JP5481495B2 - フッ素化イオノマーの核を有するフルオロポリマー粒子 - Google Patents
フッ素化イオノマーの核を有するフルオロポリマー粒子 Download PDFInfo
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- JP5481495B2 JP5481495B2 JP2011543668A JP2011543668A JP5481495B2 JP 5481495 B2 JP5481495 B2 JP 5481495B2 JP 2011543668 A JP2011543668 A JP 2011543668A JP 2011543668 A JP2011543668 A JP 2011543668A JP 5481495 B2 JP5481495 B2 JP 5481495B2
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- YSYRISKCBOPJRG-UHFFFAOYSA-N 4,5-difluoro-2,2-bis(trifluoromethyl)-1,3-dioxole Chemical compound FC1=C(F)OC(C(F)(F)F)(C(F)(F)F)O1 YSYRISKCBOPJRG-UHFFFAOYSA-N 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 6
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- PYLIXCKOHOHGKQ-UHFFFAOYSA-L disodium;hydrogen phosphate;heptahydrate Chemical compound O.O.O.O.O.O.O.[Na+].[Na+].OP([O-])([O-])=O PYLIXCKOHOHGKQ-UHFFFAOYSA-L 0.000 description 6
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- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 6
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- MKTOIPPVFPJEQO-UHFFFAOYSA-N 4-(3-carboxypropanoylperoxy)-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OOC(=O)CCC(O)=O MKTOIPPVFPJEQO-UHFFFAOYSA-N 0.000 description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 5
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- JMGNVALALWCTLC-UHFFFAOYSA-N 1-fluoro-2-(2-fluoroethenoxy)ethene Chemical compound FC=COC=CF JMGNVALALWCTLC-UHFFFAOYSA-N 0.000 description 4
- GVEUEBXMTMZVSD-UHFFFAOYSA-N 3,3,4,4,5,5,6,6,6-nonafluorohex-1-ene Chemical group FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C=C GVEUEBXMTMZVSD-UHFFFAOYSA-N 0.000 description 4
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- QMIWYOZFFSLIAK-UHFFFAOYSA-N 3,3,3-trifluoro-2-(trifluoromethyl)prop-1-ene Chemical group FC(F)(F)C(=C)C(F)(F)F QMIWYOZFFSLIAK-UHFFFAOYSA-N 0.000 description 3
- SLWGRAIAXWXVQY-UHFFFAOYSA-N 3-(2-ethoxypropoxy)prop-2-enenitrile Chemical compound CCOC(C)COC=CC#N SLWGRAIAXWXVQY-UHFFFAOYSA-N 0.000 description 3
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- UZUFPBIDKMEQEQ-UHFFFAOYSA-N perfluorononanoic acid Chemical compound OC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F UZUFPBIDKMEQEQ-UHFFFAOYSA-N 0.000 description 2
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- UVHZTXUBKSUXED-UHFFFAOYSA-N 2,3,3,3-tetrafluoro-2-(1,1,2,2,2-pentafluoroethoxy)propanoyl fluoride Chemical compound FC(=O)C(F)(C(F)(F)F)OC(F)(F)C(F)(F)F UVHZTXUBKSUXED-UHFFFAOYSA-N 0.000 description 1
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- AXMJGXMRGDCRND-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[4-(2,4,4-trimethylpentan-2-yl)cyclohexyl]oxyethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CC(C)(C)CC(C)(C)C1CCC(OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO)CC1 AXMJGXMRGDCRND-UHFFFAOYSA-N 0.000 description 1
- SVQOKUWDNBOKFD-UHFFFAOYSA-N 2-ethenoxyethanesulfonyl fluoride Chemical compound FS(=O)(=O)CCOC=C SVQOKUWDNBOKFD-UHFFFAOYSA-N 0.000 description 1
- PYIMQPQWCZJYNU-UHFFFAOYSA-N 2-propoxypropanoyl fluoride Chemical class CCCOC(C)C(F)=O PYIMQPQWCZJYNU-UHFFFAOYSA-N 0.000 description 1
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- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 1
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- 241000467686 Eschscholzia lobbii Species 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- 229920001410 Microfiber Polymers 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
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- 230000002378 acidificating effect Effects 0.000 description 1
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- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- ORBBVPFDROYXQS-UHFFFAOYSA-N ammonium perfluorononanoate Chemical compound N.OC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F ORBBVPFDROYXQS-UHFFFAOYSA-N 0.000 description 1
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- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
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- 239000012159 carrier gas Substances 0.000 description 1
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- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229910001902 chlorine oxide Inorganic materials 0.000 description 1
- QABCGOSYZHCPGN-UHFFFAOYSA-N chloro(dimethyl)silicon Chemical compound C[Si](C)Cl QABCGOSYZHCPGN-UHFFFAOYSA-N 0.000 description 1
- 238000004590 computer program Methods 0.000 description 1
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- 238000010411 cooking Methods 0.000 description 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 1
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- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920001198 elastomeric copolymer Polymers 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000004446 fluoropolymer coating Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
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- 230000005484 gravity Effects 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
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- 239000011229 interlayer Substances 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
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- 238000003754 machining Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
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- 239000003607 modifier Substances 0.000 description 1
- 125000002560 nitrile group Chemical group 0.000 description 1
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- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- ZWBAMYVPMDSJGQ-UHFFFAOYSA-N perfluoroheptanoic acid Chemical compound OC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F ZWBAMYVPMDSJGQ-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
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- 238000005070 sampling Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 238000006557 surface reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000001721 transfer moulding Methods 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/26—Tetrafluoroethene
- C08F214/265—Tetrafluoroethene with non-fluorinated comonomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/18—Monomers containing fluorine
- C08F14/26—Tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/08—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing fluorine
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B70/00—Technologies for an efficient end-user side electric power management and consumption
- Y02B70/10—Technologies improving the efficiency by using switched-mode power supplies [SMPS], i.e. efficient power electronics conversion e.g. power factor correction or reduction of losses in power supplies or efficient standby modes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
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| US14011508P | 2008-12-23 | 2008-12-23 | |
| US61/140,115 | 2008-12-23 | ||
| PCT/US2009/069368 WO2010075494A1 (en) | 2008-12-23 | 2009-12-23 | Fluoropolymer particles having a nucleus of fluorinated ionomer |
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| JP2012513532A JP2012513532A (ja) | 2012-06-14 |
| JP2012513532A5 JP2012513532A5 (enExample) | 2013-02-07 |
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| CN (1) | CN102264779B (enExample) |
| WO (1) | WO2010075494A1 (enExample) |
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| CN101998968B (zh) * | 2008-04-14 | 2012-08-29 | 旭硝子株式会社 | 聚四氟乙烯细粉的制造方法 |
| EP2935370A1 (en) | 2012-12-18 | 2015-10-28 | E. I. du Pont de Nemours and Company | Process for producing fluoroelastomers |
| CN109111663A (zh) * | 2013-07-30 | 2019-01-01 | 索尔维特殊聚合物意大利有限公司 | 含氟热塑性弹性体组合物 |
| CN106459546A (zh) * | 2014-06-04 | 2017-02-22 | 大金工业株式会社 | 聚四氟乙烯水性分散液 |
| US9902787B2 (en) | 2014-06-04 | 2018-02-27 | Daikin Industries, Ltd. | Polytetrafluoroethylene powder |
| KR102719413B1 (ko) * | 2017-03-17 | 2024-10-21 | 솔베이 스페셜티 폴리머스 이태리 에스.피.에이. | 플루오로중합체의 제조 방법 |
| JP7283383B2 (ja) * | 2017-06-05 | 2023-05-30 | Ａｇｃ株式会社 | 架橋性含フッ素弾性共重合体の製造方法 |
| US11767379B2 (en) | 2018-03-01 | 2023-09-26 | Daikin Industries, Ltd. | Method for manufacturing fluoropolymer |
| TWI821458B (zh) | 2018-11-19 | 2023-11-11 | 日商大金工業股份有限公司 | 組成物及拉伸體 |
| EP3885372A4 (en) | 2018-11-19 | 2022-08-17 | Daikin Industries, Ltd. | PROCESS FOR PRODUCTION OF MODIFIED POLYTETRAFLUORETHYLENE AND COMPOSITION |
| JP7417129B2 (ja) | 2019-04-26 | 2024-01-18 | ダイキン工業株式会社 | 水の処理方法および組成物 |
| WO2020218620A1 (ja) | 2019-04-26 | 2020-10-29 | ダイキン工業株式会社 | フルオロポリマー水性分散液の製造方法、排水の処理方法、及び、フルオロポリマー水性分散液 |
| CN120271939A (zh) | 2019-09-05 | 2025-07-08 | 大金工业株式会社 | 组合物及其制造方法 |
| JP7368759B2 (ja) | 2019-09-05 | 2023-10-25 | ダイキン工業株式会社 | パーフルオロエラストマーの製造方法および組成物 |
| WO2021100834A1 (ja) * | 2019-11-19 | 2021-05-27 | ダイキン工業株式会社 | ポリテトラフルオロエチレンの製造方法 |
| WO2021100836A1 (ja) | 2019-11-19 | 2021-05-27 | ダイキン工業株式会社 | フルオロポリマーの製造方法、ポリテトラフルオロエチレンの製造方法、パーフルオロエラストマーの製造方法および組成物 |
| CN114651019B (zh) | 2019-11-19 | 2024-11-08 | 大金工业株式会社 | 含氟聚合物的制造方法 |
| EP4249525A4 (en) | 2020-11-19 | 2024-10-16 | Daikin Industries, Ltd. | METHOD FOR PREPARING AN AQUEOUS PERFLUOROLASTOMER DISPERSION, COMPOSITION, CROSS-LINKABLE COMPOSITION AND CROSS-LINKED PRODUCT |
| CN116406386A (zh) | 2020-11-19 | 2023-07-07 | 大金工业株式会社 | 含氟弹性体水性分散液的制造方法和组合物 |
| JP7606110B2 (ja) | 2020-11-19 | 2024-12-25 | ダイキン工業株式会社 | ポリテトラフルオロエチレンの製造方法およびポリテトラフルオロエチレンを含有する組成物 |
| CN116981741A (zh) | 2021-03-10 | 2023-10-31 | 大金工业株式会社 | 涂料组合物、涂布膜、层积体和涂装物品 |
| EP4342921A4 (en) | 2021-05-19 | 2025-04-23 | Daikin Industries, Ltd. | Process for producing a fluoropolymer, process for producing polytetrafluoroethylene and composition |
| JP7741413B2 (ja) | 2021-06-11 | 2025-09-18 | ダイキン工業株式会社 | 含フッ素エラストマー水性分散液の製造方法、組成物および水性分散液 |
| WO2023277140A1 (ja) | 2021-06-30 | 2023-01-05 | ダイキン工業株式会社 | 高純度フルオロポリマー含有組成物の製造方法および高純度フルオロポリマー含有組成物 |
| CN117500848A (zh) | 2021-06-30 | 2024-02-02 | 大金工业株式会社 | 含氟聚合物组合物的制造方法和含氟聚合物组合物 |
| WO2023182229A1 (ja) | 2022-03-23 | 2023-09-28 | ダイキン工業株式会社 | フルオロポリマーの製造方法および組成物 |
| WO2023210819A1 (ja) | 2022-04-28 | 2023-11-02 | ダイキン工業株式会社 | フルオロポリマーの製造方法 |
| CN119072500A (zh) | 2022-04-28 | 2024-12-03 | 大金工业株式会社 | 含有氟树脂的组合物的制造方法和含有氟树脂的组合物 |
| WO2023210818A1 (ja) | 2022-04-28 | 2023-11-02 | ダイキン工業株式会社 | フッ素ゴムを含有する組成物 |
| CN120548621A (zh) | 2023-01-18 | 2025-08-26 | 大金工业株式会社 | 电化学器件用合剂、电化学器件用合剂片、电极和电化学器件 |
| CN120530501A (zh) | 2023-01-18 | 2025-08-22 | 大金工业株式会社 | 四氟乙烯系聚合物组合物、电化学器件用粘结剂、电极合剂、电极和二次电池 |
| JP2026504211A (ja) * | 2023-02-06 | 2026-02-03 | サイエンスコ スペシャルティ ポリマーズ イタリー エス．ピー．エー． | フルオロエラストマーを製造する方法 |
| CN121646623A (zh) | 2023-08-08 | 2026-03-10 | Ａｇｃ株式会社 | 含氟聚合物的制造方法、水性分散液、粒子和组合物 |
| CN121712842A (zh) | 2023-08-08 | 2026-03-20 | Ａｇｃ株式会社 | 含氟聚合物的制造方法、水性分散液、粒子和组合物 |
| CN121712810A (zh) | 2023-08-14 | 2026-03-20 | 大金工业株式会社 | 含氟聚合物水性分散液的制造方法和含氟聚合物水性分散液 |
| CN121752344A (zh) | 2023-08-28 | 2026-03-27 | 大金工业株式会社 | 水溶性含氟聚合物的回收方法 |
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| US2559752A (en) * | 1951-03-06 | 1951-07-10 | Du Pont | Aqueous colloidal dispersions of polymers |
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| US3037953A (en) * | 1961-04-26 | 1962-06-05 | Du Pont | Concentration of aqueous colloidal dispersions of polytetrafluoroethylene |
| US3271341A (en) * | 1961-08-07 | 1966-09-06 | Du Pont | Aqueous colloidal dispersions of polymer |
| US3282875A (en) * | 1964-07-22 | 1966-11-01 | Du Pont | Fluorocarbon vinyl ether polymers |
| US3291843A (en) * | 1963-10-08 | 1966-12-13 | Du Pont | Fluorinated vinyl ethers and their preparation |
| US3391099A (en) * | 1966-04-25 | 1968-07-02 | Du Pont | Polymerization process |
| GB1292268A (en) | 1970-02-16 | 1972-10-11 | Bitterfeld Chemie | Process for the dimerisation of hexafluoropropene epoxide |
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-
2009
- 2009-12-18 US US12/641,370 patent/US8835547B2/en not_active Expired - Fee Related
- 2009-12-23 WO PCT/US2009/069368 patent/WO2010075494A1/en not_active Ceased
- 2009-12-23 CN CN200980152413.9A patent/CN102264779B/zh not_active Expired - Fee Related
- 2009-12-23 EP EP09796262A patent/EP2370480B1/en not_active Revoked
- 2009-12-23 JP JP2011543668A patent/JP5481495B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP2370480A1 (en) | 2011-10-05 |
| JP2012513532A (ja) | 2012-06-14 |
| WO2010075494A1 (en) | 2010-07-01 |
| US8835547B2 (en) | 2014-09-16 |
| CN102264779A (zh) | 2011-11-30 |
| US20100160531A1 (en) | 2010-06-24 |
| EP2370480B1 (en) | 2013-01-23 |
| CN102264779B (zh) | 2014-01-08 |
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