JP6830069B2 - 改良された機械的湿し性を有するフルオロポリマー組成物 - Google Patents
改良された機械的湿し性を有するフルオロポリマー組成物 Download PDFInfo
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- JP6830069B2 JP6830069B2 JP2017566799A JP2017566799A JP6830069B2 JP 6830069 B2 JP6830069 B2 JP 6830069B2 JP 2017566799 A JP2017566799 A JP 2017566799A JP 2017566799 A JP2017566799 A JP 2017566799A JP 6830069 B2 JP6830069 B2 JP 6830069B2
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- Prior art keywords
- fluoropolymer
- weight
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- monomer
- vinyl
- Prior art date
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- -1 amide compound Chemical class 0.000 claims description 33
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical group FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 31
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- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
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- 239000000565 sealant Substances 0.000 description 4
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- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- ZHUWXKIPGGZNJW-UHFFFAOYSA-N 6-methylheptyl 3-sulfanylpropanoate Chemical compound CC(C)CCCCCOC(=O)CCS ZHUWXKIPGGZNJW-UHFFFAOYSA-N 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 3
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- 239000004952 Polyamide Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
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- 229920002981 polyvinylidene fluoride Polymers 0.000 description 3
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- 150000003839 salts Chemical class 0.000 description 3
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- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 3
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 3
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
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- HCLJOFJIQIJXHS-UHFFFAOYSA-N 2-[2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOCCOC(=O)C=C HCLJOFJIQIJXHS-UHFFFAOYSA-N 0.000 description 2
- RCEJCSULJQNRQQ-UHFFFAOYSA-N 2-methylbutanenitrile Chemical compound CCC(C)C#N RCEJCSULJQNRQQ-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
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- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
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- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
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- BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 description 1
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- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 description 1
- UUIVKBHZENILKB-UHFFFAOYSA-N 2,2-dibromo-2-cyanoacetamide Chemical compound NC(=O)C(Br)(Br)C#N UUIVKBHZENILKB-UHFFFAOYSA-N 0.000 description 1
- FXRLMCRCYDHQFW-UHFFFAOYSA-N 2,3,3,3-tetrafluoropropene Chemical compound FC(=C)C(F)(F)F FXRLMCRCYDHQFW-UHFFFAOYSA-N 0.000 description 1
- AVTLBBWTUPQRAY-UHFFFAOYSA-N 2-(2-cyanobutan-2-yldiazenyl)-2-methylbutanenitrile Chemical compound CCC(C)(C#N)N=NC(C)(CC)C#N AVTLBBWTUPQRAY-UHFFFAOYSA-N 0.000 description 1
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- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 description 1
- LTHJXDSHSVNJKG-UHFFFAOYSA-N 2-[2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOCCOC(=O)C(C)=C LTHJXDSHSVNJKG-UHFFFAOYSA-N 0.000 description 1
- RDBCQSHUCYOVHR-UHFFFAOYSA-N 2-bromo-1-nitropropane-1,1-diol Chemical compound CC(Br)C(O)(O)[N+]([O-])=O RDBCQSHUCYOVHR-UHFFFAOYSA-N 0.000 description 1
- IEVADDDOVGMCSI-UHFFFAOYSA-N 2-hydroxybutyl 2-methylprop-2-enoate Chemical compound CCC(O)COC(=O)C(C)=C IEVADDDOVGMCSI-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 description 1
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
- FDMFUZHCIRHGRG-UHFFFAOYSA-N 3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)C=C FDMFUZHCIRHGRG-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
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Description
アクリル系:CH2=CH−C(=O)−OR
メタクリル系:CH2=C(CH3)−C(=O)−OR、
ここでRは、4個以上の炭素の炭化水素基で、直鎖状もしくは分岐状の炭化水素基であってよい。
アクリル系:CH2=CH−C(=O)−OR
メタクリル系:CH2=C(CH3)−C(=O)−OR、
ここでRは、4個以上の炭素の炭化水素基で、直鎖状もしくは分岐状の炭化水素基であってよい。
得られた示差走査熱量測定の測定値から、T.G.Fox,Bull.Am.Phys.Soc.,1,123(1956)に記載されているFoxの式を使用して、ガラス転移温度を計算した。
フッ化ビニリデンモノマー単位/ヘキサフルオロプロピレンモノマー単位の組成が75重量%/25重量%であるフッ化ビニリデンポリマーの水性ラテックスを、必要な量の脱イオン水を添加することにより、所望の固形分重量%に調節した。その調節したラテックスを、機械式攪拌機ならびに反応剤および不活性ガスを導入するための入口を備えたジャケット付き反応容器に加えた。アルゴンを流し始め、撹拌を開始した。混合物の中へ、第一のビニルポリマーのために必要とされる第一のモノマー混合物をイソオクチル−3−メルカプトプロピオネートと共に添加することを開始し、それと同時に、トリプロピレングリコールメチルエーテルの中に溶解させたアゾビス(2−メチルブチロニトリル)の混合物の添加も開始した。第一のモノマー混合物の添加は、50〜60分の時間で終了した。第一のモノマー混合物および連鎖移動剤、ならびにトリプロピレングリコールメチルエーテル中のアゾビス(2−メチルブチロニトリル)の添加が完了したとき、周囲温度での撹拌を30分間続けた。次いでその混合物を加熱して75℃とし、30分間保持した。第二のビニルポリマーのために必要とされる第二のモノマー混合物をイソオクチル−3−メルカプトプロピオネートと共に、混合物の中へ添加することを開始し、60分の時間をかけて完了させた。さらに30分してから、さらに水で希釈した70重量%のt−ブチルヒドロペルオキシド水溶液の添加を開始した。ヒドロペルオキシドの添加が完了したら、水の中に溶解させた還元剤のナトリウムホルムアルデヒドスルホキシレートまたはメタ重亜硫酸ナトリウムの添加を開始した。還元剤添加の後、その反応条件を20分間保持してから、冷却を開始した。そのラテックスを、場合によっては、10重量%の水酸化アンモニウム溶液を用いてpH7.5〜8.8にまで中和し、また場合によっては、反応器にフィードした全物質を規準にして800ppmのレベルで殺生物剤を添加した。
国際公開第2010/005756A1号パンフレットの実施例3の反応例を、以下の水系コーティングおよびペイントの調製における比較例として使用する。国際公開第2010/005756A1号パンフレットの反応例の第一のビニルポリマーの計算上のTgは15℃であり、そして国際公開第2010/005756A1号パンフレットの反応例の第二のビニルポリマーの計算上のTgは16℃である。
試験のための独立膜は以下のようにして調製した:配合物をガラス板の上に、8−パス湿膜アプリケーター(Paul N.Gardner Company,Inc.,Item AP−25 SS)を使用し、パス深さ10ミルで塗布し、厚み約50ミクロンの均質な乾燥膜を得た。塗布したコーティング配合物を、周囲条件下に24〜48時間放置して乾燥させ、その後、ガラス基材の上のコーティングを水の中に30〜120分間浸漬させると、そのような時間の後では、コーティング膜が、膜に延伸力が加わることなくガラス基材から容易に剥がすことができた。次いでその独立膜を、吸収用ティッシューを用いて水分を吸い取らせ、さらに少なくとも2週間はエージングさせてから、DMA試験にかけた。試験に際しては、その膜の欠陥のない領域を目視で識別した。
白色保護コーティングトップコート配合物を以下のようにして調製した:
1.安定な水性フルオロポリマーハイブリッド組成物であって、
a)フルオロポリマー、
b)前記フルオロポリマーとは不混和性である、第一のビニルポリマーであって、前記ポリマーが0℃未満のTgを有し、そして25〜100重量%の以下の構造を有する1種または複数のモノマー単位を含み:
アクリル系:CH2=CH−C(=O)−OR
メタクリル系:CH2=C(CH3)−C(=O)−OR、
[式中、Rは、4個以上の炭素の炭化水素基であり、それらは直鎖状もしくは分岐状の炭化水素基であってよい]、前記第一のビニルポリマーの残りには、次の、直鎖状もしくは分岐状であってよい3個以下の炭素の炭化水素エステル基を有するアクリル系および/またはメタクリル系のモノマー;スチレン;アルファ−メチルスチレンのモノマーから選択される単一または各種組合せた他のモノマー単位、そして5重量%までの、スチレンまたはアルファ−メチルスチレンとは異なる1種または複数の官能性モノマー単位が含まれる、第一のビニルポリマー;
c)第二のビニルポリマーであって、0℃未満のTgを有し、そして5重量%を超えるいくつかの架橋可能な官能基を有する官能性モノマー単位、50重量%のアクリル系および/またはメタクリル系のモノマー単位、ならびに50重量%までの前記アクリル系および/またはメタクリル系のモノマー単位と重合することが可能なその他のモノマー単位を含む、第二のビニルポリマー、
を含み、
10重量%未満の顔料および充填剤を含む前記フルオロポリマーハイブリッド組成物の配合物から作製した独立膜が、0℃の温度で、0.22より大きな、好ましくは0.25より大きな、より好ましくは0.03より大きな動的機械分析の損失正接、tan(δ)を有する、
安定な水性フルオロポリマーハイブリッド組成物。
2.前記フルオロポリマーが、50〜100重量パーセントのフッ化ビニリデン単位、および0〜50重量パーセントの、フッ化ビニリデンと共重合可能なビニルモノマー単位を含む、請求項1に記載の安定な水性フルオロポリマーハイブリッド組成物。
3.前記フルオロポリマーが、50〜100重量パーセント、好ましくは70〜100重量パーセントのフッ化ビニリデン単位、0〜30重量パーセントのヘキサフルオロエチレン単位、および0〜30重量部の、フッ化ビニリデンと共重合可能なビニルモノマー単位を含む、請求項1または2に記載の安定な水性フルオロポリマーハイブリッド組成物。
4.前記フルオロポリマーが、30J/g未満の結晶化度を有する、請求項1〜3のいずれか1項に記載の安定な水性フルオロポリマーハイブリッド組成物。
5.前記組成物が、5℃未満のMFFTを有する、請求項1〜4のいずれか1項に記載の安定な水性フルオロポリマーハイブリッド組成物。
6.前記第一および第二のビニルポリマーが、相互の重量比が(10:90)から(90:10)までの間、好ましくは(25:75)から(75:25)までの間で、分散体の形態で存在する、請求項1〜5のいずれか1項に記載の安定な水性フルオロポリマーハイブリッド組成物。
7.前記官能性モノマー単位が、不飽和カルボン酸;ビニルホスホン酸およびスルホン酸;アミド化合物;ヒドロキシル含有モノマー;アリルエーテルメタクリレート;アセトアセトキシ含有モノマー;酢酸ビニル;エポキシ含有モノマー;環状置換基を含むモノマー;シラノール含むモノマー;フルオロアルキルアクリレートおよびメタクリレート;アクリロニトリルおよびメタクリロニトリル;ポリオールアクリレートおよびポリオールメタクリレート、ならびにそれらの混合物、からなる群より選択される1種または複数のモノマーを含む、請求項1〜6のいずれか1項に記載の安定な水性フルオロポリマーハイブリッド組成物。
8.前記第一のビニルポリマーが、−100℃〜0℃のTgを有する、請求項1〜7のいずれか1項に記載の安定な水性フルオロポリマーハイブリッド組成物。
9.前記第二のビニルポリマーが、−70℃〜0℃のTgを有する、請求項1〜8のいずれか1項に記載の安定な水性フルオロポリマーハイブリッド組成物。
10.前記フルオロポリマーが、前記組成物の中に、全ポリマーの50〜90重量パーセントの量で含まれる、請求項1〜9のいずれか1項に記載の安定な水性フルオロポリマーハイブリッド組成物。
11.環境に優しいフルオロポリマーハイブリッド組成物を形成させるためのプロセスであって、
a)水性フルオロポリマーのシード分散体を形成させる工程であって、前記フルオロポリマー粒子が300nmよりも小さい粒径を有する、工程;
b)次いで、前記フルオロポリマーの存在下に、少なくとも2種の異なったビニルモノマー組成物を重合させて、安定なフルオロポリマーハイブリッド組成物を形成させる工程、
の工程を含み、
前記第一のビニルモノマー組成物が、前記フルオロポリマーとは不混和性でありそして0℃未満のTgおよび5%未満の官能性モノマー単位を有するポリマーを形成し、そして前記第二のビニルモノマー組成物が、0℃未満のTgを有するポリマーを形成し、そして5%を超える官能性モノマー単位を含み、
10重量%未満の顔料および充填剤を含む、本発明のフルオロポリマーハイブリッド組成物の配合物から作製された独立膜が、0℃で、0.22より大きな動的機械的損失正接(tan(δ))を有する、
プロセス。
12.膜であって、請求項1〜10のいずれか1項に記載の前記フルオロポリマーハイブリッド組成物を含む、膜。
13.コーティング組成物であって、請求項1〜10のいずれか1項に記載の前記フルオロポリマーハイブリッド組成物を含む、コーティング組成物。
14.UV安定剤、pH調節剤、着色剤、染料、水溶性樹脂、レオロジー調節添加剤および増粘剤、ならびに顔料および質顔料、ならびに充填剤をさらに含む、請求項13に記載のコーティング組成物。
15.前記最終配合物に外部架橋剤が添加される、請求項13および14に記載のコーティング組成物。
16.請求項13〜15のいずれか1項に記載の前記コーティング組成物を用いて、少なくとも一つの表面をコーティングされた基材を含む、コーティングされた基材であって、前記コーティング組成物が乾燥されてコーティングされた基材を形成する、コーティングされた基材。
17.前記基材が、プライマー処理されるかまたはプライマー処理されていない、金属、木材、ガラス、およびプラスチックからなる群より選択される、請求項21に記載のコーティングされた基材。
18.前記乾燥されたフルオロポリマーハイブリッド組成物が架橋されている、請求項17に記載のコーティングされた基材。
Claims (20)
- 安定な水性フルオロポリマーハイブリッド組成物であって、
a)フルオロポリマー、
b)前記フルオロポリマーとは不混和性である、第一のビニルポリマーであって、前記ポリマーが0℃未満のTgを有し、そして25〜100重量%の以下の構造を有する1種または複数のモノマー単位を含み:
アクリル系:CH2=CH−C(=O)−OR
メタクリル系:CH2=C(CH3)−C(=O)−OR、
[式中、Rは、4個以上の炭素の炭化水素基であり、それらは直鎖状もしくは分岐状の炭化水素基であってよい]、前記第一のビニルポリマーの残りには、次の、直鎖状もしくは分岐状であってよい3個以下の炭素の炭化水素エステル基を有するアクリル系および/またはメタクリル系のモノマー;スチレン;アルファ−メチルスチレンのモノマーから選択される単一または各種組合せた他のモノマー単位、ならびに5重量%までの、スチレンまたはアルファ−メチルスチレンとは異なる1種または複数の官能性モノマー単位が含まれる、第一のビニルポリマー;
c)第二のビニルポリマーであって、0℃未満のTgを有し、そして少なくとも50重量%のアクリル系および/またはメタクリル系のモノマー単位、ならびに50重量%までの前記アクリル系および/またはメタクリル系のモノマー単位と重合することが可能なその他のモノマー単位を含み、全モノマー単位の内の5重量%超がいくつかの架橋可能な官能基を有する官能性モノマー単位である、第二のビニルポリマー、
を含み、
10重量%未満の顔料および充填剤を含む、前記フルオロポリマーハイブリッド組成物の配合物から作製された独立膜が、0℃の温度で0.22より大きな動的機械分析の損失正接、tan(δ)を有し、
前記フルオロポリマーが、70〜100重量パーセントのフッ化ビニリデン単位、0〜30重量パーセントのヘキサフルオロプロピレン単位、および0〜30重量部の、フッ化ビニリデンと共重合可能なその他のビニルモノマー単位を含む(全部を合計して100パーセントである)、安定な水性フルオロポリマーハイブリッド組成物。 - 前記フルオロポリマーが、30J/g未満の結晶化度を有する、請求項1に記載の安定な水性フルオロポリマーハイブリッド組成物。
- 前記組成物が、5℃未満のMFFTを有する、請求項1に記載の安定な水性フルオロポリマーハイブリッド組成物。
- 前記第一および第二のビニルポリマーが、(10:90)から(90:10)までの間の重量比で存在する、請求項1に記載の安定な水性フルオロポリマーハイブリッド組成物。
- 前記第一および第二のビニルポリマーが、(25:75)から(75:25)までの間の重量比で存在する、請求項4に記載の安定な水性フルオロポリマーハイブリッド組成物。
- 前記官能性モノマー単位が、不飽和カルボン酸;ビニルホスホン酸およびスルホン酸;アミド化合物;ヒドロキシル含有モノマー;アリルエーテルメタクリレート;アセトアセトキシ含有モノマー;酢酸ビニル;エポキシ含有モノマー;環状置換基を含むモノマー;シラノールを含むモノマー;フルオロアルキルアクリレートおよびメタクリレート;アクリロニトリルおよびメタクリロニトリル;ポリオールアクリレートおよびポリオールメタクリレート、ならびにそれらの混合物、からなる群より選択される1種または複数のモノマーを含む、請求項1に記載の安定な水性フルオロポリマーハイブリッド組成物。
- 前記第一のビニルポリマーが、−100℃〜0℃のTgを有する、請求項1に記載の安定な水性フルオロポリマーハイブリッド組成物。
- 前記第二のビニルポリマーが、−70℃〜0℃のTgを有する、請求項1に記載の安定な水性フルオロポリマーハイブリッド組成物。
- 前記第一のビニルポリマーが−100℃〜0℃のTgを有し、前記第二のビニルポリマーが、−70℃〜0℃のTgを有する、請求項1に記載の安定な水性フルオロポリマーハイブリッド組成物。
- 前記フルオロポリマーが、前記組成物の中に、全ポリマーの50〜90重量パーセントの量で含まれる、請求項1に記載の安定な水性フルオロポリマーハイブリッド組成物。
- 10重量%未満の顔料および充填剤を含む、本発明のフルオロポリマーハイブリッド組成物の配合物から作製された独立膜が、0℃で、0.25より大きな動的機械的損失正接(tan(δ))を有する、請求項1に記載の安定な水性フルオロポリマーハイブリッド組成物。
- 10重量%未満の顔料および充填剤を含む、本発明のフルオロポリマーハイブリッド組成物の配合物から作製された独立膜が、0℃で、0.30より大きな動的機械的損失正接(tan(δ))を有する、請求項10に記載の安定な水性フルオロポリマーハイブリッド組成物。
- 環境に優しいフルオロポリマーハイブリッド組成物を形成させるためのプロセスであって、
a)水性フルオロポリマーのシード分散体を形成させる工程であって、前記フルオロポリマー粒子が300nmよりも小さい粒径を有する、工程;
b)次いで、前記フルオロポリマーの存在下に、第一のビニルモノマー組成物および少なくとも1種の第二のビニルモノマー組成物を重合させて、安定なフルオロポリマーハイブリッド組成物を形成させる工程、
の工程を含み、
前記第一のビニルモノマー組成物が、請求項1に記載の第一のビニルポリマーを形成し、そして前記第二のビニルモノマー組成物が、請求項1に記載の第二のビニルポリマーを形成し、
10重量%未満の顔料および充填剤を含む、本発明のフルオロポリマーハイブリッド組成物の配合物から作製された独立膜が、0℃で、0.22より大きな動的機械的損失正接(tan(δ))を有し、
前記a)のフルオロポリマーが、70〜100重量パーセントのフッ化ビニリデン単位、0〜30重量パーセントのヘキサフルオロプロピレン単位、および0〜30重量部の、フッ化ビニリデンと共重合可能なその他のビニルモノマー単位を含む(全部を合計して100パーセントである)、
プロセス。 - 膜であって、請求項1に記載の前記フルオロポリマーハイブリッド組成物を含む、膜。
- コーティング組成物であって、請求項1に記載の前記フルオロポリマーハイブリッド組成物を含む、コーティング組成物。
- UV安定剤、pH調節剤、着色剤、染料、水溶性樹脂、レオロジー調節添加剤および増粘剤、ならびに顔料および体質顔料、ならびに充填剤をさらに含む、請求項15に記載のコーティング組成物。
- 前記最終配合物に外部架橋剤が添加される、請求項15に記載のコーティング組成物。
- 請求項1に記載の安定な水性フルオロポリマーハイブリッド組成物を用いて少なくとも一つの表面をコーティングされた基材を含むコーティングされた基材であって、前記安定な水性フルオロポリマーハイブリッド組成物を乾燥させて、コーティングされた基材を形成させた、コーティングされた基材。
- 前記基材が、プライマー処理されるかまたはプライマー処理されていない、金属、木材、ガラス、およびプラスチックからなる群より選択される、請求項18に記載のコーティングされた基材。
- 前記コーティングされた基材上で乾燥させたフルオロポリマーハイブリッド組成物を架橋させた、請求項18に記載のコーティングされた基材。
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