JPH0153850B2 - - Google Patents
Info
- Publication number
- JPH0153850B2 JPH0153850B2 JP58099955A JP9995583A JPH0153850B2 JP H0153850 B2 JPH0153850 B2 JP H0153850B2 JP 58099955 A JP58099955 A JP 58099955A JP 9995583 A JP9995583 A JP 9995583A JP H0153850 B2 JPH0153850 B2 JP H0153850B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- general formula
- copper complex
- mmol
- asymmetric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/005—Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58099955A JPS59225194A (ja) | 1983-06-03 | 1983-06-03 | 新規不斉銅錯体ならびに同錯体を触媒とするシクロプロパンカルボン酸エステルの不斉合成法 |
US06/614,224 US4552972A (en) | 1983-06-03 | 1984-05-24 | Chiral copper complex |
EP84303662A EP0128012B1 (en) | 1983-06-03 | 1984-05-31 | Novel chiral copper complex and asymmetric synthesis of cyclopropanecarboxylate derivatives using said complex as catalyst |
DE8484303662T DE3461374D1 (en) | 1983-06-03 | 1984-05-31 | Novel chiral copper complex and asymmetric synthesis of cyclopropanecarboxylate derivatives using said complex as catalyst |
US06/760,507 US4603218A (en) | 1983-06-03 | 1985-07-30 | Asymmetric synthesis of cyclopropanecarboxylate derivatives using chiral copper complex as catalyst |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58099955A JPS59225194A (ja) | 1983-06-03 | 1983-06-03 | 新規不斉銅錯体ならびに同錯体を触媒とするシクロプロパンカルボン酸エステルの不斉合成法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS59225194A JPS59225194A (ja) | 1984-12-18 |
JPH0153850B2 true JPH0153850B2 (en, 2012) | 1989-11-15 |
Family
ID=14261111
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP58099955A Granted JPS59225194A (ja) | 1983-06-03 | 1983-06-03 | 新規不斉銅錯体ならびに同錯体を触媒とするシクロプロパンカルボン酸エステルの不斉合成法 |
Country Status (4)
Country | Link |
---|---|
US (2) | US4552972A (en, 2012) |
EP (1) | EP0128012B1 (en, 2012) |
JP (1) | JPS59225194A (en, 2012) |
DE (1) | DE3461374D1 (en, 2012) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4709085A (en) * | 1987-01-05 | 1987-11-24 | E. I. Du Pont De Nemours And Company | Cyclopropanation process |
US5008415A (en) * | 1988-11-14 | 1991-04-16 | Air Products And Chemicals, Inc. | Volatile fluorinated β-ketoimines and associated metal complexes |
KR20010074549A (ko) | 2000-01-25 | 2001-08-04 | 고사이 아끼오 | 키랄 구리 착물, 이의 제조 방법 및 이를 이용한 비대칭합성 |
KR20010074548A (ko) * | 2000-01-25 | 2001-08-04 | 고사이 아끼오 | 키랄 구리 착물 촉매 조성물 및 그를 이용한 비대칭 제조방법 |
JP4635343B2 (ja) * | 2000-01-25 | 2011-02-23 | 住友化学株式会社 | 光学活性な銅錯体ならびに光学活性なサリチリデンアミノアルコール化合物およびそれを用いる光学活性なシクロプロパンカルボン酸誘導体の製造方法 |
JP4029671B2 (ja) * | 2002-06-12 | 2008-01-09 | 住友化学株式会社 | 光学活性なサルドイミン銅錯体の製造方法 |
KR101113627B1 (ko) * | 2003-03-31 | 2012-02-13 | 스미또모 가가꾸 가부시끼가이샤 | 광학활성 구리 촉매 조성물 |
CN102216251B (zh) * | 2008-09-10 | 2014-08-27 | 住友化学株式会社 | 光学活性环丙烷羧酸酯化合物的制造方法、不对称铜络合物和光学活性亚水杨基氨基醇化合物 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1453234A (fr) * | 1964-02-18 | 1966-06-03 | Pechiney Progil Sa | Nouveaux composés fongicides à usage agricole |
JPS5231865B2 (en, 2012) * | 1971-08-16 | 1977-08-17 | ||
IL44167A (en) * | 1973-02-14 | 1979-09-30 | Sumitomo Chemical Co | Chiral copper-complex catalyst |
US4029683A (en) * | 1973-02-14 | 1977-06-14 | Sumitomo Chemical Company, Limited | Copper complex |
US4072700A (en) * | 1974-09-16 | 1978-02-07 | Sandoz Ltd. | Azomethine copper complexes |
GB1543605A (en) * | 1975-06-03 | 1979-04-04 | Sumitomo Chemical Co | Method for the preparation of optically active allylic esters |
US4197408A (en) * | 1975-08-01 | 1980-04-08 | Sumitomo Chemical Company, Limited | Asymmetric synthesis of alkyl chrysanthemate |
US4150046A (en) * | 1976-07-15 | 1979-04-17 | Hoechst Aktiengesellschaft | Azamethine-CU complex compounds, process for their preparation and their use |
EP0022608B1 (en) * | 1979-07-13 | 1983-07-06 | Imperial Chemical Industries Plc | Process for the preparation of cyclopropane carboxylic acid esters |
EP0023075A1 (en) * | 1979-07-13 | 1981-01-28 | Imperial Chemical Industries Plc | Process for the preparation of cyclopropane carboxylic acid esters |
-
1983
- 1983-06-03 JP JP58099955A patent/JPS59225194A/ja active Granted
-
1984
- 1984-05-24 US US06/614,224 patent/US4552972A/en not_active Expired - Lifetime
- 1984-05-31 EP EP84303662A patent/EP0128012B1/en not_active Expired
- 1984-05-31 DE DE8484303662T patent/DE3461374D1/de not_active Expired
-
1985
- 1985-07-30 US US06/760,507 patent/US4603218A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0128012A3 (en) | 1985-07-31 |
EP0128012B1 (en) | 1986-11-20 |
US4603218A (en) | 1986-07-29 |
US4552972A (en) | 1985-11-12 |
EP0128012A2 (en) | 1984-12-12 |
JPS59225194A (ja) | 1984-12-18 |
DE3461374D1 (en) | 1987-01-08 |
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