JP6385358B2 - 難燃性ポリカーボネート成形組成物v - Google Patents
難燃性ポリカーボネート成形組成物v Download PDFInfo
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- JP6385358B2 JP6385358B2 JP2015545992A JP2015545992A JP6385358B2 JP 6385358 B2 JP6385358 B2 JP 6385358B2 JP 2015545992 A JP2015545992 A JP 2015545992A JP 2015545992 A JP2015545992 A JP 2015545992A JP 6385358 B2 JP6385358 B2 JP 6385358B2
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- 239000000203 mixture Substances 0.000 title claims description 85
- 229920000515 polycarbonate Polymers 0.000 title claims description 31
- 239000004417 polycarbonate Substances 0.000 title claims description 31
- 239000003063 flame retardant Substances 0.000 title claims description 16
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims description 14
- 238000000465 moulding Methods 0.000 title description 23
- -1 methoxy, ethoxy, propoxy Chemical group 0.000 claims description 47
- 125000003118 aryl group Chemical group 0.000 claims description 27
- GKTNLYAAZKKMTQ-UHFFFAOYSA-N n-[bis(dimethylamino)phosphinimyl]-n-methylmethanamine Chemical compound CN(C)P(=N)(N(C)C)N(C)C GKTNLYAAZKKMTQ-UHFFFAOYSA-N 0.000 claims description 27
- 229920000578 graft copolymer Polymers 0.000 claims description 22
- 238000004519 manufacturing process Methods 0.000 claims description 20
- 229920001283 Polyalkylene terephthalate Polymers 0.000 claims description 17
- 125000000217 alkyl group Chemical group 0.000 claims description 16
- 229920000728 polyester Polymers 0.000 claims description 16
- 239000000460 chlorine Substances 0.000 claims description 14
- 229910052801 chlorine Inorganic materials 0.000 claims description 13
- 229920001971 elastomer Polymers 0.000 claims description 13
- 239000005060 rubber Substances 0.000 claims description 13
- 125000004122 cyclic group Chemical group 0.000 claims description 12
- 229910052736 halogen Inorganic materials 0.000 claims description 12
- 150000002367 halogens Chemical class 0.000 claims description 12
- 239000013638 trimer Substances 0.000 claims description 12
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 10
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 10
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 10
- 229910052794 bromium Inorganic materials 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
- 229920006163 vinyl copolymer Polymers 0.000 claims description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 5
- 239000011737 fluorine Substances 0.000 claims description 5
- 229910052731 fluorine Inorganic materials 0.000 claims description 5
- 239000003381 stabilizer Substances 0.000 claims description 5
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 3
- 125000003545 alkoxy group Chemical group 0.000 claims description 3
- 125000003277 amino group Chemical group 0.000 claims description 3
- 239000002216 antistatic agent Substances 0.000 claims description 3
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 3
- 125000004104 aryloxy group Chemical group 0.000 claims description 3
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 239000000314 lubricant Substances 0.000 claims description 3
- 239000006082 mold release agent Substances 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 239000012779 reinforcing material Substances 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- 150000001804 chlorine Chemical class 0.000 claims description 2
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 claims description 2
- 239000003086 colorant Substances 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- 239000002667 nucleating agent Substances 0.000 claims description 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- 229920003244 diene elastomer Polymers 0.000 claims 1
- 229920002635 polyurethane Polymers 0.000 claims 1
- 239000004814 polyurethane Substances 0.000 claims 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 30
- 239000000178 monomer Substances 0.000 description 20
- 229920000642 polymer Polymers 0.000 description 17
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 16
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 16
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 16
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 13
- 125000004432 carbon atom Chemical group C* 0.000 description 13
- 229920001577 copolymer Polymers 0.000 description 13
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 12
- KKEYFWRCBNTPAC-UHFFFAOYSA-N benzene-dicarboxylic acid Natural products OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 12
- 239000002245 particle Substances 0.000 description 11
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 9
- 229920000098 polyolefin Polymers 0.000 description 9
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 8
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 8
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 8
- 229920001169 thermoplastic Polymers 0.000 description 8
- 239000004416 thermosoftening plastic Substances 0.000 description 8
- 238000004132 cross linking Methods 0.000 description 7
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 7
- 239000004810 polytetrafluoroethylene Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000006085 branching agent Substances 0.000 description 6
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical group OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 150000002009 diols Chemical class 0.000 description 6
- 229920002554 vinyl polymer Polymers 0.000 description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- OCKWAZCWKSMKNC-UHFFFAOYSA-N [3-octadecanoyloxy-2,2-bis(octadecanoyloxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(COC(=O)CCCCCCCCCCCCCCCCC)(COC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC OCKWAZCWKSMKNC-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 5
- 150000001735 carboxylic acids Chemical class 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 230000009477 glass transition Effects 0.000 description 5
- 230000003301 hydrolyzing effect Effects 0.000 description 5
- 229920002857 polybutadiene Polymers 0.000 description 5
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 4
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
- 238000012662 bulk polymerization Methods 0.000 description 4
- 238000007720 emulsion polymerization reaction Methods 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 238000005227 gel permeation chromatography Methods 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000005062 Polybutadiene Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 125000005250 alkyl acrylate group Chemical group 0.000 description 3
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 3
- 229940106691 bisphenol a Drugs 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 3
- 229920001707 polybutylene terephthalate Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 2
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 2
- BSWWXRFVMJHFBN-UHFFFAOYSA-N 2,4,6-tribromophenol Chemical compound OC1=C(Br)C=C(Br)C=C1Br BSWWXRFVMJHFBN-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 2
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 229920001634 Copolyester Polymers 0.000 description 2
- 239000004641 Diallyl-phthalate Substances 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 2
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 150000008065 acid anhydrides Chemical class 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 125000005587 carbonate group Chemical group 0.000 description 2
- PFURGBBHAOXLIO-UHFFFAOYSA-N cyclohexane-1,2-diol Chemical compound OC1CCCCC1O PFURGBBHAOXLIO-UHFFFAOYSA-N 0.000 description 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 2
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002391 heterocyclic compounds Chemical class 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 2
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 2
- 150000003949 imides Chemical class 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 description 1
- BGGGMYCMZTXZBY-UHFFFAOYSA-N (3-hydroxyphenyl) phosphono hydrogen phosphate Chemical compound OC1=CC=CC(OP(O)(=O)OP(O)(O)=O)=C1 BGGGMYCMZTXZBY-UHFFFAOYSA-N 0.000 description 1
- 125000006833 (C1-C5) alkylene group Chemical group 0.000 description 1
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- FYBFGAFWCBMEDG-UHFFFAOYSA-N 1-[3,5-di(prop-2-enoyl)-1,3,5-triazinan-1-yl]prop-2-en-1-one Chemical compound C=CC(=O)N1CN(C(=O)C=C)CN(C(=O)C=C)C1 FYBFGAFWCBMEDG-UHFFFAOYSA-N 0.000 description 1
- KTZVZZJJVJQZHV-UHFFFAOYSA-N 1-chloro-4-ethenylbenzene Chemical compound ClC1=CC=C(C=C)C=C1 KTZVZZJJVJQZHV-UHFFFAOYSA-N 0.000 description 1
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 description 1
- YIYBRXKMQFDHSM-UHFFFAOYSA-N 2,2'-Dihydroxybenzophenone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1O YIYBRXKMQFDHSM-UHFFFAOYSA-N 0.000 description 1
- FQXGHZNSUOHCLO-UHFFFAOYSA-N 2,2,4,4-tetramethyl-1,3-cyclobutanediol Chemical compound CC1(C)C(O)C(C)(C)C1O FQXGHZNSUOHCLO-UHFFFAOYSA-N 0.000 description 1
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- 239000001294 propane Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010558 suspension polymerization method Methods 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 238000009757 thermoplastic moulding Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- XHGIFBQQEGRTPB-UHFFFAOYSA-N tris(prop-2-enyl) phosphate Chemical compound C=CCOP(=O)(OCC=C)OCC=C XHGIFBQQEGRTPB-UHFFFAOYSA-N 0.000 description 1
- 238000005199 ultracentrifugation Methods 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6581—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and nitrogen atoms with or without oxygen or sulfur atoms, as ring hetero atoms
- C07F9/65812—Cyclic phosphazenes [P=N-]n, n>=3
- C07F9/65814—Cyclic phosphazenes [P=N-]n, n>=3 n = 3 or 4
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- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6581—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and nitrogen atoms with or without oxygen or sulfur atoms, as ring hetero atoms
- C07F9/65812—Cyclic phosphazenes [P=N-]n, n>=3
- C07F9/65818—Cyclic phosphazenes [P=N-]n, n>=3 n > 4
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/5399—Phosphorus bound to nitrogen
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- Molecular Biology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
A)80〜98重量部、好ましくは85〜97重量部、より好ましくは88〜96重量部の、芳香族ポリカーボネート及び/又は芳香族ポリエステルカーボネート、
B)0.5〜6.0重量部、好ましくは1.0〜5.0重量部、特に好ましくは1.5〜4.0重量部のゴム変性したグラフト重合体、
C)0.8〜5.0重量部、好ましくは1.0〜4.5重量部、より好ましくは1.5〜4.0重量部の、少なくとも一種の式(X)の環状ホスファゼン
kは、1又は1〜10の整数、好ましくは1〜8、特に好ましくは1〜5の数を表し、
三量体含有量(k=1)が、成分Cに対して、60〜98mol%、より好ましくは65〜95mol%、特に好ましくは65〜90mol%、最も好ましくは65〜85mol%、特に70〜85mol%であり、
Rは、それぞれの場合に、同一であるか、又は異なるものであって、アミン基;それぞれ所望によりハロゲン化、好ましくはフッ素でハロゲン化されている、C1〜C8アルキル、好ましくはメチル、エチル、プロピル又はブチル;C1〜C8アルコキシ、好ましくはメトキシ、エトキシ、プロポキシ又はブトキシ;それぞれ所望によりアルキル、好ましくはC1〜C4アルキル、及び/又はハロゲン、好ましくは塩素及び/又は臭素により置換されている、C5〜C6シクロアルキル;それぞれ所望によりアルキル、好ましくはC1〜C4アルキル、及び/又はハロゲン、好ましくは塩素、臭素及び/又はヒドロキシにより置換されている、C6〜C20アリールオキシ、好ましくはフェノキシ、ナフチルオキシ;それぞれ所望によりアルキル、好ましくはC1〜C4アルキル、及び/又はハロゲン、好ましくは塩素及び/又は臭素により置換されている、C7〜C12アラルキル、好ましくはフェニル−C1〜C4アルキル;又はハロゲン基、好ましくは塩素、又はOH基を表す。)、
D)0〜5.0重量部、好ましくは0.5〜4.0重量部、より好ましくは1.0〜3.0重量部の、ゴムを含まない、ビニル(共)重合体又はポリアルキレンテレフタレート、
E)0〜15.0重量部、好ましくは0.05〜12.00重量部、より好ましくは0.2〜10.0重量部、特に好ましくは0.4〜5.0重量部、の添加剤、
F)0.05〜1.00重量部、好ましくは0.1〜0.8重量部、特に好ましくは0.1〜0.6重量部、の滴防止剤
を含んでなり、全ての重量部が好ましくは、本願では、組成物中の全ての成分A+B+C+D+E+Fの重量部の合計が100になるように、正規化されている組成物により、達成されることが分かった。
本発明に好適な成分Aによる芳香族ポリカーボネート及び/又は芳香族ポリエステルカーボネートは、文献中で公知であるか、又は、文献中で公知の方法により製造することができる(芳香族ポリカーボネートの製造に関しては、例えばSchnell、"Chemistry and Physics of Polycarbonates"、Interscience Publishers、1964及びDE-AS 1495626、独国特許出願公開第2232877号、第2703376号、第2714544号、第3000610号、第3832396号参照、芳香族ポリエステルカーボネートの製造に関しては、例えば独国特許出願公開第3007934号参照)。
Aは、単結合、C1〜C5アルキレン、C2〜C5アルキリデン、C5〜C6シクロアルキリデン、−O−、−SO−、−CO−、−S−、−SO2−、C6〜C12アリーレンであり、そこには所望により異原子を含むさらなる芳香族環が縮合することができる、
又は式(II)又は(III)の基であり、
xは、それぞれ相互に独立して、0、1または2であり、
pは、1または0であり、
R5及びR6は、各X1に対して個別に選択することができ、それぞれ相互に独立して、水素又はC1〜C6アルキル、好ましくは水素、メチル又はエチルであり、
X1は、炭素であり、
mは、4〜7の整数、好ましくは4または5であるが、ただし、少なくとも一個のX1上で、R5及びR6は、同時にアルキルである。)
グラフトポリマーBは、例えば、ゴム−弾性特性を備えたグラフトポリマーであって、以下のモノマーのうち少なくとも2種から実質的に得られるグラフトポリマーを含んでなる:クロロプレン、1,3−ブタジエン、イソプレン、スチレン、アクリロニトリル、エチレン、プロピレン、酢酸ビニルおよび1〜18個の炭素原子をアルコール成分中に含む(メタ)アクリル酸エステル。すなわち、上記のポリマーは、例えば、"Methoden der Organischen Chemie" (Houben-Weyl), Vol. 14/1, Georg Thieme-Verlag, Stuttgart 1961, p. 393-406およびC.B. Bucknall, "Toughened Plastics", Appl. Science Publishers, London 1977に記載されたポリマーである。
B.1)5〜95重量部、好ましくは30〜80重量部の、
B.1.1)50〜95重量部のスチレン、α−メチルスチレン、環の一部がメチルで置換されたスチレン、C1−C8アルキルメタクリレート、特に、メチルメタクリレート、C1−C8アルキルアクリレート、特に、メチルアクリレート、またはこれらの混合物、および
B.1.2)5〜50重量部のアクリロニトリル、メタクリロニトリル、C1−C8アルキルメタクリレート、特に、メチルメタクリレート、C1−C8アルキルアクリレート、特にメチルアクリレート、無水マレイン酸、C1−C4アルキルまたはフェニル−N−置換マレイミド、またはこれらの化合物の混合物、
の混合物と、
B2)5〜95重量部、好ましくは20〜70重量部、のゴム含有グラフトベースと
のグラフトポリマーを含んでなる。
I.グラフト生成物を基準として、10〜70重量%、好ましくは15〜50重量%、特に20〜40重量%、の少なくとも1種の(メタ)アクリル酸エステル、または10〜70重量%、好ましくは15〜50重量%、特に20〜40重量%、の、混合物を基準として、10〜50重量%、好ましくは20〜35重量%のアクリロニトリルまたは(メタ)アクリル酸エステルと、50〜90重量%、好ましくは65〜80重量%のスチレンとの混合物、と
II.グラフト生成物を基準として、30〜90重量%、好ましくは40〜85重量%、特に、50〜80重量%、の、IIを基準として少なくとも50重量%のブタジエンラジカルをグラフトベースとして有するブタジエンポリマーと
のグラフト反応によって得られるグラフトポリマーである。
(a)グラフトベースとして、B基準で、20〜90重量%のアクリレートゴムと、
(b)グラフトモノマーとして、B基準で、10〜80重量%の少なくとも1種の重合可能なエチレン性の不飽和モノマーであって、(a)の不存在化で形成されたそのホモポリマーまたはコポリマーが25℃以上のガラス転移温度を有するであろうモノマーと
のグラフトポリマーでもある。
本発明で使用する成分Cによるホスファゼンは、式(X)による環状ホスファゼンである。
Rは、それぞれの場合に、同一であるか、又は異なるものであって、
−アミン基、
−それぞれ所望によりハロゲン化、好ましくはフッ素でハロゲン化されている、より好ましくはモノハロゲン化されている、C1〜C8アルキル、好ましくはメチル、エチル、プロピル又はブチル、
−C1〜C8アルコキシ、好ましくはメトキシ、エトキシ、プロポキシ又はブトキシ、
−それぞれ所望によりアルキル、好ましくはC1〜C4アルキル、及び/又はハロゲン、好ましくは塩素及び/又は臭素により置換されている、C5〜C6シクロアルキル、
−それぞれ所望によりアルキル、好ましくはC1〜C4アルキル、及び/又はハロゲン、好ましくは塩素、臭素及び/又はヒドロキシにより置換されている、C6〜C20アリールオキシ、好ましくはフェノキシ、ナフチルオキシ、
−それぞれ所望によりアルキル、好ましくはC1〜C4アルキル、及び/又はハロゲン、好ましくは塩素及び/又は臭素により置換されている、C7〜C12アラルキル、好ましくはフェニル-C1〜C4アルキル、又は
−ハロゲン基、好ましくは塩素又はフッ素、又は
−OH基を表し、
kは、上記の意味を有する。)
成分Dは、一種以上の熱可塑性ビニル(共)重合体又はポリアルキレンテレフタレートを含んでなる。
D.1 50〜99重量部、好ましくは60〜80重量部のビニル芳香族化合物及び/又は環上で置換されたビニル芳香族化合物(例えばスチレン、α−メチルスチレン、p−メチルスチレン、p−クロロスチレン)及び/又は(メタ)アクリル酸(C1〜C8)−アルキルエステル(例えばメチルメタクリレート、エチルメタクリレート)、及び
D.2 1〜50重量部、好ましくは20〜40重量部のビニルシアン化物(不飽和ニトリル)、例えばアクリロニトリル及びメタクリロニトリル、及び/又は(メタ)アクリル酸(C1〜C8)−アルキルエステル、例えばメチルメタクリレート、n−ブチルアクリレート、tert−ブチルアクリレート、及び/又は不飽和カルボン酸、例えばマレイン酸、及び/又は不飽和カルボン酸の誘導体、例えば酸無水物及びイミド(例えば無水マレイン酸及びN−フェニルマレイミド)
の(共)重合体である。
組成物は、さらなる従来の重合体添加剤、例えば滴防止剤以外の難燃性相乗剤、潤滑剤及び離型剤(例えばペンタエリトリトールテトラステアレート)、核形成剤、安定剤(例えばUV/光安定剤、熱安定剤、酸化防止剤、エステル交換反応防止剤、加水分解安定剤)、帯電防止剤(例えば導電性ブラック、カーボン繊維、カーボンナノチューブ並びに有機帯電防止剤、例えばポリアルキレンエーテル、アルキルスルホナート又はポリアミド含有重合体)並びに着色剤、顔料、充填剤及び補強材料、特にガラス繊維、鉱物補強材料及び炭素繊維を含むことができる。
所望により使用するさらなる添加剤と共に、特に好ましい難燃性組成物は、成分Fとして、フッ素化ポリオレフィンを、0.05〜1.0重量部、好ましくは0.1〜0.8重量部、特に好ましくは0.2〜0.6重量部の量で含んでなる。
ビスフェノールAを基剤とする直鎖状ポリカーボネート、重量平均分子量Mw27,500g/mol(標準としてポリカーボネートで、ジクロロメタン中でGPCにより測定)
ABSグラフト重合体、ABS重合体に対して、アクリロニトリル27重量%及びスチレン73重量%の混合物43重量%を、ABS重合体に対して、粒子状架橋したポリブタジエンゴム(平均粒子径d50=0.35μm)57重量%の存在下でエマルション重合により製造
塊状重合によって調製した、重量平均分子量Mwが130kg/モル(GPCにより測定)の77重量%のスチレンと23重量%のアクリロニトリルのコポリマー
潤滑剤/離型剤としてのペンタエリトリトールテトラステアレート
熱安定剤Irganox(登録商標)B900(80%Irgafos(登録商標)168及び20%Irganox(登録商標)1076の混合物、BASF AG、Ludwigshafen/Irgafos(登録商標)168(トリス(2,4−ジ−tert−ブチル−フェニル)ホスファイト)/Irganox(登録商標)1076(2,6−ジ−tert−ブチル−4−(オクタデカノキシカルボニルエチル)フェノール)
ポリテトラフルオロエチレン粉体、CFP 6000 N、DuPont
表1に挙げた物質を、速度225rpm及び処理量20kg/h、機械温度260℃、双軸スクリュー押出機(ZSK-25)(Werner und Pfleiderer)で配合し、造粒した。
Claims (12)
- 組成物であって、
A)80〜98重量部の、芳香族ポリカーボネート及び/又は芳香族ポリエステルカーボネート、
B)0.5〜6.0重量部のゴム変性したグラフト重合体、
C)0.8〜5.0重量部の、少なくとも一種の式(X)の環状ホスファゼン
kが、1又は1〜10の整数、好ましくは1〜8、特に好ましくは1〜5の数を表し、
三量体含有量(k=1)が、成分Cに対して、60〜98mol%であり、
Rが、それぞれの場合に、同一であるか、又は異なるものであって、アミン基;それぞれ所望によりハロゲン化、好ましくはフッ素でハロゲン化されている、C1〜C8アルキル、好ましくはメチル、エチル、プロピル又はブチル;C1〜C8アルコキシ、好ましくはメトキシ、エトキシ、プロポキシ又はブトキシ;それぞれ所望によりアルキル、好ましくはC1〜C4アルキル、及び/又はハロゲン、好ましくは塩素及び/又は臭素により置換されている、C5〜C6シクロアルキル;それぞれ所望によりアルキル、好ましくはC1〜C4アルキル、及び/又はハロゲン、好ましくは塩素、臭素及び/又はヒドロキシにより置換されている、C6〜C20アリールオキシ、好ましくはフェノキシ、ナフチルオキシ;それぞれ所望によりアルキル、好ましくはC1〜C4アルキル、及び/又はハロゲン、好ましくは塩素及び/又は臭素により置換されている、C7〜C12アラルキル、好ましくはフェニル−C1〜C4アルキル;又はハロゲン基、好ましくは塩素、又はOH基を表す。)、
D)0〜5.0重量部の、ゴムを含まない、ビニル(共)重合体又はポリアルキレンテレフタレート、
E)0〜15.0重量部の添加剤、
F)0.05〜1.00重量部、好ましくは0.1〜0.8重量部、より好ましくは0.1〜0.6重量部の滴防止剤
を含んでなり、全ての重量部が好ましくは、組成物中の全ての成分A+B+C+D+E+Fの重量部の合計が100になるように、正規化されており、
成分Cの量が1.0〜4.5重量部である、組成物。 - 三量体(k=1)の含有量が、成分Cに対して、60〜98mol%、より好ましくは65〜95mol%、特に好ましくは65〜90mol%である、請求項1に記載の組成物。
- 成分Cが、プロポキシホスファゼン、フェノキシホスファゼン、メチルフェノキシホスファゼン、アミノホスファゼン及びフルオロアルキルホスファゼンを含んでなる群から選択される、請求項1または2に記載の組成物。
- Rがフェノキシである、請求項1〜3のいずれか一項に記載の組成物。
- 前記三量体(k=1)の含有量が、成分Cに対して、65〜85mol%である、請求項1に記載の組成物。
- それぞれの場合に成分Cに対して、前記三量体含有量(k=1)が、65〜85mol%、前記四量体含有量(k=2)が10〜20mol%であり、より高級のオリゴマー状ホスファゼン(k=3、4、5、6及び7)の含有量が5〜15mol%であり、k>=8のホスファゼンオリゴマーの含有量が0〜1mol%である、請求項1〜5のいずれか一項に記載の組成物。
- 成分Dが、0.5〜4.0重量部の量で存在する、請求項1〜6のいずれか一項に記載の組成物。
- 前記芳香族ポリカーボネートの平均分子量(重量平均)が、22,000〜30,000g/モルである、請求項1〜7のいずれか一項に記載の組成物。
- 成分Eとして、難燃性相乗剤、潤滑剤及び離型剤、核形成剤、安定剤、帯電防止剤、着色剤、顔料及び充填剤並びに補強材料を含んでなる群から選択された少なくとも一種の添加剤を含んでなる、請求項1〜8のいずれか一項に記載の組成物。
- 成分Bのグラフトベースが、ジエンゴム、EP(D)Mゴム、アクリレート、ポリウレタン、シリコーン、クロロプレン及びエチレン/酢酸ビニルゴムを含んでなる群から選択される、請求項1〜9のいずれか一項に記載の組成物。
- 請求項1〜10のいずれか一項に記載の組成物の、射出成形又は熱成形された成形製品の製造における使用。
- 請求項1〜10のいずれか一項に記載の組成物から得られる成形製品。
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