JP5384940B2 - 飽和および不飽和アルデヒドの不飽和カルボン酸への酸化のための触媒およびその製造方法と使用方法 - Google Patents
飽和および不飽和アルデヒドの不飽和カルボン酸への酸化のための触媒およびその製造方法と使用方法 Download PDFInfo
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- JP5384940B2 JP5384940B2 JP2008547537A JP2008547537A JP5384940B2 JP 5384940 B2 JP5384940 B2 JP 5384940B2 JP 2008547537 A JP2008547537 A JP 2008547537A JP 2008547537 A JP2008547537 A JP 2008547537A JP 5384940 B2 JP5384940 B2 JP 5384940B2
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- Prior art keywords
- compound
- heteropolyacid
- solid particles
- molybdenum
- inert
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
- B01J27/198—Vanadium
- B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/34—Mechanical properties
- B01J35/37—Crush or impact strength
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
- B01J2235/15—X-ray diffraction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/34—Mechanical properties
- B01J35/36—Mechanical strength
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/316,211 | 2005-12-22 | ||
| US11/316,211 US7273829B2 (en) | 2005-12-22 | 2005-12-22 | Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof |
| PCT/US2006/048757 WO2007073492A2 (en) | 2005-12-22 | 2006-12-22 | Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009521316A JP2009521316A (ja) | 2009-06-04 |
| JP2009521316A5 JP2009521316A5 (enExample) | 2010-02-12 |
| JP5384940B2 true JP5384940B2 (ja) | 2014-01-08 |
Family
ID=38189123
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008547537A Expired - Fee Related JP5384940B2 (ja) | 2005-12-22 | 2006-12-22 | 飽和および不飽和アルデヒドの不飽和カルボン酸への酸化のための触媒およびその製造方法と使用方法 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US7273829B2 (enExample) |
| EP (1) | EP1971565B1 (enExample) |
| JP (1) | JP5384940B2 (enExample) |
| WO (1) | WO2007073492A2 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8481448B2 (en) * | 2010-07-19 | 2013-07-09 | Saudi Basic Industries Corporation | Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof |
| JP6653871B2 (ja) * | 2015-03-11 | 2020-02-26 | 国立大学法人北海道大学 | メタクリル酸製造用触媒及びその製造方法、並びにメタクリル酸の製造方法 |
| CN110062656B (zh) * | 2016-12-12 | 2022-05-13 | 三菱化学株式会社 | α,β-不饱和羧酸制造用催化剂前体的制造方法 |
| CN108906123A (zh) * | 2018-07-03 | 2018-11-30 | 上海应用技术大学 | 一种杂多酸-氧化石墨烯复合催化材料、制备方法及其应用 |
| KR102876188B1 (ko) * | 2020-09-03 | 2025-10-27 | 가부시키가이샤 닛폰 쇼쿠바이 | 아크릴산 제조용 촉매와 그의 제조 방법 및 아크릴산의 제조 방법 |
| CN114276850B (zh) * | 2021-12-24 | 2023-02-07 | 安徽工业大学 | 一种氟掺杂石墨烯负载Pb复合材料及其制备方法和应用 |
| CN116196950B (zh) * | 2023-02-16 | 2024-05-24 | 北华大学 | 一种双金属掺杂杂多酸催化剂的合成方法及在木质素转化中的应用 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5413876B2 (enExample) * | 1974-10-23 | 1979-06-02 | ||
| US4118419A (en) * | 1975-12-03 | 1978-10-03 | Mitsubishi Rayon Company, Ltd. | Catalytic process for the preparation of an unsaturated carboxylic acid |
| JPS60232247A (ja) * | 1984-05-02 | 1985-11-18 | Nippon Shokubai Kagaku Kogyo Co Ltd | ヘテロポリ酸系触媒の再生方法 |
| JP2574948B2 (ja) * | 1990-02-08 | 1997-01-22 | 株式会社日本触媒 | メタクリル酸の製造方法 |
| DE4022212A1 (de) * | 1990-07-12 | 1992-01-16 | Basf Ag | Massen der allgemeinen formel mo(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)2(pfeil abwaerts)(pfeil hoch)p(pfeil hoch)(pfeil abwaerts)a(pfeil abwaerts)(pfeil hoch)v(pfeil hoch)(pfeil abwaerts)b(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)1(pfeil hoch)(pfeil abwaerts)c(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)2(pfeil hoch)(pfeil abwaerts)d(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)3(pfeil hoch)(pfeil abwaerts)e(pfeil abwaerts)(pfeil hoch)s(pfeil hoch)(pfeil hoch)b(pfeil hoch)(pfeil abwaerts)f(pfeil abwaerts)(pfeil hoch)r(pfeil hoch)(pfeil hoch)e(pfeil hoch)(pfeil abwaerts)g(pfeil abwaerts)(pfeil hoch)s(pfeil hoch)(pfeil abwaerts)h(pfeil abwaerts)(pfeil hoch)o(pfeil hoch)(pfeil abwaerts)n(pfeil abwaerts) |
| US5198579A (en) * | 1990-11-14 | 1993-03-30 | Mitsui Toatsu Chemicals, Inc. | Catalyst for oxidizing methacrolein and method for preparing methacrylic acid |
| JPH0531368A (ja) * | 1990-11-14 | 1993-02-09 | Mitsui Toatsu Chem Inc | メタクリル酸製造用触媒及びメタクリル酸の製造方法 |
| TW349033B (en) | 1994-05-31 | 1999-01-01 | Nippon Catalytic Chem Ind | Catalyst for production of methacrylic acid and method for production of methacrylic acid by the use of the catalysta catalyst for the production of methacrylic acid by the vapor-phase catalytic oxidation and/or oxidative dehydrogenation of at least one compound |
| JPH08157414A (ja) * | 1994-12-01 | 1996-06-18 | Mitsui Toatsu Chem Inc | メタクリル酸製造用触媒及びメタクリル酸の製造方法 |
| JP3370589B2 (ja) * | 1997-12-25 | 2003-01-27 | 三菱レイヨン株式会社 | メタクリル酸製造用触媒およびそれを用いたメタクリル酸の製造法 |
| US6060419A (en) * | 1998-01-05 | 2000-05-09 | Sunoco, Inc. (R&M) | Wells-Dawson type heteropolyacids, their preparation and use as oxidation catalysts |
| US5990348A (en) | 1998-01-05 | 1999-11-23 | Sunoco, Inc. | Conversion of alkanes to unsaturated carboxylic acids over heteroploy acids supported on polyoxometallate salts |
| US6043184A (en) | 1998-01-05 | 2000-03-28 | Sunoco, Inc. (R&M) | Heteropoly acids supported on polyoxometallate salts and their preparation |
| BR0013338B1 (pt) * | 1999-08-19 | 2012-01-24 | catalizador de leito fluidificado para a amoxidacão de propileno para acrilonitrila. | |
| US6387841B1 (en) * | 1999-08-23 | 2002-05-14 | Rohm And Haas Company | Polyoxometallate supported catalysts |
| WO2002024328A1 (en) * | 2000-09-21 | 2002-03-28 | Nippon Kayaku Kabushiki Kaisha | Catalyst for methacrylic acid production, coated catalyst, and process for producing the same |
| JP4022047B2 (ja) * | 2001-02-07 | 2007-12-12 | 三菱レイヨン株式会社 | メタクリル酸合成用触媒の製造方法、メタクリル酸合成用触媒およびメタクリル酸の製造方法 |
| JP4634633B2 (ja) * | 2001-03-30 | 2011-02-16 | 三菱レイヨン株式会社 | 不飽和カルボン酸合成用触媒、その調製方法、およびその触媒を用いた不飽和カルボン酸の合成方法 |
| JP2002306970A (ja) * | 2001-04-12 | 2002-10-22 | Mitsubishi Rayon Co Ltd | メタクリル酸製造用触媒、その製造方法、および、メタクリル酸の製造方法 |
| MY144325A (en) * | 2003-02-20 | 2011-08-29 | Nippon Kayaku Kk | Catalyst for producing methacrylic acid and preparation method thereof |
-
2005
- 2005-12-22 US US11/316,211 patent/US7273829B2/en not_active Expired - Lifetime
-
2006
- 2006-12-22 EP EP06848678.6A patent/EP1971565B1/en not_active Not-in-force
- 2006-12-22 WO PCT/US2006/048757 patent/WO2007073492A2/en not_active Ceased
- 2006-12-22 JP JP2008547537A patent/JP5384940B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP1971565A2 (en) | 2008-09-24 |
| JP2009521316A (ja) | 2009-06-04 |
| EP1971565B1 (en) | 2016-09-28 |
| WO2007073492A9 (en) | 2007-08-09 |
| US7273829B2 (en) | 2007-09-25 |
| US20070149806A1 (en) | 2007-06-28 |
| EP1971565A4 (en) | 2012-01-04 |
| WO2007073492A3 (en) | 2007-11-22 |
| WO2007073492A2 (en) | 2007-06-28 |
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