201202329 六、發明說明： 【發明所屬之技術領域】 本發明涉及-種薄膜，由於低摩擦係數而具有良好的滑性， 處理期間具有良好的加球，並且在產生袋型時由 的袋深能力（袋深的形成特性）。 _歡而具有良好 特別是’本發明涉及-種具有低摩擦舰及低模數的_ 有不同_和不同尺寸的無機和錢餘混合以製備母料，並 $ 用-種管型薄膜製造裝置將母料投人；且本發明涉及 封材料及改善袋深能力中具有良好的加工性的尼龍薄臈。 表侑在 【先前技術】 相對於其他薄膜來說，尼龍_具有較高的氣體阻隔性，因此 於真空包裝原材料、氣球及其它類似物，料來被·化學 二次電池包裝袋。 农久 ㈣2，當製造尼龍薄麟，在拉伸過程或加驗理_，為防止阻塞 口彎曲皺稽’要加入少量的添加劑。依據種類不同，各個薄膜具有或 Z同的雜，但它們需要具有高速生產率及撕開特性，並在後處理 對印刷、層壓等可輕易處理，以及其各自的物理特性。 在生產和後處理中如果義不具容易性，儘管它們具有良好的特性， 也很難於«上制，且，適當的後處理及_的雜是重要的。 換句魏，許多水分在尼龍_表面上被魏伴隨增加的尼龍表面的 水为吸收，也就是增加尼龍薄膜的摩擦係數，且因此導致其滑性下降。這 種，象惡化了諸如分切、印刷、層壓薄膜等等在後處理_的活動能力和 y操作性。隨著缺陷的增加，明顯惡化可操作性以及降低產量，因此 製造成本，且因此，需要改善薄膜的滑性。 為了改善薄朗滑性，細微的不平滑可形成在在薄膜表面上用以減少 與薄膜的接觸_，或者義表面藉由具有良好的材料被不均句化。 藉由在薄膜表面形成細微的不平滑以減少接觸面積且因此降低摩擦係 ’作為用於改善'薄赌性方法的賴，訂财法：-種㈣麵製造 201202329 =時的慢慢冷卻，藉由晶球的生長，在薄膜表面上形成 j利公開第加51·觸號）；一種由於晶體成核劑的添加;^方= 生= 在薄膜表面上形成不均勻的方法（日本專利公開第如52==的 =直接在薄臈表面塗佈二氧化料精細滑石粉末的方法（日本專利= =Sho·^)號；-種在聚合聚合物及製造薄膜時，藉^ = ::==法’等等。除此之外’還有壓花處—^ 另外’為改善薄膜的雜，藉由_良好活性的材料來非 的表面’已知的方法是在原料中混合具有良好活性的另 ii^="mide)、碳統合她旨料，制於师_直接塗^ 然而，上述方法可能改善了滑性，但在製造過程或品質一致 ，。由於製造_的條件被限制’利用擠難造薄 冷部明顯地降低了可操作性。在_表面塗佈精細粉末的方法會亞化= 環境且在㈣塗佈量和處料來微㈣面有_。此外，壓$ 處理，化學處理科需要㈣的製程，都會導致成本的增加，並亞化薄^ 的物理特性，如_度和表面光澤度^此外，在補中混合贱碳氣^ 脂的方法會導致於後處理期間印刷或層壓中黏接的問題。 ， 此外，在聚合時增加無機微粒的方法有較佳優點，像是降低製造 但在聚合時即便於萃取歧朗無雜子鮮取㈣，由於在高溫 間的兩驗性條件下絲增進分散性的製程，會有粒子變成破裂或被炫化的 問題8 薄膜’基本上，在大多數後處理中如印刷、層壓、沈積等等，需要高 黏合強度’合強度基本上依賴基縣面的化學結構，但是在相同化^ 分下大都依賴表面的物理形狀。 實際上’如果滑劑是多量的’摩擦係數就會很容易降低，即使滑劑稍 稍增加。但是#合強度已主要取胁化學成分，關此可將其忽略。就其 本身而論’滑劑的成分、尺寸、形狀等因素對其的滑性均有影響，但實際 上，後處理期間滑劑對表面黏合劑強度的影響可忽略不計。 丁 然而’藉由滑劑中使祕粒來改善表面的突起，導致與表面接觸面積 201202329 於印刷或層壓中的黏合劑強 增加’藉以改善黏合劑強度，如後處理期間 度及沈積中的黏合力。 【發明内容】 工性 本發明的目的旨在提供-種尼龍薄膜，該薄膜因具有低摩擦係數而表 現出改善的雜’並且具有錄的_雛絲現出傑㈣後處理加 -方面’根據本發明’尼龍賊包括複數個無機微粒⑷和複數 機微粒（Β)，該等無機微粒（Α)及該等有機微粒（Β)的每一個都 均微粒尺寸1至5叫、以及概個織錄（c)，具有平均齡尺寸〇 〇5 f ，其找缝_具有在刪至13_ppm範_的錢總 量，根據ASTM D腦，摩擦係數為〇.05至〇 3，根據astm職模數 範圍為250至350kg/cm2，且根據ASTMD聰，薄膜霧度為1〇至5〇。 根據本發明的尼龍薄膜，使用具有相對黏性係數為2 6至3 5的尼龍作 為基底樹脂，以及藉她合每-_具有〗至5叫的平均難尺寸且 接近於球體的無機微粒（Α)和有機微粒（Β)與平均微粒尺寸為〇 〇5至/ 且形狀料規舰_無機齡（C)來製備難母料。紐粒母料藉由使 用圓形模具並以管狀方式雙轴拉伸來擠壓，藉以製造尼龍薄膜。 本發明人發現將上述三種微粒混合及使用，將獲得紐不到的效果， 如由於在塗層和印射摩擦係數顯著下降域合強度提高而改進了後處理 加工性’這促進了本發明的完成。 在此’該微粒母料可藉由分別或全部投入無機微粒（Α)、有機微粒 及無機微粒（C)來製備。無機微粒（Α)和無機微粒⑻係選自魏鹽、 氧化銘、二氧化碎及高嶺土’有機微粒（Β)可使用丙稀酸系、苯乙稀系、 石夕_系聚合物微粒。更具體來說’由__、氧化|g、二氧切等所組 成之天然或者合成的駐可料織聽（A)。有機粒⑻為合成珠型， 並可應用聚（甲基）丙稀酸或聚苯乙烯、有機料。無機微粒⑹可應用 高嶺土’二氧化矽等。 201202329 在用於製造尼麟麟雜巾，添加該所製制母料触 至麵PPm的無機微粒⑷，麵至ω，_ f ⑹賴。所獅於_==/ 管里尹進订’ 5“型為同時雙歸伸類型。該所形 250〜400kg/mm2 的縱向(machine direction，MD)模數。 ' 下面將詳細描述本發明。 本發明旨在糾添加含有域齡的母料触來财 膜的滑性。這裡，三種無機微粒均具有不同形狀和不同尺寸作 在改善滑性方面也表現出良好的效果。然而，如果增加二寺’因此 膜具有增加的霧度。對於具有形狀接近球形的無機^ ^ 成的薄 ⑻,’由於無機微粒⑷和有機微粒（Β)具有小的表 和性變得相對較弱。這導致在微粒間的界面中粒子間的親 似於非晶態形式的情況下的聚合物被拉伸有類 於具有這些特性的無機微粒⑷和有機微粒（‘=33對 責，而若它們尺寸大則會增加薄膜霧度。因此格昂 機微粒⑻用於商業領域，在薄膜允許的霧度範圍内需將H詈m 低。然而，廷會使其表現出良好的 在/ 最 起數量是小的，_面是很光滑的。結果膜表面上的突 在後處理__接觸面積減小，藉以_合41 變小’且因此’ 根據本發明’具讀無機録（A)及錢雜⑻ 的無機微粒（C) ’也與微粒⑷和⑻一起添加 °八尺寸 不規則的塊狀雜且其平均尺寸為G5至 ii，，、、機微粒（C)具有 ，也被添加時，會形成大量的突起，且接^積1無機微粒 :強度。再者’與只用無機微粒（A)微J二^改善黏 ^可以在高濕度下改善滑性。當利用大尺寸無機I時，由種情 201202329 昧良好，擦特性’但是摩擦係數明顯增加。然而，當添加無 數的增加。’至在减度7"都會形成大4的小突起，藉崎低摩擦係 仏似無機Ϊ粒（Α)及有機練（Β)具有平均齡尺寸1至5叫。如果平 你叙丈於.1μΐϊ1，製造薄膜後形成不光滑的影響是小的，且因此摩擦 舱去二減小。而如果平均微粒尺寸大於5μΠ1，由於製造薄膜時微 ^和薄膜的霧度鴨增加而導致細的斷裂增加。 ‘里二、及粒,（C)具有平均微粒尺寸〇·05至2μΠ1且呈不規則塊狀形狀。 ㈣tii平均微粒尺寸小於⑽叫，觀細後*光滑效果是小的，因此 1。黏α強度’且製備母料時於組合期間會出現很多結塊，因此減小 2=描而如果它的平均微粒尺寸大於2叫，由於大量微粒，薄膜霧度 曰加0無機微粒（C)較佳的微粒尺寸為無機微粒（Α)的1/1〇〇 至1/25如果無機微粒（C)的微粒尺寸大於無機微粒（Α)的肪，薄膜 j度月顯地增加’且由於無機微粒（c)具有塊狀形狀，在製備母料或製 =薄膜時就會报料丨現結塊。這些塊狀結構使_造成缺陷 ，且因此， 2生產細胞«會產生缺陷。而如果域齡⑹的齡財小於無機微 r A微粒尺寸的1/1〇〇，在製備母料時就會出現大量的微粒結塊，因此 3製備母料的難度。另外’用於母料組合中的尼龍薄雌佳是具有相對 ^又2.6胃至3.5 (以95%的硫酸方法測量）。如果相對黏度小於2.6，微粒可 刀散H疋優異的’但在與尼龍薄麟底細旨齡時，黏度差異是大的。結 果'^刀沒被印刷或黏著塗佈的控制點（此⑽沉k ?〇油）於製造薄膜後在 印刷或黏著劑塗佈時被產生’導致惡化了最終產品的品質 。而如果相對黏 又於3.5 ’微粒可分散性是降⑽，因此增加了滿足薄膜所需物理特性的 另外，本發明主要將濟石、氧化紹、二氧化石夕、高嶺土201202329 VI. Description of the Invention: [Technical Field] The present invention relates to a film which has good slip property due to a low coefficient of friction, a good ball during processing, and a bag depth capability when a bag type is produced. (The formation characteristics of the bag depth). _ 欢 欢 有 有 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 The masterbatch is injected; and the present invention relates to a sealing material and a nylon thin crucible having good processability in improving bag depth. [Previous Art] Nylon_ has a high gas barrier property with respect to other films, and therefore, it is used to vacuum-package raw materials, balloons, and the like to be used in chemical secondary battery packaging bags. Farming for a long time (4) 2, when manufacturing nylon thin lin, in the stretching process or adding a test _, in order to prevent the obstruction of the mouth bending wrinkles, to add a small amount of additives. Depending on the type, each film has the same or the same impurity, but they are required to have high-speed productivity and tearing properties, and can be easily handled by post-processing for printing, lamination, etc., and their respective physical properties. In the production and after-treatment, if the meaning is not easy, although they have good characteristics, it is difficult to make it, and proper post-processing and _ is important. In other words, a lot of water is absorbed on the nylon surface by the water on the surface of the nylon which is accompanied by the addition of Wei, that is, the friction coefficient of the nylon film is increased, and thus the slip property is lowered. This, for example, deteriorates the activity ability and y operability of the post-processing such as slitting, printing, laminating film, and the like. As the defects increase, the operability is remarkably deteriorated and the yield is lowered, so the manufacturing cost, and therefore, the smoothness of the film needs to be improved. In order to improve the thinness and smoothness, fine unevenness may be formed on the surface of the film to reduce contact with the film, or the surface may be unevenly sentenced by having a good material. By forming a fine unevenness on the surface of the film to reduce the contact area and thus reducing the friction system as a method for improving the 'thin gambling method', the method of financing: - (4) face making 201202329 = slow cooling, borrow From the growth of the crystal ball, a surface of the film is formed on the surface of the film; a type of nucleating agent; a method of forming a non-uniformity on the surface of the film (Japanese Patent Publication No.) For example, 52== = direct application of dioxide dioxide fine talc powder on the surface of thin enamel (Japanese patent = = Sho · ^) No.; - when polymerizing polymers and manufacturing films, by ^ = ::== Method 'etc. In addition to 'there is also embossing - ^ another 'to improve the film's impurities, by the _ good active material to the surface of the 'known method is mixed in the raw material with good activity Another ii^="mide), carbon integration of her purpose, made by the teacher _ direct coating ^ However, the above method may improve the slippery, but the manufacturing process or quality is consistent. Since the conditions of the manufacturing_ are limited, the operability is remarkably lowered by the use of the squeezing cold portion. The method of coating the fine powder on the surface of the surface will be sub-ized = environment and there will be _ on the micro (four) side of the (four) coating amount and the material. In addition, the pressure of $ treatment, the chemical treatment department needs (four) of the process, will lead to an increase in cost, and the physical characteristics of the sub-thin, such as _ degree and surface gloss ^ In addition, the method of mixing 贱 carbon gas in the supplement This can cause problems in bonding during printing or lamination during post processing. In addition, the method of adding inorganic fine particles during polymerization has a preferable advantage, such as lowering the production, but even if the extraction is inferior to the extraction during the polymerization (4), the dispersion is improved due to the two test conditions under high temperature. The process, there will be particles that become cracked or stunned. 8 Films 'Basically, in most post-processing such as printing, lamination, deposition, etc., high bond strength is required. The strength of the bond is basically dependent on the base county. The chemical structure, but under the same chemistry, mostly depends on the physical shape of the surface. In fact, if the slip agent is a large amount, the friction coefficient is easily lowered even if the slip agent is slightly increased. However, #合强度 has mainly taken the threat of chemical composition, which can be ignored. As far as it is concerned, the composition, size, shape and other factors of the slip agent have an effect on the slipperiness of the slip agent. However, in practice, the effect of the slip agent on the surface adhesive strength during the post-treatment is negligible. Ding, however, 'improving the surface protrusions by using the secret agent in the slip agent, resulting in a strong contact with the surface contact area 201202329 in printing or laminating' to improve the bond strength, such as post-treatment period and deposition. Adhesion. SUMMARY OF THE INVENTION The object of the present invention is to provide a nylon film which exhibits improved miscellaneousness due to its low coefficient of friction and has a recorded _ 雏 现 现 四 四 四 四 四 四 四 四 四 四The 'nylon thief of the present invention includes a plurality of inorganic fine particles (4) and a plurality of inorganic fine particles (Β), and each of the inorganic fine particles (Α) and the organic fine particles (Β) has a particle size of 1 to 5, and a general weave. Record (c), with an average age of 〇〇5 f, and its finding _ has the total amount of money deleted to 13_ppm _, according to ASTM D brain, the friction coefficient is 〇.05 to 〇3, according to the astm model The range is from 250 to 350 kg/cm2, and according to ASTM D., the film has a haze of from 1 to 5 Torr. According to the nylon film of the present invention, nylon having a relative viscosity coefficient of from 26 to 35 is used as the base resin, and inorganic fine particles which are close to the sphere and have an average difficulty size and are close to the sphere. And the organic fine particles (Β) and the average particle size of 〇〇5 to / and the shape of the ship _ inorganic age (C) to prepare difficult masterbatch. The granule masterbatch is extruded by using a circular die and biaxially stretching in a tubular manner, thereby producing a nylon film. The present inventors have found that the mixing and use of the above three kinds of microparticles will achieve an effect which is not satisfactory, such as improved post-processing workability due to a significant decrease in the coating strength of the coating and the printing friction coefficient, which promotes the process of the present invention. carry out. Here, the fine particle master batch can be prepared by separately or exclusively introducing inorganic fine particles (ruthenium), organic fine particles, and inorganic fine particles (C). The inorganic fine particles (yttrium) and the inorganic fine particles (8) are selected from the group consisting of Wei salt, oxidized crystal, oxidized ground and kaolin. The organic fine particles (Β) may be acrylic acid, styrene or stellite polymer fine particles. More specifically, the natural or synthetic resilience (A) consisting of __, oxidized |g, dioxo, and the like. The organic particles (8) are synthetic bead type, and poly(methyl)acrylic acid or polystyrene or organic materials can be used. As the inorganic fine particles (6), kaolin's cerium oxide or the like can be applied. 201202329 In the production of Ni Lin Lin miscellaneous towels, the inorganic fine particles (4) which are added to the surface PPm by the prepared masterbatch are added to face ω, _ f (6). The lion is in the _==/ tube Yinyin order '5' type is the simultaneous double-reduction type. The shape is 250~400kg/mm2 in the machine direction (MD) modulus. The invention will be described in detail below. The present invention aims to correct the slipperiness of a masterbatch containing a domain age, and the three inorganic microparticles have different shapes and different sizes to exhibit good effects in improving slipperiness. However, if two are added, Temple's film therefore has an increased haze. For thin films (8) having a shape close to a spherical shape, 'because inorganic particles (4) and organic particles (Β) have a relatively small surface and become relatively weak. The polymer in the case where the particles are in the amorphous form in the interface between the particles is stretched to have inorganic particles (4) and organic particles having these characteristics ('=33), and if they are large in size, It will increase the haze of the film. Therefore, the Gon machine particles (8) are used in the commercial field, and H詈m is required to be low in the allowable haze range of the film. However, the Ting will make it show a good in/the minimum amount is small, _ face is very smooth. Result film The protrusion on the surface is post-processed __the contact area is reduced, whereby _41 is smaller and thus 'in accordance with the invention' inorganic particles (C) with read inorganic record (A) and money (8) 'also with particles (4) Adding an eight-size irregular block-like impurity together with (8) and having an average size of G5 to ii, and, as the machine particle (C) has, when added, a large number of protrusions are formed, and an inorganic particle is formed. :Intensity. Furthermore, it can improve the slipperiness under high humidity with the use of inorganic microparticles (A) micro-J 2 ^. When using large-size inorganic I, it is good by the situation 201202329, rubbing characteristics 'but friction The coefficient increases significantly. However, when adding a myriad of increases, 'to the reduction of 7" will form a large 4 small protrusions, and the low friction coefficient of the slag is like inorganic granules (Α) and organic training (Β) with average age size. 1 to 5 calls. If you are flat at .1μΐϊ1, the effect of forming a film after the matte is small, and therefore the friction chamber is reduced by two. If the average particle size is larger than 5μΠ1, due to the microfilm The haze of the film increases and the fine fracture increases. Second, and the particles, (C) have an average particle size of 〇·05 to 2μΠ1 and have an irregular block shape. (4) The average particle size of tii is less than (10), and the smoothing effect is small, so 1. Sticky α strength And when the masterbatch is prepared, a lot of agglomerates will appear during the combination, so the reduction 2 = description and if its average particle size is greater than 2, due to the large number of particles, the film haze adds 0 inorganic particles (C) preferred particles The size is 1/1 〇〇 to 1/25 of the inorganic fine particles (Α). If the particle size of the inorganic fine particles (C) is larger than that of the inorganic fine particles (Α), the film increases exponentially by a degree and the inorganic particles (c) It has a block shape and is reported to be agglomerated when preparing a masterbatch or a film. These block structures cause _ to cause defects, and therefore, 2 production cells «will produce defects. On the other hand, if the age of the age (6) is less than 1/1 of the size of the inorganic micro-AR particles, a large amount of particulate agglomeration will occur during the preparation of the master batch, and therefore 3 is difficult to prepare the master batch. In addition, the nylon thinner used in the masterbatch combination has a relative hardness of 2.6 to 3.5 (measured by the 95% sulfuric acid method). If the relative viscosity is less than 2.6, the particles can be excellently dispersed, but the difference in viscosity is large when it is fine with nylon. As a result, the control point where the knife was not printed or adhered (this (10) sinking k 〇 oil) was produced at the time of printing or adhesive coating after the film was manufactured, resulting in deterioration of the quality of the final product. On the other hand, if the relative viscosity is 3.5 Å, the dispersibility of the particles is decreased (10), so that the physical properties required for the film are increased. In addition, the present invention mainly comprises shale, oxidized, sulphur dioxide, kaolin.
、Na20、CaO 用來作為無機微粒⑷和無機微粒⑹，以及將㈣酸系、苯乙稀系或 石夕啦聚合物微粒等用來作為有機微粒⑻。這些在製備母料時可單獨地 或混合地組合。 藉由利用無機微粒（A)、有機微粒⑻和無機微粒（c)所製備的母 料最佳地具有微粒含量〇 5至3Qwt%。如果微粒含量小於Q 5感，製備母 201202329 料的數量就會增加，因此增加了維護母料品質的難度，也增加處理母料的 成本，且因此增加製備成本。而如果微粒含量大於30wt%，微粒可分散性 就會被惡化，且由於微粒含量高，則很難生產出品質統一的母料。此外， 薄膜t微粒可分散性被惡化，且薄膜微粒的數量很難控制。此外，基於薄 膜總含量’上述無機微粒的最佳含量為1600至BOOOppm。 此外，可包含100至lOOOppm的無機微粒（A)、1000至1〇〇〇〇ppm的 有機微粒（B)、以及500至2000ppm的無機微粒（c)。 如果無機微粒（A)的含量低於i〇〇ppm，即使具有大尺寸的有機微粒 (B)的含量提高，其彎曲特性也會嚴重被破壞。而如果無機微粒的含量高 於lOOOppm，在不改善彎曲特性或低摩擦係數特性及製造成本的情況下， 薄膜霧度會明顯增加。 如果有機微粒（B)的含量低於i〇〇〇ppm，考慮到霧度，即使大量投入 具有大尺寸的無機微粒（A)，低摩擦特性也报難實現。而如果有機微粒（B) 的含量尚於10000ppm，則滑性太高以致於彎曲很困難，且薄膜霧度明顯增 加’且製造成本也增加。 >如果無機微粒（C)的含量低於5〇〇ppm，印刷和黏附性就會嚴重被破 壞。而如果無機微粒（C)的含量高於2〇〇〇ppm，在不改善印刷和黏附性下， 製造成本就會增加。 本發明的尼龍薄膜不受尼龍6的限制，且可包括尼龍式雙軸拉伸薄膜。 通常，本發’用尼龍細具有—適當厚度5至5()μιη，且顧在尼龍薄膜 的基底樹脂具有較佳之相雜度3 〇至3 6。如果基膜的相對黏度小於3， 製造後尼龍薄膜的物理特性就會被破壞。而如果基膜的相對黏度高於36 , 基底樹脂在熔化擠壓時沒有良好的流動特性，且拉伸特性是不夠的，其無 法滿足所需的物理特性。 本發明旨在提供一種具有低摩擦係數和低模數的尼龍薄膜，並在袋型 的袋深能力中具有更好的效果。 【實施方式】 以下，藉由具體示例來詳細描述本發明，但是本發明並不侷限於以下 幾個例子。 201202329 通過下述方法來測量本發明薄膜的物理特性。 1) 摩擦係數 测量方法.美國材料實驗協會（ASTM) D1894 使用儀器.摩擦試驗裝置（ToyosejJ^，tr模型） 測量條件·測量尼龍薄膜之電暈處理表面的摩擦係數 2) 模數 測量方法.美國材料實驗協會（ASTM) D882 使用儀器·央氏拉伸強度试驗機5566 (Instron 5566) 測量條件：拉伸率500mm/min，溫度2(TC，相對濕度65% 樣品尺寸：寬15mm，長l〇〇mm 根據上述方法測量後決定拉伸應力為2%應力 3) 霧度 測量方法：美國材料實驗協會（ASTM) Di〇〇3 使用儀器：顏色及色差計 (Nopon denshoku，1001DP 模型） 示例1 如表1所示’以lwt%的球形氧化紹（縱橫比(aspectratio)，1.02)作為 無機微粒（A)的成分，5wt%的聚甲基丙烯酸甲酯珠粒（KOLON Diasphere ) 作為有機微粒（B)的成分，以及2wt°/〇具有不規則塊狀之高嶺土作為無機 微粒（C)的成分，基於母料總重量加％，混入具有相對黏度3 3的尼龍6 中’且藉由利用一雙螺旋型擠壓機在245°C下，使用所得的混合物(resulting mixture)來製備混合的母料。 接著’根據表3所示的含量，混合的母料被混入具有相對黏度3.3的尼 龍6中。利用一圓形模具(circulardie)在265°c下擠出所得的混合物，且同 時在一管型令以3x3倍的拉伸比被雙軸拉伸，接著熱定型，藉以製造尼龍 薄膜。此外’將鋁箔貼至製造的薄膜上用以生產袋型(pouch form)，且接著 測量袋型的深度。 結果記錄在表3中。 示例2至6 每個混合的母料都用與示例1之相同的方法來製備，除了如表1所示 201202329 控制微粒尺寸和無機微粒（A)、有機微粒（B)和無機微粒（c)的含 及控制尼龍6的相對黏度之外。 一接著，混合的母料被混入具有相對黏度3.3的尼龍6中，含量如表3所 示。藉由使用-圓職具在265t下擠出所得的混合物，且同時在—管型中 以3xj倍的拉伸比被雙轴拉伸，接著熱定型，藉以製造尼龍薄膜。此外， 將銘羯貼至製造的細上用以生產雜，且接著測量袋型的深度，並記錄 在表3中。 ° 、 結果記錄在表3中。 示例7 八球形合成沸石’作為無機微粒（Α)的組成成分，基於母料的總重量百 分比wt% ’被混入具有相對黏度3 3的尼龍6中如表1所示，使得其包含如 表1所示的含量，且藉由利用一雙螺旋槳麵機於245t下，使用所得的飞 合物來製備母料A，如示例1。 沖 聚甲基㈣酸甲g旨珠粒（K〇LC)N Diasphere)，作為有機微粒⑻的 S’ ’基於母料_重量百分比痛’也被混人具有相對黏度3 3的尼 央制供j1所不’使得其包含如表1所示的含量，且使用所得的混合物 來製備母料B，如示例1。 塊狀高嶺土’作為無機微粒（c)驗成成分，基於母料_重量百分 =wt%，亦被混入具有相對黏度3 3的尼龍6中如表丨所示，使得其包含如 表1所不的含量，且使用所得的混合物來製備母料c。 _ f著’這三種製備的母料都混入具有相對黏度3·3的尼龍6中如表1所 二由利用圓形模具擠出所得的混合物，如示例j，且在一管型中被雙 =伸’藉以製造尼龍_。此外，_被貼至所形成的賴上用以生產 敕型，且接著袋型的深度被測量且記錄在表3中。 結果記錄在表3中。 示例8至12 齡龍相如神'! 7以相同的方法來製造，除了如表1所示要添加 (Α)、繼粒（Β)及纖粒（G) _碰證之外。此 且貼至所喊的賴上㈣生產袋型，且接著袋型的深度被測量 且〇己録在表4中。 201202329 結果記錄在表4中。 比較示例1至6 對每個比較示例而言，製備具有含量如表2所示之每個母料，且使用 母料來製造薄膜，如示例1。結果記錄在表4中。 表1 母料的製備方法（百分比(％)表示重量百分比(wt%)) 示例 無機微 粒（A ) 的含量 無機微 粒（A) 的微粒 尺寸 有機微 粒（Β) 的含量 有機微 粒（Β) 的微粒 尺寸 無機微 粒（C) 的含量 無機微 粒（c) 的微粒 尺寸 母料樹 脂的相 對黏度 備註 1 1% 3μηι 5% 5μιη 2% 0.05μηι 3.3 混合的 母料 2 1% 3μηι 10% 5μηι 2% 0.05μΓη 2.6 混合的 母料 3 5% 3μπι 30% 5μηι 15% 0.05μηι 3.1 混合的 母料 4 1% 2μηι 5% 5μηι 2% Ο.Οδμηι 3.1 混合的 母料 5 1% 5μηι 5% 5μηι 2% 0.05μιη 3.1 混合的 母料 6 5% 5μπι 30% 5μηι 15% 0.2μηι 3.1 混合的 母料 三種非 7 1% 3μηι 5% 5μηι 2% 0.05μιη 3.3 混合母 料 三種非 8 1% 3μηι 10% 5μηι 2% 0.05μιη 2.6 混合的 母料 9 5% 3μπι 30% 5μηι 15% 0.05μηι 3.1 三種非 混合的 11 201202329 母料 10 5% 2μηι 30% 5μιη 15% 0.08μιη 3.1 三種非 混合的 母料 11 1% 5μηι 5% 5μηι 2% 0.05μηι 3.1 三種非 混合的 母料 12 1% 5μπι 5% 5μιη 2% 0.2μηι 3.1 三種非 混合的 母料 表2 (百分比(％)表示重量百分比(Wt%)) 無機微 粒（Α) 的含量 無機微 粒（Α) 的微粒 尺寸 有機微 粒（Β) 的含量 有機微 粒（Β) 的微粒 尺寸 無機微 粒（C) 的含量 無機微 粒（c) 的微粒 尺寸 母料樹 脂的相 對黏度 備註 1 0.4% 3μηι 0.4% 5μηι 0.4% 0.05μηι 3.3 混合母 料 2 26% 3μηι 2% 5μπι 2% 0.05μιη 2.6 混合母 料 比 較 3 5% 5μιη 20% 5μηι 10% 0.3μηι 3.1 混合母 料 示 例 4 25% 3μηι 3% 5μηι 40% 0.05μηι 3.3 非混合 母料 5 5% 3μηι 30% 5μιη 15% 0.05μηι 2.6 非混合 母料 6 1% 5μηι 10% 5μπι 2% 0.3μπι 3.1 非混合 母料 12 201202329 表3 (百分比(％)表示重量百分比(Wt°/o)) 母料投入比 薄膜中微粒的 量（ppm) 摩 擦 係 數 模數 (kg/cm2) 霧 度 袋深能 力（mm) 無機 微粒 (A) 有機 微粒 (B) 無機 微粒 (C) 總量 示 例 1 3% (混合） 300 1500 600 2400 0.28 280 20 6.9 示 例 2 4% (混合） 400 4000 800 5200 0.18 275 45 9 示 例 3 1% (混合） 500 3000 1500 5000 0.25 295 40 8.2 示 例 4 3% (混合） 300 1500 600 2400 0.28 281 25 6.8 示 例 5 4% (混合） 400 2000 800 3200 0.3 273 30 8 示 例 6 1% (混合） 500 3000 1500 5000 0.26 295 42 7.8 比 較 示 例 1 5% (混合） 200 200 200 600 0.75 260 5 2 比 較 0.5% (混合） 1300 100 100 1500 0.6 370 22 3 13 201202329 示 例 2 比 較 示 例 3 0.5% (混合） 250 1000 500 1750 0.45 320 20 - *發生在生產袋型時於鋁箔和比較示例3間的分層現象。 表4 (百分比(％)表示重量百分比(wt%)) 201202329 母料投入比 薄膜中微粒的量（ppm) 摩擦 係數 模數（kg/cm2) 霧 度 袋深能力 (mm) 母料 A 母料 B 母料 C 無機微 粒（A) 有機微 粒（B) 無機微 粒（C) 總量 示 例7 3% 3% 3% 300 1500 600 2400 0.28 270 20 7 示 例8 4% 4% 4% 400 4000 800 5200 0.18 260 45 9.2 示 例9 0.5% 0.5% 0.5% 250 1500 750 2500 0.3 300 25 8 示 例 10 1% 1% 1% 500 3000 1500 5000 0.25 290 40 9 示 例 11 2% 2% 2% 200 1000 400 1600 0.29 280 18 6.5 示 例 12 4% 4% 4% 400 2000 800 3200 0.26 260 28 7.3 比 較 示 例4 0.2% 2% 10% 500 1000 40000 41500 0.42 260 51 5 比 較 示 例5 0.1% 0.1% 0.1% 50 300 150 500 0.58 380 8 5 比 較 示 例6 4% 4% 4% 400 4000 800 5200 0.18 260 52 - 15 201202329 由於具有尚霧度和大量微粒聚集缺陷，比較示例6不能作為一種細胞 袋(cell pouch)。 由表3和表4的結果可以看出，本發明製造的尼龍薄膜具有較低的摩 擦係數和較低的模數，以及較佳的袋型袋深能力。 【圖式簡單說明】 叙 【主要元件符號說明】 盔Na20 and CaO are used as the inorganic fine particles (4) and the inorganic fine particles (6), and the (four) acid-based, styrene-based or shisha polymer fine particles are used as the organic fine particles (8). These may be combined singly or in combination when preparing the master batch. The masterbatch prepared by using the inorganic fine particles (A), the organic fine particles (8) and the inorganic fine particles (c) preferably has a particle content of 〇 5 to 3 Qwt%. If the particulate content is less than the Q 5 sense, the amount of the master 201202329 material is increased, thereby increasing the difficulty of maintaining the masterbatch quality, and also increasing the cost of processing the masterbatch, and thus increasing the manufacturing cost. On the other hand, if the content of the particles is more than 30% by weight, the dispersibility of the particles is deteriorated, and since the content of the particles is high, it is difficult to produce a masterbatch of uniform quality. Further, the dispersibility of the film t particles is deteriorated, and the number of film particles is difficult to control. Further, the optimum content of the above inorganic fine particles based on the total film content is 1600 to BOOOppm. Further, 100 to 1000 ppm of inorganic fine particles (A), 1000 to 1 ppm of organic fine particles (B), and 500 to 2000 ppm of inorganic fine particles (c) may be contained. If the content of the inorganic fine particles (A) is less than i 〇〇 ppm, even if the content of the organic fine particles (B) having a large size is increased, the bending property is severely deteriorated. On the other hand, if the content of the inorganic fine particles is more than 1000 ppm, the haze of the film is remarkably increased without improving the bending property or the low friction coefficient characteristics and the manufacturing cost. If the content of the organic fine particles (B) is less than i 〇〇〇 ppm, considering the haze, even if a large amount of inorganic fine particles (A) having a large size is supplied, low friction characteristics are difficult to achieve. On the other hand, if the content of the organic fine particles (B) is still 10,000 ppm, the slip property is so high that the bending is difficult, and the haze of the film is remarkably increased, and the manufacturing cost is also increased. > If the content of the inorganic fine particles (C) is less than 5 Å, the printing and adhesion are severely deteriorated. On the other hand, if the content of the inorganic fine particles (C) is more than 2 〇〇〇 ppm, the manufacturing cost is increased without improving the printing and adhesion. The nylon film of the present invention is not limited by nylon 6, and may include a nylon biaxially stretched film. In general, the present invention has a suitable thickness of 5 to 5 () μηη with nylon, and the base resin of the nylon film has a preferred phase impurity of 3 〇 to 36. If the relative viscosity of the base film is less than 3, the physical properties of the nylon film after manufacture are destroyed. On the other hand, if the relative viscosity of the base film is higher than 36, the base resin does not have good flow characteristics at the time of melt extrusion, and the tensile properties are insufficient, which cannot satisfy the desired physical properties. SUMMARY OF THE INVENTION The present invention is directed to a nylon film having a low coefficient of friction and a low modulus, and which has a better effect in the pocket depth of the bag type. [Embodiment] Hereinafter, the present invention will be described in detail by way of specific examples, but the invention is not limited to the following examples. 201202329 The physical properties of the film of the present invention were measured by the following method. 1) Measurement method of friction coefficient. American Society for Testing and Materials (ASTM) D1894 Instrumentation. Friction test device (ToyosejJ^, tr model) Measurement conditions · Measurement of friction coefficient of corona treated surface of nylon film 2) Modulus measurement method. Materials Experiment Association (ASTM) D882 Instrumentation · Young's Tensile Strength Tester 5566 (Instron 5566) Measurement conditions: elongation rate 500mm/min, temperature 2 (TC, relative humidity 65% sample size: width 15mm, length l 〇〇mm Determines the tensile stress to 2% stress after measurement according to the above method. 3) Haze measurement method: American Society for Testing and Materials (ASTM) Di〇〇3 Instrument: Color and color difference meter (Nopon denshoku, 1001DP model) Example 1 As shown in Table 1, '1 wt% of spherical oxide (aspectratio, 1.02) was used as a component of the inorganic fine particles (A), and 5 wt% of polymethylmethacrylate beads (KOLON Diasphere) was used as organic fine particles ( The component of B), and the 2 wt ° /〇 kaolin having irregular block shape as a component of the inorganic fine particles (C), added to the nylon 6 having a relative viscosity of 3 3 based on the total weight of the master batch, and utilized by Twin-screw type extruder at 245 ° C, to prepare a mixed master batch resulting mixture (resulting mixture). Then, according to the contents shown in Table 3, the mixed master batch was mixed into the nylon 6 having a relative viscosity of 3.3. The resulting mixture was extruded at 265 ° C using a circular die, and at the same time, biaxially stretched at a draw ratio of 3 x 3 times in a tubular form, followed by heat setting, whereby a nylon film was produced. Further, aluminum foil was attached to the manufactured film to produce a pouch form, and then the depth of the bag type was measured. The results are reported in Table 3. Examples 2 to 6 Each of the mixed master batches was prepared in the same manner as in Example 1, except that as shown in Table 1, 201202329 controlled particle size and inorganic fine particles (A), organic fine particles (B), and inorganic fine particles (c) Contains and controls the relative viscosity of nylon 6. Subsequently, the mixed masterbatch was mixed into a nylon 6 having a relative viscosity of 3.3, as shown in Table 3. The resulting mixture was extruded at 265 Torr by using a - round tool, and simultaneously biaxially stretched at a draw ratio of 3xj in a tube type, followed by heat setting, whereby a nylon film was produced. In addition, the inscription was attached to the manufactured fine to produce the miscellaneous, and then the depth of the pouch type was measured and recorded in Table 3. °, the results are recorded in Table 3. Example 7 Eight-spherical synthetic zeolite 'as a constituent of inorganic fine particles (Α), based on the total weight percentage of the masterbatch wt% 'mixed into nylon 6 having a relative viscosity of 3 3 as shown in Table 1, so that it is contained as shown in Table 1. The indicated content, and the masterbatch A was prepared using the resulting fly conjugate at 245 t using a twin propeller machine, as in Example 1. The polymethyl (tetra) acid is a bead (K〇LC) N Diasphere), as the organic microparticle (8) S' 'based on the masterbatch _ weight percent pain' is also mixed with a relative viscosity of 3 3 J1 did not 'comprise it as shown in Table 1, and the resulting mixture was used to prepare Masterbatch B, as in Example 1. As a component of the inorganic fine particles (c), the bulky kaolin is also incorporated into the nylon 6 having a relative viscosity of 3 3 as shown in Table ,, so that it contains as shown in Table 1. The content is not, and the resulting mixture is used to prepare the masterbatch c. _ f 'These three prepared masterbatches are mixed into a nylon 6 having a relative viscosity of 3. 3 as shown in Table 1 by a mixture extruded by a circular die, as in the example j, and in a tube type = stretched 'to make nylon _. Further, _ was attached to the formed lap to produce a 敕 type, and then the depth of the pouch type was measured and recorded in Table 3. The results are reported in Table 3. Examples 8 to 12 ages are like the gods!! 7 is manufactured in the same way, except that as shown in Table 1, it is necessary to add (Α), granules (Β) and granules (G) _. This is attached to the shouting (4) production bag type, and then the depth of the bag type is measured and recorded in Table 4. 201202329 The results are recorded in Table 4. Comparative Examples 1 to 6 For each of the comparative examples, each master batch having a content as shown in Table 2 was prepared, and a master batch was used to manufacture a film, as in Example 1. The results are reported in Table 4. Table 1 Preparation method of the master batch (percent (%) represents weight percentage (wt%)) Example content of inorganic fine particles (A) Particle size of inorganic fine particles (A) Content of organic fine particles (Β) Particles of organic fine particles (Β) Content of size inorganic fine particles (C) Particle size of inorganic fine particles (c) Relative viscosity of master batch resin Remarks 1 1% 3μηι 5% 5μιη 2% 0.05μηι 3.3 Mixed masterbatch 2 1% 3μηι 10% 5μηι 2% 0.05μΓη 2.6 Mixed masterbatch 3 5% 3μπι 30% 5μηι 15% 0.05μηι 3.1 Mixed masterbatch 4 1% 2μηι 5% 5μηι 2% Ο.Οδμηι 3.1 Mixed masterbatch 5 1% 5μηι 5% 5μηι 2% 0.05μιη 3.1 Mixed masterbatch 6 5% 5μπι 30% 5μηι 15% 0.2μηι 3.1 Mixed masterbatch three non-7 1% 3μηι 5% 5μηι 2% 0.05μιη 3.3 Mixed masterbatch three non-8 1% 3μηι 10% 5μηι 2% 0.05μιη 2.6 Mixed masterbatch 9 5% 3μπι 30% 5μηι 15% 0.05μηι 3.1 Three unmixed 11 201202329 Masterbatch 10 5% 2μηι 30% 5μιη 15% 0.08μιη 3.1 Three non-mixed Masterbatch 11 1% 5μηι 5% 5μηι 2% 0.05μηι 3.1 Three unmixed masterbatch 12 1% 5μπι 5% 5μιη 2% 0.2μηι 3.1 Three non-mixed masterbatches Table 2 (% (%) means weight percent ( Wt%)) Content of inorganic fine particles (Α) Particle size of inorganic fine particles (Α) Content of organic fine particles (Β) Particle size of organic fine particles (Β) Particle size Content of inorganic fine particles (C) Particle size of inorganic fine particles (c) Relative Viscosity of Resin Remarks 1 0.4% 3μηι 0.4% 5μηι 0.4% 0.05μηι 3.3 Mixed Masterbatch 2 26% 3μηι 2% 5μπι 2% 0.05μιη 2.6 Mixed Masterbatch Comparison 3 5% 5μιη 20% 5μηι 10% 0.3μηι 3.1 Mix Masterbatch Example 4 25% 3μηι 3% 5μηι 40% 0.05μηι 3.3 Non-mixed masterbatch 5 5% 3μηι 30% 5μιη 15% 0.05μηι 2.6 Non-mixed masterbatch 6 1% 5μηι 10% 5μπι 2% 0.3μπι 3.1 Non-mixed mother Material 12 201202329 Table 3 (Percentage (%) means weight percent (Wt°/o)) Master batch input ratio of particles in the film (ppm) Friction coefficient modulus (kg/cm2) Haze pocket depth (mm) Inorganic Granules (A) Organic Microparticles (B) Inorganic Microparticles (C) Total Example 1 3% (Mixed) 300 1500 600 2400 0.28 280 20 6.9 Example 2 4% (Mixed) 400 4000 800 5200 0.18 275 45 9 Example 3 1% (Mixed) 500 3000 1500 5000 0.25 295 40 8.2 Example 4 3% (Mixed) 300 1500 600 2400 0.28 281 25 6.8 Example 5 4% (Mixed) 400 2000 800 3200 0.3 273 30 8 Example 6 1% (Mixed) 500 3000 1500 5000 0.26 295 42 7.8 Comparative example 1 5% (mixed) 200 200 200 600 0.75 260 5 2 Comparison 0.5% (mixed) 1300 100 100 1500 0.6 370 22 3 13 201202329 Example 2 Comparison example 3 0.5% (mixed) 250 1000 500 1750 0.45 320 20 - * The delamination between the aluminum foil and the comparative example 3 occurred in the production of the bag type. Table 4 (% (%) means weight percent (wt%)) 201202329 Masterbatch input ratio of particles in the film (ppm) Friction coefficient modulus (kg/cm2) Haze bag depth (mm) Masterbatch A Masterbatch B Masterbatch C Inorganic microparticles (A) Organic microparticles (B) Inorganic microparticles (C) Total amount example 7 3% 3% 3% 300 1500 600 2400 0.28 270 20 7 Example 8 4% 4% 4% 400 4000 800 5200 0.18 260 45 9.2 Example 9 0.5% 0.5% 0.5% 250 1500 750 2500 0.3 300 25 8 Example 10 1% 1% 1% 500 3000 1500 5000 0.25 290 40 9 Example 11 2% 2% 2% 200 1000 400 1600 0.29 280 18 6.5 Example 12 4% 4% 4% 400 2000 800 3200 0.26 260 28 7.3 Comparison example 4 0.2% 2% 10% 500 1000 40000 41500 0.42 260 51 5 Comparative example 5 0.1% 0.1% 0.1% 50 300 150 500 0.58 380 8 5 Comparative Example 6 4% 4% 4% 400 4000 800 5200 0.18 260 52 - 15 201202329 Comparative Example 6 cannot be used as a cell pouch due to the presence of a haze and a large amount of particle aggregation defects. As can be seen from the results of Tables 3 and 4, the nylon film produced by the present invention has a lower coefficient of friction and a lower modulus, and a better bag-type bag depth. [Simple description of the diagram] [Major component symbol description] Helmet
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