JP5889417B2 - 金属担体触媒からの貴金属回収方法 - Google Patents
金属担体触媒からの貴金属回収方法 Download PDFInfo
- Publication number
- JP5889417B2 JP5889417B2 JP2014534111A JP2014534111A JP5889417B2 JP 5889417 B2 JP5889417 B2 JP 5889417B2 JP 2014534111 A JP2014534111 A JP 2014534111A JP 2014534111 A JP2014534111 A JP 2014534111A JP 5889417 B2 JP5889417 B2 JP 5889417B2
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- JP
- Japan
- Prior art keywords
- metal
- catalyst
- solution
- heating
- nitric acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003054 catalyst Substances 0.000 title claims description 54
- 229910000510 noble metal Inorganic materials 0.000 title claims description 36
- 238000000034 method Methods 0.000 title claims description 32
- 239000000243 solution Substances 0.000 claims description 55
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 32
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 28
- 229910017604 nitric acid Inorganic materials 0.000 claims description 27
- 238000010438 heat treatment Methods 0.000 claims description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 238000005406 washing Methods 0.000 claims description 9
- 239000007864 aqueous solution Substances 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 28
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 25
- 239000000758 substrate Substances 0.000 description 16
- 239000002253 acid Substances 0.000 description 15
- 229910052751 metal Inorganic materials 0.000 description 15
- 239000002184 metal Substances 0.000 description 15
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 14
- 239000010410 layer Substances 0.000 description 13
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 12
- 239000010970 precious metal Substances 0.000 description 11
- 238000011084 recovery Methods 0.000 description 9
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 9
- 238000010306 acid treatment Methods 0.000 description 8
- 238000004090 dissolution Methods 0.000 description 8
- 229910052697 platinum Inorganic materials 0.000 description 7
- 229910052763 palladium Inorganic materials 0.000 description 6
- 229910052703 rhodium Inorganic materials 0.000 description 6
- 239000010948 rhodium Substances 0.000 description 6
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 6
- 238000007796 conventional method Methods 0.000 description 5
- 238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 5
- 230000001681 protective effect Effects 0.000 description 5
- 229910052714 tellurium Inorganic materials 0.000 description 5
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 4
- 238000000975 co-precipitation Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 239000002585 base Substances 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 238000005485 electric heating Methods 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000009616 inductively coupled plasma Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000011002 quantification Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000012898 sample dilution Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000001119 stannous chloride Substances 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000000967 suction filtration Methods 0.000 description 1
- 238000009210 therapy by ultrasound Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/009—General processes for recovering metals or metallic compounds from spent catalysts
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/04—Obtaining noble metals by wet processes
- C22B11/042—Recovery of noble metals from waste materials
- C22B11/048—Recovery of noble metals from waste materials from spent catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/JP2012/072793 WO2014038048A1 (ja) | 2012-09-06 | 2012-09-06 | 金属担体触媒からの貴金属回収方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP5889417B2 true JP5889417B2 (ja) | 2016-03-22 |
JPWO2014038048A1 JPWO2014038048A1 (ja) | 2016-08-08 |
Family
ID=50236697
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014534111A Expired - Fee Related JP5889417B2 (ja) | 2012-09-06 | 2012-09-06 | 金属担体触媒からの貴金属回収方法 |
Country Status (5)
Country | Link |
---|---|
US (1) | US20150218671A1 (zh) |
JP (1) | JP5889417B2 (zh) |
CN (1) | CN104603305A (zh) |
CA (1) | CA2884227A1 (zh) |
WO (1) | WO2014038048A1 (zh) |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03154640A (ja) * | 1989-11-13 | 1991-07-02 | Nissan Motor Co Ltd | メタル触媒からの貴金属回収方法 |
JPH0834619A (ja) * | 1994-07-25 | 1996-02-06 | Cataler Kogyo Kk | メタル担体触媒からの貴金属回収方法 |
WO2005087375A1 (ja) * | 2004-03-15 | 2005-09-22 | Ishifuku Metal Industry Co., Ltd. | 金属担体触媒装置からの貴金属回収方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2863762A (en) * | 1956-12-28 | 1958-12-09 | Universal Oil Prod Co | Recovery of noble metals |
JP4347783B2 (ja) * | 2004-11-04 | 2009-10-21 | 日鉱金属株式会社 | 廃触媒からの白金及びレニウムの回収方法 |
CN100567528C (zh) * | 2006-11-17 | 2009-12-09 | 南化集团研究院 | 一种从废钯碳催化剂中回收贵金属钯的方法 |
BE1017974A3 (fr) * | 2008-01-30 | 2010-02-02 | Variabel Daniel | Procede de valorisation d'elements de supports catalytiques usagers et/ou defectueux |
TWI357930B (en) * | 2008-03-07 | 2012-02-11 | Ind Tech Res Inst | Method for recovery of noble metals |
-
2012
- 2012-09-06 CN CN201280075627.2A patent/CN104603305A/zh active Pending
- 2012-09-06 WO PCT/JP2012/072793 patent/WO2014038048A1/ja active Application Filing
- 2012-09-06 JP JP2014534111A patent/JP5889417B2/ja not_active Expired - Fee Related
- 2012-09-06 US US14/425,579 patent/US20150218671A1/en not_active Abandoned
- 2012-09-06 CA CA2884227A patent/CA2884227A1/en not_active Abandoned
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03154640A (ja) * | 1989-11-13 | 1991-07-02 | Nissan Motor Co Ltd | メタル触媒からの貴金属回収方法 |
JPH0834619A (ja) * | 1994-07-25 | 1996-02-06 | Cataler Kogyo Kk | メタル担体触媒からの貴金属回収方法 |
WO2005087375A1 (ja) * | 2004-03-15 | 2005-09-22 | Ishifuku Metal Industry Co., Ltd. | 金属担体触媒装置からの貴金属回収方法 |
Also Published As
Publication number | Publication date |
---|---|
JPWO2014038048A1 (ja) | 2016-08-08 |
WO2014038048A1 (ja) | 2014-03-13 |
US20150218671A1 (en) | 2015-08-06 |
CA2884227A1 (en) | 2014-03-13 |
CN104603305A (zh) | 2015-05-06 |
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