JP5897141B2 - マスク基材用ヒドロゲル組成物及びそれを用いたヒドロゲルの製造方法 - Google Patents
マスク基材用ヒドロゲル組成物及びそれを用いたヒドロゲルの製造方法 Download PDFInfo
- Publication number
- JP5897141B2 JP5897141B2 JP2014534460A JP2014534460A JP5897141B2 JP 5897141 B2 JP5897141 B2 JP 5897141B2 JP 2014534460 A JP2014534460 A JP 2014534460A JP 2014534460 A JP2014534460 A JP 2014534460A JP 5897141 B2 JP5897141 B2 JP 5897141B2
- Authority
- JP
- Japan
- Prior art keywords
- hydrogel
- acrylate
- styrene copolymer
- styrene
- mass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000017 hydrogel Substances 0.000 title claims description 122
- 239000000203 mixture Substances 0.000 title claims description 43
- 239000000758 substrate Substances 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 48
- 229920001577 copolymer Polymers 0.000 claims description 35
- 229920006037 cross link polymer Polymers 0.000 claims description 27
- 239000002537 cosmetic Substances 0.000 claims description 25
- 239000000499 gel Substances 0.000 claims description 25
- 239000003814 drug Substances 0.000 claims description 24
- 229940079593 drug Drugs 0.000 claims description 23
- 229920000642 polymer Polymers 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 239000003431 cross linking reagent Substances 0.000 claims description 17
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 16
- 239000008213 purified water Substances 0.000 claims description 16
- 150000005846 sugar alcohols Polymers 0.000 claims description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 13
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 12
- 239000007864 aqueous solution Substances 0.000 claims description 10
- 230000006835 compression Effects 0.000 claims description 10
- 238000007906 compression Methods 0.000 claims description 10
- 229940048053 acrylate Drugs 0.000 claims description 9
- 235000010418 carrageenan Nutrition 0.000 claims description 9
- 239000000679 carrageenan Substances 0.000 claims description 9
- 229920001525 carrageenan Polymers 0.000 claims description 9
- 229940113118 carrageenan Drugs 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims description 9
- 229920001285 xanthan gum Polymers 0.000 claims description 7
- 239000000230 xanthan gum Substances 0.000 claims description 7
- 235000010493 xanthan gum Nutrition 0.000 claims description 7
- 229940082509 xanthan gum Drugs 0.000 claims description 7
- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 claims description 6
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical group CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 6
- 229920002581 Glucomannan Polymers 0.000 claims description 6
- 229920000161 Locust bean gum Polymers 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 229940046240 glucomannan Drugs 0.000 claims description 6
- 235000011187 glycerol Nutrition 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 235000010420 locust bean gum Nutrition 0.000 claims description 6
- 239000000711 locust bean gum Substances 0.000 claims description 6
- 229940047670 sodium acrylate Drugs 0.000 claims description 6
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims description 5
- VAPQAGMSICPBKJ-UHFFFAOYSA-N 2-nitroacridine Chemical compound C1=CC=CC2=CC3=CC([N+](=O)[O-])=CC=C3N=C21 VAPQAGMSICPBKJ-UHFFFAOYSA-N 0.000 claims description 5
- 102100026735 Coagulation factor VIII Human genes 0.000 claims description 5
- 101000911390 Homo sapiens Coagulation factor VIII Proteins 0.000 claims description 5
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 5
- 235000010443 alginic acid Nutrition 0.000 claims description 5
- 229920000615 alginic acid Polymers 0.000 claims description 5
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims description 5
- OMDQUFIYNPYJFM-XKDAHURESA-N (2r,3r,4s,5r,6s)-2-(hydroxymethyl)-6-[[(2r,3s,4r,5s,6r)-4,5,6-trihydroxy-3-[(2s,3s,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 claims description 4
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims description 4
- 229920001817 Agar Polymers 0.000 claims description 4
- 229920000926 Galactomannan Polymers 0.000 claims description 4
- 229920002148 Gellan gum Polymers 0.000 claims description 4
- 229920002907 Guar gum Polymers 0.000 claims description 4
- 239000008272 agar Substances 0.000 claims description 4
- 235000010419 agar Nutrition 0.000 claims description 4
- WPKYZIPODULRBM-UHFFFAOYSA-N azane;prop-2-enoic acid Chemical compound N.OC(=O)C=C WPKYZIPODULRBM-UHFFFAOYSA-N 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 239000000665 guar gum Substances 0.000 claims description 4
- 235000010417 guar gum Nutrition 0.000 claims description 4
- 229960002154 guar gum Drugs 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 229920001983 poloxamer Polymers 0.000 claims description 4
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 claims description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 2
- SSZWWUDQMAHNAQ-UHFFFAOYSA-N 3-chloropropane-1,2-diol Chemical compound OCC(O)CCl SSZWWUDQMAHNAQ-UHFFFAOYSA-N 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 2
- 229920000166 polytrimethylene carbonate Polymers 0.000 claims description 2
- 235000013772 propylene glycol Nutrition 0.000 claims description 2
- DYPJJAAKPQKWTM-UHFFFAOYSA-N 2-chloropropane-1,3-diol Chemical compound OCC(Cl)CO DYPJJAAKPQKWTM-UHFFFAOYSA-N 0.000 claims 1
- 238000000465 moulding Methods 0.000 claims 1
- 238000000746 purification Methods 0.000 claims 1
- 239000004745 nonwoven fabric Substances 0.000 description 13
- 239000010408 film Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 6
- 239000013538 functional additive Substances 0.000 description 4
- 229920006249 styrenic copolymer Polymers 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- 238000002835 absorbance Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000005243 fluidization Methods 0.000 description 3
- -1 lysinyl urea Chemical compound 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 2
- 230000003796 beauty Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 235000015097 nutrients Nutrition 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- FPIPGXGPPPQFEQ-UHFFFAOYSA-N 13-cis retinol Natural products OCC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- VLRGXXKFHVJQOL-UHFFFAOYSA-N 3-chloropentane-2,4-dione Chemical compound CC(=O)C(Cl)C(C)=O VLRGXXKFHVJQOL-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 206010003645 Atopy Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229940061720 alpha hydroxy acid Drugs 0.000 description 1
- 150000001280 alpha hydroxy acids Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 210000005260 human cell Anatomy 0.000 description 1
- 229920001477 hydrophilic polymer Polymers 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- BEJNERDRQOWKJM-UHFFFAOYSA-N kojic acid Chemical compound OCC1=CC(=O)C(O)=CO1 BEJNERDRQOWKJM-UHFFFAOYSA-N 0.000 description 1
- 229960004705 kojic acid Drugs 0.000 description 1
- WZNJWVWKTVETCG-UHFFFAOYSA-N kojic acid Natural products OC(=O)C(N)CN1C=CC(=O)C(O)=C1 WZNJWVWKTVETCG-UHFFFAOYSA-N 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000008177 pharmaceutical agent Substances 0.000 description 1
- 239000008055 phosphate buffer solution Substances 0.000 description 1
- ZUBIJGNKOJGGCI-UHFFFAOYSA-M potassium;prop-2-enoate Chemical class [K+].[O-]C(=O)C=C ZUBIJGNKOJGGCI-UHFFFAOYSA-M 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 description 1
- 229960003415 propylparaben Drugs 0.000 description 1
- 229960003471 retinol Drugs 0.000 description 1
- 235000020944 retinol Nutrition 0.000 description 1
- 239000011607 retinol Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical class [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L39/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions of derivatives of such polymers
- C08L39/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
- C08L39/06—Homopolymers or copolymers of N-vinyl-pyrrolidones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0212—Face masks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/042—Gels
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/733—Alginic acid; Salts thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- A61K8/8117—Homopolymers or copolymers of aromatic olefines, e.g. polystyrene; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
- C08J3/075—Macromolecular gels
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/246—Intercrosslinking of at least two polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L5/00—Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/24—Thermal properties
- A61K2800/244—Endothermic; Cooling; Cooling sensation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2305/00—Characterised by the use of polysaccharides or of their derivatives not provided for in groups C08J2301/00 or C08J2303/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
- C08J2325/08—Copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
- C08J2325/08—Copolymers of styrene
- C08J2325/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2333/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2339/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Derivatives of such polymers
- C08J2339/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
- C08J2339/06—Homopolymers or copolymers of N-vinyl-pyrrolidones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/54—Aqueous solutions or dispersions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
Description
の基材がなくてもヒドロゲル自体を基材として使用することができる。
lymer)、スチレン/VP共重合体(Styrene/VP Copolymer)及びスチレン/アクリレート共重合体(Styrene/Acrylates Copolymer)からなる群より選ばれる1種または2種以上が挙げられる。
ングしたヒドロゲル組成物層を室温で冷却してヒドロゲルを製造する段階(S140)と、上記冷却したヒドロゲルを熱処理する段階(S150)とを含む方法で製造される。また、該方法はS150段階の後に、上記熱処理したヒドロゲルを所望の形状に成形する段階(S160)と、上記成形したヒドロゲルを美容剤または薬剤に浸漬させる段階(S170)とをさらに含む。その上、上記S110段階に機能添加剤をさらに添加してもよい。
アクリル系架橋重合体としてナトリウムアクリレート/C10−30アルキルアクリレートクロスポリマー2質量%、及びスチレン系共重合体としてスチレン/VP共重合体3質量を精製水72質量%に添加した後、60℃で撹拌した。別途に多価アルコールとしてグリセリン20質量%に、ゲル化高分子としてカラギーナン2質量%、キサンタンガム0.5質量%、ローカストビーンガム0.5質量%を混合してから、これを上記水溶液中に添加し、70℃で2時間撹拌してヒドロゲル組成物を製造した。
アクリル系架橋重合体としてカリウムアクリレート/C10−30アルキルアクリレートクロスポリマー3質量%、及びスチレン系共重合体としてスチレン/アクリレート共重合体4質量%、精製水70.2質量%、グリセリン20質量%、ゲル化高分子としてカラギーナン1.8質量%、グルコマンナン1.0質量%を使用したことを除き、上記実施例1と同様に実施してヒドロゲルを製造した。
架橋剤としてスチレン系共重合体であるブチレン/エチレン/スチレン共重合体6質量%、多価アルコール17質量%、精製水74.7質量%、ゲル化高分子としてカラギーナン1.0質量%、キサンタンガム0.8質量%、及びグルコマンナン0.5質量%を使用したことを除き、上記実施例1と同様に実施してヒドロゲルを製造した。
架橋剤としてアクリル系架橋重合体であるナトリウムアクリレート/C10−30アルキルアクリレートクロスポリマー5質量%、精製水71.4質量%、グリセリン20質量%、ゲル化高分子としてカラギーナン2.3質量%、アルギン0.5質量%及びローカストビンゴム0.8質量%を使用したことを除き、上記実施例1と同様に実施してヒドロゲルを製造した。
アクリル系架橋重合体とスチレン系架橋重合体を用いずに、多価アルコールとしてグリセリン20質量%、ゲル化高分子としてカラギーナン2質量%、キサンタンガム0.5質量%及びローカストビーンガム0.5質量%を精製水77質量%に分散させたことを除き、上記実施例1と同様に実施してヒドロゲルを製造した。
上記実施例及び比較例により製造されたヒドロゲルに、液状の美容剤を含浸させて物性を測定し、その結果を表1に示した。
◎:性状維持
○:全面積のうち10%未満でゲルが分解(流動化)した
□:全面積のうち30%未満でゲルが分解(流動化)した
△:全面積のうち50%未満でゲルが分解(流動化)した
X:全面積のうち70%未満でゲルが分解(流動化)した
Claims (5)
- 架橋剤0.1乃至10質量%、ゲル化高分子0.2乃至6質量%、多価アルコール0.5乃至20質量%及び精製水70乃至90質量%を含み、
前記架橋剤は、アクリル系架橋重合体とスチレン系共重合体とが2:8乃至8:2の質量比で混合された混合物であり、
前記アクリル系架橋重合体は、ナトリウムアクリレート/C10−30アルキルアクリレートクロスポリマーまたはカリウムアクリレート/C10−30アルキルアクリレートクロスポリマーであり、
前記スチレン系共重合体は、アクリレート/エチルヘキシルアクリレート/HEMA/スチレン共重合体、ブチレン/エチレン/スチレン共重合体、アンモニウムアクリレート/メチルスチレン/スチレン共重合体、スチレン/VP共重合体及びスチレン/アクリレート共重合体からなる群より選ばれる1種以上であり、
前記ゲル化高分子は、ガラクトマンナン、グルコマンナン、グアーガム、ローカストビーンガム、プルロニック、寒天、アルギン、カラギーナン、キサンタンガム及びジェランからなる群より選ばれる1種以上であることを特徴とする、マスク基材用ヒドロゲル組成物。 - 前記多価アルコールは、1,2−エタンジオール、1,2−プロパンジオール、1,3−プロパンジオール、3−クロロ−1,2−プロパンジオール、2−クロロ−1,3−プロパンジオール、及びグリセリンからなる群より選ばれる1種以上であることを特徴とする、請求項1に記載のマスク基材用ヒドロゲル組成物。
- 室温で精製水に架橋剤を添加した後、40乃至85℃の温度で撹拌して水溶液を製造する段階と、
室温で多価アルコールにゲル化高分子を溶解させた後、前記水溶液に添加して40乃至80℃で撹拌することで、ヒドロゲル組成物を製造する段階と、
前記ヒドロゲル組成物を0.5乃至2mmの厚さに圧縮コーティングする段階と、
前記圧縮コーティングしたヒドロゲル組成物層を室温で冷却して、ヒドロゲルを製造する段階と、
前記冷却したヒドロゲルを40乃至85℃の温度で、12時間乃至36時間熱処理する段階とを含み、
前記架橋剤は、アクリル系架橋重合体とスチレン系共重合体とが2:8乃至8:2の質量比で混合された混合物であり、
前記アクリル系架橋重合体は、ナトリウムアクリレート/C10−30アルキルアクリレートクロスポリマーまたはカリウムアクリレート/C10−30アルキルアクリレートクロスポリマーであり、
前記スチレン系共重合体は、アクリレート/エチルヘキシルアクリレート/HEMA/スチレン共重合体、ブチレン/エチレン/スチレン共重合体、アンモニウムアクリレート/メチルスチレン/スチレン共重合体、スチレン/VP共重合体及びスチレン/アクリレート共重合体からなる群より選ばれる1種以上であり、
前記ゲル化高分子は、ガラクトマンナン、グルコマンナン、グアーガム、ローカストビーンガム、プルロニック、寒天、アルギン、カラギーナン、キサンタンガム及びジェランからなる群より選ばれる1種以上であることを特徴とする、マスク基材用ヒドロゲルの製造方法。 - 前記熱処理したヒドロゲルを所望の形状に成形する段階と、前記成形したヒドロゲルを美容剤または薬剤に浸漬させる段階とをさらに含むことを特徴とする、請求項3に記載のマスク基材用ヒドロゲルの製造方法。
- 前記冷却したヒドロゲルの強度は、1.5乃至7.0kg/cm2であることを特徴とする、請求項3に記載のマスク基材用ヒドロゲルの製造方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-2011-0100690 | 2011-10-04 | ||
KR1020110100690A KR101367105B1 (ko) | 2011-10-04 | 2011-10-04 | 마스크 기재용 하이드로겔 조성물 및 이를 이용한 하이드로겔의 제조방법 |
PCT/KR2012/007312 WO2013051795A1 (ko) | 2011-10-04 | 2012-09-12 | 마스크 기재용 하이드로겔 조성물 및 이를 이용한 하이드로겔의 제조방법 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2014528443A JP2014528443A (ja) | 2014-10-27 |
JP5897141B2 true JP5897141B2 (ja) | 2016-03-30 |
Family
ID=48043932
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014534460A Active JP5897141B2 (ja) | 2011-10-04 | 2012-09-12 | マスク基材用ヒドロゲル組成物及びそれを用いたヒドロゲルの製造方法 |
Country Status (6)
Country | Link |
---|---|
US (1) | US10011712B2 (ja) |
EP (1) | EP2765160B1 (ja) |
JP (1) | JP5897141B2 (ja) |
KR (1) | KR101367105B1 (ja) |
CN (1) | CN103857744B (ja) |
WO (1) | WO2013051795A1 (ja) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103520070B (zh) * | 2013-10-08 | 2015-10-21 | 天津工业大学 | 一种高弹性无支撑环保型凝胶面膜及其制备方法 |
CN104173264B (zh) * | 2014-07-19 | 2017-04-12 | 云南荣之健生物科技有限公司 | 玫瑰精油水凝胶贴及其制作方法 |
GB2535562B8 (en) * | 2014-09-30 | 2017-07-19 | Chongqing Mj Medical Devices Co Ltd | Hydrogel compositions and their use in the treatment of symptoms induced by hypertrophic scars |
KR101730129B1 (ko) | 2014-12-31 | 2017-05-12 | 주식회사 필켐 | 주입 성형이 가능한 겔화 지연형 하이드로겔 조성물 및 이의 제조방법 |
EP3328354B1 (en) | 2015-07-28 | 2023-06-28 | Mary Kay, Inc. | Topical skin formulations |
US10617608B2 (en) | 2015-09-25 | 2020-04-14 | Lotte Fine Chemical Co., Ltd. | Composition for hydrogel sheet, hydrogel sheet manufactured therefrom, and method for manufacturing same |
KR20180032752A (ko) | 2016-09-22 | 2018-04-02 | 롯데정밀화학 주식회사 | 하이드로겔 시트용 조성물, 이로부터 제조되는 하이드로겔 시트 및 이의 제조 방법 |
KR102435660B1 (ko) * | 2015-11-06 | 2022-08-24 | 롯데정밀화학 주식회사 | 건조 하이드로겔 시트의 제조방법 및 그 제조방법에 의해 제조된 건조 하이드로겔 시트 |
CN105232354B (zh) * | 2015-11-12 | 2018-01-16 | 广州沁瀚生物科技有限公司 | 生物透气美容用面膜及其制备方法 |
KR101709290B1 (ko) * | 2016-03-25 | 2017-02-23 | 주식회사 한웅메디칼 | 하이드로겔 조성물 및 그것으로 이루어진 하이드로겔층을 포함하는 하이드로겔 시트 제품 |
CN105769748A (zh) * | 2016-04-19 | 2016-07-20 | 桂林理工大学 | 一种木薯淀粉水凝胶地皮菜提取物面膜基质及其制备方法 |
CN105816335A (zh) * | 2016-04-29 | 2016-08-03 | 诺斯贝尔化妆品股份有限公司 | 一种含有多种天然亲水性凝胶的面膜布 |
KR20180060173A (ko) * | 2016-11-28 | 2018-06-07 | 롯데정밀화학 주식회사 | 다공성 하이드로겔 시트의 제조방법 및 그 제조방법에 의해 제조된 다공성 하이드로겔 시트 |
CN108210344A (zh) * | 2016-12-21 | 2018-06-29 | 常州柚盾实业投资有限公司 | 一种改性膜布及其制备方法 |
JP7311094B2 (ja) * | 2019-02-12 | 2023-07-19 | 株式会社みやびコスメティックス | ゲル状組成物を浸漬するための液剤 |
FR3096581B1 (fr) * | 2019-05-31 | 2021-10-22 | Chanel Parfums Beaute | Gel aqueux solide comprenant un mélange de gomme de xanthane et de gomme de carroube |
KR102398721B1 (ko) * | 2020-05-19 | 2022-05-17 | 코스맥스아이큐어 주식회사 | 식물성 추출물을 담지하는 하이드로겔 플레이크, 이를 이용한 하이드로겔 마스크 팩, 및 이의 제조 방법 |
EP4023205A4 (en) * | 2020-11-19 | 2022-09-14 | Jincostech Co., Ltd. | HYDROGEL PATCH WITH ADDITIVE SOLUTION ADAPTABLE TO THE SYNERESE PATTERN AND METHOD FOR MAKING THE COMPOSITION |
KR102256234B1 (ko) * | 2020-11-19 | 2021-05-26 | (주)진코스텍 | 이수패턴 조절 충전액을 포함하는 하이드로겔 패치 및 그 제조방법 |
EP4346745A1 (de) * | 2021-05-25 | 2024-04-10 | Beiersdorf AG | Hydrogele mit biopolymeren |
Family Cites Families (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5492618A (en) * | 1977-12-30 | 1979-07-23 | Japan Synthetic Rubber Co Ltd | Poultice |
US4965071A (en) * | 1988-10-19 | 1990-10-23 | The Gillette Company | Wrinkle masking composition of sodium polystyrene sulfonate and process for use |
EP0850043B1 (en) * | 1995-08-31 | 2002-01-30 | The Procter & Gamble Company | Skin conditioning composition containing silicone gum, mixture of polyoxyethylenes and glycerol compound |
JP2000514052A (ja) * | 1996-07-01 | 2000-10-24 | ハンス・シュヴァルツコプフ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング・ウント・コンパニー・コマンディットゲゼルシャフト | ケラチン繊維を処理するためのヒドロゲル形成剤および配合物の使用 |
JPH10338619A (ja) * | 1997-06-06 | 1998-12-22 | Pola Chem Ind Inc | 透明化粧料 |
JP4787386B2 (ja) * | 1998-05-08 | 2011-10-05 | 花王株式会社 | 粘土鉱物入りシート状化粧料およびその製造方法 |
WO2001095889A1 (fr) | 2000-06-13 | 2001-12-20 | Hisamitsu Pharmaceutical Co., Inc. | Platre |
JP4190303B2 (ja) * | 2002-02-18 | 2008-12-03 | 日本精化株式会社 | カチオン性共重合体 |
FR2832061B1 (fr) * | 2002-04-15 | 2004-05-28 | Oreal | Hydrogel sur support comme produit apres-rasage |
AU2003276707A1 (en) * | 2002-10-30 | 2004-05-25 | Showa Denko K.K. | Adhesive composition for dermal patch and production process thereof |
JP3905457B2 (ja) * | 2002-10-31 | 2007-04-18 | 花王株式会社 | 化粧料及びその使用方法 |
DE10260873A1 (de) | 2002-12-23 | 2004-07-15 | Beiersdorf Ag | Selbstklebende Polymermatrix mit einem Gehalt an Meeresalgenextrakt und Glycerin |
DE10260872B4 (de) * | 2002-12-23 | 2013-09-26 | Beiersdorf Ag | Verwendung von gelbildendem Polymer, Wasser, Alkohol und Meeresalgenextrakt zur Einstellung von Elastizität und Haftvermögen selbstklebender kosmetischer Polymermatrices |
US7993654B2 (en) | 2002-12-23 | 2011-08-09 | Beiersdorf Ag | Self-adhesive polymer matrix containing sea algae extract |
JP4519408B2 (ja) * | 2003-01-30 | 2010-08-04 | ライオン株式会社 | 貼付剤組成及びその製造方法 |
JP2005008613A (ja) * | 2003-05-28 | 2005-01-13 | Kanae Technos:Kk | パック用ゲルシート |
KR100506543B1 (ko) | 2003-08-14 | 2005-08-05 | 주식회사 제닉 | 온도 감응성 상태변화 하이드로겔 조성물 및 그 제조방법 |
EP1773287A1 (en) * | 2004-07-23 | 2007-04-18 | The Procter and Gamble Company | Substrate based skin care device |
JP2006089459A (ja) * | 2004-08-24 | 2006-04-06 | Kao Corp | シート状組成物 |
DE102005032237A1 (de) * | 2005-07-07 | 2007-01-11 | Beiersdorf Ag | Emulgatorkombination für Kosmetika |
CN100389145C (zh) * | 2006-09-29 | 2008-05-21 | 北京大学 | 含天然高分子的水凝胶及其辐射制备方法 |
KR100841742B1 (ko) * | 2006-12-14 | 2008-06-27 | 화인코주식회사 | 하이드로겔 마스크 팩, 이의 제조 방법 및 이의 제조에이용되는 조성물 |
KR100937625B1 (ko) * | 2007-08-10 | 2010-01-20 | 주식회사 제닉 | 가용성 웹 공극필름 및 이의 제조방법 |
DE102007039229A1 (de) | 2007-08-20 | 2009-02-26 | Ics Innovative Care Systems Andernach Gmbh | Wasser- und wirkstoffhaltiges Gel |
KR101468579B1 (ko) * | 2008-03-24 | 2014-12-03 | 아이큐어 주식회사 | 약물 또는 활성물질의 안정성을 향상시키는 속용성 필름조성물, 속용성 필름 제제 및 이를 이용한이온영동패취세트 |
JP4993508B2 (ja) | 2008-07-16 | 2012-08-08 | 信越化学工業株式会社 | 皮膜形成性重合体を含む化粧料 |
JP5398062B2 (ja) * | 2009-03-16 | 2014-01-29 | 積水化成品工業株式会社 | ハイドロゲル外用剤 |
WO2010143196A1 (en) * | 2009-04-03 | 2010-12-16 | Cavinkare Pvt Ltd. | Novel synergistic transparent / translucent hydrogel composition; method of preparing it and a sheet / film made thereform |
KR101179654B1 (ko) * | 2009-07-20 | 2012-09-04 | 주식회사 인섹트 바이오텍 | 아라자임을 함유한 하이드로젤을 이용한 스킨케어 마스크 |
JP5511319B2 (ja) * | 2009-11-10 | 2014-06-04 | 三栄源エフ・エフ・アイ株式会社 | 乾燥ゲルシートおよびその利用 |
KR101207403B1 (ko) | 2011-01-28 | 2012-12-04 | 한국생산기술연구원 | 수계 액정성 고분자를 이용한 실버 나노와이어 잉크 및 이의 제조방법 |
-
2011
- 2011-10-04 KR KR1020110100690A patent/KR101367105B1/ko active IP Right Grant
-
2012
- 2012-09-12 EP EP12837935.1A patent/EP2765160B1/en active Active
- 2012-09-12 WO PCT/KR2012/007312 patent/WO2013051795A1/ko active Application Filing
- 2012-09-12 CN CN201280048942.6A patent/CN103857744B/zh active Active
- 2012-09-12 JP JP2014534460A patent/JP5897141B2/ja active Active
- 2012-09-12 US US14/349,202 patent/US10011712B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
US20140239536A1 (en) | 2014-08-28 |
CN103857744A (zh) | 2014-06-11 |
EP2765160B1 (en) | 2019-11-13 |
JP2014528443A (ja) | 2014-10-27 |
CN103857744B (zh) | 2017-11-10 |
US10011712B2 (en) | 2018-07-03 |
EP2765160A1 (en) | 2014-08-13 |
KR101367105B1 (ko) | 2014-02-26 |
KR20130036543A (ko) | 2013-04-12 |
WO2013051795A1 (ko) | 2013-04-11 |
EP2765160A4 (en) | 2015-06-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5897141B2 (ja) | マスク基材用ヒドロゲル組成物及びそれを用いたヒドロゲルの製造方法 | |
AU765572B2 (en) | Process for coating a perforated substrate | |
KR101507301B1 (ko) | 점착성 하이드로겔 조성물 및 이를 이용한 점착성 하이드로겔 시트의 제조방법 | |
EP3481443B1 (en) | A medical dressing comprising a carrier and a composite material | |
CN105153359A (zh) | 一种导电水凝胶和导电水凝胶卷材及其制备方法 | |
EP1100555A1 (en) | Bioadhesive compositions and wound dressings containing them | |
JPH10513123A (ja) | 超吸収体を有する基材、その製造方法およびその使用 | |
CN102940583A (zh) | 一种可作为营养面膜的温敏水凝胶及其制备方法 | |
KR101678656B1 (ko) | 기능성이 강화된 하이드로겔 마스크팩의 제조방법 | |
KR20170053515A (ko) | 건조 하이드로겔 시트의 제조방법 및 그 제조방법에 의해 제조된 건조 하이드로겔 시트 | |
KR101782470B1 (ko) | 하이드로겔이 코팅된 미용팩용 베이스 시트 및 이의 제조 방법 | |
WO2019172509A1 (ko) | 하이드로겔의 제조방법 | |
KR20160146259A (ko) | 바이오 셀룰로오스를 포함하는 하이드로겔의 제조방법 | |
CN105504328B (zh) | 一种室温下一步涂覆改善壳聚糖膜血液相容性的方法 | |
CN112250901B (zh) | 一种多功能互穿网络聚合物乳液在聚氨酯软泡塑料改性中的应用 | |
CN111803387B (zh) | 一种缓释保湿气凝胶面膜基质及其制备方法和应用 | |
KR102272285B1 (ko) | 수용성 부직포를 기초로 한 피부 부착용 박막 패치 | |
TW202210044A (zh) | 一種具梯度濃度結構之材料的配方、結構及其應用 | |
JP2017506532A (ja) | 隔離された酸素触媒を有する多層構造体 | |
KR101903036B1 (ko) | 미용팩용 부직포 구조체 및 그 제조방법 | |
JPH03223213A (ja) | アルギン酸塩含水ゲルシートの製造方法 | |
KR102572532B1 (ko) | 하이드로콜로이드 마스크팩 및 그 제조방법 | |
TW201713315A (zh) | 含聚苯乙烯乳膠顆粒及溫度感應型材料之緩釋型奈米纖維貼布及其製備方法 | |
CN113559308A (zh) | 一种硅酮凝胶敷料及其制备方法 | |
JP2004010524A (ja) | 薬品保持材及び患部治療材 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20150604 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20150610 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150910 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20160217 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20160301 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5897141 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |