JP5876744B2 - 泡吐出容器用身体洗浄剤 - Google Patents
泡吐出容器用身体洗浄剤 Download PDFInfo
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- JP5876744B2 JP5876744B2 JP2012032641A JP2012032641A JP5876744B2 JP 5876744 B2 JP5876744 B2 JP 5876744B2 JP 2012032641 A JP2012032641 A JP 2012032641A JP 2012032641 A JP2012032641 A JP 2012032641A JP 5876744 B2 JP5876744 B2 JP 5876744B2
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- Prior art keywords
- foam
- acid
- cleaning agent
- foam discharge
- pump
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Description
(1)(A)次の一般式(I)で示されるN−アシルアスパラギン酸又はその塩
(B)次の一般式(II)で示されるN−アシル−L−グルタミン酸又はその塩
(C)次の一般式(III)で示されるアルキルジメチルアミノ酢酸ベタイン
(D)次の一般式(IV)で示されるポリオキシエチレンアルキルエーテル硫酸塩、
以上を必須成分として含有することを特徴とする泡吐出容器用身体洗浄剤。
従来の身体洗浄剤では泡の持続性(スタミナ)が十分でなかったために、身体洗浄の途中で泡の量が少なくなったり、泡が消えてしまってその泡を手に取って身体を広く洗うことが困難であった。しかし、本発明の泡吐出容器用の身体洗浄剤で得られる泡は、きめ細かいクリーミイな泡であって、泡の持続性(スタミナ)が非常に良好であるので、簡単に泡が消えることがなく、泡吐出容器から手のひらに吐出した泡そのもので身体全体を広く洗うことが可能になった。
また、本発明の泡吐出容器用身体洗浄剤は、洗浄、すすぎ後、タオルで拭いて乾燥した後の肌のつっぱり感が少なく、しっとりとした感触を与えることができ、更に、常温又は低温の環境下において長期間保存しても濁り、沈殿、分離等を生ずることのなく、均一で透明な液体状態を保つ、安定性に優れた身体洗浄剤である。
本発明の泡吐出容器用身体洗浄剤は、次の(A)のN−アシルアスパラギン酸又はその塩と(B)のN−アシル−L−グルタミン酸又はその塩という2種類のN−アシル-アミノ酸系界面活性剤を必須の成分として使用し、更に、これに次の(C)のアルキルジメチルアミノ酢酸ベタインと(D)のポリオキシエチレンアルキルエーテル硫酸塩とを必須成分として組み合わせて調製した組成物であり、このような組成物とすることによってはじめて上述したような優れた作用効果を奏したものである。
R4−O(CH2CH2O)n−SO3M3 (IV)
表1及び表2に示す身体洗浄剤組成物からなる試験液をポンプフォーマーの付いたボトル(泡吐出容器、吉野工業所製)に入れ、予め水道水1.3gを滴下して湿らせた模擬皮膚としての人工皮革(出光テクノファイン製、商品名:人工皮革サプラーレ)の上に、泡吐出容器のポンプを1回押して泡を吐出させた。1回のポンプからの泡の吐出量は、容積で15mL、重量で約1gであった。この人工皮革の一定の洗浄範囲(縦30cm×横10cm)の表面を、吐出した泡と一緒に片手の手のひらで15回こすった。そして、1分放置した後に人工皮革上の泡量を目視で観察した。
この操作は1つの試験液について2サンプルずつ左右の手のひらで同時に行い、2回目は左右を入れ替えてもう一度行い、2回の平均泡量を求めた。
◎◎・・・・泡は明らかに多い(泡が洗浄範囲の90%以上残っている)
◎ ・・・・泡は多い(泡が洗浄範囲の70%以上、90%未満残っている)
○ ・・・・泡はやや多い(泡が洗浄範囲の50%以上、70%未満残っている)
△ ・・・・泡はやや少ない(泡が洗浄範囲の30%以上、50%未満残っている)
× ・・・・泡は少ない(泡が洗浄範囲の30%未満残っている)
洗浄後の肌のしっとり感は、以下のような官能試験で評価した。
試験液をポンプフォーマーの付いたボトルに入れ、パネラーの片方の手のひらにポンプを1回押して泡を吐出した。予め温水で濡らした前腕部に泡を移し、往復15回擦った。その後温水ですすぎ、タオルで拭く。室温で30分乾燥させた後の肌の感触を、以下の5段階評点で評価した。サンプルの評価点はパネラー10名の平均値で示す。
明らかにしっとりする 5点
しっとりする 4点
普通 3点
あまりしっとりしない 2点
ほとんどしっとりしない 1点
洗浄剤溶液の安定性を以下の方法で評価した。
試験液をガラス瓶に入れて、25℃及び0℃の恒温機の中に1カ月間保存した。1カ月経過した後に恒温機から取出し、液の状態を目視で観察し、次の基準で評価した。
○・・・・析出物の無い均一透明液である。
△・・・・薄い濁り液である。
×・・・・濁り、沈殿又は分離が認められる不均一液である。
ポンプの詰まり程度を以下の方法で評価した。
試験液をポンプフォーマーの付いたボトルに入れ、最初にポンプを数回押して泡を吐出させた。その後、ボトルを0℃及び25℃の恒温機に入れて保存し、1週間に1回取り出し、ポンプを押して泡が吐出できるかポンプの詰まり状態を調べた。試験は最終的には4週間まで行い、総合評価した。
○・・・・4週間で一度もポンプの詰まりがない。
△・・・・2週間以後で、1回以上ポンプの詰まりが発生する。
×・・・・1週間でポンプの詰まりが発生する。
まず、成分(A)〜成分(D)のうちのいずれかを欠く場合には、比較例1〜5に示すように、泡の量が少なく泡のスタミナがない、又は液の安定性が悪い、或いはポンプの詰まりが発生するという問題があった。特に、0℃の低温度の場合には全てのもので保存後の組成物の液体において濁りや沈殿が発生し、また、1週間後でポンプに詰まりが発生して使い物にならなかった。
Claims (3)
- 更に、(E)プロピレングリコール、1,3−ブチレングリコール、グリセリンから選ばれる多価アルコールの1種又は2種以上を2〜8質量%含有する請求項1に記載の泡吐出容器用身体洗浄剤。
- 更に、(F)トリメチルグリシンを1〜4質量%含有する請求項1又は2に記載の泡吐出容器用身体洗浄剤。
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