JP6878314B2 - 表面に組成物を塗布するための装置及び方法 - Google Patents
表面に組成物を塗布するための装置及び方法 Download PDFInfo
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- JP6878314B2 JP6878314B2 JP2017564471A JP2017564471A JP6878314B2 JP 6878314 B2 JP6878314 B2 JP 6878314B2 JP 2017564471 A JP2017564471 A JP 2017564471A JP 2017564471 A JP2017564471 A JP 2017564471A JP 6878314 B2 JP6878314 B2 JP 6878314B2
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- CITBNDNUEPMTFC-UHFFFAOYSA-M sodium;2-(hydroxymethylamino)acetate Chemical compound [Na+].OCNCC([O-])=O CITBNDNUEPMTFC-UHFFFAOYSA-M 0.000 description 1
- AXMCIYLNKNGNOT-UHFFFAOYSA-N sodium;3-[[4-[(4-dimethylazaniumylidenecyclohexa-2,5-dien-1-ylidene)-[4-[ethyl-[(3-sulfophenyl)methyl]amino]phenyl]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](C)C)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S(O)(=O)=O)=C1 AXMCIYLNKNGNOT-UHFFFAOYSA-N 0.000 description 1
- FJBHGWADYLMEJG-UHFFFAOYSA-M sodium;3-[[4-[[4-(diethylamino)phenyl]-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]cyclohexa-2,5-dien-1-ylidene]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C=CC(=CC=1)N(CC)CC=1C=C(C=CC=1)S([O-])(=O)=O)=C(C=C1)C=CC1=[N+](CC)CC1=CC=CC(S([O-])(=O)=O)=C1 FJBHGWADYLMEJG-UHFFFAOYSA-M 0.000 description 1
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 1
- QEKATQBVVAZOAY-UHFFFAOYSA-M sodium;4-propan-2-ylbenzenesulfonate Chemical compound [Na+].CC(C)C1=CC=C(S([O-])(=O)=O)C=C1 QEKATQBVVAZOAY-UHFFFAOYSA-M 0.000 description 1
- CRPCXAMJWCDHFM-UHFFFAOYSA-M sodium;5-oxopyrrolidine-2-carboxylate Chemical compound [Na+].[O-]C(=O)C1CCC(=O)N1 CRPCXAMJWCDHFM-UHFFFAOYSA-M 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical class O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 1
- 239000001797 sucrose acetate isobutyrate Substances 0.000 description 1
- UVGUPMLLGBCFEJ-SWTLDUCYSA-N sucrose acetate isobutyrate Chemical compound CC(C)C(=O)O[C@H]1[C@H](OC(=O)C(C)C)[C@@H](COC(=O)C(C)C)O[C@@]1(COC(C)=O)O[C@@H]1[C@H](OC(=O)C(C)C)[C@@H](OC(=O)C(C)C)[C@H](OC(=O)C(C)C)[C@@H](COC(C)=O)O1 UVGUPMLLGBCFEJ-SWTLDUCYSA-N 0.000 description 1
- 235000010983 sucrose acetate isobutyrate Nutrition 0.000 description 1
- 150000003445 sucroses Chemical class 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium group Chemical group [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229950009390 symclosene Drugs 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- ZXQVPEBHZMCRMC-UHFFFAOYSA-R tetraazanium;iron(2+);hexacyanide Chemical compound [NH4+].[NH4+].[NH4+].[NH4+].[Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] ZXQVPEBHZMCRMC-UHFFFAOYSA-R 0.000 description 1
- MTJLTGSCCYRJRM-UHFFFAOYSA-N tetracyclo[9.2.2.02,10.03,8]pentadeca-1,3,5,7,10,12,14-heptaene Chemical compound C1=CC=2C=3C=4C=CC=CC=4CC=3C1=CC=2 MTJLTGSCCYRJRM-UHFFFAOYSA-N 0.000 description 1
- QTTDXDAWQMDLOF-UHFFFAOYSA-J tetrasodium 3-[[4-[[4-[(6-amino-1-hydroxy-3-sulfonatonaphthalen-2-yl)diazenyl]-6-sulfonatonaphthalen-1-yl]diazenyl]naphthalen-1-yl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].Nc1ccc2c(O)c(N=Nc3ccc(N=Nc4ccc(N=Nc5cc(c6cccc(c6c5)S([O-])(=O)=O)S([O-])(=O)=O)c5ccccc45)c4ccc(cc34)S([O-])(=O)=O)c(cc2c1)S([O-])(=O)=O QTTDXDAWQMDLOF-UHFFFAOYSA-J 0.000 description 1
- RTKIYNMVFMVABJ-UHFFFAOYSA-L thimerosal Chemical compound [Na+].CC[Hg]SC1=CC=CC=C1C([O-])=O RTKIYNMVFMVABJ-UHFFFAOYSA-L 0.000 description 1
- 229940033663 thimerosal Drugs 0.000 description 1
- 238000000427 thin-film deposition Methods 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 229940104230 thymidine Drugs 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 230000000699 topical effect Effects 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- ZKWDCFPLNQTHSH-UHFFFAOYSA-N tribromoisocyanuric acid Chemical compound BrN1C(=O)N(Br)C(=O)N(Br)C1=O ZKWDCFPLNQTHSH-UHFFFAOYSA-N 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- 150000004961 triphenylmethanes Chemical class 0.000 description 1
- VRVDFJOCCWSFLI-UHFFFAOYSA-K trisodium 3-[[4-[(6-anilino-1-hydroxy-3-sulfonatonaphthalen-2-yl)diazenyl]-5-methoxy-2-methylphenyl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].COc1cc(N=Nc2cc(c3cccc(c3c2)S([O-])(=O)=O)S([O-])(=O)=O)c(C)cc1N=Nc1c(O)c2ccc(Nc3ccccc3)cc2cc1S([O-])(=O)=O VRVDFJOCCWSFLI-UHFFFAOYSA-K 0.000 description 1
- 239000012588 trypsin Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000010698 whale oil Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 150000003732 xanthenes Chemical class 0.000 description 1
- 229940075420 xanthine Drugs 0.000 description 1
- 229940071104 xylenesulfonate Drugs 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B12/00—Arrangements for controlling delivery; Arrangements for controlling the spray area
- B05B12/08—Arrangements for controlling delivery; Arrangements for controlling the spray area responsive to condition of liquid or other fluent material to be discharged, of ambient medium or of target ; responsive to condition of spray devices or of supply means, e.g. pipes, pumps or their drive means
- B05B12/12—Arrangements for controlling delivery; Arrangements for controlling the spray area responsive to condition of liquid or other fluent material to be discharged, of ambient medium or of target ; responsive to condition of spray devices or of supply means, e.g. pipes, pumps or their drive means responsive to conditions of ambient medium or target, e.g. humidity, temperature position or movement of the target relative to the spray apparatus
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
- A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
- A47L13/20—Mops
- A47L13/22—Mops with liquid-feeding devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C11/00—Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
- B05C11/10—Storage, supply or control of liquid or other fluent material; Recovery of excess liquid or other fluent material
- B05C11/1002—Means for controlling supply, i.e. flow or pressure, of liquid or other fluent material to the applying apparatus, e.g. valves
- B05C11/1015—Means for controlling supply, i.e. flow or pressure, of liquid or other fluent material to the applying apparatus, e.g. valves responsive to a conditions of ambient medium or target, e.g. humidity, temperature ; responsive to position or movement of the coating head relative to the target
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
Landscapes
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Coating Apparatus (AREA)
- Detergent Compositions (AREA)
Description
組成物をその上に付着させる表面を特定する工程と、
センサと、組成物のリザーバと、CPUと、少なくとも1つのノズルを備える少なくとも1つのマイクロ流体ダイとを有する装置を提供する工程と、
表面の少なくとも一部の上にセンサを位置決めする工程と、
センサを作動させて、表面に関する情報を取得する工程と、
取得した情報をCPUに提供する工程と、
CPUに、表面上の1つ以上の偏差の位置を計算するように指示する工程と、
少なくとも1つのノズルを作動させて、表面上に組成物を付着させる工程と、を含む、方法。
所望の物質を標的表面に塗布するための具体的な方法は、具体的な望まれる用途及び結果によって異なる。しかしながら、特定の工程を、本発明の様々な実施形態に対して概して適用することが可能である。以下の実施例は非限定的であることが意図されており、適切な場合、追加工程又は代替工程を含んでもよいことが十分に想定される。
本発明の装置の非限定的な例は、センサ及びアプリケータを備えた手持ち式装置である。アプリケータは、1つ以上のノズルと、所望の表面に塗布される組成物を収容するためのリザーバとを備えることができる。装置はまた、任意の照明光源とCPUとを備えていてもよい。照明光源は、感知対象の表面を照らすことができ、センサは、表面に塗布する物質の量及び場所を決定するために使用される、表面からの情報を感知することができる。簡単な例では、装置は、表面の画像を記録するセンサと、表面上のどこに物質を付着させるか及びどのくらい付着させるかを決定するために画像を解析するCPUと、所望の量の物質を表面上の望まれる位置に塗布するためのアプリケータとを備えていてもよい。
本発明は、任意の所望の組成物、物質、又は組成物若しくは物質の混合物を利用することができる。例えば、組成物としては、インク、染料、顔料、接着剤、硬化性組成物、光学活性化化合物、金属酸化物、漂白剤、テクスチャ低減ポリマー、シリコーン、ステイン、塗料、界面活性剤、洗浄剤、悪臭軽減剤、潤滑剤、充填剤、香料、香り、ポリマー類、ポリマー添加剤、粒子、光学調整剤、調光剤(optical matcher)、並びに殺菌剤及び抗菌剤などの他の活性物質、及びこれら又は他の物質の組み合わせを挙げることができ、これらのうちのいくつかについては本明細書において更に説明する。
図1は、本発明による手持ち式器具又は装置40の実施例の分解図を示す。装置40は表面18の真上に示されており、物理的スペーサー42によって隔てられている。物理的スペーサー42は、装置40の一部であってもよく、又は、ユーザーが装置を表面18の上に位置付けるのを支援するために使用できる、別個の部品であってもよい。図のように、スペーサー18は、表面18に接触したときのように、既定の予め定められた高さαを有しているが、スペーサーが調節可能であり得ること、又は異なる目的のために異なるスペーサーを使用できることが企図される。スペーサー18は、ユーザーが機械的及び電気的要素を表面の上方に、及び全てを表面から既知の距離に維持するのを支援する。
色:
本発明の方法及び装置は、表面の色、反射率、又は他の審美的特徴を提供する及び/又は変更するために使用され得る。例えば、表面の一部に色を加えることが望ましい場合がある。表面のその部分の色を変更するため、表面の元の色を復元するため、表面の色又は他の特徴(例えば、欠陥又は退色)などを隠すために、色を加えることが望ましい場合がある。したがって、色料、色相剤、顔料又は他の物質を含む組成物又は組成物の混合物を提供することが望ましい場合がある。そのような組成物の例としては、インク、染料、金属酸化物、及び顔料(集合的に「着色剤」と称する)が挙げられるが、これらに限定されない。着色剤としては、無機又は有機顔料及び粉末を挙げることができる。有機顔料としては、天然着色剤、並びに合成モノマー着色剤及び合成ポリマー着色剤を挙げることができる。有機顔料としては、連邦医薬品化粧品法及び連邦食品医薬品化粧品法のブルー、ブラウン、グリーン、オレンジ、レッド、イエローなどとして指定される、アゾ、インジゴイド、トリフェニルメタン、アントラキノン、及びキサンチン染料などの種々の芳香族型を挙げることができる。無機顔料としては、酸化鉄、フェロシアン化第二鉄アンモニウム、マンガンバイオレット、ウルトラマリン、クロム、水酸化クロム着色剤、及びこれらの混合物を挙げることができる。顔料は、親水性又は疎水性などの所望の特徴を顔料が有するようにする1つ以上の成分でコーティングされてもよい。代表的なコーティング材料としては、シリコーン、レシチン、アミノ酸、リン脂質、無機及び有機油、ポリエチレン、並びに他の高分子物質を挙げることができる。例示的なシリコーン処理顔料は、米国特許第5,143,722号に開示されている。無機の白色又は無着色の顔料としては、TiO2、ZnO、ZrO2、中空球状物又は半導体量子ドットを挙げることができ、これらは多くの供給業者から市販されている。その他の好適な着色剤は、米国特許第7,166,279号に特定されている。
接着剤は、本発明の装置及び方法を用いて表面に塗布することができる。接着剤を表面に単独で塗布する、又は接着剤に粘着する別の物質と共に若しくは該物質を見込んで接着剤を塗布することが望ましい場合がある。接着剤の例としては、例えば、2001年4月23日に出願され、Blatchfordらに付与された、米国特許第6,461,467号;1994年11月4日に出願され、Delgadoらに付与された、米国特許第5,614,310号;及び、1991年4月5日に出願され、Heineckeらに付与された、米国特許第5,160,315号に記載されているものが挙げられる。
例えば特定の波長のエネルギー、赤外光、又は紫外線に曝露されると硬化する、あるいは別の方法で活性化される組成物は、当該技術分野において既知であり、本発明の装置及び方法によって塗布され得る。例えば、光硬化性組成物を表面に選択的に塗布した後、表面を硬化エネルギー源に暴露することにより、光硬化性組成物を硬化させることができる。表面全体を活性化源に暴露することができ、又は暴露は装置によって、塗布と同時に、かつ表面に塗布された物質に対して選択的に行われてもよい。
本発明の方法及び装置は、亀裂、へこみ、裂け目、開口部などの、表面の凹部を充填するために使用されてもよい。例えば、装置及び方法は、木造床、タイル、レンズ、カウンタートップ、舗道、壁、及び他の硬質表面の亀裂を充填するために使用されてもよい。加えて、方法及び装置は、皮、プラスチック、布地、フィルム、箔などの可撓性表面の亀裂等を充填するために使用されてもよい。このような目的のために使用することができる組成物の例としては、国際公開第1994010237(A1)号に開示されている塗装木材用の水性水中油型エマルションスクラッチ被覆組成物;米国特許出願公開第2011/189387号に開示されている木造床の引っかき傷の修理用の組成物;米国特許出願公開第2008/0152876号に開示されている化粧板修理用の硬化性充填組成物;米国特許第8,128,718号に開示されている組成物;米国特許第5,334,335号に開示されている固形研磨材料;米国特許第5,082,691号、米国特許第5,821,291号、及び国際公開第9607706号に見出すことができる上記のものが挙げられる。他の充填剤としては、特許第5106801号により詳細に記載されているような、ポリテトラメチレングリコール及び/又は変成ポリテトラメチレングリコールを含むポリオールと、ポリイソシアネート化合物とを反応させて得られる末端にイソシアネート基を有するウレタンプレポリマーが挙げられる。
本発明の方法及び装置は、硬質表面に対する洗浄組成物の正確な塗布を提供するために用いられてもよい。例えば、セラミック、ビニル、無ワックスビニル、リノリウム、メラミン樹脂、ガラス、鋼、厨房作業板、任意のプラスチック、プラスチック化木材、金属、又は任意の塗装若しくはワニス仕上げしくは密封表面などのような異なる材料からできている、床、壁、タイル、コーキング材、グラウト、窓、食器棚、流し、シャワー、シャワー用プラスチック製カーテン、洗面台、トイレ、備え付けの家具及び取付具などの、表面上のある特定の場所を洗浄するのが望ましい場合がある。1つの具体的な用途は、グラウトラインからのかび又はかび汚れの洗浄又は除去である。家庭の硬質表面はまた、家庭用電化製品を含むが、その例としては、冷蔵庫、冷凍庫、食洗器、自動式乾燥機、オーブン、マイクロ波式オーブンレンジ、食洗器等が挙げられるが、これらに限られない。そのような硬質表面は、個人の家庭において、また商業用、企業用、及び工業用環境においても見出され得る。
本発明の方法及び装置はまた、表面の離散的な領域を衛生化するために使用され得る。洗浄と同様に、これは、使用される活性物質の量を低減するのに役立つことができ、また、周囲の表面又は環境にダメージを与えないために、非常に限られた領域を標的にすることができる。
本発明の方法及び装置はまた、表面の局所洗浄及び/又はカーペット、カーテン、ブラインド、衣類、壁紙、布地、衣類等の表面及び材料の脱臭のために使用され得る。本発明の装置及び方法と共に使用するのに好適な組成物の例は、国際公開第95/04127号、同第96/015308号、及び同第200026329に開示されている。構成する更なる組成物は、国際公開第96/15308号に開示されている。例えば、組成物は、キレート剤、又はキレート剤の組み合わせを、汚れ懸濁ポリカルボキシレート若しくはポリアミンポリマー、又はその混合物と共に含んでもよく、その結果、カーペットからの粒子状の汚れの除去に対して相乗効果を発揮する。更に、キレート剤と汚れ懸濁ポリカルボキシレート又はポリアミンポリマーとの組み合わせは、活性酸素源を更に含む水性洗浄組成物において使用するのに特に好適であり、それによって、漂白可能な汚れのような他の種類の染み及び汚れに対して良好な洗浄性能を提供すると同時に、優れた粒子状の汚れ除去性能がもたらされる。
(a)Bacillus lentus、Bacillus alkalophilus(P27963、ELYA_BACAO)、Bacillus subtilis、Bacillus amyloliquefaciens(P00782、SUBT_BACAM)、Bacillus pumilus(P07518)、及びBacillus gibsonii(DSM14391)等のBacillusに由来するものを含むサブチリシン(EC 3.4.21.62)。
(b)フサリウムプロテアーゼ、及びCellumonas(A2RQE2)に由来するキモトリプシンプロテアーゼを含む(例えば、ブタ起源又はウシ起源の)トリプシン等のトリプシン型又はキモトリプシン型プロテアーゼ。
(c)Bacillus amyloliquefaciens(P06832,NPRE_BACAM)に由来するものを含むメタロプロテアーゼ。
(a)S58A+V60S+I83T+A150G+L227G+T231R+N233R+I255A+P256K;
(b)S58A+V60S+I86V+A150G+L227G+T231R+N233R+I255A+P256K;
(c)S58A+V60S+I86V+T143S+A150G+L227G+T231R+N233R+I255A+P256K;
(d)S58A+V60S+I86V+T143S+A150G+G163K+S216P+L227G+T231R+N233R+I255A+P256K;
(e)E1*+S58A+V60S+I86V+T143S+A150G+L227G+T231R+N233R+I255A+P256K;
(f)S58A+V60S+I86V+K98I+E99K+T143S+A150G+L227G+T231R+N233R+I255A+P256K;
(g)E1N+S58A+V60S+I86V+K98I+E99K+T143S+A150G+L227G+T231R+N233R+I255A+P256K+L259F;
(h)S58A+V60S+I86V+K98I+E99K+D102A+T143S+A150G+L227G+T231R+N233R+I255A+P256K;
(i)N33Q+S58A+V60S+I86V+T143S+A150G+L227G+T231R+N233R+I255A+P256K;
(j)E1*+S58A+V60S+I86V+K98I+E99K+T143S+A150G+L227G+T231R+N233R+I255A+P256K;
(k)E1N+S58A+V60S+I86V+K98I+E99K+T143S+A150G+S216P+L227G+T231R+N233R+I255A+P256K;
(l)D27N+S58A+V60S+I86V+G91N+N94R+Dl U N+T143S+A150G+L227G+T231R+N233R+I255A+P256K;
(m)E1N+S58A+V60S+I86V+K98I+E99K+T143S+A150G+E210A+S216P+L227G+T231R+N233R+1255A+P256K;
(n)A150G+E210V+T231R+N233R+I255A+P256K;及び
(o)I202L+E210G+T231R+N233R+I255A+P256K。
本発明の方法及び装置は、表面及び材料の汚れ防止のために使用され得る。本発明と共に使用することができる汚れ防止組成物は、米国特許第8,633,146号及び同第8,637,442号に詳細に記載されている。
本発明の方法及び装置は、表面及び材料の前処理のために使用され得る。前処理は、洗浄及び他の作業を容易にするのに役立つことができ、又は、後続処理又は表面若しくは材料の使用を見込んで表面上に物質を定置するために用いることができる。本発明と共に使用することができる前処理組成物としては、単なる短鎖アルコール、アルコールアルコキシレート、及びsolvactant、例えばC8P2、C6P1等が挙げられるが、これらに限定されない。更なる前処理組成物としては、アルキルフェノール及びアルキルフェノールエトキシレート、例えば、C4−C6PhOH、C4−C6PhE1等が挙げられる。更なる他の前処理組成物としては、より長鎖のアルコール及びエトキシレート並びにグリセロールエーテル、例えば、C12、及びC14などが挙げられる。
本発明の方法及び装置は、香料と悪臭抑制物質とを含む組成物を分注するために使用され得る。多くの場合香料は香りをマスキングするが、このような悪臭抑制技術は、悪臭抑制技術で処理された芳香を放つ部位又は芳香を放たない部位の香りと過度に干渉しない。
本組成物は、布地色調剤(色合い剤、青味剤、又は白化剤と称される場合もある)を含み得る。典型的には、色調剤は、布地に青又は紫の色合いをもたらす。色調剤は、単独又は組み合わせのいずれかで使用し、特定の色調の色合いを作り出し、かつ/又は異なるタイプの布地に色合いをつけることができる。これは、例えば赤と緑−青の染料とを混合して青又は紫の色合いを生じさせることにより提供され得る。色調剤は、任意の既知の化学クラスの染料から選択されてもよく、これらは、アクリジン、アントラキノン(多環式キノンを含む)、アジン、予め金属化(premetallized)されているアゾを含むアゾ(例えば、モノアゾ、ジアゾ、トリスアゾ、テトラキスアゾ、ポリアゾ)、ベンゾジフラン及びベンゾジフラノン、カロテノイド、クマリン、シアニン、ジアザヘミシアニン、ジフェニルメタン、ホルマザン、ヘミシアニン、インジゴイド、メタン、ナフタルイミド、ナフトキノン、ニトロ及びニトロソ、オキサジン、フタロシアニン、ピラゾール、スチルベン、スチリル、トリアリールメタン、トリフェニルメタン、キサンテン、並びにこれらの混合物を含むが、これらに限定されない。
組成物は、漂白料及び/又は漂白剤を含んでもよい。好適な漂白剤としては、漂白活性化剤、有効酸素の供給源、予形成過酸、漂白触媒、還元漂白剤、及びこれらの任意の組み合わせが挙げられる。存在する場合には、漂白剤、又はその任意の成分(例えば、予形成過酸)は、カプセル化等によりコーティングすることができ、又は尿素若しくはシクロデキストリンを使用する等によりクラスレート化(clathrated)することができる。
本方法及び装置はまた、布地の毛玉を防止する及び/又は布地から毛玉を除去するのを支援するために使用され得る。本発明と共に使用することができる組成物としては、約0.25%〜約50%、約0.5%〜約25%、約0.75%〜約15%、又は約1%〜約10%の可溶化剤を含む組成物が挙げられるが、これらに限定されない。可溶化剤は、溶媒、乳化剤、界面活性剤、布地柔軟活性物質、及びその混合物からなる群から選択され得る。好ましくは、溶媒は、0.25%〜50%、1%〜20%、又は2%〜10%の範囲内で存在する。好ましくは、乳化剤は、0.1%〜10%、0.5%〜5%、0.1〜35%、1%〜25%、又は1.5%〜20%の範囲内で存在する。好ましくは、活性物質は、1%〜35%、2%〜20%、又は3%〜10%の範囲内で存在する。
本発明の方法及び装置はまた、布地及び硬質表面などの表面の色を復元するために使用され得る。色復元のために使用可能な組成物の例としては、以下の特許に記載されている組成物:米国特許出願公開第200924562号、国際公開第2010025097号、米国特許出願公開第20080242584号、米国特許出願公開第20110177994号、米国特許出願公開第2008/0242584A1号、米国特許出願公開第00906906号、米国特許出願公開第200906907号、米国特許出願公開第2009088363号、米国特許出願公開第2009209445号、米国特許第8,003,589号、米国特許第8,188,026号、米国特許第8,236,745号、米国特許第8,357,648号、米国特許出願公開第2009249562号、米国特許第8,097,047号、米国特許出願公開第2012246840号、米国特許出願公開第200917811号、米国特許出願公開第200917812号、国際公開第8084460号、国際公開第8084461号、米国特許出願公開第2010056419号、米国特許出願公開第201005642号、米国特許出願公開第2010056421号、米国特許出願公開第201129661号、米国特許第8,193,141号、米国特許第8,372,795号、米国特許第8,193,141号、米国特許第8,969,281号、及び以下の実施例に記載されている組成物が挙げられる。
2アルキルエトキシレート、The Procter & Gamble Companyから入手可能。
3直鎖アルキルベンゼンスルホネート、The Procter & Gamble Companyから入手可能。
4非イオン性界面活性剤、Huntsman Corp.から入手可能。
5ジアリルジメチルアンモニウムクロリドのホモポリマー、ポリマー分子量約100,000〜約150,000。
6ジアリルジメチルアンモニウムクロリドのホモポリマー、ポリマー分子量約5,000〜約15,000。
7ジメチルジアリルアンモニウムクロリドとアクリル酸のコポリマー、分子量約450,000〜550,000ダルトン。
8ラウリルアミドプロピルベタイン又はC12〜C16ココアミドプロピルベタイン(Inolexから商品名Lexaine(登録商標)CG30で供給)。
9分散剤、エトキシル化タローアミン、BASFから入手可能。
本方法及び装置はまた、しわ抑制組成物を付着させるために使用され得る。しわ抑制組成物の例は、米国特許第6,908,962号、同第6,491,840号、同第6,815,411号、同第7,465,699号、同第6.645,392号、同第7,341,674(B1)号により詳細に記載されている。しわ抑制組成物の更なる例を以下の実施例5及び6に記載する。
(2)主に約250℃未満の沸点を有する成分を含有する香料。
(3)主に約250℃以上の沸点を有する成分を含有する香料。
(4)主に約3.0以下のClogPを有する成分を含有する香料。
(b)ビニルアセテート/ビニルプロピオネート/クロトン酸コポリマー。
(c)ポリビニルピロリドン/アクリル酸コポリマー。
(d)エチルアクリレート/アクリル酸/N−t−ブチルアクリルアミドコポリマー。
(e)エチルアクリレート/メタクリル酸/メチルメタクリレート/アクリル酸コポリマー。
(f)ポリアクリレート分散体。
(2)Presperse Inc.(Somerset,New Jersey)から入手可能
(3)Air producets and Chemicals,Inc.(Allentown,Pennsylvania)から入手可能
本方法及び装置はまた、しわ抑制組成物を付着させるために使用され得る。布地回復組成物の例としては、布地の孔又は裂け目を封じ込める組成物が挙げられる。例えば、組成物は、布地材料の孔又は裂け目の部位に塗布された後に硬化して、孔又は裂け目が更に目立って大きくなるのを防止するのに十分な程度に布地の糸を結合させることができる。そのような組成物は、例えばストッキング又はタイツなどの靴下類の物品のほつれ又は孔が更に「伝線」するのを防止するのに特に有用である。この目的のために使用可能な組成物の例としては、結着剤、例えば、ニトロセルロース、セルロースプロピオネート、セルロースアセテートブチレート、エチルセルロース、スクロースアセテートイソブチレート、ポリビニルアセテート、ポリビニルアルコール、アクリル樹脂及び/又はポリメチルメタクリレートなどと、有機溶媒とを有する組成物が挙げられるが、これらに限定されない。布地回復組成物の更なる例は、英国特許第2251437号により詳細に記載されている。
本発明の方法及び装置は、布地柔軟化組成物を適用するために使用され得る。このため、組成物は、布地柔軟化活性物質(「FSA」)を含み得る。好適な布地柔軟化活性物質には、四級アンモニウム化合物(クォート)、アミン、脂肪酸エステル、ショ糖エステル、シリコーン、分散性ポリオレフィン、粘土、多糖、脂肪酸、ソフトニングオイル、ポリマーラテックス、及びこれらの混合物からなる群から選択される物質が挙げられるが、これらに限定されない。水不溶性布地ケア有益剤の非限定的な例としては、分散性ポリエチレン及びポリマーラテックスが挙げられる。
[R1R2R3SiO1/2](j+2)[(R4Si(X−Z)O2/2]k[R4R4SiO2/2]m[R4SiO3/2]j
(式中、
jは、0〜約98の整数であり;一態様では、jは、0〜約48の整数であり;一態様では、jは、0であり;
kは、0〜約200の整数であり、一態様では、kは、0〜約50の整数であり、k=0であるとき、R1、R2又はR3のうちの少なくとも1つは、−X−Zであり;
mは、4〜約5,000の整数であり;一態様では、mは、約10〜約4,000の整数であり;別の態様では、mは、約50〜約2,000の整数であり;
R1、R2及びR3は、それぞれ独立して、H、OH、C1〜C32アルキル、C1〜C32置換アルキル、C5〜C32又はC6〜C32アリール、C5〜C32又はC6〜C32置換アリール、C6〜C32アルキルアリール、C6〜C32置換アルキルアリール、C1〜C32アルコキシ、C1〜C32置換アルコキシ及びX−Zからなる群から選択され;
各R4は、独立して、H、OH、C1〜C32アルキル、C1〜C32置換アルキル、C5〜C32又はC6〜C32アリール、C5〜C32又はC6〜C32置換アリール、C6〜C32アルキルアリール、C6〜C32置換アルキルアリール、C1〜C32アルコキシ及びC1〜C32置換アルコキシからなる群から選択され;
当該アルキルシロキサンポリマーにおける各Xは、2〜12個の炭素原子を含む置換又は非置換二価アルキレンラジカルを含み、一態様では、各二価アルキレンラジカルは、独立して、−(CH2)s−からなる群から選択され、sは、約2〜約8、約2〜約4の整数であり;一態様では、当該アルキルシロキサンポリマーにおける各Xは、:−CH2−CH(OH)−CH2;−CH2−CH2−CH(OH)−;及び
−CH2−CH(OH)−CH2−R5;
式中、各R5は、独立して、H、C1〜C32アルキル、C1〜C32置換アルキル、C5〜C32又はC6〜C32アリール、C5〜C32又はC6〜C32置換アリール、C6〜C32アルキルアリール、C6〜C32置換アルキルアリール、−(CHR6−CHR6−O−)w−L及びシロキシル残基からなる群から選択され;
各R6は、独立して、H、C1〜C18アルキルから選択され;
各Lは、独立して、−C(O)−R7又は
R7から選択され;
wは、0〜約500の整数であり、一態様では、wは、1〜約200の整数であり;一態様では、wは、約1〜約50の整数であり;
各R7は、独立して、H、C1〜C32アルキル;C1〜C32置換アルキル、C5〜C32又はC6〜C32アリール、C5〜C32又はC6〜C32置換アリール、C6〜C32アルキルアリール、C6〜C32置換アルキルアリール及びシロキシル残基からなる群から選択され;
各Tは、独立して、H、及び
式中、当該オルガノシリコーンにおける各vは、1〜約10の整数であり、一態様では、vは、1〜約5の整数であり、当該オルガノシリコーンにおける各Qの全ての添え字vの合計は、1〜約30、又は1〜約20、又は更には1〜約10の整数である)。
[R1R2R3SiO1/2](j+2)[(R4Si(X−Z)O2/2]k[R4R4SiO2/2]m[R4SiO3/2]j
(式中、
jは、0〜約98の整数であり;一態様では、jは、0〜約48の整数であり;一態様では、jは、0であり;
kは、0〜約200の整数であり、k=0であるとき、R1、R2又はR3のうちの少なくとも1つは、−X−Zであり;一態様では、kは、0〜約50の整数であり;
mは、4〜約5,000の整数であり;一態様では、mは、約10〜約4,000の整数であり;別の態様では、mは、約50〜約2,000の整数であり;
R1、R2及びR3は、それぞれ独立して、H、OH、C1〜C32アルキル、C1〜C32置換アルキル、C5〜C32又はC6〜C32アリール、C5〜C32又はC6〜C32置換アリール、C6〜C32アルキルアリール、C6〜C32置換アルキルアリール、C1〜C32アルコキシ、C1〜C32置換アルコキシ及びX−Zからなる群から選択され;
各R4は、独立して、H、OH、C1〜C32アルキル、C1〜C32置換アルキル、C5〜C32又はC6〜C32アリール、C5〜C32又はC6〜C32置換アリール、C6〜C32アルキルアリール、C6〜C32置換アルキルアリール、C1〜C32アルコキシ及びC1〜C32置換アルコキシからなる群から選択され;
各Xは、2〜12個の炭素原子を含む置換又は非置換二価アルキレンラジカルを含み;一態様では、各Xは、独立して、−(CH2)s−O−;−CH2−CH(OH)−CH2−O−;
A−は、好適な電荷平衡アニオンである。一態様では、A−は、Cl−、Br−、
I−、硫酸メチル、スルホン酸トルエン、炭酸及びリン酸から成る群から選択され、
当該オルガノシリコーンにおける各追加のZは、独立して、H、C1〜C32アルキル、C1〜C32置換アルキル、C5〜C32又はC6〜C32アリール、C5〜C32又はC6〜C32置換アリール、C6〜C32アルキルアリール、C6〜C32置換アルキルアリール、R5、
各R5は、独立して、H;C1〜C32アルキル;C1〜C32置換アルキル、C5〜C32又はC6〜C32アリール、C5〜C32又はC6〜C32置換アリール、又はC6〜C32アルキルアリール、又はC6〜C32置換アルキルアリール、−(CHR6−CHR6−O−)w−CHR6−CHR6−L及びシロキシル残基からなる群から選択され、式中、各Lは、独立して、−C(O)−R7又は−O−R7、
wは、0〜約500の整数であり、一態様では、wは、0〜約200の整数であり、一態様では、wは、0〜約50の整数であり;
各R6は、独立して、H又はC1〜C18アルキルから選択され;
各R7は、独立して、H;C1〜C32アルキル;C1〜C32置換アルキル、C5〜C32又はC6〜C32アリール、C5〜C32又はC6〜C32置換アリール、C6〜C32アルキルアリール、及びC6〜C32置換アルキルアリール、及びシロキシル残基からなる群から選択され;
各Tは、独立して、H;
当該オルガノシリコーンにおける各vは、1〜約10の整数であり、一態様では、vは、1〜約5の整数であり、当該オルガノシリコーンにおける各Zの全ての添え字vの合計は、1〜約30、又は1〜約20、又は更には1〜約10の整数である)。
MwDxTyQz
[式中、
M=[SiR1R2R3O1/2]、[SiR1R2G1O1/2]、[SiR1G1G2O1/2]、[SiG1G2G3O1/2]、又はこれらの組み合わせであり;
D=[SiR1R2O2/2]、[SiR1G1O2/2]、[SiG1G2O2/2]、又はこれらの組み合わせであり;
T=[SiR1O3/2]、[SiG1O3/2]、又はこれらの組み合わせであり;
Q=[SiO4/2]であり;
w=1〜(2+y+2z)の整数であり;
x=5〜15,000の整数であり;
y=0〜98の整数であり;
z=0〜98の整数であり;
R1、R2及びR3は、H、OH、C1〜C32アルキル、C1〜C32置換アルキル、C5〜C32又はC6〜C32アリール、C5〜C32又はC6〜C32置換アリール、C6〜C32アルキルアリール、C6〜C32置換アルキルアリール、C1〜C32アルコキシ、C1〜C32置換アルコキシ、C1〜C32アルキルアミノ、並びにC1〜C32置換アルキルアミノからなる群から各々独立して選択され;
M、D、又はTの少なくとも1つは、少なくとも1つのG1、G2、又はG3部分を組み込んでおり;並びにG1、G2、又はG3は、各々独立して、次式から各々独立して選択され:
Xは、C1〜C32アルキレン、C1〜C32置換アルキレン、C5〜C32又はC6〜C32アリーレン、C5〜C32又はC6〜C32置換アリーレン、C6〜C32アリールアルキレン、C6〜C32置換アリールアルキレン、C1〜C32アルコキシ、C1〜C32置換アルコキシ、C1〜C32アルキレンアミノ、C1〜C32置換アルキレンアミノ、開環エポキシド及び開環グリシジルからなる群から選択される二価ラジカルを含むが、但し、Xが、繰り返しアルキレンオキシド部分を含まない場合には、Xは、P、N及びOからなる群から選択されるヘテロ原子を更に含むことができることを条件とし;各R4は、H、C1〜C32アルキル、C1〜C32置換アルキル、C5〜C32又はC6〜C32アリール、C5〜C32又はC6〜C32置換アリール、C6〜C32アルキルアリール、及びC6〜C32置換アルキルアリールからなる群から独立して選択される、同一の又は異なる一価ラジカルを含み;Eは、C1〜C32アルキレン、C1〜C32置換アルキレン、C5〜C32又はC6〜C32アリーレン、C5〜C32又はC6〜C32置換アリーレン、C6〜C32アリールアルキレン、C6〜C32置換アリールアルキレン、C1〜C32アルコキシ、C1〜C32置換アルコキシ、C1〜C32アルキレンアミノ、C1〜C32置換アルキレンアミノ、開環エポキシド及び開環グリシジルからなる群から選択される二価ラジカルを含むが、但し、Eが、繰り返しアルキレンオキシド部分を含まない場合には、Eは、P、N及びOからなる群から選択されるヘテロ原子を更に含むことができることを条件とし;E’は、C1〜C32アルキレン、C1〜C32置換アルキレン、C5〜C32又はC6〜C32アリーレン、C5〜C32又はC6〜C32置換アリーレン、C6〜C32アリールアルキレン、C6〜C32置換アリールアルキレン、C1〜C32アルコキシ、C1〜C32置換アルコキシ、C1〜C32アルキレンアミノ、C1〜C32置換アルキレンアミノ、開環エポキシド及び開環グリシジルからなる群から選択される二価ラジカルを含むが、但し、E’が、繰り返しアルキレンオキシド部分を含まない場合には、E’は、P、N及びOからなる群から選択されるヘテロ原子を更に含むことができることを条件とし;pは、1〜50から独立して選択される整数であり;nは、1又は2から独立して選択される整数であり;G1、G2又はG3のうちの少なくとも1つが、正電荷を有するとき、A−tは、好適な電荷平衡アニオン(単数又は複数)であり、したがって、電荷平衡アニオン(単数又は複数)の全電荷であるkは、G1、G2又はG3部分の正味電荷と大きさが等しく、かつ符号が反対であり;tは1、2、又は3から独立して選択される整数であり;k≦(p*2/t)+1であり;したがって、カチオン電荷の総数は、オルガノポリシロキサン分子中のアニオン電荷の総数と釣り合い;少なくとも1つのEはエチレン部分を含まない]。
本発明の方法及び装置はアイロン助剤を含んでもよい。アイロン助剤組成物の例は、米国特許第6,491,840号、米国特許第6,495,058号、及び米国特許出願公開第2003/0071075(A1)号に記載されている。
本発明の方法及び装置は、表面を保護することができる組成物を塗布するために使用され得る。例えば、ファイバー材料をダメージから保護する、印刷されたデザインを保護する、表面を変性させて撥水性にする又はより親水性にする組成物が塗布され得る。組成物はまた、石、コンクリート、プラスチック、木材等などの固体表面上に保護被覆を提供して、濡れ損、汚れ、物体が表面にぶつかることによって生じる損傷、光による損傷、及び化学物質による損傷等を防ぐのに役立ち得る。保護剤として使用するのに適した物質としては、油、テフロンコーティング材料、シリコーン、ダスティング材料、ワックス、ポリマー、エポキシ材料、UVブロッカー、被膜生成材料、及びこれらの組合せ、並びに表面を保護することが知られている又は見出されている他の材料を挙げることができるが、これらに限定されない。
本発明の方法及び装置は、硬質表面及び可撓性表面を処理するために、他の種類の組成物を塗布するために使用され得る。例えば、以下の特許は、洗浄を支援する、布地及び他の表面に所望の特性を与えるのを支援する、及び、布地を洗濯する、ないしは別の方法で処理する際に、材料及びエネルギーを節約するを支援するために使用することができる組成物を開示している:米国特許第6,503,413号、米国特許出願公開第2005/060811号、及び米国特許出願公開第2005/098759号。
Claims (22)
- 家庭または職場で表面に組成物を塗布するための装置であって、前記装置は、
a.1つ以上のアプリケータノズルを有するマイクロ流体ダイを備えるアプリケータヘッドと、
b.前記組成物を保持するためのリザーバと、
c.センサと、
d.CPUと、を備え、
前記センサが、前記表面の少なくとも一部を感知して、前記CPUに前記表面に関する情報を提供するように構成されており、前記CPUが、前記センサからの前記情報を分析して表面偏差を識別し、前記CPUが、前記表面偏差に基づいて前記1つ以上のアプリケータノズルを作動させ、
前記リザーバは、粒子の一部及びその他のゴミが前記1つ以上のアプリケータノズルの外に保持されるためのフィルターを備え、
前記組成物は、着色剤を含む組成物、接着剤、光硬化性組成物、充填剤、硬質表面に対する洗浄組成物、殺菌組成物、局所洗浄組成物、汚れ防止組成物、前処理組成物、臭気制御のために使用され得る組成物、布地色調剤を含む組成物、漂白剤を含む組成物、布地の毛玉を防止する及び/又は布地から毛玉を除去するための組成物、色を復元するための組成物、しわ抑制組成物、布地回復組成物、布地柔軟化組成物、アイロン助剤、ファイバー材料または固体表面を加工するための組成物からなる群から選択され、
前記装置が、ハンドルと、前記ハンドルと連結するヘッドと、を有する用具に取り付けられる、装置。 - 前記センサが、色、輝度、反射率、屈折率、温度、表面の高さ、質感、色の差異、臭気、前記表面の変化、埃、前記表面の不規則性、材料組成、細菌、又はこれらの組み合わせを感知する、請求項1に記載の装置。
- 前記センサがカメラである、請求項1又は2に記載の装置。
- 前記マイクロ流体ダイが複数のノズルを備える、請求項1〜3のいずれか一項に記載の装置。
- 前記マイクロ流体ダイが、加熱要素又は電気機械的アクチュエータを備える、請求項1〜4のいずれか一項に記載の装置。
- 前記センサが色センサであり、前記センサ及び前記CPUが、背景Lの±1.5%のΔLS値を識別するようにプログラムされている、請求項1〜5のいずれか一項に記載の装置。
- 所定のΔLS値が、3より大きい、請求項6に記載の装置。
- 前記センサが1つ以上の画像を撮影し、各画像が、グレースケールで撮影されるか又はグレースケールに変換されるかのいずれかである、請求項6又は7に記載の装置。
- 前記グレースケールが約0〜255単位の範囲を有する、請求項8に記載の装置。
- 前記CPUが、前記1つ以上のノズルを作動させて、前記表面偏差の位置が特定されている又は特定されていない前記表面に前記組成物を塗布するように構成されている、請求項1〜9のいずれか一項に記載の装置。
- 前記CPUが、前記1つ以上のノズルを、不連続な付着パターンで作動させるように構成されている、請求項1〜10のいずれか一項に記載の装置。
- 前記CPUが、前記1つ以上のノズルを、連続した付着パターンで作動させるように構成されている、請求項1〜11のいずれか一項に記載の装置。
- ノズルの吐出回数及び/又は頻度が、前記装置のユーザーによって調節されることができる、請求項1〜12のいずれか一項に記載の装置。
- 前記1つ以上のノズルが、直線状、複数列状、オフセット状、正弦波状、曲線状、円形状、又は鋸刃状であるアレイ状に配設される、請求項1〜13のいずれか一項に記載の装置。
- 前記装置が、前記表面を修復する、磨き直す、及び/又は復元するために使用される、又は組成物を硬質表面に塗布するために使用される、又は組成物を布地に塗布するために使用される、請求項1〜14のいずれか一項に記載の装置。
- 前記用具の前記ヘッドは、下向きに面する表面を有し、
前記ヘッドはシートに位置するために、前記シートは前記下向きに面する表面に取り付けられ、または、前記シートは前記下向きに面する表面に相対して配置される、請求項1〜15のいずれか一項に記載の装置。 - 家庭または職場で組成物を表面上に付着させる方法であって、
前記組成物をその上に付着させる表面を特定する工程と、
センサと、前記組成物のリザーバと、CPUと、少なくとも1つのノズルを備える少なくとも1つのマイクロ流体ダイとを有する装置を提供する工程と、
前記表面の少なくとも一部の上に前記センサを位置決めする工程と、
前記センサを作動させて、前記表面に関する情報を取得する工程と、
前記取得した情報を前記CPUに提供する工程と、
前記CPUに、前記表面上の1つ以上の偏差の位置を計算するように指示する工程と、
前記少なくとも1つのノズルを作動させて、前記組成物を前記表面上に付着させる工程と、を含み、
前記リザーバは、粒子の一部及びその他のゴミが前記少なくとも1つのノズルの外に保持されるためのフィルターを備え、
前記組成物は、着色剤を含む組成物、接着剤、光硬化性組成物、充填剤、硬質表面に対する洗浄組成物、殺菌組成物、局所洗浄組成物、汚れ防止組成物、前処理組成物、臭気制御のために使用され得る組成物、布地色調剤を含む組成物、漂白剤を含む組成物、布地の毛玉を防止する及び/又は布地から毛玉を除去するための組成物、色を復元するための組成物、しわ抑制組成物、布地回復組成物、布地柔軟化組成物、アイロン助剤、ファイバー材料または固体表面を加工するための組成物からなる群から選択され、
前記装置が、ハンドルと、前記ハンドルと連結するヘッドと、を有する用具に取り付けられる、方法。 - 前記組成物を前記表面上に付着させた後に、前記表面を感知する追加工程を含む、請求項17に記載の方法。
- 前記センサが、前記表面の、色の変化、輝度、反射率、屈折率、温度、質感、表面の高さ、臭気、前記表面の変化、埃、前記表面の不規則性、細菌、又はこれらの組み合わせ、及びこれらの混合物を感知する、請求項17又は18に記載の方法。
- 装置であって、前記装置は、表面に組成物を塗布して、前記表面の少なくとも一部を修復する、復元する、及び/又は磨き直すための、又は、靴の表面に組成物を塗布して、前記表面の少なくとも一部を修復する、復元する、及び/又は磨き直すための、又は、布地の表面に組成物を塗布するための、センサと、CPUと、粒子の一部及びその他のゴミが1つ以上のアプリケータノズルの外に保持されるためのフィルターを備えるリザーバと、マイクロ流体ダイとを備え、
前記組成物は、着色剤を含む組成物、接着剤、光硬化性組成物、充填剤、硬質表面に対する洗浄組成物、殺菌組成物、局所洗浄組成物、汚れ防止組成物、前処理組成物、臭気制御のために使用され得る組成物、布地色調剤を含む組成物、漂白剤を含む組成物、布地の毛玉を防止する及び/又は布地から毛玉を除去するための組成物、色を復元するための組成物、しわ抑制組成物、布地回復組成物、布地柔軟化組成物、アイロン助剤、ファイバー材料または固体表面を加工するための組成物からなる群から選択され、
前記装置が、ハンドルと、前記ハンドルと連結するヘッドと、を有する用具に取り付けられる、装置の使用。 - 前記表面が、床、壁、カウンタートップ、電化製品、窓、家具、道具、スクリーン、布地、カーペット、床敷物、織物、塗面、グラウト、タイル、又はこれらの組み合わせの群から選択される、請求項20に記載の装置の使用。
- 前記布地が、織布、不織布、皮又は他の動物ベースの材料、マイクロファイバー、織物、プラスチック、綿、羊毛、合成繊維、及び合成繊維と天然繊維との組み合わせの群から選択される、請求項20に記載の装置の使用。
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US14/736,551 | 2015-06-11 | ||
US14/736,551 US10188192B2 (en) | 2014-06-13 | 2015-06-11 | Apparatus and methods for modifying keratinous surfaces |
US14/968,279 | 2015-12-14 | ||
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CN103556464B (zh) | 2013-10-29 | 2015-06-10 | 宋子奎 | 织物功能修复剂组合物及其制备方法 |
JP2017526617A (ja) * | 2014-06-13 | 2017-09-14 | ザ プロクター アンド ギャンブル カンパニー | 角質表面を改質するためのトリートメント組成物、装置及び方法 |
JP6374991B2 (ja) * | 2014-06-13 | 2018-08-15 | ザ プロクター アンド ギャンブル カンパニー | トリートメント組成物を角質表面に付着させるためのカートリッジ |
US9924875B2 (en) * | 2014-06-13 | 2018-03-27 | The Procter & Gamble Company | Apparatus and methods for modifying keratinous surfaces |
CN106457288B (zh) * | 2014-06-13 | 2021-05-11 | 宝洁公司 | 改变角质表面的设备和方法 |
CA2949118C (en) * | 2014-06-13 | 2019-07-23 | The Procter & Gamble Company | Apparatus and methods for modifying keratinous surfaces |
WO2015191821A2 (en) * | 2014-06-13 | 2015-12-17 | The Procter & Gamble Company | Apparatus and methods for modifying keratinous surfaces |
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