KR102316669B1 - 에탄의 에틸렌으로의 산화 탈수소화를 위한, 비표면적이 증가하고 활성이 더 높은 MoVNbTe 촉매의 합성 - Google Patents

에탄의 에틸렌으로의 산화 탈수소화를 위한, 비표면적이 증가하고 활성이 더 높은 MoVNbTe 촉매의 합성 Download PDF

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KR102316669B1
KR102316669B1 KR1020197025651A KR20197025651A KR102316669B1 KR 102316669 B1 KR102316669 B1 KR 102316669B1 KR 1020197025651 A KR1020197025651 A KR 1020197025651A KR 20197025651 A KR20197025651 A KR 20197025651A KR 102316669 B1 KR102316669 B1 KR 102316669B1
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mixed oxide
oxide material
tellurium
mixture
starting compounds
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게르하르트 메슈틀
클라우스 바닝거
다니엘 멜처
마리아 크루츠 잔체스-잔체스
율리아 트세글라코바
요하네스 레르허
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클라리안트 프로두크테 (도이칠란트) 게엠베하
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KR1020197025651A 2017-01-31 2018-01-26 에탄의 에틸렌으로의 산화 탈수소화를 위한, 비표면적이 증가하고 활성이 더 높은 MoVNbTe 촉매의 합성 Active KR102316669B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102017000865.5A DE102017000865A1 (de) 2017-01-31 2017-01-31 Synthese eines MoVNbTe-Katalysators mit erhöhter spezifischer Oberfläche und höherer Aktivität für die oxidative Dehyxdrierung von Ethan zu Ethylen
DE102017000865.5 2017-01-31
PCT/EP2018/052012 WO2018141653A1 (de) 2017-01-31 2018-01-26 Synthese eines movnbte-katalysators mit erhöhter spezifischer oberfläche und höherer aktivität für die oxidative dehydrierung von ethan zu ethylen

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KR20190112793A KR20190112793A (ko) 2019-10-07
KR102316669B1 true KR102316669B1 (ko) 2021-10-27

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US (1) US11161096B2 (enExample)
EP (1) EP3576874A1 (enExample)
JP (1) JP6917463B2 (enExample)
KR (1) KR102316669B1 (enExample)
CN (1) CN110234431B (enExample)
DE (1) DE102017000865A1 (enExample)
WO (1) WO2018141653A1 (enExample)

Families Citing this family (12)

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DE102017000861A1 (de) * 2017-01-31 2018-08-02 Clariant Produkte (Deutschland) Gmbh Synthese eines MoVTeNb-Katalysators aus preisgünstigen Metalloxiden
DE102017000862A1 (de) * 2017-01-31 2018-08-02 Clariant Produkte (Deutschland) Gmbh Synthese eines MoVNbTe-Katalysators mit reduziertem Gehalt an Niob und Tellur und höherer Aktivität für die oxidative Dehydrierung von Ethan
DE102017000848A1 (de) * 2017-01-31 2018-08-02 Clariant Produkte (Deutschland) Gmbh Verfahren zur Herstellung molybdänhaltiger Mischoxidmaterialien
CA3120625A1 (en) 2018-12-19 2020-06-25 Shell Internationale Research Maatschappij B.V. Catalyst for alkane oxidative dehydrogenation and/or alkene oxidation
JP7644760B2 (ja) 2019-12-20 2025-03-12 ノバ ケミカルズ(インターナショナル)ソシエテ アノニム 酸化的脱水素化プロセスからの一酸化炭素、酸素及びアセチレンの除去
KR20230135599A (ko) 2021-02-04 2023-09-25 노바 케미컬즈 (인터내셔널) 소시에테 아노님 에탄의 odh를 위한 탄탈륨을 포함하는 혼합 금속 산화물촉매
DE102021202505A1 (de) 2021-03-15 2022-09-15 Clariant International Ltd. Verfahren und Anlage zur Herstellung einer Zielverbindung
DE102021005596A1 (de) 2021-11-11 2023-05-11 Alexander Damps Verfahren zur oxidativen Aromatisierung von kurzkettigen Alkanen
US11890594B2 (en) 2021-12-30 2024-02-06 Uop Llc Chemical homogeneity and catalytic performance of mixed-metal oxide catalysts
CN114950475B (zh) * 2022-06-06 2023-12-19 河北大学 一种高熵二维催化剂的低温制备方法和应用
CN115676782A (zh) * 2022-12-06 2023-02-03 武汉船用电力推进装置研究所(中国船舶重工集团公司第七一二研究所) 一种碲粉为原料制备超细二氧化碲的方法
CN120826276A (zh) * 2023-03-13 2025-10-21 诺瓦化学品(国际)股份有限公司 制备用于氧化脱氢的催化剂

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10119933A1 (de) 2001-04-23 2002-10-24 Basf Ag Verfahren zur Herstellung von Acrylsäure durch heterogen katalysierte Gasphasenoxidation von Propan
EP1598112A2 (en) 2001-06-14 2005-11-23 Rohm and Haas Company Process for preparing a mixed metal oxide catalyst by vapor deposition
JP2007535511A (ja) * 2004-04-30 2007-12-06 ビーエーエスエフ アクチェンゲゼルシャフト 少なくとも1種のc3−炭化水素前駆化合物を不均一系触媒により気相部分酸化することによってアクリル酸を製造する方法
US20140336411A1 (en) 2011-08-09 2014-11-13 Clariant Produkte (Deutschland) Gmbh Catalyst for the oxidation of hydrocarbons consisting of molybdenum, vanadium, niobium, tellurium, manganese and cobalt
US20150148563A1 (en) 2011-08-09 2015-05-28 Clariant Produkte (Deutschland) Gmbh Catalyst Material for the Oxidation of Hydrocarbons

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2608768B2 (ja) 1987-11-25 1997-05-14 三菱化学株式会社 ニトリルの製造法
KR930004254A (ko) 1991-08-08 1993-03-22 에또 다께또시 니트릴의 제조방법
EP0608838B1 (en) 1993-01-28 1997-04-16 Mitsubishi Chemical Corporation Method for producing an unsaturated carboxylic acid
JP3484729B2 (ja) 1993-06-11 2004-01-06 三菱化学株式会社 エチレンの製造方法
JP3500682B2 (ja) 1994-02-23 2004-02-23 三菱化学株式会社 アルカンよりニトリルを製造するための触媒
JP3576251B2 (ja) 1995-02-17 2004-10-13 井上玩具煙火株式会社 噴き出し花火
US5945368A (en) * 1995-10-02 1999-08-31 Huntsman Petrochemical Corporation Molybdenum-modified vanadium-phosphorus oxide catalysts for the production of maleic anhydride
JP2000143244A (ja) * 1998-07-24 2000-05-23 Mitsubishi Chemicals Corp 複合金属酸化物の製造方法
ES2265984T3 (es) 1999-10-18 2007-03-01 Mitsubishi Rayon Co., Ltd. Metodo para producir acrilonitrilo, catalizador para uso en el metodo, y metodo para producir el catalizador.
US6867328B2 (en) 2000-07-18 2005-03-15 Basf Aktiengesellschaft Method for producing acrylic acid by the heterogeneously catalysed gas-phase oxidation of propane
US6656873B2 (en) 2001-06-14 2003-12-02 Sanjay Chaturvedi Mixed metal oxide catalyst
DE10248584A1 (de) * 2002-10-17 2004-04-29 Basf Ag Multimetalloxidmassen
US7038082B2 (en) 2002-10-17 2006-05-02 Basf Aktiengesellschaft Preparation of a multimetal oxide material
US20050027295A1 (en) 2003-08-01 2005-02-03 Yang Lin Min Interlocking nail
DE102004027999A1 (de) 2004-06-09 2005-01-27 Basf Ag Verfahren zur Herstellung einer Multimetalloxidmasse
JP5517407B2 (ja) 2004-06-09 2014-06-11 ビーエーエスエフ ソシエタス・ヨーロピア 多金属酸化物材料の製造方法
US7009075B2 (en) * 2004-06-30 2006-03-07 Saudi Basic Industries Corporation Process for the selective conversion of alkanes to unsaturated carboxylic acids
EP1930074A1 (en) 2006-12-08 2008-06-11 Robert Prof. Dr. Schlögl Novel mesoporous mixed metal oxide catalyst and method for the preparation thereof
DE112009000404T5 (de) 2008-02-25 2010-12-30 Sakthivel, Ayyamperumal, Dr., Vadodara Phasen-angereicherter MoVTeNb-Mischoxidkatalysator und Verfahren zu seiner Herstellung
CA2655841C (en) * 2009-02-26 2016-06-21 Nova Chemicals Corporation Supported oxidative dehydrogenation catalyst
EP2781262B1 (en) 2013-03-22 2020-05-27 Clariant International Ltd Removable protective coating for the receipt of a dust free catalyst
CN103285888B (zh) * 2013-04-18 2016-03-16 沈阳化工大学 一种用于丙烯一步氧化制备丙烯酸反应的催化剂及其制备方法
CN104549373B (zh) * 2013-10-28 2017-06-20 中国石油化工股份有限公司 低碳烷烃氨氧化催化剂
JP6498749B2 (ja) 2015-03-26 2019-04-10 旭化成株式会社 触媒の製造方法、及び不飽和ニトリルの製造方法
JP6777848B2 (ja) 2016-07-08 2020-10-28 富士通株式会社 制御装置、及びストレージ装置

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10119933A1 (de) 2001-04-23 2002-10-24 Basf Ag Verfahren zur Herstellung von Acrylsäure durch heterogen katalysierte Gasphasenoxidation von Propan
EP1598112A2 (en) 2001-06-14 2005-11-23 Rohm and Haas Company Process for preparing a mixed metal oxide catalyst by vapor deposition
JP2007535511A (ja) * 2004-04-30 2007-12-06 ビーエーエスエフ アクチェンゲゼルシャフト 少なくとも1種のc3−炭化水素前駆化合物を不均一系触媒により気相部分酸化することによってアクリル酸を製造する方法
US20140336411A1 (en) 2011-08-09 2014-11-13 Clariant Produkte (Deutschland) Gmbh Catalyst for the oxidation of hydrocarbons consisting of molybdenum, vanadium, niobium, tellurium, manganese and cobalt
US20150148563A1 (en) 2011-08-09 2015-05-28 Clariant Produkte (Deutschland) Gmbh Catalyst Material for the Oxidation of Hydrocarbons

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