JP5485263B2 - ポリウレタンディスパージョン - Google Patents
ポリウレタンディスパージョン Download PDFInfo
- Publication number
- JP5485263B2 JP5485263B2 JP2011505971A JP2011505971A JP5485263B2 JP 5485263 B2 JP5485263 B2 JP 5485263B2 JP 2011505971 A JP2011505971 A JP 2011505971A JP 2011505971 A JP2011505971 A JP 2011505971A JP 5485263 B2 JP5485263 B2 JP 5485263B2
- Authority
- JP
- Japan
- Prior art keywords
- urethane prepolymer
- polyol
- gas barrier
- adhesive
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920003009 polyurethane dispersion Polymers 0.000 title claims description 49
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 137
- 230000004888 barrier function Effects 0.000 claims description 114
- 229920005862 polyol Polymers 0.000 claims description 104
- 150000003077 polyols Chemical class 0.000 claims description 93
- 239000000853 adhesive Substances 0.000 claims description 92
- 230000001070 adhesive effect Effects 0.000 claims description 92
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 86
- -1 alkane polyol Chemical class 0.000 claims description 58
- 238000006243 chemical reaction Methods 0.000 claims description 54
- 239000005056 polyisocyanate Substances 0.000 claims description 51
- 229920001228 polyisocyanate Polymers 0.000 claims description 51
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 38
- 239000004970 Chain extender Substances 0.000 claims description 33
- 229920006267 polyester film Polymers 0.000 claims description 30
- 239000006185 dispersion Substances 0.000 claims description 29
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 26
- 229920005989 resin Polymers 0.000 claims description 25
- 239000011347 resin Substances 0.000 claims description 25
- 239000002253 acid Substances 0.000 claims description 23
- 229920005749 polyurethane resin Polymers 0.000 claims description 22
- 239000011248 coating agent Substances 0.000 claims description 18
- 229920005906 polyester polyol Polymers 0.000 claims description 17
- 238000007740 vapor deposition Methods 0.000 claims description 16
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 14
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 14
- 229920002635 polyurethane Polymers 0.000 claims description 12
- 239000004814 polyurethane Substances 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 150000005846 sugar alcohols Polymers 0.000 claims description 11
- 150000007519 polyprotic acids Polymers 0.000 claims description 10
- 229920005992 thermoplastic resin Polymers 0.000 claims description 10
- 239000012948 isocyanate Substances 0.000 claims description 9
- 150000002513 isocyanates Chemical group 0.000 claims description 9
- 238000010030 laminating Methods 0.000 claims description 8
- 239000004840 adhesive resin Substances 0.000 claims description 7
- 229920006223 adhesive resin Polymers 0.000 claims description 7
- 125000005442 diisocyanate group Chemical group 0.000 claims description 6
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 claims description 5
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 5
- 239000007789 gas Substances 0.000 description 106
- 239000010408 film Substances 0.000 description 54
- 238000000034 method Methods 0.000 description 48
- 230000015572 biosynthetic process Effects 0.000 description 29
- 238000003786 synthesis reaction Methods 0.000 description 28
- 239000010410 layer Substances 0.000 description 23
- 238000002360 preparation method Methods 0.000 description 23
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 22
- 239000002245 particle Substances 0.000 description 20
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 19
- 229920001225 polyester resin Polymers 0.000 description 16
- 239000004645 polyester resin Substances 0.000 description 16
- 125000000129 anionic group Chemical group 0.000 description 15
- 239000003795 chemical substances by application Substances 0.000 description 15
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 14
- 238000000576 coating method Methods 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 13
- 238000010438 heat treatment Methods 0.000 description 13
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 13
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 11
- 238000005259 measurement Methods 0.000 description 11
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 10
- 238000002156 mixing Methods 0.000 description 10
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 8
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 8
- 239000002585 base Substances 0.000 description 8
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 8
- 229940117969 neopentyl glycol Drugs 0.000 description 8
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 8
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 7
- 125000003118 aryl group Chemical group 0.000 description 7
- 150000002009 diols Chemical class 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- 229920000768 polyamine Polymers 0.000 description 7
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 6
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 6
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 6
- 239000005058 Isophorone diisocyanate Substances 0.000 description 6
- 239000004721 Polyphenylene oxide Substances 0.000 description 6
- 125000001931 aliphatic group Chemical group 0.000 description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 238000006068 polycondensation reaction Methods 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- 229920000570 polyether Polymers 0.000 description 6
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 6
- 101001073193 Homo sapiens Pescadillo homolog Proteins 0.000 description 5
- 102100035816 Pescadillo homolog Human genes 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 5
- 125000002723 alicyclic group Chemical group 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229920000515 polycarbonate Polymers 0.000 description 5
- 239000004417 polycarbonate Substances 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- 238000001771 vacuum deposition Methods 0.000 description 5
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000004594 Masterbatch (MB) Substances 0.000 description 4
- 239000001361 adipic acid Substances 0.000 description 4
- 235000011037 adipic acid Nutrition 0.000 description 4
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000005540 biological transmission Effects 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 238000000151 deposition Methods 0.000 description 4
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 4
- DOVJROOSBVOVCS-UHFFFAOYSA-N ethane-1,1,1,2,2-pentol Chemical compound OC(O)C(O)(O)O DOVJROOSBVOVCS-UHFFFAOYSA-N 0.000 description 4
- 229910010272 inorganic material Inorganic materials 0.000 description 4
- 239000011147 inorganic material Substances 0.000 description 4
- 239000010954 inorganic particle Substances 0.000 description 4
- 239000005001 laminate film Substances 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- 239000011146 organic particle Substances 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 230000035699 permeability Effects 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000005809 transesterification reaction Methods 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 229940058015 1,3-butylene glycol Drugs 0.000 description 3
- 229940043375 1,5-pentanediol Drugs 0.000 description 3
- CFIHLFGSTIFVLP-UHFFFAOYSA-N 1-pentoxyethane-1,2-diol Chemical compound CCCCCOC(O)CO CFIHLFGSTIFVLP-UHFFFAOYSA-N 0.000 description 3
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 description 3
- SXFJDZNJHVPHPH-UHFFFAOYSA-N 3-methylpentane-1,5-diol Chemical compound OCCC(C)CCO SXFJDZNJHVPHPH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 125000005907 alkyl ester group Chemical group 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 150000001414 amino alcohols Chemical class 0.000 description 3
- 235000019437 butane-1,3-diol Nutrition 0.000 description 3
- 239000011247 coating layer Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000000539 dimer Substances 0.000 description 3
- 238000004945 emulsification Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- IZBNPGGKEWJZQN-UHFFFAOYSA-N ethane-1,1,1,2,2,2-hexol Chemical compound OC(O)(O)C(O)(O)O IZBNPGGKEWJZQN-UHFFFAOYSA-N 0.000 description 3
- 239000001530 fumaric acid Substances 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- IIRDTKBZINWQAW-UHFFFAOYSA-N hexaethylene glycol Chemical compound OCCOCCOCCOCCOCCOCCO IIRDTKBZINWQAW-UHFFFAOYSA-N 0.000 description 3
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- 230000003472 neutralizing effect Effects 0.000 description 3
- 239000012299 nitrogen atmosphere Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- AZYRZNIYJDKRHO-UHFFFAOYSA-N 1,3-bis(2-isocyanatopropan-2-yl)benzene Chemical compound O=C=NC(C)(C)C1=CC=CC(C(C)(C)N=C=O)=C1 AZYRZNIYJDKRHO-UHFFFAOYSA-N 0.000 description 2
- ICLCCFKUSALICQ-UHFFFAOYSA-N 1-isocyanato-4-(4-isocyanato-3-methylphenyl)-2-methylbenzene Chemical compound C1=C(N=C=O)C(C)=CC(C=2C=C(C)C(N=C=O)=CC=2)=C1 ICLCCFKUSALICQ-UHFFFAOYSA-N 0.000 description 2
- JVYDLYGCSIHCMR-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)butanoic acid Chemical compound CCC(CO)(CO)C(O)=O JVYDLYGCSIHCMR-UHFFFAOYSA-N 0.000 description 2
- OJRJDENLRJHEJO-UHFFFAOYSA-N 2,4-diethylpentane-1,5-diol Chemical compound CCC(CO)CC(CC)CO OJRJDENLRJHEJO-UHFFFAOYSA-N 0.000 description 2
- ULMZOZMSDIOZAF-UHFFFAOYSA-N 3-hydroxy-2-(hydroxymethyl)propanoic acid Chemical compound OCC(CO)C(O)=O ULMZOZMSDIOZAF-UHFFFAOYSA-N 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 2
- 239000004606 Fillers/Extenders Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 150000001463 antimony compounds Chemical class 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- BMRWNKZVCUKKSR-UHFFFAOYSA-N butane-1,2-diol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000012295 chemical reaction liquid Substances 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 238000003851 corona treatment Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- 208000028659 discharge Diseases 0.000 description 2
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- BXKDSDJJOVIHMX-UHFFFAOYSA-N edrophonium chloride Chemical compound [Cl-].CC[N+](C)(C)C1=CC=CC(O)=C1 BXKDSDJJOVIHMX-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- 150000002291 germanium compounds Chemical class 0.000 description 2
- 239000012760 heat stabilizer Substances 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 238000007733 ion plating Methods 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
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Classifications
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
- B32B2037/1276—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives water-based adhesive
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2170/00—Compositions for adhesives
- C08G2170/80—Compositions for aqueous adhesives
Description
合成例1
撹拌機、温度計、還流管、窒素導入管を備えた4つ口フラスコに、エステルA190.7重量部、ジエチレングリコール3.4重量部、ジメチロールプロピオン酸21.3重量部、メチルエチルケトン175.0重量部を仕込み、混合した。
表1に示す配合処方にて反応させた以外は、合成例1と同様の方法により、合成例2〜5の密着性ウレタンプレポリマーを調製した。但し、合成例2については、反応温度75℃、合成例3〜5については、反応温度70℃でそれぞれ反応させた。
合成例6
撹拌機、温度計、還流管、窒素導入管を備えた4つ口フラスコに、エチレングリコール46.7重量部、ジメチロールプロピオン酸20.7重量部、メチルエチルケトン175.0重量部を仕込み、混合した。
表1に示す配合処方にて反応させた以外は、合成例6と同様の方法により、合成例7のガスバリア性ウレタンプレポリマーを調製した。但し、反応温度を65℃とした。
H6XDI:1,3−ビス(イソシアナトメチル)シクロヘキサン(水添キシリレンジイソシアネート)
IPDI:3−イソシアナトメチル−3,5,5−トリメチルシクロヘキシルイソシアネート(イソホロンジイソシアネート)
XDI:1,3−キシリレンジイソシアネート
エステルA:ポリエステルポリオール((テレフタル酸/イソフタル酸/アジピン酸=1/1/1(モル比))/(エチレングリコール/ネオペンチルグリコール=1/1(モル比))、数平均分子量:3000)
エステルB:ポリエステルポリオール((イソフタル酸/セバシン酸=1/1(モル比))/(エチレングリコール/ネオペンチルグリコール=1/3(モル比))、数平均分子量2500)
エステルC:ポリエステルポリオール(アジピン酸/(ネオペンチルグリコール/1,6−ヘキサンジオール=2/1(モル比))、数平均分子量2000)
PTG2000:ポリテトラメチレンエーテルグリコール(数平均分子量:2000)
PC2000:ポリカーボネートグリコール(数平均分子量:2000)
EG:エチレングリコール
DEG:ジエチレングリコール
NPG:ネオペンチルグリコール
DMPA:ジメチロールプロピオン酸
TEA:トリエチルアミン
MET:メチルエチルケトン
スタノクト:オクチル酸第1スズ
また、表1中、NCO基含有率は、JISK1556(2006)に準拠して測定した。
調製例1(ガスバリア性樹脂の水分散液)
イオン交換水700重量部に、合成例6により得られたガスバリア性ウレタンプレポリマー415.6重量部を配合し、ホモディスパー(プライミクス社製)にて5分間撹拌し、水分散させた。
イオン交換水700重量部に、合成例1により得られた密着性ウレタンプレポリマー447.7重量部を配合し、ホモディスパーにて5分間撹拌し、水分散させた。
イオン交換水700重量部に、合成例1により得られた密着性ウレタンプレポリマー149.2重量部、および、合成例6により得られたガスバリア性ウレタンプレポリマー277.0重量部を配合し、ホモディスパーにて5分間撹拌し、水分散させた。
表2に示す配合処方にて反応させた以外は、調製例3と同様の方法により、調製例4〜7のポリウレタンディスパージョンを調製した。
実施例1
調製例1および調製例2のポリウレタンディスパージョンを、調製例2のポリウレタンディスパージョンの固形分に対する、調製例1のポリウレタンディスパージョンの固形分の重量比が3となるように配合し、次いで、水性ポリウレタン樹脂の固形分が5重量%となるようにイオン交換水に配合し、アンカーコート剤(AC1)を調製した。
表3に示す配合処方でアンカーコート剤を調製した以外は、実施例1と同様の方法により、実施例2〜6、および、比較例1〜2のアンカーコート剤を製造した。
(a)ポリエステル樹脂
テレフタル酸ジメチル100重量部、エチレングリコール61重量部の混合物に、酢酸マグネシウム0.04重量部、三酸化アンチモン0.02重量部を添加して、徐々に昇温し、最終的には220℃でメタノールを留出させながらエステル交換反応を行った。
上記の(a)においてポリエステルを製造する際、エステル交換反応後に、平均粒子径2.4μmの凝集シリカ粒子のエチレングリコールスラリーを添加してから重縮合反応を行い、粒子濃度2質量%の粒子マスターバッチを得た。
ポリエチレンテレフタレート樹脂と粒子マスターバッチを質量比98:2で混合し、その混合物を真空乾燥した後、押出機に供給して、280℃で溶融押出し、8μmカットのステンレス繊維焼結フィルター(FSS)で濾過した後、T字型口金からシート状に押出し、これを表面温度25℃の冷却ドラムに、静電密着法によって冷却固化させた。
(a)酸素透過率の測定
PES1〜PES8の蒸着ポリエステルフィルムの、23℃、0%RHにおける酸素透過率を、酸素透過率測定装置(オキストラン、モコン社製)を用い、JISK7126(2000)のB法(等圧法)に準拠して測定した。なお、測定は2回行い、それら2つの測定値の平均値を、PES1〜8における酸素透過率の値とした。
PES1〜PES8の蒸着ポリエステルフィルムの、40℃、90%RHにおける水蒸気透過率を、水蒸気透過率測定装置(パーマトラン、モコン社製)を用い、JISK7129(2000)のB法(赤外センサー法)に準拠して測定した。なお、測定は2回行い、それら2つの測定値の平均値を、PES1〜8における水蒸気透過率の値とした。
PES1〜PES8の蒸着ポリエステルフィルムの蒸着層側に、ポリウレタン系接着剤(A−310/A−3=10重量部/1重量部、溶媒として酢酸エチル12重量部、三井化学ポリウレタン社製)を用いて、未延伸ポリプロピレンフィルム(CPP、T3501、厚み50μm、東レ合成フィルム社製)を貼り合わせた。
PES1〜PES8の蒸着ポリエステルフィルムの蒸着層側に、ポリウレタン系接着剤(A−310/A−3=10重量部/1重量部、溶媒として酢酸エチル12重量部、三井化学ポリウレタン社製)を用いて、未延伸ポリプロピレンフィルム(CPP、T3501、厚み50μm、東レ合成フィルム社製)を貼り合わせた。
Claims (10)
- イソシアネート基末端ウレタンプレポリマーと、鎖伸長剤との反応により得られる水性ポリウレタン樹脂が、水分散されてなるポリウレタンディスパージョンであって、
前記イソシアネート基末端ウレタンプレポリマーが、密着性を付与するための密着性ウレタンプレポリマーと、ガスバリア性を付与するためのガスバリア性ウレタンプレポリマーとを含み、
前記密着性ウレタンプレポリマーは、ポリイソシアネート成分と、数平均分子量400以上の高分子量ポリオールを含むポリオール成分との反応により得られ、
前記ガスバリア性ウレタンプレポリマーは、ポリイソシアネート成分と、数平均分子量400以上の高分子量ポリオールを含まず、数平均分子量400未満の低分子量ポリオールを含むポリオール成分との反応により得られ、
熱可塑性樹脂フィルムの少なくとも片面に無機蒸着膜を積層および貼着するためのアンカーコート剤として用いられる
ことを特徴とする、ポリウレタンディスパージョン。 - 前記水性ポリウレタン樹脂が、前記密着性ウレタンプレポリマーおよび前記ガスバリア性ウレタンプレポリマーの混合物と、鎖伸長剤との反応により得られる密着性−ガスバリア性樹脂を含むことを特徴とする、請求項1に記載のポリウレタンディスパージョン。
- 前記水性ポリウレタン樹脂が、前記密着性ウレタンプレポリマーと、前記鎖伸長剤との反応により得られる密着性樹脂、および、前記ガスバリア性ウレタンプレポリマーと、前記鎖伸長剤との反応により得られるガスバリア性樹脂を含むことを特徴とする、請求項1に記載のポリウレタンディスパージョン。
- 前記密着性ウレタンプレポリマーを得るための前記ポリオール成分が、ポリエステルポリオール、および、ポリヒドロキシアルカン酸を含むことを特徴とする、請求項1に記載のポリウレタンディスパージョン。
- 前記ガスバリア性ウレタンプレポリマーを得るためのポリオール成分が、ポリヒドロキシアルカン酸を含む低分子量ポリオールからなることを特徴とする、請求項1に記載のポリウレタンディスパージョン。
- 前記ポリエステルポリオールが、分子中に環構造を有することを特徴とする、請求項4に記載のポリウレタンディスパージョン。
- 前記ポリエステルポリオールが、多塩基酸と、多価アルコールとの反応により得られ、
前記多塩基酸が、テレフタル酸、イソフタル酸およびオルソフタル酸からなる群から選択される少なくとも1種の多塩基酸であることを特徴とする、請求項4に記載のポリウレタンディスパージョン。 - 前記ポリイソシアネート成分が、芳香脂肪族ジイソシアネートおよび/または脂環族ジイソシアネートを含み、
前記低分子量ポリオールが、炭素数2〜6のアルカンポリオールおよび/または炭素数2〜6のポリオキシアルキレングリコールと、ポリヒドロキシアルカン酸とを含むことを特徴とする、請求項5に記載のポリウレタンディスパージョン。 - 前記ポリイソシアネート成分が、キシリレンジイソシアネートおよび/または水添キシリレンジイソシアネートを含むことを特徴とする、請求項8に記載のポリウレタンディスパージョン。
- 前記熱可塑性樹脂フィルムが、ポリエステルフィルムであることを特徴とする、請求項1に記載のポリウレタンディスパージョン。
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JPWO2010110076A1 (ja) | 2012-09-27 |
CN102333803B (zh) | 2013-11-27 |
KR101375414B1 (ko) | 2014-03-17 |
WO2010110076A1 (ja) | 2010-09-30 |
CN102333803A (zh) | 2012-01-25 |
US20120016075A1 (en) | 2012-01-19 |
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