JP5756746B2 - ポリウレタン増粘剤 - Google Patents
ポリウレタン増粘剤 Download PDFInfo
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- JP5756746B2 JP5756746B2 JP2011507900A JP2011507900A JP5756746B2 JP 5756746 B2 JP5756746 B2 JP 5756746B2 JP 2011507900 A JP2011507900 A JP 2011507900A JP 2011507900 A JP2011507900 A JP 2011507900A JP 5756746 B2 JP5756746 B2 JP 5756746B2
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- Prior art keywords
- polyurethane
- section
- preparation
- hydrophilic
- sections
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004814 polyurethane Substances 0.000 title claims description 273
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- 239000000203 mixture Substances 0.000 claims description 81
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- 239000004721 Polyphenylene oxide Substances 0.000 claims description 49
- 230000002209 hydrophobic effect Effects 0.000 claims description 49
- 229920000570 polyether Polymers 0.000 claims description 49
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- 150000003839 salts Chemical class 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 33
- 125000005442 diisocyanate group Chemical group 0.000 claims description 27
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- -1 zinc carboxylate Chemical class 0.000 claims description 24
- 125000000217 alkyl group Chemical group 0.000 claims description 23
- 125000004432 carbon atom Chemical group C* 0.000 claims description 21
- 230000008569 process Effects 0.000 claims description 21
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- 125000001931 aliphatic group Chemical group 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 13
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- 125000004429 atom Chemical group 0.000 description 4
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- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000008040 ionic compounds Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- YDLYQMBWCWFRAI-UHFFFAOYSA-N n-Hexatriacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC YDLYQMBWCWFRAI-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 239000006254 rheological additive Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- LGWZGBCKVDSYPH-UHFFFAOYSA-N triacontane Chemical compound [CH2]CCCCCCCCCCCCCCCCCCCCCCCCCCCCC LGWZGBCKVDSYPH-UHFFFAOYSA-N 0.000 description 1
- OLTHARGIAFTREU-UHFFFAOYSA-N triacontane Natural products CCCCCCCCCCCCCCCCCCCCC(C)CCCCCCCC OLTHARGIAFTREU-UHFFFAOYSA-N 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- GAWWVVGZMLGEIW-GNNYBVKZSA-L zinc ricinoleate Chemical compound [Zn+2].CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O.CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O GAWWVVGZMLGEIW-GNNYBVKZSA-L 0.000 description 1
- 229940100530 zinc ricinoleate Drugs 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- IFNXAMCERSVZCV-UHFFFAOYSA-L zinc;2-ethylhexanoate Chemical compound [Zn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O IFNXAMCERSVZCV-UHFFFAOYSA-L 0.000 description 1
- NVKSAUAQUPYOPO-UHFFFAOYSA-L zinc;decanoate Chemical compound [Zn+2].CCCCCCCCCC([O-])=O.CCCCCCCCCC([O-])=O NVKSAUAQUPYOPO-UHFFFAOYSA-L 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3726—Polyurethanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/24—Catalysts containing metal compounds of tin
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
- C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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Description
(a)2つの末端セクション(T)が疎水性であり、
(b)各セクションTが親水性セクション(S)に直接結合し、
(c)各セクションSが少なくとも一つの側で少なくとも1つの疎水性セクション(D)に直接結合し、
(d)ここで、少なくとも1つの親水性セクション(P)が存在し、ここで、1より多いセクションPが存在する場合、少なくとも1つの疎水性セクションDが2つのセクションPを分け、
ポリウレタンが少なくとも3つの親水性セクションを含み、各親水性セクションSの分子量と各親水性セクションPの分子量との比が1:1.4〜1:140であり、少なくとも2つの疎水性セクションDが脂肪族ジイソシアネート基であり、少なくとも1つの親水性セクションPが少なくとも1500g/molの分子量を有するポリエーテル基である、前記ポリウレタン又は異なるポリウレタンPUの混合物に関する。
1.少なくとも1500g/molの分子量を有する、少なくとも1種のポリエーテルジオールを、少なくとも1種のカルボン酸亜鉛及び/又は少なくとも1種のチタンアルコラートの存在下で、少なくとも1種の脂肪族ジイソシアネートと反応させる。
減圧下にポリエーテルジオールを置き、水を十分に除去して(好ましくは約300ppm以下の水含有量になるまで)、それから溶媒を混合すること、あるいは、
ポリエーテルジオールとキシレン、トルエン又はアセトン等の溶媒とを混合して、例えば、約300ppmの水含有量になるまで共沸蒸留によって水を除去すること(但し、この場合その溶媒は完全には除去されない。しかし、残存溶媒中のポリエーテルの溶液は、溶液中でその反応に使用される)
からなる。
水性分散液における本発明のポリウレタンPUの動粘度は、23℃において10重量%強度の分散液の形態で測定した。以下にリストする実施例では、この目的のため、動粘度を常にせん断速度100 1/s及び350 1/sで決定した。これらの2つの数値は、水性分散液において本発明のポリウレタンPUが非ニュートン又はニュートン増粘挙動を示すかどうかに関しての言及を可能とする。DIN53019により動粘度を決定するために以下を使用した。
シリンダー測定システム、Z4 DINシリンダー(直径14mm)
使用する機器:Anton Paar社のPhysica Rheolab MCI携帯回転型粘度計
シリンダー測定システム、Z4 DINシリンダー(直径14mm)
合成例1:ポリウレタンPU1の調製
6000g/molの数平均分子量を有する17.75kgの線状ポリエチレングリコール(例えば、BASF SE社のPluriol(登録商標)E6000)を、窒素下で23.50kgのキシレンに溶解させた。約140℃に溶液を加熱した後、反応混合液の水含有量がわずか約140ppmとなるようにキシレンを蒸留した。
6000g/molの数平均分子量を有する17.75kgの線状ポリエチレングリコール(例えば、BASF SE 社のPluriol(登録商標)E6000)を、窒素下で23.50kgのキシレンに溶解させた。約140℃に溶液を加熱した後、反応混合液の水含有量がまだ、わずか約250ppmになるようにキシレンを蒸留した。
6000g/molの数平均分子量を有する120.00gの線状ポリエチレングリコール(例えば、BASF SE社のPluriol(登録商標)E6000)を窒素下で467.00gのキシレンに溶解させた。約140℃に溶液を加熱した後、反応混合液の水含有量が300ppmより少なくなるようにキシレンを蒸留した。
6000g/molの数平均分子量を有する17.75kgの線状ポリエチレングリコール(例えば、BASF SE社のPluriol(登録商標)E6000)を窒素下で23.50kgのキシレンに溶解させた。約140℃にその溶液を加熱した後、反応混合液の水含有量が約120ppmになるようにキシレンを蒸留した。
6000g/molの分子量を有する240.00gの線状ポリエチレングリコール(例えば、BASF SE社のPluriol(登録商標)E6000)を窒素下で934.00gのキシレンに溶解させた。その溶液を約140℃に加熱した後、反応混合液の水含有量が300ppmより少なくなるようにキシレンを蒸留した。
6000g/molの分子量を有する180.00gの線状ポリエチレングリコール(例えば、BASF SE社のPluriol(登録商標)E6000)を窒素下で180.00gのアセトンに溶解させた。溶液を加熱還流した後(内部温度約56℃)、1362.4gのアセトンをさらに連続して加え、同時に合計1362.4gのアセトンを蒸留した。反応混合液の水含有量はまだ、わずか約240ppmであった。
6000g/molの数平均分子量を有する120.00gの線状ポリエチレングリコール(例えば、BASF SE社のPluriol(登録商標)E6000)を窒素下で467.00gのキシレンに溶解させた。その溶液を約140℃に加熱した後、反応混合液の水含有量がまだ、わずか約120ppmになるようにキシレンを蒸留した。
9000g/molの数平均分子量を有する180.00gの線状ポリエチレングリコール(例えば、BASF SE社のPluriol(登録商標)E9000)を窒素下で467.00gのキシレンに溶解させた。その溶液を約140℃に加熱した後、反応混合液の水含有量がまだ、わずか約70ppmになるようにキシレンを蒸留した。
9000g/molの数平均分子量を有する180.00gの線状ポリエチレングリコール(例えば、BASF SE社のPluriol(登録商標)E9000)を窒素下で467.00gのキシレンに溶解させた。その溶液を約140℃に加熱した後、反応混合液の水含有量がまだ、わずか約70ppmになるようにキシレンを蒸留した。
1500g/molの数平均分子量を有する120.00gの線状ポリエチレングリコール(例えば、BASF SE社のPluriol(登録商標)E1500)を窒素下で467.00gのキシレンに溶解させた。その溶液を約140℃に加熱した後、反応混合液の水含有量がまだ、わずか約110ppmになるようにキシレンを蒸留した。
1500g/molの数平均分子量を有する90.00gの線状ポリエチレングリコール(例えば、BASF SE社のPluriol(登録商標)E1500)を窒素下で467.00gのキシレンに溶解させた。その溶液を約140℃に加熱した後、反応混合液の水含有量がまだ、わずか約80ppmになるようにキシレンを蒸留した。
水における本発明に係るポリウレタンのCMCを動的光散乱法により決定した。このためにゴニオメーターSP−86(ALV-Laser Vertriebsgesellschaft mbH, Langen, Germany)をDLS/SLSユニットと組み合わせるようにして使用した。そのユニットは、ALV5000相関器及び波長633nmのHe−Neレーザー(両方とも同様にALV, Langen)も含んだ。0.0001g/L〜10g/Lの濃度を含む一連の測定のために使用した条件は、23℃で測定角90°であった。その評価は、先行技術で周知のプログラム(CONTIN(Constrained Inversion)と称される)を用いて強度分布により行った(CONTINも同様に、ALV, Langen)。
CMCを決定するための比較において、ステアリルアルコール、ジイソシアネート及びポリエチレングリコールから調製した、先行技術である非イオン性の疎水性変性エトキシル化ウレタン(Aculyn(登録商標)46としてRohm & Haasから販売されている)を使用した。Aculyn(登録商標)46は測定可能なCMCを有していなかった。0.001〜10g/Lの濃度において、比較的大きく、不確定の100〜500nmの凝集体が主成分として常に存在していた。
合成例1及び2で調製したポリウレタンPU1及びPU2の混合液に関しては、0.1g/Lにおいて、平均粒径30nmを有する明確なミセルが存在することが見出された。よって、その両方のCMCは0.1g/Lより小さかった。合成例4で調製した本発明のポリウレタンPU4に関しては、1g/LのPU4の濃度において、17nmの直径を有するミセルが存在すること、また、0.1g/Lの濃度においては、15nmの粒径のミセルと、それより少ない割合の、約200nmの大きさで不確定な凝集体の両方が互いに存在することが見出された。従って、この場合も0.1g/Lより小さいCMCが存在していた。
化粧品調製物は、水相Bを油相Aに加えて、得られたO/Wエマルジョンを保存剤(相C)と混合することによって調製した。これにより、非イオン系調製物P.1.1〜P.1.5が得られた(表1)。
化粧品調製物は、水相Bを油相Aに加えて、得られたO/Wエマルジョンを保存剤(相C)と混合することによって調製した。これにより、非イオン系調製物P.2.1〜P.2.5が得られた(表2)。
水を含有し、さらに助剤を含む調製物(例えば、調製例で限定されずに開示される化粧品調製物)の動粘度は、Brookfield粘度計(Brookfield)、モデルDV-II+Pro粘度計(モデル:RVDVII+Pro)により決定した。使用した測定系は、20℃において20rpmのせん断速度に設定したRVスピンドルであった。
Claims (13)
- 交互の親水性及び疎水性セクションからなる実質的に線状の骨格を有し、少なくとも1種のカルボン酸亜鉛もしくは少なくとも1種のチタンアルコラート又はそれらの混合物の存在下で調製された水分散性ポリウレタン(PU)であり、
(a)2つの末端セクション(T)が疎水性の、分岐した又は分岐していないアルキル基であって、2つの疎水性末端セクションTの少なくとも1つが分岐したアルキル基であり、
(b)各セクションTが親水性セクション(S)に直接結合し、少なくとも2つの親水性セクションSがエチレンオキシド基であり、その数は2〜30個の基であり、
(c)各セクションSが少なくとも一つの側で少なくとも1つの疎水性セクション(D)に直接結合し、
(d)少なくとも1つの親水性セクション(P)が存在し、1より多いセクションPが存在する場合、少なくとも1つの疎水性セクションDが2つのセクションPを分離し、
該ポリウレタンが少なくとも3つの親水性セクションを含み、各親水性セクションSの分子量と各親水性セクションPの分子量との比が1:1.4〜1:140であり、少なくとも2つの疎水性セクションDが脂肪族ジイソシアネート基であり、少なくとも1つの親水性セクションPが少なくとも1500g/molの数平均分子量を有するポリエーテル基である、前記ポリウレタン、又は異なるポリウレタンPUの混合物。 - 疎水性末端セクションTが4〜30個の炭素原子を有する、請求項1に記載のポリウレタン。
- 疎水性セクションDが2〜20個の炭素原子の範囲の炭素原子鎖を含む、請求項1又は2に記載のポリウレタン。
- 親水性セクションの全てがポリエーテル基である、請求項1〜3のいずれか1項に記載のポリウレタン。
- 少なくとも1つの親水性セクションPが1500〜10000g/molの数平均分子量を有する、請求項1〜4のいずれか1項に記載のポリウレタン。
- 2段階で調製を行う、請求項1〜5のいずれか1項に記載のポリウレタンの調製方法。
- 少なくとも1種のカルボン酸亜鉛もしくは少なくとも1種のチタンアルコラート又はそれらの混合物の存在下で、少なくとも1種のポリエーテルジオールを少なくとも1種の脂肪族ジイソシアネートと反応させ、第2工程で、少なくとも1種のアルコキシル化脂肪アルコールと反応させ、次いでワークアップを行う、請求項6に記載の方法。
- 使用するポリエーテルジオールと使用するジイソシアネートとの比が1:1.1〜1:1.75である、請求項6又は7に記載の方法。
- 少なくとも1種のカルボン酸亜鉛の存在下で調製を行う、請求項6〜8のいずれか1項に記載の方法。
- 水を含有する調製物を製造するための、請求項1〜5のいずれか1項に記載のポリウレタン又は請求項6〜9のいずれか1項に記載の方法により調製されたポリウレタンの使用。
- 調製物が水の他、少なくとも1種の塩もしくは少なくとも1種の界面活性剤又はそれらの混合物を含む、請求項10に記載の使用。
- 請求項1〜5のいずれか1項に記載の少なくとも1種のポリウレタン又は請求項6〜9のいずれか1項に記載の方法により調製された少なくとも1種のポリウレタンを含む調製物。
- 調製物が水性分散液である、請求項12に記載の調製物。
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EP08155673A EP2184304A1 (de) | 2008-05-06 | 2008-05-06 | Polyurethanverdicker |
PCT/EP2009/055439 WO2009135856A1 (de) | 2008-05-06 | 2009-05-06 | Polyurethanverdicker |
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WO2012052383A2 (de) | 2010-10-22 | 2012-04-26 | Basf Se | Polyurethanverdicker |
BR112013009597B1 (pt) * | 2010-10-22 | 2020-02-04 | Basf Se | poliuretano espessante |
WO2012098176A1 (de) | 2011-01-20 | 2012-07-26 | Basf Se | Dendritische polyether-polyurethan-verdicker |
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US20160067172A1 (en) * | 2014-09-08 | 2016-03-10 | Elementis Specialties, Inc. | Sulfate-Free Personal Care Compositions and Methods |
JP6113695B2 (ja) * | 2014-10-31 | 2017-04-12 | 株式会社 資生堂 | 弾力ジェル状組成物 |
EP3023446A1 (en) | 2014-11-18 | 2016-05-25 | Basf Se | Continuous high-throughput process for the preparation of polyurethanes |
FR3039833B1 (fr) * | 2015-08-05 | 2017-09-01 | Coatex Sas | Agent epaississant pour systemes aqueux, formulations le contenant et utilisations |
WO2018065574A1 (en) | 2016-10-07 | 2018-04-12 | Basf Se | Latex paint containing titanium dioxide pigment |
JP7448318B2 (ja) | 2018-07-31 | 2024-03-12 | 株式会社Adeka | 化粧料用乳化組成物 |
WO2020025383A1 (en) | 2018-08-02 | 2020-02-06 | Basf Se | Process for producing an aqueous polymer dispersion |
EP3887420A1 (en) * | 2018-11-28 | 2021-10-06 | Basf Se | Process for producing a polyurethane composition |
CA3138823A1 (en) | 2019-05-08 | 2020-11-12 | Basf Se | Aqueous polymer latex |
ES2966171T3 (es) | 2019-07-26 | 2024-04-18 | Basf Se | Proceso de producción de una dispersión polimérica acuosa |
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RU2010149451A (ru) | 2012-06-20 |
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CA2725448A1 (en) | 2009-11-12 |
EP2274355A1 (de) | 2011-01-19 |
BRPI0912222B1 (pt) | 2019-02-12 |
US20110166291A1 (en) | 2011-07-07 |
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US10240110B2 (en) | 2019-03-26 |
WO2009135856A1 (de) | 2009-11-12 |
ES2628107T3 (es) | 2017-08-01 |
BRPI0912222A2 (pt) | 2015-10-06 |
JP2011520003A (ja) | 2011-07-14 |
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