªã¢ãŸãŒã«èªå°äœã§ããïŒâã¢
ããâïŒâãã³ãžã«ããªïŒïŒïŒïŒïŒâããªã¢ãŸãŒ
ã«ã®éå¡©ãç±³åœç¹èš±3301678å·æ现æžèšèŒã®ïŒâ
ïŒïŒã«ã«ããã·ãšãã«ïŒâïŒâã¡ãã«âïŒâãã¢
ãŸãªã³âïŒããªã³ã®éå¡©ãªã©ã®ããªã³ååç©ã®é
å¡©ã§ããã ãã®ä»ã«ãã€ããåºãæããååç©ã®éå¡©ãã
ããäŸãã°ç¹å ¬æ44â30270ãå45â18416å ¬å ±èš
èŒã®ãã³ãŸããªã¢ãŸãŒã«ããã³ãã®èªå°äœã®é
å¡©ãäŸãã°ãã³ãŸããªã¢ãŸãŒã«ã®éå¡©ãã¡ãã«ã
ã³ãŸããªã¢ãŸãŒã«ã®éå¡©ãªã©ã®ã¢ã«ãã«çœ®æãã³
ãŸããªã¢ãŸãŒã«ã®éå¡©ãïŒâã¯ãããã³ãŸããªã¢
ãŸãŒã«ã®éå¡©ã®ãããªããã²ã³çœ®æãã³ãŸããªã¢
ãŸãŒã«ã®éå¡©ãããã«ã«ã«ãã€ãããã³ãŸããªã¢
ãŸãŒã«ã®éå¡©ã®ãããªã«ã«ãã€ãããã³ãŸããªã¢
ãŸãŒã«ã®éå¡©ãç±³åœç¹èš±4220709å·æ现æžèšèŒã®
ïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«ãïŒââããã©ãŸãŒ
ã«ã®éå¡©ãã«ã«ããŸãŒã«ã®éå¡©ããµãã«ãªã³ã®é
å¡©ãã€ãããŸãŒã«ãã€ãããŸãŒã«èªå°äœã®éå¡©ãª
ã©ãããã ãŸããªãµãŒããã€ã¹ã¯ããŒãžã€ãŒVol170ã
1978幎ïŒæã®No.17029å·ã«èšèŒãããŠããéå¡©ã
ã¹ãã¢ãªã³é žé ãªã©ã®ææ©éå±å¡©ãæ¬çºæã«äœ¿çš
ã§ããææ©éå±å¡©é žåå€ã§ããã ææ©éå¡©é žåå€ã¯ãïŒçš®ä»¥äžäœ¿çšããããšãã§
ããã æ¬çºæã®å ç±äžã§ã®ç±çŸåéçšã¯ååæããã«
ãªã€ãŠããªãã以äžã®ããã«èããããšãã§ã
ãã æå ææã«å ãç §å°ãããšæå æ§ãæã€ããã²
ã³åéã«æœåã圢æããããããã«ã€ããŠã¯ã
T.H.Jamesèã®âThe Theory of the
Photographic Processâ3rd Editionã®105é ã
148é ã«èšèŒãããŠããã æå ææãå ç±ããããšã«ãããéå å€ãæ¬çº
æã®å Žåã¯è²çŽ äŸäžæ§ç©è³ªããæœåæ žã觊åªãšã
ãŠãããã²ã³åéãŸãã¯ããã²ã³éãšææ©éå¡©é ž
åå€ãéå ããéãçæããããèªèº«ã¯é žåãã
ãããã®é žåãããè²çŽ äŸäžæ§ç©è³ªã¯éè£ããŠè²
çŽ ãæŸåºãããã ãããã®ããã²ã³åéãææ©éå¡©é žåå€ã®äœã
æ¹ãäž¡æ¹ã®æ··åã®ãæ¹ãªã©ã«ã€ããŠã¯ããªãµãŒã
ãã€ã¹ã¯ããŒãžã€17029å·ãç¹éæ50â32928ãç¹
éæ51â42529ãç±³åœç¹èš±3700458ãç¹éæ49â
13244å·ãç¹éæ50â17216å·ã«èšèŒãããŠããã æ¬çºæã«ãããŠæå æ§ããã²ã³åéããã³ææ©
éå¡©é žåå€ã®å¡åžéã¯éã«æç®ããŠåèšã§50mgã
10ïœïŒm2ãé©åœã§ããã æ¬çºæã®æå æ§ããã²ã³åéãææ©éå¡©é žåå€
ã¯äžèšã®ãã€ã³ããŒäžã§èª¿æŽãããããŸãè²çŽ äŸ
äžæ§ç©è³ªãäžèšã®ãã€ã³ããŒäžã«åæ£ãããã æ¬çºæã«çšãããããã€ã³ããŒã¯ãåç¬ã§ãã
ããã¯çµã¿åããŠå«æããããšãã§ããããã®ã
ã€ã³ããŒã«ã¯ã芪氎æ§ã®ãã®ãçšããããšãã§ã
ãã芪氎æ§ãã€ã³ããŒãšããŠã¯ãéæãåéæã®
芪氎æ§ã³ãã€ãã代衚çã§ãããäŸãã°ãŒã©ã
ã³ããŒã©ãã³èªå°äœãã»ã«ããŒã¹èªå°äœçã®ã¿ã³
ãã¯è³ªãããã³ãã³ãã¢ã©ãã¢ãŽã çã®å€ç³é¡ã®
ãããªå€©ç¶ç©è³ªãšãããªããã«ãããªãã³ãã¢ã¯
ãªã«ã¢ããéåäœçã®æ°Žæº¶æ§ããªããã«ååç©ã®
ãããªåæéåç©è³ªãå«ããä»ã®åæéåååç©
ã«ã¯ãã©ããã¯ã¹ã®åœ¢ã§ãç¹ã«åçææã®å¯žåºŠå®
å®æ§ãå¢å ãããåæ£ç¶ããã«ååç©ãããã æ¬çºæã«çšããããããã²ã³åéã¯ãã¡ãã³è²
çŽ é¡ãã®ä»ã«ãã€ãŠåå å¢æãããŠããããçšã
ãããè²çŽ ã«ã¯ãã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ãã³è²
çŽ ãè€åã·ã¢ãã³è²çŽ ãè€åã¡ãã·ã¢ãã³è²çŽ ã
ããããŒã©ãŒã·ã¢ãã³è²çŽ ãããã·ã¢ãã³è²çŽ ã
ã¹ããªã«è²çŽ ããã³ãããªããœããŒã«è²çŽ ãå å«
ããããç¹ã«æçšãªè²çŽ ã¯ãã·ã¢ãã³è²çŽ ãã¡ã
ã·ã¢ãã³è²çŽ ãããã³è€åã¡ãã·ã¢ãã³è²çŽ ã«å±
ããè²çŽ ã§ããããããã®è²çŽ é¡ã«ã¯ãå¡©åºæ§ç°
ç¯ç°æ žãšããŠã·ã¢ãã³è²çŽ é¡ã«éåžžå©çšãããæ ž
ã®ãããããé©çšã§ã©ãããããªãã¡ããããªã³
æ žããªããµãŸãªã³æ žããã¢ãŸãªã³æ žããããŒã«
æ žããªããµãŸãŒã«æ žããã¢ãŸãŒã«æ žãã»ã¬ããŸãŒ
ã«æ žãã€ãããŸãŒã«æ žãããã©ãŸãŒã«æ žãããªãž
ã³æ žãªã©ïŒãããã®æ žã«èç°åŒçåæ°ŽçŽ ç°ãèå
ããæ žïŒåã³ãããã®æ žã«è³éŠæçåæ°ŽçŽ ç°ãè
åããæ žãå³ã¡ãã€ã³ãã¬ãã³æ žããã³ãŸã€ã³ã
ã¬ãã³æ žãã€ã³ããŒã«æ žããã³ãºãªããµããŒã«
æ žãããããªããµãŸãŒã«æ žããã³ãºãã¢ãŸãŒã«
æ žãããããã¢ãŸãŒã«æ žããã³ãŸã»ã¬ããŸãŒã«
æ žããã³ãºã€ãããŸãŒã«æ žããããªã³æ žãªã©ãé©
çšã§ããããããã®æ žã¯ççŽ ååäžã«çœ®æãããŠ
ããŠãããã ã¡ãã·ã¢ãã³è²çŽ ãŸãã¯è€åã¡ãã·ã¢ãã³è²çŽ
ã«ã¯ã±ãã¡ãã¬ã³æ§é ãæããæ žãšããŠããã©ãŸ
ãªã³âïŒâãªã³æ žãããªããã³ãã€ã³æ žãïŒâã
ãªãªããµãŸãªãžã³âïŒïŒïŒâãžãªã³æ žããã¢ãŸãª
ãžã³âïŒïŒïŒâãžãªã³æ žãããŒããã³æ žãããªã
ã«ãããŒã«é žæ žãªã©ã®ïŒãïŒå¡ç°ç¯ç°æ žãé©çšã
ãããšãã§ããã æçšãªå¢æè²çŽ ãšããŠã¯äŸãã°ããã€ãç¹èš±
929050å·ãç±³åœç¹èš±2231658å·ãå2493748å·ãå
2503776å·ãå2519001å·ãå2912329å·ãå
3656959å·ãå3672897å·ãå3694217å·ãå
4025349å·ãå4046572å·ãè±åœç¹èš±1242588å·ã
ç¹å ¬æ44â14030å·ãå52â24844å·ã«èšèŒããã
ãã®ãæããããšãåºæ¥ãã ãããã®å¢æè²çŽ ã¯åç¬ã«çšããŠãããããã
ããã®çµåããçšããŠããããå¢æè²çŽ ã®çµåã
ã¯ç¹ã«ã匷è²å¢æã®ç®çã§ãã°ãã°çšããããã
ãã®ä»£è¡šäŸã¯ç±³åœç¹èš±2688545å·ãå2977229å·ã
å3397060å·ãå3522052å·ãå3527641å·ãå
3617293å·ãå3628964å·ãå3666480å·ãå
3672898å·ãå3679428å·ãå3703377å·ãå
3769301å·ãå3814609å·ãå3837862å·ãå
4026707å·ãè±åœç¹èš±1344281å·ãå1507803å·ã
ç¹å ¬æ43â4936å·ãå53â12375å·ãç¹éæ52â
110618å·ãå52â109925å·ã«èšèŒãããŠããã å¢æè²çŽ ãšãšãã«ãããèªèº«åå å¢æäœçšãã
ããªãè²çŽ ãããã¯å¯èŠå ãå®è³ªçã«åžåããªã
ç©è³ªã§ãã€ãŠã匷è²å¢æã瀺ãç©è³ªãä¹³å€äžã«å«
ãã§ããããäŸãã°ãå«çªçŽ ç°ç¯ç°åºã§çœ®æãã
ãã¢ããã¹ãã«ååç©ïŒããšãã°ç±³åœç¹èš±
2933390å·ãå3635721å·ã«èšèŒã®ãã®ïŒãè³éŠæ
ææ©é žãã«ã ã¢ã«ãããçž®åç©ïŒããšãã°ç±³åœç¹
èš±3743510å·ã«èšèŒã®ãã®ïŒãã«ãããŠã å¡©ãã¢ã¶
ã€ã³ãã³ååç©ãªã©ãå«ãã§ããããç±³åœç¹èš±
3615613å·ãå3615641å·ãå3617295å·ãå
3635721å·ã«èšèŒã®çµåãã¯ç¹ã«æçšã§ããã æ¬çºæã§çšããããæ¯æäœã¯ãåŠç枩床ã«èã
ãããšã®ã§ãããã®ã§ãããäžè¬çãªæ¯æäœãšã
ãŠã¯ãã¬ã©ã¹ïŒçŽïŒéå±ããã³ãã®é¡äŒŒäœãçšã
ãããã°ããã§ãªããã¢ã»ãã«ã»ã«ããŒãºãã€ã«
ã ïŒã»ã«ããŒãºãšã¹ãã«ãã€ã«ã ïŒããªããã«ã¢
ã»ã¿ãŒã«ãã€ã«ã ïŒããªã¹ãã¬ã³ãã€ã«ã ïŒããª
ã«ãŒãããŒããã€ã«ã ïŒããªãšãã¬ã³ãã¬ãã¿ã¬
ãŒããã€ã«ã åã³ãããã«é¢é£ãããã€ã«ã ãŸã
ã¯æš¹èææãå«ãŸãããç±³åœç¹èš±3634089å·ïŒå
第3725070å·èšèŒã®ããªãšã¹ãã«ã¯å¥œãŸããçšã
ãããã æ¬çºæã«æŒããŠã¯çš®ã ã®è²çŽ æŸåºå©å€ãçšãã
ããšãã§ãããè²çŽ æŸåºå©å€ãšã¯æå æ§ããã²ã³
åéããã³ïŒãŸãã¯ææ©éå¡©é žåå€ãšè²çŽ äŸäžæ§
ç©è³ªãšã®é žåéå åå¿ãä¿é²ããåŒãç¶ããŠèµ·ã
ãè²çŽ ã®æŸåºåå¿ã§é žåãããè²çŽ äŸäžæ§ç©è³ªã«
æ±æ žçã«äœçšããŠè²çŽ æŸåºãä¿é²ããããšã®ã§ã
ããã®ã§ãå¡©åºãŸãã¯å¡©åºåé§äœãçšããããã
æ¬çºæã«ãããŠã¯åå¿ã®ä¿é²ã®ãããããã®è²çŽ
æŸåºå©å€ãçšããããšã¯ç¹ã«æå©ã§ããã 奜ãŸããå¡©åºã®äŸãšããŠã¯ãã¢ãã³é¡ãããã
ããšãã§ããããªã¢ã«ãã«ã¢ãã³é¡ãããããã·
ã«ã¢ãã³é¡ãèèªæããªã¢ãã³é¡ãâã¢ã«ãã«
眮æè³éŠæã¢ãã³é¡ãâããããã·ã«ã¢ã«ãã«
眮æè³éŠæã¢ãã³é¡ããã³ãïœâïŒãžã¢ã«ãã«ã¢
ããïŒããšãã«ãã¡ã¿ã³é¡ããããããšãã§ã
ãããŸãç±³åœç¹èš±ç¬¬2410644å·ã«ã¯ããã¿ã€ã³ãš
ãŠåããã©ã¡ãã«ã¢ã³ã¢ããŠã ããžã¢ãããã¿ã³
ãžãããã¯ãã©ã€ãããç±³åœç¹èš±ç¬¬3506444å·ã«
ã¯ãŠã¬ã¢ãïŒâã¢ããã«ããã³é žã®ãããªã¢ãã
é žãå«ãææ©ååç©ãèšèŒããæçšã§ãããå¡©åº
åé§äœã¯ãå ç±ã«ããå¡©åºæ§æåãæŸåºãããã®
ã§ãããå žåçãªå¡©åºåé§äœã®äŸã¯è±åœç¹èš±ç¬¬
998949å·ã«èšèŒãããŠããã奜ãŸããå¡©åºåé§äœ
ã¯ãã«ã«ãã³é žãšææ©å¡©åºã®å¡©ã§ããæçšãªã«ã«
ãã³é žãšããŠã¯ããªã¯ããé ¢é žãããªã¯ããé ¢
é žãæçšãªå¡©åºãšããŠã¯ã°ã¢ããžã³ããããªãž
ã³ãã¢ã«ããªã³ãïœâãã«ã€ãžã³ãïŒâãã³ãªã³
ãªã©ããããç±³åœç¹èš±ç¬¬3220846å·èšèŒã®ã°ã¢ã
ãžã³ããªã¯ããé ¢é žã¯ç¹ã«æçšã§ããããŸãç¹é
æ50â22625å·å ¬å ±ã«èšèŒãããŠããã¢ã«ãã³ã¢
ããé¡ã¯é«æž©ã§å解ãå¡©åºãçæãããã®ã§å¥œãŸ
ããçšããããã ãããã®è²çŽ æŸåºå©å€ã¯åºãç¯å²ã§çšããããš
ãã§ãããæçšãªç¯å²ã¯æå ææã®å¡åžä¹Ÿèãé
éã«æç®ãããã®ã®50ééããŒã»ã³ã以äžãæŽã«
奜ãŸããã¯ã0.01ééããŒã»ã³ããã40ééããŒ
ã»ã³ãã®ç¯å²ã§ããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã§ã¯äžèšäžè¬åŒ
ã§ç€ºãããååç©ãçšãããšçŸåãä¿é²ãããè²
çŽ ã®æŸåºãä¿é²ããæå©ã§ããã ãäžè¬åŒã äžåŒã«ãããŠA1ïŒA2ïŒA3ïŒA4ã¯åäžããŸãã¯
ç°ãªã€ãŠããŠãè¯ããããããæ°ŽçŽ ååãã¢ã«ã
ã«åºã眮æã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºãã¢ã©
ã«ãã«åºãã¢ãªãŒã«åºã眮æã¢ãªãŒã«åºããã³è€
çŽ ç°æ®åºã®äžããéžã°ãã眮æåºãè¡šããããŸã
A1ãšA2ãããã¯A3ãšA4ãé£çµããŠç°ã圢æããŠ
ããŠãããã å ·äœäŸãšããŠã¯ãH2NSO2NH2ïŒH2NSO2N
ïŒCH3ïŒ2ïŒH2NSO2NïŒC2H5ïŒ2ïŒH2NSO2NHCH3ïŒ
H2NSO2NïŒC2H4OHïŒ2ïŒCH3NHSO2NHCH3ïŒ
ãåŒãçãæããããã
äžèšååç©ã¯åºãç¯å²ã§çšããããšãã§ããã
æçšãªç¯å²ã¯ãæå
ææã®å¡åžä¹Ÿèãééã«æ
ç®ãããã®ã®20ééããŒã»ã³ã以äžãæŽã«å¥œãŸã
ãã¯0.1ãã15ééããŒã»ã³ãã§ããã æ¬çºæã§ã¯ãæ°ŽæŸåºååç©ãçšãããšè²çŽ æŸåº
åå¿ãä¿é²ããæå©ã§ããã æ°ŽæŸåºååç©ãšã¯ãç±çŸåäžã«å解ããŠæ°ŽãæŸ
åºããååç©ã®ããšã§ããããããã®ååç©ã¯ç¹
ã«ç¹ç¶ã®è»¢åæºæã«ãããŠç¥ãããæ¥æ¬ç¹èš±æ50
â88386å·å ¬éå ¬å ±èšèŒã®NH4FeïŒSO4ïŒ2ã»12H2O
ãªã©ãæçšã§ããã ãŸãæ¬çºæã«æŒããŠã¯çŸåã®æŽ»æ§åãšåæã«ç»
åã®å®å®åãã¯ããååç©ãçšããããšãã§ã
ãããã®äžã§ç±³åœç¹èš±ç¬¬3301678å·èšèŒã®ïŒâã
ãããã·ãšãã«ã€ãœããŠãããŠã ã»ããªã¯ããã¢
ã»ããŒãã«ä»£è¡šãããã€ãœããŠãããŠã é¡ãç±³åœ
ç¹èš±ç¬¬3669670å·èšèŒã®ïŒïŒïŒâïŒïŒïŒïŒâãžãª
ããµãªã¯ã¿ã³ïŒãã¹ïŒã€ãœããŠãããŠã ã»ããªã
ããã¢ã»ããŒãïŒãªã©ã®ãã¹ã€ãœããŠãããŠã
é¡ã西ç¬ç¹èš±ç¬¬2162714å·å ¬éèšèŒã®ããªãŒã«å
åç©é¡ãç±³åœç¹èš±4012260å·èšèŒã®ïŒâã¢ããâ
ïŒâãã¢ãŸãªãŠã ã»ããªã¯ããã¢ã»ããŒããïŒâ
ã¢ããâïŒâããã¢ãšãã«âïŒâãã¢ãŸãªãŠã ã»
ããªã¯ããã¢ã»ããŒããªã©ã®ãã¢ãŸãªãŠã ååç©
é¡ãç±³åœç¹èš±ç¬¬4060420å·èšèŒã®ãã¹ïŒïŒâã¢ã
ãâïŒâãã¢ãŸãªãŠã ïŒã¡ãã¬ã³ãã¹ïŒã¹ã«ãã
ã«ã¢ã»ããŒãïŒãïŒâã¢ããâïŒâãã¢ãŸãªãŠã
ããšãã«ã¹ã«ããã«ã¢ã»ããŒããªã©ã®ããã«é žæ§
éšãšããŠÎ±âã¹ã«ããã«ã¢ã»ããŒããæããåå
ç©é¡ãç±³åœç¹èš±ç¬¬4088496å·èšèŒã®ãé žæ§éšãšã
ãŠïŒâã«ã«ããã·ã«ã«ããã·ã¢ããããã€ååç©
é¡ãªã©ã奜ãŸããçšããããã æ¬çºæã«æŒããŠã¯ãç±æº¶å€ãå«æãããããšã
ã§ãããããã§âç±æº¶å€âãšã¯ãåšå²æž©åºŠã«ãã
ãŠåºäœã§ãããã䜿çšãããç±åŠç枩床ãŸãã¯ã
ã以äžã®æž©åºŠã«ãããŠä»ã®æåãšäžç·ã«ãªã€ãŠæ··
åèç¹ã瀺ãéå æ°Žå解æ§ã®ææ©ææã§ãããç±
溶å€ã«ã¯ãçŸåè¬ã®æº¶åªãšãªãããååç©ãé«èª
é»çã®ç©è³ªã§éå¡©ã®ç©ççŸåãä¿é²ããããšãç¥
ãããŠããååç©ãªã©ãæçšã§ãããæçšãªç±æº¶
å€ãšããŠã¯ãç±³åœç¹èš±ç¬¬3347675å·èšèŒã®ããªã°
ãªã³ãŒã«é¡ããšãã°å¹³åååé1500ã20000ã®ã
ãªãšãã¬ã³ã°ãªã³ãŒã«ãããªãšãã¬ã³ãªããµã€ã
ã®ãªã¬ã€ã³é žãšã¹ãã«ãªã©ã®èªå°äœãã¿ã€ããã
ã¢ãã¹ãã¢ãªã³ãâSO2âïŒâCOâåºãæããé«
èªé»çã®ååç©ãããšãã°ãã¢ã»ãã¢ããããµã¯
ã·ã³ã€ããããšãã«ã«ã«ãã¡ãŒãããŠã¬ã¢ãã¡ã
ã«ã¹ã«ãã³ã¢ããããšãã¬ã³ã«ãŒãããŒããç±³åœ
ç¹èš±ç¬¬3667959å·èšèŒã®æ¥µæ§ç©è³ªãïŒâãããã
ã·ãã¿ã³é žã®ã©ã¯ãã³ãã¡ãã«ã¹ã«ãã€ãã«ã¡ã¿
ã³ãããã©ãããããªããšã³âïŒïŒïŒâãžãªããµ
ã€ãããªãµãŒããã€ã¹ã¯ããŒãžã€ãŒèª1976幎12æ
å·26ã28ããŒãžèšèŒã®ïŒïŒ10âãã«ã³ãžãªãŒã«ã
ã¢ãã¹é žã¡ãã«ãã¹ããªã³é žãããšãã«ãªã©ã奜
ãŸããçšããããã æ¬çºæã®å Žåã¯ãè²çŽ äŸäžæ§ç©è³ªãçè²ããŠã
ãæŽã«ãã€ã©ãžãšãŒã·ãšã³é²æ¢ããã¬ãŒã·ãšã³é²
æ¢ç©è³ªãææãæå ææäžã«å«æãããããšã¯ã
ãçšå¿ èŠã§ã¯ãªããæŽã«é®®é床ãè¯åããããã
ã«ç¹å ¬æ48â3692å·å ¬å ±ãç±³åœç¹èš±ç¬¬3253921å·ã
å2527583å·ãå2956879å·ãªã©ã®åæ现æžã«èšèŒ
ãããŠããããã€ã«ã¿ãŒææãåžåæ§ç©è³ªãå«æ
ãããããšãã§ããããŸã奜ãŸããã¯ãããã®æ
æãšããŠã¯ç±è±è²æ§ã®ãã®ã奜ãŸãããäŸãã°ç±³
åœç¹èš±ç¬¬3769019å·ãå第3745009å·ãå第
3615432å·ã«èšèŒãããŠãããããªææã奜ãŸã
ãã æ¬çºæã«çšããããæå ææã¯ãå¿ èŠã«å¿ããŠ
ç±çŸåæå ææãšããŠç¥ãããŠããå皮添å å€ã
æå 局以äžã®å±€ããšãã°éé»é²æ¢å±€ãé»å°å±€ãä¿
è·å±€ãäžéå±€ãAHå±€ãã¯ããå±€ãªã©ãå«æãã
ããšãã§ããã æ¬çºæã®æå ææã®åçä¹³å€å±€ãŸãã¯ä»ã®èŠªæ°Ž
æ§ã³ãã€ãå±€ã«ã¯å¡åžå©å€ã垯é»é²æ¢ãã¹ããªæ§
æ¹è¯ãä¹³ååæ£ãæ¥çé²æ¢ããã³åçç¹æ§æ¹è¯
ïŒããšãã°çŸåä¿é²ã硬調åãå¢æïŒãªã©çš®ã ã®
ç®çã§çš®ã ã®çé¢æŽ»æ§å€ãå«ãã§ãããã ããšãã°ãµããã³ïŒã¹ããã€ãç³»ïŒãã¢ã«ãã¬
ã³ãªããµã€ãèªå°äœïŒäŸãã°ããªãšãã¬ã³ã°ãªã³
ãŒã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ïŒããªãããã¬ã³
ã°ãªã³ãŒã«çž®åç©ãããªãšãã¬ã³ã°ãªã³ãŒã«ã¢ã«
ãã«ãšãŒãã«é¡ãŸãã¯ããªãšãã¬ã³ã°ãªã³ãŒã«ã¢
ã«ãã«ã¢ãªãŒã«ãšãŒãã«é¡ãããªãšãã¬ã³ã°ãªã³
ãŒã«ãšã¹ãã«é¡ãããªãšãã¬ã³ã°ãªã³ãŒã«ãœã«ã
ã¿ã³ãšã¹ãã«é¡ãããªã¢ã«ãã¬ã³ã°ãªã³ãŒã«ã¢ã«
ãã«ã¢ãã³ãŸãã¯ã¢ããé¡ãã·ãªã³ãŒã³ã®ããªãš
ãã¬ã³ãªããµã€ãä»å ç©é¡ïŒãã°ãªã·ããŒã«èªå°
äœïŒããšãã°ã¢ã«ã±ãã«ã³ãã¯é žããªã°ãªã»ãª
ããã¢ã«ãã«ããšããŒã«ããªã°ãªã»ãªãïŒãå€äŸ¡
ã¢ã«ã³ãŒã«ã®èèªé žãšã¹ãã«é¡ãç³ã®ã¢ã«ãã«ãš
ã¹ãã«é¡ãªã©ã®éã€ãªã³æ§çé¢æŽ»æ§å€ïŒã¢ã«ãã«
ã«ã«ãã³é žå¡©ãã¢ã«ãã«ã¹ã«ããªã³é žå¡©ãã¢ã«ã
ã«ãã³ãŒã³ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ããã¿ã¬ã³
ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ç¡«é žãšã¹ãã«é¡ãã¢ã«
ãã«ãªã³é žãšã¹ãã«é¡ãâã¢ã·ã«ââã¢ã«ã
ã«ã¿ãŠãªã³é¡ãã¹ã«ãã³ãã¯é žãšã¹ãã«é¡ãã¹ã«
ãã¢ã«ãã«ããªãªãã·ãšãã¬ã³ã¢ã«ãã«ããšãã«
ãšãŒãã«é¡ãããªãªãã·ãšãã¬ã³ã¢ã«ãã«ãªã³é ž
ãšã¹ãã«é¡ãªã©ã®ãããªãã«ã«ããã·åºãã¹ã«ã
åºããã¹ãåºãç¡«é žãšã¹ãã«åºãçé žãšã¹ãã«åº
çã®é žæ§åºãå«ãã¢ããªã³çé¢æŽ»æ§å€ïŒã¢ããé ž
é¡ãã¢ããã¢ã«ãã«ã¹ã«ãã³é žé¡ãã¢ããã¢ã«ã
ã«ç¡«é žãŸãã¯çé žãšã¹ãã«é¡ãã¢ã«ãã«ãã¿ã€ã³
é¡ãã¢ãã³ãªãã·ãé¡ãªã©ã®äž¡æ§çé¢æŽ»æ§å€ïŒã¢
ã«ãã«ã¢ãã³å¡©é¡ãèèªæãããã¯è³éŠæ第ïŒçŽ
ã¢ã³ã¢ããŠã å¡©é¡ãããªãžããŠã ãã€ãããŸãªãŠ
ã ãªã©ã®è€çŽ ç°ç¬¬ïŒçŽã¢ã³ã¢ããŠã å¡©é¡ãããã³
èèªæãŸãã¯è€çŽ ç°ãå«ããã¹ãããŠã ãŸãã¯ã¹
ã«ãããŠã å¡©é¡ãªã©ã®ã«ããªã³çé¢æŽ»æ§å€ãçšã
ãããšãã§ããã äžèšã®çé¢æŽ»æ§å€ã®äžã§ãååå ã«ãšãã¬ã³ãª
ããµã€ãã®ç¹°ãè¿ãåäœãæããããªãšãã¬ã³ã°
ãªã³ãŒã«åéã€ãªã³çé¢æŽ»æ§å€ãæå ææäžã«å«
ãŸããããšã¯å¥œãŸãããç¹ã«å¥œãŸããã¯ãšãã¬ã³
ãªããµã€ãã®ç¹°ãè¿ãåäœãïŒä»¥äžã§ãããã®ã
æãŸããã äžèšã®æ¡ä»¶ãæºããéã€ãªã³æ§çé¢æŽ»æ§å€ã¯ã
åœè©²åé以å€ã«æŒãŠãåºç¯ã«äœ¿çšããããã®æ§
é ã»æ§è³ªã»åææ³ã«ã€ããŠã¯å ¬ç¥ã§ããã代衚ç
ãªå ¬ç¥æç®ã«ã¯Surfactant Science
Seriesvolume1.Nonionic SurfactantsïŒEdited
by Martin J.SchickïŒMarcel Dekker
Inc.1967ïŒãSurface Active Ethylene Oxide
AdductsïŒSchoufeldt.NèPergamon Press1969ïŒ
ãªã©ãããããããã®æç®ã«èšèŒã®éã€ãªã³æ§ç
é¢æŽ»æ§å€ã§äžèšã®æ¡ä»¶ãæºãããã®ã§æ¬çºæã§å¥œ
ãŸããçšããããã ãããã®éã€ãªã³æ§çé¢æŽ»æ§å€ã¯ãåç¬ã§ãã
ãŸãïŒçš®ä»¥äžã®æ··åç©ãšããŠãçšããããã ããªãšãã¬ã³ã°ãªã³ãŒã«åéã€ãªã³çé¢æŽ»æ§å€
ã¯èŠªæ°Žæ§ãã€ã³ããŒã«å¯ŸããŠãçéé以äžã奜ãŸ
ããã¯50ïŒ ä»¥äžã§çšããããã æ¬çºæã®æå ææã«ã¯ãããªãžããŠã å¡©ããã€
éœã€ãªã³æ§ååç©ãå«æããããšãã§ãããããª
ãžããŠã åºããã€éœã€ãªã³æ§ååç©ã®äŸãšããŠã¯
PSA JonrnalïŒSection  36ïŒ1953ïŒïŒ
USP2648604ãUSP3671247ãç¹å ¬æ44â30074ã
ç¹å ¬æ44â9503çã«èšèŒãããŠããã æ¬çºæã®åçæå ææåã³è²çŽ åºå®ææã«ã¯ã
åçä¹³å€å±€ãã®ä»ã®ãã€ã³ããŒå±€ã«ç¡æ©ãŸãã¯æ
æ©ã®ç¡¬èå€ãå«æããŠãããäŸãã°ã¯ãã å¡©ïŒã¯
ãã ããšãŠãã³ãé ¢é žã¯ãã ãªã©ïŒãã¢ã«ããã
é¡ãïŒãã«ã ã¢ã«ããããã°ãªãªããµãŒã«ãã°ã«
ã¿ãŒã«ã¢ã«ããããªã©ïŒãâã¡ãããŒã«ååç©
ïŒãžã¡ãããŒã«å°¿çŽ ãã¡ãããŒã«ãžã¡ãã«ããã³
ãã€ã³ãªã©ïŒããžãªããµã³èªå°äœïŒïŒïŒïŒâãžã
ãããã·ãžãªããµã³ãªã©ïŒã掻æ§ããã«ååç©
ïŒïŒïŒïŒïŒïŒâããªã¢ã¯ãªãã€ã«âãããµããã
âïœâããªã¢ãžã³ãïŒïŒïŒâããã«ã¹ã«ããã«â
ïŒâãããããŒã«ãªã©ïŒã掻æ§ããã²ã³ååç©
ïŒïŒïŒïŒâãžã¯ãã«âïŒâããããã·âïœâããª
ã¢ãžã³ãªã©ïŒãã ã³ããã²ã³é žé¡ïŒã ã³ã¯ãã«é žã
ã ã³ããšããã·ã¯ãã«é žãªã©ïŒããªã©ãåç¬ãŸã
ã¯çµã¿åãããŠçšããããšãã§ããã å皮添å å€ãšããŠã¯âResearch Disclosureâ
Vol170ïŒïŒæ1978幎ã®17029å·ã«èšèŒãããŠãã
æ·»å å€ããšãã°å å¡å€ãé®®é床æ¹è¯çšææãAH
ææãå¢æè²çŽ ããããå€ãè¢å å¢çœå€ãéè²é²
æ¢å€ãªã©ãããã æ¬çºæã«ãããŠã¯ç±çŸåæå å±€ãšåæ§ãä¿è·
å±€ãäžéå±€ãäžå¡å±€ãããã¯å±€ãã®ä»ã®å±€ã«ã€ã
ãŠããããããã®å¡åžæ¶²ã調液ãã浞挬æ³ããšã¢
ãŒãã€ãæ³ãã«ãŒãã³å¡åžæ³ãŸãã¯ç±³åœç¹èš±ç¬¬
3681294å·æ现æžèšèŒã®ããããŒå¡åžæ³ãªã©ã®
çš®ã ã®å¡åžæ³ã§æ¯æäœäžã«é 次å¡åžã也ç¥ããã
ãšã«ããæå ææãäœãããšãã§ããã æŽã«å¿ èŠãªãã°ç±³åœç¹èš±ç¬¬2761791å·æ现æžå
ã³è±åœç¹èš±837095å·æ现æžã«èšèŒãããŠããæ¹æ³
ã«ãã€ãŠïŒå±€ãŸãã¯ãã以äžãåæã«å¡åžããã
ãšãã§ããã æ¬çºæã«ãããŠã¯çš®ã ã®é²å æ段ãçšããããš
ãã§ãããæœåã¯ãå¯èŠå ãå«ã茻å°ç·ã®ç»åç¶
é²å ã«ãã€ãŠåŸããããäžè¬ã«ã¯ãéåžžã®ã«ã©ãŒ
ããªã³ãã«äœ¿ãããå æºäŸãã°ã¿ã³ã°ã¹ãã³ã©ã³
ããæ°Žéç¯ããšãŒãã©ã³ããªã©ã®ããã²ã³ã©ã³
ãããã»ãã³ã©ã³ããã¬ãŒã¶ãŒå æºãããã³
CRTå æºãè¢å 管ãçºå ãã€ãªãŒããªã©ãå æº
ãšããŠäœ¿ãããšãã§ããã åå³ãšããŠã¯ã補å³ãªã©ã®ç·ç»åã¯ãã¡ããã®
ããšãé調ãæããåçç»åã§ãããããŸãã«ã¡
ã©ãçšããŠäººç©åã颚æ¯åãæ®åœ±ããããšãå¯èœ
ã§ãããåå³ããã®çŒä»ã¯ãåå³ãšéããŠå¯ççŒ
ä»ãããŠããåå°çŒä»ãããŠããããŸãåŒäŒžãçŒ
ä»ãããŠãããã ãŸããããªã«ã¡ã©ãªã©ã«ããæ®åœ±ãããç»åã
ãã¬ãå±ããéãããŠããç»åæ å ±ããçŽæ¥
CRTãFOTã«åºãããã®åãå¯çãã¬ã³ãºã«ã
ãç±çŸåææäžã«çµåãããŠãçŒä»ãããšãå¯èœ
ã§ããã ãŸãæè¿å€§å·Ÿãªé²æ©ãèŠãããLEDïŒçºå ãã€
ãªãŒãïŒã¯ãåçš®ã®æ©åšã«ãããŠãé²å æ段ãšã
ãŠãŸãã¯è¡šç€ºæ段ãšããŠçšãããã€ã€ããããã®
LEDã¯ãéå ãæå¹ã«åºããã®ãäœãããšãå°
é£ã§ããããã®å Žåã«ã©ãŒç»åãåçããã«ã¯ã
LEDãšããŠç·å ãèµ€å ãèµ€å€å ãçºããïŒçš®ã
䜿ãããããã®å ã«æå ããææéšåãåã ãã€
ãšããŒããŒã³ã¿ãã·ã¢ã³ã®ææãæŸåºããããã«
èšèšããã°ããã ããªãã¡ç·æå éšåïŒå±€ïŒãã€ãšããŒè²çŽ äŸäž
æ§ç©è³ªãå«ã¿ãèµ€æå éšåïŒå±€ïŒãããŒã³ã¿è²çŽ
äŸäžæ§ç©è³ªããèµ€å€æå éšåïŒå±€ïŒãã·ã¢ã³è²çŽ
äŸäžæ§ç©è³ªãå«ãããã«ããŠããã°ããããã以
å€ã®å¿ èŠã«å¿ããŠç°ã€ãçµåããå¯èœã§ããã äžèšã®åå³ãçŽæ¥ã«å¯çãŸãã¯æ圱ããæ¹æ³ä»¥
å€ã«ãå æºã«ããç §å°ãããåå³ãå é»ç®¡ã
CCDãªã©ã®åå çŽ åã«ãããèªã¿ãšãã³ã³ããŠ
ãŒã¿ãŒãªã©ã®ã¡ã¢ãªãŒã«å ¥ãããã®æ å ±ãå¿ èŠã«
å¿ããŠå å·¥ããããããç»ååŠçãã»ã©ããã
åŸããã®ç»åæ å ±ãCRTã«åçããããããç»
åç¶å æºãšããŠå©çšããããåŠçãããæ å ±ã«ã
ãšã¥ããŠãçŽæ¥ïŒçš®LEDãçºå ãããŠé²å ãã
æ¹æ³ãããã æ¬çºæã«ãããŠã¯æå ææãžã®é²å ã®åŸãåŸã
ããæœåã¯ãäŸãã°ãçŽ80âãçŽ250âã§çŽ0.5ç§
ããçŽ300ç§ã®ããã«é©åºŠã«äžæãã枩床ã§è©²èŠ
çŽ ãå ç±ããããšã«ããçŸåããããšãã§ããã
äžèšç¯å²ã«å«ãŸãã枩床ã§ããã°ãå ç±æéã®å¢
倧åã¯ççž®ã«ãã€ãŠé«æž©ãäœæž©ã®ãããã§ã䜿çš
å¯èœã§ãããç¹ã«çŽ110âãçŽ160âã®æž©åºŠç¯å²ã
æçšã§ããã 該å ç±æ段ã¯ãåãªãç±æ¿ãã¢ã€ãã³ãç±ããŒ
ã©ãŒãã«ãŒãã³ããã¿ã³ãã¯ã€ããªã©ãå©çšãã
çºç±äœåã¯ãã®é¡äŒŒç©ã§ãã€ãŠããã æ¬çºæã«æŒããŠãç±çŸåã«ããåç»åã圢æã
ããããå ·äœçãªæ¹æ³ã¯ã芪氎æ§ã®å¯åæ§è²çŽ ã
移åãããããšã§ããããã®ããã«ãæ¬çºæã®æ
å ææã¯ãæ¯æäœäžã«å°ããšãããã²ã³åéãå¿
èŠã«å¿ããŠææ©éå¡©é žåå€ãšãã®éå å€ã§ããã
è²çŽ äŸäžæ§ç©è³ªãããã³ãã€ã³ããŒãå«ãæå å±€
ïŒïŒãšãïŒïŒå±€ã§åœ¢æããã芪氎æ§ã§æ¡æ£æ§ã®
è²çŽ ãåããšããããšã®ã§ããè²çŽ åºå®å±€ïŒïŒ
ããæ§æãããã äžè¿°ã®æå å±€ïŒïŒãšè²çŽ åºå®å±€ïŒïŒãšã¯ã
åäžã®æ¯æäœäžã«åœ¢æããŠããããããŸãå¥ã ã®
æ¯æäœäžã«åœ¢æããããšãã§ãããè²çŽ åºå®å±€
ïŒïŒãšãæå å±€ïŒïŒãšã¯ã²ãã¯ããããšãã§
ãããããšãã°ãåæ§é²å åŸåäžå ç±çŸåããã
ã®åŸãè²çŽ åºå®å±€ïŒïŒåã¯æå å±€ãã²ãã¯ãã
ããšãã§ããããŸããæå å±€ïŒïŒãæ¯æäœäžã«
å¡åžããæå ææãšãåºå®å±€ïŒïŒãæ¯æäœäžã«
å¡åžããåºå®ææãšãå¥ã ã«åœ¢æãããå Žåã«
ã¯ãæå ææã«åæ§é²å ããŠåäžå ç±åŸãåºå®æ
æãéãå¯åæ§è²çŽ ãåºå®å±€ïŒïŒã«ç§»ãããšã
ã§ããã ãŸããæå ææïŒïŒã®ã¿ãåæ§é²å ãããã®
åŸè²çŽ åºå®å±€ïŒïŒãéãåãããŠåäžå ç±ãã
æ¹æ³ãããã è²çŽ åºå®å±€ïŒïŒã¯ãè²çŽ åºå®ã®ãããäŸãã°
è²çŽ åªæå€ãå«ãããšãã§ãããåªæå€ãšããŠã¯
çš®ã ã®åªæå€ãçšããããšãã§ããç¹ã«æçšãªã
ã®ã¯ããªããŒåªæå€ã§ãããåªæå€ã®ã»ãã«å¡©
åºãå¡©åºãã¬ã«ãŒãµãŒãªã©ãããã³ç±æº¶å€ãå«ã
ã§ããããç¹ã«æå å±€ïŒïŒãšè²çŽ åºå®å±€ïŒïŒ
ãšãå¥ã®æ¯æäœäžã«åœ¢æãããŠããå Žåã«ã¯ãå¡©
åºãå¡©åºãã¬ã«ãŒãµãŒãåºå®å±€ïŒïŒã«å«ãŸãã
ããšã¯ç¹ã«æçšã§ããã æ¬çºæã«çšããããããªããŒåªæå€ãšã¯ãäºçŽ
ããã³äžçŽã¢ããåºãå«ãããªããŒãå«çªçŽ è€çŽ
ç°éšåããã€ããªããŒããããã®åçŽã«ããªã³åº
ãå«ãããªããŒãªã©ã§ååéã5000ã200000ãç¹
ã«10000ã50000ã®ãã®ã§ããã äŸãã°ç±³åœç¹èš±2548564å·ãå2484430å·ãå
3148061å·ãå3756814å·æ现æžçã«é瀺ãããŠã
ãããã«ããªãžã³ããªããŒãåã³ããã«ããªãžã
ãŠã ã«ããªã³ããªããŒïŒç±³åœç¹èš±3625694å·ãå
3859096å·ãå4128538å·ãè±åœç¹èš±1277453å·æ
现æžçã«é瀺ãããŠãããŒã©ãã³çãšæ¶æ©å¯èœãª
ããªããŒåªæå€ïŒç±³åœç¹èš±3958995å·ãå2721852
å·ãå2798063å·ãç¹éæ54â115228å·ãå54â
145529å·ãå54â126027å·æ现æžã«é瀺ãããŠã
ãæ°Žæ§ãŸã«ååªæå€ïŒç±³åœç¹èš±3898088å·æ现æž
ã«é瀺ãããŠããæ°Žäžæº¶æ§åªæå€ïŒç±³åœç¹èš±
4168976å·ïŒç¹éæ54â137333å·ïŒæ现æžçã«é
瀺ã®ææãšå ±æçµåãè¡ãããšã®ã§ããåå¿æ§åª
æå€ïŒæŽã«ç±³åœç¹èš±3709690å·ãå3788855å·ãå
3642482å·ãå3488706å·ãå3557066å·ãå
3271147å·ãå3271148å·ãç¹éæ50â71332å·ã
å53â30328å·ãå52â15558å·ãå53â125å·ã
å53â1024å·æ现æžã«é瀺ããŠããåªæå€ãæã
ãããšãåºæ¥ãã ãã®ä»ç±³åœç¹èš±2675316å·ãå2882156å·æ现æž
ã«èšèŒã®åªæå€ãæããããšãã§ããã ãããã®åªæå€ã®å ãäŸãã°ããŒã©ãã³çãã
ãªãã¯ã¹ãšæ¶æ©åå¿ãããã®ãæ°Žäžæº¶æ§ã®åªæ
å€ãåã³æ°Žæ§ãŸã«ïŒåã¯ã©ããã¯ã¹åæ£ç©ïŒååª
æå€ã奜ãŸããçšããããšãåºæ¥ãã ç¹ã«å¥œãŸããããªããŒåªæå€ã以äžã«ç€ºãã (1) ïŒçŽã¢ã³ã¢ããŠã åºããã¡ããã€ãŒã©ãã³ãš
å ±æçµåã§ããåºïŒäŸãã°ã¢ã«ãããåºãã¯ã
ãã¢ã«ã«ãã€ã«åºãã¯ããã¢ã«ãã«åºãããã«
ã¹ã«ããã«åºãããªãžããŠã ããããªãã«åºã
ããã«ã«ã«ããã«åºãã¢ã«ãã«ã¹ã«ãããã·åº
ãªã©ïŒãæããããªã㌠äŸãã° (2) äžèšäžè¬åŒã§è¡šããããã¢ãããŒã®ç¹°ãè¿ã
åäœãšä»ã®ãšãã¬ã³æ§äžé£œåã¢ãããŒã®ç¹°ãè¿
ãåäœãšãããªãã³ããªããŒãšãæ¶æ©å€ïŒäŸã
ã°ãã¹ã¢ã«ã«ã³ã¹ã«ãããŒãããã¹ã¢ã¬ã³ã¹ã«
ãããŒãïŒãšã®åå¿çæç©ã Rb 1ïŒïŒšãã¢ã«ãã«åº Rb 2ïŒïŒšãã¢ã«ãã«åºãã¢ãªãŒã«åº ïŒïŒäŸ¡åº Rb 3ãRb 4ãRb 5ïŒã¢ã«ãã«åºãã¢ãªãŒã«åºããŸã
ã¯Rb 3ãRb 5ã®å°ãªããšãïŒã€ãçµåããŠã
ããç°ã圢æããŠãããã ïŒã¢ããªã³ ïŒäžèšã®ã¢ã«ãã«åºãã¢ãªãŒã«åºã¯çœ®æããã
ãã®ãå«ããïŒ (3) äžèšäžè¬åŒã§è¡šããããããªã㌠ïœïŒçŽ0.25ãçŽïŒã¢ã«ïŒ ïœïŒçŽïŒãçŽ90ã¢ã«ïŒ ïœïŒçŽ10ãçŽ99ã¢ã«ïŒ ïŒãšãã¬ã³æ§äžé£œåçµåãå°ãªããšãïŒã€ã
ã€ã¢ãã㌠ïŒå ±éåå¯èœãªãšãã¬ã³æ§äžé£œåã¢ãã㌠ïŒïŒ®ïŒïŒ° Rb 1ãRb 2ãRb 3ïŒã¢ã«ãã«åºãç°ç¶çåæ°ŽçŽ åºã
ãŸãRb 1ãRb 3ã®å°ãªããšãäºã€ã¯çµåããŠ
ç°ã圢æããŠããããïŒãããã®åºãç°ã¯
眮æãããŠããŠããããïŒ (4) (a)ïŒ(b)åã³(c)ããæãã³ããªã㌠(a)
ç®ãããã®ã®20ééããŒã»ã³ã以äžãæŽã«å¥œãŸã
ãã¯0.1ãã15ééããŒã»ã³ãã§ããã æ¬çºæã§ã¯ãæ°ŽæŸåºååç©ãçšãããšè²çŽ æŸåº
åå¿ãä¿é²ããæå©ã§ããã æ°ŽæŸåºååç©ãšã¯ãç±çŸåäžã«å解ããŠæ°ŽãæŸ
åºããååç©ã®ããšã§ããããããã®ååç©ã¯ç¹
ã«ç¹ç¶ã®è»¢åæºæã«ãããŠç¥ãããæ¥æ¬ç¹èš±æ50
â88386å·å ¬éå ¬å ±èšèŒã®NH4FeïŒSO4ïŒ2ã»12H2O
ãªã©ãæçšã§ããã ãŸãæ¬çºæã«æŒããŠã¯çŸåã®æŽ»æ§åãšåæã«ç»
åã®å®å®åãã¯ããååç©ãçšããããšãã§ã
ãããã®äžã§ç±³åœç¹èš±ç¬¬3301678å·èšèŒã®ïŒâã
ãããã·ãšãã«ã€ãœããŠãããŠã ã»ããªã¯ããã¢
ã»ããŒãã«ä»£è¡šãããã€ãœããŠãããŠã é¡ãç±³åœ
ç¹èš±ç¬¬3669670å·èšèŒã®ïŒïŒïŒâïŒïŒïŒïŒâãžãª
ããµãªã¯ã¿ã³ïŒãã¹ïŒã€ãœããŠãããŠã ã»ããªã
ããã¢ã»ããŒãïŒãªã©ã®ãã¹ã€ãœããŠãããŠã
é¡ã西ç¬ç¹èš±ç¬¬2162714å·å ¬éèšèŒã®ããªãŒã«å
åç©é¡ãç±³åœç¹èš±4012260å·èšèŒã®ïŒâã¢ããâ
ïŒâãã¢ãŸãªãŠã ã»ããªã¯ããã¢ã»ããŒããïŒâ
ã¢ããâïŒâããã¢ãšãã«âïŒâãã¢ãŸãªãŠã ã»
ããªã¯ããã¢ã»ããŒããªã©ã®ãã¢ãŸãªãŠã ååç©
é¡ãç±³åœç¹èš±ç¬¬4060420å·èšèŒã®ãã¹ïŒïŒâã¢ã
ãâïŒâãã¢ãŸãªãŠã ïŒã¡ãã¬ã³ãã¹ïŒã¹ã«ãã
ã«ã¢ã»ããŒãïŒãïŒâã¢ããâïŒâãã¢ãŸãªãŠã
ããšãã«ã¹ã«ããã«ã¢ã»ããŒããªã©ã®ããã«é žæ§
éšãšããŠÎ±âã¹ã«ããã«ã¢ã»ããŒããæããåå
ç©é¡ãç±³åœç¹èš±ç¬¬4088496å·èšèŒã®ãé žæ§éšãšã
ãŠïŒâã«ã«ããã·ã«ã«ããã·ã¢ããããã€ååç©
é¡ãªã©ã奜ãŸããçšããããã æ¬çºæã«æŒããŠã¯ãç±æº¶å€ãå«æãããããšã
ã§ãããããã§âç±æº¶å€âãšã¯ãåšå²æž©åºŠã«ãã
ãŠåºäœã§ãããã䜿çšãããç±åŠç枩床ãŸãã¯ã
ã以äžã®æž©åºŠã«ãããŠä»ã®æåãšäžç·ã«ãªã€ãŠæ··
åèç¹ã瀺ãéå æ°Žå解æ§ã®ææ©ææã§ãããç±
溶å€ã«ã¯ãçŸåè¬ã®æº¶åªãšãªãããååç©ãé«èª
é»çã®ç©è³ªã§éå¡©ã®ç©ççŸåãä¿é²ããããšãç¥
ãããŠããååç©ãªã©ãæçšã§ãããæçšãªç±æº¶
å€ãšããŠã¯ãç±³åœç¹èš±ç¬¬3347675å·èšèŒã®ããªã°
ãªã³ãŒã«é¡ããšãã°å¹³åååé1500ã20000ã®ã
ãªãšãã¬ã³ã°ãªã³ãŒã«ãããªãšãã¬ã³ãªããµã€ã
ã®ãªã¬ã€ã³é žãšã¹ãã«ãªã©ã®èªå°äœãã¿ã€ããã
ã¢ãã¹ãã¢ãªã³ãâSO2âïŒâCOâåºãæããé«
èªé»çã®ååç©ãããšãã°ãã¢ã»ãã¢ããããµã¯
ã·ã³ã€ããããšãã«ã«ã«ãã¡ãŒãããŠã¬ã¢ãã¡ã
ã«ã¹ã«ãã³ã¢ããããšãã¬ã³ã«ãŒãããŒããç±³åœ
ç¹èš±ç¬¬3667959å·èšèŒã®æ¥µæ§ç©è³ªãïŒâãããã
ã·ãã¿ã³é žã®ã©ã¯ãã³ãã¡ãã«ã¹ã«ãã€ãã«ã¡ã¿
ã³ãããã©ãããããªããšã³âïŒïŒïŒâãžãªããµ
ã€ãããªãµãŒããã€ã¹ã¯ããŒãžã€ãŒèª1976幎12æ
å·26ã28ããŒãžèšèŒã®ïŒïŒ10âãã«ã³ãžãªãŒã«ã
ã¢ãã¹é žã¡ãã«ãã¹ããªã³é žãããšãã«ãªã©ã奜
ãŸããçšããããã æ¬çºæã®å Žåã¯ãè²çŽ äŸäžæ§ç©è³ªãçè²ããŠã
ãæŽã«ãã€ã©ãžãšãŒã·ãšã³é²æ¢ããã¬ãŒã·ãšã³é²
æ¢ç©è³ªãææãæå ææäžã«å«æãããããšã¯ã
ãçšå¿ èŠã§ã¯ãªããæŽã«é®®é床ãè¯åããããã
ã«ç¹å ¬æ48â3692å·å ¬å ±ãç±³åœç¹èš±ç¬¬3253921å·ã
å2527583å·ãå2956879å·ãªã©ã®åæ现æžã«èšèŒ
ãããŠããããã€ã«ã¿ãŒææãåžåæ§ç©è³ªãå«æ
ãããããšãã§ããããŸã奜ãŸããã¯ãããã®æ
æãšããŠã¯ç±è±è²æ§ã®ãã®ã奜ãŸãããäŸãã°ç±³
åœç¹èš±ç¬¬3769019å·ãå第3745009å·ãå第
3615432å·ã«èšèŒãããŠãããããªææã奜ãŸã
ãã æ¬çºæã«çšããããæå ææã¯ãå¿ èŠã«å¿ããŠ
ç±çŸåæå ææãšããŠç¥ãããŠããå皮添å å€ã
æå 局以äžã®å±€ããšãã°éé»é²æ¢å±€ãé»å°å±€ãä¿
è·å±€ãäžéå±€ãAHå±€ãã¯ããå±€ãªã©ãå«æãã
ããšãã§ããã æ¬çºæã®æå ææã®åçä¹³å€å±€ãŸãã¯ä»ã®èŠªæ°Ž
æ§ã³ãã€ãå±€ã«ã¯å¡åžå©å€ã垯é»é²æ¢ãã¹ããªæ§
æ¹è¯ãä¹³ååæ£ãæ¥çé²æ¢ããã³åçç¹æ§æ¹è¯
ïŒããšãã°çŸåä¿é²ã硬調åãå¢æïŒãªã©çš®ã ã®
ç®çã§çš®ã ã®çé¢æŽ»æ§å€ãå«ãã§ãããã ããšãã°ãµããã³ïŒã¹ããã€ãç³»ïŒãã¢ã«ãã¬
ã³ãªããµã€ãèªå°äœïŒäŸãã°ããªãšãã¬ã³ã°ãªã³
ãŒã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ïŒããªãããã¬ã³
ã°ãªã³ãŒã«çž®åç©ãããªãšãã¬ã³ã°ãªã³ãŒã«ã¢ã«
ãã«ãšãŒãã«é¡ãŸãã¯ããªãšãã¬ã³ã°ãªã³ãŒã«ã¢
ã«ãã«ã¢ãªãŒã«ãšãŒãã«é¡ãããªãšãã¬ã³ã°ãªã³
ãŒã«ãšã¹ãã«é¡ãããªãšãã¬ã³ã°ãªã³ãŒã«ãœã«ã
ã¿ã³ãšã¹ãã«é¡ãããªã¢ã«ãã¬ã³ã°ãªã³ãŒã«ã¢ã«
ãã«ã¢ãã³ãŸãã¯ã¢ããé¡ãã·ãªã³ãŒã³ã®ããªãš
ãã¬ã³ãªããµã€ãä»å ç©é¡ïŒãã°ãªã·ããŒã«èªå°
äœïŒããšãã°ã¢ã«ã±ãã«ã³ãã¯é žããªã°ãªã»ãª
ããã¢ã«ãã«ããšããŒã«ããªã°ãªã»ãªãïŒãå€äŸ¡
ã¢ã«ã³ãŒã«ã®èèªé žãšã¹ãã«é¡ãç³ã®ã¢ã«ãã«ãš
ã¹ãã«é¡ãªã©ã®éã€ãªã³æ§çé¢æŽ»æ§å€ïŒã¢ã«ãã«
ã«ã«ãã³é žå¡©ãã¢ã«ãã«ã¹ã«ããªã³é žå¡©ãã¢ã«ã
ã«ãã³ãŒã³ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ããã¿ã¬ã³
ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ç¡«é žãšã¹ãã«é¡ãã¢ã«
ãã«ãªã³é žãšã¹ãã«é¡ãâã¢ã·ã«ââã¢ã«ã
ã«ã¿ãŠãªã³é¡ãã¹ã«ãã³ãã¯é žãšã¹ãã«é¡ãã¹ã«
ãã¢ã«ãã«ããªãªãã·ãšãã¬ã³ã¢ã«ãã«ããšãã«
ãšãŒãã«é¡ãããªãªãã·ãšãã¬ã³ã¢ã«ãã«ãªã³é ž
ãšã¹ãã«é¡ãªã©ã®ãããªãã«ã«ããã·åºãã¹ã«ã
åºããã¹ãåºãç¡«é žãšã¹ãã«åºãçé žãšã¹ãã«åº
çã®é žæ§åºãå«ãã¢ããªã³çé¢æŽ»æ§å€ïŒã¢ããé ž
é¡ãã¢ããã¢ã«ãã«ã¹ã«ãã³é žé¡ãã¢ããã¢ã«ã
ã«ç¡«é žãŸãã¯çé žãšã¹ãã«é¡ãã¢ã«ãã«ãã¿ã€ã³
é¡ãã¢ãã³ãªãã·ãé¡ãªã©ã®äž¡æ§çé¢æŽ»æ§å€ïŒã¢
ã«ãã«ã¢ãã³å¡©é¡ãèèªæãããã¯è³éŠæ第ïŒçŽ
ã¢ã³ã¢ããŠã å¡©é¡ãããªãžããŠã ãã€ãããŸãªãŠ
ã ãªã©ã®è€çŽ ç°ç¬¬ïŒçŽã¢ã³ã¢ããŠã å¡©é¡ãããã³
èèªæãŸãã¯è€çŽ ç°ãå«ããã¹ãããŠã ãŸãã¯ã¹
ã«ãããŠã å¡©é¡ãªã©ã®ã«ããªã³çé¢æŽ»æ§å€ãçšã
ãããšãã§ããã äžèšã®çé¢æŽ»æ§å€ã®äžã§ãååå ã«ãšãã¬ã³ãª
ããµã€ãã®ç¹°ãè¿ãåäœãæããããªãšãã¬ã³ã°
ãªã³ãŒã«åéã€ãªã³çé¢æŽ»æ§å€ãæå ææäžã«å«
ãŸããããšã¯å¥œãŸãããç¹ã«å¥œãŸããã¯ãšãã¬ã³
ãªããµã€ãã®ç¹°ãè¿ãåäœãïŒä»¥äžã§ãããã®ã
æãŸããã äžèšã®æ¡ä»¶ãæºããéã€ãªã³æ§çé¢æŽ»æ§å€ã¯ã
åœè©²åé以å€ã«æŒãŠãåºç¯ã«äœ¿çšããããã®æ§
é ã»æ§è³ªã»åææ³ã«ã€ããŠã¯å ¬ç¥ã§ããã代衚ç
ãªå ¬ç¥æç®ã«ã¯Surfactant Science
Seriesvolume1.Nonionic SurfactantsïŒEdited
by Martin J.SchickïŒMarcel Dekker
Inc.1967ïŒãSurface Active Ethylene Oxide
AdductsïŒSchoufeldt.NèPergamon Press1969ïŒ
ãªã©ãããããããã®æç®ã«èšèŒã®éã€ãªã³æ§ç
é¢æŽ»æ§å€ã§äžèšã®æ¡ä»¶ãæºãããã®ã§æ¬çºæã§å¥œ
ãŸããçšããããã ãããã®éã€ãªã³æ§çé¢æŽ»æ§å€ã¯ãåç¬ã§ãã
ãŸãïŒçš®ä»¥äžã®æ··åç©ãšããŠãçšããããã ããªãšãã¬ã³ã°ãªã³ãŒã«åéã€ãªã³çé¢æŽ»æ§å€
ã¯èŠªæ°Žæ§ãã€ã³ããŒã«å¯ŸããŠãçéé以äžã奜ãŸ
ããã¯50ïŒ ä»¥äžã§çšããããã æ¬çºæã®æå ææã«ã¯ãããªãžããŠã å¡©ããã€
éœã€ãªã³æ§ååç©ãå«æããããšãã§ãããããª
ãžããŠã åºããã€éœã€ãªã³æ§ååç©ã®äŸãšããŠã¯
PSA JonrnalïŒSection  36ïŒ1953ïŒïŒ
USP2648604ãUSP3671247ãç¹å ¬æ44â30074ã
ç¹å ¬æ44â9503çã«èšèŒãããŠããã æ¬çºæã®åçæå ææåã³è²çŽ åºå®ææã«ã¯ã
åçä¹³å€å±€ãã®ä»ã®ãã€ã³ããŒå±€ã«ç¡æ©ãŸãã¯æ
æ©ã®ç¡¬èå€ãå«æããŠãããäŸãã°ã¯ãã å¡©ïŒã¯
ãã ããšãŠãã³ãé ¢é žã¯ãã ãªã©ïŒãã¢ã«ããã
é¡ãïŒãã«ã ã¢ã«ããããã°ãªãªããµãŒã«ãã°ã«
ã¿ãŒã«ã¢ã«ããããªã©ïŒãâã¡ãããŒã«ååç©
ïŒãžã¡ãããŒã«å°¿çŽ ãã¡ãããŒã«ãžã¡ãã«ããã³
ãã€ã³ãªã©ïŒããžãªããµã³èªå°äœïŒïŒïŒïŒâãžã
ãããã·ãžãªããµã³ãªã©ïŒã掻æ§ããã«ååç©
ïŒïŒïŒïŒïŒïŒâããªã¢ã¯ãªãã€ã«âãããµããã
âïœâããªã¢ãžã³ãïŒïŒïŒâããã«ã¹ã«ããã«â
ïŒâãããããŒã«ãªã©ïŒã掻æ§ããã²ã³ååç©
ïŒïŒïŒïŒâãžã¯ãã«âïŒâããããã·âïœâããª
ã¢ãžã³ãªã©ïŒãã ã³ããã²ã³é žé¡ïŒã ã³ã¯ãã«é žã
ã ã³ããšããã·ã¯ãã«é žãªã©ïŒããªã©ãåç¬ãŸã
ã¯çµã¿åãããŠçšããããšãã§ããã å皮添å å€ãšããŠã¯âResearch Disclosureâ
Vol170ïŒïŒæ1978幎ã®17029å·ã«èšèŒãããŠãã
æ·»å å€ããšãã°å å¡å€ãé®®é床æ¹è¯çšææãAH
ææãå¢æè²çŽ ããããå€ãè¢å å¢çœå€ãéè²é²
æ¢å€ãªã©ãããã æ¬çºæã«ãããŠã¯ç±çŸåæå å±€ãšåæ§ãä¿è·
å±€ãäžéå±€ãäžå¡å±€ãããã¯å±€ãã®ä»ã®å±€ã«ã€ã
ãŠããããããã®å¡åžæ¶²ã調液ãã浞挬æ³ããšã¢
ãŒãã€ãæ³ãã«ãŒãã³å¡åžæ³ãŸãã¯ç±³åœç¹èš±ç¬¬
3681294å·æ现æžèšèŒã®ããããŒå¡åžæ³ãªã©ã®
çš®ã ã®å¡åžæ³ã§æ¯æäœäžã«é 次å¡åžã也ç¥ããã
ãšã«ããæå ææãäœãããšãã§ããã æŽã«å¿ èŠãªãã°ç±³åœç¹èš±ç¬¬2761791å·æ现æžå
ã³è±åœç¹èš±837095å·æ现æžã«èšèŒãããŠããæ¹æ³
ã«ãã€ãŠïŒå±€ãŸãã¯ãã以äžãåæã«å¡åžããã
ãšãã§ããã æ¬çºæã«ãããŠã¯çš®ã ã®é²å æ段ãçšããããš
ãã§ãããæœåã¯ãå¯èŠå ãå«ã茻å°ç·ã®ç»åç¶
é²å ã«ãã€ãŠåŸããããäžè¬ã«ã¯ãéåžžã®ã«ã©ãŒ
ããªã³ãã«äœ¿ãããå æºäŸãã°ã¿ã³ã°ã¹ãã³ã©ã³
ããæ°Žéç¯ããšãŒãã©ã³ããªã©ã®ããã²ã³ã©ã³
ãããã»ãã³ã©ã³ããã¬ãŒã¶ãŒå æºãããã³
CRTå æºãè¢å 管ãçºå ãã€ãªãŒããªã©ãå æº
ãšããŠäœ¿ãããšãã§ããã åå³ãšããŠã¯ã補å³ãªã©ã®ç·ç»åã¯ãã¡ããã®
ããšãé調ãæããåçç»åã§ãããããŸãã«ã¡
ã©ãçšããŠäººç©åã颚æ¯åãæ®åœ±ããããšãå¯èœ
ã§ãããåå³ããã®çŒä»ã¯ãåå³ãšéããŠå¯ççŒ
ä»ãããŠããåå°çŒä»ãããŠããããŸãåŒäŒžãçŒ
ä»ãããŠãããã ãŸããããªã«ã¡ã©ãªã©ã«ããæ®åœ±ãããç»åã
ãã¬ãå±ããéãããŠããç»åæ å ±ããçŽæ¥
CRTãFOTã«åºãããã®åãå¯çãã¬ã³ãºã«ã
ãç±çŸåææäžã«çµåãããŠãçŒä»ãããšãå¯èœ
ã§ããã ãŸãæè¿å€§å·Ÿãªé²æ©ãèŠãããLEDïŒçºå ãã€
ãªãŒãïŒã¯ãåçš®ã®æ©åšã«ãããŠãé²å æ段ãšã
ãŠãŸãã¯è¡šç€ºæ段ãšããŠçšãããã€ã€ããããã®
LEDã¯ãéå ãæå¹ã«åºããã®ãäœãããšãå°
é£ã§ããããã®å Žåã«ã©ãŒç»åãåçããã«ã¯ã
LEDãšããŠç·å ãèµ€å ãèµ€å€å ãçºããïŒçš®ã
䜿ãããããã®å ã«æå ããææéšåãåã ãã€
ãšããŒããŒã³ã¿ãã·ã¢ã³ã®ææãæŸåºããããã«
èšèšããã°ããã ããªãã¡ç·æå éšåïŒå±€ïŒãã€ãšããŒè²çŽ äŸäž
æ§ç©è³ªãå«ã¿ãèµ€æå éšåïŒå±€ïŒãããŒã³ã¿è²çŽ
äŸäžæ§ç©è³ªããèµ€å€æå éšåïŒå±€ïŒãã·ã¢ã³è²çŽ
äŸäžæ§ç©è³ªãå«ãããã«ããŠããã°ããããã以
å€ã®å¿ èŠã«å¿ããŠç°ã€ãçµåããå¯èœã§ããã äžèšã®åå³ãçŽæ¥ã«å¯çãŸãã¯æ圱ããæ¹æ³ä»¥
å€ã«ãå æºã«ããç §å°ãããåå³ãå é»ç®¡ã
CCDãªã©ã®åå çŽ åã«ãããèªã¿ãšãã³ã³ããŠ
ãŒã¿ãŒãªã©ã®ã¡ã¢ãªãŒã«å ¥ãããã®æ å ±ãå¿ èŠã«
å¿ããŠå å·¥ããããããç»ååŠçãã»ã©ããã
åŸããã®ç»åæ å ±ãCRTã«åçããããããç»
åç¶å æºãšããŠå©çšããããåŠçãããæ å ±ã«ã
ãšã¥ããŠãçŽæ¥ïŒçš®LEDãçºå ãããŠé²å ãã
æ¹æ³ãããã æ¬çºæã«ãããŠã¯æå ææãžã®é²å ã®åŸãåŸã
ããæœåã¯ãäŸãã°ãçŽ80âãçŽ250âã§çŽ0.5ç§
ããçŽ300ç§ã®ããã«é©åºŠã«äžæãã枩床ã§è©²èŠ
çŽ ãå ç±ããããšã«ããçŸåããããšãã§ããã
äžèšç¯å²ã«å«ãŸãã枩床ã§ããã°ãå ç±æéã®å¢
倧åã¯ççž®ã«ãã€ãŠé«æž©ãäœæž©ã®ãããã§ã䜿çš
å¯èœã§ãããç¹ã«çŽ110âãçŽ160âã®æž©åºŠç¯å²ã
æçšã§ããã 該å ç±æ段ã¯ãåãªãç±æ¿ãã¢ã€ãã³ãç±ããŒ
ã©ãŒãã«ãŒãã³ããã¿ã³ãã¯ã€ããªã©ãå©çšãã
çºç±äœåã¯ãã®é¡äŒŒç©ã§ãã€ãŠããã æ¬çºæã«æŒããŠãç±çŸåã«ããåç»åã圢æã
ããããå ·äœçãªæ¹æ³ã¯ã芪氎æ§ã®å¯åæ§è²çŽ ã
移åãããããšã§ããããã®ããã«ãæ¬çºæã®æ
å ææã¯ãæ¯æäœäžã«å°ããšãããã²ã³åéãå¿
èŠã«å¿ããŠææ©éå¡©é žåå€ãšãã®éå å€ã§ããã
è²çŽ äŸäžæ§ç©è³ªãããã³ãã€ã³ããŒãå«ãæå å±€
ïŒïŒãšãïŒïŒå±€ã§åœ¢æããã芪氎æ§ã§æ¡æ£æ§ã®
è²çŽ ãåããšããããšã®ã§ããè²çŽ åºå®å±€ïŒïŒ
ããæ§æãããã äžè¿°ã®æå å±€ïŒïŒãšè²çŽ åºå®å±€ïŒïŒãšã¯ã
åäžã®æ¯æäœäžã«åœ¢æããŠããããããŸãå¥ã ã®
æ¯æäœäžã«åœ¢æããããšãã§ãããè²çŽ åºå®å±€
ïŒïŒãšãæå å±€ïŒïŒãšã¯ã²ãã¯ããããšãã§
ãããããšãã°ãåæ§é²å åŸåäžå ç±çŸåããã
ã®åŸãè²çŽ åºå®å±€ïŒïŒåã¯æå å±€ãã²ãã¯ãã
ããšãã§ããããŸããæå å±€ïŒïŒãæ¯æäœäžã«
å¡åžããæå ææãšãåºå®å±€ïŒïŒãæ¯æäœäžã«
å¡åžããåºå®ææãšãå¥ã ã«åœ¢æãããå Žåã«
ã¯ãæå ææã«åæ§é²å ããŠåäžå ç±åŸãåºå®æ
æãéãå¯åæ§è²çŽ ãåºå®å±€ïŒïŒã«ç§»ãããšã
ã§ããã ãŸããæå ææïŒïŒã®ã¿ãåæ§é²å ãããã®
åŸè²çŽ åºå®å±€ïŒïŒãéãåãããŠåäžå ç±ãã
æ¹æ³ãããã è²çŽ åºå®å±€ïŒïŒã¯ãè²çŽ åºå®ã®ãããäŸãã°
è²çŽ åªæå€ãå«ãããšãã§ãããåªæå€ãšããŠã¯
çš®ã ã®åªæå€ãçšããããšãã§ããç¹ã«æçšãªã
ã®ã¯ããªããŒåªæå€ã§ãããåªæå€ã®ã»ãã«å¡©
åºãå¡©åºãã¬ã«ãŒãµãŒãªã©ãããã³ç±æº¶å€ãå«ã
ã§ããããç¹ã«æå å±€ïŒïŒãšè²çŽ åºå®å±€ïŒïŒ
ãšãå¥ã®æ¯æäœäžã«åœ¢æãããŠããå Žåã«ã¯ãå¡©
åºãå¡©åºãã¬ã«ãŒãµãŒãåºå®å±€ïŒïŒã«å«ãŸãã
ããšã¯ç¹ã«æçšã§ããã æ¬çºæã«çšããããããªããŒåªæå€ãšã¯ãäºçŽ
ããã³äžçŽã¢ããåºãå«ãããªããŒãå«çªçŽ è€çŽ
ç°éšåããã€ããªããŒããããã®åçŽã«ããªã³åº
ãå«ãããªããŒãªã©ã§ååéã5000ã200000ãç¹
ã«10000ã50000ã®ãã®ã§ããã äŸãã°ç±³åœç¹èš±2548564å·ãå2484430å·ãå
3148061å·ãå3756814å·æ现æžçã«é瀺ãããŠã
ãããã«ããªãžã³ããªããŒãåã³ããã«ããªãžã
ãŠã ã«ããªã³ããªããŒïŒç±³åœç¹èš±3625694å·ãå
3859096å·ãå4128538å·ãè±åœç¹èš±1277453å·æ
现æžçã«é瀺ãããŠãããŒã©ãã³çãšæ¶æ©å¯èœãª
ããªããŒåªæå€ïŒç±³åœç¹èš±3958995å·ãå2721852
å·ãå2798063å·ãç¹éæ54â115228å·ãå54â
145529å·ãå54â126027å·æ现æžã«é瀺ãããŠã
ãæ°Žæ§ãŸã«ååªæå€ïŒç±³åœç¹èš±3898088å·æ现æž
ã«é瀺ãããŠããæ°Žäžæº¶æ§åªæå€ïŒç±³åœç¹èš±
4168976å·ïŒç¹éæ54â137333å·ïŒæ现æžçã«é
瀺ã®ææãšå ±æçµåãè¡ãããšã®ã§ããåå¿æ§åª
æå€ïŒæŽã«ç±³åœç¹èš±3709690å·ãå3788855å·ãå
3642482å·ãå3488706å·ãå3557066å·ãå
3271147å·ãå3271148å·ãç¹éæ50â71332å·ã
å53â30328å·ãå52â15558å·ãå53â125å·ã
å53â1024å·æ现æžã«é瀺ããŠããåªæå€ãæã
ãããšãåºæ¥ãã ãã®ä»ç±³åœç¹èš±2675316å·ãå2882156å·æ现æž
ã«èšèŒã®åªæå€ãæããããšãã§ããã ãããã®åªæå€ã®å ãäŸãã°ããŒã©ãã³çãã
ãªãã¯ã¹ãšæ¶æ©åå¿ãããã®ãæ°Žäžæº¶æ§ã®åªæ
å€ãåã³æ°Žæ§ãŸã«ïŒåã¯ã©ããã¯ã¹åæ£ç©ïŒååª
æå€ã奜ãŸããçšããããšãåºæ¥ãã ç¹ã«å¥œãŸããããªããŒåªæå€ã以äžã«ç€ºãã (1) ïŒçŽã¢ã³ã¢ããŠã åºããã¡ããã€ãŒã©ãã³ãš
å ±æçµåã§ããåºïŒäŸãã°ã¢ã«ãããåºãã¯ã
ãã¢ã«ã«ãã€ã«åºãã¯ããã¢ã«ãã«åºãããã«
ã¹ã«ããã«åºãããªãžããŠã ããããªãã«åºã
ããã«ã«ã«ããã«åºãã¢ã«ãã«ã¹ã«ãããã·åº
ãªã©ïŒãæããããªã㌠äŸãã° (2) äžèšäžè¬åŒã§è¡šããããã¢ãããŒã®ç¹°ãè¿ã
åäœãšä»ã®ãšãã¬ã³æ§äžé£œåã¢ãããŒã®ç¹°ãè¿
ãåäœãšãããªãã³ããªããŒãšãæ¶æ©å€ïŒäŸã
ã°ãã¹ã¢ã«ã«ã³ã¹ã«ãããŒãããã¹ã¢ã¬ã³ã¹ã«
ãããŒãïŒãšã®åå¿çæç©ã Rb 1ïŒïŒšãã¢ã«ãã«åº Rb 2ïŒïŒšãã¢ã«ãã«åºãã¢ãªãŒã«åº ïŒïŒäŸ¡åº Rb 3ãRb 4ãRb 5ïŒã¢ã«ãã«åºãã¢ãªãŒã«åºããŸã
ã¯Rb 3ãRb 5ã®å°ãªããšãïŒã€ãçµåããŠã
ããç°ã圢æããŠãããã ïŒã¢ããªã³ ïŒäžèšã®ã¢ã«ãã«åºãã¢ãªãŒã«åºã¯çœ®æããã
ãã®ãå«ããïŒ (3) äžèšäžè¬åŒã§è¡šããããããªã㌠ïœïŒçŽ0.25ãçŽïŒã¢ã«ïŒ ïœïŒçŽïŒãçŽ90ã¢ã«ïŒ ïœïŒçŽ10ãçŽ99ã¢ã«ïŒ ïŒãšãã¬ã³æ§äžé£œåçµåãå°ãªããšãïŒã€ã
ã€ã¢ãã㌠ïŒå ±éåå¯èœãªãšãã¬ã³æ§äžé£œåã¢ãã㌠ïŒïŒ®ïŒïŒ° Rb 1ãRb 2ãRb 3ïŒã¢ã«ãã«åºãç°ç¶çåæ°ŽçŽ åºã
ãŸãRb 1ãRb 3ã®å°ãªããšãäºã€ã¯çµåããŠ
ç°ã圢æããŠããããïŒãããã®åºãç°ã¯
眮æãããŠããŠããããïŒ (4) (a)ïŒ(b)åã³(c)ããæãã³ããªã㌠(a)
ãåŒãåã¯
ãåŒã
ïŒæ°ŽçŽ ååãã¢ã«ãã«åºãŸãã¯ããã²ã³å
åïŒã¢ã«ãã«åºã¯çœ®æãããŠããŠããããïŒ (b) ã¢ã¯ãªã«é žãšã¹ãã« (c) ã¢ã¯ãªã«ãããªã« (5) äžèšäžè¬åŒã§è¡šããããããè¿ãåäœã1/3
以äžæããæ°Žäžæº¶æ§ã®ããªã㌠Rb 1ãRb 2ãRb 3ïŒããããã¢ã«ãã«åºãè¡šããã
Rb 1ãRb 3ã®ççŽ æ°ã®ç·åã12以äžã®ãã®ã
ïŒã¢ã«ãã«åºã¯çœ®æãããŠããŠããããïŒ ïŒžïŒã¢ããªã³ åªæå±€ã«äœ¿çšãããŒã©ãã³ã¯ãå ¬ç¥ã®åçš®ã®ãŒ
ã©ãã³ãçšãããããäŸãã°ç³ç°åŠçãŒã©ãã³ã
é žåŠçãŒã©ãã³ãªã©ã®ãŒã©ãã³ã®è£œé æ³ã®ç°ãªã
ãã®ãããããã¯ãåŸããããããã®ãŒã©ãã³ã
ååŠçã«ããã¿ã«åãã¹ã«ããã«åãªã©ã®å€æ§ã
è¡ã€ããŒã©ãã³ãçšããããšãã§ããããŸãå¿ èŠ
ãªå Žåã«ã¯ãè±å¡©åŠçãè¡ã€ãŠäœ¿çšããããšãã§
ããã æ¬çºæã®ããªããŒåªæå€ãšãŒã©ãã³ã®æ··åæ¯ã
ãã³ããªããŒåªæå€ã®å¡åžéã¯ãåªæãããã¹ã
è²çŽ ã®éãããªããŒåªæå€ã®çš®é¡ãçµæãæŽã«çš
ããããç»å圢æéçšãªã©ã«å¿ããŠãåœæ¥è ã容
æã«å®ããããšãã§ããããåªæå€ïŒãŒã©ãã³æ¯
ã20ïŒ80ã80ïŒ20ïŒééæ¯ïŒãåªæå€å¡åžéã¯0.5
ãïŒïœïŒm2ã§äœ¿çšããã®ã奜ãŸããã è²çŽ åºå®å±€ïŒïŒã¯ãçœè²åå°å±€ãæããŠããŠ
ããããããšãã°ãéææ¯æäœäžã®åªæå€å±€ã®äž
ã«ããŒã©ãã³ã«åæ£ããäºé žåãã¿ã³å±€ãããã
ãããšãã§ãããäºé žåãã¿ã³å±€ã¯ãçœè²ã®äžé
æå±€ã圢æãã転åè²ç»åãéææ¯æäœåŽããèŠ
ãããšã«ãããåå°åã®è²åãåŸãããã æ¬çºæã«çšããããå žåçãªåºå®ææã¯ã¢ã³ã¢
ããŠã å¡©ãå«ãããªããŒããŒã©ãã³ãšæ··åããŠé
ææ¯æäœäžã«å¡åžããããšã«ããåŸãããã è²çŽ ã®æå å±€ããè²çŽ åºå®å±€ãžã®è²çŽ 移åã«
ã¯ãè²çŽ 移åå©å€ãçšããããšãã§ãããè²çŽ 移
åå©å€ã«ã¯ãæ°ŽïŒãŸãã¯èæ§ãœãŒãïŒèæ§ã«ãªïŒ
ç¡æ©ã®ã¢ã«ã«ãªéå±å¡©ãå«ãå¡©åºæ§ã®æ°Žæº¶æ¶²ãçš
ããããããŸããã¡ã¿ããŒã«ïŒïŒ®ïŒïŒ®âãžã¡ãã«
ãã«ã ã¢ããïŒã¢ã»ãã³ïŒãžã€ãœããã«ã±ãã³ãª
ã©ã®äœæ²žç¹æº¶åªããŸãã¯ãããã®äœæ²žç¹æº¶åªãšæ°Ž
åã¯å¡©åºæ§ã®æ°Žæº¶æ¶²ãšã®æ··å溶液ãçšããããã
è²çŽ 移åå©å€ã¯ãååå±€ã溶åªã§æ¹¿ãããæ¹æ³ã§
çšããŠãããããçµæ¶æ°Žããã€ã¯ãã«ãã»ã«ãšã
ãŠææäžã«å èµãããŠãããŠãããã å®æœäŸ ïŒ ãŒã©ãã³40ïœãšKBr26ïœãæ°Ž3000mlã«æº¶è§£ã
ãããã®æº¶æ¶²ã50âã«ä¿ã¡æ¹æããã 次ã«ç¡é žé34ïœãæ°Ž200mlã«æº¶ããã液ã10å
éã§äžèšæº¶æ¶²ã«æ·»å ããã ãã®åŸKI3.3ïœãæ°Ž100mlã«æº¶ããã液ãïŒåé
ã§æ·»å ããã ããããŠã§ããæ²èåéä¹³å€ã®PHã調æŽããæ²
éãããéå°ã®å¡©ãé€å»ããã ãã®åŸPHã6.0ã«åããåé400ïœã®æ²èåéä¹³
å€ãåŸãã 次ã«è²çŽ äŸäžæ§ç©è³ªã®ãŒã©ãã³åæ£ç©ã®äœãæ¹
ã«ã€ããŠè¿°ã¹ãã è²çŽ äŸäžæ§ç©è³ª(10)ãïŒïœãçé¢æŽ»æ§å€ãšããŠã
ã³ãã¯é žâïŒâãšãã«âããã·ã«ãšã¹ãã«ã¹ã«ã
ã³é žãœãŒã0.5ïœãããªâã¯ã¬ãžã«ããªã¹ããšãŒ
ãïŒTCPïŒïŒïœã秀éããé ¢é žãšãã«30mlãå
ããçŽ60âã«å ç±æº¶è§£ãããããã®æº¶æ¶²ãšãŒã©ã
ã³ã®10ïŒ æº¶æ¶²100ïœãšãæ¹ææ··åããåŸããã¢ãž
ãã€ã¶ãŒã§10åéã10000RPMã«ãŠåæ£ãããã
ã®åæ£æ¶²ãè²çŽ äŸäžæ§ç©è³ªã®åæ£ç©ãšèšãã 次ã«æå æ§å¡åžç©ã®èª¿æŽæ³ã«ã€ããŠè¿°ã¹ãã (a) æå æ§æ²èåéä¹³å€ 25ïœ (b) è²çŽ äŸäžæ§ç©è³ªã®åæ£ç© 33ïœ (c) 次ã«ç€ºãååç©ã®ïŒïŒ 氎溶液 10ml (d) 次ã«ç€ºãååç©ã®10ïŒ æ°Žæº¶æ¶² ïŒml H2NSO2NïŒCH3ïŒ2 (e) æ¬çºæã®å¡©åºãã¬ã«ãŒãµãŒ(1)ïŒïœããšã¿ããŒ
ã«20mlã«æº¶ããã溶液 以äžã®(a)ã(e)ãæ··åããå ç±æº¶è§£ãããåŸãå
ã180ÎŒã®ããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããã€ã«ã
äžã«30ÎŒmã®ãŠãšããèåã«å¡åžããããã®å¡åž
è©Šæã也ç¥åŸãã¿ã³ã°ã¹ãã³é»çãçšãã2000ã«
ã¯ã¹ã§10ç§éåç¶ã«é²å ããããã®åŸ140âã«å
ç±ããããŒããããã¯äžã§60ç§éåäžã«å ç±ã
ãããã®è©Šæããšããã 次ã«ã(e)ã®æ¬çºæã®ååç©ãé€ãããããã«æ°Ž
20mlãå ããŠäœæããè©Šæããšãäžèšãšåæ§ãª
æäœãè¡ãªã€ãã 次ã«ååå±€ãæããååææã®åœ¢ææ¹æ³ã«ã€ã
ãŠè¿°ã¹ãã ããªïŒã¢ã¯ãªã«é žã¡ãã«âã³âïŒïŒ®ïŒïŒ®âã
ãªã¡ãã«ââããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ã
ã©ã€ãïŒïŒã¢ã¯ãªã«é žã¡ãã«ãšããã«ãã³ãžã«ã¢
ã³ã¢ããŠã ã¯ãã©ã€ãã®æ¯çã¯ïŒïŒïŒïŒ10ïœã
200mlã®æ°Žã«æº¶è§£ãã10ïŒ ç³ç°åŠçãŒã©ãã³100ïœ
ãšåäžã«æ··åããããã®æ··å液ãäºé žåãã¿ã³ã
åæ£ããããªãšãã¬ã³ã§ã©ãããŒãããçŽæ¯äœäž
ã«90ÎŒmã®ãŠãšããèåã«åäžã«å¡åžããããã®
è©Šæã也ç¥åŸãååææãšããŠçšããã ååææãæ°Žã«æµžããåŸãäžè¿°ã®å ç±ããæå
ææãããããããèé¢ãæ¥ããããã«éã
åãããã 80âã®ããŒããããã¯äžã§ïŒç§å ç±ããåŸåå
ææãæå ææããã²ãã¯ãããšãååææäžã«
ãã¬ã®ããŒã³ã¿è²åãåŸãããããã®ãã¬åã®æ¿
床ã¯ããã¯ãã¹åå°æ¿åºŠèšïŒRDâ519ïŒãçšã
ãŠæž¬å®ãããšããã次ã®çµæãåŸãã è©Š æ No. æ倧æ¿åºŠ æå°æ¿åºŠ (æ¬çºæ) 2.20 0.20 (æ¯ èŒ) 0.03 0.03 以äžã®çµæããæ¬çºæã®å¡©åºãã¬ã«ãŒãµãŒãé«
ãæ¿åºŠãäžããããšããããã ããã«è©Šæã60âã®äžã§ïŒæ¥éä¿åããåŸã
åèšãšåãåŠçããããšããæå°æ¿åºŠãæé«æ¿åºŠ
ã¯åã 0.25ïŒ2.15ãšãªããæ¬çºæã®è©Šæã®ä¿åæ§
ã®ããããŠããããšããããã å®æœäŸ ïŒ äžèšã®å¡©åºãã¬ã«ãŒãµãŒãè¡šäžèšèŒã®éã ãçš
ãã以å€ã¯å®æœäŸïŒãšå šãåæ§ãªæäœãè¡ãã次
ã®çµæãåŸãã
åïŒã¢ã«ãã«åºã¯çœ®æãããŠããŠããããïŒ (b) ã¢ã¯ãªã«é žãšã¹ãã« (c) ã¢ã¯ãªã«ãããªã« (5) äžèšäžè¬åŒã§è¡šããããããè¿ãåäœã1/3
以äžæããæ°Žäžæº¶æ§ã®ããªã㌠Rb 1ãRb 2ãRb 3ïŒããããã¢ã«ãã«åºãè¡šããã
Rb 1ãRb 3ã®ççŽ æ°ã®ç·åã12以äžã®ãã®ã
ïŒã¢ã«ãã«åºã¯çœ®æãããŠããŠããããïŒ ïŒžïŒã¢ããªã³ åªæå±€ã«äœ¿çšãããŒã©ãã³ã¯ãå ¬ç¥ã®åçš®ã®ãŒ
ã©ãã³ãçšãããããäŸãã°ç³ç°åŠçãŒã©ãã³ã
é žåŠçãŒã©ãã³ãªã©ã®ãŒã©ãã³ã®è£œé æ³ã®ç°ãªã
ãã®ãããããã¯ãåŸããããããã®ãŒã©ãã³ã
ååŠçã«ããã¿ã«åãã¹ã«ããã«åãªã©ã®å€æ§ã
è¡ã€ããŒã©ãã³ãçšããããšãã§ããããŸãå¿ èŠ
ãªå Žåã«ã¯ãè±å¡©åŠçãè¡ã€ãŠäœ¿çšããããšãã§
ããã æ¬çºæã®ããªããŒåªæå€ãšãŒã©ãã³ã®æ··åæ¯ã
ãã³ããªããŒåªæå€ã®å¡åžéã¯ãåªæãããã¹ã
è²çŽ ã®éãããªããŒåªæå€ã®çš®é¡ãçµæãæŽã«çš
ããããç»å圢æéçšãªã©ã«å¿ããŠãåœæ¥è ã容
æã«å®ããããšãã§ããããåªæå€ïŒãŒã©ãã³æ¯
ã20ïŒ80ã80ïŒ20ïŒééæ¯ïŒãåªæå€å¡åžéã¯0.5
ãïŒïœïŒm2ã§äœ¿çšããã®ã奜ãŸããã è²çŽ åºå®å±€ïŒïŒã¯ãçœè²åå°å±€ãæããŠããŠ
ããããããšãã°ãéææ¯æäœäžã®åªæå€å±€ã®äž
ã«ããŒã©ãã³ã«åæ£ããäºé žåãã¿ã³å±€ãããã
ãããšãã§ãããäºé žåãã¿ã³å±€ã¯ãçœè²ã®äžé
æå±€ã圢æãã転åè²ç»åãéææ¯æäœåŽããèŠ
ãããšã«ãããåå°åã®è²åãåŸãããã æ¬çºæã«çšããããå žåçãªåºå®ææã¯ã¢ã³ã¢
ããŠã å¡©ãå«ãããªããŒããŒã©ãã³ãšæ··åããŠé
ææ¯æäœäžã«å¡åžããããšã«ããåŸãããã è²çŽ ã®æå å±€ããè²çŽ åºå®å±€ãžã®è²çŽ 移åã«
ã¯ãè²çŽ 移åå©å€ãçšããããšãã§ãããè²çŽ 移
åå©å€ã«ã¯ãæ°ŽïŒãŸãã¯èæ§ãœãŒãïŒèæ§ã«ãªïŒ
ç¡æ©ã®ã¢ã«ã«ãªéå±å¡©ãå«ãå¡©åºæ§ã®æ°Žæº¶æ¶²ãçš
ããããããŸããã¡ã¿ããŒã«ïŒïŒ®ïŒïŒ®âãžã¡ãã«
ãã«ã ã¢ããïŒã¢ã»ãã³ïŒãžã€ãœããã«ã±ãã³ãª
ã©ã®äœæ²žç¹æº¶åªããŸãã¯ãããã®äœæ²žç¹æº¶åªãšæ°Ž
åã¯å¡©åºæ§ã®æ°Žæº¶æ¶²ãšã®æ··å溶液ãçšããããã
è²çŽ 移åå©å€ã¯ãååå±€ã溶åªã§æ¹¿ãããæ¹æ³ã§
çšããŠãããããçµæ¶æ°Žããã€ã¯ãã«ãã»ã«ãšã
ãŠææäžã«å èµãããŠãããŠãããã å®æœäŸ ïŒ ãŒã©ãã³40ïœãšKBr26ïœãæ°Ž3000mlã«æº¶è§£ã
ãããã®æº¶æ¶²ã50âã«ä¿ã¡æ¹æããã 次ã«ç¡é žé34ïœãæ°Ž200mlã«æº¶ããã液ã10å
éã§äžèšæº¶æ¶²ã«æ·»å ããã ãã®åŸKI3.3ïœãæ°Ž100mlã«æº¶ããã液ãïŒåé
ã§æ·»å ããã ããããŠã§ããæ²èåéä¹³å€ã®PHã調æŽããæ²
éãããéå°ã®å¡©ãé€å»ããã ãã®åŸPHã6.0ã«åããåé400ïœã®æ²èåéä¹³
å€ãåŸãã 次ã«è²çŽ äŸäžæ§ç©è³ªã®ãŒã©ãã³åæ£ç©ã®äœãæ¹
ã«ã€ããŠè¿°ã¹ãã è²çŽ äŸäžæ§ç©è³ª(10)ãïŒïœãçé¢æŽ»æ§å€ãšããŠã
ã³ãã¯é žâïŒâãšãã«âããã·ã«ãšã¹ãã«ã¹ã«ã
ã³é žãœãŒã0.5ïœãããªâã¯ã¬ãžã«ããªã¹ããšãŒ
ãïŒTCPïŒïŒïœã秀éããé ¢é žãšãã«30mlãå
ããçŽ60âã«å ç±æº¶è§£ãããããã®æº¶æ¶²ãšãŒã©ã
ã³ã®10ïŒ æº¶æ¶²100ïœãšãæ¹ææ··åããåŸããã¢ãž
ãã€ã¶ãŒã§10åéã10000RPMã«ãŠåæ£ãããã
ã®åæ£æ¶²ãè²çŽ äŸäžæ§ç©è³ªã®åæ£ç©ãšèšãã 次ã«æå æ§å¡åžç©ã®èª¿æŽæ³ã«ã€ããŠè¿°ã¹ãã (a) æå æ§æ²èåéä¹³å€ 25ïœ (b) è²çŽ äŸäžæ§ç©è³ªã®åæ£ç© 33ïœ (c) 次ã«ç€ºãååç©ã®ïŒïŒ 氎溶液 10ml (d) 次ã«ç€ºãååç©ã®10ïŒ æ°Žæº¶æ¶² ïŒml H2NSO2NïŒCH3ïŒ2 (e) æ¬çºæã®å¡©åºãã¬ã«ãŒãµãŒ(1)ïŒïœããšã¿ããŒ
ã«20mlã«æº¶ããã溶液 以äžã®(a)ã(e)ãæ··åããå ç±æº¶è§£ãããåŸãå
ã180ÎŒã®ããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããã€ã«ã
äžã«30ÎŒmã®ãŠãšããèåã«å¡åžããããã®å¡åž
è©Šæã也ç¥åŸãã¿ã³ã°ã¹ãã³é»çãçšãã2000ã«
ã¯ã¹ã§10ç§éåç¶ã«é²å ããããã®åŸ140âã«å
ç±ããããŒããããã¯äžã§60ç§éåäžã«å ç±ã
ãããã®è©Šæããšããã 次ã«ã(e)ã®æ¬çºæã®ååç©ãé€ãããããã«æ°Ž
20mlãå ããŠäœæããè©Šæããšãäžèšãšåæ§ãª
æäœãè¡ãªã€ãã 次ã«ååå±€ãæããååææã®åœ¢ææ¹æ³ã«ã€ã
ãŠè¿°ã¹ãã ããªïŒã¢ã¯ãªã«é žã¡ãã«âã³âïŒïŒ®ïŒïŒ®âã
ãªã¡ãã«ââããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ã
ã©ã€ãïŒïŒã¢ã¯ãªã«é žã¡ãã«ãšããã«ãã³ãžã«ã¢
ã³ã¢ããŠã ã¯ãã©ã€ãã®æ¯çã¯ïŒïŒïŒïŒ10ïœã
200mlã®æ°Žã«æº¶è§£ãã10ïŒ ç³ç°åŠçãŒã©ãã³100ïœ
ãšåäžã«æ··åããããã®æ··å液ãäºé žåãã¿ã³ã
åæ£ããããªãšãã¬ã³ã§ã©ãããŒãããçŽæ¯äœäž
ã«90ÎŒmã®ãŠãšããèåã«åäžã«å¡åžããããã®
è©Šæã也ç¥åŸãååææãšããŠçšããã ååææãæ°Žã«æµžããåŸãäžè¿°ã®å ç±ããæå
ææãããããããèé¢ãæ¥ããããã«éã
åãããã 80âã®ããŒããããã¯äžã§ïŒç§å ç±ããåŸåå
ææãæå ææããã²ãã¯ãããšãååææäžã«
ãã¬ã®ããŒã³ã¿è²åãåŸãããããã®ãã¬åã®æ¿
床ã¯ããã¯ãã¹åå°æ¿åºŠèšïŒRDâ519ïŒãçšã
ãŠæž¬å®ãããšããã次ã®çµæãåŸãã è©Š æ No. æ倧æ¿åºŠ æå°æ¿åºŠ (æ¬çºæ) 2.20 0.20 (æ¯ èŒ) 0.03 0.03 以äžã®çµæããæ¬çºæã®å¡©åºãã¬ã«ãŒãµãŒãé«
ãæ¿åºŠãäžããããšããããã ããã«è©Šæã60âã®äžã§ïŒæ¥éä¿åããåŸã
åèšãšåãåŠçããããšããæå°æ¿åºŠãæé«æ¿åºŠ
ã¯åã 0.25ïŒ2.15ãšãªããæ¬çºæã®è©Šæã®ä¿åæ§
ã®ããããŠããããšããããã å®æœäŸ ïŒ äžèšã®å¡©åºãã¬ã«ãŒãµãŒãè¡šäžèšèŒã®éã ãçš
ãã以å€ã¯å®æœäŸïŒãšå šãåæ§ãªæäœãè¡ãã次
ã®çµæãåŸãã
ãè¡šã
以äžã®çµæããæ¬çºæã®å¡©åºãã¬ã«ãŒãµãŒã¯ã
ããããå¹æãæããŠããããšãããã€ãã å®æœäŸ ïŒ å®æœäŸïŒã®è²çŽ äŸäžæ§ç©è³ª(10)ã®ãããã«äžèšè²
çŽ äŸäžæ§ç©è³ªãçšããŠå®æœäŸïŒãšåæ§ãªæäœã«ã
ãè²çŽ äŸäžæ§ç©è³ªã®åæ£ç©ãäœã€ãã è²çŽ äŸäžæ§ç©è³ªïŒ42ïŒ ïŒïœ åæ£ç©ïŒïŒ ã ïŒ68ïŒ 7.5ïœ åæ£ç©ïŒïŒ ã ïŒ21ïŒ ïŒïœ åæ£ç©ïŒïŒ å®æœäŸïŒãšå šãåæ§ãªæäœã§è©Šæãäœæããå
æ§ã«åŠçãè¡ãªã€ããåŸãããçµæã次ã«ç€ºãã
ããããå¹æãæããŠããããšãããã€ãã å®æœäŸ ïŒ å®æœäŸïŒã®è²çŽ äŸäžæ§ç©è³ª(10)ã®ãããã«äžèšè²
çŽ äŸäžæ§ç©è³ªãçšããŠå®æœäŸïŒãšåæ§ãªæäœã«ã
ãè²çŽ äŸäžæ§ç©è³ªã®åæ£ç©ãäœã€ãã è²çŽ äŸäžæ§ç©è³ªïŒ42ïŒ ïŒïœ åæ£ç©ïŒïŒ ã ïŒ68ïŒ 7.5ïœ åæ£ç©ïŒïŒ ã ïŒ21ïŒ ïŒïœ åæ£ç©ïŒïŒ å®æœäŸïŒãšå šãåæ§ãªæäœã§è©Šæãäœæããå
æ§ã«åŠçãè¡ãªã€ããåŸãããçµæã次ã«ç€ºãã
ãè¡šã
以äžã®çµæããæ¬çºæã®å¡©åºãã¬ã«ãŒãµãŒãé«
ãæ倧æ¿åºŠãäžããããšãããã€ãã å®æœäŸ ïŒ æ¬¡ã«ææ©éå¡©é žåå€ãçšãããšãã®å®æœäŸã瀺
ãã ãã³ãŸããªã¢ãŸãŒã«éä¹³å€ã®èª¿è£œæ³ ãŒã©ãã³28ïœãšãã³ãŸããªã¢ãŸãŒã«13.2ïœãæ°Ž
3000mlã«æº¶è§£ããããã®æº¶æ¶²ã40âã«ä¿ã¡æ¹æã
ãããã®æº¶æ¶²ã«ç¡é žé17ïœãæ°Ž100mlã«æº¶ããã
液ãïŒåéã§å ããã ãã®ãã³ãŸããªã¢ãŸãŒã«éä¹³å€ã®PHã調æŽãã
æ²éãããéå°ã®å¡©ãé€å»ããããã®åŸPHã6.0
ã«åãããåé400ïœã®ãã³ãŸããªã¢ãŸãŒã«éä¹³
å€ãåŸãã ãã®ãã³ãŸããªã¢ãŸãŒã«éä¹³å€ãçšããŠæ¬¡ã®æ
å æ§å¡åžç©ã調補ããã (a) æ²èåéä¹³å€ïŒå®æœäŸïŒèšèŒã®ãã®ïŒ 20ïœ (b) ãã³ãŸããªã¢ãŸãŒã«éä¹³å€ 10ïœ (c) è²çŽ äŸäžæ§ç©è³ªã®åæ£ç©ïŒå®æœäŸïŒèšèŒã®ã
ã®ïŒ 33ïœ (d) 次ã«ç€ºãååç©ã®ïŒïŒ 氎溶液 10ml (e) 次ã«ç€ºãååç©ã®10ïŒ æ°Žæº¶æ¶² ïŒml H2NSO2NïŒCH3ïŒ2 (f) æ¬çºæã®å¡©åºãã¬ã«ãŒãµãŒ(1) 2.5ïœããšã¿
ããŒã«25mlã«æº¶ããã溶液 以äžã®(a)ã(f)ãæ··åãããã®åŸã¯å®æœäŸïŒãšå š
ãåæ§ãªæäœã§è©Šæãäœæãåæ§ã«åŠçãããã
ã®çµæãäžèšã«ç€ºããã è©Š æ æ倧æ¿åºŠ æå°æ¿åºŠ æ¬çºæã®å¡©åºãã¬ã«ãŒãµãŒ (1)å«æ 2.38 0.21 å¡©åºãã¬ã«ãŒãµãŒãªã 0.30 0.03 æ¬çºæã®å¡©åºãã¬ã«ãŒãµãŒãé«ãæ¿åºŠãäžãã
ããšãããã€ãã
ãæ倧æ¿åºŠãäžããããšãããã€ãã å®æœäŸ ïŒ æ¬¡ã«ææ©éå¡©é žåå€ãçšãããšãã®å®æœäŸã瀺
ãã ãã³ãŸããªã¢ãŸãŒã«éä¹³å€ã®èª¿è£œæ³ ãŒã©ãã³28ïœãšãã³ãŸããªã¢ãŸãŒã«13.2ïœãæ°Ž
3000mlã«æº¶è§£ããããã®æº¶æ¶²ã40âã«ä¿ã¡æ¹æã
ãããã®æº¶æ¶²ã«ç¡é žé17ïœãæ°Ž100mlã«æº¶ããã
液ãïŒåéã§å ããã ãã®ãã³ãŸããªã¢ãŸãŒã«éä¹³å€ã®PHã調æŽãã
æ²éãããéå°ã®å¡©ãé€å»ããããã®åŸPHã6.0
ã«åãããåé400ïœã®ãã³ãŸããªã¢ãŸãŒã«éä¹³
å€ãåŸãã ãã®ãã³ãŸããªã¢ãŸãŒã«éä¹³å€ãçšããŠæ¬¡ã®æ
å æ§å¡åžç©ã調補ããã (a) æ²èåéä¹³å€ïŒå®æœäŸïŒèšèŒã®ãã®ïŒ 20ïœ (b) ãã³ãŸããªã¢ãŸãŒã«éä¹³å€ 10ïœ (c) è²çŽ äŸäžæ§ç©è³ªã®åæ£ç©ïŒå®æœäŸïŒèšèŒã®ã
ã®ïŒ 33ïœ (d) 次ã«ç€ºãååç©ã®ïŒïŒ 氎溶液 10ml (e) 次ã«ç€ºãååç©ã®10ïŒ æ°Žæº¶æ¶² ïŒml H2NSO2NïŒCH3ïŒ2 (f) æ¬çºæã®å¡©åºãã¬ã«ãŒãµãŒ(1) 2.5ïœããšã¿
ããŒã«25mlã«æº¶ããã溶液 以äžã®(a)ã(f)ãæ··åãããã®åŸã¯å®æœäŸïŒãšå š
ãåæ§ãªæäœã§è©Šæãäœæãåæ§ã«åŠçãããã
ã®çµæãäžèšã«ç€ºããã è©Š æ æ倧æ¿åºŠ æå°æ¿åºŠ æ¬çºæã®å¡©åºãã¬ã«ãŒãµãŒ (1)å«æ 2.38 0.21 å¡©åºãã¬ã«ãŒãµãŒãªã 0.30 0.03 æ¬çºæã®å¡©åºãã¬ã«ãŒãµãŒãé«ãæ¿åºŠãäžãã
ããšãããã€ãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ æ¯æäœäžã«å°ãªããšãæå æ§ããã²ã³åéã
ãã€ã³ããŒãæå æ§ããã²ã³åéã«å¯ŸããŠéå æ§
ã§ããããã€æå æ§ããã²ã³åéãšå ç±ã«ããå
å¿ããŠèŠªæ°Žæ§è²çŽ ãæŸåºããè²çŽ äŸäžæ§ç©è³ªäžŠã³
ã«äžèšäžè¬åŒ(A)ããã³ïŒãŸãã¯äžè¬åŒ(B)ã§ç€ºãå¡©
åºãã¬ã«ãŒãµãŒãæããç±çŸåã«ã©ãŒæå ææã äžè¬åŒ(A)ãåŒã äžè¬åŒ(B)ãåŒã ããã§A1ïŒA2ïŒA5ïŒA6ïŒA7ïŒA8ã¯ãããã
æ°ŽçŽ ååãã¢ã«ãã«åºã眮æã¢ã«ãã«åºãã·ã¯ã
ã¢ã«ãã«åºãã¢ã«ã±ãã«åºãã¢ã©ã«ãã«åºãã¢ãª
ãŒã«åºã眮æã¢ãªãŒã«åºãã¢ã·ã«åºåã³è€çŽ ç°åŒ
åºã®äžããéžã°ãã眮æåºãè¡šããããŸãA1ãš
A2ã¯é£çµããŠç°ã圢æããŠããŠããããããã«
A5ïŒA6ïŒA7ïŒA8ã¯ãã®äžã®ïŒã€ãé£çµããŠç°ã
圢æããŠããŠãããã A3ïŒA4ã¯ããããæ°ŽçŽ ååãã¢ã«ãã«åºã眮
æã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºãã¢ã©ã«ãã«åº
ãè¡šããããŸãA3ãšA4ã¯é£çµããŠç°ã圢æããŠ
ããŠããããã ãåŒããäºéçµåãšãªã€ãŠã€ããåºã圢æã ãŠããŠãããã
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58043860A JPS59168440A (ja) | 1983-03-16 | 1983-03-16 | ç±çŸåã«ã©âæå ææ |
DE8484301832T DE3463978D1 (en) | 1983-03-16 | 1984-03-16 | Heat developable color light-sensitive materials |
EP84301832A EP0120661B1 (en) | 1983-03-16 | 1984-03-16 | Heat developable color light-sensitive materials |
US06/590,396 US4511650A (en) | 1983-03-16 | 1984-03-16 | Heat developable color light-sensitive materials with base releasors |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58043860A JPS59168440A (ja) | 1983-03-16 | 1983-03-16 | ç±çŸåã«ã©âæå ææ |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS59168440A JPS59168440A (ja) | 1984-09-22 |
JPH0251498B2 true JPH0251498B2 (ja) | 1990-11-07 |
Family
ID=12675448
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP58043860A Granted JPS59168440A (ja) | 1983-03-16 | 1983-03-16 | ç±çŸåã«ã©âæå ææ |
Country Status (4)
Country | Link |
---|---|
US (1) | US4511650A (ja) |
EP (1) | EP0120661B1 (ja) |
JP (1) | JPS59168440A (ja) |
DE (1) | DE3463978D1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04135012U (ja) * | 1991-06-07 | 1992-12-16 | æ ªåŒäŒç€Ÿã±ã³ãŠãã | ã°ã©ãã€ãã¯ã€ã³ã©ã€ã¶è£ 眮 |
JPH0574018U (ja) * | 1991-02-20 | 1993-10-08 | ããªã¹ã¿ãŒé»æ©æ ªåŒäŒç€Ÿ | é³é¿çšãã£ãžã¿ã«ä¿¡å·åŠçè£ çœ® |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60230133A (ja) * | 1984-04-27 | 1985-11-15 | Fuji Photo Film Co Ltd | ç±çŸåæå ææ |
US4710631A (en) * | 1984-08-28 | 1987-12-01 | Fuji Photo Film Co., Ltd. | Temperature compensation for a semiconductor light source used for exposure of light sensitive material |
US4775613A (en) | 1985-03-30 | 1988-10-04 | Fuji Photo Film Co., Ltd. | Heat-developable light-sensitive material |
JPH083621B2 (ja) | 1985-07-31 | 1996-01-17 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ç»å圢ææ¹æ³ |
JPH0690475B2 (ja) * | 1986-02-14 | 1994-11-14 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéåçæå ææ |
US5324627A (en) * | 1992-12-21 | 1994-06-28 | Minnesota Mining And Manufacturing Company | Tetra-alkylammonium phenylsulfonylacetate thermal-dye-bleach agents |
US5314795A (en) * | 1992-12-21 | 1994-05-24 | Minnesota Mining And Manufacturing Company | Thermal-dye-bleach construction comprising a polymethine dye and a thermal carbanion-generating agent |
US5300420A (en) * | 1993-06-01 | 1994-04-05 | Minnesota Mining And Manufacturing Company | Stabilizers for photothermography with nitrile blocking groups |
US5395747A (en) * | 1993-12-20 | 1995-03-07 | Minnesota Mining & Manufacturing Company | Stabilized thermal-dye-bleach constructions |
US5492805A (en) * | 1994-06-30 | 1996-02-20 | Minnesota Mining And Manufacturing Company | Blocked leuco dyes for photothermographic elements |
US5492804A (en) * | 1994-06-30 | 1996-02-20 | Minnesota Mining And Manufacturing Company | Chromogenic leuco redox-dye-releasing compounds for photothermographic elements |
US5492803A (en) * | 1995-01-06 | 1996-02-20 | Minnesota Mining And Manufacturing Company | Hydrazide redox-dye-releasing compounds for photothermographic elements |
ES2400633T3 (es) | 2008-11-24 | 2013-04-11 | Basf Se | Composición curable que comprende una base termolatente |
EP2199856B1 (en) | 2008-12-18 | 2013-08-07 | Agfa Graphics N.V. | Cationic radiation curable compositions |
US11401370B2 (en) | 2018-02-26 | 2022-08-02 | Nippon Kayaku Kabushiki Kaisha | Base proliferating agent, and base-reactive resin composition containing said base proliferating agent |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3220846A (en) * | 1960-06-27 | 1965-11-30 | Eastman Kodak Co | Use of salts of readily decarboxylated acids in thermography, photography, photothermography and thermophotography |
US4088496A (en) * | 1976-12-22 | 1978-05-09 | Eastman Kodak Company | Heat developable photographic materials and process |
JPS57179840A (en) * | 1981-04-30 | 1982-11-05 | Fuji Photo Film Co Ltd | Heat developing color photosensitive material |
JPS57198458A (en) * | 1981-06-01 | 1982-12-06 | Fuji Photo Film Co Ltd | Heat developing color photosensitive material |
-
1983
- 1983-03-16 JP JP58043860A patent/JPS59168440A/ja active Granted
-
1984
- 1984-03-16 DE DE8484301832T patent/DE3463978D1/de not_active Expired
- 1984-03-16 EP EP84301832A patent/EP0120661B1/en not_active Expired
- 1984-03-16 US US06/590,396 patent/US4511650A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0574018U (ja) * | 1991-02-20 | 1993-10-08 | ããªã¹ã¿ãŒé»æ©æ ªåŒäŒç€Ÿ | é³é¿çšãã£ãžã¿ã«ä¿¡å·åŠçè£ çœ® |
JPH04135012U (ja) * | 1991-06-07 | 1992-12-16 | æ ªåŒäŒç€Ÿã±ã³ãŠãã | ã°ã©ãã€ãã¯ã€ã³ã©ã€ã¶è£ 眮 |
Also Published As
Publication number | Publication date |
---|---|
EP0120661A2 (en) | 1984-10-03 |
JPS59168440A (ja) | 1984-09-22 |
US4511650A (en) | 1985-04-16 |
DE3463978D1 (en) | 1987-07-02 |
EP0120661A3 (en) | 1984-11-21 |
EP0120661B1 (en) | 1987-05-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPH0245181B2 (ja) | Netsugenzokaraakankozairyo | |
JPH0245180B2 (ja) | ||
JPS6215853B2 (ja) | ||
JPH0140974B2 (ja) | ||
JPH0251494B2 (ja) | ||
JPH0251498B2 (ja) | ||
JPH0414338B2 (ja) | ||
JPH0411019B2 (ja) | ||
JPH0115054B2 (ja) | ||
JPH0362258B2 (ja) | ||
JPH0362257B2 (ja) | ||
JPH0143946B2 (ja) | ||
JPH0369093B2 (ja) | ||
JPH0434736B2 (ja) | ||
JPH0362255B2 (ja) | ||
EP0123904B2 (en) | Heat developable photographic material | |
JPH0374376B2 (ja) | ||
JPH0554668B2 (ja) | ||
JPS6261940B2 (ja) | ||
JPH0413704B2 (ja) | ||
JPH0374377B2 (ja) | ||
JPH0554670B2 (ja) | ||
JPH0374379B2 (ja) | ||
JPH0362259B2 (ja) | ||
JPH0368373B2 (ja) |