JP6917463B2 - 大きくされた比表面積およびエタンからエチレンへの酸化的脱水素化に対するより高い活性を有するMoVNbTe触媒の合成 - Google Patents

大きくされた比表面積およびエタンからエチレンへの酸化的脱水素化に対するより高い活性を有するMoVNbTe触媒の合成 Download PDF

Info

Publication number
JP6917463B2
JP6917463B2 JP2019540555A JP2019540555A JP6917463B2 JP 6917463 B2 JP6917463 B2 JP 6917463B2 JP 2019540555 A JP2019540555 A JP 2019540555A JP 2019540555 A JP2019540555 A JP 2019540555A JP 6917463 B2 JP6917463 B2 JP 6917463B2
Authority
JP
Japan
Prior art keywords
mixed oxide
mixture
oxide material
starting compounds
tellurium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2019540555A
Other languages
English (en)
Japanese (ja)
Other versions
JP2020506862A (ja
JP2020506862A5 (enExample
Inventor
メストル・ゲルハルト
ヴァニンガー・クラウス
メルツァー・ダニエル
サンチェス−サンチェス・マリア・クルツ
ツェグラコヴァ・ユリア
レルヒャー・ヨハネス
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clariant Produkte Deutschland GmbH
Original Assignee
Clariant Produkte Deutschland GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clariant Produkte Deutschland GmbH filed Critical Clariant Produkte Deutschland GmbH
Publication of JP2020506862A publication Critical patent/JP2020506862A/ja
Publication of JP2020506862A5 publication Critical patent/JP2020506862A5/ja
Application granted granted Critical
Publication of JP6917463B2 publication Critical patent/JP6917463B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/633Pore volume less than 0.5 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24Chromium, molybdenum or tungsten
    • B01J23/28Molybdenum
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B19/00Selenium; Tellurium; Compounds thereof
    • C01B19/002Compounds containing, besides selenium or tellurium, more than one other element, with -O- and -OH not being considered as anions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15X-ray diffraction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002Mixed oxides other than spinels, e.g. perovskite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/61310-100 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/615100-500 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/617500-1000 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/6350.5-1.0 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/638Pore volume more than 1.0 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/70Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • B01J37/031Precipitation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • B01J37/031Precipitation
    • B01J37/033Using Hydrolysis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • B01J37/036Precipitation; Co-precipitation to form a gel or a cogel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • B01J37/10Heat treatment in the presence of water, e.g. steam
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03Monocarboxylic acids
    • C07C57/04Acrylic acid; Methacrylic acid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/50Constitutive chemical elements of heterogeneous catalysts of Group V (VA or VB) of the Periodic Table
    • B01J2523/55Vanadium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/50Constitutive chemical elements of heterogeneous catalysts of Group V (VA or VB) of the Periodic Table
    • B01J2523/56Niobium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/60Constitutive chemical elements of heterogeneous catalysts of Group VI (VIA or VIB) of the Periodic Table
    • B01J2523/64Tellurium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/60Constitutive chemical elements of heterogeneous catalysts of Group VI (VIA or VIB) of the Periodic Table
    • B01J2523/68Molybdenum
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/70Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/12Surface area
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/14Pore volume
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/20Vanadium, niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/20Vanadium, niobium or tantalum
    • C07C2523/22Vanadium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24Chromium, molybdenum or tungsten
    • C07C2523/28Molybdenum
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/057Selenium or tellurium; Compounds thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2019540555A 2017-01-31 2018-01-26 大きくされた比表面積およびエタンからエチレンへの酸化的脱水素化に対するより高い活性を有するMoVNbTe触媒の合成 Active JP6917463B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102017000865.5A DE102017000865A1 (de) 2017-01-31 2017-01-31 Synthese eines MoVNbTe-Katalysators mit erhöhter spezifischer Oberfläche und höherer Aktivität für die oxidative Dehyxdrierung von Ethan zu Ethylen
DE102017000865.5 2017-01-31
PCT/EP2018/052012 WO2018141653A1 (de) 2017-01-31 2018-01-26 Synthese eines movnbte-katalysators mit erhöhter spezifischer oberfläche und höherer aktivität für die oxidative dehydrierung von ethan zu ethylen

Publications (3)

Publication Number Publication Date
JP2020506862A JP2020506862A (ja) 2020-03-05
JP2020506862A5 JP2020506862A5 (enExample) 2021-04-30
JP6917463B2 true JP6917463B2 (ja) 2021-08-11

Family

ID=62200392

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2019540555A Active JP6917463B2 (ja) 2017-01-31 2018-01-26 大きくされた比表面積およびエタンからエチレンへの酸化的脱水素化に対するより高い活性を有するMoVNbTe触媒の合成

Country Status (7)

Country Link
US (1) US11161096B2 (enExample)
EP (1) EP3576874A1 (enExample)
JP (1) JP6917463B2 (enExample)
KR (1) KR102316669B1 (enExample)
CN (1) CN110234431B (enExample)
DE (1) DE102017000865A1 (enExample)
WO (1) WO2018141653A1 (enExample)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102017000861A1 (de) * 2017-01-31 2018-08-02 Clariant Produkte (Deutschland) Gmbh Synthese eines MoVTeNb-Katalysators aus preisgünstigen Metalloxiden
DE102017000862A1 (de) * 2017-01-31 2018-08-02 Clariant Produkte (Deutschland) Gmbh Synthese eines MoVNbTe-Katalysators mit reduziertem Gehalt an Niob und Tellur und höherer Aktivität für die oxidative Dehydrierung von Ethan
DE102017000848A1 (de) * 2017-01-31 2018-08-02 Clariant Produkte (Deutschland) Gmbh Verfahren zur Herstellung molybdänhaltiger Mischoxidmaterialien
CA3120625A1 (en) 2018-12-19 2020-06-25 Shell Internationale Research Maatschappij B.V. Catalyst for alkane oxidative dehydrogenation and/or alkene oxidation
JP7644760B2 (ja) 2019-12-20 2025-03-12 ノバ ケミカルズ(インターナショナル)ソシエテ アノニム 酸化的脱水素化プロセスからの一酸化炭素、酸素及びアセチレンの除去
KR20230135599A (ko) 2021-02-04 2023-09-25 노바 케미컬즈 (인터내셔널) 소시에테 아노님 에탄의 odh를 위한 탄탈륨을 포함하는 혼합 금속 산화물촉매
DE102021202505A1 (de) 2021-03-15 2022-09-15 Clariant International Ltd. Verfahren und Anlage zur Herstellung einer Zielverbindung
DE102021005596A1 (de) 2021-11-11 2023-05-11 Alexander Damps Verfahren zur oxidativen Aromatisierung von kurzkettigen Alkanen
US11890594B2 (en) 2021-12-30 2024-02-06 Uop Llc Chemical homogeneity and catalytic performance of mixed-metal oxide catalysts
CN114950475B (zh) * 2022-06-06 2023-12-19 河北大学 一种高熵二维催化剂的低温制备方法和应用
CN115676782A (zh) * 2022-12-06 2023-02-03 武汉船用电力推进装置研究所(中国船舶重工集团公司第七一二研究所) 一种碲粉为原料制备超细二氧化碲的方法
CN120826276A (zh) * 2023-03-13 2025-10-21 诺瓦化学品(国际)股份有限公司 制备用于氧化脱氢的催化剂

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2608768B2 (ja) 1987-11-25 1997-05-14 三菱化学株式会社 ニトリルの製造法
KR930004254A (ko) 1991-08-08 1993-03-22 에또 다께또시 니트릴의 제조방법
EP0608838B1 (en) 1993-01-28 1997-04-16 Mitsubishi Chemical Corporation Method for producing an unsaturated carboxylic acid
JP3484729B2 (ja) 1993-06-11 2004-01-06 三菱化学株式会社 エチレンの製造方法
JP3500682B2 (ja) 1994-02-23 2004-02-23 三菱化学株式会社 アルカンよりニトリルを製造するための触媒
JP3576251B2 (ja) 1995-02-17 2004-10-13 井上玩具煙火株式会社 噴き出し花火
US5945368A (en) * 1995-10-02 1999-08-31 Huntsman Petrochemical Corporation Molybdenum-modified vanadium-phosphorus oxide catalysts for the production of maleic anhydride
JP2000143244A (ja) * 1998-07-24 2000-05-23 Mitsubishi Chemicals Corp 複合金属酸化物の製造方法
ES2265984T3 (es) 1999-10-18 2007-03-01 Mitsubishi Rayon Co., Ltd. Metodo para producir acrilonitrilo, catalizador para uso en el metodo, y metodo para producir el catalizador.
DE10119933A1 (de) 2001-04-23 2002-10-24 Basf Ag Verfahren zur Herstellung von Acrylsäure durch heterogen katalysierte Gasphasenoxidation von Propan
US6867328B2 (en) 2000-07-18 2005-03-15 Basf Aktiengesellschaft Method for producing acrylic acid by the heterogeneously catalysed gas-phase oxidation of propane
US6656873B2 (en) 2001-06-14 2003-12-02 Sanjay Chaturvedi Mixed metal oxide catalyst
EP1598112A3 (en) 2001-06-14 2005-11-30 Rohm and Haas Company Process for preparing a mixed metal oxide catalyst by vapor deposition
DE10248584A1 (de) * 2002-10-17 2004-04-29 Basf Ag Multimetalloxidmassen
US7038082B2 (en) 2002-10-17 2006-05-02 Basf Aktiengesellschaft Preparation of a multimetal oxide material
US20050027295A1 (en) 2003-08-01 2005-02-03 Yang Lin Min Interlocking nail
EP1745001A1 (de) * 2004-04-30 2007-01-24 Basf Aktiengesellschaft Verfahren zur herstellung von acrylsäure durch heterogen katalysierte gasphasenpartialoxidation wenigstens einer c3-kohlenwasserstoffvorläuferverbindung
DE102004027999A1 (de) 2004-06-09 2005-01-27 Basf Ag Verfahren zur Herstellung einer Multimetalloxidmasse
JP5517407B2 (ja) 2004-06-09 2014-06-11 ビーエーエスエフ ソシエタス・ヨーロピア 多金属酸化物材料の製造方法
US7009075B2 (en) * 2004-06-30 2006-03-07 Saudi Basic Industries Corporation Process for the selective conversion of alkanes to unsaturated carboxylic acids
EP1930074A1 (en) 2006-12-08 2008-06-11 Robert Prof. Dr. Schlögl Novel mesoporous mixed metal oxide catalyst and method for the preparation thereof
DE112009000404T5 (de) 2008-02-25 2010-12-30 Sakthivel, Ayyamperumal, Dr., Vadodara Phasen-angereicherter MoVTeNb-Mischoxidkatalysator und Verfahren zu seiner Herstellung
CA2655841C (en) * 2009-02-26 2016-06-21 Nova Chemicals Corporation Supported oxidative dehydrogenation catalyst
DE102011109816B4 (de) 2011-08-09 2017-04-06 Clariant Produkte (Deutschland) Gmbh Katalysatormaterial für die Oxidation von Kohlenwasserstoffen
DE102011109774B4 (de) * 2011-08-09 2017-04-20 Clariant Produkte (Deutschland) Gmbh Katalysatormaterial für die Oxidation von Kohlenwasserstoffen
EP2781262B1 (en) 2013-03-22 2020-05-27 Clariant International Ltd Removable protective coating for the receipt of a dust free catalyst
CN103285888B (zh) * 2013-04-18 2016-03-16 沈阳化工大学 一种用于丙烯一步氧化制备丙烯酸反应的催化剂及其制备方法
CN104549373B (zh) * 2013-10-28 2017-06-20 中国石油化工股份有限公司 低碳烷烃氨氧化催化剂
JP6498749B2 (ja) 2015-03-26 2019-04-10 旭化成株式会社 触媒の製造方法、及び不飽和ニトリルの製造方法
JP6777848B2 (ja) 2016-07-08 2020-10-28 富士通株式会社 制御装置、及びストレージ装置

Also Published As

Publication number Publication date
DE102017000865A1 (de) 2018-08-02
WO2018141653A8 (de) 2019-02-14
JP2020506862A (ja) 2020-03-05
CN110234431A (zh) 2019-09-13
KR102316669B1 (ko) 2021-10-27
EP3576874A1 (de) 2019-12-11
US11161096B2 (en) 2021-11-02
WO2018141653A1 (de) 2018-08-09
CN110234431B (zh) 2023-03-24
KR20190112793A (ko) 2019-10-07
US20200139349A1 (en) 2020-05-07

Similar Documents

Publication Publication Date Title
JP6917463B2 (ja) 大きくされた比表面積およびエタンからエチレンへの酸化的脱水素化に対するより高い活性を有するMoVNbTe触媒の合成
JP6872027B2 (ja) 低価格の金属酸化物からのMoVTeNb触媒の合成
JP6876813B2 (ja) ニオブおよびテルルの低下した含有量ならびにエタンの酸化的脱水素化に対するより高い活性を有するMoVNbTe触媒の合成
JP4197254B2 (ja) プロパンの不均一系触媒部分酸化によるアクリル酸の製法
US11007509B2 (en) Method for producing mixed oxide materials containing molybdenum
US10479760B2 (en) Synthetic methods for the preparation of propylene ammoxidation catalysts
JP7314122B2 (ja) エタンのエチレンへの酸化的脱水素のためのMoVNbTeシェル触媒の合成
WO2018148158A1 (en) New synthetic methods for the preparation of propylene ammoxidation catalysts
JP2008537508A (ja) プロパンをアクリル酸へ選択的酸化するための触媒の改良された製造方法

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20190919

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20200924

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20200930

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20201222

A524 Written submission of copy of amendment under article 19 pct

Free format text: JAPANESE INTERMEDIATE CODE: A524

Effective date: 20210322

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20210323

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20210630

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20210719

R150 Certificate of patent or registration of utility model

Ref document number: 6917463

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250