JP5844807B2 - パウチ用ナイロンフィルム - Google Patents
パウチ用ナイロンフィルム Download PDFInfo
- Publication number
- JP5844807B2 JP5844807B2 JP2013518245A JP2013518245A JP5844807B2 JP 5844807 B2 JP5844807 B2 JP 5844807B2 JP 2013518245 A JP2013518245 A JP 2013518245A JP 2013518245 A JP2013518245 A JP 2013518245A JP 5844807 B2 JP5844807 B2 JP 5844807B2
- Authority
- JP
- Japan
- Prior art keywords
- film
- particles
- inorganic particles
- nylon
- nylon film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920006284 nylon film Polymers 0.000 title claims description 28
- 239000010954 inorganic particle Substances 0.000 claims description 55
- 239000002245 particle Substances 0.000 claims description 50
- 239000011146 organic particle Substances 0.000 claims description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000005995 Aluminium silicate Substances 0.000 claims description 6
- 235000012211 aluminium silicate Nutrition 0.000 claims description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 229910021536 Zeolite Inorganic materials 0.000 claims description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 5
- 230000001788 irregular Effects 0.000 claims description 5
- 239000010457 zeolite Substances 0.000 claims description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 description 37
- 239000004594 Masterbatch (MB) Substances 0.000 description 26
- 238000004519 manufacturing process Methods 0.000 description 16
- 238000007639 printing Methods 0.000 description 11
- 230000008569 process Effects 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 229920002292 Nylon 6 Polymers 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 9
- 239000000126 substance Substances 0.000 description 8
- 239000011347 resin Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 230000000704 physical effect Effects 0.000 description 6
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 239000012748 slip agent Substances 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 239000011324 bead Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000013329 compounding Methods 0.000 description 4
- 239000011888 foil Substances 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 239000004677 Nylon Substances 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- 238000010030 laminating Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920001778 nylon Polymers 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 238000004804 winding Methods 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 2
- 238000004049 embossing Methods 0.000 description 2
- 238000009998 heat setting Methods 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 238000012805 post-processing Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000010583 slow cooling Methods 0.000 description 2
- 238000007740 vapor deposition Methods 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 239000003484 crystal nucleating agent Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- FTQWRYSLUYAIRQ-UHFFFAOYSA-N n-[(octadecanoylamino)methyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCNC(=O)CCCCCCCCCCCCCCCCC FTQWRYSLUYAIRQ-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0018—Combinations of extrusion moulding with other shaping operations combined with shaping by orienting, stretching or shrinking, e.g. film blowing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D7/00—Producing flat articles, e.g. films or sheets
- B29D7/01—Films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/16—Solid spheres
- C08K7/18—Solid spheres inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2377/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
測定方法:ASTM D1894
使用機器:Friction tester(Toyoseiki、Model TR type)
測定条件:ナイロンフィルムのコロナ処理面同士摩擦係数測定
測定方法:ASTM D882
使用機器:Instron 5566
測定条件:延伸速度500mm/min、温度20℃、相対湿度65%
試片大きさ:幅15mm、長さ100mm
測定方法:ASTM D1003
使用機器:Color and color difference meter
(Nopon denshoku、Model 1001DP)
相対粘度が3.3であるナイロン6に、下記表1に示すように、無機粒子(A)成分として球形アルミナ(アスペクト比(aspect ratio) 1.02)を全体マスターバッチに対して1重量%、有機粒子(B)成分としてPMMAビーズ(bead)(KOLON Diasphere)5重量%、無機粒子(C)として不規則な塊状のカオリンを2重量%を混合し、ツインスクリュータイプの押出機で245℃条件で混合マスターバッチを製造した。
下記表1のように、無機粒子(A)、有機粒子(B)、及び無機粒子(C)の粒径と含量を調節し、ナイロン6の相対粘度を調節したことを除いては実施例1と同様な方法により混合マスターバッチを製造した。
無機粒子(A)成分として球形合成ゼオライトを全体マスターバッチに対して下記表1に記載された含量になるように、相対粘度が下記表1に記載されたナイロン6と混合し、実施例1のようにツインスクリュータイプの押出機で245℃条件でマスターバッチAを製造した。
無機粒子(A)、有機粒子(B)、及び無機粒子(C)を下記表1のように変化して添加したことを除いては前記実施例7と同様な方式により製造した。また、前記のように製造されたフィルムを利用してアルミホイルを接着した後、パウチ(Pouch)形態を製造し、その深さを測定して表4に示した。
比較例として、下記表2のような含量でマスターバッチを製造し、実施例1のようにフィルムを製膜した。その結果を下記表4に収録した。
Claims (3)
- 平均粒径が1〜5μmである無機粒子(A)100〜1000ppmと有機粒子(B)1000〜10000ppm、及び平均粒径0.05〜0.2μmである無機粒子(C)500〜2000ppmを含み、前記無機粒子(A)及び有機粒子(B)は、球形であり、前記無機粒子(C)は、不規則塊状であることを特徴とするナイロンフィルム。
- 前記無機粒子(A)及び無機粒子(C)は、ゼオライト、アルミナ、シリカ、カオリン、Na2O、CaOから選択され、有機粒子(B)は、アクリル系、スチレン系またはシリコーン系高分子粒子である請求項1に記載のナイロンフィルム。
- 前記ナイロンフィルムは、環状ダイで押出し、チューブラー方式で二軸延伸して製造される請求項1または2に記載のナイロンフィルム。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-2010-0062268 | 2010-06-29 | ||
KR20100062268 | 2010-06-29 | ||
KR1020110062470A KR101427677B1 (ko) | 2010-06-29 | 2011-06-27 | 파우치용 나일론 필름 |
KR10-2011-0062470 | 2011-06-27 | ||
PCT/KR2011/004714 WO2012002704A2 (en) | 2010-06-29 | 2011-06-28 | Nylon film for pouch |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2013533913A JP2013533913A (ja) | 2013-08-29 |
JP5844807B2 true JP5844807B2 (ja) | 2016-01-20 |
Family
ID=45609283
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2013518245A Active JP5844807B2 (ja) | 2010-06-29 | 2011-06-28 | パウチ用ナイロンフィルム |
Country Status (4)
Country | Link |
---|---|
JP (1) | JP5844807B2 (ja) |
KR (1) | KR101427677B1 (ja) |
CN (1) | CN102971366B (ja) |
TW (1) | TWI492977B (ja) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101995478B1 (ko) * | 2013-03-29 | 2019-07-02 | 코오롱인더스트리 주식회사 | 나일론필름 및 이의 제조방법 |
WO2015037962A1 (ko) * | 2013-09-16 | 2015-03-19 | 코오롱인더스트리 주식회사 | 나일론 필름 |
KR102290455B1 (ko) * | 2013-09-16 | 2021-08-18 | 코오롱인더스트리 주식회사 | 나일론 필름 |
KR20160076022A (ko) | 2014-12-19 | 2016-06-30 | 주식회사 효성 | 슬립성이 향상된 나일론 필름과 그의 제조방법 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07233266A (ja) * | 1993-12-28 | 1995-09-05 | Toyobo Co Ltd | 滑り性の改善された二軸延伸ポリアミド樹脂フィルム |
JP3429386B2 (ja) * | 1995-03-23 | 2003-07-22 | 株式会社興人 | 易接着性ポリアミドフィルム |
JP2000239522A (ja) * | 1999-02-25 | 2000-09-05 | Toray Ind Inc | フィルム用ポリアミド樹脂組成物、その製造方法及び2軸延伸フィルム |
JP2001225386A (ja) * | 2000-02-17 | 2001-08-21 | Mitsubishi Engineering Plastics Corp | ポリアミドフィルム |
JP2002080714A (ja) * | 2000-02-18 | 2002-03-19 | Mitsubishi Engineering Plastics Corp | ポリアミド樹脂組成物およびフィルム |
JP2001341197A (ja) | 2000-06-05 | 2001-12-11 | Unitika Ltd | 透明蒸着用二軸延伸ナイロンフィルム |
TWI281891B (en) * | 2002-03-01 | 2007-06-01 | Teijin Ltd | Biaxially oriented multi-layered laminated film and method for manufacture thereof |
KR100897847B1 (ko) * | 2002-04-02 | 2009-05-15 | 주식회사 코오롱 | 슬립성 및 접착력이 우수한 이축연신 나일론 필름 |
-
2011
- 2011-06-27 KR KR1020110062470A patent/KR101427677B1/ko active IP Right Grant
- 2011-06-28 JP JP2013518245A patent/JP5844807B2/ja active Active
- 2011-06-28 CN CN201180033004.4A patent/CN102971366B/zh active Active
- 2011-06-29 TW TW100122912A patent/TWI492977B/zh active
Also Published As
Publication number | Publication date |
---|---|
KR101427677B1 (ko) | 2014-08-13 |
TW201202329A (en) | 2012-01-16 |
KR20120001643A (ko) | 2012-01-04 |
JP2013533913A (ja) | 2013-08-29 |
CN102971366B (zh) | 2016-04-20 |
CN102971366A (zh) | 2013-03-13 |
TWI492977B (zh) | 2015-07-21 |
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