JP5750375B2 - フッ素化イオノマーの分散微粒子を使用する水性重合により製造されるフルオロポリマー - Google Patents

フッ素化イオノマーの分散微粒子を使用する水性重合により製造されるフルオロポリマー Download PDF

Info

Publication number
JP5750375B2
JP5750375B2 JP2011543633A JP2011543633A JP5750375B2 JP 5750375 B2 JP5750375 B2 JP 5750375B2 JP 2011543633 A JP2011543633 A JP 2011543633A JP 2011543633 A JP2011543633 A JP 2011543633A JP 5750375 B2 JP5750375 B2 JP 5750375B2
Authority
JP
Japan
Prior art keywords
reactor
fluorinated
polymerization
tfe
fluorinated ionomer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2011543633A
Other languages
English (en)
Japanese (ja)
Other versions
JP2012513530A (ja
JP2012513530A5 (https=
Inventor
ケネス・ウェイン・レフュー
ラルフ・バーチャード・ロイド
チャールズ・ジョウゼフ・ノエルケ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of JP2012513530A publication Critical patent/JP2012513530A/ja
Publication of JP2012513530A5 publication Critical patent/JP2012513530A5/ja
Application granted granted Critical
Publication of JP5750375B2 publication Critical patent/JP5750375B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18Monomers containing fluorine
    • C08F214/26Tetrafluoroethene
    • C08F214/262Tetrafluoroethene with fluorinated vinyl ethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18Monomers containing fluorine
    • C08F14/26Tetrafluoroethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18Monomers containing fluorine
    • C08F214/26Tetrafluoroethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
JP2011543633A 2008-12-23 2009-12-22 フッ素化イオノマーの分散微粒子を使用する水性重合により製造されるフルオロポリマー Active JP5750375B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US14011408P 2008-12-23 2008-12-23
US61/140,114 2008-12-23
PCT/US2009/069155 WO2010075359A1 (en) 2008-12-23 2009-12-22 Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer

Publications (3)

Publication Number Publication Date
JP2012513530A JP2012513530A (ja) 2012-06-14
JP2012513530A5 JP2012513530A5 (https=) 2013-02-07
JP5750375B2 true JP5750375B2 (ja) 2015-07-22

Family

ID=41559919

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2011543633A Active JP5750375B2 (ja) 2008-12-23 2009-12-22 フッ素化イオノマーの分散微粒子を使用する水性重合により製造されるフルオロポリマー

Country Status (5)

Country Link
US (1) US8153738B2 (https=)
EP (2) EP2367858B1 (https=)
JP (1) JP5750375B2 (https=)
CN (1) CN102264777B (https=)
WO (1) WO2010075359A1 (https=)

Families Citing this family (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2267047B1 (en) * 2008-04-14 2012-01-18 Asahi Glass Company, Limited Production method of polytetrafluoroethylene fine powder
US20090281241A1 (en) * 2008-05-09 2009-11-12 E. I. Du Pont De Nemours And Company Aqueous Polymerization of Fluorinated Monomer Using a Mixture of Fluoropolyether Acids or Salts
US8835547B2 (en) * 2008-12-23 2014-09-16 E I Du Pont De Nemours And Company Fluoropolymer particles having a nucleus of fluorinated ionomer
US8436054B2 (en) 2008-12-23 2013-05-07 E I Du Pont De Nemours And Company Fluorinated ionomer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer produced in situ
WO2012064858A1 (en) 2010-11-09 2012-05-18 E. I. Du Pont De Nemours And Company Reducing the telogenic behavior of hydrocarbon-containing surfactants in aqueous dispersion fluoromonomer polymerization
EP3533811B1 (en) 2010-11-09 2021-08-11 The Chemours Company FC, LLC Nucleation in aqueous polymerization of fluoromonomer
JP6109073B2 (ja) 2010-11-09 2017-04-05 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company 炭化水素界面活性剤を用いたフルオロモノマーの水性重合
GB201021790D0 (en) * 2010-12-23 2011-02-02 3M Innovative Properties Co Fluoropolymer compostions and purification methods thereof
EP2927248B1 (en) 2012-11-30 2018-06-13 Daikin Industries, Ltd. Production method for polytetrafluoroethylene aqueous dispersion
WO2014084399A1 (ja) 2012-11-30 2014-06-05 ダイキン工業株式会社 ポリテトラフルオロエチレン水性分散液及びポリテトラフルオロエチレンファインパウダー
CN111040058B (zh) * 2012-11-30 2022-10-25 大金工业株式会社 聚四氟乙烯水性分散液的制造方法
EP2935370A1 (en) * 2012-12-18 2015-10-28 E. I. du Pont de Nemours and Company Process for producing fluoroelastomers
CN105431485A (zh) * 2013-07-30 2016-03-23 索尔维特殊聚合物意大利有限公司 含氟热塑性弹性体组合物
JP6622209B2 (ja) 2013-11-26 2019-12-18 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー フルオロモノマーの水性重合において核を形成するためのポリアルキレンオキシドの使用
EP3156449A4 (en) * 2014-06-04 2017-09-06 Daikin Industries, Ltd. Polytetrafluoroethylene aqueous dispersion
EP3153532B1 (en) * 2014-06-04 2019-11-20 Daikin Industries, Ltd. Polytetrafluoroethylene powder
CN107614466A (zh) * 2015-05-11 2018-01-19 卡姆帕特薄膜系统公司 用于烯烃‑烷烃分离膜的共聚物
CN110997735B (zh) * 2017-08-10 2024-03-01 大金工业株式会社 精制聚四氟乙烯水性分散液的制造方法、改性聚四氟乙烯粉末的制造方法、聚四氟乙烯成型体的制造方法以及组合物
EP3760649B1 (en) 2018-03-01 2024-01-24 Daikin Industries, Ltd. Method for manufacturing fluoropolymer
TWI821458B (zh) * 2018-11-19 2023-11-11 日商大金工業股份有限公司 組成物及拉伸體
WO2020105651A1 (ja) 2018-11-19 2020-05-28 ダイキン工業株式会社 変性ポリテトラフルオロエチレンの製造方法及び組成物
JP7417129B2 (ja) 2019-04-26 2024-01-18 ダイキン工業株式会社 水の処理方法および組成物
JP7389366B2 (ja) 2019-04-26 2023-11-30 ダイキン工業株式会社 フルオロポリマー水性分散液の製造方法、排水の処理方法、及び、フルオロポリマー水性分散液
CN118146427A (zh) * 2019-07-23 2024-06-07 大金工业株式会社 含氟聚合物的制造方法、聚四氟乙烯组合物和聚四氟乙烯粉末
WO2021045165A1 (ja) 2019-09-05 2021-03-11 ダイキン工業株式会社 パーフルオロエラストマーの製造方法および組成物
JP7231868B2 (ja) 2019-09-05 2023-03-02 ダイキン工業株式会社 組成物およびその製造方法
WO2021100836A1 (ja) 2019-11-19 2021-05-27 ダイキン工業株式会社 フルオロポリマーの製造方法、ポリテトラフルオロエチレンの製造方法、パーフルオロエラストマーの製造方法および組成物
JP7417131B2 (ja) * 2019-11-19 2024-01-18 ダイキン工業株式会社 ポリテトラフルオロエチレンの製造方法
CN116234794A (zh) 2020-10-01 2023-06-06 科慕埃弗西有限公司 含氟聚合物的水性聚合反应中的低反应性烃分散剂
WO2022107894A1 (ja) 2020-11-19 2022-05-27 ダイキン工業株式会社 ポリテトラフルオロエチレンの製造方法およびポリテトラフルオロエチレンを含有する組成物
EP4249517A4 (en) 2020-11-19 2024-10-16 Daikin Industries, Ltd. PROCESS FOR PRODUCING AN AQUEOUS DISPERSION OF FLUORINE-CONTAINING ELASTOMER, AND COMPOSITION
JP7549257B2 (ja) 2020-11-19 2024-09-11 ダイキン工業株式会社 パーフルオロエラストマー水性分散液の製造方法、組成物、架橋性組成物および架橋物
WO2022163815A1 (ja) * 2021-01-28 2022-08-04 ダイキン工業株式会社 フルオロポリマー組成物の製造方法
KR20230150868A (ko) 2021-03-10 2023-10-31 다이킨 고교 가부시키가이샤 도료 조성물, 도포막, 적층체 및 도장 물품
JPWO2022244784A1 (https=) 2021-05-19 2022-11-24
JP7741413B2 (ja) 2021-06-11 2025-09-18 ダイキン工業株式会社 含フッ素エラストマー水性分散液の製造方法、組成物および水性分散液
CN115466343B (zh) * 2021-06-11 2023-10-27 中昊晨光化工研究院有限公司 一种聚醚二酸或其盐类表面活性剂及其应用
WO2023277140A1 (ja) 2021-06-30 2023-01-05 ダイキン工業株式会社 高純度フルオロポリマー含有組成物の製造方法および高純度フルオロポリマー含有組成物
WO2023277139A1 (ja) 2021-06-30 2023-01-05 ダイキン工業株式会社 フルオロポリマー組成物の製造方法およびフルオロポリマー組成物
JP7657762B2 (ja) * 2021-09-30 2025-04-07 ダイキン工業株式会社 ポリテトラフルオロエチレンファインパウダー
EP4497762A4 (en) 2022-03-23 2026-03-18 Daikin Ind Ltd PROCESS FOR PRODUCING FLUORIDED POLYMER, AND COMPOSITION
CN119095910A (zh) 2022-04-28 2024-12-06 大金工业株式会社 含有氟橡胶的组合物
CN119072500A (zh) 2022-04-28 2024-12-03 大金工业株式会社 含有氟树脂的组合物的制造方法和含有氟树脂的组合物
JP7787462B2 (ja) 2022-04-28 2025-12-17 ダイキン工業株式会社 フルオロポリマーの製造方法
WO2024154773A1 (ja) 2023-01-18 2024-07-25 ダイキン工業株式会社 テトラフルオロエチレン系ポリマー組成物、電気化学デバイス用バインダー、電極合剤、電極、及び、二次電池
EP4456182A4 (en) 2023-01-18 2025-09-03 Daikin Ind Ltd MIXTURE FOR ELECTROCHEMICAL DEVICE, MIXTURE SHEET FOR ELECTROCHEMICAL DEVICE, ELECTRODE AND ELECTROCHEMICAL DEVICE
WO2024214644A1 (ja) * 2023-04-10 2024-10-17 Agc株式会社 含フッ素重合体の製造方法、水性分散液及び固体組成物
JP7820661B2 (ja) 2023-08-14 2026-02-26 ダイキン工業株式会社 フルオロポリマー水性分散液の製造方法およびフルオロポリマー水性分散液
JP7689278B2 (ja) 2023-08-28 2025-06-06 ダイキン工業株式会社 水溶性含フッ素ポリマーの回収方法

Family Cites Families (62)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2559752A (en) * 1951-03-06 1951-07-10 Du Pont Aqueous colloidal dispersions of polymers
US2713593A (en) * 1953-12-21 1955-07-19 Minnesota Mining & Mfg Fluorocarbon acids and derivatives
US3037953A (en) * 1961-04-26 1962-06-05 Du Pont Concentration of aqueous colloidal dispersions of polytetrafluoroethylene
US3271341A (en) * 1961-08-07 1966-09-06 Du Pont Aqueous colloidal dispersions of polymer
US3282875A (en) * 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
US3291843A (en) * 1963-10-08 1966-12-13 Du Pont Fluorinated vinyl ethers and their preparation
US3391099A (en) * 1966-04-25 1968-07-02 Du Pont Polymerization process
GB1292268A (en) 1970-02-16 1972-10-11 Bitterfeld Chemie Process for the dimerisation of hexafluoropropene epoxide
US3704272A (en) * 1970-09-15 1972-11-28 Du Pont Concentration of polytetrafluoroethylene aqueous dispersion
US4358545A (en) * 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
JPS5816622U (ja) * 1981-07-23 1983-02-01 株式会社リコー カメラシステムにおける信号伝達装置
US4380618A (en) * 1981-08-21 1983-04-19 E. I. Du Pont De Nemours And Company Batch polymerization process
US4552631A (en) * 1983-03-10 1985-11-12 E. I. Du Pont De Nemours And Company Reinforced membrane, electrochemical cell and electrolysis process
DE3486428T2 (de) 1983-12-26 1996-10-10 Daikin Ind Ltd Halogen enthaltendes Polyether
US4621116A (en) * 1984-12-07 1986-11-04 E. I. Du Pont De Nemours And Company Process for copolymerization of tetrafluoroethylene in the presence of a dispersing agent comprising a perfluoroalkoxybenzene sulfonic acid or salt
US4743658A (en) * 1985-10-21 1988-05-10 E. I. Du Pont De Nemours And Company Stable tetrafluoroethylene copolymers
US4940525A (en) * 1987-05-08 1990-07-10 The Dow Chemical Company Low equivalent weight sulfonic fluoropolymers
US4952630A (en) * 1987-12-31 1990-08-28 E. I. Du Pont De Nemours And Company Modified polytetrafluoroethylene resins and blends thereof
JP3172983B2 (ja) * 1993-09-20 2001-06-04 ダイキン工業株式会社 ビニリデンフルオライド系重合体の水性分散液およびその製法
US5422411A (en) * 1993-09-21 1995-06-06 Ballard Power Systems Inc. Trifluorostyrene and substituted trifluorostyrene copolymeric compositions and ion-exchange membranes formed therefrom
US5637748A (en) * 1995-03-01 1997-06-10 E. I. Du Pont De Nemours And Company Process for synthesizing fluorinated nitrile compounds
JP3346090B2 (ja) * 1995-03-31 2002-11-18 ダイキン工業株式会社 ポリテトラフルオロエチレン水性分散液組成物及びその用途
US5789508A (en) * 1995-08-31 1998-08-04 E. I. Du Pont De Nemours And Company Polymerization process
US5688884A (en) * 1995-08-31 1997-11-18 E. I. Du Pont De Nemours And Company Polymerization process
US5763552A (en) * 1996-07-26 1998-06-09 E. I. Du Pont De Nemours And Company Hydrogen-containing flourosurfacant and its use in polymerization
US5866711A (en) * 1996-09-13 1999-02-02 E. I. Du Pont De Nemours And Company Fluorocyanate and fluorocarbamate monomers and polymers thereof
US5969067A (en) * 1996-09-13 1999-10-19 E.I. Dupont De Nemours And Company Phosphorus-containing fluoromonomers and polymers thereof
CN1233267A (zh) * 1996-10-15 1999-10-27 纳幕尔杜邦公司 含有高度氟化的离子交换聚合物颗粒的组合物
CN1154633C (zh) * 1997-03-31 2004-06-23 大金工业株式会社 卤代乙烯醚类磺酸衍生物的制法
US6395848B1 (en) * 1999-05-20 2002-05-28 E. I. Du Pont De Nemours And Company Polymerization of fluoromonomers
US6482979B1 (en) 1999-12-22 2002-11-19 Dyneon Llc Perfluorinated acid fluorides and preparation thereof
EP1283225B1 (en) 2000-02-16 2006-05-03 Daikin Industries, Ltd. Process for producing fluoroionomer, method for purification and concentration of the ionomer, and method of film formation
US7045571B2 (en) * 2001-05-21 2006-05-16 3M Innovative Properties Company Emulsion polymerization of fluorinated monomers
US6737489B2 (en) * 2001-05-21 2004-05-18 3M Innovative Properties Company Polymers containing perfluorovinyl ethers and applications for such polymers
BR0215428A (pt) 2002-01-04 2004-12-14 Du Pont Dispersão aquosa, composição de revestimento da dispersão aquosa, substratos revestidos e filme auto-sustentado
US6902839B2 (en) * 2002-05-31 2005-06-07 Korea Advanced Institute Of Science And Technology Polymer electrolyte membrane for fuel cell and method for producing the same
JP4096764B2 (ja) 2002-06-17 2008-06-04 ダイキン工業株式会社 含フッ素結晶性ポリマー分散体製造方法
US6841616B2 (en) * 2003-03-28 2005-01-11 Arkema Inc. Polymerization of halogen-containing monomers using siloxane surfactant
JP2004359870A (ja) 2003-06-05 2004-12-24 Daikin Ind Ltd 界面活性剤、含フッ素重合体の製造方法及び含フッ素重合体水性分散液
JP2004358397A (ja) 2003-06-05 2004-12-24 Daikin Ind Ltd 界面活性剤、含フッ素重合体の製造方法及び含フッ素重合体水性分散液
US7589234B2 (en) * 2003-07-02 2009-09-15 Daikin Industries, Ltd. Fluoroalkyl carboxylic acid derivative, method for producing fluorine-containing polymer, and aqueous dispersion of fluorine-containing polymer
US7557164B2 (en) * 2003-08-19 2009-07-07 E. I. Du Pont De Nemours And Company Membranes of fluorinated ionomer blended with nonionomeric fluoropolymers for electrochemical cells
US20050090613A1 (en) * 2003-10-22 2005-04-28 Daikin Industries, Ltd. Process for preparing fluorine-containing polymer latex
DE60336400D1 (de) * 2003-10-24 2011-04-28 3M Innovative Properties Co Wässrige Dispersionen von Polytetrafluorethylenteilchen
US7071271B2 (en) * 2003-10-30 2006-07-04 3M Innovative Properties Company Aqueous emulsion polymerization of functionalized fluoromonomers
ATE529451T1 (de) * 2003-11-17 2011-11-15 3M Innovative Properties Co Wässrige ptfe-dispersionen mit einem niedrigen gehalt an fluorierten emulgatoren
JP2005320501A (ja) * 2004-04-07 2005-11-17 Daikin Ind Ltd 含フッ素エラストマー重合体の製造方法
US7563828B2 (en) * 2004-07-16 2009-07-21 Alcatel-Lucent Usa Inc. Solid state proton conductor system derived from hybrid composite inorganic-organic multicomponent material
US20060014887A1 (en) 2004-07-19 2006-01-19 3M Innovative Properties Company Method of hydrolyzing a dispersion of ionic fluoropolymer
GB0511779D0 (en) * 2005-06-10 2005-07-20 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers in the presence of a partially fluorinated oligomer as an emulsifier
GB0514387D0 (en) * 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a perfluoropolyether surfactant
GB0514398D0 (en) * 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant
US7671112B2 (en) * 2005-07-15 2010-03-02 3M Innovative Properties Company Method of making fluoropolymer dispersion
CN100558753C (zh) 2005-10-17 2009-11-11 旭硝子株式会社 聚四氟乙烯水性乳化液、由其制得的聚四氟乙烯细粉和多孔体
JP5141256B2 (ja) 2005-10-20 2013-02-13 旭硝子株式会社 ポリテトラフルオロエチレン水性分散液およびその製品
WO2007046377A1 (ja) 2005-10-20 2007-04-26 Asahi Glass Company, Limited 溶融成形可能なフッ素樹脂の製造方法
EP1942118B1 (en) 2005-10-26 2013-09-11 Asahi Glass Company, Limited Fluororesin with low fluorine-containing emulsifier residual and method for producing same
EP2017292B1 (en) * 2006-05-10 2011-09-07 Daikin Industries, Ltd. Process for production of fluorine-containing polymers
EP2079766B1 (en) * 2006-11-09 2011-05-18 E.I. Du Pont De Nemours And Company Aqueous polymerization of fluorinated monomer using polymerization agent comprising high molecular weight fluoropolyether acid or salt and fluoropolyether acid or salt surfactant
JP5439186B2 (ja) 2006-11-09 2014-03-12 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー フルオロポリエーテル酸または塩および炭化水素系界面活性剤を含む重合剤を用いるフッ素化モノマーの水性重合
US7989566B2 (en) 2008-01-22 2011-08-02 Dupont Performance Elastomers Llc Process for producing fluoropolymers
US8058376B2 (en) * 2008-12-23 2011-11-15 E. I. Du Pont De Nemours And Company Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated lonomer produced in situ

Also Published As

Publication number Publication date
JP2012513530A (ja) 2012-06-14
US20100160490A1 (en) 2010-06-24
EP2367858B1 (en) 2016-05-04
CN102264777B (zh) 2014-05-07
EP3091039A1 (en) 2016-11-09
EP2367858A1 (en) 2011-09-28
US8153738B2 (en) 2012-04-10
WO2010075359A1 (en) 2010-07-01
CN102264777A (zh) 2011-11-30
EP3091039B1 (en) 2023-03-01

Similar Documents

Publication Publication Date Title
JP5750375B2 (ja) フッ素化イオノマーの分散微粒子を使用する水性重合により製造されるフルオロポリマー
JP5481495B2 (ja) フッ素化イオノマーの核を有するフルオロポリマー粒子
JP5703233B2 (ja) その場生成されるフッ素化イオノマーの分散した微粒子を使用する水性重合によって製造されるフルオロポリマー
JP5588679B2 (ja) フルオロポリエーテル酸または塩および短鎖フッ素系界面活性剤を含む重合剤を用いるフッ素化モノマーの水性重合
JP5758810B2 (ja) その場生成されるフッ素化イオノマーの分散した微粒子を使用する水性重合によって製造されるフッ素化イオノマー
EP2367862B1 (en) Aqueous polymerization of fluorinated monomer using hydrogen containing branched fluoroether surfactant
JP2012513533A (ja) フッ素化イオノマーの分散した微粒子を使用する水性重合によって製造されるフッ素化イオノマー

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20121214

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20121214

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20130612

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20130625

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20130925

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20131002

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20131224

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20140617

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20140912

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20140922

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20141217

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20150428

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20150518

R150 Certificate of patent or registration of utility model

Ref document number: 5750375

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313113

S531 Written request for registration of change of domicile

Free format text: JAPANESE INTERMEDIATE CODE: R313531

R360 Written notification for declining of transfer of rights

Free format text: JAPANESE INTERMEDIATE CODE: R360

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

R360 Written notification for declining of transfer of rights

Free format text: JAPANESE INTERMEDIATE CODE: R360

R371 Transfer withdrawn

Free format text: JAPANESE INTERMEDIATE CODE: R371

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313113

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250