JP5517145B2 - 水性塗料組成物 - Google Patents
水性塗料組成物 Download PDFInfo
- Publication number
- JP5517145B2 JP5517145B2 JP2009020433A JP2009020433A JP5517145B2 JP 5517145 B2 JP5517145 B2 JP 5517145B2 JP 2009020433 A JP2009020433 A JP 2009020433A JP 2009020433 A JP2009020433 A JP 2009020433A JP 5517145 B2 JP5517145 B2 JP 5517145B2
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- JP
- Japan
- Prior art keywords
- meth
- acrylate
- ethylenically unsaturated
- unsaturated monomer
- activated carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 23
- 239000003973 paint Substances 0.000 title claims description 18
- 239000000203 mixture Substances 0.000 title claims description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 70
- 239000000178 monomer Substances 0.000 claims description 50
- -1 1- ( Nonylphenoxy) methyl-2- (2-propenyloxy) ethoxy Chemical group 0.000 claims description 36
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 35
- 239000006185 dispersion Substances 0.000 claims description 30
- 239000011347 resin Substances 0.000 claims description 28
- 229920005989 resin Polymers 0.000 claims description 28
- 239000008199 coating composition Substances 0.000 claims description 23
- 239000002245 particle Substances 0.000 claims description 19
- 239000004094 surface-active agent Substances 0.000 claims description 17
- 239000000049 pigment Substances 0.000 claims description 15
- 239000011148 porous material Substances 0.000 claims description 15
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 13
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- 238000002296 dynamic light scattering Methods 0.000 claims description 8
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 7
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- JLIDVCMBCGBIEY-UHFFFAOYSA-N 1-penten-3-one Chemical compound CCC(=O)C=C JLIDVCMBCGBIEY-UHFFFAOYSA-N 0.000 claims description 4
- 150000005215 alkyl ethers Chemical class 0.000 claims description 4
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 claims description 4
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 3
- 239000002518 antifoaming agent Substances 0.000 claims description 3
- PBZROIMXDZTJDF-UHFFFAOYSA-N hepta-1,6-dien-4-one Chemical compound C=CCC(=O)CC=C PBZROIMXDZTJDF-UHFFFAOYSA-N 0.000 claims description 3
- FUSUHKVFWTUUBE-UHFFFAOYSA-N vinyl methyl ketone Natural products CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 claims description 3
- CMXNFXBFNYHFAL-UHFFFAOYSA-N 5-methylhex-1-en-3-one Chemical compound CC(C)CC(=O)C=C CMXNFXBFNYHFAL-UHFFFAOYSA-N 0.000 claims description 2
- 125000001539 acetonyl group Chemical group [H]C([H])([H])C(=O)C([H])([H])* 0.000 claims description 2
- YAQXJPBLJAFSFJ-UHFFFAOYSA-N acetyl acetate;prop-2-enoic acid Chemical compound OC(=O)C=C.CC(=O)OC(C)=O YAQXJPBLJAFSFJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims description 2
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 238000004040 coloring Methods 0.000 claims description 2
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- 239000013543 active substance Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 239000002562 thickening agent Substances 0.000 description 19
- 239000011248 coating agent Substances 0.000 description 16
- 238000000576 coating method Methods 0.000 description 16
- 238000000034 method Methods 0.000 description 16
- 238000012360 testing method Methods 0.000 description 15
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 14
- 239000000126 substance Substances 0.000 description 13
- 239000007789 gas Substances 0.000 description 11
- 239000000839 emulsion Substances 0.000 description 9
- 238000001179 sorption measurement Methods 0.000 description 9
- 238000011156 evaluation Methods 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 239000003945 anionic surfactant Substances 0.000 description 7
- 238000003860 storage Methods 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 239000004721 Polyphenylene oxide Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229920000570 polyether Polymers 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 4
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000003610 charcoal Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000003505 polymerization initiator Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 239000005909 Kieselgur Substances 0.000 description 3
- IBVAQQYNSHJXBV-UHFFFAOYSA-N adipic acid dihydrazide Chemical compound NNC(=O)CCCCC(=O)NN IBVAQQYNSHJXBV-UHFFFAOYSA-N 0.000 description 3
- 238000004220 aggregation Methods 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 3
- 229920002620 polyvinyl fluoride Polymers 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000010454 slate Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 2
- 235000017491 Bambusa tulda Nutrition 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 102000011632 Caseins Human genes 0.000 description 2
- 108010076119 Caseins Proteins 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 239000004606 Fillers/Extenders Substances 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 244000082204 Phyllostachys viridis Species 0.000 description 2
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000000809 air pollutant Substances 0.000 description 2
- 231100001243 air pollutant Toxicity 0.000 description 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 239000011425 bamboo Substances 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- HCOMFAYPHBFMKU-UHFFFAOYSA-N butanedihydrazide Chemical compound NNC(=O)CCC(=O)NN HCOMFAYPHBFMKU-UHFFFAOYSA-N 0.000 description 2
- XEVRDFDBXJMZFG-UHFFFAOYSA-N carbonyl dihydrazine Chemical compound NNC(=O)NN XEVRDFDBXJMZFG-UHFFFAOYSA-N 0.000 description 2
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- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
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- 125000000524 functional group Chemical group 0.000 description 2
- 239000010903 husk Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
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- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 2
- QYZFTMMPKCOTAN-UHFFFAOYSA-N n-[2-(2-hydroxyethylamino)ethyl]-2-[[1-[2-(2-hydroxyethylamino)ethylamino]-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanamide Chemical compound OCCNCCNC(=O)C(C)(C)N=NC(C)(C)C(=O)NCCNCCO QYZFTMMPKCOTAN-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
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- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
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- ZNGSVRYVWHOWLX-KHFUBBAMSA-N (1r,2s)-2-(methylamino)-1-phenylpropan-1-ol;hydrate Chemical compound O.CN[C@@H](C)[C@H](O)C1=CC=CC=C1.CN[C@@H](C)[C@H](O)C1=CC=CC=C1 ZNGSVRYVWHOWLX-KHFUBBAMSA-N 0.000 description 1
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 1
- 229920003067 (meth)acrylic acid ester copolymer Polymers 0.000 description 1
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- OSNILPMOSNGHLC-UHFFFAOYSA-N 1-[4-methoxy-3-(piperidin-1-ylmethyl)phenyl]ethanone Chemical compound COC1=CC=C(C(C)=O)C=C1CN1CCCCC1 OSNILPMOSNGHLC-UHFFFAOYSA-N 0.000 description 1
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- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 1
- VXQBJTKSVGFQOL-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl acetate Chemical compound CCCCOCCOCCOC(C)=O VXQBJTKSVGFQOL-UHFFFAOYSA-N 0.000 description 1
- FWLHAQYOFMQTHQ-UHFFFAOYSA-N 2-N-[8-[[8-(4-aminoanilino)-10-phenylphenazin-10-ium-2-yl]amino]-10-phenylphenazin-10-ium-2-yl]-8-N,10-diphenylphenazin-10-ium-2,8-diamine hydroxy-oxido-dioxochromium Chemical compound O[Cr]([O-])(=O)=O.O[Cr]([O-])(=O)=O.O[Cr]([O-])(=O)=O.Nc1ccc(Nc2ccc3nc4ccc(Nc5ccc6nc7ccc(Nc8ccc9nc%10ccc(Nc%11ccccc%11)cc%10[n+](-c%10ccccc%10)c9c8)cc7[n+](-c7ccccc7)c6c5)cc4[n+](-c4ccccc4)c3c2)cc1 FWLHAQYOFMQTHQ-UHFFFAOYSA-N 0.000 description 1
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- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 1
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- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- TZMACLAARXHRRZ-UHFFFAOYSA-N 2-hydroxypropane-1,2,3-tricarbohydrazide Chemical compound NNC(=O)CC(O)(C(=O)NN)CC(=O)NN TZMACLAARXHRRZ-UHFFFAOYSA-N 0.000 description 1
- CTHJQRHPNQEPAB-UHFFFAOYSA-N 2-methoxyethenylbenzene Chemical compound COC=CC1=CC=CC=C1 CTHJQRHPNQEPAB-UHFFFAOYSA-N 0.000 description 1
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- QCAHUFWKIQLBNB-UHFFFAOYSA-N 3-(3-methoxypropoxy)propan-1-ol Chemical compound COCCCOCCCO QCAHUFWKIQLBNB-UHFFFAOYSA-N 0.000 description 1
- MCDBEBOBROAQSH-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propyl prop-2-enoate Chemical compound CO[Si](C)(OC)CCCOC(=O)C=C MCDBEBOBROAQSH-UHFFFAOYSA-N 0.000 description 1
- XDQWJFXZTAWJST-UHFFFAOYSA-N 3-triethoxysilylpropyl prop-2-enoate Chemical compound CCO[Si](OCC)(OCC)CCCOC(=O)C=C XDQWJFXZTAWJST-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- NDWUBGAGUCISDV-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate Chemical compound OCCCCOC(=O)C=C NDWUBGAGUCISDV-UHFFFAOYSA-N 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Paints Or Removers (AREA)
Description
該水性分散体の動的光散乱法によって測定される平均粒子径は、該活性炭の平均細孔直径よりも大きいことを特徴とする水性塗料組成物が提供される。
スチレンや、メチルスチレン、クロロスチレン、メトキシスチレン等のスチレン系単量体;
2−ヒドロキシエチル(メタ)アクリレートや、2(3)−ヒドロキシプロピル(メタ)アクリレート、4−ヒドロキシブチルアクリレート、アリルアルコール多価アルコールのモノ(メタ)アクリル酸エステル等の水酸基含有単量体;
(メタ)アクリルアミドや、マレインアミド等のアミド基含有単量体;
2−アミノエチル(メタ)アクリレートや、ジメチルアミノエチル(メタ)アクリレート、3−アミノプロピル(メタ)アクリレート、2−ブチルアミノエチル(メタ)アクリレート、ビニルピリジン等のアミノ基含有単量体;
グリシジル(メタ)アクリレートや、アリルグリシジルエーテル、2個以上のグリシジル基を有するエポキシ化合物と活性水素原子を有するエチレン性不飽和単量体との反応により得られるエポキシ基含有単量体やオリゴノマー;
その他N−メチロール基を有したN−メチロールアクリルアミドや、酢酸ビニル、塩化ビニル、更には、エチレン、ブタジエン、アクリロニトリル、ジアルキルフマレート
等が代表的なものとして挙げられ、これらを適宜組み合わせて使用することができる。
乳化重合反応時の温度にて相互に反応する官能基を持つ単量体を組合せ、例えば、カルボキシル基とグリシジル基や、水酸基とイソシアネート基等の組合せの官能基を持つエチレン性不飽和単量体を選択含有させた単量体混合物を使用する方法;
加水分解縮合反応する、(メタ)アクリロキシプロピルトリメトキシシラン、や、(メタ)アクリロキシプロピルトリエトキシシラン、(メタ)アクリロキシプロピルメチルジメトキシシラン等のシリル基含有エチレン性不飽和単量体を含有させた単量体混合物を使用する方法;
を併用することも可能である。
ケイ酸塩、金属ケイ酸塩、モンロリロナイト、有機モンモリロナイト、コロイド状アルミナ等の無機系増粘剤;
ポリアクリル酸ソーダ、ポリアクリル酸−(メタ)アクリル酸エステル共重合体等のポリアクリル酸系増粘剤;
「UH−814N」、「UH−462」、「UH−420」、「UH−472」、「UH−540」(以上、旭電化社製)、「SNシックナー612」、「SNシックナー621N」、「SNシックナー625N」、「SNシックナー627N」(以上、サンノプコ社製)等のウレタン会合型増粘剤;
カルボキシメチルセルロース、メチルセルロース、ヒドロキシエチルセルロース等の繊維素誘導体系増粘剤;
カゼイン、カゼイン酸ソーダ、カゼイン酸アンモニウム等のタンパク質系増粘剤;
アルギン酸ソーダ等のアルギン酸系増粘剤;
ポリビニルアルコール、ポリビニルピロリドン、ポリビニルベンジルエーテル共重合体等のポリビニル系増粘剤;
プルロニックポリエーテル、ポリエーテルジアルキルエステル、ポリエーテルジアルキルエーテル、ポリエーテルエポキシ変性物等のポリエーテル系増粘剤;
ビニルメチルエーテル−無水マレイン酸共重合体の部分エステル等の無水マレイン酸共重合体系増粘剤;
ポリアマイドアミン塩等のポリアマイド系増粘剤
等を挙げることができ、これらは単独で又は2種以上組み合わせて使用することができる。
撹拌装置、温度計、冷却管及び滴下装置を備えた反応器中に、イオン交換水240部、炭酸水素ナトリウム塩(pH調整剤)0.5部、ポリオキシエチレン−1−(アリルオキシメチル)アルキルエーテル硫酸エステルアンモニウム塩(反応型アニオン性界面活性剤;第一工業製薬株式会社製アクアレンKH−10)2部をそれぞれ仕込み、反応器内部を窒素で置換しながら、80℃まで昇温した後、過硫酸カリウム(重合開始剤)1.5部を加え、続いて、予め別容器で撹拌混合しておいた表1に示す乳化物(a1〜a4)を、3時間かけて連続滴下し、滴下終了後、80℃で2時間攪拌を続けながら熟成し、40℃まで冷却した後、28%アンモニア水にてpH9.0に調整し、動的光散乱法によって測定される平均粒子径が、それぞれ100nm(最小値50nm)、95nm(最小値50nm)、105nm(最小値50nm)、90nm(最小値50nm)の水性樹脂分散体(A1〜A4)を得た。
撹拌装置、温度計、冷却管及び滴下装置を備えた反応器中に、イオン交換水525部、ポリオキシエチレン−1−(アリルオキシメチル)アルキルエーテル硫酸エステルアンモニウム塩(反応型アニオン性界面活性剤;第一工業製薬株式会社製アクアレンKH−10)10部をそれぞれ仕込み、反応器内部を窒素で置換しながら、80℃まで昇温した後、過硫酸カリウム(重合開始剤)1.5部を加え、続いて、予め別容器で撹拌混合しておいた表1に示す乳化物(a5)を、3時間かけて連続滴下し、滴下終了後、80℃で2時間撹拌を続けながら熟成し、40℃まで冷却した後、28%アンモニア水にてpH9.0に調整し、動的光散乱法によって測定された平均粒子径30nm(最小値5nm)、水性樹脂分散体(A5)を得た。
水性樹脂分散体(A1)の製造において、界面活性剤を非反応型アニオン性界面活性剤;ポリオキシエチレンジスチリル化フェニルエーテル硫酸アンモニウム(第一工業製薬製ハイテノールNF08)2部に変更し、表1に示す乳化物(a6)を滴下する以外は同様の手順によって、動的光散乱法によって測定された平均粒子径90nm(最小値50nm)の水性樹脂分散体(A6)を得た。
BA:アクリル酸ブチル
DAAM:ジアセトンアクリルアミド
AA:アクリル酸
KH10:第一工業製薬製反応型アニオン性界面活性剤
NF08:第一工業製薬製非反応型アニオン性界面活性剤
上記で得られた、水性樹脂分散体(A1〜A6)に、ヒドラジド基保有化学物質(B)として、アジピン酸ジヒドラジド及び、増粘剤として、Natrosol(Hercules Incorporated社製;ヒドロキシエチルセルロース系増粘剤)を60℃の湯で溶解した後、冷却したものを添加し撹拌機にて10分間撹拌を行った。その後、撹拌を続けながら活性炭(C1〜C2)及び、分散用界面活性剤としてノイゲンEA−157(第一工業製薬製ポリオキシエチレンスチレン化フェニルエーテル)を加え、更に、粘性調整として、プライマルRM8(Rohm and Haas Company製ウレタン会合型増粘剤)、防腐剤として、Proxel AM(アーチ・ケミカルズ・ジャパン株式会社)をそれぞれ添加した後、20分間撹拌し各水性塗料組成物を得た。詳細な配合比率及び、評価結果を表2に示す。
水性塗料組成物を50℃恒温機内へ1ヶ月間保管し、塗料の粘度及び外観を確認。塗料粘度はストーマー粘度計を用いて測定した。
評価基準
○;ストーマー粘度計による測定粘度が、初期値±5KUであり、沈殿等が確認されないこと。
△;沈殿、凝集等は確認されないが、ストーマー粘度計による測定粘度が、初期値±5よりも大きい場合
×;沈殿、凝集等が確認される。
水性塗料組成物をスレート板上に6milアプリケーターにて塗装し、23℃の室内にて1週間乾燥させた後、外観を確認した。
評価基準
○;割れ等が全く確認されない。
△;肉眼では確認できない微少な割れが局所的に発生している。
×;肉眼で全面に微少な割れが確認される。
23℃雰囲気下における引張試験を下地追従性試験として行った。試験方法は、JIS A6909に準拠し、膜厚が0.2mmのダンベル型試験片を作製した。島津製作所製オートグラフAG−I 100kNを用いて測定した。
評価基準
○;300%以上
△;100%以上、300%未満
×;100%未満
スレート板上に、6milアプリケーターで塗装した後、23℃室温下で1週間乾燥し、試験片を得た。その試験片をJIS A6909に準拠し、洗浄試験機にセットし、ブラシに約450gfの荷重を加えながら表面をこすった。500回ブラシを往復させた後、試験片を水で洗い、ブラシでこすった部分について表面の剥がれ及び磨耗による基板の露出の有無を目視観察する。
評価基準
○;塗膜表面上に剥がれや基材の露出が全く無い。
△;塗膜表面上の一部に剥がれや基材の露出がある。
×;塗膜の50%以上が剥がれや摩耗による露出が認められる。
・試験ガスの調整
試験ガス調整用テドラーバッグを用いて、アセトアルデヒド標準ガス(ガス濃度6,000ppm)を普通空気で希釈して3L(ガス濃度80〜100ppm)とする。その後、ミニコックを閉じてバッグ内のアセトアルデヒド濃度をより均一にするためにバッグの両端を交互に押して内部のガスを混合してから静置する。
・試験板の作製
面積が10×10cmのスレート板に水性塗料組成物を塗布量1.5gを間隔1時間をおいて2回塗装し、シリカゲルを入れたデシケーター内で1週間かけて乾燥させた。
・試験操作
評価用テドラーバッグの片面にそれぞれ切れ込みを入れ、そこから上記で作製した試験板を挿入し、出来るだけバッグ内の空気を排出した後、開口部をヒートシール装置で密閉した。その後、試験ガスを調整したテドラーバッグをシリコーンチューブで接続し、両方のバッグのコックを開いてから試験ガスを調整したバッグを手で押さえて試験ガスを試験片の入ったバッグに送り込む。その後速やかにコックを閉じて、室温23℃の部屋に30分間静置した後、アセトアルデヒド濃度を検知管を用いてガス濃度測定を2回行い、その平均値を初期値とした。但し、いずれの初期値も80〜100ppmの範囲から外れる場合は、試験ガスの調整からやり直した。
評価基準
○;アセトアルデヒド濃度が10ppm未満
△;アセトアルデヒド濃度が10ppm以上30ppm未満
×;アセトアルデヒド濃度が30ppm以上
Claims (3)
- α,β−エチレン性不飽和単量体と共重合可能な界面活性剤及び、カルボキシル基を有するエチレン性不飽和単量体を必須成分とし、カルボキシル基を除くカルボニル基を有するエチレン性不飽和単量体が0.5質量%〜10質量%共重合された水性樹脂分散体(A)であって、α,β−エチレン性不飽和単量体と共重合性を有さない非反応型界面活性剤が含まれていない水性樹脂分散体(A)、分子中にヒドラジド基を2個以上有する化合物(B)、及び活性炭(C)を含む水性塗料組成物であって、
該水性樹脂分散体(A)の動的光散乱法によって測定される平均粒子径は、該活性炭の平均細孔直径よりも大きく、
該α,β−エチレン性不飽和単量体と共重合可能な界面活性剤が、ポリオキシエチレン−1−(アリルオキシメチル)アルキルエーテル硫酸エステルアンモニウム塩、α−スルホ−ω−(1−(ノニルフェノキシ)メチル−2−(2−プロペニルオキシ)エトキシ)ポリ(オキシ−1,2−エタンジイル)アンモニウム塩、ポリオキシエチレンプロペニルアルキルフェニルエーテル硫酸エステルアンモニウム塩、及びポリオキシアルキレンアルケニルエーテル硫酸アンモニウム塩よりなる群から選択される少なくとも1種であり、
該カルボキシル基を除くカルボニル基を有するエチレン性不飽和単量体が、アクロレイン、ジアセトン(メタ)アクリルアミド、ホルミスチロール、(メタ)アクリルオキシアルキルプロパナール、ジアセトン(メタ)アクリレート、アセトニル(メタ)アクリレート、アセトアセトキシエチル(メタ)アクリレート、2−ヒドロキシプロピル(メタ)アクリレート−アセチルアセテート、ブタンジオール−1,4−アクリレート−アセチルアクリレート、ビニルメチルケトン、ビニルエチルケトン、及びビニルイソブチルケトンよりなる群から選択される少なくとも1種であることを特徴とする水性塗料組成物。 - 活性炭や着色顔料の分散用に用いられる界面活性剤及び、消泡剤や、防腐剤の添加剤に含まれる界面活性剤の総量が、塗料組成物100質量部に対し、3質量部以下である請求項1に記載の水性塗料組成物。
- 前記活性炭(C)が、粒径0.1〜10μmであり、温度1000〜1200℃で焼成している請求項1〜2のいずれかに記載の水性塗料組成物。
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JPH10140045A (ja) * | 1996-11-06 | 1998-05-26 | Lock Paint Kk | 被塗物中の有害物質の放散防止に有効な塗料組成物 |
JP2003073613A (ja) * | 2001-09-04 | 2003-03-12 | Kansai Paint Co Ltd | 水性塗料用樹脂組成物 |
JP4203845B2 (ja) * | 2002-10-31 | 2009-01-07 | 大日本塗料株式会社 | 水性塗料組成物 |
JP4410623B2 (ja) * | 2004-07-09 | 2010-02-03 | 関西ペイント株式会社 | 水性樹脂分散体の製造方法 |
JP5127021B2 (ja) * | 2006-07-11 | 2013-01-23 | 特種東海製紙株式会社 | 調湿性塗料 |
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