JP7639833B2 - アルデヒドの製造方法及びアルコールの製造方法、並びに触媒組成物 - Google Patents

アルデヒドの製造方法及びアルコールの製造方法、並びに触媒組成物 Download PDF

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JP7639833B2
JP7639833B2 JP2022575409A JP2022575409A JP7639833B2 JP 7639833 B2 JP7639833 B2 JP 7639833B2 JP 2022575409 A JP2022575409 A JP 2022575409A JP 2022575409 A JP2022575409 A JP 2022575409A JP 7639833 B2 JP7639833 B2 JP 7639833B2
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group
catalyst
producing
aldehyde
mass
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JPWO2023112762A1 (https=
JPWO2023112762A5 (https=
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将士 三宅
崇 佐藤
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Mitsubishi Chemical Corp
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Mitsubishi Chemical Corp
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4053—Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4092—Regeneration or reactivation of catalysts containing metals involving a stripping step, with stripping gas or solvent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/80—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
JP2022575409A 2021-12-14 2022-12-06 アルデヒドの製造方法及びアルコールの製造方法、並びに触媒組成物 Active JP7639833B2 (ja)

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JP2024191174A JP2025010331A (ja) 2021-12-14 2024-10-30 アルデヒドの製造方法及びアルコールの製造方法、並びに触媒組成物

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JP2021202681 2021-12-14
JP2021202681 2021-12-14
PCT/JP2022/044805 WO2023112762A1 (ja) 2021-12-14 2022-12-06 アルデヒドの製造方法及びアルコールの製造方法、並びに触媒組成物

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JPWO2023112762A5 JPWO2023112762A5 (https=) 2023-11-15
JP7639833B2 true JP7639833B2 (ja) 2025-03-05

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JP2024191174A Pending JP2025010331A (ja) 2021-12-14 2024-10-30 アルデヒドの製造方法及びアルコールの製造方法、並びに触媒組成物

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US (1) US20240327325A1 (https=)
EP (1) EP4450484A4 (https=)
JP (2) JP7639833B2 (https=)
CN (1) CN118414322A (https=)
WO (1) WO2023112762A1 (https=)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001114794A (ja) 1999-10-12 2001-04-24 Mitsubishi Chemicals Corp 第８族貴金属及び／又は有機ホスファイト化合物の回収方法
WO2005049202A1 (ja) 2003-11-20 2005-06-02 Mitsubishi Chemical Corporation ロジウム錯体触媒の回収方法
WO2019098242A1 (ja) 2017-11-15 2019-05-23 三菱ケミカル株式会社 アルデヒドの製造方法及びアルコールの製造方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3415906A (en) 1964-05-29 1968-12-10 Hooker Chemical Corp Phosphite phospholane and phosphorinane compounds
DE2912230B1 (de) * 1979-03-28 1980-10-09 Union Carbide Corp Verfahren zur Rueckgewinnung und Reaktivierung gebrauchter Rhodium- und Phosphin-enthaltender Katalysatoren aus Reaktionsprodukten der Rhodium-katalysierten Oxosynthese
JPS5923858B2 (ja) * 1981-01-22 1984-06-05 三菱化学株式会社 ロジウム錯体の取得方法
GB8334359D0 (en) 1983-12-23 1984-02-01 Davy Mckee Ltd Process
US4599206A (en) 1984-02-17 1986-07-08 Union Carbide Corporation Transition metal complex catalyzed reactions
US4737588A (en) 1984-12-28 1988-04-12 Union Carbide Corporation Transition metal complex catalyzed reactions
US5648554A (en) * 1995-04-12 1997-07-15 Mitsubishi Chemical Corporation Method for producing aldehydes
JP3959754B2 (ja) * 1995-04-12 2007-08-15 三菱化学株式会社 アルデヒド類の製造方法
JP4534732B2 (ja) 2004-11-25 2010-09-01 三菱化学株式会社 ヒドロホルミル化方法
JP4548103B2 (ja) * 2004-11-30 2010-09-22 三菱化学株式会社 ヒドロホルミル化方法
JP2013147445A (ja) * 2012-01-18 2013-08-01 Mitsubishi Chemicals Corp アルデヒドの製造方法
JP7180603B2 (ja) 2017-08-24 2022-11-30 三菱ケミカル株式会社 ジヒドロキシビフェニル化合物、ビスホスファイト化合物、触媒、アルデヒド類の製造方法及びアルコールの製造方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001114794A (ja) 1999-10-12 2001-04-24 Mitsubishi Chemicals Corp 第８族貴金属及び／又は有機ホスファイト化合物の回収方法
WO2005049202A1 (ja) 2003-11-20 2005-06-02 Mitsubishi Chemical Corporation ロジウム錯体触媒の回収方法
WO2019098242A1 (ja) 2017-11-15 2019-05-23 三菱ケミカル株式会社 アルデヒドの製造方法及びアルコールの製造方法

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JP2025010331A (ja) 2025-01-20
US20240327325A1 (en) 2024-10-03
JPWO2023112762A1 (https=) 2023-06-22
EP4450484A1 (en) 2024-10-23
EP4450484A4 (en) 2025-08-27
WO2023112762A1 (ja) 2023-06-22
CN118414322A (zh) 2024-07-30

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