TWI482657B - Seawater desulfurization system and power generation system - Google Patents
Seawater desulfurization system and power generation system Download PDFInfo
- Publication number
- TWI482657B TWI482657B TW100143573A TW100143573A TWI482657B TW I482657 B TWI482657 B TW I482657B TW 100143573 A TW100143573 A TW 100143573A TW 100143573 A TW100143573 A TW 100143573A TW I482657 B TWI482657 B TW I482657B
- Authority
- TW
- Taiwan
- Prior art keywords
- seawater
- exhaust gas
- flue gas
- absorption tower
- remaining
- Prior art date
Links
- 239000013535 sea water Substances 0.000 title claims description 305
- 238000006477 desulfuration reaction Methods 0.000 title claims description 158
- 230000023556 desulfurization Effects 0.000 title claims description 158
- 238000010248 power generation Methods 0.000 title claims description 13
- 239000007789 gas Substances 0.000 claims description 121
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 86
- 239000003546 flue gas Substances 0.000 claims description 86
- 238000010521 absorption reaction Methods 0.000 claims description 76
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 42
- 238000010790 dilution Methods 0.000 claims description 41
- 239000012895 dilution Substances 0.000 claims description 41
- 238000002156 mixing Methods 0.000 claims description 40
- 229910052717 sulfur Inorganic materials 0.000 claims description 36
- 239000011593 sulfur Substances 0.000 claims description 36
- 238000007254 oxidation reaction Methods 0.000 claims description 31
- 230000003647 oxidation Effects 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 239000007921 spray Substances 0.000 claims description 17
- 239000007788 liquid Substances 0.000 claims description 15
- 238000010926 purge Methods 0.000 claims description 10
- 238000011084 recovery Methods 0.000 claims description 10
- 239000000428 dust Substances 0.000 claims description 7
- 239000006096 absorbing agent Substances 0.000 claims description 3
- 239000002817 coal dust Substances 0.000 claims description 3
- 239000000779 smoke Substances 0.000 claims description 3
- 238000007865 diluting Methods 0.000 claims description 2
- 238000003303 reheating Methods 0.000 claims description 2
- 230000003009 desulfurizing effect Effects 0.000 claims 1
- 230000001105 regulatory effect Effects 0.000 description 9
- 239000000446 fuel Substances 0.000 description 7
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 7
- 229910052815 sulfur oxide Inorganic materials 0.000 description 7
- 239000005864 Sulphur Substances 0.000 description 6
- 238000005273 aeration Methods 0.000 description 6
- 230000001590 oxidative effect Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 230000004069 differentiation Effects 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- -1 hydrogen ions Chemical class 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 238000009423 ventilation Methods 0.000 description 2
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000001263 FEMA 3042 Substances 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229940079826 hydrogen sulfite Drugs 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000010742 number 1 fuel oil Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/20—Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/74—Treatment of water, waste water, or sewage by oxidation with air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K9/00—Plants characterised by condensers arranged or modified to co-operate with the engines
- F01K9/003—Plants characterised by condensers arranged or modified to co-operate with the engines condenser cooling circuits
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B1/00—Methods of steam generation characterised by form of heating method
- F22B1/02—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
- F22B1/18—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J15/00—Arrangements of devices for treating smoke or fumes
- F23J15/02—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
- F23J15/04—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material using washing fluids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/10—Inorganic absorbents
- B01D2252/103—Water
- B01D2252/1035—Sea water
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/08—Seawater, e.g. for desalination
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/18—Nature of the water, waste water, sewage or sludge to be treated from the purification of gaseous effluents
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2219/00—Treatment devices
- F23J2219/40—Sorption with wet devices, e.g. scrubbers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2900/00—Special arrangements for conducting or purifying combustion fumes; Treatment of fumes or ashes
- F23J2900/15041—Means for absorbing SOx using seawater
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Hydrology & Water Resources (AREA)
- Combustion & Propulsion (AREA)
- Organic Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Physics & Mathematics (AREA)
- General Chemical & Material Sciences (AREA)
- Sustainable Energy (AREA)
- Sustainable Development (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- Thermal Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
- Chimneys And Flues (AREA)
- Gas Separation By Absorption (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011042962A JP5773687B2 (ja) | 2011-02-28 | 2011-02-28 | 海水排煙脱硫システムおよび発電システム |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201238644A TW201238644A (en) | 2012-10-01 |
| TWI482657B true TWI482657B (zh) | 2015-05-01 |
Family
ID=46757540
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW100143573A TWI482657B (zh) | 2011-02-28 | 2011-11-28 | Seawater desulfurization system and power generation system |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP5773687B2 (enExample) |
| CN (1) | CN103282101B (enExample) |
| CL (1) | CL2013001879A1 (enExample) |
| TW (1) | TWI482657B (enExample) |
| WO (1) | WO2012117586A1 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5892265B2 (ja) * | 2012-12-19 | 2016-03-23 | 富士電機株式会社 | 排ガス浄化装置 |
| EP2952243B1 (en) | 2013-01-29 | 2018-09-19 | Fuji Electric Co., Ltd. | Seawater quantity controller for scrubber, seawater quantity control method for scrubber, alkali quantity controller, and alkali quantity control method |
| JP2014233702A (ja) * | 2013-06-04 | 2014-12-15 | 三菱重工業株式会社 | 海水脱硫装置及び海水脱硫システム |
| JP6302191B2 (ja) * | 2013-09-02 | 2018-03-28 | 三菱日立パワーシステムズ株式会社 | 発電システム |
| KR101740678B1 (ko) * | 2014-07-18 | 2017-05-26 | 후지 덴키 가부시키가이샤 | 스크러버의 해수량 제어장치, 스크러버의 해수량 제어방법 및 알칼리량 제어장치 |
| CN104162361A (zh) * | 2014-07-29 | 2014-11-26 | 江苏南极机械有限责任公司 | 一种利用海水吸收净化柴油机尾气中so2的装置及吸收方法 |
| EP3189883B1 (en) * | 2014-09-02 | 2019-09-04 | Fuji Electric Co., Ltd. | Exhaust gas treatment device and waste water treatment method for exhaust gas treatment device |
| JP6632452B2 (ja) * | 2016-03-31 | 2020-01-22 | 三菱日立パワーシステムズ株式会社 | 充填塔用の充填物及び海水脱硫装置 |
| CN106076066A (zh) * | 2016-06-11 | 2016-11-09 | 彭斯干 | 海水式碳捕集封存方法及装置 |
| CN109843714B (zh) * | 2017-03-24 | 2021-09-24 | 三菱造船株式会社 | 船舶用脱硫装置的排水系统 |
| CN112373667A (zh) * | 2017-03-28 | 2021-02-19 | 三菱动力株式会社 | 船舶用脱硫装置及船舶 |
| KR101918663B1 (ko) | 2018-04-18 | 2018-11-14 | 주식회사 지스코 | 발전시스템 |
| CN112452126B (zh) * | 2020-11-25 | 2025-01-21 | 南通电力设计院有限公司 | 一种用于火力发电的气体脱硫处理系统 |
| CN113198294B (zh) * | 2021-05-21 | 2021-11-19 | 华能国际电力股份有限公司大连电厂 | 一种海水脱硫控制方法和设备 |
| CN113740197B (zh) * | 2021-06-29 | 2025-02-14 | 西安热工研究院有限公司 | 一种烟气海水脱硫装置的除雾器性能评估系统及方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11244646A (ja) * | 1998-03-05 | 1999-09-14 | Ishikawajima Harima Heavy Ind Co Ltd | 排煙脱硫装置の吸収剤スラリー流量制御方法及び装置 |
| JP2005066505A (ja) * | 2003-08-26 | 2005-03-17 | Mitsubishi Heavy Ind Ltd | 排ガス処理装置および処理方法 |
| JP2008207149A (ja) * | 2007-02-28 | 2008-09-11 | Mitsubishi Heavy Ind Ltd | 海水排煙脱硫システム |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102112210B (zh) * | 2008-06-13 | 2014-03-26 | 武汉晶源环境工程有限公司 | 海船排烟脱硫方法及装置 |
| JP5231957B2 (ja) * | 2008-11-27 | 2013-07-10 | バブコック日立株式会社 | 湿式脱硫装置 |
-
2011
- 2011-02-28 JP JP2011042962A patent/JP5773687B2/ja not_active Expired - Fee Related
- 2011-08-25 WO PCT/JP2011/069148 patent/WO2012117586A1/ja not_active Ceased
- 2011-08-25 CN CN201180061109.0A patent/CN103282101B/zh not_active Expired - Fee Related
- 2011-11-28 TW TW100143573A patent/TWI482657B/zh not_active IP Right Cessation
-
2013
- 2013-06-25 CL CL2013001879A patent/CL2013001879A1/es unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11244646A (ja) * | 1998-03-05 | 1999-09-14 | Ishikawajima Harima Heavy Ind Co Ltd | 排煙脱硫装置の吸収剤スラリー流量制御方法及び装置 |
| JP2005066505A (ja) * | 2003-08-26 | 2005-03-17 | Mitsubishi Heavy Ind Ltd | 排ガス処理装置および処理方法 |
| JP2008207149A (ja) * | 2007-02-28 | 2008-09-11 | Mitsubishi Heavy Ind Ltd | 海水排煙脱硫システム |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103282101B (zh) | 2015-06-03 |
| JP5773687B2 (ja) | 2015-09-02 |
| TW201238644A (en) | 2012-10-01 |
| JP2012179521A (ja) | 2012-09-20 |
| CL2013001879A1 (es) | 2013-11-29 |
| CN103282101A (zh) | 2013-09-04 |
| WO2012117586A1 (ja) | 2012-09-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |