JPH0157125B2 - - Google Patents
Info
- Publication number
- JPH0157125B2 JPH0157125B2 JP62058145A JP5814587A JPH0157125B2 JP H0157125 B2 JPH0157125 B2 JP H0157125B2 JP 62058145 A JP62058145 A JP 62058145A JP 5814587 A JP5814587 A JP 5814587A JP H0157125 B2 JPH0157125 B2 JP H0157125B2
- Authority
- JP
- Japan
- Prior art keywords
- fluorine
- bromo
- iodo
- iodine
- containing elastomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001971 elastomer Polymers 0.000 claims description 64
- 229910052731 fluorine Inorganic materials 0.000 claims description 60
- 239000011737 fluorine Substances 0.000 claims description 60
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 59
- 239000000806 elastomer Substances 0.000 claims description 40
- -1 bromine compound Chemical class 0.000 claims description 31
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 26
- 229910052740 iodine Inorganic materials 0.000 claims description 26
- 239000011630 iodine Substances 0.000 claims description 26
- 238000006116 polymerization reaction Methods 0.000 claims description 26
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 22
- 229910052794 bromium Inorganic materials 0.000 claims description 22
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 150000001336 alkenes Chemical class 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 9
- 239000003505 polymerization initiator Substances 0.000 claims description 8
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 7
- 150000005827 chlorofluoro hydrocarbons Chemical group 0.000 claims description 4
- 150000001993 dienes Chemical class 0.000 claims description 4
- 150000002430 hydrocarbons Chemical group 0.000 claims description 4
- 238000007717 redox polymerization reaction Methods 0.000 claims 1
- 238000000034 method Methods 0.000 description 23
- 239000007789 gas Substances 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 229920000642 polymer Polymers 0.000 description 16
- 238000004073 vulcanization Methods 0.000 description 16
- 229920001577 copolymer Polymers 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 14
- 239000008367 deionised water Substances 0.000 description 12
- 229910021641 deionized water Inorganic materials 0.000 description 12
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 11
- ZYNPYKGTNSXKPI-UHFFFAOYSA-N 1-bromo-1,1,2,2-tetrafluoro-2-iodoethane Chemical compound FC(F)(Br)C(F)(F)I ZYNPYKGTNSXKPI-UHFFFAOYSA-N 0.000 description 11
- 150000001451 organic peroxides Chemical class 0.000 description 11
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 11
- 239000000203 mixture Substances 0.000 description 10
- 239000000178 monomer Substances 0.000 description 9
- 238000007906 compression Methods 0.000 description 8
- 230000006835 compression Effects 0.000 description 8
- 238000004132 cross linking Methods 0.000 description 8
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 7
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 7
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 238000010060 peroxide vulcanization Methods 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- YOALFLHFSFEMLP-UHFFFAOYSA-N azane;2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanoic acid Chemical compound [NH4+].[O-]C(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YOALFLHFSFEMLP-UHFFFAOYSA-N 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 6
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical compound FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 6
- 239000005060 rubber Substances 0.000 description 6
- 229920001897 terpolymer Polymers 0.000 description 6
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 5
- 235000011126 aluminium potassium sulphate Nutrition 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 5
- 229940050271 potassium alum Drugs 0.000 description 5
- GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 229920006027 ternary co-polymer Polymers 0.000 description 5
- BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 4
- 150000002497 iodine compounds Chemical class 0.000 description 4
- 150000002978 peroxides Chemical class 0.000 description 4
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- LGPPATCNSOSOQH-UHFFFAOYSA-N 1,1,2,3,4,4-hexafluorobuta-1,3-diene Chemical compound FC(F)=C(F)C(F)=C(F)F LGPPATCNSOSOQH-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 238000010926 purge Methods 0.000 description 3
- DDMOUSALMHHKOS-UHFFFAOYSA-N 1,2-dichloro-1,1,2,2-tetrafluoroethane Chemical compound FC(F)(Cl)C(F)(F)Cl DDMOUSALMHHKOS-UHFFFAOYSA-N 0.000 description 2
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 2
- AYCANDRGVPTASA-UHFFFAOYSA-N 1-bromo-1,2,2-trifluoroethene Chemical group FC(F)=C(F)Br AYCANDRGVPTASA-UHFFFAOYSA-N 0.000 description 2
- WCIOJVGOBKXQPK-UHFFFAOYSA-N 1-ethenoxy-3-propoxypropane Chemical compound CCCOCCCOC=C WCIOJVGOBKXQPK-UHFFFAOYSA-N 0.000 description 2
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 2
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
- IVIVPNPSOKZKJQ-UHFFFAOYSA-N 2-bromo-1-chloro-1-iodoethane Chemical compound ClC(I)CBr IVIVPNPSOKZKJQ-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 235000010323 ascorbic acid Nutrition 0.000 description 2
- 229960005070 ascorbic acid Drugs 0.000 description 2
- 239000011668 ascorbic acid Substances 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- WUHPSARYLVYQOT-UHFFFAOYSA-N bromo-chloro-iodomethane Chemical compound ClC(Br)I WUHPSARYLVYQOT-UHFFFAOYSA-N 0.000 description 2
- 239000012986 chain transfer agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- HQWPLXHWEZZGKY-UHFFFAOYSA-N diethylzinc Chemical compound CC[Zn]CC HQWPLXHWEZZGKY-UHFFFAOYSA-N 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- DGLRDKLJZLEJCY-UHFFFAOYSA-L disodium hydrogenphosphate dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].OP([O-])([O-])=O DGLRDKLJZLEJCY-UHFFFAOYSA-L 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- 150000002367 halogens Chemical group 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- ZQBFAOFFOQMSGJ-UHFFFAOYSA-N hexafluorobenzene Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1F ZQBFAOFFOQMSGJ-UHFFFAOYSA-N 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 229910000464 lead oxide Inorganic materials 0.000 description 2
- 150000002902 organometallic compounds Chemical class 0.000 description 2
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 2
- 235000010265 sodium sulphite Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
- LALRXNPLTWZJIJ-UHFFFAOYSA-N triethylborane Chemical compound CCB(CC)CC LALRXNPLTWZJIJ-UHFFFAOYSA-N 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- OSXLRDYJNUYAQG-UHFFFAOYSA-N (1-bromo-1,2,2-trifluoro-2-iodoethyl)benzene Chemical compound FC(F)(I)C(F)(Br)C1=CC=CC=C1 OSXLRDYJNUYAQG-UHFFFAOYSA-N 0.000 description 1
- WRXCBRHBHGNNQA-UHFFFAOYSA-N (2,4-dichlorobenzoyl) 2,4-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC(Cl)=CC=C1C(=O)OOC(=O)C1=CC=C(Cl)C=C1Cl WRXCBRHBHGNNQA-UHFFFAOYSA-N 0.000 description 1
- WSRKYYKHNUTYFT-UHFFFAOYSA-N (2-bromo-1,2,2-trifluoro-1-iodoethyl)benzene Chemical compound FC(F)(Br)C(F)(I)C1=CC=CC=C1 WSRKYYKHNUTYFT-UHFFFAOYSA-N 0.000 description 1
- KDGNCLDCOVTOCS-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy propan-2-yl carbonate Chemical compound CC(C)OC(=O)OOC(C)(C)C KDGNCLDCOVTOCS-UHFFFAOYSA-N 0.000 description 1
- RIPYNJLMMFGZSX-UHFFFAOYSA-N (5-benzoylperoxy-2,5-dimethylhexan-2-yl) benzenecarboperoxoate Chemical compound C=1C=CC=CC=1C(=O)OOC(C)(C)CCC(C)(C)OOC(=O)C1=CC=CC=C1 RIPYNJLMMFGZSX-UHFFFAOYSA-N 0.000 description 1
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 description 1
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- RKIMETXDACNTIE-UHFFFAOYSA-N 1,1,2,2,3,3,4,4,5,5,6,6-dodecafluorocyclohexane Chemical compound FC1(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C1(F)F RKIMETXDACNTIE-UHFFFAOYSA-N 0.000 description 1
- RBTROQHBNLSUTL-UHFFFAOYSA-N 1,1,2,2,3,4-hexafluoro-3,4-bis(trifluoromethyl)cyclobutane Chemical compound FC(F)(F)C1(F)C(F)(F)C(F)(F)C1(F)C(F)(F)F RBTROQHBNLSUTL-UHFFFAOYSA-N 0.000 description 1
- UGCSPKPEHQEOSR-UHFFFAOYSA-N 1,1,2,2-tetrachloro-1,2-difluoroethane Chemical compound FC(Cl)(Cl)C(F)(Cl)Cl UGCSPKPEHQEOSR-UHFFFAOYSA-N 0.000 description 1
- AEGUVNHLYAZFAU-UHFFFAOYSA-N 1,1,2,3,3,4,4,5,5,6,6,7,8,8-tetradecafluoroocta-1,7-diene Chemical compound FC(F)=C(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)=C(F)F AEGUVNHLYAZFAU-UHFFFAOYSA-N 0.000 description 1
- TUPKEVIZDLRARX-UHFFFAOYSA-N 1,1,2,3,3,4,4,5,6,6-decafluorohexa-1,5-diene Chemical compound FC(F)=C(F)C(F)(F)C(F)(F)C(F)=C(F)F TUPKEVIZDLRARX-UHFFFAOYSA-N 0.000 description 1
- FRCZRYZUJVSGKJ-UHFFFAOYSA-N 1,1,2,3,3-pentafluoropenta-1,4-diene Chemical compound FC(F)=C(F)C(F)(F)C=C FRCZRYZUJVSGKJ-UHFFFAOYSA-N 0.000 description 1
- NDMMKOCNFSTXRU-UHFFFAOYSA-N 1,1,2,3,3-pentafluoroprop-1-ene Chemical compound FC(F)C(F)=C(F)F NDMMKOCNFSTXRU-UHFFFAOYSA-N 0.000 description 1
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 1
- FWTUDISDSYABRU-UHFFFAOYSA-N 1,1,2-trifluorobuta-1,3-diene Chemical compound FC(F)=C(F)C=C FWTUDISDSYABRU-UHFFFAOYSA-N 0.000 description 1
- MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical group FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 description 1
- QWSXJTYKCBAUTM-UHFFFAOYSA-N 1,1,2-trifluoropenta-1,4-diene Chemical compound FC(F)=C(F)CC=C QWSXJTYKCBAUTM-UHFFFAOYSA-N 0.000 description 1
- NALFRYPTRXKZPN-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane Chemical compound CC1CC(C)(C)CC(OOC(C)(C)C)(OOC(C)(C)C)C1 NALFRYPTRXKZPN-UHFFFAOYSA-N 0.000 description 1
- MHDBWTRDEVNJDK-UHFFFAOYSA-N 1,1-dibromo-1,2,2-trifluoro-2-iodoethane Chemical compound FC(F)(I)C(F)(Br)Br MHDBWTRDEVNJDK-UHFFFAOYSA-N 0.000 description 1
- XHGMOUXCWNPJHF-UHFFFAOYSA-N 1,1-difluoroethene;1,1,2,3,3,3-hexafluoroprop-1-ene;1,1,2,2-tetrafluoroethene Chemical group FC(F)=C.FC(F)=C(F)F.FC(F)=C(F)C(F)(F)F XHGMOUXCWNPJHF-UHFFFAOYSA-N 0.000 description 1
- SUTQSIHGGHVXFK-UHFFFAOYSA-N 1,2,2-trifluoroethenylbenzene Chemical compound FC(F)=C(F)C1=CC=CC=C1 SUTQSIHGGHVXFK-UHFFFAOYSA-N 0.000 description 1
- QVHWOZCZUNPZPW-UHFFFAOYSA-N 1,2,3,3,4,4-hexafluorocyclobutene Chemical compound FC1=C(F)C(F)(F)C1(F)F QVHWOZCZUNPZPW-UHFFFAOYSA-N 0.000 description 1
- GZQZKLFXWPAMFW-UHFFFAOYSA-N 1,2,3,4,5-pentafluoro-6-(1,2,2-trifluoroethenyl)benzene Chemical compound FC(F)=C(F)C1=C(F)C(F)=C(F)C(F)=C1F GZQZKLFXWPAMFW-UHFFFAOYSA-N 0.000 description 1
- YUBJHLYGOOZDRN-UHFFFAOYSA-N 1,2-dibromo-1,1,2-trifluoro-2-iodoethane Chemical compound FC(F)(Br)C(F)(Br)I YUBJHLYGOOZDRN-UHFFFAOYSA-N 0.000 description 1
- WFLOTYSKFUPZQB-UHFFFAOYSA-N 1,2-difluoroethene Chemical group FC=CF WFLOTYSKFUPZQB-UHFFFAOYSA-N 0.000 description 1
- WOZVGAHPIHZYDB-UHFFFAOYSA-N 1,3,3-trifluoro-2-(trifluoromethyl)cyclopropene Chemical compound FC1=C(C(F)(F)F)C1(F)F WOZVGAHPIHZYDB-UHFFFAOYSA-N 0.000 description 1
- VSKRZGAHPADTKN-UHFFFAOYSA-N 1,3-dibromo-1,1,2,3,3-pentafluoro-2-iodopropane Chemical compound FC(F)(Br)C(F)(I)C(F)(F)Br VSKRZGAHPADTKN-UHFFFAOYSA-N 0.000 description 1
- GWQOYRSARAWVTC-UHFFFAOYSA-N 1,4-bis(2-tert-butylperoxypropan-2-yl)benzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=C(C(C)(C)OOC(C)(C)C)C=C1 GWQOYRSARAWVTC-UHFFFAOYSA-N 0.000 description 1
- NQSBUGFPVYOZPE-UHFFFAOYSA-N 1,4-dibromo-1,1,2,2,3,4,4-heptafluoro-3-iodobutane Chemical compound FC(F)(Br)C(F)(F)C(F)(I)C(F)(F)Br NQSBUGFPVYOZPE-UHFFFAOYSA-N 0.000 description 1
- DLDJOUCIGKCPJB-UHFFFAOYSA-N 1,4-dibromo-1,1,2,2-tetrafluoro-3-iodobutane Chemical compound FC(F)(Br)C(F)(F)C(I)CBr DLDJOUCIGKCPJB-UHFFFAOYSA-N 0.000 description 1
- IPJGAEWUPXWFPL-UHFFFAOYSA-N 1-[3-(2,5-dioxopyrrol-1-yl)phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC(N2C(C=CC2=O)=O)=C1 IPJGAEWUPXWFPL-UHFFFAOYSA-N 0.000 description 1
- FPYMBRJPVPWOOF-UHFFFAOYSA-N 1-bromo-1,1,2,2,3,3,4,4-octafluoro-4-iodobutane Chemical compound FC(F)(Br)C(F)(F)C(F)(F)C(F)(F)I FPYMBRJPVPWOOF-UHFFFAOYSA-N 0.000 description 1
- WHFBTQVXURKRCS-UHFFFAOYSA-N 1-bromo-1,1,2,2,3,3-hexafluoro-3-iodopropane Chemical compound FC(F)(Br)C(F)(F)C(F)(F)I WHFBTQVXURKRCS-UHFFFAOYSA-N 0.000 description 1
- BTQZUYNSEJJLRP-UHFFFAOYSA-N 1-bromo-1,1,2-trifluoro-2-iodoethane Chemical compound FC(I)C(F)(F)Br BTQZUYNSEJJLRP-UHFFFAOYSA-N 0.000 description 1
- QFUPCQOEAWRBJY-UHFFFAOYSA-N 1-bromo-1,1,3,3,3-pentafluoro-2-iodo-2-(trifluoromethyl)propane Chemical compound FC(F)(F)C(I)(C(F)(F)F)C(F)(F)Br QFUPCQOEAWRBJY-UHFFFAOYSA-N 0.000 description 1
- QWNMDXFAEWEEGU-UHFFFAOYSA-N 1-bromo-1,1,3,3,3-pentafluoro-2-iodopropane Chemical compound FC(F)(F)C(I)C(F)(F)Br QWNMDXFAEWEEGU-UHFFFAOYSA-N 0.000 description 1
- ZHVTUQCSZQAJBO-UHFFFAOYSA-N 1-bromo-1,1-dichloro-2-iodoethane Chemical compound ClC(Cl)(Br)CI ZHVTUQCSZQAJBO-UHFFFAOYSA-N 0.000 description 1
- YHXBPTMWEVZYKI-UHFFFAOYSA-N 1-bromo-1,1-difluoro-2-iodoethane Chemical compound FC(F)(Br)CI YHXBPTMWEVZYKI-UHFFFAOYSA-N 0.000 description 1
- FAPGSCPYPKJSMQ-UHFFFAOYSA-N 1-bromo-1,2,2-trifluoro-1,2-diiodoethane Chemical compound FC(F)(I)C(F)(Br)I FAPGSCPYPKJSMQ-UHFFFAOYSA-N 0.000 description 1
- PQHSQXYTCWSJII-UHFFFAOYSA-N 1-bromo-1,2,2-trifluoro-2-iodo-1-methoxyethane Chemical compound COC(F)(Br)C(F)(F)I PQHSQXYTCWSJII-UHFFFAOYSA-N 0.000 description 1
- MAYVQPHNAMGGRG-UHFFFAOYSA-N 1-bromo-1-chloro-1,2,2-trifluoro-2-iodoethane Chemical compound FC(F)(I)C(F)(Cl)Br MAYVQPHNAMGGRG-UHFFFAOYSA-N 0.000 description 1
- XNJBEFHLFOJVIM-UHFFFAOYSA-N 1-bromo-1-chloro-2-iodoethane Chemical compound ClC(Br)CI XNJBEFHLFOJVIM-UHFFFAOYSA-N 0.000 description 1
- KUCYTFNRNXWBMD-UHFFFAOYSA-N 1-bromo-1-fluoro-2-iodoethane Chemical compound FC(Br)CI KUCYTFNRNXWBMD-UHFFFAOYSA-N 0.000 description 1
- RAVFYHBLDJHLGL-UHFFFAOYSA-N 1-bromo-2-chloro-1,1,2-trifluoro-2-iodoethane Chemical compound FC(F)(Br)C(F)(Cl)I RAVFYHBLDJHLGL-UHFFFAOYSA-N 0.000 description 1
- YYXZXVKJHZLXBZ-UHFFFAOYSA-N 1-bromo-2-chloro-1,2,2-trifluoro-1-iodoethane Chemical compound FC(F)(Cl)C(F)(Br)I YYXZXVKJHZLXBZ-UHFFFAOYSA-N 0.000 description 1
- SLHWROGCLXPCIX-UHFFFAOYSA-N 1-bromo-2-chloro-3-(1-chloro-1,2,2-trifluoro-2-iodoethoxy)-1,1,2,3,3-pentafluoropropane Chemical compound IC(C(OC(C(C(Br)(F)F)(Cl)F)(F)F)(Cl)F)(F)F SLHWROGCLXPCIX-UHFFFAOYSA-N 0.000 description 1
- DOINMEJSPQSOMF-UHFFFAOYSA-N 1-bromo-2-ethoxy-1,1,2-trifluoro-2-iodoethane Chemical compound CCOC(F)(I)C(F)(F)Br DOINMEJSPQSOMF-UHFFFAOYSA-N 0.000 description 1
- RVEJZBIPHJKAMS-UHFFFAOYSA-N 1-bromo-2-iodobutane Chemical compound CCC(I)CBr RVEJZBIPHJKAMS-UHFFFAOYSA-N 0.000 description 1
- HKQCJJOXYWQRFN-UHFFFAOYSA-N 1-bromo-2-iodoethane Chemical compound BrCCI HKQCJJOXYWQRFN-UHFFFAOYSA-N 0.000 description 1
- LKVPLELRULCBKF-UHFFFAOYSA-N 1-bromo-2-iodopropane Chemical compound CC(I)CBr LKVPLELRULCBKF-UHFFFAOYSA-N 0.000 description 1
- CJJMXEVOMLWYEB-UHFFFAOYSA-N 1-chloro-1,2,2-trifluoroethene;1,1-difluoroethene;1,1,2,3,3,3-hexafluoroprop-1-ene Chemical group FC(F)=C.FC(F)=C(F)Cl.FC(F)=C(F)C(F)(F)F CJJMXEVOMLWYEB-UHFFFAOYSA-N 0.000 description 1
- SMNFKNGBGMBAHK-UHFFFAOYSA-N 1-ethenoxy-1,2,2-trifluoroethene Chemical compound FC(F)=C(F)OC=C SMNFKNGBGMBAHK-UHFFFAOYSA-N 0.000 description 1
- OZCMOJQQLBXBKI-UHFFFAOYSA-N 1-ethenoxy-2-methylpropane Chemical compound CC(C)COC=C OZCMOJQQLBXBKI-UHFFFAOYSA-N 0.000 description 1
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- TVYRMULDUQGHBU-UHFFFAOYSA-N 2-(bromomethyl)-1,1,1,3,3,3-hexafluoro-2-iodopropane Chemical compound FC(F)(F)C(I)(CBr)C(F)(F)F TVYRMULDUQGHBU-UHFFFAOYSA-N 0.000 description 1
- JXJOCUZLOZDGAY-UHFFFAOYSA-N 2-bromo-1,1,1,2,3,4,4,4-octafluoro-3-iodobutane Chemical compound FC(F)(F)C(F)(Br)C(F)(I)C(F)(F)F JXJOCUZLOZDGAY-UHFFFAOYSA-N 0.000 description 1
- PHFNNKVECBHCNH-UHFFFAOYSA-N 2-bromo-1,1,1,3,3,3-hexafluoro-2-(iodomethyl)propane Chemical compound FC(F)(F)C(Br)(CI)C(F)(F)F PHFNNKVECBHCNH-UHFFFAOYSA-N 0.000 description 1
- BSHZJZJCDWRIHD-UHFFFAOYSA-N 2-bromo-1,1,1,3,3-pentafluoro-3-iodopropane Chemical compound FC(F)(F)C(Br)C(F)(F)I BSHZJZJCDWRIHD-UHFFFAOYSA-N 0.000 description 1
- JBMFBBSTEQPRJQ-UHFFFAOYSA-N 2-bromo-1,1,2,3,3,4,4-heptafluoro-1,4-diiodobutane Chemical compound FC(F)(I)C(F)(F)C(F)(Br)C(F)(F)I JBMFBBSTEQPRJQ-UHFFFAOYSA-N 0.000 description 1
- RLQLXOJSNNBGBF-UHFFFAOYSA-N 2-bromo-1,1,2,3,3-pentafluoro-1,3-diiodopropane Chemical compound FC(F)(I)C(F)(Br)C(F)(F)I RLQLXOJSNNBGBF-UHFFFAOYSA-N 0.000 description 1
- OOYWCRJPFDIDJF-UHFFFAOYSA-N 2-bromo-1,1,2-trifluoro-1-iodoethane Chemical compound FC(Br)C(F)(F)I OOYWCRJPFDIDJF-UHFFFAOYSA-N 0.000 description 1
- LFNCSMYARNDZQT-UHFFFAOYSA-N 2-bromo-1,1-difluoro-1-iodoethane Chemical compound FC(F)(I)CBr LFNCSMYARNDZQT-UHFFFAOYSA-N 0.000 description 1
- JATYZZCNEHBCJV-UHFFFAOYSA-N 2-bromo-1-fluoro-1-iodoethane Chemical compound FC(I)CBr JATYZZCNEHBCJV-UHFFFAOYSA-N 0.000 description 1
- HYESVVKSUYUZKJ-UHFFFAOYSA-N 2-bromo-1-iodobutane Chemical compound CCC(Br)CI HYESVVKSUYUZKJ-UHFFFAOYSA-N 0.000 description 1
- QEBGRPQAKNUHIS-UHFFFAOYSA-N 2-bromo-1-iodopropane Chemical compound CC(Br)CI QEBGRPQAKNUHIS-UHFFFAOYSA-N 0.000 description 1
- 125000005999 2-bromoethyl group Chemical group 0.000 description 1
- FIIVGPMBWVKOIF-UHFFFAOYSA-N 2-chloro-1,1,2-trifluoro-1-iodoethane Chemical compound FC(Cl)C(F)(F)I FIIVGPMBWVKOIF-UHFFFAOYSA-N 0.000 description 1
- KRDXTHSSNCTAGY-UHFFFAOYSA-N 2-cyclohexylpyrrolidine Chemical compound C1CCNC1C1CCCCC1 KRDXTHSSNCTAGY-UHFFFAOYSA-N 0.000 description 1
- PGYJSURPYAAOMM-UHFFFAOYSA-N 2-ethenoxy-2-methylpropane Chemical compound CC(C)(C)OC=C PGYJSURPYAAOMM-UHFFFAOYSA-N 0.000 description 1
- GNUGVECARVKIPH-UHFFFAOYSA-N 2-ethenoxypropane Chemical compound CC(C)OC=C GNUGVECARVKIPH-UHFFFAOYSA-N 0.000 description 1
- QMIWYOZFFSLIAK-UHFFFAOYSA-N 3,3,3-trifluoro-2-(trifluoromethyl)prop-1-ene Chemical compound FC(F)(F)C(=C)C(F)(F)F QMIWYOZFFSLIAK-UHFFFAOYSA-N 0.000 description 1
- YQRSSGXSTMFWAO-UHFFFAOYSA-N 3-bromo-1,1,1,2,2-pentafluoro-4-iodobutane Chemical compound FC(F)(F)C(F)(F)C(Br)CI YQRSSGXSTMFWAO-UHFFFAOYSA-N 0.000 description 1
- OKAOCEQMGLNDPU-UHFFFAOYSA-N 3-bromo-1,1,2,2-tetrafluoro-1,4-diiodobutane Chemical compound FC(F)(I)C(F)(F)C(Br)CI OKAOCEQMGLNDPU-UHFFFAOYSA-N 0.000 description 1
- QGRBBWULYFLOBP-UHFFFAOYSA-N 3-bromo-1,1,2,3,4,4-hexafluoro-4-iodobut-1-ene Chemical compound FC(F)=C(F)C(F)(Br)C(F)(F)I QGRBBWULYFLOBP-UHFFFAOYSA-N 0.000 description 1
- MKTOIPPVFPJEQO-UHFFFAOYSA-N 4-(3-carboxypropanoylperoxy)-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OOC(=O)CCC(O)=O MKTOIPPVFPJEQO-UHFFFAOYSA-N 0.000 description 1
- GGFHBNXGTWVPHP-UHFFFAOYSA-N 4-bromo-1,1,1,2,2-pentafluoro-3-iodobutane Chemical compound FC(F)(F)C(F)(F)C(I)CBr GGFHBNXGTWVPHP-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- YWXQUNJCSHJEGT-UHFFFAOYSA-N FC(C(F)(F)Br)(C(C(F)=C(C(C(C(F)(F)I)(F)F)=C1F)F)=C1F)F Chemical compound FC(C(F)(F)Br)(C(C(F)=C(C(C(C(F)(F)I)(F)F)=C1F)F)=C1F)F YWXQUNJCSHJEGT-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical class [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- DXXYTBCIXZGERI-UHFFFAOYSA-N O.O.O.O.O.O.O.[Fe] Chemical compound O.O.O.O.O.O.O.[Fe] DXXYTBCIXZGERI-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 229910018830 PO3H Inorganic materials 0.000 description 1
- 229910006069 SO3H Inorganic materials 0.000 description 1
- 229920006172 Tetrafluoroethylene propylene Polymers 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 125000006165 cyclic alkyl group Chemical group 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 229940087091 dichlorotetrafluoroethane Drugs 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 229920006226 ethylene-acrylic acid Polymers 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 229920005560 fluorosilicone rubber Polymers 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- CBEQRNSPHCCXSH-UHFFFAOYSA-N iodine monobromide Chemical compound IBr CBEQRNSPHCCXSH-UHFFFAOYSA-N 0.000 description 1
- SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- BCCOBQSFUDVTJQ-UHFFFAOYSA-N octafluorocyclobutane Chemical compound FC1(F)C(F)(F)C(F)(F)C1(F)F BCCOBQSFUDVTJQ-UHFFFAOYSA-N 0.000 description 1
- 235000019407 octafluorocyclobutane Nutrition 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- QYZLKGVUSQXAMU-UHFFFAOYSA-N penta-1,4-diene Chemical compound C=CCC=C QYZLKGVUSQXAMU-UHFFFAOYSA-N 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- YVBBRRALBYAZBM-UHFFFAOYSA-N perfluorooctane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YVBBRRALBYAZBM-UHFFFAOYSA-N 0.000 description 1
- RVZRBWKZFJCCIB-UHFFFAOYSA-N perfluorotributylamine Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)N(C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F RVZRBWKZFJCCIB-UHFFFAOYSA-N 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002589 poly(vinylethylene) polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000007348 radical reaction Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- PNWOTXLVRDKNJA-UHFFFAOYSA-N tert-butylperoxybenzene Chemical compound CC(C)(C)OOC1=CC=CC=C1 PNWOTXLVRDKNJA-UHFFFAOYSA-N 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- WZEOZJQLTRFNCU-UHFFFAOYSA-N trifluoro(trifluoromethoxy)methane Chemical compound FC(F)(F)OC(F)(F)F WZEOZJQLTRFNCU-UHFFFAOYSA-N 0.000 description 1
- GRPURDFRFHUDSP-UHFFFAOYSA-N tris(prop-2-enyl) benzene-1,2,4-tricarboxylate Chemical compound C=CCOC(=O)C1=CC=C(C(=O)OCC=C)C(C(=O)OCC=C)=C1 GRPURDFRFHUDSP-UHFFFAOYSA-N 0.000 description 1
- KJWHEZXBZQXVSA-UHFFFAOYSA-N tris(prop-2-enyl) phosphite Chemical compound C=CCOP(OCC=C)OCC=C KJWHEZXBZQXVSA-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5814587A JPS63308008A (ja) | 1986-04-01 | 1987-03-13 | パ−オキサイド加硫可能な含フツ素エラストマ−の製造方法 |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61-74483 | 1986-04-01 | ||
| JP7448386 | 1986-04-01 | ||
| JP62-21591 | 1987-01-03 | ||
| JP5814587A JPS63308008A (ja) | 1986-04-01 | 1987-03-13 | パ−オキサイド加硫可能な含フツ素エラストマ−の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63308008A JPS63308008A (ja) | 1988-12-15 |
| JPH0157125B2 true JPH0157125B2 (ru) | 1989-12-04 |
Family
ID=26399216
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5814587A Granted JPS63308008A (ja) | 1986-04-01 | 1987-03-13 | パ−オキサイド加硫可能な含フツ素エラストマ−の製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63308008A (ru) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006090728A1 (ja) * | 2005-02-23 | 2006-08-31 | Daikin Industries, Ltd. | 含フッ素エラストマーおよび含フッ素エラストマーの製造方法 |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000053835A (ja) | 1998-08-07 | 2000-02-22 | Nippon Mektron Ltd | 加硫性フッ素ゴム組成物 |
| JP4304841B2 (ja) * | 2000-07-28 | 2009-07-29 | ユニマテック株式会社 | 押出加工性に優れたゲル成分含有含フッ素エラストマー |
| JP4540868B2 (ja) * | 2001-03-15 | 2010-09-08 | 日本メクトロン株式会社 | 加硫可能なフッ素ゴム組成物とその用途 |
| JP4785713B2 (ja) * | 2002-04-23 | 2011-10-05 | ユニマテック株式会社 | 含フッ素エラストマーおよびその組成物 |
| JP4491547B2 (ja) * | 2002-04-23 | 2010-06-30 | Ｎｏｋ株式会社 | 含フッ素エラストマー組成物 |
| JP4640021B2 (ja) * | 2004-08-25 | 2011-03-02 | 旭硝子株式会社 | 含フッ素共重合体 |
| WO2009069320A1 (ja) * | 2007-11-28 | 2009-06-04 | Unimatec Co., Ltd. | フルオロエラストマーの製造法 |
| CA2723453C (en) | 2008-06-13 | 2012-12-04 | Unimatec Co., Ltd. | Polyfluoroalkadiene mixture and method for producing the same |
| GB201012944D0 (en) * | 2010-08-02 | 2010-09-15 | 3M Innovative Properties Co | Peroxide curable fluoroelastomers containing modifiers and iodine or bromine endgroups |
| JP6451626B2 (ja) * | 2013-04-26 | 2019-01-16 | Nok株式会社 | フッ素ゴム組成物 |
| JP7479848B2 (ja) * | 2017-06-30 | 2024-05-09 | ソルベイ スペシャルティ ポリマーズ イタリー エス．ピー．エー． | 部分フッ素化ポリマーの製造方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3937690A (en) * | 1972-06-19 | 1976-02-10 | Dynamit Nobel Aktiengesellschaft | Process for the preparation of thermoplastically workable fluoro-olefin polymers |
| US4000356A (en) * | 1972-06-19 | 1976-12-28 | Dynamit Nobel Aktiengesellschaft | Process for the preparation of thermoplastically workable fluoro-olefin polymers |
| JPS53125491A (en) * | 1977-04-08 | 1978-11-01 | Daikin Ind Ltd | Fluorine-containing polymer easily curable and its curable composition |
| JPS5920310A (ja) * | 1982-07-27 | 1984-02-02 | Daikin Ind Ltd | 含フッ素ポリマー硬化用組成物 |
-
1987
- 1987-03-13 JP JP5814587A patent/JPS63308008A/ja active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3937690A (en) * | 1972-06-19 | 1976-02-10 | Dynamit Nobel Aktiengesellschaft | Process for the preparation of thermoplastically workable fluoro-olefin polymers |
| US4000356A (en) * | 1972-06-19 | 1976-12-28 | Dynamit Nobel Aktiengesellschaft | Process for the preparation of thermoplastically workable fluoro-olefin polymers |
| JPS53125491A (en) * | 1977-04-08 | 1978-11-01 | Daikin Ind Ltd | Fluorine-containing polymer easily curable and its curable composition |
| JPS5920310A (ja) * | 1982-07-27 | 1984-02-02 | Daikin Ind Ltd | 含フッ素ポリマー硬化用組成物 |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006090728A1 (ja) * | 2005-02-23 | 2006-08-31 | Daikin Industries, Ltd. | 含フッ素エラストマーおよび含フッ素エラストマーの製造方法 |
| JPWO2006090728A1 (ja) * | 2005-02-23 | 2008-07-24 | ダイキン工業株式会社 | 含フッ素エラストマーおよび含フッ素エラストマーの製造方法 |
| JP4665964B2 (ja) * | 2005-02-23 | 2011-04-06 | ダイキン工業株式会社 | 含フッ素エラストマーおよび含フッ素エラストマーの製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63308008A (ja) | 1988-12-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4943622A (en) | Process for producing peroxide-vulcanizable, fluorine-containing elastomer | |
| US5225504A (en) | Process for producing peroxide-vulcanizable, fluorine-containing elastomer | |
| US5151492A (en) | Process for producing peroxide-vulcanizable, fluorine-containing elastomer | |
| US6160053A (en) | Flourine-containing copolymer composition | |
| US4748223A (en) | Process for producing peroxide-vulcanizable, fluorine-containing elastomer | |
| JPH0219129B2 (ru) | ||
| WO1996017877A1 (fr) | Copolymere de type caoutchouc fluore et composition durcissante realisee avec ce copolymere | |
| EP1783146B1 (en) | Elastomeric fluorocopolymer, composition containing the same, and crossliked rubbers | |
| US7544753B2 (en) | Process for producing elastic fluorocopolymer and crosslinked fluororubber | |
| JP3240181B2 (ja) | フツ素モノマー及び非共役ジエンの活性二重結合を含む非架橋コポリマー及びその製造法 | |
| US20110207889A1 (en) | Fluorinated elastic copolymer, process for producing same, and crosslinked rubber | |
| JP2007517964A (ja) | 低温特性の改良されたフルオロエラストマーおよびその製造方法 | |
| US6160051A (en) | Process for producing fluorine-containing block copolymer | |
| EP1630179B1 (en) | Fluorocopolymer | |
| JPH0157125B2 (ru) | ||
| JP5725167B2 (ja) | 含フッ素エラストマーの製造方法 | |
| US4774302A (en) | Process for producing peroxide-vulcanizable, fluorine-containing elastomer | |
| EP2221318A1 (en) | Process for producing fluoroelastomer | |
| US6281312B1 (en) | Process for producing fluorinated copolymer, fluorinated copolymer, crosslinkable composition containing same and sealant | |
| JPH0116845B2 (ru) | ||
| JP2006070245A (ja) | 含フッ素共重合体 | |
| JP3278979B2 (ja) | 耐寒・耐アルコール性含フッ素弾性状共重合体 | |
| JPH0219147B2 (ru) | ||
| JP5163287B2 (ja) | 含フッ素弾性共重合体、その製造方法および架橋ゴム | |
| RU2378291C2 (ru) | Эластичный фторсополимер, его смесь и сшитый каучук |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |