JP5580780B2 - １種類の溶媒を用いた乳化による、ポリエステルラテックスを製造するためのプロセス - Google Patents

１種類の溶媒を用いた乳化による、ポリエステルラテックスを製造するためのプロセス Download PDF

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Publication number
JP5580780B2
JP5580780B2 JP2011106386A JP2011106386A JP5580780B2 JP 5580780 B2 JP5580780 B2 JP 5580780B2 JP 2011106386 A JP2011106386 A JP 2011106386A JP 2011106386 A JP2011106386 A JP 2011106386A JP 5580780 B2 JP5580780 B2 JP 5580780B2
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mixture
resin
emulsion
contacting
solvent
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Expired - Fee Related
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JP2011106386A
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Japanese (ja)
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JP2011236425A5 (https=
JP2011236425A (ja
Inventor
サンティアゴ・フォーシェ
キンバリー・ディー・ノセッラ
シンガン・エス・キウ
デイヴィッド・アール・カーセバ
シャオヤン・オウ
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Xerox Corp
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Xerox Corp
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Publication of JP2011236425A5 publication Critical patent/JP2011236425A5/ja
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    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/0802—Preparation methods
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • C08J3/07—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media from polymer solutions
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/0819—Developers with toner particles characterised by the dimensions of the particles
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/087—Binders for toner particles
    • G03G9/08742—Binders for toner particles comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • G03G9/08755—Polyesters
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/087—Binders for toner particles
    • G03G9/08784—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775
    • G03G9/08795—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775 characterised by their chemical properties, e.g. acidity, molecular weight, sensitivity to reactants
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/087—Binders for toner particles
    • G03G9/08784—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775
    • G03G9/08797—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775 characterised by their physical properties, e.g. viscosity, solubility, melting temperature, softening temperature, glass transition temperature
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/097—Plasticisers; Charge controlling agents
    • G03G9/09708—Inorganic compounds
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/097—Plasticisers; Charge controlling agents
    • G03G9/09708—Inorganic compounds
    • G03G9/09725—Silicon-oxides; Silicates
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/097—Plasticisers; Charge controlling agents
    • G03G9/09733—Organic compounds
    • G03G9/0975—Organic compounds anionic
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/097—Plasticisers; Charge controlling agents
    • G03G9/09733—Organic compounds
    • G03G9/09766—Organic compounds comprising fluorine
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/097—Plasticisers; Charge controlling agents
    • G03G9/09783—Organo-metallic compounds
    • G03G9/09791—Metallic soaps of higher carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Developing Agents For Electrophotography (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
JP2011106386A 2010-05-12 2011-05-11 １種類の溶媒を用いた乳化による、ポリエステルラテックスを製造するためのプロセス Expired - Fee Related JP5580780B2 (ja)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US12/778,431 US8192913B2 (en) 2010-05-12 2010-05-12 Processes for producing polyester latexes via solvent-based emulsification
US12/778,431 2010-05-12
US12/784,802 2010-05-21
US12/784,802 US8338071B2 (en) 2010-05-12 2010-05-21 Processes for producing polyester latexes via single-solvent-based emulsification

Publications (3)

Publication Number Publication Date
JP2011236425A JP2011236425A (ja) 2011-11-24
JP2011236425A5 JP2011236425A5 (https=) 2014-06-26
JP5580780B2 true JP5580780B2 (ja) 2014-08-27

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JP2011106386A Expired - Fee Related JP5580780B2 (ja) 2010-05-12 2011-05-11 １種類の溶媒を用いた乳化による、ポリエステルラテックスを製造するためのプロセス

Country Status (3)

Country Link
US (1) US8338071B2 (https=)
JP (1) JP5580780B2 (https=)
CA (1) CA2739206C (https=)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120135346A1 (en) * 2010-11-29 2012-05-31 Xerox Corporation Processes for producing polyester latexes with bio-based solvents
JP5852906B2 (ja) * 2012-03-01 2016-02-03 花王株式会社 電子写真用トナーの製造方法
KR20130126482A (ko) * 2012-05-10 2013-11-20 캐논 가부시끼가이샤 토너 및 토너 제조 방법
US9090760B2 (en) 2013-04-04 2015-07-28 Xerox Corporation Continuous latex production processes
US9639013B2 (en) 2013-04-04 2017-05-02 Xerox Corporation Continuous coalescence processes
US8968978B2 (en) * 2013-06-13 2015-03-03 Xerox Corporation Phase inversion emulsification reclamation process
US9188895B2 (en) 2013-12-16 2015-11-17 Xerox Corporation Toner additives for improved charging
US9267032B1 (en) * 2014-11-06 2016-02-23 Xerox Corporation Crystalline polyester latex production by solvent reuse phase inversion emulsification
US9410037B2 (en) * 2014-12-05 2016-08-09 Xerox Corporation Crystalline latex production
US9341966B1 (en) * 2014-12-18 2016-05-17 Xerox Corporation Single solvent formulation for preparation of crystalline polyester latex via phase inversion emulsification
US9562142B2 (en) * 2015-05-08 2017-02-07 Xerox Corporation Process for crystalline latex production
US9964880B1 (en) * 2017-03-22 2018-05-08 Xerox Corporation Phase inversion emulsification process for controlling latex particle size

Family Cites Families (67)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3590000A (en) 1967-06-05 1971-06-29 Xerox Corp Solid developer for latent electrostatic images
US3800588A (en) 1971-04-30 1974-04-02 Mts System Corp Multiple axis control system for vibration test apparatus
US3933954A (en) 1973-11-28 1976-01-20 E. I. Du Pont De Nemours And Company Preparation of powders having spherical-shaped particles from ionomer resins and ethylene/carboxylic acid copolymer resins
US4056653A (en) 1973-11-28 1977-11-01 E. I. Du Pont De Nemours And Company Spherical-shaped particles from ionomer resins and ethylene/carboxylic acid copolymer resins
US4298672A (en) 1978-06-01 1981-11-03 Xerox Corporation Toners containing alkyl pyridinium compounds and their hydrates
US4338390A (en) 1980-12-04 1982-07-06 Xerox Corporation Quarternary ammonium sulfate or sulfonate charge control agents for electrophotographic developers compatible with viton fuser
US5354804A (en) 1991-05-09 1994-10-11 Tosoh Corporation Method of emulsifying thermoplastic resin composition
US5302486A (en) 1992-04-17 1994-04-12 Xerox Corporation Encapsulated toner process utilizing phase separation
US5290654A (en) 1992-07-29 1994-03-01 Xerox Corporation Microsuspension processes for toner compositions
US5278020A (en) 1992-08-28 1994-01-11 Xerox Corporation Toner composition and processes thereof
DE69329811T2 (de) * 1992-09-01 2001-08-16 Kao Corp., Tokio/Tokyo Kapseltoner zur Wärme- und Druck-Fixierung und Verfahren zu dessen Herstellung
BR9307346A (pt) 1992-11-02 1999-06-01 Ferro Corp Processo para preparação de materiais de revestimento
US5308734A (en) 1992-12-14 1994-05-03 Xerox Corporation Toner processes
US5346797A (en) 1993-02-25 1994-09-13 Xerox Corporation Toner processes
US5348832A (en) 1993-06-01 1994-09-20 Xerox Corporation Toner compositions
US5418108A (en) 1993-06-25 1995-05-23 Xerox Corporation Toner emulsion aggregation process
US5403693A (en) 1993-06-25 1995-04-04 Xerox Corporation Toner aggregation and coalescence processes
US5370963A (en) 1993-06-25 1994-12-06 Xerox Corporation Toner emulsion aggregation processes
US5344738A (en) 1993-06-25 1994-09-06 Xerox Corporation Process of making toner compositions
US5364729A (en) 1993-06-25 1994-11-15 Xerox Corporation Toner aggregation processes
US5405728A (en) 1993-06-25 1995-04-11 Xerox Corporation Toner aggregation processes
US5366841A (en) 1993-09-30 1994-11-22 Xerox Corporation Toner aggregation processes
EP0716344A1 (en) 1994-12-05 1996-06-12 Konica Corporation Light-sensitive composition and light-sensitive lithographic printing plate using the same
US5501935A (en) 1995-01-17 1996-03-26 Xerox Corporation Toner aggregation processes
US5977210A (en) 1995-01-30 1999-11-02 Xerox Corporation Modified emulsion aggregation processes
US5527658A (en) 1995-03-13 1996-06-18 Xerox Corporation Toner aggregation processes using water insoluble transition metal containing powder
US5496676A (en) 1995-03-27 1996-03-05 Xerox Corporation Toner aggregation processes
US5565296A (en) 1995-07-03 1996-10-15 Xerox Corporation Coated carriers by aggregation processes
US5585215A (en) 1996-06-13 1996-12-17 Xerox Corporation Toner compositions
US5723252A (en) 1996-09-03 1998-03-03 Xerox Corporation Toner processes
US5650255A (en) 1996-09-03 1997-07-22 Xerox Corporation Low shear toner aggregation processes
US5683848A (en) 1996-10-02 1997-11-04 Xerox Corporation Acrylonitrile-modified toner composition and processes
US5650256A (en) 1996-10-02 1997-07-22 Xerox Corporation Toner processes
US5763133A (en) 1997-03-28 1998-06-09 Xerox Corporation Toner compositions and processes
US5928577A (en) 1997-04-08 1999-07-27 E. I. Du Pont De Nemours And Company Spherical particles of a coating composition
US5827633A (en) 1997-07-31 1998-10-27 Xerox Corporation Toner processes
US5766818A (en) 1997-10-29 1998-06-16 Xerox Corporation Toner processes with hydrolyzable surfactant
US5853943A (en) 1998-01-09 1998-12-29 Xerox Corporation Toner processes
US5840462A (en) 1998-01-13 1998-11-24 Xerox Corporation Toner processes
US5869215A (en) 1998-01-13 1999-02-09 Xerox Corporation Toner compositions and processes thereof
US5853944A (en) 1998-01-13 1998-12-29 Xerox Corporation Toner processes
US5910387A (en) 1998-01-13 1999-06-08 Xerox Corporation Toner compositions with acrylonitrile and processes
US5919595A (en) 1998-01-13 1999-07-06 Xerox Corporation Toner process with cationic salts
US5916725A (en) 1998-01-13 1999-06-29 Xerox Corporation Surfactant free toner processes
US5863698A (en) 1998-04-13 1999-01-26 Xerox Corporation Toner processes
US5994020A (en) 1998-04-13 1999-11-30 Xerox Corporation Wax containing colorants
US6063827A (en) 1998-07-22 2000-05-16 Xerox Corporation Polyester process
US6214507B1 (en) 1998-08-11 2001-04-10 Xerox Corporation Toner compositions
US6184270B1 (en) 1998-09-21 2001-02-06 Eric J. Beckman Production of power formulations
US6080807A (en) 1998-11-12 2000-06-27 Owens Corning Fiberglas Technology, Inc. Solvent-free polyester emulsions
CA2373551C (en) 1999-05-20 2009-10-06 The Dow Chemical Company A continuous process of extruding and mechanically dispersing a polymeric resin in an aqueous or non-aqueous medium
JP2004514038A (ja) 2000-11-17 2004-05-13 ダウ　グローバル　テクノロジーズ　インコーポレイティド 固形、半固形及び液状の樹脂の分散系、及び該分散系の製造方法
US6593049B1 (en) 2001-03-26 2003-07-15 Xerox Corporation Toner and developer compositions
DE10126649A1 (de) 2001-06-01 2002-12-12 Basf Coatings Ag Kontinuierliches Verfahren zur Herstellung von Pulverlacksuspensionen (Pulverslurries) und Pulverlacken
US6756176B2 (en) 2002-09-27 2004-06-29 Xerox Corporation Toner processes
US6830860B2 (en) 2003-01-22 2004-12-14 Xerox Corporation Toner compositions and processes thereof
ATE466911T1 (de) 2003-07-23 2010-05-15 Dow Corning Mechanisches inversionsverfahren zur herstellung von silikon-öl-in-wasser-emulsionen
US7247413B2 (en) * 2003-09-22 2007-07-24 Konica Minolta Business Technologies, Inc. Electrostatic latent-image developing toner
US7029817B2 (en) * 2004-02-13 2006-04-18 Xerox Corporation Toner processes
US7329476B2 (en) 2005-03-31 2008-02-12 Xerox Corporation Toner compositions and process thereof
JP4561622B2 (ja) * 2005-12-20 2010-10-13 富士ゼロックス株式会社 静電荷像現像トナー用樹脂粒子分散液及びその製造方法、静電荷像現像トナー及びその製造方法、静電荷像現像剤、並びに、画像形成方法
US7858285B2 (en) * 2006-11-06 2010-12-28 Xerox Corporation Emulsion aggregation polyester toners
US7547499B2 (en) 2006-12-22 2009-06-16 Xerox Corporation Low melt toner
US7989135B2 (en) 2008-02-15 2011-08-02 Xerox Corporation Solvent-free phase inversion process for producing resin emulsions
US8492065B2 (en) 2008-03-27 2013-07-23 Xerox Corporation Latex processes
JP5215100B2 (ja) * 2008-09-17 2013-06-19 花王株式会社 電子写真用トナー
JP5321007B2 (ja) * 2008-11-20 2013-10-23 富士ゼロックス株式会社 樹脂水分散体の製造システム、樹脂水分散体の製造方法および静電荷像現像用トナー

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Publication number Publication date
CA2739206A1 (en) 2011-11-12
CA2739206C (en) 2014-07-22
US8338071B2 (en) 2012-12-25
US20110281216A1 (en) 2011-11-17
JP2011236425A (ja) 2011-11-24

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