JP6542774B2 - 非対称ポリエンを使用してエチレン系ポリマーを形成するための方法 - Google Patents

非対称ポリエンを使用してエチレン系ポリマーを形成するための方法 Download PDF

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Publication number
JP6542774B2
JP6542774B2 JP2016537556A JP2016537556A JP6542774B2 JP 6542774 B2 JP6542774 B2 JP 6542774B2 JP 2016537556 A JP2016537556 A JP 2016537556A JP 2016537556 A JP2016537556 A JP 2016537556A JP 6542774 B2 JP6542774 B2 JP 6542774B2
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reaction
ethylene
polyene
polymer
reaction part
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JP2017500399A (ja
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オットー・ジェイ・バービー
ステファン・ヒンリッチ
クリストファー・アール・エディ
サラ・ムンジャル
ジョン・オー・オズビー
ショーン・ダブリュ・エワート
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Dow Global Technologies LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/04—Homopolymers or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/282—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing two or more oxygen atoms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
JP2016537556A 2013-12-26 2014-12-23 非対称ポリエンを使用してエチレン系ポリマーを形成するための方法 Active JP6542774B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201361920899P 2013-12-26 2013-12-26
US61/920,899 2013-12-26
PCT/US2014/072138 WO2015100318A1 (en) 2013-12-26 2014-12-23 Processes to form ethylene-based polymers using asymmetrical polyenes

Related Child Applications (1)

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JP2019075556A Division JP2019151848A (ja) 2013-12-26 2019-04-11 非対称ポリエンを使用してエチレン系ポリマーを形成するための方法

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Publication Number Publication Date
JP2017500399A JP2017500399A (ja) 2017-01-05
JP6542774B2 true JP6542774B2 (ja) 2019-07-10

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JP2016537556A Active JP6542774B2 (ja) 2013-12-26 2014-12-23 非対称ポリエンを使用してエチレン系ポリマーを形成するための方法
JP2019075556A Pending JP2019151848A (ja) 2013-12-26 2019-04-11 非対称ポリエンを使用してエチレン系ポリマーを形成するための方法

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US (2) US9718906B2 (enExample)
EP (1) EP3087111B1 (enExample)
JP (2) JP6542774B2 (enExample)
KR (1) KR102278813B1 (enExample)
CN (1) CN105829362B (enExample)
BR (1) BR112016013701B1 (enExample)
ES (1) ES2717973T3 (enExample)
SG (1) SG11201605091RA (enExample)
WO (1) WO2015100318A1 (enExample)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102208726B1 (ko) 2013-05-22 2021-01-29 다우 글로벌 테크놀로지스 엘엘씨 고용융 강도 및 중간-고밀도 조절을 갖는 저밀도 에틸렌-기반 폴리머 조성물
JP6609254B2 (ja) * 2013-12-26 2019-11-20 ダウ グローバル テクノロジーズ エルエルシー 非対称ポリエンを使用して、エチレン系ポリマーの調製のための反応器の安定性を改善する方法
EP3626752B1 (en) 2013-12-26 2021-04-21 Dow Global Technologies LLC Ethylene-based polymers formed using asymmetrical polyenes
KR102359175B1 (ko) 2014-06-27 2022-02-08 다우 글로벌 테크놀로지스 엘엘씨 일산화탄소 및 레올로지 개질제로부터 유도된 단위를 포함하는 에틸렌계 폴리머
US9856338B2 (en) 2014-06-27 2018-01-02 Dow Global Technologies Llc Processes to prepare ethylene-based polymers using a distribution of carbon monoxide
WO2016209381A1 (en) 2015-06-24 2016-12-29 Dow Global Technologies Llc Processes to prepare ethylene-based polymers with improved melt-strength
CN107750259B (zh) * 2015-06-25 2021-04-09 陶氏环球技术有限责任公司 具有低己烷可萃取率和低密度的乙烯基聚合物
WO2016210160A1 (en) * 2015-06-25 2016-12-29 Dow Global Technologies Llc Improved process to make tubular ethylene based polymers with high g' and broad mwd
EP3168238A1 (en) 2015-11-10 2017-05-17 Dow Global Technologies LLC Ethylene-based polymers formed by high pressure free radical polymerizations
EP3260472A1 (en) * 2016-06-24 2017-12-27 Dow Global Technologies LLC Ethylene-based polymers formed by high pressure free radical polymerizations
BR112018074634B1 (pt) 2016-06-24 2022-12-27 Dow Global Technologies Llc Processo de polimerização de alta pressão para formar um polímero à base de etileno, polímero à base de etileno, composição e configuração de cabo ou de fio
EP3260473A1 (en) 2016-06-24 2017-12-27 Dow Global Technologies LLC High pressure, free radical polymerizations to produce ethylene-based polymers
EP3630853B1 (en) 2017-06-02 2021-03-17 Dow Global Technologies LLC Ethylene-based polymers and processes for the same
KR102153474B1 (ko) 2017-06-20 2020-09-08 주식회사 엘지화학 에틸렌 비닐아세테이트 공중합 공정 제어 시스템 및 그 제어 방법
JP7050630B2 (ja) * 2018-08-30 2022-04-08 信越化学工業株式会社 （メタ）アクリロイル化合物及びその製造方法
JP7384593B2 (ja) * 2019-08-22 2023-11-21 株式会社三共 遊技機
WO2025072152A1 (en) 2023-09-29 2025-04-03 Dow Global Technologies Llc Process for the production of ldpe

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2095493A5 (enExample) * 1970-06-11 1972-02-11 Leuna Werke Veb
JPS4827748B1 (enExample) * 1970-07-10 1973-08-25
US4503185A (en) * 1984-06-22 1985-03-05 Air Products And Chemicals, Inc. Vinyl acetate/ethylene copolymer emulsions for paper coating compositions
JPH0635496B2 (ja) * 1986-02-26 1994-05-11 日本石油化学株式会社 新規なエチレン共重合体
US6545088B1 (en) 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
JP3157163B2 (ja) 1991-12-30 2001-04-16 ザ・ダウ・ケミカル・カンパニー エチレンインターポリマーの重合
US6448341B1 (en) 1993-01-29 2002-09-10 The Dow Chemical Company Ethylene interpolymer blend compositions
RU2113443C1 (ru) 1993-01-29 1998-06-20 Дзе Дау Кемикал Компани Способ получения композиции сополимеров этилена и альфа-олефинов, композиция сополимеров этилена и альфа-олефинов
US5869575A (en) 1995-08-02 1999-02-09 The Dow Chemical Company Ethylene interpolymerizations
SE507045C2 (sv) 1996-05-31 1998-03-23 Borealis As Etensampolymer med förhöjd omättnadsgrad och sätt för framställning därav
JP2003048928A (ja) * 2001-05-29 2003-02-21 Nippon Shokubai Co Ltd 反応性希釈剤及び硬化性樹脂組成物
CA2599636C (en) 2005-03-09 2012-03-27 Saudi Basic Industries Corporation A process for the preparation of an ethylene copolymer in a tubular reactor
CN101432322B (zh) 2006-03-24 2011-01-26 沙特基础工业公司 挤出涂布组合物
JP5332350B2 (ja) * 2008-07-03 2013-11-06 Ｊｎｃ株式会社 感光性重合体組成物
JP5540495B2 (ja) * 2008-11-17 2014-07-02 大日本印刷株式会社 ハードコート層用硬化性樹脂組成物、及びハードコートフィルム
US8729186B2 (en) 2009-12-18 2014-05-20 Dow Global Technologies Llc Polymerization process to make low density polyethylene
CN102762609A (zh) * 2009-12-18 2012-10-31 陶氏环球技术有限责任公司 生产低密度聚乙烯的聚合方法
BR112013007508A2 (pt) 2010-09-30 2019-09-24 Dow Global Technologies Llc processo de polimerização em alta pressãp para formar um interpolímero a base de etileno, interpolímero a base de etileno e artigo
WO2012044504A1 (en) * 2010-09-30 2012-04-05 Dow Global Technologies Llc Polymerization process to make low density polyethylene
SG190030A1 (en) 2010-10-29 2013-06-28 Dow Global Technologies Llc Ethylene-based polymers and processes for the same
BR112013016031B1 (pt) 2010-12-22 2020-04-07 Basell Polyolefine Gmbh processo para preparar copolímero de etileno na presença de iniciador da polimerização por radicais livres por copolimerização de etileno, copolímero de etileno obtido por tal processo e seu uso, bem como processo para revestimento por extrusão de um substrato
CN103403040B (zh) * 2011-03-03 2015-11-25 巴塞尔聚烯烃股份有限公司 在具有至少两个具有不同链转移剂浓度的反应区的管式反应器中制备乙烯均聚物或共聚物的方法
ES2564234T3 (es) * 2011-10-19 2016-03-21 Dow Global Technologies Llc Procedimientos de polimerización con distribuciones de etileno de nueva aportación para preparar polímeros basados en etileno de baja densidad
WO2013078018A2 (en) 2011-11-23 2013-05-30 Dow Global Technologies Llc Low density ethylene-based polymers with broad molecular weight distributions and low extractables
WO2013095969A1 (en) * 2011-12-22 2013-06-27 Dow Global Technologies Llc Ethylene-based polymers with improved melt strength and processes for the same
EP2636691A1 (en) 2012-03-07 2013-09-11 Borealis AG Process and plant for manufacturing polyethylene-diene-copolymers
KR20140117524A (ko) 2012-04-02 2014-10-07 보레알리스 아게 억제제를 사용하는 에틸렌 중합 공정
US9505860B2 (en) 2012-04-02 2016-11-29 Borealis Ag High-pressure radial ethylene polymerization process in which ethylene is polymerized with a specific polyunsaturated olefin grade
JP6339565B2 (ja) * 2012-06-27 2018-06-06 ダウ グローバル テクノロジーズ エルエルシー エチレン系ポリマーおよびそのプロセス
JP6609254B2 (ja) * 2013-12-26 2019-11-20 ダウ グローバル テクノロジーズ エルエルシー 非対称ポリエンを使用して、エチレン系ポリマーの調製のための反応器の安定性を改善する方法
EP3626752B1 (en) * 2013-12-26 2021-04-21 Dow Global Technologies LLC Ethylene-based polymers formed using asymmetrical polyenes

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Publication number Publication date
US20170335034A1 (en) 2017-11-23
EP3087111B1 (en) 2019-01-30
CN105829362B (zh) 2019-06-07
WO2015100318A1 (en) 2015-07-02
US20160297904A1 (en) 2016-10-13
CN105829362A (zh) 2016-08-03
US9718906B2 (en) 2017-08-01
KR20160103023A (ko) 2016-08-31
ES2717973T3 (es) 2019-06-26
SG11201605091RA (en) 2016-07-28
BR112016013701B1 (pt) 2022-01-04
JP2019151848A (ja) 2019-09-12
JP2017500399A (ja) 2017-01-05
KR102278813B1 (ko) 2021-07-21
BR112016013701A2 (enExample) 2017-08-08
EP3087111A1 (en) 2016-11-02
US10005863B2 (en) 2018-06-26

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