JP5459842B2 - 架橋可能なアラミドコポリマー - Google Patents
架橋可能なアラミドコポリマー Download PDFInfo
- Publication number
- JP5459842B2 JP5459842B2 JP2009527042A JP2009527042A JP5459842B2 JP 5459842 B2 JP5459842 B2 JP 5459842B2 JP 2009527042 A JP2009527042 A JP 2009527042A JP 2009527042 A JP2009527042 A JP 2009527042A JP 5459842 B2 JP5459842 B2 JP 5459842B2
- Authority
- JP
- Japan
- Prior art keywords
- aramid copolymer
- moiety
- crosslinkable
- aramid
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920003235 aromatic polyamide Polymers 0.000 title claims description 54
- 239000004760 aramid Substances 0.000 title claims description 50
- 239000000203 mixture Substances 0.000 claims description 49
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 26
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 23
- 239000000178 monomer Substances 0.000 claims description 22
- 229920001577 copolymer Polymers 0.000 claims description 17
- 125000003118 aryl group Chemical group 0.000 claims description 16
- 239000003431 cross linking reagent Substances 0.000 claims description 13
- 229920000642 polymer Polymers 0.000 claims description 12
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 claims description 10
- 239000004971 Cross linker Substances 0.000 claims description 10
- 238000004132 cross linking Methods 0.000 claims description 9
- 229920002125 Sokalan® Polymers 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- LXEJRKJRKIFVNY-UHFFFAOYSA-N terephthaloyl chloride Chemical compound ClC(=O)C1=CC=C(C(Cl)=O)C=C1 LXEJRKJRKIFVNY-UHFFFAOYSA-N 0.000 claims description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- 239000004584 polyacrylic acid Substances 0.000 claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 6
- -1 hydroxyphenylene moiety Chemical group 0.000 claims description 5
- ZGDMDBHLKNQPSD-UHFFFAOYSA-N 2-amino-5-(4-amino-3-hydroxyphenyl)phenol Chemical compound C1=C(O)C(N)=CC=C1C1=CC=C(N)C(O)=C1 ZGDMDBHLKNQPSD-UHFFFAOYSA-N 0.000 claims description 3
- 239000000835 fiber Substances 0.000 claims description 3
- 125000002843 carboxylic acid group Chemical group 0.000 claims description 2
- UONVFNLDGRWLKF-UHFFFAOYSA-N 2,5-diaminobenzoic acid Chemical compound NC1=CC=C(N)C(C(O)=O)=C1 UONVFNLDGRWLKF-UHFFFAOYSA-N 0.000 claims 3
- VOGDKZZTBPDRBD-UHFFFAOYSA-N 2-[2-(4,5-dihydro-1,3-oxazol-2-yl)phenyl]-4,5-dihydro-1,3-oxazole Chemical compound O1CCN=C1C1=CC=CC=C1C1=NCCO1 VOGDKZZTBPDRBD-UHFFFAOYSA-N 0.000 claims 2
- 238000000465 moulding Methods 0.000 claims 1
- 238000007493 shaping process Methods 0.000 claims 1
- 238000009987 spinning Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 29
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 26
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 19
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 15
- 239000008367 deionised water Substances 0.000 description 14
- 229910021641 deionized water Inorganic materials 0.000 description 14
- 229910052757 nitrogen Inorganic materials 0.000 description 13
- 239000011521 glass Substances 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 7
- 229910001220 stainless steel Inorganic materials 0.000 description 7
- 239000010935 stainless steel Substances 0.000 description 7
- SXGMVGOVILIERA-UHFFFAOYSA-N (2R,3S)-2,3-diaminobutanoic acid Natural products CC(N)C(N)C(O)=O SXGMVGOVILIERA-UHFFFAOYSA-N 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- 239000002826 coolant Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 5
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 5
- 229920001228 polyisocyanate Polymers 0.000 description 4
- 239000005056 polyisocyanate Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229920000561 Twaron Polymers 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 125000005647 linker group Chemical group 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 3
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 150000001539 azetidines Chemical class 0.000 description 2
- 150000001541 aziridines Chemical class 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 150000007974 melamines Chemical class 0.000 description 2
- 150000002918 oxazolines Chemical class 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- VJSWHFHHDROXKV-UHFFFAOYSA-N 1,4-diaminocyclohexa-2,4-diene-1-carboxylic acid Chemical compound NC1=CCC(N)(C(O)=O)C=C1 VJSWHFHHDROXKV-UHFFFAOYSA-N 0.000 description 1
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 1
- CDMDQYCEEKCBGR-UHFFFAOYSA-N 1,4-diisocyanatocyclohexane Chemical compound O=C=NC1CCC(N=C=O)CC1 CDMDQYCEEKCBGR-UHFFFAOYSA-N 0.000 description 1
- SBJCUZQNHOLYMD-UHFFFAOYSA-N 1,5-Naphthalene diisocyanate Chemical compound C1=CC=C2C(N=C=O)=CC=CC2=C1N=C=O SBJCUZQNHOLYMD-UHFFFAOYSA-N 0.000 description 1
- LFSYUSUFCBOHGU-UHFFFAOYSA-N 1-isocyanato-2-[(4-isocyanatophenyl)methyl]benzene Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=CC=C1N=C=O LFSYUSUFCBOHGU-UHFFFAOYSA-N 0.000 description 1
- VZDIRINETBAVAV-UHFFFAOYSA-N 2,4-diisocyanato-1-methylcyclohexane Chemical compound CC1CCC(N=C=O)CC1N=C=O VZDIRINETBAVAV-UHFFFAOYSA-N 0.000 description 1
- GTVOOBOQZVIAQN-UHFFFAOYSA-N 2,5-diamino-4-hydroxybenzoic acid Chemical compound NC1=CC(C(O)=O)=C(N)C=C1O GTVOOBOQZVIAQN-UHFFFAOYSA-N 0.000 description 1
- RLXBOUUYEFOFSW-UHFFFAOYSA-N 2,5-diaminobenzene-1,4-diol Chemical compound NC1=CC(O)=C(N)C=C1O RLXBOUUYEFOFSW-UHFFFAOYSA-N 0.000 description 1
- XQRUEDXXCQDNOT-UHFFFAOYSA-N 2,5-diaminophenol Chemical compound NC1=CC=C(N)C(O)=C1 XQRUEDXXCQDNOT-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- KKKKCPPTESQGQH-UHFFFAOYSA-N 2-(4,5-dihydro-1,3-oxazol-2-yl)-4,5-dihydro-1,3-oxazole Chemical compound O1CCN=C1C1=NCCO1 KKKKCPPTESQGQH-UHFFFAOYSA-N 0.000 description 1
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- GRJYYSBCZGRTJY-UHFFFAOYSA-N 2-[2-[2-(4,5-dihydro-1,3-oxazol-2-yl)ethoxy]ethyl]-4,5-dihydro-1,3-oxazole Chemical compound N=1CCOC=1CCOCCC1=NCCO1 GRJYYSBCZGRTJY-UHFFFAOYSA-N 0.000 description 1
- GZQKJQLFIGBEIE-UHFFFAOYSA-N 2-[4-(4,5-dihydro-1,3-oxazol-2-yl)butyl]-4,5-dihydro-1,3-oxazole Chemical compound N=1CCOC=1CCCCC1=NCCO1 GZQKJQLFIGBEIE-UHFFFAOYSA-N 0.000 description 1
- ZDNUPMSZKVCETJ-UHFFFAOYSA-N 2-[4-(4,5-dihydro-1,3-oxazol-2-yl)phenyl]-4,5-dihydro-1,3-oxazole Chemical compound O1CCN=C1C1=CC=C(C=2OCCN=2)C=C1 ZDNUPMSZKVCETJ-UHFFFAOYSA-N 0.000 description 1
- QZWKEPYTBWZJJA-UHFFFAOYSA-N 3,3'-Dimethoxybenzidine-4,4'-diisocyanate Chemical compound C1=C(N=C=O)C(OC)=CC(C=2C=C(OC)C(N=C=O)=CC=2)=C1 QZWKEPYTBWZJJA-UHFFFAOYSA-N 0.000 description 1
- BTQLWKNIJDKIAB-UHFFFAOYSA-N 6-methylidene-n-phenylcyclohexa-2,4-dien-1-amine Chemical compound C=C1C=CC=CC1NC1=CC=CC=C1 BTQLWKNIJDKIAB-UHFFFAOYSA-N 0.000 description 1
- FJNCXZZQNBKEJT-UHFFFAOYSA-N 8beta-hydroxymarrubiin Natural products O1C(=O)C2(C)CCCC3(C)C2C1CC(C)(O)C3(O)CCC=1C=COC=1 FJNCXZZQNBKEJT-UHFFFAOYSA-N 0.000 description 1
- 229920003319 Araldite® Polymers 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Natural products OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 229920003270 Cymel® Polymers 0.000 description 1
- 229920000271 Kevlar® Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 229920001494 Technora Polymers 0.000 description 1
- OEOQTSUNXODXQL-UHFFFAOYSA-N [2-[3-(2-methylaziridin-1-yl)propanoyloxy]-2-[3-(2-methylaziridin-1-yl)propanoyloxymethyl]butyl] 3-(2-methylaziridin-1-yl)propanoate Chemical compound C1C(C)N1CCC(=O)OCC(OC(=O)CCN1C(C1)C)(CC)COC(=O)CCN1CC1C OEOQTSUNXODXQL-UHFFFAOYSA-N 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 150000004984 aromatic diamines Chemical class 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229940106691 bisphenol a Drugs 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000004761 kevlar Substances 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- CMDHNEAPXOZXBI-UHFFFAOYSA-N n-[4-[4-(hydroxyamino)phenyl]phenyl]hydroxylamine Chemical class C1=CC(NO)=CC=C1C1=CC=C(NO)C=C1 CMDHNEAPXOZXBI-UHFFFAOYSA-N 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004950 technora Substances 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 150000004998 toluenediamines Chemical class 0.000 description 1
- 239000004762 twaron Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
- C08G69/32—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from aromatic diamines and aromatic dicarboxylic acids with both amino and carboxylic groups aromatically bound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/48—Polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/10—Polyamides derived from aromatically bound amino and carboxyl groups of amino-carboxylic acids or of polyamines and polycarboxylic acids
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
- D01F6/80—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from copolyamides
- D01F6/805—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from copolyamides from aromatic copolyamides
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/90—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
- D01F6/905—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides of aromatic polyamides
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyamides (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06018906.5 | 2006-09-09 | ||
| EP06018906 | 2006-09-09 | ||
| PCT/EP2007/007653 WO2008028605A2 (en) | 2006-09-09 | 2007-09-01 | Crosslinkable aramid copolymers |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010502794A JP2010502794A (ja) | 2010-01-28 |
| JP2010502794A5 JP2010502794A5 (https=) | 2014-01-09 |
| JP5459842B2 true JP5459842B2 (ja) | 2014-04-02 |
Family
ID=37608697
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009527042A Expired - Fee Related JP5459842B2 (ja) | 2006-09-09 | 2007-09-01 | 架橋可能なアラミドコポリマー |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US8268937B2 (https=) |
| EP (1) | EP2064289A2 (https=) |
| JP (1) | JP5459842B2 (https=) |
| KR (1) | KR101473676B1 (https=) |
| CN (1) | CN101511938B (https=) |
| IL (1) | IL197063A (https=) |
| RU (1) | RU2446194C2 (https=) |
| WO (1) | WO2008028605A2 (https=) |
| ZA (1) | ZA200901206B (https=) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008150577A (ja) * | 2006-11-22 | 2008-07-03 | Teijin Ltd | 光学異方性ドープおよびその製造方法 |
| KR20110015567A (ko) * | 2008-04-25 | 2011-02-16 | 데이진 아라미드 비.브이. | 가교결합된 아라미드 중합체 |
| US9457496B2 (en) * | 2011-03-23 | 2016-10-04 | Akron Polymer Systems, Inc. | Aromatic polyamide films for transparent flexible substrates |
| TWI502006B (zh) * | 2011-06-29 | 2015-10-01 | Akron Polymer Systems Inc | 用於透明可撓性基材之芳香族聚醯胺薄膜 |
| US9856376B2 (en) * | 2011-07-05 | 2018-01-02 | Akron Polymer Systems, Inc. | Aromatic polyamide films for solvent resistant flexible substrates |
| WO2013019572A1 (en) | 2011-07-29 | 2013-02-07 | E. I. Du Pont De Nemours And Company | Process for forming an aramid copolymer |
| BR112014000536B8 (pt) | 2011-07-29 | 2023-02-28 | Du Pont | polímero |
| KR102160496B1 (ko) | 2011-08-19 | 2020-09-28 | 아크론 폴리머 시스템즈, 인코포레이티드 | 열안정성 저복굴절 코폴리이미드 필름 |
| US9963548B1 (en) * | 2012-04-24 | 2018-05-08 | Akron Polymer Systems, Inc. | Solvent resistant, aromatic polyamide films for transparent flexible substrates |
| EP2676987A1 (en) * | 2012-06-21 | 2013-12-25 | Universidad De Burgos | Cross-linked aramid |
| JP6204478B2 (ja) * | 2012-09-24 | 2017-09-27 | アクロン ポリマー システムズ，インク． | ポリアミド溶液、ディスプレイ用素子、光学用素子、又は照明用素子の製造方法、およびポリアミド溶液の製造方法 |
| JP2015529284A (ja) * | 2012-09-24 | 2015-10-05 | アクロン ポリマー システムズ，インク． | ディスプレイ用素子、光学用素子、又は照明用素子の製造のための芳香族ポリアミド溶液 |
| KR101988050B1 (ko) * | 2012-12-06 | 2019-06-11 | 도레이케미칼 주식회사 | 메타아라미드 공중합체 및 이를 통해 제조된 메타아라미드 필름 |
| WO2014105890A1 (en) * | 2012-12-26 | 2014-07-03 | Akron Polymer Systems, Inc. | Aromatic polyamide films for solvent resistant flexible substrates |
| EP3040455B1 (en) * | 2013-08-30 | 2018-07-04 | Nissan Chemical Industries, Ltd. | Fiber-forming composition and bio-compatible material using said fiber |
| KR20160068798A (ko) * | 2013-10-04 | 2016-06-15 | 아크론 폴리머 시스템즈, 인코포레이티드 | 수지 조성물, 기판, 전자장치를 제조하는 방법 및 전자장치 |
| US20150266999A1 (en) * | 2014-03-18 | 2015-09-24 | Light Polymers B.V. | Insolubilization of water-soluble polyaramide by cross-linking with polyfunctional aziridine |
| US9829617B2 (en) | 2014-11-10 | 2017-11-28 | Light Polymers Holding | Polymer-small molecule film or coating having reverse or flat dispersion of retardation |
| US9856172B2 (en) | 2015-08-25 | 2018-01-02 | Light Polymers Holding | Concrete formulation and methods of making |
| CN109950456B (zh) * | 2017-12-20 | 2022-01-18 | 微宏动力系统（湖州）有限公司 | 一种芳族聚酰胺浆料、多孔隔膜及其制备方法 |
| US10962696B2 (en) | 2018-01-31 | 2021-03-30 | Light Polymers Holding | Coatable grey polarizer |
| CN108659527B (zh) * | 2018-05-02 | 2021-01-05 | 元源新材料有限公司 | 一种高强度玻纤复合材料及其制备方法 |
| KR102265389B1 (ko) | 2018-05-04 | 2021-06-14 | 주식회사 엘지화학 | 폴리아미드 필름 적층체 |
| US11370914B2 (en) | 2018-07-24 | 2022-06-28 | Light Polymers Holding | Methods of forming polymeric polarizers from lyotropic liquid crystals and polymeric polarizers formed thereby |
| US12072520B2 (en) | 2021-11-11 | 2024-08-27 | Light Polymers Holding | Linear polarizers and methods of forming a linear polarizer |
| CN117363007B (zh) * | 2023-12-08 | 2024-02-23 | 烟台泰和新材高分子新材料研究院有限公司 | 一种改性芳纶原液及其制备方法和用途 |
| JP2025109588A (ja) * | 2024-01-12 | 2025-07-25 | 太陽ホールディングス株式会社 | ポリヒドロキシアミド化合物、感光性樹脂組成物、ドライフィルム、硬化物および電子部品 |
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| US3386965A (en) | 1964-08-31 | 1968-06-04 | Monsanto Co | Aromatic polyamides having pendent carboxyl groups and process therefor |
| US3904519A (en) * | 1971-10-19 | 1975-09-09 | Us Interior | Reverse osmosis process using crosslinked aromatic polyamide membranes |
| JPS5543367B2 (https=) | 1975-01-08 | 1980-11-06 | ||
| NL172680C (nl) | 1979-06-08 | 1983-10-03 | Akzo Nv | Werkwijze ter vervaardiging van vezels uit poly-p-fenyleentereftaalamide en de aldus vervaardigde produkten. |
| JPS63199262A (ja) * | 1987-02-13 | 1988-08-17 | Sekisui Chem Co Ltd | ポリアミド組成物 |
| US5212258A (en) * | 1991-10-29 | 1993-05-18 | E. I Du Pont De Nemours And Company | Aramid block copolymers |
| JPH05194731A (ja) * | 1992-01-22 | 1993-08-03 | Teijin Ltd | 全芳香族ポリアミド成形物 |
| JP3410649B2 (ja) * | 1997-11-25 | 2003-05-26 | 株式会社巴川製紙所 | 導電性組成物およびそれを用いた面状発熱体 |
| JP3532749B2 (ja) * | 1997-12-29 | 2004-05-31 | 株式会社巴川製紙所 | 導電性組成物、それを用いた導電性接着剤 |
| RU2213814C2 (ru) * | 2000-12-29 | 2003-10-10 | ООО Научно-производственная фирма "Термостойкие изделия" | Способ получения полиоксадиазольного волокна или нити |
| DE10137376A1 (de) | 2001-07-31 | 2003-02-27 | Infineon Technologies Ag | Geklebte Chip- und Waferstapel |
| JP2006310574A (ja) * | 2005-04-28 | 2006-11-09 | Nippon Kayaku Co Ltd | 両面フレキシブルプリント基板の製造法及び両面フレキシブルプリント基板。 |
| US9480154B2 (en) * | 2005-07-21 | 2016-10-25 | Nippon Kayaku Kabushiki Kaisha | Polyamide resin, epoxy resin compositions, and cured articles thereof |
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2007
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- 2007-09-01 JP JP2009527042A patent/JP5459842B2/ja not_active Expired - Fee Related
- 2007-09-01 RU RU2009113171/05A patent/RU2446194C2/ru not_active IP Right Cessation
- 2007-09-01 WO PCT/EP2007/007653 patent/WO2008028605A2/en not_active Ceased
- 2007-09-01 US US12/310,135 patent/US8268937B2/en not_active Expired - Fee Related
- 2007-09-01 KR KR1020097007264A patent/KR101473676B1/ko not_active Expired - Fee Related
- 2007-09-01 EP EP07802070A patent/EP2064289A2/en not_active Withdrawn
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| ZA200901206B (en) | 2010-03-31 |
| US20090318660A1 (en) | 2009-12-24 |
| IL197063A (en) | 2013-02-28 |
| RU2009113171A (ru) | 2010-10-20 |
| CN101511938A (zh) | 2009-08-19 |
| US8268937B2 (en) | 2012-09-18 |
| WO2008028605A2 (en) | 2008-03-13 |
| CN101511938B (zh) | 2012-10-10 |
| KR20090053947A (ko) | 2009-05-28 |
| WO2008028605A3 (en) | 2008-07-03 |
| KR101473676B1 (ko) | 2014-12-18 |
| IL197063A0 (en) | 2009-11-18 |
| RU2446194C2 (ru) | 2012-03-27 |
| JP2010502794A (ja) | 2010-01-28 |
| EP2064289A2 (en) | 2009-06-03 |
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