JP5529466B2 - 透明樹脂成形体及びその製造方法 - Google Patents
透明樹脂成形体及びその製造方法 Download PDFInfo
- Publication number
- JP5529466B2 JP5529466B2 JP2009200324A JP2009200324A JP5529466B2 JP 5529466 B2 JP5529466 B2 JP 5529466B2 JP 2009200324 A JP2009200324 A JP 2009200324A JP 2009200324 A JP2009200324 A JP 2009200324A JP 5529466 B2 JP5529466 B2 JP 5529466B2
- Authority
- JP
- Japan
- Prior art keywords
- irradiation
- transmittance
- fluororesin
- melting point
- resin composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920005989 resin Polymers 0.000 title claims description 51
- 239000011347 resin Substances 0.000 title claims description 51
- 238000004519 manufacturing process Methods 0.000 title claims description 13
- 238000002844 melting Methods 0.000 claims description 58
- 230000008018 melting Effects 0.000 claims description 58
- 239000011342 resin composition Substances 0.000 claims description 45
- 238000000465 moulding Methods 0.000 claims description 33
- 230000005865 ionizing radiation Effects 0.000 claims description 25
- 239000000654 additive Substances 0.000 claims description 23
- 230000000996 additive effect Effects 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 19
- 238000004132 cross linking Methods 0.000 claims description 18
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 5
- 230000001678 irradiating effect Effects 0.000 claims description 4
- 239000011203 carbon fibre reinforced carbon Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- 238000002834 transmittance Methods 0.000 description 84
- 238000011156 evaluation Methods 0.000 description 48
- 238000010894 electron beam technology Methods 0.000 description 27
- 229910000679 solder Inorganic materials 0.000 description 27
- 230000000052 comparative effect Effects 0.000 description 25
- 238000010438 heat treatment Methods 0.000 description 18
- 230000003287 optical effect Effects 0.000 description 16
- -1 ethylene-tetrafluoroethylene-hexafluoropropylene Chemical group 0.000 description 13
- 239000008188 pellet Substances 0.000 description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 11
- 239000000178 monomer Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- 229920005992 thermoplastic resin Polymers 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 6
- 238000001746 injection moulding Methods 0.000 description 6
- 239000004417 polycarbonate Substances 0.000 description 6
- 230000001133 acceleration Effects 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 229920006129 ethylene fluorinated ethylene propylene Polymers 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 5
- 239000005977 Ethylene Substances 0.000 description 4
- 239000007983 Tris buffer Substances 0.000 description 4
- 238000004040 coloring Methods 0.000 description 4
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 4
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 4
- 239000012788 optical film Substances 0.000 description 4
- 230000003746 surface roughness Effects 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 229920006351 engineering plastic Polymers 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920009441 perflouroethylene propylene Polymers 0.000 description 3
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 3
- PDFSXHZXNZCKNF-UHFFFAOYSA-N 3,3,4,4,5,5,6,6,7,7,8,8-dodecafluorodeca-1,9-diene Chemical compound C=CC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C=C PDFSXHZXNZCKNF-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004431 polycarbonate resin Substances 0.000 description 2
- 229920005668 polycarbonate resin Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 229940113165 trimethylolpropane Drugs 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- 239000004420 Iupilon Substances 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
- INXWLSDYDXPENO-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(CO)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C INXWLSDYDXPENO-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 125000005067 haloformyl group Chemical group 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002493 microarray Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Optics & Photonics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Physics & Mathematics (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Laminated Bodies (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009200324A JP5529466B2 (ja) | 2009-08-31 | 2009-08-31 | 透明樹脂成形体及びその製造方法 |
| US13/126,984 US20110213089A1 (en) | 2009-08-31 | 2010-08-02 | Molded transparent resin and process for producing the same |
| DE112010003497T DE112010003497T5 (de) | 2009-08-31 | 2010-08-02 | Klarer Harz-Formkörper und Verfahren zu dessen Herstellung |
| PCT/JP2010/063017 WO2011024610A1 (ja) | 2009-08-31 | 2010-08-02 | 透明樹脂成形体及びその製造方法 |
| CN201080003116.0A CN102203172B (zh) | 2009-08-31 | 2010-08-02 | 透明树脂成型体及其制造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009200324A JP5529466B2 (ja) | 2009-08-31 | 2009-08-31 | 透明樹脂成形体及びその製造方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2011052063A JP2011052063A (ja) | 2011-03-17 |
| JP2011052063A5 JP2011052063A5 (https=) | 2012-05-17 |
| JP5529466B2 true JP5529466B2 (ja) | 2014-06-25 |
Family
ID=43627720
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009200324A Active JP5529466B2 (ja) | 2009-08-31 | 2009-08-31 | 透明樹脂成形体及びその製造方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20110213089A1 (https=) |
| JP (1) | JP5529466B2 (https=) |
| CN (1) | CN102203172B (https=) |
| DE (1) | DE112010003497T5 (https=) |
| WO (1) | WO2011024610A1 (https=) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6003905B2 (ja) * | 2012-01-30 | 2016-10-05 | 旭硝子株式会社 | 光学部材、その製造方法および該光学部材を備えた物品 |
| US9963564B2 (en) * | 2014-01-08 | 2018-05-08 | Daikin Industries, Ltd. | Modified fluorine-containing copolymer and fluorine resin molded article |
| JP5897772B2 (ja) | 2014-02-25 | 2016-03-30 | 住友電気工業株式会社 | 透明ポリアミド樹脂組成物、透明ポリアミド樹脂架橋成形体 |
| JPWO2016002887A1 (ja) * | 2014-07-04 | 2017-04-27 | 旭硝子株式会社 | フッ素樹脂組成物およびその製造方法、ならびに、成形物、発泡成形物および被覆電線 |
| JP2017025245A (ja) * | 2015-07-27 | 2017-02-02 | 住友電気工業株式会社 | 耐熱性透明樹脂成形体及びその製造方法 |
| WO2018034238A1 (ja) * | 2016-08-16 | 2018-02-22 | ダイキン工業株式会社 | 成形品及び成形品の製造方法 |
| US11552356B2 (en) * | 2017-06-02 | 2023-01-10 | Sumitomo Electric Fine Polymer, Inc. | Electricity storage device member, method of manufacturing the same, and electricity storage device |
| WO2019156067A1 (ja) * | 2018-02-07 | 2019-08-15 | ダイキン工業株式会社 | 低分子量ポリテトラフルオロエチレンを含む組成物の製造方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3116226A (en) * | 1959-03-16 | 1963-12-31 | Du Pont | Irradiation of fluorocarbon copoluymers |
| USRE28628E (en) * | 1971-03-01 | 1975-11-25 | Du Pont | Radiation treated poly(ethylene/chlorotrifluoroethylene) and poly(ethylene/tetrafluoroethylene) having improved high temperature properties |
| JP3317452B2 (ja) * | 1992-10-05 | 2002-08-26 | 株式会社レイテック | 改質ポリテトラフルオロエチレンとその製造方法 |
| JP3337785B2 (ja) * | 1993-10-26 | 2002-10-21 | 日本原子力研究所 | 改質ポリテトラフルオロエチレンの製造方法 |
| JP3563928B2 (ja) * | 1997-07-31 | 2004-09-08 | 日本原子力研究所 | 改質フッ素樹脂シート |
| JP3836255B2 (ja) * | 1998-06-10 | 2006-10-25 | 株式会社レイテック | 改質フッ素樹脂の製造方法 |
| JP2002293953A (ja) * | 2001-03-30 | 2002-10-09 | Nippon Mektron Ltd | フッ素樹脂成形体 |
| JP2002327067A (ja) * | 2001-05-07 | 2002-11-15 | Reitekku:Kk | 架橋フッ素樹脂の製造方法 |
| JP2005171051A (ja) | 2003-12-10 | 2005-06-30 | Teijin Chem Ltd | 光学部材およびその製造に適した芳香族ポリカーボネート樹脂 |
| JP2008231400A (ja) | 2007-02-20 | 2008-10-02 | Suzuka Fuji Xerox Co Ltd | 光学素子用樹脂組成物及び硬化性樹脂組成物 |
-
2009
- 2009-08-31 JP JP2009200324A patent/JP5529466B2/ja active Active
-
2010
- 2010-08-02 DE DE112010003497T patent/DE112010003497T5/de not_active Withdrawn
- 2010-08-02 WO PCT/JP2010/063017 patent/WO2011024610A1/ja not_active Ceased
- 2010-08-02 US US13/126,984 patent/US20110213089A1/en not_active Abandoned
- 2010-08-02 CN CN201080003116.0A patent/CN102203172B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2011052063A (ja) | 2011-03-17 |
| CN102203172A (zh) | 2011-09-28 |
| US20110213089A1 (en) | 2011-09-01 |
| DE112010003497T5 (de) | 2012-09-20 |
| CN102203172B (zh) | 2014-06-18 |
| WO2011024610A1 (ja) | 2011-03-03 |
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