JP5773687B2 - 海水排煙脱硫システムおよび発電システム - Google Patents
海水排煙脱硫システムおよび発電システム Download PDFInfo
- Publication number
- JP5773687B2 JP5773687B2 JP2011042962A JP2011042962A JP5773687B2 JP 5773687 B2 JP5773687 B2 JP 5773687B2 JP 2011042962 A JP2011042962 A JP 2011042962A JP 2011042962 A JP2011042962 A JP 2011042962A JP 5773687 B2 JP5773687 B2 JP 5773687B2
- Authority
- JP
- Japan
- Prior art keywords
- seawater
- flue gas
- gas desulfurization
- surplus
- exhaust gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000013535 sea water Substances 0.000 title claims description 321
- 238000006477 desulfuration reaction Methods 0.000 title claims description 157
- 230000023556 desulfurization Effects 0.000 title claims description 157
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims description 118
- 239000003546 flue gas Substances 0.000 title claims description 118
- 238000010248 power generation Methods 0.000 title claims description 13
- 239000007789 gas Substances 0.000 claims description 96
- 238000010521 absorption reaction Methods 0.000 claims description 83
- 238000002156 mixing Methods 0.000 claims description 44
- 238000010790 dilution Methods 0.000 claims description 43
- 239000012895 dilution Substances 0.000 claims description 43
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 42
- 229910052717 sulfur Inorganic materials 0.000 claims description 42
- 239000011593 sulfur Substances 0.000 claims description 42
- 238000007254 oxidation reaction Methods 0.000 claims description 28
- 230000003647 oxidation Effects 0.000 claims description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 239000007788 liquid Substances 0.000 claims description 16
- 238000011084 recovery Methods 0.000 claims description 15
- 239000007921 spray Substances 0.000 claims description 12
- 239000000428 dust Substances 0.000 claims description 10
- 238000007599 discharging Methods 0.000 claims 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 9
- 238000005273 aeration Methods 0.000 description 7
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 238000010586 diagram Methods 0.000 description 6
- 230000001590 oxidative effect Effects 0.000 description 6
- 239000000446 fuel Substances 0.000 description 5
- 238000007865 diluting Methods 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 230000003009 desulfurizing effect Effects 0.000 description 2
- -1 hydrogen ions Chemical class 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229910052815 sulfur oxide Inorganic materials 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000006114 decarboxylation reaction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000010742 number 1 fuel oil Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/20—Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/74—Treatment of water, waste water, or sewage by oxidation with air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K9/00—Plants characterised by condensers arranged or modified to co-operate with the engines
- F01K9/003—Plants characterised by condensers arranged or modified to co-operate with the engines condenser cooling circuits
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B1/00—Methods of steam generation characterised by form of heating method
- F22B1/02—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
- F22B1/18—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J15/00—Arrangements of devices for treating smoke or fumes
- F23J15/02—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
- F23J15/04—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material using washing fluids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/10—Inorganic absorbents
- B01D2252/103—Water
- B01D2252/1035—Sea water
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/08—Seawater, e.g. for desalination
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/18—Nature of the water, waste water, sewage or sludge to be treated from the purification of gaseous effluents
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2219/00—Treatment devices
- F23J2219/40—Sorption with wet devices, e.g. scrubbers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2900/00—Special arrangements for conducting or purifying combustion fumes; Treatment of fumes or ashes
- F23J2900/15041—Means for absorbing SOx using seawater
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Combustion & Propulsion (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Sustainable Energy (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Sustainable Development (AREA)
- Biomedical Technology (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Treating Waste Gases (AREA)
- Chimneys And Flues (AREA)
- Gas Separation By Absorption (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011042962A JP5773687B2 (ja) | 2011-02-28 | 2011-02-28 | 海水排煙脱硫システムおよび発電システム |
| PCT/JP2011/069148 WO2012117586A1 (ja) | 2011-02-28 | 2011-08-25 | 海水排煙脱硫システムおよび発電システム |
| CN201180061109.0A CN103282101B (zh) | 2011-02-28 | 2011-08-25 | 海水排烟脱硫系统及发电系统 |
| TW100143573A TWI482657B (zh) | 2011-02-28 | 2011-11-28 | Seawater desulfurization system and power generation system |
| CL2013001879A CL2013001879A1 (es) | 2011-02-28 | 2013-06-25 | Sistema de desulfurizacion de gas de combustion de agua de mar que comprende una unidad de absorcion de desulfurizacion de gas de combustion, una pileta de mezcla de dilucion dispuesta en un lado aguas abajo de dicha unidad de absorcion, una linea de abastecimiento de agua de mar, una cañeria de derivacion de exceso de agua de mar y una valvula de control dispuesta en dicha cañeria de derivacion; sistema de generacion de energia |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011042962A JP5773687B2 (ja) | 2011-02-28 | 2011-02-28 | 海水排煙脱硫システムおよび発電システム |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012179521A JP2012179521A (ja) | 2012-09-20 |
| JP2012179521A5 JP2012179521A5 (enExample) | 2013-12-26 |
| JP5773687B2 true JP5773687B2 (ja) | 2015-09-02 |
Family
ID=46757540
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011042962A Expired - Fee Related JP5773687B2 (ja) | 2011-02-28 | 2011-02-28 | 海水排煙脱硫システムおよび発電システム |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP5773687B2 (enExample) |
| CN (1) | CN103282101B (enExample) |
| CL (1) | CL2013001879A1 (enExample) |
| TW (1) | TWI482657B (enExample) |
| WO (1) | WO2012117586A1 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014098120A1 (ja) * | 2012-12-19 | 2014-06-26 | 富士電機株式会社 | 排ガス浄化装置 |
| WO2014119513A1 (ja) * | 2013-01-29 | 2014-08-07 | 富士電機株式会社 | スクラバの海水量制御装置、スクラバの海水量制御方法、アルカリ量制御装置及びアルカリ量制御方法 |
| JP2014233702A (ja) * | 2013-06-04 | 2014-12-15 | 三菱重工業株式会社 | 海水脱硫装置及び海水脱硫システム |
| JP6302191B2 (ja) * | 2013-09-02 | 2018-03-28 | 三菱日立パワーシステムズ株式会社 | 発電システム |
| EP3170546A4 (en) * | 2014-07-18 | 2018-01-17 | Fuji Electric Co., Ltd. | Seawater amount control apparatus for scrubber, seawater amount control method for scrubber and alkali amount control apparatus |
| CN104162361A (zh) * | 2014-07-29 | 2014-11-26 | 江苏南极机械有限责任公司 | 一种利用海水吸收净化柴油机尾气中so2的装置及吸收方法 |
| EP3189883B1 (en) | 2014-09-02 | 2019-09-04 | Fuji Electric Co., Ltd. | Exhaust gas treatment device and waste water treatment method for exhaust gas treatment device |
| JP6632452B2 (ja) * | 2016-03-31 | 2020-01-22 | 三菱日立パワーシステムズ株式会社 | 充填塔用の充填物及び海水脱硫装置 |
| CN106076066A (zh) * | 2016-06-11 | 2016-11-09 | 彭斯干 | 海水式碳捕集封存方法及装置 |
| KR102145718B1 (ko) * | 2017-03-24 | 2020-08-19 | 미츠비시 조우센 가부시키가이샤 | 선박용 탈황 장치의 배수 시스템 |
| KR20200129186A (ko) * | 2017-03-28 | 2020-11-17 | 미츠비시 파워 가부시키가이샤 | 선박용 탈황 장치 및 선박 |
| KR101918663B1 (ko) | 2018-04-18 | 2018-11-14 | 주식회사 지스코 | 발전시스템 |
| CN112452126B (zh) * | 2020-11-25 | 2025-01-21 | 南通电力设计院有限公司 | 一种用于火力发电的气体脱硫处理系统 |
| CN113198294B (zh) * | 2021-05-21 | 2021-11-19 | 华能国际电力股份有限公司大连电厂 | 一种海水脱硫控制方法和设备 |
| CN113740197B (zh) * | 2021-06-29 | 2025-02-14 | 西安热工研究院有限公司 | 一种烟气海水脱硫装置的除雾器性能评估系统及方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11244646A (ja) * | 1998-03-05 | 1999-09-14 | Ishikawajima Harima Heavy Ind Co Ltd | 排煙脱硫装置の吸収剤スラリー流量制御方法及び装置 |
| JP4381064B2 (ja) * | 2003-08-26 | 2009-12-09 | 三菱重工業株式会社 | 排ガス処理装置および処理方法 |
| JP5259964B2 (ja) * | 2007-02-28 | 2013-08-07 | 三菱重工業株式会社 | 海水排煙脱硫システム |
| WO2009149603A1 (zh) * | 2008-06-13 | 2009-12-17 | Peng Sigan | 海船排烟脱硫方法及装置 |
| JP5231957B2 (ja) * | 2008-11-27 | 2013-07-10 | バブコック日立株式会社 | 湿式脱硫装置 |
-
2011
- 2011-02-28 JP JP2011042962A patent/JP5773687B2/ja not_active Expired - Fee Related
- 2011-08-25 WO PCT/JP2011/069148 patent/WO2012117586A1/ja not_active Ceased
- 2011-08-25 CN CN201180061109.0A patent/CN103282101B/zh not_active Expired - Fee Related
- 2011-11-28 TW TW100143573A patent/TWI482657B/zh not_active IP Right Cessation
-
2013
- 2013-06-25 CL CL2013001879A patent/CL2013001879A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP2012179521A (ja) | 2012-09-20 |
| TW201238644A (en) | 2012-10-01 |
| CL2013001879A1 (es) | 2013-11-29 |
| TWI482657B (zh) | 2015-05-01 |
| CN103282101A (zh) | 2013-09-04 |
| CN103282101B (zh) | 2015-06-03 |
| WO2012117586A1 (ja) | 2012-09-07 |
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