JP5658682B2 - 共役ジエン類のアニオン重合用の新規な開始系およびジエンエラストマーの製造方法 - Google Patents
共役ジエン類のアニオン重合用の新規な開始系およびジエンエラストマーの製造方法 Download PDFInfo
- Publication number
- JP5658682B2 JP5658682B2 JP2011542815A JP2011542815A JP5658682B2 JP 5658682 B2 JP5658682 B2 JP 5658682B2 JP 2011542815 A JP2011542815 A JP 2011542815A JP 2011542815 A JP2011542815 A JP 2011542815A JP 5658682 B2 JP5658682 B2 JP 5658682B2
- Authority
- JP
- Japan
- Prior art keywords
- elastomer
- amine
- elastomers
- living
- initiator composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
- C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
- C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L15/00—Compositions of rubber derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0858988 | 2008-12-23 | ||
| FR0858988A FR2940294B1 (fr) | 2008-12-23 | 2008-12-23 | Nouveau systeme d'amorcage pour polymerisation anionique de dienes conjugues, procede de preparation d'elastomeres dieniques. |
| PCT/EP2009/067747 WO2010072761A1 (fr) | 2008-12-23 | 2009-12-22 | Nouveau système d'amorçage pour polymérisation anionique de diènes conjugués, procédé de préparation d'élastomères diéniques |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012513516A JP2012513516A (ja) | 2012-06-14 |
| JP2012513516A5 JP2012513516A5 (enExample) | 2013-02-14 |
| JP5658682B2 true JP5658682B2 (ja) | 2015-01-28 |
Family
ID=40852414
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011542815A Expired - Fee Related JP5658682B2 (ja) | 2008-12-23 | 2009-12-22 | 共役ジエン類のアニオン重合用の新規な開始系およびジエンエラストマーの製造方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US8394903B2 (enExample) |
| EP (1) | EP2382242B1 (enExample) |
| JP (1) | JP5658682B2 (enExample) |
| FR (1) | FR2940294B1 (enExample) |
| WO (1) | WO2010072761A1 (enExample) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2951186B1 (fr) * | 2009-10-12 | 2012-01-06 | Michelin Soc Tech | Composition de caoutchouc a base de glycerol et d'un elastomere fonctionnalise et bande de roulement pour pneumatique |
| FR2995609B1 (fr) | 2012-07-25 | 2014-11-28 | Michelin & Cie | Pneumatique ayant une adherence sur sol mouille amelioree |
| FR3000081B1 (fr) | 2012-12-21 | 2015-07-17 | Michelin & Cie | Composition de caoutchouc comportant de la cellulose |
| FR3003573B1 (fr) | 2013-03-22 | 2017-10-27 | Michelin & Cie | Composition de caouthcouc comportant des particules hybrides |
| FR3009558B1 (fr) * | 2013-08-09 | 2015-09-04 | Michelin & Cie | Elastomere dienique couple possedant une fonction silanol en milieu de chaine et fonctionnalise amine en extremite de chaine et composition de caoutchouc le comprenant |
| FR3014880B1 (fr) | 2013-12-18 | 2015-12-25 | Michelin & Cie | Pneumatique pour velocipede. |
| FR3019548B1 (fr) | 2014-04-03 | 2016-04-01 | Michelin & Cie | Composition de caoutchouc comprenant une resine dicyclopentadiene aromatique |
| EP4050014A3 (en) | 2014-10-23 | 2022-12-14 | Inpria Corporation | Organometallic solution based high resolution patterning compositions |
| FR3029929B1 (fr) | 2014-12-15 | 2018-02-02 | Michelin & Cie | Composition de caoutchouc renforcee pour pneumatique |
| FR3030542B1 (fr) | 2014-12-19 | 2018-05-18 | Michelin & Cie | Bande de roulement de pneumatique |
| FR3047735A1 (fr) | 2016-02-12 | 2017-08-18 | Michelin & Cie | Composition de caoutchouc comprenant une silice essentiellement spherique et peu structuree |
| FR3052783B1 (fr) | 2016-06-15 | 2018-05-25 | Compagnie Generale Des Etablissements Michelin | Composition de caoutchouc renforcee pour pneumatique |
| FR3052782B1 (fr) | 2016-06-15 | 2018-06-01 | Compagnie Generale Des Etablissements Michelin | Composition de caoutchouc renforcee pour pneumatique |
| FR3053345B1 (fr) | 2016-06-30 | 2018-07-06 | Compagnie Generale Des Etablissements Michelin | Composition de caoutchouc comprenant un agent de couplage polysulfure de monohydroxysilane |
| FR3059331A1 (fr) | 2016-11-28 | 2018-06-01 | Compagnie Generale Des Etablissements Michelin | Bande de roulement pour pneumatique |
| FR3060565A1 (fr) | 2016-12-16 | 2018-06-22 | Michelin & Cie | Polysulfure d'alcoxysilane |
| FR3060453A1 (fr) | 2016-12-20 | 2018-06-22 | Compagnie Generale Des Etablissements Michelin | Pneumatique pour vehicule portant des lourdes charges comprenant une nouvelle bande de roulement |
| FR3060452A1 (fr) | 2016-12-20 | 2018-06-22 | Compagnie Generale Des Etablissements Michelin | Pneumatique pour vehicule portant des lourdes charges comprenant une nouvelle bande de roulement |
| FR3061189B1 (fr) | 2016-12-22 | 2020-10-30 | Michelin & Cie | Composition de caoutchouc renforcee |
| FR3061188A1 (fr) | 2016-12-22 | 2018-06-29 | Compagnie Generale Des Etablissements Michelin | Composition de caoutchouc renforcee |
| FR3068041B1 (fr) | 2017-06-22 | 2019-07-19 | Compagnie Generale Des Etablissements Michelin | Pneumatique pour vehicule portant des lourdes charges comprenant une nouvelle bande de roulement |
| FR3069550A1 (fr) | 2017-07-28 | 2019-02-01 | Compagnie Generale Des Etablissements Michelin | Elastomere etendu a la resine |
| CA2975104A1 (en) * | 2017-08-02 | 2019-02-02 | Seastar Chemicals Inc. | Organometallic compounds and methods for the deposition of high purity tin oxide |
| FR3079842B1 (fr) | 2018-04-06 | 2020-10-09 | Michelin & Cie | Pneumatique comportant une composition de caoutchouc comprenant un nouvel agent de couplage polysulfure porteur de groupes associatifs azotes |
| US11441018B2 (en) * | 2019-09-12 | 2022-09-13 | The Goodyear Tire & Rubber Company | Pneumatic tire having tread with three elastomers |
| US12209183B2 (en) | 2021-03-16 | 2025-01-28 | The Goodyear Rubber & Tire Company | Pneumatic tire having tread with three elastomers |
| FR3127223B1 (fr) | 2021-09-20 | 2023-08-18 | Michelin & Cie | Procédé d’obtention par extrusion d’une composition élastomérique renforcée. |
| WO2024035914A1 (en) | 2022-08-12 | 2024-02-15 | Gelest, Inc. | High purity tin compounds containing unsaturated substituent and method for preparation thereof |
| WO2024076481A1 (en) | 2022-10-04 | 2024-04-11 | Gelest, Inc. | Cyclic azastannane and cyclic oxostannane compounds and methods for preparation thereof |
Family Cites Families (50)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2849432A (en) | 1956-02-06 | 1958-08-26 | Firestone Tire & Rubber Co | Polymerization of diolefines |
| DE2355941A1 (de) | 1973-11-09 | 1975-05-15 | Bayer Ag | Polymerisation und copolymerisation von dienen |
| JPS5938209A (ja) | 1982-08-28 | 1984-03-02 | Japan Synthetic Rubber Co Ltd | 分岐状共役ジエン系重合体 |
| JPS5938209B2 (ja) | 1982-10-09 | 1984-09-14 | 出光石油化学株式会社 | シクロヘキサンの製造方法 |
| US4935471A (en) | 1987-10-15 | 1990-06-19 | The Goodyear Tire & Rubber Company | Capped polydienes |
| US5153159A (en) | 1990-04-09 | 1992-10-06 | Bridgestone/Firestone, Inc. | Elastomers and products having reduced hysteresis |
| US5268439A (en) * | 1991-01-02 | 1993-12-07 | Bridgestone/Firestone, Inc. | Tin containing elastomers and products having reduced hysteresis properties |
| US5523371A (en) | 1991-12-30 | 1996-06-04 | Bridgestone Corporation | Functionalized polymer of improved hysteresis properties prepared using amino-substituted aryllithium polymerization initiators |
| US5274106A (en) | 1991-12-30 | 1993-12-28 | Bridgestone Corporation | Amino-substituted aryllithium compounds as anionic polymerization initiators |
| US5238893A (en) | 1991-12-30 | 1993-08-24 | Bridgestone Corporation | Method of preparing an anionic polymerization initiator |
| US5519086A (en) | 1991-12-30 | 1996-05-21 | Bridgestone Corporation | Low-hysteresis elastomer compositions using amino-substituted aryllithium polymerization initiators |
| US5332810A (en) | 1992-10-02 | 1994-07-26 | Bridgestone Corporation | Solubilized anionic polymerization initiator and preparation thereof |
| US5329005A (en) | 1992-10-02 | 1994-07-12 | Bridgestone Corporation | Soluble anionic polymerization initiators and preparation thereof |
| US5393721A (en) | 1992-10-16 | 1995-02-28 | Bridgestone Corporation | Anionic polymerization initiators and reduced hysteresis products therefom |
| US5674798A (en) | 1992-10-16 | 1997-10-07 | Bridgestone Corporation | Hydrocarbon soluble anionic polymerization initiators |
| DE69315965T2 (de) | 1992-10-30 | 1998-04-16 | Bridgestone Corp | Lösliche, anionische Polymerisationsinitiatoren und erhaltene Produkte |
| US5643848A (en) | 1992-10-30 | 1997-07-01 | Bridgestone Corporation | Soluble anionic polymerization initiators and products therefrom |
| JP3330991B2 (ja) * | 1992-12-28 | 2002-10-07 | 株式会社ブリヂストン | 重合体の製造方法 |
| JP3378605B2 (ja) * | 1993-03-25 | 2003-02-17 | 株式会社ブリヂストン | 重合体の製造方法 |
| ES2119008T3 (es) | 1993-04-30 | 1998-10-01 | Bridgestone Corp | Iniciadores de polimerizacion anionica y productos de histeresis reducida de los mismos. |
| DE69415861T2 (de) | 1993-05-24 | 1999-05-27 | Bridgestone Corp., Tokio/Tokyo | Solubilisierte anionische Polymerisationsinitiatoren und daraus hergestellte Produkte |
| FR2722503A1 (fr) | 1994-07-15 | 1996-01-19 | Michelin & Cie | Polymeres dieniques fonctionnels, leur procede de preparation et leur utilisation dans des compositions elastomeres chargees a la silice utilisables pour des enveloppes de pneumatiques |
| FR2722505B1 (fr) | 1994-07-15 | 1996-09-27 | Michelin & Cie | Compositions elastomeres chargees a la silice utilisables pour des enveloppes de pneumatiques |
| EP0693505B1 (en) | 1994-07-18 | 1999-05-06 | Bridgestone Corporation | Elastomers and products having reduced hysteresis and process for the preparation thereof |
| US5567815A (en) | 1994-07-18 | 1996-10-22 | Bridgestone Corporation | Teritary amine containing antonic initiators used in preparing polymers and process for the preparation thereof |
| ES2160136T3 (es) | 1994-10-25 | 2001-11-01 | Bridgestone Corp | Polimeros que contienen aminas y productos de los mismos. |
| US5527753A (en) | 1994-12-13 | 1996-06-18 | Fmc Corporation | Functionalized amine initiators for anionic polymerization |
| US5574109A (en) | 1995-02-01 | 1996-11-12 | Bridgestone Corporation | Aminoalkyllithium compounds containing cyclic amines and polymers therefrom |
| US5610227A (en) | 1995-06-07 | 1997-03-11 | Bridgestone/Firestone, Inc. | Lithium amino magnesiate polymerization initiators and elastomers having reduced hysteresis |
| FR2740778A1 (fr) | 1995-11-07 | 1997-05-09 | Michelin & Cie | Composition de caoutchouc a base de silice et de polymere dienique fonctionalise ayant une fonction silanol terminale |
| FR2744127A1 (fr) | 1996-01-26 | 1997-08-01 | Michelin & Cie | Composition de caoutchouc a base d'un polymere dienique ayant une fonction silanol et comprenant un derive organosilane |
| US5852189A (en) | 1996-12-31 | 1998-12-22 | Bridgestone Corporation | Tertiaryaminoalkyllithium initiators and the preparation thereof |
| US5786441A (en) | 1996-12-31 | 1998-07-28 | Bridgestone Corporation | Polymers, elastomeric compounds and products thereof, derived from novel amine compounds containing side-chain organolithium moieties |
| US5912343A (en) | 1996-12-31 | 1999-06-15 | Bridgestone Corporation | Tertiary amines containing side-chain organolithium structures and method for the preparation thereof |
| US6252007B1 (en) * | 1997-07-11 | 2001-06-26 | Bridgestone Corporation | Elastomers having a reduced hysteresis via interaction of polymer with silica surfaces |
| US5935893A (en) | 1997-08-01 | 1999-08-10 | Bridgestone Corporation | Aliphatic solutions of aminoalkyllithium compounds |
| US6184338B1 (en) | 1997-08-27 | 2001-02-06 | Fmc Corporation | Anionic polymerization initiators containing tertiary amine functionality, their chain extended analogues, and processes for using the same |
| KR100285229B1 (ko) | 1999-03-03 | 2001-03-15 | 조충환 | 용액 중합 스티렌-부타디엔 고무 및 부타디엔 고무의 제조방법 |
| JP4598909B2 (ja) | 1999-12-02 | 2010-12-15 | 株式会社ブリヂストン | ゴム組成物及びそれを用いた空気入りタイヤ |
| ATE290565T1 (de) | 2000-02-24 | 2005-03-15 | Michelin Soc Tech | Vulkanisierbare kautschukmischung zur herstellung eines luftreifens und luftreifen, der eine solche zusammensetzung enthält |
| ATE555162T1 (de) | 2000-05-26 | 2012-05-15 | Michelin Soc Tech | Kautschukzusammensetzung für reifen mit lauffläche |
| GB2368845B (en) | 2000-08-31 | 2004-06-30 | Goodyear Tire & Rubber | Synthesis of a functionalized lithium initiator from a dilithium initiator and an alkylaminoaryl compound |
| CN1274719C (zh) | 2001-09-27 | 2006-09-13 | Jsr株式会社 | 共轭二烯(共)聚合橡胶、(共)聚合橡胶的制造方法、橡胶组合物、复合体以及轮胎 |
| US6765065B2 (en) | 2002-01-09 | 2004-07-20 | Sumitomo Chemical Company, Limited | Process for producing modified polymer rubber |
| JP4829475B2 (ja) | 2004-02-20 | 2011-12-07 | 株式会社ブリヂストン | 変性共役ジエン系重合体、並びにそれを用いたゴム組成物及びタイヤ |
| US20050203251A1 (en) | 2004-03-11 | 2005-09-15 | Sumitomo Chemical Company, Limited | Process for producing modified diene polymer rubber |
| FR2915202B1 (fr) | 2007-04-18 | 2009-07-17 | Michelin Soc Tech | Elastomere dienique couple monomodal possedant une fonction silanol en milieu de chaine, son procede d'obtention et composition de caoutchouc le contenant. |
| FR2918064B1 (fr) | 2007-06-28 | 2010-11-05 | Michelin Soc Tech | Procede de preparation d'un copolymere dienique a bloc polyether, composition de caoutchouc renforcee et enveloppe de pneumatique. |
| FR2918065B1 (fr) | 2007-06-28 | 2011-04-15 | Michelin Soc Tech | Procede de preparation d'un copolymere dienique a bloc polyether, composition de caoutchouc renforcee et enveloppe de pneumatique. |
| FR2930554B1 (fr) | 2008-04-29 | 2012-08-17 | Michelin Soc Tech | Melange elastomerique comprenant majoritairement un elastomere dienique couple par un groupe amino-alcoxysilane, composition de caoutchouc le comprenant et leurs procedes d'obtention. |
-
2008
- 2008-12-23 FR FR0858988A patent/FR2940294B1/fr not_active Expired - Fee Related
-
2009
- 2009-12-22 JP JP2011542815A patent/JP5658682B2/ja not_active Expired - Fee Related
- 2009-12-22 EP EP09796732A patent/EP2382242B1/fr not_active Not-in-force
- 2009-12-22 US US13/139,757 patent/US8394903B2/en active Active
- 2009-12-22 WO PCT/EP2009/067747 patent/WO2010072761A1/fr not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| US20110251354A1 (en) | 2011-10-13 |
| FR2940294A1 (fr) | 2010-06-25 |
| JP2012513516A (ja) | 2012-06-14 |
| EP2382242A1 (fr) | 2011-11-02 |
| US8394903B2 (en) | 2013-03-12 |
| EP2382242B1 (fr) | 2012-10-10 |
| WO2010072761A1 (fr) | 2010-07-01 |
| FR2940294B1 (fr) | 2011-02-18 |
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