JP5977248B2 - ホスホン酸及び精油を用いる、植物製品の収穫前又は収穫後の処理の新規な方法 - Google Patents
ホスホン酸及び精油を用いる、植物製品の収穫前又は収穫後の処理の新規な方法 Download PDFInfo
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- 239000000341 volatile oil Substances 0.000 title claims description 57
- 238000000034 method Methods 0.000 title claims description 41
- 238000011282 treatment Methods 0.000 title claims description 26
- 238000012794 pre-harvesting Methods 0.000 title claims description 6
- 238000003306 harvesting Methods 0.000 title description 13
- 150000003009 phosphonic acids Chemical class 0.000 title description 3
- 239000000203 mixture Substances 0.000 claims description 78
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 37
- 150000003505 terpenes Chemical class 0.000 claims description 30
- 235000007586 terpenes Nutrition 0.000 claims description 30
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 claims description 26
- 239000000126 substance Substances 0.000 claims description 26
- 239000010634 clove oil Substances 0.000 claims description 19
- 241000196324 Embryophyta Species 0.000 claims description 13
- 229960002217 eugenol Drugs 0.000 claims description 13
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 claims description 12
- 239000005770 Eugenol Substances 0.000 claims description 12
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 claims description 12
- 239000002585 base Substances 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 12
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 8
- 239000011591 potassium Substances 0.000 claims description 8
- 229910052700 potassium Inorganic materials 0.000 claims description 8
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims description 6
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 claims description 6
- 239000000787 lecithin Substances 0.000 claims description 6
- 235000010445 lecithin Nutrition 0.000 claims description 6
- 229940067606 lecithin Drugs 0.000 claims description 6
- 239000002420 orchard Substances 0.000 claims description 6
- 239000003549 soybean oil Substances 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 239000003995 emulsifying agent Substances 0.000 claims description 5
- 239000012875 nonionic emulsifier Substances 0.000 claims description 5
- 241000228143 Penicillium Species 0.000 claims description 4
- 241001361634 Rhizoctonia Species 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 150000001340 alkali metals Chemical class 0.000 claims description 4
- 238000011065 in-situ storage Methods 0.000 claims description 4
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- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000005792 Geraniol Substances 0.000 claims description 3
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- 229940113087 geraniol Drugs 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
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- 229940111617 oregano oil Drugs 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- 235000012424 soybean oil Nutrition 0.000 claims description 3
- 239000010678 thyme oil Substances 0.000 claims description 3
- 241000159512 Geotrichum Species 0.000 claims description 2
- 239000005819 Potassium phosphonate Substances 0.000 claims description 2
- 239000005844 Thymol Substances 0.000 claims description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 2
- 125000003277 amino group Chemical group 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- 230000000844 anti-bacterial effect Effects 0.000 claims description 2
- RECUKUPTGUEGMW-UHFFFAOYSA-N carvacrol Chemical compound CC(C)C1=CC=C(C)C(O)=C1 RECUKUPTGUEGMW-UHFFFAOYSA-N 0.000 claims description 2
- 235000007746 carvacrol Nutrition 0.000 claims description 2
- HHTWOMMSBMNRKP-UHFFFAOYSA-N carvacrol Natural products CC(=C)C1=CC=C(C)C(O)=C1 HHTWOMMSBMNRKP-UHFFFAOYSA-N 0.000 claims description 2
- YXXXKCDYKKSZHL-UHFFFAOYSA-M dipotassium;dioxido(oxo)phosphanium Chemical compound [K+].[K+].[O-][P+]([O-])=O YXXXKCDYKKSZHL-UHFFFAOYSA-M 0.000 claims description 2
- 230000000855 fungicidal effect Effects 0.000 claims description 2
- WYXXLXHHWYNKJF-UHFFFAOYSA-N isocarvacrol Natural products CC(C)C1=CC=C(O)C(C)=C1 WYXXLXHHWYNKJF-UHFFFAOYSA-N 0.000 claims description 2
- 229960000790 thymol Drugs 0.000 claims description 2
- -1 Ji Mall Substances 0.000 claims 1
- 241001363490 Monilia Species 0.000 claims 1
- 241000233614 Phytophthora Species 0.000 claims 1
- 241001024317 Sarcops calvus Species 0.000 claims 1
- IIRVGTWONXBBAW-UHFFFAOYSA-M disodium;dioxido(oxo)phosphanium Chemical compound [Na+].[Na+].[O-][P+]([O-])=O IIRVGTWONXBBAW-UHFFFAOYSA-M 0.000 claims 1
- 239000004615 ingredient Substances 0.000 claims 1
- 150000007529 inorganic bases Chemical class 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 150000007530 organic bases Chemical class 0.000 claims 1
- 239000004476 plant protection product Substances 0.000 claims 1
- 238000012251 post-harvest treatment method Methods 0.000 claims 1
- 235000013399 edible fruits Nutrition 0.000 description 16
- 230000000694 effects Effects 0.000 description 15
- 235000012055 fruits and vegetables Nutrition 0.000 description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- OZYJVQJGKRFVHQ-UHFFFAOYSA-L dipotassium trioxidophosphanium Chemical compound [K+].[K+].[O-]P([O-])=O OZYJVQJGKRFVHQ-UHFFFAOYSA-L 0.000 description 8
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 8
- 241000233866 Fungi Species 0.000 description 7
- 239000000243 solution Substances 0.000 description 6
- 235000013311 vegetables Nutrition 0.000 description 6
- 239000004480 active ingredient Substances 0.000 description 4
- 201000010099 disease Diseases 0.000 description 4
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 4
- 210000002615 epidermis Anatomy 0.000 description 4
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- 240000007817 Olea europaea Species 0.000 description 3
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- 230000002195 synergetic effect Effects 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 241001672694 Citrus reticulata Species 0.000 description 2
- BJIOGJUNALELMI-ONEGZZNKSA-N Isoeugenol Natural products COC1=CC(\C=C\C)=CC=C1O BJIOGJUNALELMI-ONEGZZNKSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 235000002725 Olea europaea Nutrition 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- BJIOGJUNALELMI-ARJAWSKDSA-N cis-isoeugenol Chemical compound COC1=CC(\C=C/C)=CC=C1O BJIOGJUNALELMI-ARJAWSKDSA-N 0.000 description 2
- 235000020971 citrus fruits Nutrition 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
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- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 2
- 229920000053 polysorbate 80 Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 2
- BJIOGJUNALELMI-UHFFFAOYSA-N trans-isoeugenol Natural products COC1=CC(C=CC)=CC=C1O BJIOGJUNALELMI-UHFFFAOYSA-N 0.000 description 2
- LDVVMCZRFWMZSG-OLQVQODUSA-N (3ar,7as)-2-(trichloromethylsulfanyl)-3a,4,7,7a-tetrahydroisoindole-1,3-dione Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)Cl)C(=O)[C@H]21 LDVVMCZRFWMZSG-OLQVQODUSA-N 0.000 description 1
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 description 1
- 241000235349 Ascomycota Species 0.000 description 1
- 239000005739 Bordeaux mixture Substances 0.000 description 1
- 241001465180 Botrytis Species 0.000 description 1
- 239000005745 Captan Substances 0.000 description 1
- 239000005973 Carvone Substances 0.000 description 1
- 244000223760 Cinnamomum zeylanicum Species 0.000 description 1
- 241000222199 Colletotrichum Species 0.000 description 1
- 208000034656 Contusions Diseases 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 241000371644 Curvularia ravenelii Species 0.000 description 1
- 206010061818 Disease progression Diseases 0.000 description 1
- 241000221785 Erysiphales Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 206010017533 Fungal infection Diseases 0.000 description 1
- 241000223218 Fusarium Species 0.000 description 1
- 235000006679 Mentha X verticillata Nutrition 0.000 description 1
- 235000002899 Mentha suaveolens Nutrition 0.000 description 1
- 235000001636 Mentha x rotundifolia Nutrition 0.000 description 1
- 208000031888 Mycoses Diseases 0.000 description 1
- 241001028048 Nicola Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000002233 Penicillium roqueforti Nutrition 0.000 description 1
- 241000787934 Phlyctema Species 0.000 description 1
- 231100000674 Phytotoxicity Toxicity 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 241001643641 Xeda Species 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 229940117949 captan Drugs 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 235000017803 cinnamon Nutrition 0.000 description 1
- 239000010630 cinnamon oil Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 1
- 230000005750 disease progression Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 230000009474 immediate action Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 231100000208 phytotoxic Toxicity 0.000 description 1
- 230000000885 phytotoxic effect Effects 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- WKSAUQYGYAYLPV-UHFFFAOYSA-N pyrimethamine Chemical compound CCC1=NC(N)=NC(N)=C1C1=CC=C(Cl)C=C1 WKSAUQYGYAYLPV-UHFFFAOYSA-N 0.000 description 1
- 229960000611 pyrimethamine Drugs 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 210000003491 skin Anatomy 0.000 description 1
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- 239000007921 spray Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
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- 239000000725 suspension Substances 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/26—Phosphorus; Compounds thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N27/00—Biocides, pest repellants or attractants, or plant growth regulators containing hydrocarbons
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N61/00—Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B7/00—Preservation or chemical ripening of fruit or vegetables
- A23B7/14—Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
- A23B7/153—Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of liquids or solids
- A23B7/154—Organic compounds; Microorganisms; Enzymes
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B7/00—Preservation or chemical ripening of fruit or vegetables
- A23B7/14—Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
- A23B7/153—Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of liquids or solids
- A23B7/157—Inorganic compounds
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Microbiology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Biotechnology (AREA)
- Mycology (AREA)
Description
‐ ホスホン酸の少なくとも部分的に塩化した形態、及び
‐ 精油若しくは精油に含まれる1以上のテルペン物質、及び/又はこれらの混合物の常温での適用(塗布)を含む、収穫前又は収穫後の植物製品の処理方法に関する。
HxMyPO3
(ここで、Mは、金属原子、特にアルカリ金属若しくはアルカリ土類金属、又はアンモニウム基、又はアミノ基を表し、
xは、1〜2.8、特に1〜2.5、特に1.3〜1.7であり、
yは、0.2〜2、特に0.5〜2、特に1.3〜1.7であり、
且つ、x+y=3である。)に相当する。
‐ ホスホン酸
‐ 塩基、及び
‐ 精油若しくは精油に含まれる1以上のテルペン物質、及び/又はこれらの混合物
の常温での適用からなる、収穫前又は収穫後の植物製品の処理方法に関する。
‐ ホスホン酸
‐ 塩基、及び
‐ 精油若しくは精油に含まれる1以上のテルペン物質、及び/又はこれらの混合物
の常温での適用を含む、収穫前又は収穫後の植物製品の処理方法に関する。
− 丁子油:20質量%
− 非イオン性乳化剤:18質量%
− 加水分解されたレシチン:27質量%
− 大豆油:35質量%
を含む、Bioxeda(登録商標、Xeda製)組成物に実際に言及され得た。
− 水中で、
− 10質量/容量%と60質量/容量%の間のホスホン酸塩、
− 1質量/容量%と20質量/容量%の間の精油若しくは精油に含まれる1以上のテルペン物質及び/又はこれらの混合物
を含む。
− 10質量/容量%と20質量/容量%の間のホスホン酸、3質量/容量%と10質量/容量%の間の精油若しくは精油に含まれる1以上のテルペン物質及び/又はこれらの混合物、並びに10質量/容量%と20質量/容量%の間の塩基を含む。
− 精油:20質量%
− 非イオン性乳化剤:18質量%
− 加水分解されたレシチン:27質量%
− 大豆油:35質量%
を含む組成物との混合により調製され得る。
常温でのホスホン酸及び精油(又はその活性成分のテルペン)の組み合わせの活性
柑橘類に対する常温でのホスホン酸及び丁子油の組み合わせの活性
コレトトリカム グロエオスポリオイデス(Colletotrichum gloeosporioides)に感染したオリーブの木に対する、常温でのホスホン酸及び丁子油の組み合わせの活性
本発明に係る組成物の調製
Claims (20)
- ‐ ホスホン酸の少なくとも部分的に塩化した形態、及び
‐ 丁子油、タイム油、及びオレガノ油から選択され、テルペン物質としては、オイゲノール、チモール、ゲラニオール、カルバクロールから選択される、精油若しくは精油に含まれる1以上のテルペン物質、及び/又はこれらの混合物
の常温での適用を含む、植物製品の収穫前又は収穫後の処理方法。 - 前記ホスホン酸の塩が一般式:
HxMyPO3
(式中、
Mは、アルカリ金属若しくはアルカリ土類金属等の金属原子、又はアンモニウム基、又はアミノ基を示し、
xは、1と2.8の間であり、
yは0.2と2の間であり、
x+y=3である)
を有する、請求項1に記載の方法。 - 前記塩が、MがカリウムであるH1.5M1.5PO3の一般式を有する、請求項1又は2に記載の方法。
- 前記ホスホン酸の塩が、対応する塩基の存在下で、前もって調製される、又は処理組成物中でその場で形成される、請求項1〜3のいずれか一項に記載の方法。
- 前記精油若しくは精油に含まれる1以上のテルペン物質、及び/又はこれらの混合物が、丁子油若しくはオイゲノール、又はそれらの混合物から選択される、請求項1〜4のいずれか一項に記載の方法。
- ‐ ホスホン酸
‐ 塩基、及び
‐ 前記精油若しくは精油に含まれる1以上のテルペン物質、及び/又はこれらの混合物
の常温での適用を含む、請求項1〜5のいずれか一項に記載の方法。 - 殺真菌処理及び/又は殺細菌処理のための、請求項1〜6のいずれか一項に記載の方法。
- フィトフトラ(Phytophthora)、モニリア(Monilia)、ペニシリウム種(Penicillium sp)、ゲオトリクム種(Geotrichum sp)、リゾクトニア(Rhizoctonia)、ヘルミントスポリウム(Helminthosporium)、又はコレトトリカム(Colletotrichum)の処理
のための、請求項1〜7のいずれか一項に記載の方法。 - スプレーにより行われる、請求項1〜8のいずれか一項に記載の方法。
- 果樹園において行われる、請求項1〜9のいずれか一項に記載の方法。
- 前記精油若しくは精油に含まれる1以上のテルペン物質、及び/又はこれらの混合物の適用のための用量が、300ppmと4500ppmの間であり、ホスホン酸カリウム塩の適用のための用量が、1000ppmと20000ppmの間である、請求項1〜10のいずれか一項に記載の方法。
- 長時間に亘る、同時の、別々の、又は連続した成分の適用を含む、請求項1〜11のいずれか一項に記載の方法。
- 一方で、前記精油若しくは精油に含まれる1以上のテルペン物質、及び/又はこれらの混合物を、他方で、ホスホン酸の塩を含む組成物へ加えることによる、成分の混合物を調製する準備工程をさらに含む、請求項1〜12のいずれか一項に記載の方法。
- 前記ホスホン酸の塩を含む組成物が、750g/Lのセスキホスファイトカリウムの濃縮した水溶液である、請求項13に記載の方法。
- 精油若しくは精油に含まれる1以上のテルペン物質、及び/又はこれらの混合物を含む前記組成物が、
− 丁子油:20質量%
− 非イオン性乳化剤:18質量%
− 加水分解されたレシチン:27質量%
− 大豆油:35質量%
からなる、請求項13又は14に記載の方法。 - 1以上の他の植物衛生上の植物保護製品の適用を含む、請求項1〜15のいずれか一項に記載の方法。
- 少なくとも部分的に塩化した形態のホスホン酸と、丁子油、タイム油、及びオレガノ油から選択される精油若しくはオイゲノール、チモール、ゲラニオール、及びカルバクロールから選択される精油に含まれる1以上のテルペン物質、及び/又はこれらの混合物とを含み、非イオン性乳化剤、レシチン、大豆油、無機塩基、有機塩基、水、1以上の有機溶媒、並びに/又は1以上の乳化剤を含む組成物。
- − 水中で、
− 10質量/容量%と60質量/容量%の間のホスホン酸の塩、
− 1質量/容量%と20質量/容量%の間の前記精油若しくは精油に含まれる1以上のテルペン物質、及び/又はこれらの混合物
を含む、請求項17に記載の組成物。 - pHが5と8の間である、請求項17又は18に記載の組成物。
- 前記ホスホン酸の塩が、MがカリウムであるH1.5M1.5PO3の一般式を有する、請求項17〜19のいずれか一項に記載の組成物。
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ES2498840B1 (es) | 2013-02-20 | 2015-09-04 | Decco Worldwide Post-Harvest Holdings B.V. | Método para el tratamiento y control de enfermedades de postrecolección de frutas y hortalizas y composiciones que comprenden extractos naturales y formulaciones fitofortificantes y/o fungicidas para aplicar en dicho método |
EP3164374A4 (en) | 2014-07-02 | 2017-11-15 | Ralco Nutrition, Inc. | Agricultural compositions and applications utilizing essential oils |
CN105192060B (zh) * | 2015-11-04 | 2018-11-27 | 江苏常丰农化有限公司 | 一种香蕉催熟保鲜剂 |
CN106489939A (zh) * | 2016-08-31 | 2017-03-15 | 浙江新安化工集团股份有限公司 | 一种含有萜烯类化合物的表面活性剂及其用途 |
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RU2667910C1 (ru) * | 2018-06-05 | 2018-09-25 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Российский химико-технологический университет имени Д.И. Менделеева" (РХТУ им. Д.И. Менделеева) | Способ получения 4-аллил-2-метоксифеноксифторциклофосфазенов |
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US11771095B2 (en) | 2020-03-13 | 2023-10-03 | Harpe Bioherbicide Solutions Inc. | Herbicidal Mentha pantsd, extract compositions and methods of using same000000000000000,001 |
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