JP6843414B1 - 黒鉛化基窒素錯体化のＦｅ（ＩＩＩ）−Ｆｅ▲０▼触媒の調製方法 - Google Patents
黒鉛化基窒素錯体化のＦｅ（ＩＩＩ）−Ｆｅ▲０▼触媒の調製方法 Download PDFInfo
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- JP6843414B1 JP6843414B1 JP2020150766A JP2020150766A JP6843414B1 JP 6843414 B1 JP6843414 B1 JP 6843414B1 JP 2020150766 A JP2020150766 A JP 2020150766A JP 2020150766 A JP2020150766 A JP 2020150766A JP 6843414 B1 JP6843414 B1 JP 6843414B1
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 239000003054 catalyst Substances 0.000 title claims abstract description 51
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 238000000034 method Methods 0.000 title claims abstract description 27
- 229910052757 nitrogen Inorganic materials 0.000 title claims abstract description 27
- 238000005087 graphitization Methods 0.000 title claims description 17
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 130
- 229910052742 iron Inorganic materials 0.000 claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 16
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 claims abstract description 8
- 150000003751 zinc Chemical class 0.000 claims abstract description 7
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 5
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 5
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 33
- 239000000243 solution Substances 0.000 claims description 28
- 239000006185 dispersion Substances 0.000 claims description 26
- 238000006243 chemical reaction Methods 0.000 claims description 16
- 239000012265 solid product Substances 0.000 claims description 13
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 10
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 239000008367 deionised water Substances 0.000 claims description 8
- 229910021641 deionized water Inorganic materials 0.000 claims description 8
- 230000032683 aging Effects 0.000 claims description 7
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 7
- XIOUDVJTOYVRTB-UHFFFAOYSA-N 1-(1-adamantyl)-3-aminothiourea Chemical compound C1C(C2)CC3CC2CC1(NC(=S)NN)C3 XIOUDVJTOYVRTB-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 230000000536 complexating effect Effects 0.000 claims description 6
- 229960005070 ascorbic acid Drugs 0.000 claims description 5
- 235000010323 ascorbic acid Nutrition 0.000 claims description 5
- 239000011668 ascorbic acid Substances 0.000 claims description 5
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 5
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 4
- 238000010668 complexation reaction Methods 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 3
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- -1 iron ions Chemical class 0.000 claims description 2
- 229910000358 iron sulfate Inorganic materials 0.000 claims description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 2
- WOSISLOTWLGNKT-UHFFFAOYSA-L iron(2+);dichloride;hexahydrate Chemical compound O.O.O.O.O.O.Cl[Fe]Cl WOSISLOTWLGNKT-UHFFFAOYSA-L 0.000 claims description 2
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 claims description 2
- 239000004246 zinc acetate Substances 0.000 claims description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 2
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 2
- 229960001763 zinc sulfate Drugs 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 abstract description 21
- MYSWGUAQZAJSOK-UHFFFAOYSA-N ciprofloxacin Chemical compound C12=CC(N3CCNCC3)=C(F)C=C2C(=O)C(C(=O)O)=CN1C1CC1 MYSWGUAQZAJSOK-UHFFFAOYSA-N 0.000 abstract description 12
- 239000002957 persistent organic pollutant Substances 0.000 abstract description 12
- 238000010586 diagram Methods 0.000 abstract description 9
- 239000012621 metal-organic framework Substances 0.000 abstract description 8
- HEFNNWSXXWATRW-UHFFFAOYSA-N Ibuprofen Chemical compound CC(C)CC1=CC=C(C(C)C(O)=O)C=C1 HEFNNWSXXWATRW-UHFFFAOYSA-N 0.000 abstract description 7
- CXOFVDLJLONNDW-UHFFFAOYSA-N Phenytoin Chemical compound N1C(=O)NC(=O)C1(C=1C=CC=CC=1)C1=CC=CC=C1 CXOFVDLJLONNDW-UHFFFAOYSA-N 0.000 abstract description 7
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 abstract description 7
- 229960000520 diphenhydramine Drugs 0.000 abstract description 7
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 abstract description 6
- 229960003405 ciprofloxacin Drugs 0.000 abstract description 6
- 229960002036 phenytoin Drugs 0.000 abstract description 6
- 239000005631 2,4-Dichlorophenoxyacetic acid Substances 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 4
- 238000004523 catalytic cracking Methods 0.000 abstract description 3
- HXKWSTRRCHTUEC-UHFFFAOYSA-N 2,4-Dichlorophenoxyaceticacid Chemical compound OC(=O)C(Cl)OC1=CC=C(Cl)C=C1 HXKWSTRRCHTUEC-UHFFFAOYSA-N 0.000 abstract description 2
- 239000011230 binding agent Substances 0.000 abstract description 2
- 238000011065 in-situ storage Methods 0.000 abstract description 2
- 239000002243 precursor Substances 0.000 abstract description 2
- 239000010865 sewage Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 11
- 239000003344 environmental pollutant Substances 0.000 description 11
- 231100000719 pollutant Toxicity 0.000 description 11
- 238000000354 decomposition reaction Methods 0.000 description 10
- 239000007800 oxidant agent Substances 0.000 description 9
- 241000894007 species Species 0.000 description 9
- 230000001590 oxidative effect Effects 0.000 description 7
- 239000011941 photocatalyst Substances 0.000 description 7
- MFLKDEMTKSVIBK-UHFFFAOYSA-N zinc;2-methylimidazol-3-ide Chemical compound [Zn+2].CC1=NC=C[N-]1.CC1=NC=C[N-]1 MFLKDEMTKSVIBK-UHFFFAOYSA-N 0.000 description 7
- 239000013154 zeolitic imidazolate framework-8 Substances 0.000 description 6
- 238000003421 catalytic decomposition reaction Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 229940090034 ibu Drugs 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 238000001669 Mossbauer spectrum Methods 0.000 description 2
- 238000000026 X-ray photoelectron spectrum Methods 0.000 description 2
- 239000004964 aerogel Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000005264 electron capture Effects 0.000 description 2
- 238000010828 elution Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 2
- 230000002085 persistent effect Effects 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
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- 238000006467 substitution reaction Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- OVSKIKFHRZPJSS-DOMIDYPGSA-N 2-(2,4-dichlorophenoxy)acetic acid Chemical compound OC(=O)[14CH2]OC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-DOMIDYPGSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 229910017108 Fe—Fe Inorganic materials 0.000 description 1
- 229910017135 Fe—O Inorganic materials 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910007541 Zn O Inorganic materials 0.000 description 1
- 239000000370 acceptor Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 229910001566 austenite Inorganic materials 0.000 description 1
- AAMATCKFMHVIDO-UHFFFAOYSA-N azane;1h-pyrrole Chemical compound N.C=1C=CNC=1 AAMATCKFMHVIDO-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033558 biomineral tissue development Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
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- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000192 extended X-ray absorption fine structure spectroscopy Methods 0.000 description 1
- 229940044631 ferric chloride hexahydrate Drugs 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- NQXWGWZJXJUMQB-UHFFFAOYSA-K iron trichloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].Cl[Fe+]Cl NQXWGWZJXJUMQB-UHFFFAOYSA-K 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000004776 molecular orbital Methods 0.000 description 1
- 150000002829 nitrogen Chemical class 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
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- 230000000171 quenching effect Effects 0.000 description 1
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- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
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- 231100000331 toxic Toxicity 0.000 description 1
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- 238000004065 wastewater treatment Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/24—Nitrogen compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/725—Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010562502.9A CN111790422B (zh) | 2020-06-18 | 2020-06-18 | 一种石墨化基氮络合的Fe(III)-Fe0催化剂及其合成方法和应用 |
| CN202010562502.9 | 2020-06-18 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP6843414B1 true JP6843414B1 (ja) | 2021-03-17 |
| JP2021194637A JP2021194637A (ja) | 2021-12-27 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2020150766A Active JP6843414B1 (ja) | 2020-06-18 | 2020-09-08 | 黒鉛化基窒素錯体化のＦｅ（ＩＩＩ）−Ｆｅ▲０▼触媒の調製方法 |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP6843414B1 (zh) |
| CN (1) | CN111790422B (zh) |
Cited By (12)
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| CN113522317A (zh) * | 2021-08-22 | 2021-10-22 | 沈阳药科大学 | 由MOFs衍生的钴基双金属硫/碳催化剂的制备方法和应用 |
| CN113702538A (zh) * | 2021-09-02 | 2021-11-26 | 中国烟草总公司郑州烟草研究院 | 磁性多孔碳基QuEChERS净化材料及在样品前处理和烟草农残检测中的应用 |
| CN113893882A (zh) * | 2021-11-10 | 2022-01-07 | 武汉纺织大学 | 一种基于金属有机配体的铜氧化物催化剂及其制备方法和应用 |
| CN113991131A (zh) * | 2021-10-28 | 2022-01-28 | 徐州工程学院 | 一种碳化铁/四氧化三铁@碳复合催化剂的制备方法及应用 |
| CN114100646A (zh) * | 2021-11-09 | 2022-03-01 | 西南交通大学 | 双铁功能化羊粪生物炭复合材料及其制备方法与应用 |
| CN114146691A (zh) * | 2021-12-20 | 2022-03-08 | 苏州海狸生物医学工程有限公司 | 一种磁性复合材料及其制备方法 |
| CN114618554A (zh) * | 2022-03-24 | 2022-06-14 | 湖南大学 | 铁卟啉衍生的多孔铁氮掺杂碳复合电芬顿催化材料及其制备方法和应用 |
| CN114632533A (zh) * | 2022-03-09 | 2022-06-17 | 深圳信息职业技术学院 | 一种亚纳米金属催化剂及其制备方法、应用方法 |
| CN114832846A (zh) * | 2022-05-06 | 2022-08-02 | 东南大学 | 一种降解氮杂环污染物的磁性核-壳结构复合催化剂、制法及处理系统和处理方法 |
| CN114849708A (zh) * | 2022-06-10 | 2022-08-05 | 苏州大学 | 一种三维大孔碳锚定的单原子铁催化剂及其制备方法与应用 |
| CN115224293A (zh) * | 2022-08-17 | 2022-10-21 | 郑州大学 | 一种orr和oer双功能催化剂及其制备方法和应用 |
| CN115888793A (zh) * | 2022-12-21 | 2023-04-04 | 西华师范大学 | 一种g-C3N4负载的铁单原子催化剂的制备方法及应用 |
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|---|---|---|---|---|
| CN112691676B (zh) * | 2021-02-01 | 2024-03-01 | 河南师范大学 | 一种Zn掺杂α-Fe2O3/石墨烯气凝胶复合催化剂的制备方法及其氧化体系和应用 |
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|---|---|---|---|---|
| CN106669677A (zh) * | 2017-01-05 | 2017-05-17 | 中国科学院新疆理化技术研究所 | 以石墨烯为载体的磁性铁基非均相类芬顿催化剂的制备方法及应用 |
| CN107376837A (zh) * | 2017-07-27 | 2017-11-24 | 武汉工程大学 | 一种石墨烯/金属有机框架气凝胶吸附/催化材料的制备方法 |
| CN110116016A (zh) * | 2019-05-14 | 2019-08-13 | 广州大学 | 一种原位掺杂型铁系类芬顿催化剂及其合成方法和应用 |
-
2020
- 2020-06-18 CN CN202010562502.9A patent/CN111790422B/zh active Active
- 2020-09-08 JP JP2020150766A patent/JP6843414B1/ja active Active
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113522317A (zh) * | 2021-08-22 | 2021-10-22 | 沈阳药科大学 | 由MOFs衍生的钴基双金属硫/碳催化剂的制备方法和应用 |
| CN113702538A (zh) * | 2021-09-02 | 2021-11-26 | 中国烟草总公司郑州烟草研究院 | 磁性多孔碳基QuEChERS净化材料及在样品前处理和烟草农残检测中的应用 |
| CN113991131B (zh) * | 2021-10-28 | 2023-05-16 | 徐州工程学院 | 一种碳化铁/四氧化三铁@碳复合催化剂的制备方法及应用 |
| CN113991131A (zh) * | 2021-10-28 | 2022-01-28 | 徐州工程学院 | 一种碳化铁/四氧化三铁@碳复合催化剂的制备方法及应用 |
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| CN113893882A (zh) * | 2021-11-10 | 2022-01-07 | 武汉纺织大学 | 一种基于金属有机配体的铜氧化物催化剂及其制备方法和应用 |
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| CN115888793A (zh) * | 2022-12-21 | 2023-04-04 | 西华师范大学 | 一种g-C3N4负载的铁单原子催化剂的制备方法及应用 |
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| CN111790422A (zh) | 2020-10-20 |
| JP2021194637A (ja) | 2021-12-27 |
| CN111790422B (zh) | 2022-05-10 |
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