JP6800999B2 - ３ｄプリントフルオロポリマー構造体 - Google Patents

３ｄプリントフルオロポリマー構造体 Download PDF

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JP6800999B2
JP6800999B2 JP2018551842A JP2018551842A JP6800999B2 JP 6800999 B2 JP6800999 B2 JP 6800999B2 JP 2018551842 A JP2018551842 A JP 2018551842A JP 2018551842 A JP2018551842 A JP 2018551842A JP 6800999 B2 JP6800999 B2 JP 6800999B2
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fluoropolymer
printed
article according
weight
pvdf
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JP2019511616A (ja
JP2019511616A5 (enExample
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デイビッド・シン−レン・リウ
グレゴリー・エス・オブライエン
デイビッド・エイ・ザイラー
マーク・オーバート
ジェイムズ・ジェイ・ヘンリー
トーマス・ローランド
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アーケマ・インコーポレイテッド
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    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C08F14/22—Vinylidene fluoride
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Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11248071B2 (en) * 2016-04-01 2022-02-15 Arkema Inc. 3-D printed fluoropolymer structures
WO2017173258A1 (en) * 2016-04-01 2017-10-05 Arkema Inc. 3-d printed fluoropolymer structures
CN109952203B (zh) 2016-06-01 2022-04-01 阿科玛法国公司 用于3d打印的尺寸稳定的丙烯酸系合金
US11027484B2 (en) * 2017-03-21 2021-06-08 Purdue Research Foundation 3D printed fluoropolymer-based energetic compositions
CN107964166A (zh) * 2017-12-12 2018-04-27 成都育芽科技有限公司 一种免喷涂3d打印用聚丙烯复合材料
JP7428649B2 (ja) * 2017-12-29 2024-02-06 アーケマ・インコーポレイテッド ３ｄプリンティング用の非中実コアフィラメント
FR3076832B1 (fr) * 2018-01-15 2019-12-06 Arkema France Poudre de polymere fluore a fenetre de frittage elargie par traitement thermique et son utilisation dans le frittage laser
FR3076833B1 (fr) * 2018-01-15 2020-07-24 Arkema France Poudre de polymere fluore adaptee au prototypage rapide par frittage laser
EP3785883A4 (en) * 2018-04-27 2022-01-19 Daikin Industries, Ltd. FORM POWDER
JP6641414B2 (ja) * 2018-04-27 2020-02-05 クレハ合繊株式会社 分離体、機械要素、運動ガイド装置および産業用機械
CN109135169A (zh) * 2018-07-11 2019-01-04 黄河科技学院 石墨烯和芳纶纤维混合增强酚醛树脂板材的制作方法
US12215220B2 (en) 2018-10-04 2025-02-04 Arkema France 3-D printed semi-crystalline and amorphous polymer articles
US11820075B2 (en) * 2018-12-06 2023-11-21 Jabil Inc. Apparatus, system and method of imparting specified characteristics to additively manufactured foam
JP7156022B2 (ja) * 2018-12-28 2022-10-19 セイコーエプソン株式会社 三次元造形物の製造方法および三次元造形装置
CN109825068A (zh) * 2019-01-18 2019-05-31 常州先风三维科技有限公司 一种用于选择性激光烧结的尼龙复合粉末及其制备方法
CN109897372A (zh) * 2019-01-18 2019-06-18 常州先风三维科技有限公司 一种用于选择性激光烧结的低密度尼龙复合粉末及其制备方法
US12187877B2 (en) 2019-02-20 2025-01-07 Basell Polyolefine Gmbh Extrusion additive manufacturing process for producing polyethylene articles
CN110066485A (zh) * 2019-04-20 2019-07-30 西北工业大学 一种离子聚合物金属复合材料基膜3d制备方法
CN110483948B (zh) * 2019-08-13 2022-08-26 江苏澳盛复合材料科技有限公司 一种3d打印用碳纤维/聚醚醚酮复合线材
WO2021101868A1 (en) * 2019-11-18 2021-05-27 Arkema Inc. Acrylic support structure for 3d printed fluoropolymer article
WO2021202813A1 (en) * 2020-03-31 2021-10-07 Greene, Tweed Technologies, Inc. Articles formed from fluorine-containing elastomer compositions using an additive manufacturing method and additive manufacturing methods for thermoset elastomer compositions
US20210402650A1 (en) * 2020-06-30 2021-12-30 Fibrecycle Materials Corp. Method of manufacturing feedstock from recycled-fibers
CN112045992B (zh) * 2020-08-13 2021-09-21 四川大学 一种高β晶含量PVDF的熔融沉积成型3D打印方法
EP4215568B1 (en) * 2020-09-30 2025-11-26 Daikin Industries, Ltd. Composition for three-dimensional shaping and three-dimensional shaped object
CN112409731B (zh) * 2020-10-21 2023-02-24 浙江巨化技术中心有限公司 一种3d打印用含氟树脂组合物及其制备方法
CN112341736B (zh) * 2020-12-24 2022-09-09 浙江巨化技术中心有限公司 一种可用于3d打印的氟树脂组合物
EP4472825A1 (en) 2022-01-31 2024-12-11 Signify Holding B.V. Anti-adhesion between sections in fdm-printed object
EP4316781A1 (en) 2022-08-01 2024-02-07 Arkema France Method for manufacturing an article by material additive extrusion printing using a rheology modifier
CN115594789B (zh) * 2022-11-01 2023-09-19 万华化学集团股份有限公司 一种丙烯酸共聚制备聚偏氟乙烯树脂的方法

Family Cites Families (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2559752A (en) 1951-03-06 1951-07-10 Du Pont Aqueous colloidal dispersions of polymers
JPH0664929B2 (ja) * 1985-04-02 1994-08-22 レイケム・コ−ポレイシヨン 電気デバイス
FR2739626B1 (fr) * 1995-10-05 1997-11-21 Solvay Composition reticulable de polymere du fluorure de vinylidene, procede pour reticuler la composition et articles faconnes
IT1295535B1 (it) 1996-07-01 1999-05-12 Ausimont Spa Processo di polimerizzazione di vinilidenfluoruro (vdf)
JP2000037810A (ja) * 1998-07-21 2000-02-08 Minnesota Mining & Mfg Co <3M> 装飾用フィルム
US6401002B1 (en) * 1999-04-29 2002-06-04 Nanotek Instruments, Inc. Layer manufacturing apparatus and process
EP1211288A1 (fr) * 2000-12-01 2002-06-05 Atofina Composition conductrice à base de polymère fluoré
US20020113331A1 (en) 2000-12-20 2002-08-22 Tan Zhang Freeform fabrication method using extrusion of non-cross-linking reactive prepolymers
EP2269808B1 (en) * 2003-05-21 2017-03-22 3D Systems Incorporated Thermoplastic powder material system for appearance models from 3D printing systems
US7375157B2 (en) * 2003-06-09 2008-05-20 3M Innovative Properties Company Melt-processible polymer composition comprising fluoropolymer having long chain branches
FR2877009B1 (fr) * 2004-10-21 2007-03-09 Solvay Composition polymere a base de pvdf homopolymere et de copolymere thermoplastique fluore
FR2882298B1 (fr) * 2005-02-23 2010-02-26 Arkema Film multicouche protecteur a base de pvdf et de pmma
GB0511460D0 (en) * 2005-06-06 2005-07-13 Univ Liverpool Process
US20060281845A1 (en) 2005-06-10 2006-12-14 Ramin Amin-Sanayei Aqueous process for making fluoropolymers
US8080621B2 (en) 2005-06-10 2011-12-20 Arkema Inc. Aqueous process for making fluoropolymers
US8338518B2 (en) 2005-06-10 2012-12-25 Arkema Inc. Aqueous process for making a stable fluoropolymer dispersion
EP1743920A1 (en) * 2005-07-13 2007-01-17 Solvay Solexis S.p.A. Thermoplastic fluoropolymer composition
US8124699B2 (en) 2005-08-08 2012-02-28 Arkema Inc. Polymerization of fluoropolymers using alkyl phosphonate surfactants
JP2007191576A (ja) * 2006-01-19 2007-08-02 Daikin Ind Ltd 熱可塑性重合体組成物、熱可塑性樹脂組成物、それを用いた成形品および熱可塑性樹脂組成物の製造方法
US20090274912A1 (en) * 2006-04-21 2009-11-05 Arkema France Multilayer structure having a grafted polyvinylidene fluoride blend layer
WO2007133912A2 (en) * 2006-05-10 2007-11-22 Arkema Inc. Use of fluoropolymers in laser sintering
DE102007024469B4 (de) * 2007-05-25 2009-04-23 Eos Gmbh Electro Optical Systems Verfahren zum schichtweisen Herstellen eines dreidimensionalen Objekts
EP2123430B1 (en) * 2008-05-20 2020-07-01 EOS GmbH Electro Optical Systems Influencing specific mechanical properties of three-dimensional objects manufactured by a selective sintering by means of electromagnetic radiation from a powder comprising at least one polymer or copolymer
US9117568B2 (en) * 2009-04-03 2015-08-25 Vorbeck Materials Corp. Polymer compositions containing carbonaceous fillers
US8801990B2 (en) 2010-09-17 2014-08-12 Stratasys, Inc. Method for building three-dimensional models in extrusion-based additive manufacturing systems using core-shell semi-crystalline consumable filaments
US8920697B2 (en) 2010-09-17 2014-12-30 Stratasys, Inc. Method for building three-dimensional objects in extrusion-based additive manufacturing systems using core-shell consumable filaments
US9580551B2 (en) * 2011-12-12 2017-02-28 Advanced Laser Materials, Llc Method and system for laser sintering with pretreated material
US9592530B2 (en) 2012-11-21 2017-03-14 Stratasys, Inc. Additive manufacturing with polyamide consumable materials
US9527242B2 (en) 2012-11-21 2016-12-27 Stratasys, Inc. Method for printing three-dimensional parts wtih crystallization kinetics control
WO2015006697A1 (en) * 2013-07-11 2015-01-15 Heikkila Kurt E Surface modified particulate and sintered extruded products
EP3024881B1 (en) 2013-07-26 2018-09-05 Hewlett-Packard Development Company L.P. Composite support material for three-dimensional printing
RU2016107779A (ru) 2013-08-09 2017-09-12 Кимберли-Кларк Ворлдвайд, Инк. Полимерный материал для трехмерной печати
US9482249B2 (en) * 2013-09-09 2016-11-01 General Electric Company Three-dimensional printing process, swirling device and thermal management process
WO2015048155A1 (en) 2013-09-24 2015-04-02 Fenner U.S., Inc. Improved filament for fused deposit modeling
US10370510B2 (en) 2013-10-08 2019-08-06 Stratasys, Inc. Consumable filaments having reversible reinforcement for extrusion-based additive manufacturing
US8827684B1 (en) * 2013-12-23 2014-09-09 Radiant Fabrication 3D printer and printhead unit with multiple filaments
KR102310155B1 (ko) 2014-01-17 2021-10-07 루브리졸 어드밴스드 머티어리얼스, 인코포레이티드 선택적 레이저 소결에서 열가소성 폴리우레탄을 이용하는 방법 및 이의 시스템 및 물품
WO2015156877A2 (en) * 2014-01-17 2015-10-15 Graphene 3D Lab Inc. Fused filament fabrication using multi-segment filament
JP6238793B2 (ja) * 2014-03-03 2017-11-29 株式会社クレハ フッ化ビニリデン系樹脂の溶融成形方法
GB201406683D0 (en) * 2014-04-14 2014-05-28 Montanuniversitat Leoben Resin composition suitable for printing and printing method utilizing the same
WO2015175682A1 (en) 2014-05-16 2015-11-19 Stratasys, Inc. High-temperature soluble support material for additive manufacturing
EP3145993B1 (en) * 2014-05-19 2021-09-29 Arkema, Inc. High melt flow fluoropolymer composition
US20160016369A1 (en) * 2014-05-21 2016-01-21 University Of South Carolina Novel Additive Manufacturing-Based Electric Poling Process of PVDF Polymer for Piezoelectric Device Applications
JP6745788B2 (ja) 2014-07-22 2020-08-26 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 熱溶解フィラメント製造プロセスにおいて使用するための混合物
US10059053B2 (en) 2014-11-04 2018-08-28 Stratasys, Inc. Break-away support material for additive manufacturing
US20160200046A1 (en) * 2015-01-14 2016-07-14 Xactiv, Inc. Apparatus and methods for fabricating an object
US20180361657A1 (en) * 2015-12-11 2018-12-20 Sabic Global Technologies B.V. Method of additive manufacturing to make objects having improved and tailored properties
CN108367489A (zh) * 2015-12-11 2018-08-03 沙特基础工业全球技术有限公司 在增材制造方法中改善层间粘合的粘合促进层
JP2018536565A (ja) * 2015-12-11 2018-12-13 サビック グローバル テクノロジーズ ベスローテン フェンノートシャップ 層間接着を改善する付加製造方法
US11179886B2 (en) * 2016-01-21 2021-11-23 3M Innovative Properties Company Additive processing of fluoropolymers
WO2017173258A1 (en) * 2016-04-01 2017-10-05 Arkema Inc. 3-d printed fluoropolymer structures
US10315409B2 (en) * 2016-07-20 2019-06-11 Xerox Corporation Method of selective laser sintering
JP6825293B2 (ja) * 2016-09-30 2021-02-03 セイコーエプソン株式会社 三次元造形物製造用組成物および三次元造形物の製造方法
WO2018118956A1 (en) * 2016-12-20 2018-06-28 3M Innovative Properties Company Composition including fluoropolymer and inorganic filler and method of making a three-dimensional article
US20190023817A1 (en) * 2017-02-16 2019-01-24 The Regents Of The University Of Michigan Ferroelectric polymers from dehydrofluorinated PVDF
CN110300768A (zh) * 2017-02-16 2019-10-01 索尔维特殊聚合物意大利有限公司 用于制造三维物体的方法
WO2018169789A1 (en) * 2017-03-13 2018-09-20 Arkema Inc. Polymer binder
US11248121B2 (en) * 2018-01-25 2022-02-15 Ut-Battelle, Llc Lignin-based polymers with enhanced melt extrusion ability
WO2019147896A1 (en) * 2018-01-25 2019-08-01 Ut-Battelle, Llc Lignin-based polymers with enhanced melt extrusion ability

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