JP5837514B2 - 金属−配位子錯体及び触媒 - Google Patents

金属−配位子錯体及び触媒 Download PDF

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JP5837514B2
JP5837514B2 JP2012553934A JP2012553934A JP5837514B2 JP 5837514 B2 JP5837514 B2 JP 5837514B2 JP 2012553934 A JP2012553934 A JP 2012553934A JP 2012553934 A JP2012553934 A JP 2012553934A JP 5837514 B2 JP5837514 B2 JP 5837514B2
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metal
formula
ligand complex
catalyst
olefin
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JP2013520418A (ja
JP2013520418A5 (enExample
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クロシン イェルジィ
クロシン イェルジィ
フィゲロア ラス
フィゲロア ラス
ピー．フォンテイン フィリップ
ピー．フォンテイン フィリップ
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Dow Global Technologies LLC
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/74—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
    • C08F4/76—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2012553934A 2010-02-19 2011-02-08 金属−配位子錯体及び触媒 Active JP5837514B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US30614710P 2010-02-19 2010-02-19
US61/306,147 2010-02-19
PCT/US2011/024012 WO2011102989A1 (en) 2010-02-19 2011-02-08 Metal-ligand complexes and catalysts

Publications (3)

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JP2013520418A JP2013520418A (ja) 2013-06-06
JP2013520418A5 JP2013520418A5 (enExample) 2014-03-27
JP5837514B2 true JP5837514B2 (ja) 2015-12-24

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JP2012553934A Active JP5837514B2 (ja) 2010-02-19 2011-02-08 金属−配位子錯体及び触媒

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US (1) US8202954B2 (enExample)
EP (1) EP2536735B1 (enExample)
JP (1) JP5837514B2 (enExample)
KR (1) KR101827023B1 (enExample)
CN (1) CN102822180B (enExample)
BR (1) BR112012020718A2 (enExample)
ES (1) ES2691727T3 (enExample)
WO (1) WO2011102989A1 (enExample)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014139861A1 (en) 2013-03-11 2014-09-18 Universität Bayreuth Complexes for the catalytic oligomerization of olefins
EP2801579B1 (en) * 2013-05-08 2016-10-19 Arlanxeo Netherlands B.V. Metal complex with a Lewis base ligand
KR102322501B1 (ko) * 2013-12-19 2021-11-05 다우 글로벌 테크놀로지스 엘엘씨 금속-리간드 착물, 이것으로부터 유도된 올레핀 중합 촉매, 및 그 촉매를 이용하는 올레핀 중합 방법
CN105732406A (zh) * 2014-12-10 2016-07-06 中国科学技术大学 含环庚三烯结构的铝化合物催化剂、合成及其用途
ES2946762T3 (es) * 2017-03-15 2023-07-25 Dow Global Technologies Llc Sistema de catalizador para la formación de copolímero multibloque
US11078224B2 (en) 2017-04-07 2021-08-03 Applied Materials, Inc. Precursors for the atomic layer deposition of transition metals and methods of use
BR112020019180A2 (pt) 2018-03-19 2021-01-05 Dow Global Technologies Llc Compostos organometálicos terminados em silício e processos para preparar os mesmos
BR112020019193A2 (pt) 2018-03-19 2021-01-05 Dow Global Technologies Llc Compostos organometálicos terminados em silício e processos para preparar os mesmos
US20210017311A1 (en) 2018-03-19 2021-01-21 Dow Silicones Corporation Silicon-terminated telechelic polyolefin compositions and processes for preparing the same
TW201938569A (zh) 2018-03-19 2019-10-01 美商陶氏全球科技有限責任公司 用基於矽烷基之官能化試劑官能化有機金屬化合物之方法及由此製備之矽烷基官能化化合物
EP3774035B1 (en) 2018-03-30 2025-05-21 Dow Global Technologies LLC Olefin polymerization activators
JP7364585B2 (ja) 2018-03-30 2023-10-18 ダウ グローバル テクノロジーズ エルエルシー オレフィン重合のための二核助触媒としての高溶解性ビスホウ酸
WO2019191539A1 (en) 2018-03-30 2019-10-03 Dow Global Technologies Llc Highly soluble alkyl substituted carbenium borate as co-catalysts for olefin polymerizations
JP2021519362A (ja) 2018-03-30 2021-08-10 ダウ グローバル テクノロジーズ エルエルシー オレフィン重合活性化剤
US11542350B2 (en) 2018-03-30 2023-01-03 Dow Global Technologies Llc Binuclear olefin polymerization activators
CN113498414A (zh) 2018-12-28 2021-10-12 陶氏环球技术有限责任公司 包括遥爪聚烯烃的可固化组合物
CN113412264B (zh) 2018-12-28 2024-06-25 陶氏环球技术有限责任公司 有机金属链转移剂
SG11202107051UA (en) 2018-12-28 2021-07-29 Dow Global Technologies Llc Telechelic polyolefins and processes for preparing the same
CN113454091A (zh) 2018-12-28 2021-09-28 陶氏环球技术有限责任公司 包括不饱和聚烯烃的可固化组合物
EP3902867A4 (en) 2018-12-28 2022-09-14 Dow Global Technologies LLC CURABLE COMPOSITIONS CONTAINING UNSATURATED POLYOLEFINS
SG11202110448UA (en) 2019-03-28 2021-10-28 Dow Global Technologies Llc Anionic group iii complexes as weakly coordinating anions for olefin polymerization catalyst activators
BR112021021366A2 (pt) 2019-04-30 2022-03-15 Dow Global Technologies Llc Processo de polimerização
WO2020243241A1 (en) 2019-05-31 2020-12-03 Dow Global Technologies Llc Monobindentate, bis-bidentate, and tetrabidentate guanidine group iv transition metal olefin copolymerization catalysts
US20230399450A1 (en) 2020-11-10 2023-12-14 Dow Global Technologies Llc Preparation of non-polar-polar block copolymers via vinyl-terminated polyolefins
MX2023005126A (es) 2020-11-10 2023-08-18 Dow Global Technologies Llc Preparación de aditivos de copolímeros en bloque de poliolefina poliacrilato para el aumento de energía superficial de polietileno.
JP2022158997A (ja) * 2021-03-31 2022-10-17 三井化学株式会社 遷移金属化合物、オレフィン重合用触媒およびオレフィン重合体の製造方法
BR112023022572A2 (pt) 2021-05-12 2024-01-16 Dow Global Technologies Llc Processo para formar uma composição de reologia modificada, composição de reologia modificada, e, artigo
EP4399232A2 (en) 2021-09-10 2024-07-17 Dow Global Technologies LLC Borate cocatalysts for polyolefin production
CN117999292A (zh) 2021-09-10 2024-05-07 陶氏环球技术有限责任公司 用于烯烃聚合的烃溶性硼酸盐助催化剂
CN115301291B (zh) * 2022-08-08 2024-04-09 万华化学集团股份有限公司 一种异核双金属配合物自组装型mcm-56分子筛催化剂和制备方法及应用

Family Cites Families (74)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7163907B1 (en) 1987-01-30 2007-01-16 Exxonmobil Chemical Patents Inc. Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
JP2545006B2 (ja) 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5350723A (en) 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
WO1994000500A1 (en) 1992-06-26 1994-01-06 Exxon Chemical Patents Inc. Solution phase polymerization process utilizing metallocene catalyst with production of olefin polymers
JP3453160B2 (ja) * 1993-03-12 2003-10-06 出光石油化学株式会社 ポリオレフィンの製造方法
US5372682A (en) 1993-06-24 1994-12-13 The Dow Chemical Company Electrochemical preparation of addition polymerization catalysts
US5470993A (en) 1993-06-24 1995-11-28 The Dow Chemical Company Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom
US5625087A (en) 1994-09-12 1997-04-29 The Dow Chemical Company Silylium cationic polymerization activators for metallocene complexes
PL322446A1 (en) 1995-01-24 1998-02-02 Du Pont Alpha-olefines and olefinic polymers and methods of obtaining them
JP3990458B2 (ja) 1996-03-27 2007-10-10 ダウ グローバル テクノロジーズ インコーポレーテッド 溶解度の高いオレフィン重合触媒活性剤
JP2000517349A (ja) 1996-03-27 2000-12-26 ザ ダウ ケミカル カンパニー 分散した触媒活性剤による溶液重合法
JP4050802B2 (ja) * 1996-08-02 2008-02-20 シチズン電子株式会社 カラー表示装置
WO1998006727A1 (en) 1996-08-08 1998-02-19 The Dow Chemical Company 3-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process
US6015868A (en) 1996-10-03 2000-01-18 The Dow Chemical Company Substituted indenyl containing metal complexes and olefin polymerization process
US5783512A (en) 1996-12-18 1998-07-21 The Dow Chemical Company Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same
US5965756A (en) 1996-12-19 1999-10-12 The Dow Chemical Company Fused ring substituted indenyl metal complexes and polymerization process
RU2186073C2 (ru) 1996-12-19 2002-07-27 Дзе Дау Кемикал Компани Комплексы металлов, содержащие лиганды 3-арилзамещенного инденила, катализатор полимеризации олефинов и способ полимеризации
TR199901645T2 (xx) * 1997-01-14 2000-04-21 E.I. Du Pont De Nemours And Company Olefinlerin polimerizasyonu.
US6103657A (en) 1997-07-02 2000-08-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
US6096676A (en) * 1997-07-02 2000-08-01 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
JPH1160624A (ja) * 1997-08-19 1999-03-02 Tosoh Corp オレフィン重合用触媒およびポリオレフィンの製造方法
US6150297A (en) 1997-09-15 2000-11-21 The Dow Chemical Company Cyclopentaphenanthrenyl metal complexes and polymerization process
CA2215444C (en) * 1997-09-15 2005-08-02 Stephen John Brown Catalyst having a ketimide ligand
US6696379B1 (en) 1997-09-19 2004-02-24 The Dow Chemical Company Supported modified alumoxane catalyst activator
JPH11236409A (ja) * 1998-02-20 1999-08-31 Nippon Polyolefin Kk オレフィン重合用触媒成分、オレフィン重合用触媒及びポリオレフィンの製造方法
CA2243726C (en) * 1998-07-21 2006-12-12 Nova Chemicals Ltd. Cyclopentadienyl/phosphinimine catalyst with one and only one activatable ligand
JP4501872B2 (ja) * 1998-09-09 2010-07-14 住友化学株式会社 変性アルミニウムオキシ化合物、付加重合用触媒成分、付加重合用触媒、オレフィン重合体の製造方法、アルケニル芳香族炭化水素重合体の製造方法、および共重合体
US6620953B1 (en) * 1998-11-25 2003-09-16 Bassell Polyolefine Gmbh Method for producing monoaryloxy-ansa-metallocenes
DE60001558T2 (de) 1999-05-13 2004-01-08 Dow Global Technologies, Inc., Midland Di- und tri-heteroatom-substituierte metall-indenylkomplexe
US6340730B1 (en) * 1999-12-06 2002-01-22 Univation Technologies, Llc Multiple catalyst system
US6825295B2 (en) 1999-12-10 2004-11-30 Dow Global Technologies Inc. Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
JP4790184B2 (ja) 1999-12-10 2011-10-12 ダウ、グローバル、テクノロジーズ、リミテッド、ライアビリティー、カンパニー 置換４族金属錯体、触媒及びオレフィン重合法
US6696380B2 (en) * 2000-01-12 2004-02-24 Darryl Stephen Williams Procatalysts, catalyst systems, and use in olefin polymerization
US20020034829A1 (en) * 2000-03-24 2002-03-21 Keith Hall Combinatorial synthesis and analysis of metal-ligand compositions using soluble metal precursors
CA2411712C (en) 2000-06-30 2011-01-25 Dow Global Technologies Inc. Polycyclic, fused ring compounds, metal complexes and polymerization process
US6900321B2 (en) 2000-11-07 2005-05-31 Symyx Technologies, Inc. Substituted pyridyl amine complexes, and catalysts
WO2002053603A2 (en) * 2000-12-28 2002-07-11 Univation Technologies, Llc Polymerization catalyst system, polymerization process and polymer therefrom
CN1208357C (zh) * 2001-03-05 2005-06-29 斯蒂茨丁荷兰聚合物学会 烯烃聚合催化剂组分和催化剂体系和使用这类催化剂体系的聚合方法
CA2446116A1 (en) 2001-05-14 2002-11-21 Dow Global Technologies Inc. 3-aryl-substituted cyclopentadienyl metal complexes and polymerization process
KR100440480B1 (ko) 2001-08-31 2004-07-14 주식회사 엘지화학 폴리올레핀 제조용 촉매 및 이를 이용한 폴리올레핀의제조방법
US6960635B2 (en) 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
US6919467B2 (en) * 2001-12-18 2005-07-19 Univation Technologies, Llc Imino-amide catalyst compositions for the polymerization of olefins
US7199255B2 (en) * 2001-12-18 2007-04-03 Univation Technologies, Llc Imino-amide catalysts for olefin polymerization
ATE403684T1 (de) 2002-03-14 2008-08-15 Dow Global Technologies Inc Metallkomplexe mit substituierten indenylliganden und polymerisationsverfahren
US20050010039A1 (en) 2002-03-14 2005-01-13 Graf David D Polycyclic fused heteroring compounds metal complexes and polymerization process
WO2003091262A1 (en) 2002-04-24 2003-11-06 Symyx Technologies, Inc. Bridged bi-aromatic ligands, complexes, catalysts and processes for polymerizing and poymers therefrom
JP2005539060A (ja) 2002-09-12 2005-12-22 ダウ・グローバル・テクノロジーズ・インコーポレイテッド 金属錯体の製造方法
WO2004074333A2 (en) 2003-02-18 2004-09-02 Dow Global Technologies Inc. Process for homo- or copolymerizationof conjugated olefines
US6953764B2 (en) 2003-05-02 2005-10-11 Dow Global Technologies Inc. High activity olefin polymerization catalyst and process
JP5086637B2 (ja) * 2003-07-09 2012-11-28 ランクセス エラストマーズ ビー．ブイ． エチレン、α−オレフィン、およびビニルノルボルネンのモノマー単位を含むポリマーの製造方法
RU2386646C2 (ru) 2004-01-22 2010-04-20 Дау Глобал Текнолоджиз Инк. Функционализированные эластомерные композиции
CN1976965B (zh) 2004-03-17 2012-10-10 陶氏环球技术有限责任公司 用于形成乙烯多嵌段共聚物的包含梭移剂的催化剂组合物
RU2359979C2 (ru) 2004-03-17 2009-06-27 Дау Глобал Текнолоджиз Инк. Композиция катализатора, содержащая агент челночного переноса цепи для образования сополимера этилена
US7608668B2 (en) 2004-03-17 2009-10-27 Dow Global Technologies Inc. Ethylene/α-olefins block interpolymers
EP1725571A1 (de) 2004-03-17 2006-11-29 Georg-August-Universität Göttingen Sauerstoffverbrückter bimetallischer komplex, dessen herstellung und verwendung für die polymerisations-katalyse
EP1730205B1 (en) * 2004-03-17 2012-09-26 Lanxess Elastomers B.V. Polimerization catalyst comprising an amidine ligand
NZ549262A (en) 2004-03-17 2010-08-27 Dow Global Technologies Inc Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
US7355089B2 (en) 2004-03-17 2008-04-08 Dow Global Technologies Inc. Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates
DE602005026531D1 (de) 2004-06-22 2011-04-07 Dsm Ip Assets Bv Verfahren zur herstellung eines polymers
ZA200708785B (en) 2005-03-17 2009-01-28 Dow Global Technologies Inc Catalyst composition comprising shuttling agent for regio-irregular multi-block copolymer formation
US7067686B1 (en) 2005-07-21 2006-06-27 Univation Technologies, Llc Synthesis of benzyl-metal compounds
US7301040B2 (en) * 2005-08-18 2007-11-27 Fina Technology, Inc. Bidentate catalyst for olefin polymerization, methods of forming such and products therefrom
MY157940A (en) 2005-09-15 2016-08-15 Dow Global Technologies Inc Catalytic olefin block copolymers with controlled block sequence distribution
BR122017016853B1 (pt) 2005-09-15 2018-05-15 Dow Global Technologies Inc. Processo para a polimerização de um ou mais monômeros polimerizáveis por adição
BRPI0617042B1 (pt) 2005-09-15 2018-05-15 Dow Global Technologies Inc. Processo para preparar um polímero ramificado, processo para preparar um copolímero em pseudo-bloco multi-ramificado e polímero em pseudo-bloco ramificado
US8557921B2 (en) 2006-08-25 2013-10-15 Dow Global Technologies Llc Production of meta-block copolymers by polymer segment interchange
BRPI0812643B1 (pt) 2007-07-13 2019-01-15 Dow Global Technologies Inc interpolímero de etileno/a-olefina
US7947793B2 (en) 2008-01-30 2011-05-24 Dow Global Technologies Llc Ethylene/α-olefin block copolymers
US8372927B2 (en) * 2008-08-21 2013-02-12 Dow Global Technologies, Llc Metal-ligand complexes and catalysts
SG10201702989VA (en) * 2010-02-19 2017-05-30 Dow Global Technologies Llc Process for polymerizing an olefin monomer and catalyst therefor

Also Published As

Publication number Publication date
KR20130008561A (ko) 2013-01-22
CN102822180A (zh) 2012-12-12
KR101827023B1 (ko) 2018-02-07
ES2691727T3 (es) 2018-11-28
US8202954B2 (en) 2012-06-19
EP2536735A1 (en) 2012-12-26
EP2536735B1 (en) 2018-08-01
JP2013520418A (ja) 2013-06-06
US20110207902A1 (en) 2011-08-25
CN102822180B (zh) 2016-06-15
BR112012020718A2 (pt) 2016-04-26
WO2011102989A1 (en) 2011-08-25

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