JP7132781B2 - 蓄電デバイス用負極材料 - Google Patents
蓄電デバイス用負極材料 Download PDFInfo
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- JP7132781B2 JP7132781B2 JP2018138368A JP2018138368A JP7132781B2 JP 7132781 B2 JP7132781 B2 JP 7132781B2 JP 2018138368 A JP2018138368 A JP 2018138368A JP 2018138368 A JP2018138368 A JP 2018138368A JP 7132781 B2 JP7132781 B2 JP 7132781B2
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- negative electrode
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- 238000003860 storage Methods 0.000 title claims description 28
- 239000010405 anode material Substances 0.000 title description 2
- 239000002245 particle Substances 0.000 claims description 84
- 239000007773 negative electrode material Substances 0.000 claims description 54
- 229910045601 alloy Inorganic materials 0.000 claims description 35
- 239000000956 alloy Substances 0.000 claims description 35
- 239000000843 powder Substances 0.000 claims description 32
- 239000003575 carbonaceous material Substances 0.000 claims description 22
- 229910021332 silicide Inorganic materials 0.000 claims description 21
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 claims description 21
- 239000011247 coating layer Substances 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 11
- 230000005611 electricity Effects 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 229910052718 tin Inorganic materials 0.000 claims description 8
- 239000011164 primary particle Substances 0.000 claims description 7
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 229910052758 niobium Inorganic materials 0.000 claims description 6
- 229910052720 vanadium Inorganic materials 0.000 claims description 6
- 239000006230 acetylene black Substances 0.000 claims description 5
- 239000002134 carbon nanofiber Substances 0.000 claims description 4
- 239000002041 carbon nanotube Substances 0.000 claims description 4
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 4
- 239000003273 ketjen black Substances 0.000 claims description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 3
- 238000004220 aggregation Methods 0.000 claims 1
- 230000002776 aggregation Effects 0.000 claims 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 60
- 229910001416 lithium ion Inorganic materials 0.000 description 60
- 239000012071 phase Substances 0.000 description 37
- 239000011149 active material Substances 0.000 description 21
- 239000002994 raw material Substances 0.000 description 15
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 14
- 238000007599 discharging Methods 0.000 description 12
- 239000008151 electrolyte solution Substances 0.000 description 11
- 238000000034 method Methods 0.000 description 11
- 238000000498 ball milling Methods 0.000 description 9
- 229910052786 argon Inorganic materials 0.000 description 7
- 239000011230 binding agent Substances 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 230000008602 contraction Effects 0.000 description 7
- 239000003792 electrolyte Substances 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 239000010410 layer Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 6
- 239000004020 conductor Substances 0.000 description 6
- 239000011148 porous material Substances 0.000 description 6
- 239000006227 byproduct Substances 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 4
- 238000009689 gas atomisation Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000003801 milling Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000010298 pulverizing process Methods 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 238000000889 atomisation Methods 0.000 description 3
- 238000010296 bead milling Methods 0.000 description 3
- 239000003990 capacitor Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000011889 copper foil Substances 0.000 description 3
- 230000006698 induction Effects 0.000 description 3
- 229910000765 intermetallic Inorganic materials 0.000 description 3
- 238000002955 isolation Methods 0.000 description 3
- 238000003701 mechanical milling Methods 0.000 description 3
- 238000001000 micrograph Methods 0.000 description 3
- 239000010453 quartz Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 239000003115 supporting electrolyte Substances 0.000 description 3
- 239000002344 surface layer Substances 0.000 description 3
- 239000002033 PVDF binder Substances 0.000 description 2
- 239000004642 Polyimide Substances 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000001186 cumulative effect Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000006104 solid solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- 229910018068 Li 2 O Inorganic materials 0.000 description 1
- 229910010661 Li22Si5 Inorganic materials 0.000 description 1
- 229910013870 LiPF 6 Inorganic materials 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 229910018540 Si C Inorganic materials 0.000 description 1
- 229910003481 amorphous carbon Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229910021383 artificial graphite Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000019241 carbon black Nutrition 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000009690 centrifugal atomisation Methods 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000007770 graphite material Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- -1 lithium hexafluorophosphate Chemical compound 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 229910021382 natural graphite Inorganic materials 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000011163 secondary particle Substances 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000009692 water atomization Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/386—Silicon or alloys based on silicon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/027—Negative electrodes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Power Engineering (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Manufacturing & Machinery (AREA)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2018138368A JP7132781B2 (ja) | 2018-07-24 | 2018-07-24 | 蓄電デバイス用負極材料 |
PCT/JP2019/025079 WO2020021937A1 (ja) | 2018-07-24 | 2019-06-25 | 蓄電デバイス用負極材料 |
KR1020207028802A KR20210033936A (ko) | 2018-07-24 | 2019-06-25 | 축전 디바이스용 음극재료 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2018138368A JP7132781B2 (ja) | 2018-07-24 | 2018-07-24 | 蓄電デバイス用負極材料 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2020017375A JP2020017375A (ja) | 2020-01-30 |
JP7132781B2 true JP7132781B2 (ja) | 2022-09-07 |
Family
ID=69182314
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2018138368A Active JP7132781B2 (ja) | 2018-07-24 | 2018-07-24 | 蓄電デバイス用負極材料 |
Country Status (3)
Country | Link |
---|---|
JP (1) | JP7132781B2 (ko) |
KR (1) | KR20210033936A (ko) |
WO (1) | WO2020021937A1 (ko) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2024065690A (ja) * | 2022-10-31 | 2024-05-15 | 大同特殊鋼株式会社 | リチウムイオン電池用の負極材料粉末 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2014186992A (ja) | 2013-02-19 | 2014-10-02 | Sanyo Special Steel Co Ltd | 蓄電デバイス用Si系合金負極材料およびそれを用いた電極 |
JP2015115140A (ja) | 2013-12-10 | 2015-06-22 | エルジー・ケム・リミテッド | 二次電池用負極材及びそれを用いた二次電池 |
JP2015133320A (ja) | 2013-12-13 | 2015-07-23 | エルジー・ケム・リミテッド | 二次電池用負極材及びこれを用いた二次電池 |
JP2016225143A (ja) | 2015-05-29 | 2016-12-28 | エルジー・ケム・リミテッド | 二次電池用負極材料及びそれを用いた非水電解質二次電池 |
JP2017228403A (ja) | 2016-06-21 | 2017-12-28 | 山陽特殊製鋼株式会社 | 蓄電デバイス用負極材料 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013168328A (ja) | 2012-02-16 | 2013-08-29 | Hitachi Chemical Co Ltd | 負極材料、負極材料の製造方法、リチウムイオン二次電池用負極、及びリチウムイオン二次電池 |
JP6630632B2 (ja) | 2016-06-01 | 2020-01-15 | 山陽特殊製鋼株式会社 | 蓄電デバイス用負極材料 |
-
2018
- 2018-07-24 JP JP2018138368A patent/JP7132781B2/ja active Active
-
2019
- 2019-06-25 WO PCT/JP2019/025079 patent/WO2020021937A1/ja active Application Filing
- 2019-06-25 KR KR1020207028802A patent/KR20210033936A/ko unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2014186992A (ja) | 2013-02-19 | 2014-10-02 | Sanyo Special Steel Co Ltd | 蓄電デバイス用Si系合金負極材料およびそれを用いた電極 |
JP2015115140A (ja) | 2013-12-10 | 2015-06-22 | エルジー・ケム・リミテッド | 二次電池用負極材及びそれを用いた二次電池 |
JP2015133320A (ja) | 2013-12-13 | 2015-07-23 | エルジー・ケム・リミテッド | 二次電池用負極材及びこれを用いた二次電池 |
JP2016225143A (ja) | 2015-05-29 | 2016-12-28 | エルジー・ケム・リミテッド | 二次電池用負極材料及びそれを用いた非水電解質二次電池 |
JP2017228403A (ja) | 2016-06-21 | 2017-12-28 | 山陽特殊製鋼株式会社 | 蓄電デバイス用負極材料 |
Also Published As
Publication number | Publication date |
---|---|
WO2020021937A1 (ja) | 2020-01-30 |
JP2020017375A (ja) | 2020-01-30 |
KR20210033936A (ko) | 2021-03-29 |
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