JPH0251477B2 - - Google Patents
Info
- Publication number
- JPH0251477B2 JPH0251477B2 JP58234855A JP23485583A JPH0251477B2 JP H0251477 B2 JPH0251477 B2 JP H0251477B2 JP 58234855 A JP58234855 A JP 58234855A JP 23485583 A JP23485583 A JP 23485583A JP H0251477 B2 JPH0251477 B2 JP H0251477B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- additive
- nitrogen
- carbon atoms
- residue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000654 additive Substances 0.000 claims description 50
- 230000000996 additive effect Effects 0.000 claims description 39
- 239000000295 fuel oil Substances 0.000 claims description 33
- 239000002253 acid Substances 0.000 claims description 19
- -1 alkylene dicarboxylic acid Chemical compound 0.000 claims description 18
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims description 16
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 15
- 125000005265 dialkylamine group Chemical group 0.000 claims description 14
- 125000002947 alkylene group Chemical group 0.000 claims description 12
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 12
- 229930195729 fatty acid Natural products 0.000 claims description 12
- 239000000194 fatty acid Substances 0.000 claims description 12
- 239000007795 chemical reaction product Substances 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 11
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 239000012188 paraffin wax Substances 0.000 claims description 10
- 150000002148 esters Chemical class 0.000 claims description 8
- 150000004665 fatty acids Chemical class 0.000 claims description 8
- 150000001735 carboxylic acids Chemical class 0.000 claims description 7
- 125000005472 straight-chain saturated fatty acid group Chemical group 0.000 claims description 7
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 6
- 150000003628 tricarboxylic acids Chemical class 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 3
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 229920006226 ethylene-acrylic acid Polymers 0.000 claims description 2
- 150000008064 anhydrides Chemical class 0.000 claims 1
- 239000012530 fluid Substances 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 238000009835 boiling Methods 0.000 description 21
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 17
- 239000000203 mixture Substances 0.000 description 14
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 13
- 239000003921 oil Substances 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 12
- 230000000694 effects Effects 0.000 description 10
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 10
- 235000021357 Behenic acid Nutrition 0.000 description 9
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 9
- 229940116226 behenic acid Drugs 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 8
- 238000005886 esterification reaction Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 230000032050 esterification Effects 0.000 description 5
- 150000004671 saturated fatty acids Chemical class 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 4
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 4
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 239000005642 Oleic acid Substances 0.000 description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical class NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000010771 distillate fuel oil Substances 0.000 description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 3
- 239000003350 kerosene Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- 238000007127 saponification reaction Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- 235000021353 Lignoceric acid Nutrition 0.000 description 2
- CQXMAMUUWHYSIY-UHFFFAOYSA-N Lignoceric acid Natural products CCCCCCCCCCCCCCCCCCCCCCCC(=O)OCCC1=CC=C(O)C=C1 CQXMAMUUWHYSIY-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- 229920002582 Polyethylene Glycol 600 Polymers 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000005690 diesters Chemical class 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- FARYTWBWLZAXNK-WAYWQWQTSA-N ethyl (z)-3-(methylamino)but-2-enoate Chemical compound CCOC(=O)\C=C(\C)NC FARYTWBWLZAXNK-WAYWQWQTSA-N 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- XMHIUKTWLZUKEX-UHFFFAOYSA-N hexacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O XMHIUKTWLZUKEX-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- UTOPWMOLSKOLTQ-UHFFFAOYSA-N octacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001228 polyisocyanate Polymers 0.000 description 2
- 239000005056 polyisocyanate Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 235000003441 saturated fatty acids Nutrition 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 238000010583 slow cooling Methods 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 150000005691 triesters Chemical class 0.000 description 2
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 2
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 2
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- 229920003067 (meth)acrylic acid ester copolymer Polymers 0.000 description 1
- YAXKTBLXMTYWDQ-UHFFFAOYSA-N 1,2,3-butanetriol Chemical compound CC(O)C(O)CO YAXKTBLXMTYWDQ-UHFFFAOYSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- LNETULKMXZVUST-UHFFFAOYSA-N 1-naphthoic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1 LNETULKMXZVUST-UHFFFAOYSA-N 0.000 description 1
- SZSSMFVYZRQGIM-UHFFFAOYSA-N 2-(hydroxymethyl)-2-propylpropane-1,3-diol Chemical compound CCCC(CO)(CO)CO SZSSMFVYZRQGIM-UHFFFAOYSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- WMRCTEPOPAZMMN-UHFFFAOYSA-N 2-undecylpropanedioic acid Chemical compound CCCCCCCCCCCC(C(O)=O)C(O)=O WMRCTEPOPAZMMN-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 239000005643 Pelargonic acid Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- ZNFNDZCXTPWRLQ-UHFFFAOYSA-N butane-1,1,1-tricarboxylic acid Chemical compound CCCC(C(O)=O)(C(O)=O)C(O)=O ZNFNDZCXTPWRLQ-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000003747 fuel oil additive Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- XYXCXCJKZRDVPU-UHFFFAOYSA-N hexane-1,2,3-triol Chemical compound CCCC(O)C(O)CO XYXCXCJKZRDVPU-UHFFFAOYSA-N 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- HKUFIYBZNQSHQS-UHFFFAOYSA-N n-octadecyloctadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCNCCCCCCCCCCCCCCCCCC HKUFIYBZNQSHQS-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Liquid Carbonaceous Fuels (AREA)
Description
æ¬çºæã¯çææ²¹çšæµåæ§æ¹è¯æ·»å å€ã«é¢ããã
ã®ã§ããã è¿å¹Žçææ²¹ç¹ã«è»œæ²¹ã®å Žåã¯ç¯æ²¹ã®æºçãªéèŠ
ããŸããªãããã«ãäœæ²žç¹éšåã®å²åãæžå°ãã
沞ç¹ç¯å²ãçãããããåŸãªãç¶æ³ã«ãªãã€ã€ã
ãããã®ããã«è»œæ²¹ã®æ²žç¹ç¯å²ãçãããããšã«
ãã€ãŠãã®äžã«å«ãŸããïœâãã©ãã€ã³ã®ççŽ é
ååžãçããªããåŸæ¥åºã䜿çšãããŠãããšãã¬
ã³âé ¢é žããã«ç³»ãã¯ãã倧éšåã®æµåæ§æ¹è¯æ·»
å å€ãæ·»å ããŠããããçææ²¹ã®å€§ããªçšéãå
ããå çæ©é¢ã®çæãã€ã«ã¿ãŒã®ç®ãè©°ãããšã
ãå±éºãªçŸè±¡ãæ¹ãèµ·ããäœæž©ã«ããããã€ã«ã¿
ãŒã®ç®è©°æž©åºŠãäœäžãããããšãäžå¯èœãªå Žåã
å€ããªã€ãŠããããã®åé¡ã解決ãããããã§ã«
ããããã®æ¹çãåãããŠãããããããããŸã§
ã®ãšãããã®ãããªçã沞ç¹ç¯å²ã®çææ²¹ã«å¯Ÿã
ãŠãCEPPïŒäœæž©æ¿Ÿéåšç®è©°ãç¹ãIP306ïŒãäœäž
ãããããšãã§ããŠãæµåç¹ãéäžãããèœåã
åææã«åããæµåæ§æ¹è¯å€ã¯èŠåºãããŠããª
ãã æ¬çºæè ãã¯äžèšã®æ²žç¹ç¯å²ãçãçææ²¹ã«å¯Ÿ
ããŠããããCEPPéäžèœã瀺ãããã€ããçšåºŠ
ã®æµåç¹ïŒPPïŒéäžèœãå Œãåããæµåæ§æ¹è¯
æ·»å å€ãéçºãã¹ãç 究ãéããçµææ¬çºæã«å°
éãããããªãã¡ãæ¬çºæã¯(A)ã¢ã«ã«ã³ããªãªãŒ
ã«ã®ããªãªãã·ã¢ã«ãã¬ã³ãšãŒãã«ïŒè©²ãšãŒãã«
ã®å¹³åååéã¯250ã6000ã§ããïŒãšççŽ æ°14ã
30ã®çŽé飜åèèªé ž(c)ãŸãã¯è©²èèªé ž(c)ãšä»ã®ã«
ã«ãã³é žãšã®æ··åã«ã«ãã³é žïŒcâ²ïŒãšã®å®å šãšã¹
ãã«ïŒããã³å¿ èŠã«ãã(B)ã¢ã«ã±ãã«ã³ãã¯é žã®
å«çªçŽ èªå°äœãå¡©çŽ åãã©ãã€ã³ãšããã¿ã¬ã³ãš
ã®çž®åç©ãé·éã¢ã«ãã¬ã³ãžã«ã«ãã³é žã®å«çªçŽ
èªå°äœãããªã«ã«ãã³é žã®å«çªçŽ èªå°äœããã³ãž
ã€ãœã·ã¢ããŒãååç©ãšãžã¢ã«ãã«ã¢ãã³ãšã®å°¿
çŽ ããã³ïŒãŸãã¯ããŠãŒã¬ããèªå°äœãããªã矀
ããéžã°ããååç©ãå«æããããšãç¹åŸŽãšãã
çææ²¹çšæµåæ§æ¹è¯æ·»å å€ã§ããã æ¬çºæã®æµåæ§æ¹è¯æ·»å å€ïŒä»¥äžãæ¬çºæã®æ·»
å å€ãšãããïŒã®(A)æåã§ããã¢ã«ã«ã³ããªãªãŒ
ã«ã®ããªãªãã·ã¢ã«ãã¬ã³ãšãŒãã«ãšççŽ æ°14ã
30ã®çŽé飜åèèªé žãå¿ é ãšããŠå«ãã«ã«ãã³é ž
ãšã®å®å šãšã¹ãã«ãšããŠã¯äžè¬åŒ ïŒåŒäžãã¯ã¢ã«ã«ã³ããªãªãŒã«ã®æ®åºïŒïŒ¡ã¯ç
çŽ æ°ïŒãïŒã®ã¢ã«ãã¬ã³åºïŒRâ²ã¯ã«ã«ãã³é žæ®
åºã§ãããïŒåã®Râ²ã®ãã¡å°ãªããšãïŒåã¯ç
çŽ æ°14ã30ã®çŽé飜åèèªé žã®æ®åºã§ãããïœã¯
âãïŒOAïŒoOHã3ã®å¹³åååéã250ã6000ã«ãª
ãæ°ã§ãããã ã§ç€ºãããååç©ããããããã äžè¬åŒ(1)ã«ãããŠãæ®åºïŒ²ã圢æããã¢ã«ã«ã³
ããªãªãŒã«ãšããŠã¯ã°ãªã»ãªã³ãããªã¡ãããŒã«
ãšã¿ã³ãããªã¡ãããŒã«ãããã³ãããªã¡ãããŒ
ã«ãã¿ã³ãïŒïŒïŒïŒïŒâãã¿ã³ããªãªãŒã«ãïŒïŒ
ïŒïŒïŒâãã¿ã³ããªãªãŒã«ãïŒïŒïŒïŒïŒâãããµ
ã³ããªãªãŒã«ããã³ãããã®äºçš®ä»¥äžã®æ··åç©ã
ãããããããããã®ãã¡ã§å¥œãŸãããã®ã¯ã°ãª
ã»ãªã³ãããªã¡ãããŒã«ããã³ããªã¡ãããŒã«ã
ããã³ã§ããã äžè¬åŒ(1)ã«ãããŠãæ®åºïŒ²ãïŒäŸ¡ãŸãã¯ïŒäŸ¡ã¢
ã«ã³ãŒã«ã®æ®åºã®å Žåã¯PPéäžèœãã»ãšãã©ãª
ãCEPPéäžèœãäžååã§ããã ã®ççŽ æ°ïŒâïŒã®ã¢ã«ãã¬ã³åºãšããŠã¯ãšã
ã¬ã³ããããã¬ã³ãããã¬ã³ïŒïŒïŒïŒâïŒïŒïŒïŒ
âïŒïŒïŒïŒâããã³ïŒïŒïŒâïŒåºããããããã
ãããã¯ïŒçš®ä»¥äžã§ãã€ãŠãããããããã®ãã¡
奜ãŸããã®ã¯ãšãã¬ã³åºããã³ãããã¬ã³åºã§ã
ãã äžè¬åŒ(1)ã«ãããŠãïŒåã®Râ²ã®ãã¡å°ãªããš
ãïŒåãå ããççŽ æ°14ã30ã®çŽé飜åèèªé žã®
æ®åºã圢æããèèªé žãšããŠã¯ããªã¹ãã³é žãã
ã«ããã³é žãã¹ãã¢ãªã³é žãã¢ã©ãã³é žãããã³
é žããªã°ãã»ãªã³é žãã»ããã³é žãã¢ã³ã¿ã³é žã
ã¡ãªã·ã³é žãªã©ããããã奜ãŸãããã®ã¯ãã«ã
ãã³é žãã¹ãã¢ãªã³é žãã¢ã©ãã³é žãããã³é žã
ããã³ãªã°ãã»ãªã³é žã§ããããããã¯åç¬ãŸã
ã¯æ··åç©ã§ãã€ãŠããããããšãã°çèã®ãããª
倩ç¶æ²¹èãå æ°Žå解ããŠåŸãããèèªé žãæ°ŽçŽ æ·»
å ããŠåŸãããæ··åèèªé žããã®ãŸãŸå©çšããã
ãšãã§ããã Râ²ã®ã«ã«ãã³é žæ®åºã圢æããä»ã®ã«ã«ãã³
é žãšããŠççŽ æ°ïŒã30ã®ã«ã«ãã³é žããšãã°ççŽ
æ°ïŒã13ã®çŽé飜åèèªé žïŒé ¢é žãããããªã³
é žãé ªé žãã«ããã³é žãã«ããªã«é žããã©ã«ãŽã³
é žãã©ãŠãªã³é žãªã©ïŒãäžé£œåèèªé žïŒãªã¬ã€ã³
é žããªããŒã«é žããªãã¬ã€ã³é žãªã©ïŒããªãã·é ž
ïŒã°ãªã³ãŒã«é žããªã·ãã¬ã€ã³é žãªã©ïŒãåå²èèª
é žïŒïŒâãšãã«ãããµã³é žãã€ãœã¹ãã¢ãªã³é žãª
ã©ïŒãè³éŠæã«ã«ãã³é žïŒå®æ¯éŠé žãããã¿ã¬ã³
ã«ã«ãã³é žãªã©ïŒããã³ãããã®ïŒçš®ä»¥äžã®æ··å
ç©ããããããããããã®ãã¡å¥œãŸããã®ã¯äžèš
çŽé飜åèèªé žããã³äžé£œåèèªé žã§ããã äžè¬åŒ(1)ã«ãããŠïŒåã®Râ²ã®ãã¡ççŽ æ°14ã
30ã®èèªæçŽé飜åã«ã«ãã³é žã®æ®åºãå«ãŸããª
ãå Žåã¯CFPPããã³PPã®äœäžå¹æãå°ãªãã ïœã¯ïŒ²âãïŒOAïŒoOHã3ã®å¹³åååéã250ã
6000ã«ãªãæ°ã奜ãŸããã¯250ã2000ã«ãªãæ°ã§
ãããïŒïŒã€ã®ïœã¯åäžã§ãç°ãªã€ãŠããŠãã
ããïŒãŸãïœã¯OHåœãã®å¹³åååéã83以äžãª
ãæ°ã§ãããïœã250ãããäœãå¹³åååéã«ãª
ãæ°ã®å ŽåããŸãOHåœãã®å¹³åååéã83æªæº
ãšãªãæ°ã®å Žåäžè¬ã«çææ²¹ã«å¯Ÿãã溶解æ§ã¯è¯
奜ã§ãããæ¬æ·»å å€ã®éèŠãªæ§èœã§ããCFPPé
äžèœãååã§ãªãããŸãååé6000ãè¶ããå Žå
ãçææ²¹ã«å¯Ÿãã溶解æ§ãååã§ãªãããããã¯
溶解æ§ãä¿ãããŠãCFPPéäžèœãååã§ãªãã
ååéã®ç¯å²ã¯250ã2000ã«ãããŠã¯éåžžã«ãã
ããCFPPéäžèœã瀺ããšå ±ã«PPéäžèœãå Œã
åãžãããçææ²¹ã«å¯ŸããŠè¯å¥œãªæº¶è§£æ§ãä¿æã
ãŠããã äžè¬åŒ(1)ã§ç€ºãããååç©ã¯å®å šãšã¹ãã«ã§ãª
ããã°ãªããªããååç©ãéšåãšã¹ãã«ïŒã¢ããŸ
ãã¯ãžãšã¹ãã«ïŒã®å Žåã¯CFPPããã³PPã®äœ
äžå¹æãå°ãªãã ãŸããæ¬çºæã«ãããŠ(A)æåãšããŠã¯ãäžè¬åŒ
(1)ã§ç€ºãããã«ä»£ããŠããŸãã¯ãããšãšãã«ãã«
ã«ãã³é žã®äžéšãšããŠã¢ãžãã³é žãã»ããã³é žã
ããã«ã³ãžã«ã«ãã³é žããã¿ã³ããªã«ã«ãã³é žãª
ã©ã®ããªã«ã«ãã³é žããçææ²¹ã«å¯Ÿãã溶解æ§ã
æªåããªãç¯å²ã«ãããŠïŒéåžžã«ã«ãã³é žæåäž
25ã¢ã«ïŒ 以äžïŒäœµçšãããã®ã§ãããããã®ãã
ãªãšã¹ãã«ãšããŠã¯ãäŸãã°äžè¬åŒ ãåŒäžRâ³ã¯ããªã«ã«ãã³é žæ®åºïŒïœã¯ïŒïŒïŒïŒ
âŠïŒããªã«ã«ãã³é žã®å¡©åºåºŠïŒïŒïŒ²ïŒRâ²ïŒïŒ¡ïŒïœ
ã¯äžè¬åŒ(1)ã«ããããšåãã§ããããã§ç€ºããã
ååç©ãå«æãããã®ããããããã (A)æåã¯çš®ã ã®æ¹æ³ã«ãã€ãŠè£œé ããããšãã§
ãããããšãã°å ããã¢ã«ã«ã³ããªãªãŒã«ããã®
ãŸãŸãããã¯åå¿ç³»ã«äžæŽ»æ§ãªé©åœãªæº¶åªã«æº¶è§£
ããäžè¬ã«èæ§ã¢ã«ã«ãªã®ãããªè§Šåªãå ããŠå
ç±äžã§ççŽ æ°ïŒãïŒã®ã¢ã«ãã¬ã³ãªãã·ãïŒãšã
ã¬ã³ãªãã·ãããããã¬ã³ãªãã·ããããã¬ã³ãª
ãã·ããªã©ïŒã液ç¶ãŸãã¯æ°ç¶ã§å ããåå¿ãã
ããïŒçš®ä»¥äžã®ã¢ã«ãã¬ã³ãªãã·ããåå¿ããã
å Žåã«ã¯ãïŒçš®ä»¥äžã®ã¢ã«ãã¬ã³ãªãã·ããæ··å
ããŠåå¿ãããã©ã³ãã åå éåã§ãããããŸ
ããæåã«ïŒçš®ã®ã¢ã«ãã¬ã³ãªãã·ããåå¿ãã
次ãã§ä»ã®ã¢ã«ãã¬ã³ãªãã·ããé 次ä»å ããã
ãããã¯ä»å éåãè¡ãªã€ãŠãããããã®ããã«
ããŠåŸãããããªãªãã·ã¢ã«ãã¬ã³ãšãŒãã«ã¯ã
ã®ãŸãŸãŸãã¯ç²Ÿè£œããŠæªåå¿ç©è³ªãŸãã¯è§Šåªãé€
å»ããã®ã¡ãççŽ æ°ïŒã30ã®ã«ã«ãã³é žãšéåžžç¡«
é žãªã©ã®è§Šåªãå ããŠå ç±äžã§ãšã¹ãã«åããã ãšã¹ãã«åã«ãããŠãããªãªãã·ã¢ã«ãã¬ã³ãš
ãŒãã«ã®ããããã·ã«åºãšã«ã«ãã³é žã®ã«ã«ãã
ã·ã«åºã®åœéæ¯ã¯å®è³ªçã«ïŒïŒïŒã奜ãŸããããŸ
ãããªãªãã·ã¢ã«ãã¬ã³ãšãŒãã«ïŒã¢ã«ã«å¯ŸããŠ
ççŽ æ°14â30ã®çŽé飜åèèªé žã¯ïŒã¢ã«ä»¥äžã奜
ãŸããã¯ïŒãïŒã¢ã«ã䜿çšããã ãšã¹ãã«åã«éããŠã¯ä»ã®ã«ã«ãã³é žã§ãšã¹ã
ã«åããã®ã¡ççŽ æ°14ã30ã®çŽé飜åèèªé žãå
ããŠåã³ãšã¹ãã«ååå¿ãè¡ãªã€ãŠãéã«æåã«
ççŽ æ°14ã30ã®çŽé飜åèèªé žã§ãšã¹ãã«åãã
ã®ã¡ä»ã®ã«ã«ãã³é žã§ãšã¹ãã«åããŠããŸããä»
ã®ã«ã«ãã³é žãšã®ççŽ æ°14ã30ã®çŽé飜åèèªé ž
ãå«ãæ··åç©ãçšããŠãšã¹ãã«åããŠããããå
å¿ã®é²è¡ã¯é žäŸ¡ãããããã·ã«äŸ¡ãã±ã³å䟡ãªã©
ã®è¿œè·¡ãè¡ãªãããšã«ãã€ãŠç¢ºèªã§ããã ãã®ããã«ããŠåŸããã(A)æåã«ã¯å°éã®æªå
å¿ç©ãå«ãããšããããéåžžã¯é€å»ããªããŠãäœ
ãæ¯éãªã䜿çšããããšãã§ãããæ¬çºæã«ãã
ã(A)æåã¯äœ¿çšããã¢ã«ã«ã³ããªãªãŒã«ãã¢ã«ã
ã¬ã³ãªãã·ãããã³ã«ã«ãã³é žã®çš®é¡ãããªãšãŒ
ãã«ããªãªãŒã«ã®ååéãªã©ã«ãã€ãŠç¶æ ã¯ç°ãª
ããéåžžãç²çš ãªæ¶²ç¶ãªããã¯åºç¶ã§ãããç³æ²¹
系溶å€ãã¢ã«ã³ãŒã«é¡ããšã¹ãã«é¡ãªã©ã®æº¶å€ã«
ã¯å¯æº¶ã§ãããæ°Žã«å¯ŸããŠã¯åæ£ããããšã¯ãã€
ãŠãäžæº¶ã§ããã æ¬çºæã«ãããŠã¯ãå¿ èŠã«ãã(B)æåãšããŠã¢
ã«ã±ãã«ã³ãã¯é žã®å«çªçŽ èªå°äœãå¡©çŽ åãã©ã
ã€ã³ãšããã¿ã¬ã³ãšã®çž®åç©ãé·éã¢ã«ã«ã³ãžã«
ã«ãã³é žã®å«çªçŽ èªå°äœãé·éã¢ã«ãã¬ã³ãžã«ã«
ãã³é žã®å«çªçŽ èªå°äœãããªã«ã«ãã³é žã®å«çªçŽ
èªå°äœé žããžã€ãœã·ã¢ããŒãååç©ãšãžã¢ã«ãã«
ã¢ãã³ãšã®å°¿çŽ ããã³ïŒãŸãã¯ããŠãŒã¬ããèªå°
äœã®ããããïŒçš®ãŸãã¯ïŒçš®ä»¥äžãåèšã®(A)ãšäœµ
çšããããšãã§ããã (B)æåã䜵çšããããšã«ãã€ãŠPPéäžèœãå©
é·ããããšãã倧ããªæåŸ ãããããããªããç
ææ²¹ã®æµåæ§åäžå€ãšããŠãšãã¬ã³âé ¢é žããã«
å ±éåäœããšãã¬ã³âã¢ã¯ãªã«é žãšã¹ãã«å ±éå
äœãå¡©çŽ åãã©ãã€ã³ãé·éã¢ã«ãã«åºãå«ã
ïŒã¡ã¿ïŒã¢ã¯ãªã«é žå ±éåäœãªã䜿çšãããŠãã
ããæ¬çºæã«ããã(A)æåãšãããã®éåäœåæµ
åæ§åäžå€ã䜵çšããããšãã§ãããããã®å Žå
ã«ã¯PPéäžèœãå©é·ãããå¹æã¯ã(B)æåã䜵
çšããå Žåã»ã©ã«èªããããã(A)æåã®ç¹é·ã§ã
ãçã沞ç¹ç¯å²ããã€çææ²¹ã«å¯Ÿããè¯å¥œãª
CFPPéäžèœãã(B)æå䜵çšã®å Žåã»ã©ååã«ã¯
çºæ®ã§ããªãã (B)æåã®ã¢ã«ã±ãã«ã³ãã¯é žã®å«çªçŽ èªå°äœé ž
ãšããŠC4ãC28ã®ã¢ã«ã±ãã«åºãå«ãã¢ã«ã±ãã«
ã³ãã¯é žãšã¢ããŸãã¯ãžã¢ã«ãã«ã¢ãã³ãïŒããªïŒ
ã¢ã«ãã¬ã³ããªã¢ãã³ãšã®åå¿ç©ïŒã¢ãããã
ã³ïŒãŸãã¯å¡©ïŒãããããã奜ãŸãããã«ã¯C14
ãC22ã®ã¢ã«ã±ãã«åºãå«ãã¢ã«ã±ãã«ã³ãã¯é ž
ãšC14ãC20ã®ã¢ã«ãã«åºãïŒåãã€ãžã¢ã«ãã«ã¢
ãã³ãšã®åå¿ç©ã§ããã å¡©çŽ åãã©ãã€ã³ãšããã¿ã¬ã³ãšã®çž®åç©ãšã
ãŠã¯C8以äžã®ãã©ãã€ã³ã®å¡©çŽ åç©ãšããã¿ã¬
ã³ãšã®çž®åç©ãæããããããã®ååéã¯éåžž
2000ã8000ã®ç¯å²ã§ãããé·éã¢ã«ãã¬ã³ãžã«ã«
ãã³é žã®å«çªçŽ èªå°äœãšããŠã¯ç¹éæ56â36588
å·å ¬å ±ã«èšèŒã®ãã®ãæãããããå ·äœçã«ã¯
C10以äžã®çŽéã¢ã«ãã¬ã³éãæããé眮æãŸã
ã¯ã¢ã«ãã«çœ®æã¢ã«ãã¬ã³åºããã€ãžã«ã«ãã³é ž
ãšãžã¢ã«ãã«ã¢ãã³ãšã®åå¿ç©ã§ãã€ãŠå¥œãŸãã
ã¯C14-22ã®çŽéã¢ã«ãã¬ã³åºããã€ãžã«ã«ãã³é ž
ãšC14-22ã®ã¢ã«ãã«åºïŒã±ãæãããžã¢ã«ãã«ã¢
ãã³ãšã®åå¿ç©ã§ããã ããªã«ã«ãã³é žã®å«çªçŽ èªå°äœãšããŠã¯ç¹éæ
56â84795å·å ¬å ±ã«èšèŒã®ãã®ãæããããå ·äœ
çã«ã¯è³éŠæãèèªæãŸãã¯èç°åŒããªã«ã«ãã³
é žãšãžã¢ã«ãã«ã¢ãã³ãšã®åå¿çæç©ã§ããã奜
ãŸããã¯ããªã¡ãªããé žãšC14ãC22ã®ã¢ã«ãã«åº
ïŒã±ãæãããžã¢ã«ãã«ã¢ãã³ãšã®åå¿ç©ã§ã
ãã ãŸããããªã€ãœã·ã¢ããŒãååç©ãšãžã¢ã«ãã«
ã¢ãã³ãšã®åå¿ç©ïŒå°¿çŽ ããã³ïŒãŸãã¯ããŠãŒã¬
ããèªå°äœïŒãšããŠç¹éæ56â93796å·å ¬å ±ã«èš
èŒã®ãã®ãããããããå ·äœçã«ã¯è³éŠæãèèª
æãããã³èç°åŒããªã€ãœã·ã¢ããŒããšãžã¢ã«ã
ã«ã¢ãã³ãšã®åå¿ç©ã§ãã奜ãŸããã¯ããªã¬ã³ãž
ã€ãœã·ã¢ããŒããšC14ã22ã®ã¢ã«ãã«åºïŒã±ãæã
ããžã¢ã«ãã«ã¢ãã³ã®åå¿ç©ã§ããã äžèš(B)ã¯åç¬ã§ããŸãæ··åç©ãšããŠã(A)ãšäœµçš
ã§ããã (A)ããã³(B)ã䜵çšããå Žåããã®äœ¿çšæ¯çã¯ä»»
æã«èšå®ããããšãã§ããã奜ãŸããç¯å²ã¯éé
æ¯çã§(A)ïŒ(B)ïŒïŒïŒ98ã98ïŒïŒã§ããã æ¬çºæã«ãããçææ²¹ã¯äž»ãšããŠã¯çåºçææ²¹
ããã³çåºçææ²¹ã«æ®åºæ²¹ãæ··åããçææ²¹ã§ã
ããå ·äœçã«ã¯ã¬ãœãªã³ãç¯æ²¹ã軜油ããã³éæ²¹
ïŒïŒ¡éæ²¹ãéæ²¹ïŒããããããããããã®ãã¡
奜é©ãªãã®ã¯ç¯æ²¹ã軜油ããã³ïŒ¡éæ²¹ã§ããã æ¬çºæã®æ·»å å€ãçææ²¹ã«æ·»å ããã«ããã€ãŠ
ã¯ããã®æ·»å éã¯éåžž0.0001ã0.5ïŒ ïŒéé以äž
åãïŒã§ããã奜ãŸããã¯0.001ã0.1ïŒ ã§ããã æ¬çºæã®æ·»å å€ãçæäžã«æ·»å ããæ¹æ³ã¯ç¹ã«
å¶éããªãã(A)ãš(B)ãšãããªãæ·»å å€ã®å Žåããš
ãã°(A)ããã³(B)ããããããæ··åãããããçæ
æ²¹ã«æ·»å ããæ¹æ³ã(A)ãš(B)ãšãå¥ã ã«çææ²¹ã«æ·»
å ããçææ²¹äžã§(A)ããã³(B)ãããªãæ·»å å€ã圢
æããæ¹æ³ãããããããäºãæ··åããå Žåã¯(A)
ãš(B)ãšãå æž©ããŠåäžã«æ··åããæ¹æ³(A)ã(B)ã®å°
ãªããšãäžæ¹ã溶åªã«æº¶è§£ãããŠããæ··åããæ¹
æ³ããããããããŸãäžèšã®çææ²¹äžã§æ·»å å€ã
圢æãããæ¹æ³ãšããŠã¯(A)ããã³(B)ããã®ãŸãŸã
ãŸãã¯(A)ããã³(B)ã®å°ãªããšãäžæ¹ã溶åªã«æº¶è§£
ãäž¡è ãåæãŸãã¯é 次çææ²¹äžã«æ·»å ããæ¹æ³
ããããããã æ¬çºæã®æ·»å å€ã¯ãããŸã§äœ¿çšããæ¥ããšãã¬
ã³âé ¢é žããã«å ±éåäœã§ä»£è¡šãããå ±éåäœç³»
ã®æµåæ§æ¹è¯å€ãå¡©çŽ åãã©ãã€ã³ããã¿ã¬ã³çž®
åäœã§ä»£è¡šãããçž®åäœç³»ã®æµåæ§æ¹è¯å€ãã¢ã«
ã±ãã«ã³ãã¯é žãšãžã¢ã«ãã«ã¢ãã³ã®åå¿ç©ã§ä»£
è¡šãããå«çªçŽ èªå°äœç³»æµåæ§æ¹è¯å€ãªã©ã®ãã
ãããCFPPãéäžãããããšãã§ããªãéåžžã«
çã沞ç¹ç¯å²ïŒããšãã°åçç¹ãšçµçç¹ã®æž©åºŠå·®
ã100ã150âïŒã®çææ²¹ãïœâãã©ãã€ã³å«æé
ã®é«ãçææ²¹ã«å¯ŸããŠéåžžã«äœãæ·»å éã§ããã
ãCFPPéäžèœã瀺ããšå ±ã«ãåŸæ¥ããæµåæ§æ¹
è¯å€ã®å¹æãã§ãããæ¯èŒç沞ç¹ç¯å²ã®åºãïŒã
ãšãã°åçç¹ãšçµçç¹ã®æž©åºŠå·®ã180ã220âïŒç
ææ²¹ã«å¯ŸããŠãããããCFPPéäžèœã瀺ãããŸ
ãCFPPéäžèœãšå ±ã«PPéäžèœãå ŒãåããŠã
ãã(B)æåã䜵çšããããšã«ãã€ãŠç¹ã«ãããã
CFPPéäžèœãšããããPPéäžèœããã€ãæµå
æ§æ¹è¯å€ãæäŸããããšãã§ããã ãããŸã§ååå ã«ããªãšãŒãã«çµåãæã€ãå
åç©ãçææ²¹ã®æ·»å å€ãšããŠçšããäŸã¯çç¡ã§ã¯
ãªããäŸãã°ããªãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¹ãã¢
ã¬ãŒããããªãªãã·ãšãã¬ã³ãœã«ãã¿ã³ããªãªã¬
ãŒãã®ããã«OHåºãæ®ããã圢ã®ååç©ããã
ããããã¯åç¬ã§ã¯æµåæ§æ¹è¯å¹æãååã§ãª
ãããšãã¬ã³éåäœãããã²ã³åãšãã¬ã³éå
äœïŒãšãã¬ã³ãšã¢ãã«ã«ãã³é žããã«ãšã¹ãã«å ±
éåäœããšãã¬ã³ïŒã¡ã¿ïŒã¢ã¯ãªã«é žãšã¹ãã«ãš
ã®å ±éåäœãªã©ãšäœµçšããããšã«ãã€ãŠã¯ãããŠ
å¹æãè¡šãããããšãããŠããããŸã
ã®ã§ããã è¿å¹Žçææ²¹ç¹ã«è»œæ²¹ã®å Žåã¯ç¯æ²¹ã®æºçãªéèŠ
ããŸããªãããã«ãäœæ²žç¹éšåã®å²åãæžå°ãã
沞ç¹ç¯å²ãçãããããåŸãªãç¶æ³ã«ãªãã€ã€ã
ãããã®ããã«è»œæ²¹ã®æ²žç¹ç¯å²ãçãããããšã«
ãã€ãŠãã®äžã«å«ãŸããïœâãã©ãã€ã³ã®ççŽ é
ååžãçããªããåŸæ¥åºã䜿çšãããŠãããšãã¬
ã³âé ¢é žããã«ç³»ãã¯ãã倧éšåã®æµåæ§æ¹è¯æ·»
å å€ãæ·»å ããŠããããçææ²¹ã®å€§ããªçšéãå
ããå çæ©é¢ã®çæãã€ã«ã¿ãŒã®ç®ãè©°ãããšã
ãå±éºãªçŸè±¡ãæ¹ãèµ·ããäœæž©ã«ããããã€ã«ã¿
ãŒã®ç®è©°æž©åºŠãäœäžãããããšãäžå¯èœãªå Žåã
å€ããªã€ãŠããããã®åé¡ã解決ãããããã§ã«
ããããã®æ¹çãåãããŠãããããããããŸã§
ã®ãšãããã®ãããªçã沞ç¹ç¯å²ã®çææ²¹ã«å¯Ÿã
ãŠãCEPPïŒäœæž©æ¿Ÿéåšç®è©°ãç¹ãIP306ïŒãäœäž
ãããããšãã§ããŠãæµåç¹ãéäžãããèœåã
åææã«åããæµåæ§æ¹è¯å€ã¯èŠåºãããŠããª
ãã æ¬çºæè ãã¯äžèšã®æ²žç¹ç¯å²ãçãçææ²¹ã«å¯Ÿ
ããŠããããCEPPéäžèœã瀺ãããã€ããçšåºŠ
ã®æµåç¹ïŒPPïŒéäžèœãå Œãåããæµåæ§æ¹è¯
æ·»å å€ãéçºãã¹ãç 究ãéããçµææ¬çºæã«å°
éãããããªãã¡ãæ¬çºæã¯(A)ã¢ã«ã«ã³ããªãªãŒ
ã«ã®ããªãªãã·ã¢ã«ãã¬ã³ãšãŒãã«ïŒè©²ãšãŒãã«
ã®å¹³åååéã¯250ã6000ã§ããïŒãšççŽ æ°14ã
30ã®çŽé飜åèèªé ž(c)ãŸãã¯è©²èèªé ž(c)ãšä»ã®ã«
ã«ãã³é žãšã®æ··åã«ã«ãã³é žïŒcâ²ïŒãšã®å®å šãšã¹
ãã«ïŒããã³å¿ èŠã«ãã(B)ã¢ã«ã±ãã«ã³ãã¯é žã®
å«çªçŽ èªå°äœãå¡©çŽ åãã©ãã€ã³ãšããã¿ã¬ã³ãš
ã®çž®åç©ãé·éã¢ã«ãã¬ã³ãžã«ã«ãã³é žã®å«çªçŽ
èªå°äœãããªã«ã«ãã³é žã®å«çªçŽ èªå°äœããã³ãž
ã€ãœã·ã¢ããŒãååç©ãšãžã¢ã«ãã«ã¢ãã³ãšã®å°¿
çŽ ããã³ïŒãŸãã¯ããŠãŒã¬ããèªå°äœãããªã矀
ããéžã°ããååç©ãå«æããããšãç¹åŸŽãšãã
çææ²¹çšæµåæ§æ¹è¯æ·»å å€ã§ããã æ¬çºæã®æµåæ§æ¹è¯æ·»å å€ïŒä»¥äžãæ¬çºæã®æ·»
å å€ãšãããïŒã®(A)æåã§ããã¢ã«ã«ã³ããªãªãŒ
ã«ã®ããªãªãã·ã¢ã«ãã¬ã³ãšãŒãã«ãšççŽ æ°14ã
30ã®çŽé飜åèèªé žãå¿ é ãšããŠå«ãã«ã«ãã³é ž
ãšã®å®å šãšã¹ãã«ãšããŠã¯äžè¬åŒ ïŒåŒäžãã¯ã¢ã«ã«ã³ããªãªãŒã«ã®æ®åºïŒïŒ¡ã¯ç
çŽ æ°ïŒãïŒã®ã¢ã«ãã¬ã³åºïŒRâ²ã¯ã«ã«ãã³é žæ®
åºã§ãããïŒåã®Râ²ã®ãã¡å°ãªããšãïŒåã¯ç
çŽ æ°14ã30ã®çŽé飜åèèªé žã®æ®åºã§ãããïœã¯
âãïŒOAïŒoOHã3ã®å¹³åååéã250ã6000ã«ãª
ãæ°ã§ãããã ã§ç€ºãããååç©ããããããã äžè¬åŒ(1)ã«ãããŠãæ®åºïŒ²ã圢æããã¢ã«ã«ã³
ããªãªãŒã«ãšããŠã¯ã°ãªã»ãªã³ãããªã¡ãããŒã«
ãšã¿ã³ãããªã¡ãããŒã«ãããã³ãããªã¡ãããŒ
ã«ãã¿ã³ãïŒïŒïŒïŒïŒâãã¿ã³ããªãªãŒã«ãïŒïŒ
ïŒïŒïŒâãã¿ã³ããªãªãŒã«ãïŒïŒïŒïŒïŒâãããµ
ã³ããªãªãŒã«ããã³ãããã®äºçš®ä»¥äžã®æ··åç©ã
ãããããããããã®ãã¡ã§å¥œãŸãããã®ã¯ã°ãª
ã»ãªã³ãããªã¡ãããŒã«ããã³ããªã¡ãããŒã«ã
ããã³ã§ããã äžè¬åŒ(1)ã«ãããŠãæ®åºïŒ²ãïŒäŸ¡ãŸãã¯ïŒäŸ¡ã¢
ã«ã³ãŒã«ã®æ®åºã®å Žåã¯PPéäžèœãã»ãšãã©ãª
ãCEPPéäžèœãäžååã§ããã ã®ççŽ æ°ïŒâïŒã®ã¢ã«ãã¬ã³åºãšããŠã¯ãšã
ã¬ã³ããããã¬ã³ãããã¬ã³ïŒïŒïŒïŒâïŒïŒïŒïŒ
âïŒïŒïŒïŒâããã³ïŒïŒïŒâïŒåºããããããã
ãããã¯ïŒçš®ä»¥äžã§ãã€ãŠãããããããã®ãã¡
奜ãŸããã®ã¯ãšãã¬ã³åºããã³ãããã¬ã³åºã§ã
ãã äžè¬åŒ(1)ã«ãããŠãïŒåã®Râ²ã®ãã¡å°ãªããš
ãïŒåãå ããççŽ æ°14ã30ã®çŽé飜åèèªé žã®
æ®åºã圢æããèèªé žãšããŠã¯ããªã¹ãã³é žãã
ã«ããã³é žãã¹ãã¢ãªã³é žãã¢ã©ãã³é žãããã³
é žããªã°ãã»ãªã³é žãã»ããã³é žãã¢ã³ã¿ã³é žã
ã¡ãªã·ã³é žãªã©ããããã奜ãŸãããã®ã¯ãã«ã
ãã³é žãã¹ãã¢ãªã³é žãã¢ã©ãã³é žãããã³é žã
ããã³ãªã°ãã»ãªã³é žã§ããããããã¯åç¬ãŸã
ã¯æ··åç©ã§ãã€ãŠããããããšãã°çèã®ãããª
倩ç¶æ²¹èãå æ°Žå解ããŠåŸãããèèªé žãæ°ŽçŽ æ·»
å ããŠåŸãããæ··åèèªé žããã®ãŸãŸå©çšããã
ãšãã§ããã Râ²ã®ã«ã«ãã³é žæ®åºã圢æããä»ã®ã«ã«ãã³
é žãšããŠççŽ æ°ïŒã30ã®ã«ã«ãã³é žããšãã°ççŽ
æ°ïŒã13ã®çŽé飜åèèªé žïŒé ¢é žãããããªã³
é žãé ªé žãã«ããã³é žãã«ããªã«é žããã©ã«ãŽã³
é žãã©ãŠãªã³é žãªã©ïŒãäžé£œåèèªé žïŒãªã¬ã€ã³
é žããªããŒã«é žããªãã¬ã€ã³é žãªã©ïŒããªãã·é ž
ïŒã°ãªã³ãŒã«é žããªã·ãã¬ã€ã³é žãªã©ïŒãåå²èèª
é žïŒïŒâãšãã«ãããµã³é žãã€ãœã¹ãã¢ãªã³é žãª
ã©ïŒãè³éŠæã«ã«ãã³é žïŒå®æ¯éŠé žãããã¿ã¬ã³
ã«ã«ãã³é žãªã©ïŒããã³ãããã®ïŒçš®ä»¥äžã®æ··å
ç©ããããããããããã®ãã¡å¥œãŸããã®ã¯äžèš
çŽé飜åèèªé žããã³äžé£œåèèªé žã§ããã äžè¬åŒ(1)ã«ãããŠïŒåã®Râ²ã®ãã¡ççŽ æ°14ã
30ã®èèªæçŽé飜åã«ã«ãã³é žã®æ®åºãå«ãŸããª
ãå Žåã¯CFPPããã³PPã®äœäžå¹æãå°ãªãã ïœã¯ïŒ²âãïŒOAïŒoOHã3ã®å¹³åååéã250ã
6000ã«ãªãæ°ã奜ãŸããã¯250ã2000ã«ãªãæ°ã§
ãããïŒïŒã€ã®ïœã¯åäžã§ãç°ãªã€ãŠããŠãã
ããïŒãŸãïœã¯OHåœãã®å¹³åååéã83以äžãª
ãæ°ã§ãããïœã250ãããäœãå¹³åååéã«ãª
ãæ°ã®å ŽåããŸãOHåœãã®å¹³åååéã83æªæº
ãšãªãæ°ã®å Žåäžè¬ã«çææ²¹ã«å¯Ÿãã溶解æ§ã¯è¯
奜ã§ãããæ¬æ·»å å€ã®éèŠãªæ§èœã§ããCFPPé
äžèœãååã§ãªãããŸãååé6000ãè¶ããå Žå
ãçææ²¹ã«å¯Ÿãã溶解æ§ãååã§ãªãããããã¯
溶解æ§ãä¿ãããŠãCFPPéäžèœãååã§ãªãã
ååéã®ç¯å²ã¯250ã2000ã«ãããŠã¯éåžžã«ãã
ããCFPPéäžèœã瀺ããšå ±ã«PPéäžèœãå Œã
åãžãããçææ²¹ã«å¯ŸããŠè¯å¥œãªæº¶è§£æ§ãä¿æã
ãŠããã äžè¬åŒ(1)ã§ç€ºãããååç©ã¯å®å šãšã¹ãã«ã§ãª
ããã°ãªããªããååç©ãéšåãšã¹ãã«ïŒã¢ããŸ
ãã¯ãžãšã¹ãã«ïŒã®å Žåã¯CFPPããã³PPã®äœ
äžå¹æãå°ãªãã ãŸããæ¬çºæã«ãããŠ(A)æåãšããŠã¯ãäžè¬åŒ
(1)ã§ç€ºãããã«ä»£ããŠããŸãã¯ãããšãšãã«ãã«
ã«ãã³é žã®äžéšãšããŠã¢ãžãã³é žãã»ããã³é žã
ããã«ã³ãžã«ã«ãã³é žããã¿ã³ããªã«ã«ãã³é žãª
ã©ã®ããªã«ã«ãã³é žããçææ²¹ã«å¯Ÿãã溶解æ§ã
æªåããªãç¯å²ã«ãããŠïŒéåžžã«ã«ãã³é žæåäž
25ã¢ã«ïŒ 以äžïŒäœµçšãããã®ã§ãããããã®ãã
ãªãšã¹ãã«ãšããŠã¯ãäŸãã°äžè¬åŒ ãåŒäžRâ³ã¯ããªã«ã«ãã³é žæ®åºïŒïœã¯ïŒïŒïŒïŒ
âŠïŒããªã«ã«ãã³é žã®å¡©åºåºŠïŒïŒïŒ²ïŒRâ²ïŒïŒ¡ïŒïœ
ã¯äžè¬åŒ(1)ã«ããããšåãã§ããããã§ç€ºããã
ååç©ãå«æãããã®ããããããã (A)æåã¯çš®ã ã®æ¹æ³ã«ãã€ãŠè£œé ããããšãã§
ãããããšãã°å ããã¢ã«ã«ã³ããªãªãŒã«ããã®
ãŸãŸãããã¯åå¿ç³»ã«äžæŽ»æ§ãªé©åœãªæº¶åªã«æº¶è§£
ããäžè¬ã«èæ§ã¢ã«ã«ãªã®ãããªè§Šåªãå ããŠå
ç±äžã§ççŽ æ°ïŒãïŒã®ã¢ã«ãã¬ã³ãªãã·ãïŒãšã
ã¬ã³ãªãã·ãããããã¬ã³ãªãã·ããããã¬ã³ãª
ãã·ããªã©ïŒã液ç¶ãŸãã¯æ°ç¶ã§å ããåå¿ãã
ããïŒçš®ä»¥äžã®ã¢ã«ãã¬ã³ãªãã·ããåå¿ããã
å Žåã«ã¯ãïŒçš®ä»¥äžã®ã¢ã«ãã¬ã³ãªãã·ããæ··å
ããŠåå¿ãããã©ã³ãã åå éåã§ãããããŸ
ããæåã«ïŒçš®ã®ã¢ã«ãã¬ã³ãªãã·ããåå¿ãã
次ãã§ä»ã®ã¢ã«ãã¬ã³ãªãã·ããé 次ä»å ããã
ãããã¯ä»å éåãè¡ãªã€ãŠãããããã®ããã«
ããŠåŸãããããªãªãã·ã¢ã«ãã¬ã³ãšãŒãã«ã¯ã
ã®ãŸãŸãŸãã¯ç²Ÿè£œããŠæªåå¿ç©è³ªãŸãã¯è§Šåªãé€
å»ããã®ã¡ãççŽ æ°ïŒã30ã®ã«ã«ãã³é žãšéåžžç¡«
é žãªã©ã®è§Šåªãå ããŠå ç±äžã§ãšã¹ãã«åããã ãšã¹ãã«åã«ãããŠãããªãªãã·ã¢ã«ãã¬ã³ãš
ãŒãã«ã®ããããã·ã«åºãšã«ã«ãã³é žã®ã«ã«ãã
ã·ã«åºã®åœéæ¯ã¯å®è³ªçã«ïŒïŒïŒã奜ãŸããããŸ
ãããªãªãã·ã¢ã«ãã¬ã³ãšãŒãã«ïŒã¢ã«ã«å¯ŸããŠ
ççŽ æ°14â30ã®çŽé飜åèèªé žã¯ïŒã¢ã«ä»¥äžã奜
ãŸããã¯ïŒãïŒã¢ã«ã䜿çšããã ãšã¹ãã«åã«éããŠã¯ä»ã®ã«ã«ãã³é žã§ãšã¹ã
ã«åããã®ã¡ççŽ æ°14ã30ã®çŽé飜åèèªé žãå
ããŠåã³ãšã¹ãã«ååå¿ãè¡ãªã€ãŠãéã«æåã«
ççŽ æ°14ã30ã®çŽé飜åèèªé žã§ãšã¹ãã«åãã
ã®ã¡ä»ã®ã«ã«ãã³é žã§ãšã¹ãã«åããŠããŸããä»
ã®ã«ã«ãã³é žãšã®ççŽ æ°14ã30ã®çŽé飜åèèªé ž
ãå«ãæ··åç©ãçšããŠãšã¹ãã«åããŠããããå
å¿ã®é²è¡ã¯é žäŸ¡ãããããã·ã«äŸ¡ãã±ã³å䟡ãªã©
ã®è¿œè·¡ãè¡ãªãããšã«ãã€ãŠç¢ºèªã§ããã ãã®ããã«ããŠåŸããã(A)æåã«ã¯å°éã®æªå
å¿ç©ãå«ãããšããããéåžžã¯é€å»ããªããŠãäœ
ãæ¯éãªã䜿çšããããšãã§ãããæ¬çºæã«ãã
ã(A)æåã¯äœ¿çšããã¢ã«ã«ã³ããªãªãŒã«ãã¢ã«ã
ã¬ã³ãªãã·ãããã³ã«ã«ãã³é žã®çš®é¡ãããªãšãŒ
ãã«ããªãªãŒã«ã®ååéãªã©ã«ãã€ãŠç¶æ ã¯ç°ãª
ããéåžžãç²çš ãªæ¶²ç¶ãªããã¯åºç¶ã§ãããç³æ²¹
系溶å€ãã¢ã«ã³ãŒã«é¡ããšã¹ãã«é¡ãªã©ã®æº¶å€ã«
ã¯å¯æº¶ã§ãããæ°Žã«å¯ŸããŠã¯åæ£ããããšã¯ãã€
ãŠãäžæº¶ã§ããã æ¬çºæã«ãããŠã¯ãå¿ èŠã«ãã(B)æåãšããŠã¢
ã«ã±ãã«ã³ãã¯é žã®å«çªçŽ èªå°äœãå¡©çŽ åãã©ã
ã€ã³ãšããã¿ã¬ã³ãšã®çž®åç©ãé·éã¢ã«ã«ã³ãžã«
ã«ãã³é žã®å«çªçŽ èªå°äœãé·éã¢ã«ãã¬ã³ãžã«ã«
ãã³é žã®å«çªçŽ èªå°äœãããªã«ã«ãã³é žã®å«çªçŽ
èªå°äœé žããžã€ãœã·ã¢ããŒãååç©ãšãžã¢ã«ãã«
ã¢ãã³ãšã®å°¿çŽ ããã³ïŒãŸãã¯ããŠãŒã¬ããèªå°
äœã®ããããïŒçš®ãŸãã¯ïŒçš®ä»¥äžãåèšã®(A)ãšäœµ
çšããããšãã§ããã (B)æåã䜵çšããããšã«ãã€ãŠPPéäžèœãå©
é·ããããšãã倧ããªæåŸ ãããããããªããç
ææ²¹ã®æµåæ§åäžå€ãšããŠãšãã¬ã³âé ¢é žããã«
å ±éåäœããšãã¬ã³âã¢ã¯ãªã«é žãšã¹ãã«å ±éå
äœãå¡©çŽ åãã©ãã€ã³ãé·éã¢ã«ãã«åºãå«ã
ïŒã¡ã¿ïŒã¢ã¯ãªã«é žå ±éåäœãªã䜿çšãããŠãã
ããæ¬çºæã«ããã(A)æåãšãããã®éåäœåæµ
åæ§åäžå€ã䜵çšããããšãã§ãããããã®å Žå
ã«ã¯PPéäžèœãå©é·ãããå¹æã¯ã(B)æåã䜵
çšããå Žåã»ã©ã«èªããããã(A)æåã®ç¹é·ã§ã
ãçã沞ç¹ç¯å²ããã€çææ²¹ã«å¯Ÿããè¯å¥œãª
CFPPéäžèœãã(B)æå䜵çšã®å Žåã»ã©ååã«ã¯
çºæ®ã§ããªãã (B)æåã®ã¢ã«ã±ãã«ã³ãã¯é žã®å«çªçŽ èªå°äœé ž
ãšããŠC4ãC28ã®ã¢ã«ã±ãã«åºãå«ãã¢ã«ã±ãã«
ã³ãã¯é žãšã¢ããŸãã¯ãžã¢ã«ãã«ã¢ãã³ãïŒããªïŒ
ã¢ã«ãã¬ã³ããªã¢ãã³ãšã®åå¿ç©ïŒã¢ãããã
ã³ïŒãŸãã¯å¡©ïŒãããããã奜ãŸãããã«ã¯C14
ãC22ã®ã¢ã«ã±ãã«åºãå«ãã¢ã«ã±ãã«ã³ãã¯é ž
ãšC14ãC20ã®ã¢ã«ãã«åºãïŒåãã€ãžã¢ã«ãã«ã¢
ãã³ãšã®åå¿ç©ã§ããã å¡©çŽ åãã©ãã€ã³ãšããã¿ã¬ã³ãšã®çž®åç©ãšã
ãŠã¯C8以äžã®ãã©ãã€ã³ã®å¡©çŽ åç©ãšããã¿ã¬
ã³ãšã®çž®åç©ãæããããããã®ååéã¯éåžž
2000ã8000ã®ç¯å²ã§ãããé·éã¢ã«ãã¬ã³ãžã«ã«
ãã³é žã®å«çªçŽ èªå°äœãšããŠã¯ç¹éæ56â36588
å·å ¬å ±ã«èšèŒã®ãã®ãæãããããå ·äœçã«ã¯
C10以äžã®çŽéã¢ã«ãã¬ã³éãæããé眮æãŸã
ã¯ã¢ã«ãã«çœ®æã¢ã«ãã¬ã³åºããã€ãžã«ã«ãã³é ž
ãšãžã¢ã«ãã«ã¢ãã³ãšã®åå¿ç©ã§ãã€ãŠå¥œãŸãã
ã¯C14-22ã®çŽéã¢ã«ãã¬ã³åºããã€ãžã«ã«ãã³é ž
ãšC14-22ã®ã¢ã«ãã«åºïŒã±ãæãããžã¢ã«ãã«ã¢
ãã³ãšã®åå¿ç©ã§ããã ããªã«ã«ãã³é žã®å«çªçŽ èªå°äœãšããŠã¯ç¹éæ
56â84795å·å ¬å ±ã«èšèŒã®ãã®ãæããããå ·äœ
çã«ã¯è³éŠæãèèªæãŸãã¯èç°åŒããªã«ã«ãã³
é žãšãžã¢ã«ãã«ã¢ãã³ãšã®åå¿çæç©ã§ããã奜
ãŸããã¯ããªã¡ãªããé žãšC14ãC22ã®ã¢ã«ãã«åº
ïŒã±ãæãããžã¢ã«ãã«ã¢ãã³ãšã®åå¿ç©ã§ã
ãã ãŸããããªã€ãœã·ã¢ããŒãååç©ãšãžã¢ã«ãã«
ã¢ãã³ãšã®åå¿ç©ïŒå°¿çŽ ããã³ïŒãŸãã¯ããŠãŒã¬
ããèªå°äœïŒãšããŠç¹éæ56â93796å·å ¬å ±ã«èš
èŒã®ãã®ãããããããå ·äœçã«ã¯è³éŠæãèèª
æãããã³èç°åŒããªã€ãœã·ã¢ããŒããšãžã¢ã«ã
ã«ã¢ãã³ãšã®åå¿ç©ã§ãã奜ãŸããã¯ããªã¬ã³ãž
ã€ãœã·ã¢ããŒããšC14ã22ã®ã¢ã«ãã«åºïŒã±ãæã
ããžã¢ã«ãã«ã¢ãã³ã®åå¿ç©ã§ããã äžèš(B)ã¯åç¬ã§ããŸãæ··åç©ãšããŠã(A)ãšäœµçš
ã§ããã (A)ããã³(B)ã䜵çšããå Žåããã®äœ¿çšæ¯çã¯ä»»
æã«èšå®ããããšãã§ããã奜ãŸããç¯å²ã¯éé
æ¯çã§(A)ïŒ(B)ïŒïŒïŒ98ã98ïŒïŒã§ããã æ¬çºæã«ãããçææ²¹ã¯äž»ãšããŠã¯çåºçææ²¹
ããã³çåºçææ²¹ã«æ®åºæ²¹ãæ··åããçææ²¹ã§ã
ããå ·äœçã«ã¯ã¬ãœãªã³ãç¯æ²¹ã軜油ããã³éæ²¹
ïŒïŒ¡éæ²¹ãéæ²¹ïŒããããããããããã®ãã¡
奜é©ãªãã®ã¯ç¯æ²¹ã軜油ããã³ïŒ¡éæ²¹ã§ããã æ¬çºæã®æ·»å å€ãçææ²¹ã«æ·»å ããã«ããã€ãŠ
ã¯ããã®æ·»å éã¯éåžž0.0001ã0.5ïŒ ïŒéé以äž
åãïŒã§ããã奜ãŸããã¯0.001ã0.1ïŒ ã§ããã æ¬çºæã®æ·»å å€ãçæäžã«æ·»å ããæ¹æ³ã¯ç¹ã«
å¶éããªãã(A)ãš(B)ãšãããªãæ·»å å€ã®å Žåããš
ãã°(A)ããã³(B)ããããããæ··åãããããçæ
æ²¹ã«æ·»å ããæ¹æ³ã(A)ãš(B)ãšãå¥ã ã«çææ²¹ã«æ·»
å ããçææ²¹äžã§(A)ããã³(B)ãããªãæ·»å å€ã圢
æããæ¹æ³ãããããããäºãæ··åããå Žåã¯(A)
ãš(B)ãšãå æž©ããŠåäžã«æ··åããæ¹æ³(A)ã(B)ã®å°
ãªããšãäžæ¹ã溶åªã«æº¶è§£ãããŠããæ··åããæ¹
æ³ããããããããŸãäžèšã®çææ²¹äžã§æ·»å å€ã
圢æãããæ¹æ³ãšããŠã¯(A)ããã³(B)ããã®ãŸãŸã
ãŸãã¯(A)ããã³(B)ã®å°ãªããšãäžæ¹ã溶åªã«æº¶è§£
ãäž¡è ãåæãŸãã¯é 次çææ²¹äžã«æ·»å ããæ¹æ³
ããããããã æ¬çºæã®æ·»å å€ã¯ãããŸã§äœ¿çšããæ¥ããšãã¬
ã³âé ¢é žããã«å ±éåäœã§ä»£è¡šãããå ±éåäœç³»
ã®æµåæ§æ¹è¯å€ãå¡©çŽ åãã©ãã€ã³ããã¿ã¬ã³çž®
åäœã§ä»£è¡šãããçž®åäœç³»ã®æµåæ§æ¹è¯å€ãã¢ã«
ã±ãã«ã³ãã¯é žãšãžã¢ã«ãã«ã¢ãã³ã®åå¿ç©ã§ä»£
è¡šãããå«çªçŽ èªå°äœç³»æµåæ§æ¹è¯å€ãªã©ã®ãã
ãããCFPPãéäžãããããšãã§ããªãéåžžã«
çã沞ç¹ç¯å²ïŒããšãã°åçç¹ãšçµçç¹ã®æž©åºŠå·®
ã100ã150âïŒã®çææ²¹ãïœâãã©ãã€ã³å«æé
ã®é«ãçææ²¹ã«å¯ŸããŠéåžžã«äœãæ·»å éã§ããã
ãCFPPéäžèœã瀺ããšå ±ã«ãåŸæ¥ããæµåæ§æ¹
è¯å€ã®å¹æãã§ãããæ¯èŒç沞ç¹ç¯å²ã®åºãïŒã
ãšãã°åçç¹ãšçµçç¹ã®æž©åºŠå·®ã180ã220âïŒç
ææ²¹ã«å¯ŸããŠãããããCFPPéäžèœã瀺ãããŸ
ãCFPPéäžèœãšå ±ã«PPéäžèœãå ŒãåããŠã
ãã(B)æåã䜵çšããããšã«ãã€ãŠç¹ã«ãããã
CFPPéäžèœãšããããPPéäžèœããã€ãæµå
æ§æ¹è¯å€ãæäŸããããšãã§ããã ãããŸã§ååå ã«ããªãšãŒãã«çµåãæã€ãå
åç©ãçææ²¹ã®æ·»å å€ãšããŠçšããäŸã¯çç¡ã§ã¯
ãªããäŸãã°ããªãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¹ãã¢
ã¬ãŒããããªãªãã·ãšãã¬ã³ãœã«ãã¿ã³ããªãªã¬
ãŒãã®ããã«OHåºãæ®ããã圢ã®ååç©ããã
ããããã¯åç¬ã§ã¯æµåæ§æ¹è¯å¹æãååã§ãª
ãããšãã¬ã³éåäœãããã²ã³åãšãã¬ã³éå
äœïŒãšãã¬ã³ãšã¢ãã«ã«ãã³é žããã«ãšã¹ãã«å ±
éåäœããšãã¬ã³ïŒã¡ã¿ïŒã¢ã¯ãªã«é žãšã¹ãã«ãš
ã®å ±éåäœãªã©ãšäœµçšããããšã«ãã€ãŠã¯ãããŠ
å¹æãè¡šãããããšãããŠããããŸã
ãåŒãã§ç€ºãããããã«
ããªãªãã·ã¢ã«ãã¬ã³ã°ãªã³ãŒã«ã®ãžãšã¹ãã«ã
çã沞ç¹ç¯å²ã®çåºçææ²¹ã«å¯ŸããŠããçšåºŠã®
CFPPéäžèœã瀺ãããPPéäžèœãã»ãšãã©ãª
ããšããåé¡ç¹ãããã æ¬çºæã®æ·»å å€ã¯(1)沞ç¹ç¯å²ã®çãæ²¹ã«å¯ŸããŠ
ãåºãæ²¹ã«å¯ŸããŠãããããCFPPéäžèœã瀺ã
ããã«é質ã§æ²žç¹ç¯å²ã®çãæ²¹ã«å¯ŸããŠãè¯å¥œãª
CFPPéäžèœã瀺ãïŒ(2)å°éã®æ·»å éã§ãCFPP
éäžèœãå åã§ããïŒ(3)PPéäžèœã瀺ããšïŒãš
ããç»æçãªå¹æãçºæ®ãããã®ã§ããã ãã®ãããªå¹æã¯æ¬çºæã®æ·»å å€ãæ·»å ããç
ææ²¹ãåŸå·ããªããé¡åŸ®é¡ã§ãã©ãã€ã³ã¯ãã¯ã¹
çµæ¶ã®æåºç¶æ³ã芳å¯ããããšã«ãã€ãŠæ確ã«èª
ããããšãã§ãããããªãã¡ãçã沞ç¹ç¯å²ã®ç
ææ²¹ã¯ãããªãæµåæ§æ¹è¯å€ãæ·»å ããŠããã®æ·»
å éã0.1ïŒ ãããã¯ãã以äžã«éããªãããã
åŸå·ã«ãã€ãŠæåºãããã©ãã€ã³ã¯ãã¯ã¹çµæ¶ã®
圢æ ã倧ããCFPP枬å®çšã®é網ã®ç®ãééãã
ããã«åŸ®çŽ°ãªãã®ã«ã¯ãªãåŸãªããããã«å¯ŸããŠ
æ¬çºæã®æ·»å å€ã¯ããšãã°0.01ïŒ çšåºŠã®æ·»å ã«ã
ã€ãŠãåŸå·ã«ãã€ãŠæåºãããã©ãã€ã³ã¯ãã¯ã¹
ã®çµæ¶åœ¢æ ã¯éåžžã«åŸ®çŽ°ãªãã®ãšãªããäžèšã®é
網ã®ç®ãæ¯èŒç容æã«ééã§ãã倧ãããšãªã€ãŠ
ããã äžèšå¹æãå¥ããããšããæ¬çºæã®æ·»å å€ã¯ç
ææ²¹ã茞éããéã®ãã©ãã€ã³å ã§ã®æµåæ§ãã
ããããã€ã«ã¿ãŒã®ç®è©°ããªã©ãé²æ¢ããç®çã§
æ·»å ãããæ·»å å€ãšããŠæçšã§ããã以äžå®æœäŸ
ã«ããæ¬çºæãããã«èª¬æãããããã«ãã€ãŠæ¬
çºæãéå®ããããã®ã§ã¯ãªãã å®æœäŸ ïŒ å¹³åååé1050ãããããã·ã«äŸ¡160ã®ããªã¡
ãããŒã«ãããã³ïŒPOïŒ9ïŒEOïŒ9ãããªã¡ãããŒã«
ãããã³ã®ãããã¬ã³ãªããµã€ãïŒã¢ã«ä»å ç©ã«
ããã«ãšãã¬ã³ãªããµã€ããïŒã¢ã«ä»å ãããã®
ãè¡šããã105éšãšã¹ãã¢ãªã³é ž43éšïŒ0.15ã¢ã«ïŒ
ãšããã³é ž51éšïŒ0.15ã¢ã«ïŒããã©ãã«ãšã³ã¹ã«
ãã³é ž0.5éšã觊åªãšããŠæ¹æè£ çœ®ã枩床èšãçª
çŽ å¹èŸŒã¿ç®¡åã³ææ°ç®¡ãåãããã©ã¹ã³ã«å ã
150ã160âã§çªçŽ ãå¹ããã¿ãªããïŒæéåå¿ã
ããããšã«ãã補é ããããªã¡ãããŒã«ãããã³
ïŒPOïŒ9ïŒEOïŒ9ã®æ··åèèªé žãã¹ãã¢ãªã³é žïŒãã
ã³é žïŒïŒïŒïŒïŒã¢ã«æ¯ïŒãããªãšã¹ãã«ïŒæ·¡é»è²åº
ç¶ãé žäŸ¡ïŒãããããã·ã«äŸ¡ïŒãã±ã³å䟡89ïŒã
æ¬çºæã®æ·»å å€ãšããã å®æœäŸ ïŒ å¹³åååé1050ãããããã·ã«äŸ¡160ã®ããªã¡
ãããŒã«ãããã³ïŒPOïŒ9ïŒEOïŒ9105éšãšãªã¬ã€ã³
é ž28éšïŒ0.1ã¢ã«ïŒãšããã³é ž68éšïŒ0.2ã¢ã«ïŒãš
ãå®æœäŸïŒãšåæ§ã«åå¿ãã補é ããããªã¡ãã
ãŒã«ãããã³ïŒPOïŒ9ïŒEOïŒ9ã®æ··åèèªé žããªã¬
ã€ã³é žïŒããã³é žïŒ1/2ïŒã¢ã«æ¯ïŒãããªãšã¹ãã«
ïŒæ·»é»è²åºç¶ãé žäŸ¡ïŒãããããã·ã«äŸ¡ïŒãã±ã³
å䟡85ïŒãæ¬çºæã®æ·»å å€ãšããã å®æœäŸ ïŒ å¹³åååé620ãããããã·ã«äŸ¡272ã®ã°ãªã»ãª
ã³ïŒEOïŒ12ãã°ãªã»ãªã³ã®ãšãã¬ã³ãªããµã€ã12
ã¢ã«ä»å ç©ãè¡šããã62éšïŒ0.1ã¢ã«ïŒãšããã³
é ž102éšïŒ0.3ã¢ã«ïŒãšãå®æœäŸïŒãšåæ§ã«åå¿ã
ã補é ããã°ãªã»ãªã³ïŒEOïŒ12ã®ããã³é žããªãš
ã¹ãã«ïŒæ·¡é»è²åºç¶ãé žäŸ¡ïŒãããããã·ã«äŸ¡
ïŒãã±ã³å䟡102ïŒãæ¬çºæã®æ·»å å€ãšããã æ¯èŒäŸ ïŒãïŒ æ¯èŒã®ãããšãã¬ã³âé ¢é žããã«å ±éåäœïŒæ°
å¹³åååé2500ãé ¢é žããã«å«é30ééïŒ ïŒã
PEG600ãžããããŒãããã³ããªã¡ãããŒã«ãã
ãã³ïŒPOïŒ9ïŒEOïŒ9ã®ããã³é žã¢ããšã¹ãã«ãæ¯
èŒäŸïŒãïŒããã³ïŒã®æ·»å å€ãšããã 䜿çšäŸ ïŒ å®æœäŸïŒãïŒãïŒããã³æ¯èŒäŸïŒãïŒãïŒã®æ·»
å å€ãè¡šâïŒã«ç€ºãæ§ç¶ã®ïŒçš®ã®è»œæ²¹ã«æ·»å ããŠ
æµåç¹ïŒPPïŒãšCFPPã®æž¬å®ãè¡ãªã€ãããã®
çµæãè¡šâïŒã«ç€ºãã ïŒè»œæ²¹ã®æ§ç¶ïŒ
çã沞ç¹ç¯å²ã®çåºçææ²¹ã«å¯ŸããŠããçšåºŠã®
CFPPéäžèœã瀺ãããPPéäžèœãã»ãšãã©ãª
ããšããåé¡ç¹ãããã æ¬çºæã®æ·»å å€ã¯(1)沞ç¹ç¯å²ã®çãæ²¹ã«å¯ŸããŠ
ãåºãæ²¹ã«å¯ŸããŠãããããCFPPéäžèœã瀺ã
ããã«é質ã§æ²žç¹ç¯å²ã®çãæ²¹ã«å¯ŸããŠãè¯å¥œãª
CFPPéäžèœã瀺ãïŒ(2)å°éã®æ·»å éã§ãCFPP
éäžèœãå åã§ããïŒ(3)PPéäžèœã瀺ããšïŒãš
ããç»æçãªå¹æãçºæ®ãããã®ã§ããã ãã®ãããªå¹æã¯æ¬çºæã®æ·»å å€ãæ·»å ããç
ææ²¹ãåŸå·ããªããé¡åŸ®é¡ã§ãã©ãã€ã³ã¯ãã¯ã¹
çµæ¶ã®æåºç¶æ³ã芳å¯ããããšã«ãã€ãŠæ確ã«èª
ããããšãã§ãããããªãã¡ãçã沞ç¹ç¯å²ã®ç
ææ²¹ã¯ãããªãæµåæ§æ¹è¯å€ãæ·»å ããŠããã®æ·»
å éã0.1ïŒ ãããã¯ãã以äžã«éããªãããã
åŸå·ã«ãã€ãŠæåºãããã©ãã€ã³ã¯ãã¯ã¹çµæ¶ã®
圢æ ã倧ããCFPP枬å®çšã®é網ã®ç®ãééãã
ããã«åŸ®çŽ°ãªãã®ã«ã¯ãªãåŸãªããããã«å¯ŸããŠ
æ¬çºæã®æ·»å å€ã¯ããšãã°0.01ïŒ çšåºŠã®æ·»å ã«ã
ã€ãŠãåŸå·ã«ãã€ãŠæåºãããã©ãã€ã³ã¯ãã¯ã¹
ã®çµæ¶åœ¢æ ã¯éåžžã«åŸ®çŽ°ãªãã®ãšãªããäžèšã®é
網ã®ç®ãæ¯èŒç容æã«ééã§ãã倧ãããšãªã€ãŠ
ããã äžèšå¹æãå¥ããããšããæ¬çºæã®æ·»å å€ã¯ç
ææ²¹ã茞éããéã®ãã©ãã€ã³å ã§ã®æµåæ§ãã
ããããã€ã«ã¿ãŒã®ç®è©°ããªã©ãé²æ¢ããç®çã§
æ·»å ãããæ·»å å€ãšããŠæçšã§ããã以äžå®æœäŸ
ã«ããæ¬çºæãããã«èª¬æãããããã«ãã€ãŠæ¬
çºæãéå®ããããã®ã§ã¯ãªãã å®æœäŸ ïŒ å¹³åååé1050ãããããã·ã«äŸ¡160ã®ããªã¡
ãããŒã«ãããã³ïŒPOïŒ9ïŒEOïŒ9ãããªã¡ãããŒã«
ãããã³ã®ãããã¬ã³ãªããµã€ãïŒã¢ã«ä»å ç©ã«
ããã«ãšãã¬ã³ãªããµã€ããïŒã¢ã«ä»å ãããã®
ãè¡šããã105éšãšã¹ãã¢ãªã³é ž43éšïŒ0.15ã¢ã«ïŒ
ãšããã³é ž51éšïŒ0.15ã¢ã«ïŒããã©ãã«ãšã³ã¹ã«
ãã³é ž0.5éšã觊åªãšããŠæ¹æè£ çœ®ã枩床èšãçª
çŽ å¹èŸŒã¿ç®¡åã³ææ°ç®¡ãåãããã©ã¹ã³ã«å ã
150ã160âã§çªçŽ ãå¹ããã¿ãªããïŒæéåå¿ã
ããããšã«ãã補é ããããªã¡ãããŒã«ãããã³
ïŒPOïŒ9ïŒEOïŒ9ã®æ··åèèªé žãã¹ãã¢ãªã³é žïŒãã
ã³é žïŒïŒïŒïŒïŒã¢ã«æ¯ïŒãããªãšã¹ãã«ïŒæ·¡é»è²åº
ç¶ãé žäŸ¡ïŒãããããã·ã«äŸ¡ïŒãã±ã³å䟡89ïŒã
æ¬çºæã®æ·»å å€ãšããã å®æœäŸ ïŒ å¹³åååé1050ãããããã·ã«äŸ¡160ã®ããªã¡
ãããŒã«ãããã³ïŒPOïŒ9ïŒEOïŒ9105éšãšãªã¬ã€ã³
é ž28éšïŒ0.1ã¢ã«ïŒãšããã³é ž68éšïŒ0.2ã¢ã«ïŒãš
ãå®æœäŸïŒãšåæ§ã«åå¿ãã補é ããããªã¡ãã
ãŒã«ãããã³ïŒPOïŒ9ïŒEOïŒ9ã®æ··åèèªé žããªã¬
ã€ã³é žïŒããã³é žïŒ1/2ïŒã¢ã«æ¯ïŒãããªãšã¹ãã«
ïŒæ·»é»è²åºç¶ãé žäŸ¡ïŒãããããã·ã«äŸ¡ïŒãã±ã³
å䟡85ïŒãæ¬çºæã®æ·»å å€ãšããã å®æœäŸ ïŒ å¹³åååé620ãããããã·ã«äŸ¡272ã®ã°ãªã»ãª
ã³ïŒEOïŒ12ãã°ãªã»ãªã³ã®ãšãã¬ã³ãªããµã€ã12
ã¢ã«ä»å ç©ãè¡šããã62éšïŒ0.1ã¢ã«ïŒãšããã³
é ž102éšïŒ0.3ã¢ã«ïŒãšãå®æœäŸïŒãšåæ§ã«åå¿ã
ã補é ããã°ãªã»ãªã³ïŒEOïŒ12ã®ããã³é žããªãš
ã¹ãã«ïŒæ·¡é»è²åºç¶ãé žäŸ¡ïŒãããããã·ã«äŸ¡
ïŒãã±ã³å䟡102ïŒãæ¬çºæã®æ·»å å€ãšããã æ¯èŒäŸ ïŒãïŒ æ¯èŒã®ãããšãã¬ã³âé ¢é žããã«å ±éåäœïŒæ°
å¹³åååé2500ãé ¢é žããã«å«é30ééïŒ ïŒã
PEG600ãžããããŒãããã³ããªã¡ãããŒã«ãã
ãã³ïŒPOïŒ9ïŒEOïŒ9ã®ããã³é žã¢ããšã¹ãã«ãæ¯
èŒäŸïŒãïŒããã³ïŒã®æ·»å å€ãšããã 䜿çšäŸ ïŒ å®æœäŸïŒãïŒãïŒããã³æ¯èŒäŸïŒãïŒãïŒã®æ·»
å å€ãè¡šâïŒã«ç€ºãæ§ç¶ã®ïŒçš®ã®è»œæ²¹ã«æ·»å ããŠ
æµåç¹ïŒPPïŒãšCFPPã®æž¬å®ãè¡ãªã€ãããã®
çµæãè¡šâïŒã«ç€ºãã ïŒè»œæ²¹ã®æ§ç¶ïŒ
ãè¡šã
ãè¡šã
ãè¡šã
è¡šâïŒããæãããªããã«æ¬çºæã®æ·»å å€ã¯ç
沞ç¹ç¯å²ã®è»œæ²¹ãåºæ²žç¹ç¯å²ã®è»œæ²¹ãããã«ãåŸ
æ¥ã®æè¡ãããã¯ããã«äœæ·»å éã§CFPPãéäž
ãããããšãã§ãããŸãPPãããçšåºŠéäžãã
ãããšãã§ããããšãããããç沞ç¹ç¯å²ã®è»œæ²¹
ã«å¯ŸããŠCFPPãéäžãããããšãã§ãããã
PPãéäžãããããšãã§ããªãPEG600ãžããã
ãŒãããç沞ç¹ç¯å²ã®è»œæ²¹ã«å¯ŸããŠPPã¯éäžã
ããããšãã§ãããCFPPãéäžãããããšãã§
ããªãããšãã¬ã³âé ¢é žããã«å ±éåäœãããã¯
ããã«æå©ã§ããããšã¯æããã§ããããŸã軜油
âïŒã®ãããªé質ã§ç沞ç¹ç¯å²ã®æ²¹ã«å¯ŸããŠãè¯
奜ãªæ§èœã瀺ããŠããããŸãããããã·ã«åºã®æ®
ã€ãŠããããªã¡ãããŒã«ãããã³ïŒPOïŒ9ïŒEOïŒ9
ããã³é žã¢ããšã¹ãã«ã§ã¯ã»ãšãã©å¹æã®ãªãã
ãšã瀺ããŠããã å®æœäŸ ïŒ å®æœäŸïŒã®æ·»å å€20éšãšïœâããã©ãã»ãã«ã³
ãã¯é žãžïŒïœâãªã¯ã¿ãã·ã«ïŒã¢ãã80éšã®é å
ç©ãæ¬çºæã®æ·»å å€ãšããã å®æœäŸ ïŒ å®æœäŸïŒã®æ·»å å€20éšãšïœâããã©ãã»ãã«ã³
ãã¯é žãžïŒïœâãªã¯ã¿ãã·ã«ïŒã¢ãã80éšã®é å
ç©ãæ¬çºæã®æ·»å å€ãšããã å®æœäŸ ïŒ å®æœäŸïŒã®æ·»å å€20éšãšããªã¡ãªããé žã®ãž
ïŒïœâãªã¯ã¿ãã·ã«ïŒã¢ãã³ãžã¢ãã80éšã®é å
ç©ãæ¬çºæã®æ·»å å€ãšããã 䜿çšäŸ ïŒ å®æœäŸïŒãïŒããã³ïŒã®æ·»å å€ãè¡šâïŒã«ç€ºã
ã軜油âïŒãïŒãïŒã«æ·»å ããŠPPãCFPPã枬
å®ãããçµæã¯è¡šâïŒã®éãã§ãã€ãã
沞ç¹ç¯å²ã®è»œæ²¹ãåºæ²žç¹ç¯å²ã®è»œæ²¹ãããã«ãåŸ
æ¥ã®æè¡ãããã¯ããã«äœæ·»å éã§CFPPãéäž
ãããããšãã§ãããŸãPPãããçšåºŠéäžãã
ãããšãã§ããããšãããããç沞ç¹ç¯å²ã®è»œæ²¹
ã«å¯ŸããŠCFPPãéäžãããããšãã§ãããã
PPãéäžãããããšãã§ããªãPEG600ãžããã
ãŒãããç沞ç¹ç¯å²ã®è»œæ²¹ã«å¯ŸããŠPPã¯éäžã
ããããšãã§ãããCFPPãéäžãããããšãã§
ããªãããšãã¬ã³âé ¢é žããã«å ±éåäœãããã¯
ããã«æå©ã§ããããšã¯æããã§ããããŸã軜油
âïŒã®ãããªé質ã§ç沞ç¹ç¯å²ã®æ²¹ã«å¯ŸããŠãè¯
奜ãªæ§èœã瀺ããŠããããŸãããããã·ã«åºã®æ®
ã€ãŠããããªã¡ãããŒã«ãããã³ïŒPOïŒ9ïŒEOïŒ9
ããã³é žã¢ããšã¹ãã«ã§ã¯ã»ãšãã©å¹æã®ãªãã
ãšã瀺ããŠããã å®æœäŸ ïŒ å®æœäŸïŒã®æ·»å å€20éšãšïœâããã©ãã»ãã«ã³
ãã¯é žãžïŒïœâãªã¯ã¿ãã·ã«ïŒã¢ãã80éšã®é å
ç©ãæ¬çºæã®æ·»å å€ãšããã å®æœäŸ ïŒ å®æœäŸïŒã®æ·»å å€20éšãšïœâããã©ãã»ãã«ã³
ãã¯é žãžïŒïœâãªã¯ã¿ãã·ã«ïŒã¢ãã80éšã®é å
ç©ãæ¬çºæã®æ·»å å€ãšããã å®æœäŸ ïŒ å®æœäŸïŒã®æ·»å å€20éšãšããªã¡ãªããé žã®ãž
ïŒïœâãªã¯ã¿ãã·ã«ïŒã¢ãã³ãžã¢ãã80éšã®é å
ç©ãæ¬çºæã®æ·»å å€ãšããã 䜿çšäŸ ïŒ å®æœäŸïŒãïŒããã³ïŒã®æ·»å å€ãè¡šâïŒã«ç€ºã
ã軜油âïŒãïŒãïŒã«æ·»å ããŠPPãCFPPã枬
å®ãããçµæã¯è¡šâïŒã®éãã§ãã€ãã
ãè¡šã
è¡šâïŒããæãããªããã«(A)ãš(B)ã䜵çšãããš
(A)åç¬ ã§äœ¿çšããæãšCFPPã®éäžèœã¯ã»ãŒå
ãã§ãããPPéäžèœãå¢å¹ ããæå©ã§ããããš
ããããã å®æœäŸ ïŒ å®æœäŸïŒã«ãããŠãïœâããã©ãã»ãã«ã³ãã¯
é žãžïŒïœâãªã¯ã¿ãã·ã«ïŒã¢ããã«ä»£ããŠæ¯èŒäŸ
ïŒã®æ·»å å€ãçšããé åç©ãæ¬çºæã®æ·»å å€ãšã
ãã å®æœäŸ ïŒ å®æœäŸïŒã«ãããŠãïœâããã©ãã»ãã«ã³ãã¯
é žãžïŒïœâãªã¯ã¿ãã·ã«ïŒã¢ããã«ä»£ããŠæ¯èŒäŸ
ïŒã®æ·»å å€ãçšããé åç©ãæ¬çºæã®æ·»å å€ãšã
ãã å®æœäŸ ïŒ å®æœäŸïŒã«ãããŠãããªã¡ãªããé žã®ãžïŒïœâ
ãªã¯ã¿ãã·ã«ïŒã¢ãã³ãžã¢ããã«ä»£ããŠæ¯èŒäŸïŒ
ã®æ·»å å€ãçšããé åç©ãæ¬çºæã®æ·»å å€ãšã
ãã æ¯èŒäŸ ïŒ å®æœäŸïŒã«èšèŒã®ãïœâããã©ãã»ãã«ã³ãã¯
é žãžïŒïœâãªã¯ã¿ãã·ã«ïŒã¢ãããæ¯èŒäŸïŒã®æ·»
å å€ãšããã 䜿çšäŸ ïŒ å®æœäŸïŒãïŒãæ¯èŒäŸïŒã®æ·»å å€ãã䜿çšäŸïŒ
ãšåæ§ã«ããŠPP.CFPPã枬å®ããã çµæã¯è¡šâïŒã®éãã§ãã€ãã
(A)åç¬ ã§äœ¿çšããæãšCFPPã®éäžèœã¯ã»ãŒå
ãã§ãããPPéäžèœãå¢å¹ ããæå©ã§ããããš
ããããã å®æœäŸ ïŒ å®æœäŸïŒã«ãããŠãïœâããã©ãã»ãã«ã³ãã¯
é žãžïŒïœâãªã¯ã¿ãã·ã«ïŒã¢ããã«ä»£ããŠæ¯èŒäŸ
ïŒã®æ·»å å€ãçšããé åç©ãæ¬çºæã®æ·»å å€ãšã
ãã å®æœäŸ ïŒ å®æœäŸïŒã«ãããŠãïœâããã©ãã»ãã«ã³ãã¯
é žãžïŒïœâãªã¯ã¿ãã·ã«ïŒã¢ããã«ä»£ããŠæ¯èŒäŸ
ïŒã®æ·»å å€ãçšããé åç©ãæ¬çºæã®æ·»å å€ãšã
ãã å®æœäŸ ïŒ å®æœäŸïŒã«ãããŠãããªã¡ãªããé žã®ãžïŒïœâ
ãªã¯ã¿ãã·ã«ïŒã¢ãã³ãžã¢ããã«ä»£ããŠæ¯èŒäŸïŒ
ã®æ·»å å€ãçšããé åç©ãæ¬çºæã®æ·»å å€ãšã
ãã æ¯èŒäŸ ïŒ å®æœäŸïŒã«èšèŒã®ãïœâããã©ãã»ãã«ã³ãã¯
é žãžïŒïœâãªã¯ã¿ãã·ã«ïŒã¢ãããæ¯èŒäŸïŒã®æ·»
å å€ãšããã 䜿çšäŸ ïŒ å®æœäŸïŒãïŒãæ¯èŒäŸïŒã®æ·»å å€ãã䜿çšäŸïŒ
ãšåæ§ã«ããŠPP.CFPPã枬å®ããã çµæã¯è¡šâïŒã®éãã§ãã€ãã
ãè¡šã
å®æœäŸ 10
å®æœäŸïŒã«ãããŠãïœâããã©ãã»ãã«ã³ãã¯
é žãžïŒïœâãªã¯ã¿ãã·ã«ïŒã¢ããã«ä»£ããŠé·éã¢
ã«ãã«ãå«ãã¡ã¿ã¯ãªã«é žå ±éåäœãçšããé å
ç©ãæ¬çºæã®æ·»å å€ãšããã å®æœäŸ 11 å®æœäŸïŒã«ãããŠãïœâããã©ãã»ãã«ã³ãã¯
é žãžïŒïœâãªã¯ã¿ãã·ã«ïŒã¢ããã«ä»£ããŠé·éã¢
ã«ãã«ãå«ãã¡ã¿ã¯ãªã«é žå ±éåäœãçšããé å
ç©ãæ¬çºæã®æ·»å å€ãšããã å®æœäŸ 12 å®æœäŸïŒã«ãããŠãããªã¡ãªããé žã®ãžïŒïœâ
ãªã¯ã¿ãã·ã«ïŒã¢ãã³ãžã¢ããã«ä»£ããŠé·éã¢ã«
ãã«ãå«ãã¡ã¿ã¯ãªã«é žå ±éåäœãçšããé åç©
ãæ¬çºæã®æ·»å å€ãšããã æ¯èŒäŸ ïŒ æ¯èŒã®ãããé·éã¢ã«ãã«ãå«ãã¡ã¿ã¯ãªã«é ž
å ±éåäœãæ¯èŒäŸïŒã®æ·»å å€ãšããã 䜿çšäŸ ïŒ å®æœäŸ10ã12ãæ¯èŒäŸïŒã®æ·»å å€ãã䜿çšäŸïŒ
ãšåæ§ã«ããŠPPãCFPPã枬å®ããã çµæã¯è¡šâïŒã®éãã§ãã€ãã
é žãžïŒïœâãªã¯ã¿ãã·ã«ïŒã¢ããã«ä»£ããŠé·éã¢
ã«ãã«ãå«ãã¡ã¿ã¯ãªã«é žå ±éåäœãçšããé å
ç©ãæ¬çºæã®æ·»å å€ãšããã å®æœäŸ 11 å®æœäŸïŒã«ãããŠãïœâããã©ãã»ãã«ã³ãã¯
é žãžïŒïœâãªã¯ã¿ãã·ã«ïŒã¢ããã«ä»£ããŠé·éã¢
ã«ãã«ãå«ãã¡ã¿ã¯ãªã«é žå ±éåäœãçšããé å
ç©ãæ¬çºæã®æ·»å å€ãšããã å®æœäŸ 12 å®æœäŸïŒã«ãããŠãããªã¡ãªããé žã®ãžïŒïœâ
ãªã¯ã¿ãã·ã«ïŒã¢ãã³ãžã¢ããã«ä»£ããŠé·éã¢ã«
ãã«ãå«ãã¡ã¿ã¯ãªã«é žå ±éåäœãçšããé åç©
ãæ¬çºæã®æ·»å å€ãšããã æ¯èŒäŸ ïŒ æ¯èŒã®ãããé·éã¢ã«ãã«ãå«ãã¡ã¿ã¯ãªã«é ž
å ±éåäœãæ¯èŒäŸïŒã®æ·»å å€ãšããã 䜿çšäŸ ïŒ å®æœäŸ10ã12ãæ¯èŒäŸïŒã®æ·»å å€ãã䜿çšäŸïŒ
ãšåæ§ã«ããŠPPãCFPPã枬å®ããã çµæã¯è¡šâïŒã®éãã§ãã€ãã
ãè¡šã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ (A)ã¢ã«ã«ã³ããªãªãŒã«ã®ããªãªãã·ã¢ã«ãã¬
ã³ãšãŒãã«ïŒè©²ãšãŒãã«ã®å¹³åååéã¯250ã
6000ã§ããïŒãšççŽ æ°14ã30ã®çŽé飜åèèªé ž(c)
ãŸãã¯è©²èèªé ž(c)ãšä»ã®ã«ã«ãã³é žãšã®æ··åã«ã«
ãã³é žïŒcâ²ïŒãšã®å®å šãšã¹ãã«ïŒããã³å¿ èŠã«ã
ã(B)ã¢ã«ã±ãã«ã³ãã¯é žã®å«çªçŽ èªå°äœãå¡©çŽ å
ãã©ãã€ã³ãšããã¿ã¬ã³ãšã®çž®åç©ãé·éã¢ã«ã
ã¬ã³ãžã«ã«ãã³é žã®å«çªçŽ èªå°äœãããªã«ã«ãã³
é žã®å«çªçŽ èªå°äœããã³ãžã€ãœã·ã¢ããŒãååç©
ãšãžã¢ã«ãã«ã¢ãã³ãšã®åå¿ç©ãããªã矀ããéž
ã°ããååç©ãå«æããããšãç¹åŸŽãšããçææ²¹
çšæµåæ§æ¹è¯æ·»å å€ã ïŒ å®å šãšã¹ãã«ãäžè¬åŒ ïŒåŒäžãã¯ã¢ã«ã«ã³ããªãªãŒã«ã®æ®åºïŒïŒ¡ã¯ç
çŽ æ°ïŒãïŒã®ã¢ã«ãã¬ã³åºïŒRâ²ã¯ã«ã«ãã³é žæ®
åºã§ãããïŒåã®Râ²ã®ãã¡å°ãªããšãïŒåã¯ç
çŽ æ°14ã30ã®çŽé飜åèèªé žã®æ®åºã§ãããïœã¯
âãïŒAOïŒâoOHã3ã®å¹³åååéã250ã6000ã«
ãªãæ°ã§ãããïŒã§ç€ºãããååç©ã§ããç¹èš±è«
æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ·»å å€ã ïŒ (A)ãš(B)ã®ééæ¯ãïŒïŒ98ã98ïŒïŒã§ããç¹èš±
è«æ±ã®ç¯å²ç¬¬ïŒé ãŸãã¯ç¬¬ïŒé èšèŒã®æ·»å å€ã ïŒ (B)ã®ã¢ã«ã±ãã«ã³ãã¯é žã®å«çªçŽ èªå°äœãç
çŽ æ°14ã22ã¢ã«ã±ãã«åºããã€ã¢ã«ã±ãã«ã³ãã¯
é žãŸãã¯ãã®ç¡æ°Žç©ãšã¢ã«ãã«åºã®ççŽ æ°ã14ã
20ã®ãžã¢ã«ãã«ã¢ãã³ãšã®åå¿ç©ã§ããç¹èš±è«æ±
ã®ç¯å²ç¬¬ïŒãïŒé ã®ããããèšèŒã®æ·»å å€ã ïŒ (A)ãšããšãã¬ã³âé ¢é žããã«å ±éåäœããšã
ã¬ã³âã¢ã¯ãªã«é žãšã¹ãã«å ±éåäœãå¡©çŽ åãã©
ãã€ã³ãé·éã¢ã«ãã«åºãå«ãïŒã¡ã¿ïŒã¢ã¯ãªã«
é žå ±éåäœãããªã矀ããéžã°ããéåäœåæµå
æ§åäžå€ã䜵çšããŠãªãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ãŸ
ãã¯ç¬¬ïŒé èšèŒã®æ·»å å€ã
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23485583A JPS60127392A (ja) | 1983-12-12 | 1983-12-12 | çææ²¹çšæµåæ§æ¹è¯æ·»å å€ |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23485583A JPS60127392A (ja) | 1983-12-12 | 1983-12-12 | çææ²¹çšæµåæ§æ¹è¯æ·»å å€ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60127392A JPS60127392A (ja) | 1985-07-08 |
| JPH0251477B2 true JPH0251477B2 (ja) | 1990-11-07 |
Family
ID=16977402
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23485583A Granted JPS60127392A (ja) | 1983-12-12 | 1983-12-12 | çææ²¹çšæµåæ§æ¹è¯æ·»å å€ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60127392A (ja) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007169648A (ja) * | 2005-12-22 | 2007-07-05 | Clariant Produkte (Deutschland) Gmbh | åäžããäœæž©æµåæ§ãæããæž æµæ·»å å€ãå«æããé±æ²¹ |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01103699A (ja) * | 1987-07-28 | 1989-04-20 | Sumitomo Chem Co Ltd | çææ²¹çµæç© |
| DE10155774B4 (de) * | 2001-11-14 | 2020-07-02 | Clariant Produkte (Deutschland) Gmbh | Additive fÌr schwefelarme Mineralöldestillate, umfassend einen Ester alkoxylierten Glycerins und einen polaren stickstoffhaltigen Paraffindispergator |
| JP4645073B2 (ja) * | 2004-06-21 | 2011-03-09 | æ¥æ²¹æ ªåŒäŒç€Ÿ | çææ²¹çšæ·»å å€åã³çææ²¹çµæç© |
| JP4617862B2 (ja) * | 2004-12-13 | 2011-01-26 | æ¥æ²¹æ ªåŒäŒç€Ÿ | ãã£ãŒãŒã«ãšã³ãžã³çšçææ²¹çµæç© |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5464503A (en) * | 1977-10-13 | 1979-05-24 | Lubrizol Corp | Fuel and lubricant composition*its manufacture and additive condensate |
| JPS5549082A (en) * | 1978-10-03 | 1980-04-08 | Philips Nv | Reproducer |
| JPS55164295A (en) * | 1979-06-09 | 1980-12-20 | Nippon Oil & Fats Co Ltd | Deposit prevention of petroleum sludge |
| JPS57159532A (en) * | 1981-03-27 | 1982-10-01 | Dai Ichi Kogyo Seiyaku Co Ltd | Dispersant for oily system |
| JPS57177092A (en) * | 1981-03-31 | 1982-10-30 | Exxon Research Engineering Co | Glycol ester flow improving additive for distilled fuel |
-
1983
- 1983-12-12 JP JP23485583A patent/JPS60127392A/ja active Granted
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5464503A (en) * | 1977-10-13 | 1979-05-24 | Lubrizol Corp | Fuel and lubricant composition*its manufacture and additive condensate |
| JPS5549082A (en) * | 1978-10-03 | 1980-04-08 | Philips Nv | Reproducer |
| JPS55164295A (en) * | 1979-06-09 | 1980-12-20 | Nippon Oil & Fats Co Ltd | Deposit prevention of petroleum sludge |
| JPS57159532A (en) * | 1981-03-27 | 1982-10-01 | Dai Ichi Kogyo Seiyaku Co Ltd | Dispersant for oily system |
| JPS57177092A (en) * | 1981-03-31 | 1982-10-30 | Exxon Research Engineering Co | Glycol ester flow improving additive for distilled fuel |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007169648A (ja) * | 2005-12-22 | 2007-07-05 | Clariant Produkte (Deutschland) Gmbh | åäžããäœæž©æµåæ§ãæããæž æµæ·»å å€ãå«æããé±æ²¹ |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS60127392A (ja) | 1985-07-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| AU2004205788B2 (en) | Cerium oxide nanoparticles as fuel additives | |
| KR900000894B1 (ko) | ì°ë£ì ì ëì ëì± í¥ìë°©ë² | |
| JP2508783B2 (ja) | çææ²¹çšæµåæ§åäžå€ | |
| US8044232B2 (en) | Surface-active polymer and its use in a water-in-oil emulsion | |
| JP2003268392A (ja) | ç¡æ°Žãããã«ã«ãã«ãã¯ãé žãšããããã·ã¢ãã³ããçããããçæ最æ»çšæ·»å å€ããã³ãããå«æãããäžæºçæ | |
| JPH0251477B2 (ja) | ||
| JPH0334790B2 (ja) | ||
| JPS61181892A (ja) | çææ²¹ã®æµåæ§æ¹è¯å€ | |
| JP3725347B2 (ja) | çææ²¹äœæž©æµåæ§åäžå€ããã³çææ²¹çµæç© | |
| JP3844088B2 (ja) | 最æ»æ§èœãæ¹åããã軜油çµæç© | |
| JP2551917B2 (ja) | çææ²¹çšæµåæ§åäžå€ããã³çææ²¹çµæç© | |
| JP3747293B2 (ja) | çææ²¹çšæ·»å å€ | |
| JP2602497B2 (ja) | çææ²¹çšæµåæ§æ¹è¯å€ | |
| WO1998021446A1 (en) | Inhibitors and their uses in oils | |
| US20040237385A1 (en) | Lubricity improver for diesel oil | |
| JPS6323990A (ja) | çææ²¹çšæµåæ§æ¹è¯å€ | |
| JPH0525275B2 (ja) | ||
| JP3342871B2 (ja) | ã¢ããã¢ã«ãã¬ã³ã«ã«ãã³é žã®åå¿çæç©åã³ãããå«æããé±æ²¹äžéçå | |
| JPS6260439B2 (ja) | ||
| JP3747294B2 (ja) | çææ²¹çµæç©åã³ãã®è£œé æ¹æ³ | |
| JPH0446998B2 (ja) | ||
| JPS63245488A (ja) | çææ²¹çšæµåæ§æ¹è¯å€ | |
| JP2903202B2 (ja) | çææ²¹çšæµåæ§åäžå€ããã³çææ²¹çµæç© | |
| JPS61213292A (ja) | çææ²¹ã®æµåæ§æ¹è¯å€ | |
| JPH0710982B2 (ja) | æµåæ§åäžå€ |