JP6472751B2 - ペンタブロモベンジル（メタ）アクリレートの重合方法、得られたポリマーおよびその使用 - Google Patents

ペンタブロモベンジル（メタ）アクリレートの重合方法、得られたポリマーおよびその使用 Download PDF

Info

Publication number
JP6472751B2
JP6472751B2 JP2015537415A JP2015537415A JP6472751B2 JP 6472751 B2 JP6472751 B2 JP 6472751B2 JP 2015537415 A JP2015537415 A JP 2015537415A JP 2015537415 A JP2015537415 A JP 2015537415A JP 6472751 B2 JP6472751 B2 JP 6472751B2
Authority
JP
Japan
Prior art keywords
pbbpa
water
weight
ethylene glycol
initiator
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2015537415A
Other languages
English (en)
Japanese (ja)
Other versions
JP2015532350A (ja
JP2015532350A5 (enExample
Inventor
クロイトル，バーサ
ベルーベン，ドブ
ペレド，マイケル
ラクミーレビッチ，ヤーコブ
ヒルシュソーン，ヤニブ
エプシテイン・アソー，イェレナ
ラパポート，エラ
コペル，ダン
Original Assignee
ブロミン・コンパウンズ・リミテツド
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ブロミン・コンパウンズ・リミテツド filed Critical ブロミン・コンパウンズ・リミテツド
Publication of JP2015532350A publication Critical patent/JP2015532350A/ja
Publication of JP2015532350A5 publication Critical patent/JP2015532350A5/ja
Application granted granted Critical
Publication of JP6472751B2 publication Critical patent/JP6472751B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/10—Aqueous solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/22—Esters containing halogen
    • C08F220/24—Esters containing halogen containing perhaloalkyl radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
    • C08L33/16—Homopolymers or copolymers of esters containing halogen atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/12—Applications used for fibers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30—Flame or heat resistance, fire retardancy properties

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Polymerisation Methods In General (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
JP2015537415A 2012-10-17 2013-10-17 ペンタブロモベンジル（メタ）アクリレートの重合方法、得られたポリマーおよびその使用 Active JP6472751B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261714767P 2012-10-17 2012-10-17
US61/714,767 2012-10-17
PCT/IL2013/000078 WO2014061010A1 (en) 2012-10-17 2013-10-17 Process for the polymerization of pentabromobenzyl (meth) acrylate, the polymer obtained and uses thereof

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2018187508A Division JP6625185B2 (ja) 2012-10-17 2018-10-02 ペンタブロモベンジル（メタ）アクリレートの重合方法、得られたポリマーおよびその使用

Publications (3)

Publication Number Publication Date
JP2015532350A JP2015532350A (ja) 2015-11-09
JP2015532350A5 JP2015532350A5 (enExample) 2016-11-24
JP6472751B2 true JP6472751B2 (ja) 2019-02-20

Family

ID=49679572

Family Applications (2)

Application Number Title Priority Date Filing Date
JP2015537415A Active JP6472751B2 (ja) 2012-10-17 2013-10-17 ペンタブロモベンジル（メタ）アクリレートの重合方法、得られたポリマーおよびその使用
JP2018187508A Active JP6625185B2 (ja) 2012-10-17 2018-10-02 ペンタブロモベンジル（メタ）アクリレートの重合方法、得られたポリマーおよびその使用

Family Applications After (1)

Application Number Title Priority Date Filing Date
JP2018187508A Active JP6625185B2 (ja) 2012-10-17 2018-10-02 ペンタブロモベンジル（メタ）アクリレートの重合方法、得られたポリマーおよびその使用

Country Status (6)

Country Link
US (1) US9493584B2 (enExample)
EP (1) EP2909245A1 (enExample)
JP (2) JP6472751B2 (enExample)
KR (1) KR20150083837A (enExample)
CN (1) CN104903367B (enExample)
WO (1) WO2014061010A1 (enExample)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6335922B2 (ja) 2013-01-06 2018-05-30 ブロミン・コンパウンズ・リミテツド 臭素含有芳香族化合物の調製およびその難燃剤としての利用
EP3166989B1 (en) 2014-07-08 2020-03-25 Bromine Compounds Ltd. Preparation of bromine-containing polymers useful as flame retardants
WO2016005973A1 (en) * 2014-07-08 2016-01-14 Bromine Compounds Ltd. Preparation of bromine-containing polymers and their application as flame retardants
US10626269B2 (en) 2015-09-11 2020-04-21 Mitsubishi Engineering-Plastics Corporation Polyester resin composition and method for producing same
JP6326102B2 (ja) * 2015-09-11 2018-05-16 三菱エンジニアリングプラスチックス株式会社 ポリエステル系樹脂組成物及びその製造方法
JP6792376B2 (ja) * 2016-03-31 2020-11-25 三菱エンジニアリングプラスチックス株式会社 ポリエステル系樹脂組成物及び成形品
JP6663292B2 (ja) * 2016-04-28 2020-03-11 三菱エンジニアリングプラスチックス株式会社 ポリエステル系樹脂組成物及び成形品
JP7144924B2 (ja) * 2017-08-22 2022-09-30 ポリプラスチックス株式会社 難燃性ポリブチレンテレフタレート樹脂組成物
CN111868172B (zh) 2018-03-22 2022-04-15 宝理塑料株式会社 阻燃性聚对苯二甲酸丁二醇酯树脂组合物
WO2019199403A1 (en) * 2018-04-09 2019-10-17 Albemarle Corporation Flame retardants for textile applications
JP7071236B2 (ja) * 2018-07-03 2022-05-18 ポリプラスチックス株式会社 電気絶縁部品用難燃性ポリブチレンテレフタレート樹脂組成物
JP7665278B2 (ja) * 2018-08-03 2025-04-21 ポリプラスチックス株式会社 難燃性ポリブチレンテレフタレート樹脂組成物
JP7182396B2 (ja) * 2018-08-10 2022-12-02 ポリプラスチックス株式会社 難燃性ポリブチレンテレフタレート樹脂組成物
JP7195315B2 (ja) * 2018-11-09 2022-12-23 ポリプラスチックス株式会社 難燃性ポリブチレンテレフタレート樹脂組成物
CN117024635B (zh) * 2023-07-28 2024-04-02 潍坊裕凯化工有限公司 一种制备聚丙烯酸五溴苄酯的方法

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE421072B (sv) * 1975-06-21 1981-11-23 Dynamit Nobel Ag Polymerer pa basis av pentabrombensylestrar och tetrabromxylylendiestrar samt anvendning derav som flamskyddsmedel
DE2920085C2 (de) * 1979-05-18 1986-09-25 Chemische Fabrik Kalk GmbH, 5000 Köln Verfahren zur Herstellung polymerer Pentabrombenzylacrylate
IL86605A (en) * 1988-06-02 1992-02-16 Bromine Compounds Ltd Process for the polymerization of pentabromobenzylester monoacrylate
US5387636A (en) 1991-08-14 1995-02-07 Albemarle Corporation Flame-retarded hips formulations with enhanced impact strength
IL103573A (en) * 1992-10-28 1996-10-31 Bromine Compounds Ltd Method of improving the surface compatibility of polypropylene and its compositions and articles obtained thereby
JPH08218003A (ja) * 1995-02-17 1996-08-27 Hitachi Chem Co Ltd ワニス組成物及び防汚塗料組成物
CN1137910C (zh) 1995-11-09 2004-02-11 大金工业株式会社 聚四氟乙烯细粉、其制造方法和用途
US6028156A (en) * 1996-01-16 2000-02-22 Bromine Compounds, Ltd. Process for the preparation of poly-(halobenzyl acrylate)
CA2205099A1 (en) * 1996-05-24 1997-11-24 Patricia Marie Lesko Fluorescent polymers and coating compositions
KR100490444B1 (ko) 1997-12-31 2005-09-02 삼성전자주식회사 광통신용 폴리아미드이미드
US20040058276A1 (en) * 2002-09-23 2004-03-25 Dueber Thomas E. Halo resistent, photoimagable coverlay compositions, having, advantageous application and removal properties, and methods relating thereto
JP4326003B2 (ja) * 2003-09-26 2009-09-02 株式会社日本触媒 ポリマー被覆粒子の製造方法
JP5083444B2 (ja) * 2005-09-28 2012-11-28 Ｊｎｃ株式会社 フッ素系重合体および樹脂組成物
JP5332141B2 (ja) * 2007-06-27 2013-11-06 東ソー株式会社 ポリマーエマルジョン及びその製造法
US8524813B2 (en) 2008-07-22 2013-09-03 Bromine Compounds Ltd. Flame-retarded compositions of styrene-containing polymers
JP5803064B2 (ja) * 2010-07-27 2015-11-04 Jnc株式会社 感光性高分子化合物からなる光配向剤、該光配向剤を用いた液晶配向膜および該液晶配向膜を用いた液晶表示素子
JP2012116949A (ja) * 2010-11-30 2012-06-21 Nippon Shokubai Co Ltd ポリアルキレングリコール系重合体、セメント混和剤及びセメント組成物
CN102167762B (zh) 2011-02-25 2012-07-25 山东润科化工股份有限公司 一种生产聚五溴苄基丙烯酸酯的方法
WO2012140649A1 (en) 2011-04-14 2012-10-18 Bromine Compounds Ltd. Process for the preparation of the monomer pentabromobenzyl acrylate and polymerization thereof

Also Published As

Publication number Publication date
EP2909245A1 (en) 2015-08-26
JP2015532350A (ja) 2015-11-09
JP6625185B2 (ja) 2019-12-25
US9493584B2 (en) 2016-11-15
JP2019035083A (ja) 2019-03-07
WO2014061010A1 (en) 2014-04-24
CN104903367B (zh) 2018-11-27
CN104903367A (zh) 2015-09-09
KR20150083837A (ko) 2015-07-20
US20150259440A1 (en) 2015-09-17

Similar Documents

Publication Publication Date Title
JP6625185B2 (ja) ペンタブロモベンジル（メタ）アクリレートの重合方法、得られたポリマーおよびその使用
CN107709508B (zh) 拒水剂组合物、拒水剂组合物的制造方法及物品
TW201224007A (en) Intumescent, halogen-free, silicon-phosphorus-nitrogen based polymeric flame retardant
JP7365359B2 (ja) 布帛用難燃剤
JP2014101520A (ja) 低分子量臭素化アニオン性連鎖移動芳香族ビニルポリマーを含む難燃性組成物
WO2012020806A1 (ja) 撥水撥油剤組成物および物品
US20150337125A1 (en) Brominated Flame Retardants and their use in Thermoplastic and Thermosetting Flammable Materials
WO2015162609A1 (en) Process for the polymerization of pentabromobenzyl (meth) acrylate, the polymer obtained and uses thereof
CN110157133A (zh) 一种含磷丙烯酸酯弹性体阻燃剂及其制备方法
US20190144754A1 (en) Process for preparing bromine- containing polymers
US9988332B2 (en) Preparation of bromine-containing aromatic compounds and their application as flame retardants
JP3013191B2 (ja) 改良された難燃性配合物
JPH07505910A (ja) ポリオレフィンに有用な難燃性添加剤組成物
TWI850575B (zh) 水性壓克力樹脂及其製造方法
US12565563B2 (en) Halogen-free synergist
WO2018008018A1 (en) Bromine-containing copolymers
JP7438520B2 (ja) 含ハロゲン重合体及びそれを含む繊維用難燃剤及び防炎繊維製品
WO2019016168A1 (en) AQUEOUS RETICULABLE COATING COMPOSITION
CN105348427A (zh) 一种聚合物磺酸盐阻燃剂及其制备方法和应用
WO2025245332A1 (en) Architectural compositions with improved gloss retention
US20240317972A1 (en) Polyvinyl phosphonate amine salts and flame retarded compositions containing the same
TW202602964A (zh) 包含含磷聚合物之纖維用阻燃劑及阻燃性纖維製品
JP4763836B2 (ja) リン系酸残基含有（メタ）アクリルアミド含有組成物、並びにリン系酸残基含有ビニル系重合体含有組成物、その製造方法及び用途
JPH0579698B2 (enExample)
JPH04126754A (ja) 難燃性メタクリル系樹脂組成物

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20150416

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20161003

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20161003

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20170524

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20170530

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20170824

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20171129

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20180403

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20180627

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20181002

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20190108

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20190123

R150 Certificate of patent or registration of utility model

Ref document number: 6472751

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250