JP5384940B2 - 飽和および不飽和アルデヒドの不飽和カルボン酸への酸化のための触媒およびその製造方法と使用方法 - Google Patents

飽和および不飽和アルデヒドの不飽和カルボン酸への酸化のための触媒およびその製造方法と使用方法 Download PDF

Info

Publication number
JP5384940B2
JP5384940B2 JP2008547537A JP2008547537A JP5384940B2 JP 5384940 B2 JP5384940 B2 JP 5384940B2 JP 2008547537 A JP2008547537 A JP 2008547537A JP 2008547537 A JP2008547537 A JP 2008547537A JP 5384940 B2 JP5384940 B2 JP 5384940B2
Authority
JP
Japan
Prior art keywords
compound
heteropolyacid
solid particles
molybdenum
inert
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2008547537A
Other languages
English (en)
Japanese (ja)
Other versions
JP2009521316A (ja
JP2009521316A5 (enExample
Inventor
リアン,ウーゴン
エイ スティーヴンソン,スコット
アール リンザー,ジョーゼフ
Original Assignee
サウディ ベーシック インダストリーズ コーポレイション
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by サウディ ベーシック インダストリーズ コーポレイション filed Critical サウディ ベーシック インダストリーズ コーポレイション
Publication of JP2009521316A publication Critical patent/JP2009521316A/ja
Publication of JP2009521316A5 publication Critical patent/JP2009521316A5/ja
Application granted granted Critical
Publication of JP5384940B2 publication Critical patent/JP5384940B2/ja
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002Mixed oxides other than spinels, e.g. perovskite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • B01J27/186Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198Vanadium
    • B01J27/199Vanadium with chromium, molybdenum, tungsten or polonium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34Mechanical properties
    • B01J35/37Crush or impact strength
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15X-ray diffraction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34Mechanical properties
    • B01J35/36Mechanical strength

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2008547537A 2005-12-22 2006-12-22 飽和および不飽和アルデヒドの不飽和カルボン酸への酸化のための触媒およびその製造方法と使用方法 Expired - Fee Related JP5384940B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/316,211 2005-12-22
US11/316,211 US7273829B2 (en) 2005-12-22 2005-12-22 Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof
PCT/US2006/048757 WO2007073492A2 (en) 2005-12-22 2006-12-22 Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof

Publications (3)

Publication Number Publication Date
JP2009521316A JP2009521316A (ja) 2009-06-04
JP2009521316A5 JP2009521316A5 (enExample) 2010-02-12
JP5384940B2 true JP5384940B2 (ja) 2014-01-08

Family

ID=38189123

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2008547537A Expired - Fee Related JP5384940B2 (ja) 2005-12-22 2006-12-22 飽和および不飽和アルデヒドの不飽和カルボン酸への酸化のための触媒およびその製造方法と使用方法

Country Status (4)

Country Link
US (1) US7273829B2 (enExample)
EP (1) EP1971565B1 (enExample)
JP (1) JP5384940B2 (enExample)
WO (1) WO2007073492A2 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8481448B2 (en) * 2010-07-19 2013-07-09 Saudi Basic Industries Corporation Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof
JP6653871B2 (ja) * 2015-03-11 2020-02-26 国立大学法人北海道大学 メタクリル酸製造用触媒及びその製造方法、並びにメタクリル酸の製造方法
CN110062656B (zh) * 2016-12-12 2022-05-13 三菱化学株式会社 α,β-不饱和羧酸制造用催化剂前体的制造方法
CN108906123A (zh) * 2018-07-03 2018-11-30 上海应用技术大学 一种杂多酸-氧化石墨烯复合催化材料、制备方法及其应用
KR102876188B1 (ko) * 2020-09-03 2025-10-27 가부시키가이샤 닛폰 쇼쿠바이 아크릴산 제조용 촉매와 그의 제조 방법 및 아크릴산의 제조 방법
CN114276850B (zh) * 2021-12-24 2023-02-07 安徽工业大学 一种氟掺杂石墨烯负载Pb复合材料及其制备方法和应用
CN116196950B (zh) * 2023-02-16 2024-05-24 北华大学 一种双金属掺杂杂多酸催化剂的合成方法及在木质素转化中的应用

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5413876B2 (enExample) * 1974-10-23 1979-06-02
US4118419A (en) * 1975-12-03 1978-10-03 Mitsubishi Rayon Company, Ltd. Catalytic process for the preparation of an unsaturated carboxylic acid
JPS60232247A (ja) * 1984-05-02 1985-11-18 Nippon Shokubai Kagaku Kogyo Co Ltd ヘテロポリ酸系触媒の再生方法
JP2574948B2 (ja) * 1990-02-08 1997-01-22 株式会社日本触媒 メタクリル酸の製造方法
DE4022212A1 (de) * 1990-07-12 1992-01-16 Basf Ag Massen der allgemeinen formel mo(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)2(pfeil abwaerts)(pfeil hoch)p(pfeil hoch)(pfeil abwaerts)a(pfeil abwaerts)(pfeil hoch)v(pfeil hoch)(pfeil abwaerts)b(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)1(pfeil hoch)(pfeil abwaerts)c(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)2(pfeil hoch)(pfeil abwaerts)d(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)3(pfeil hoch)(pfeil abwaerts)e(pfeil abwaerts)(pfeil hoch)s(pfeil hoch)(pfeil hoch)b(pfeil hoch)(pfeil abwaerts)f(pfeil abwaerts)(pfeil hoch)r(pfeil hoch)(pfeil hoch)e(pfeil hoch)(pfeil abwaerts)g(pfeil abwaerts)(pfeil hoch)s(pfeil hoch)(pfeil abwaerts)h(pfeil abwaerts)(pfeil hoch)o(pfeil hoch)(pfeil abwaerts)n(pfeil abwaerts)
US5198579A (en) * 1990-11-14 1993-03-30 Mitsui Toatsu Chemicals, Inc. Catalyst for oxidizing methacrolein and method for preparing methacrylic acid
JPH0531368A (ja) * 1990-11-14 1993-02-09 Mitsui Toatsu Chem Inc メタクリル酸製造用触媒及びメタクリル酸の製造方法
TW349033B (en) 1994-05-31 1999-01-01 Nippon Catalytic Chem Ind Catalyst for production of methacrylic acid and method for production of methacrylic acid by the use of the catalysta catalyst for the production of methacrylic acid by the vapor-phase catalytic oxidation and/or oxidative dehydrogenation of at least one compound
JPH08157414A (ja) * 1994-12-01 1996-06-18 Mitsui Toatsu Chem Inc メタクリル酸製造用触媒及びメタクリル酸の製造方法
JP3370589B2 (ja) * 1997-12-25 2003-01-27 三菱レイヨン株式会社 メタクリル酸製造用触媒およびそれを用いたメタクリル酸の製造法
US6060419A (en) * 1998-01-05 2000-05-09 Sunoco, Inc. (R&M) Wells-Dawson type heteropolyacids, their preparation and use as oxidation catalysts
US5990348A (en) 1998-01-05 1999-11-23 Sunoco, Inc. Conversion of alkanes to unsaturated carboxylic acids over heteroploy acids supported on polyoxometallate salts
US6043184A (en) 1998-01-05 2000-03-28 Sunoco, Inc. (R&M) Heteropoly acids supported on polyoxometallate salts and their preparation
BR0013338B1 (pt) * 1999-08-19 2012-01-24 catalizador de leito fluidificado para a amoxidacão de propileno para acrilonitrila.
US6387841B1 (en) * 1999-08-23 2002-05-14 Rohm And Haas Company Polyoxometallate supported catalysts
WO2002024328A1 (en) * 2000-09-21 2002-03-28 Nippon Kayaku Kabushiki Kaisha Catalyst for methacrylic acid production, coated catalyst, and process for producing the same
JP4022047B2 (ja) * 2001-02-07 2007-12-12 三菱レイヨン株式会社 メタクリル酸合成用触媒の製造方法、メタクリル酸合成用触媒およびメタクリル酸の製造方法
JP4634633B2 (ja) * 2001-03-30 2011-02-16 三菱レイヨン株式会社 不飽和カルボン酸合成用触媒、その調製方法、およびその触媒を用いた不飽和カルボン酸の合成方法
JP2002306970A (ja) * 2001-04-12 2002-10-22 Mitsubishi Rayon Co Ltd メタクリル酸製造用触媒、その製造方法、および、メタクリル酸の製造方法
MY144325A (en) * 2003-02-20 2011-08-29 Nippon Kayaku Kk Catalyst for producing methacrylic acid and preparation method thereof

Also Published As

Publication number Publication date
EP1971565A2 (en) 2008-09-24
JP2009521316A (ja) 2009-06-04
EP1971565B1 (en) 2016-09-28
WO2007073492A9 (en) 2007-08-09
US7273829B2 (en) 2007-09-25
US20070149806A1 (en) 2007-06-28
EP1971565A4 (en) 2012-01-04
WO2007073492A3 (en) 2007-11-22
WO2007073492A2 (en) 2007-06-28

Similar Documents

Publication Publication Date Title
JP5192495B2 (ja) 飽和および不飽和アルデヒドの不飽和カルボン酸への酸化のための触媒、およびその製造方法と使用方法
JP5612202B2 (ja) ヘテロポリ酸を含む飽和および不飽和アルデヒド類の不飽和カルボン酸への酸化のための触媒、その製造方法および使用方法
JP5684818B2 (ja) グリセリンの脱水反応によって不飽和アルデヒドおよび/または不飽和カルボン酸を製造するのに使用する触媒の製造方法と、この方法で得られる触媒
JP5160421B2 (ja) メタクロレインを酸化するための触媒およびその製造方法と使用方法
JP5379475B2 (ja) メタクロレインを酸化するための触媒およびその製造方法と使用方法
US7649111B2 (en) Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
JP4756890B2 (ja) メタクリル酸製造用触媒及びその製造方法
JP5384940B2 (ja) 飽和および不飽和アルデヒドの不飽和カルボン酸への酸化のための触媒およびその製造方法と使用方法
JP5214500B2 (ja) メタクリル酸製造用触媒の製造方法及びメタクリル酸の製造方法
JP3772392B2 (ja) 複合酸化物触媒及びメタクリル酸の製造方法
JP5280859B2 (ja) 不飽和アルデヒドの不飽和カルボン酸への酸化のためのヘテロポリ酸触媒を合成する方法
JP2008080232A (ja) メタクリル酸製造用触媒の再生方法及びメタクリル酸の製造方法
JP7105397B1 (ja) 触媒及びそれを用いた不飽和カルボン酸の製造方法
JP4902991B2 (ja) 酸化物触媒の製造方法

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20091218

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20091218

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20120621

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20120807

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20121106

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20130514

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20130812

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20130903

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20131003

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees