DE3461374D1 - Novel chiral copper complex and asymmetric synthesis of cyclopropanecarboxylate derivatives using said complex as catalyst - Google Patents
Novel chiral copper complex and asymmetric synthesis of cyclopropanecarboxylate derivatives using said complex as catalystInfo
- Publication number
- DE3461374D1 DE3461374D1 DE8484303662T DE3461374T DE3461374D1 DE 3461374 D1 DE3461374 D1 DE 3461374D1 DE 8484303662 T DE8484303662 T DE 8484303662T DE 3461374 T DE3461374 T DE 3461374T DE 3461374 D1 DE3461374 D1 DE 3461374D1
- Authority
- DE
- Germany
- Prior art keywords
- complex
- catalyst
- asymmetric synthesis
- novel chiral
- chiral copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000011914 asymmetric synthesis Methods 0.000 title 1
- 239000003054 catalyst Substances 0.000 title 1
- 150000004699 copper complex Chemical class 0.000 title 1
- YMGUBTXCNDTFJI-UHFFFAOYSA-N cyclopropanecarboxylic acid Chemical class OC(=O)C1CC1 YMGUBTXCNDTFJI-UHFFFAOYSA-N 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/005—Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58099955A JPS59225194A (ja) | 1983-06-03 | 1983-06-03 | 新規不斉銅錯体ならびに同錯体を触媒とするシクロプロパンカルボン酸エステルの不斉合成法 |
Publications (1)
Publication Number | Publication Date |
---|---|
DE3461374D1 true DE3461374D1 (en) | 1987-01-08 |
Family
ID=14261111
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE8484303662T Expired DE3461374D1 (en) | 1983-06-03 | 1984-05-31 | Novel chiral copper complex and asymmetric synthesis of cyclopropanecarboxylate derivatives using said complex as catalyst |
Country Status (4)
Country | Link |
---|---|
US (2) | US4552972A (de) |
EP (1) | EP0128012B1 (de) |
JP (1) | JPS59225194A (de) |
DE (1) | DE3461374D1 (de) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4709085A (en) * | 1987-01-05 | 1987-11-24 | E. I. Du Pont De Nemours And Company | Cyclopropanation process |
US5008415A (en) * | 1988-11-14 | 1991-04-16 | Air Products And Chemicals, Inc. | Volatile fluorinated β-ketoimines and associated metal complexes |
KR20010074549A (ko) * | 2000-01-25 | 2001-08-04 | 고사이 아끼오 | 키랄 구리 착물, 이의 제조 방법 및 이를 이용한 비대칭합성 |
KR20010074548A (ko) * | 2000-01-25 | 2001-08-04 | 고사이 아끼오 | 키랄 구리 착물 촉매 조성물 및 그를 이용한 비대칭 제조방법 |
JP4635343B2 (ja) * | 2000-01-25 | 2011-02-23 | 住友化学株式会社 | 光学活性な銅錯体ならびに光学活性なサリチリデンアミノアルコール化合物およびそれを用いる光学活性なシクロプロパンカルボン酸誘導体の製造方法 |
JP4029671B2 (ja) * | 2002-06-12 | 2008-01-09 | 住友化学株式会社 | 光学活性なサルドイミン銅錯体の製造方法 |
US7253301B2 (en) * | 2003-03-31 | 2007-08-07 | Sumitomo Chemical Company, Limited | Optically active copper catalyst composition |
WO2010030017A1 (ja) * | 2008-09-10 | 2010-03-18 | 住友化学株式会社 | 光学活性シクロプロパンカルボン酸エステル化合物の製造方法、不斉銅錯体および光学活性サリチリデンアミノアルコール化合物 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1453234A (fr) * | 1964-02-18 | 1966-06-03 | Pechiney Progil Sa | Nouveaux composés fongicides à usage agricole |
JPS5231865B2 (de) * | 1971-08-16 | 1977-08-17 | ||
IL44167A (en) * | 1973-02-14 | 1979-09-30 | Sumitomo Chemical Co | Chiral copper-complex catalyst |
US4029683A (en) * | 1973-02-14 | 1977-06-14 | Sumitomo Chemical Company, Limited | Copper complex |
US4072700A (en) * | 1974-09-16 | 1978-02-07 | Sandoz Ltd. | Azomethine copper complexes |
GB1543605A (en) * | 1975-06-03 | 1979-04-04 | Sumitomo Chemical Co | Method for the preparation of optically active allylic esters |
US4197408A (en) * | 1975-08-01 | 1980-04-08 | Sumitomo Chemical Company, Limited | Asymmetric synthesis of alkyl chrysanthemate |
US4150046A (en) * | 1976-07-15 | 1979-04-17 | Hoechst Aktiengesellschaft | Azamethine-CU complex compounds, process for their preparation and their use |
EP0022608B1 (de) * | 1979-07-13 | 1983-07-06 | Imperial Chemical Industries Plc | Verfahren zur Herstellung von Zyklopropan-carbonsäureestern |
EP0023075A1 (de) * | 1979-07-13 | 1981-01-28 | Imperial Chemical Industries Plc | Verfahren zur Herstellung von Cyclopropancarbonsäureestern |
-
1983
- 1983-06-03 JP JP58099955A patent/JPS59225194A/ja active Granted
-
1984
- 1984-05-24 US US06/614,224 patent/US4552972A/en not_active Expired - Lifetime
- 1984-05-31 EP EP84303662A patent/EP0128012B1/de not_active Expired
- 1984-05-31 DE DE8484303662T patent/DE3461374D1/de not_active Expired
-
1985
- 1985-07-30 US US06/760,507 patent/US4603218A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JPS59225194A (ja) | 1984-12-18 |
US4552972A (en) | 1985-11-12 |
EP0128012A3 (en) | 1985-07-31 |
JPH0153850B2 (de) | 1989-11-15 |
EP0128012A2 (de) | 1984-12-12 |
EP0128012B1 (de) | 1986-11-20 |
US4603218A (en) | 1986-07-29 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |