JP5315238B2 - 安定剤としての液体ホスフィットブレンド - Google Patents
安定剤としての液体ホスフィットブレンド Download PDFInfo
- Publication number
- JP5315238B2 JP5315238B2 JP2009516481A JP2009516481A JP5315238B2 JP 5315238 B2 JP5315238 B2 JP 5315238B2 JP 2009516481 A JP2009516481 A JP 2009516481A JP 2009516481 A JP2009516481 A JP 2009516481A JP 5315238 B2 JP5315238 B2 JP 5315238B2
- Authority
- JP
- Japan
- Prior art keywords
- tert
- phosphite
- bis
- pentylphenyl
- butylphenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
- C08K5/526—Esters of phosphorous acids, e.g. of H3PO3 with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/141—Esters of phosphorous acids
- C07F9/145—Esters of phosphorous acids with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/32—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing two or more of boron, silicon, phosphorus, selenium, tellurium or a metal
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Biochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US81581906P | 2006-06-20 | 2006-06-20 | |
| US60/815,819 | 2006-06-20 | ||
| US11/787,531 US7888414B2 (en) | 2006-06-20 | 2007-04-16 | Liquid phosphite blends as stabilizers |
| US11/787,531 | 2007-04-16 | ||
| PCT/US2007/009690 WO2007149143A2 (en) | 2006-06-20 | 2007-04-20 | Liquid phosphite blends as stabilizers |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009541526A JP2009541526A (ja) | 2009-11-26 |
| JP2009541526A5 JP2009541526A5 (OSRAM) | 2010-01-21 |
| JP5315238B2 true JP5315238B2 (ja) | 2013-10-16 |
Family
ID=38698227
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009516481A Expired - Fee Related JP5315238B2 (ja) | 2006-06-20 | 2007-04-20 | 安定剤としての液体ホスフィットブレンド |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US7888414B2 (OSRAM) |
| EP (1) | EP2057222B2 (OSRAM) |
| JP (1) | JP5315238B2 (OSRAM) |
| KR (1) | KR101382690B1 (OSRAM) |
| AU (1) | AU2007261715B2 (OSRAM) |
| BR (1) | BRPI0713256B1 (OSRAM) |
| CA (1) | CA2654157C (OSRAM) |
| MX (1) | MX2008016035A (OSRAM) |
| PL (2) | PL216865B1 (OSRAM) |
| RU (1) | RU2455325C2 (OSRAM) |
| SA (1) | SA07280306B1 (OSRAM) |
| TW (1) | TWI408166B (OSRAM) |
| WO (1) | WO2007149143A2 (OSRAM) |
Families Citing this family (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7888414B2 (en) | 2006-06-20 | 2011-02-15 | Chemtura Corporation | Liquid phosphite blends as stabilizers |
| US7947769B2 (en) | 2006-06-20 | 2011-05-24 | Chemtura Corporation | Liquid amylaryl phosphite compositions and alkylate compositions for manufacturing same |
| US8178005B2 (en) | 2006-06-20 | 2012-05-15 | Chemtura Corporation | Liquid phosphite compositions having different alkyl groups |
| US8008384B2 (en) * | 2006-06-20 | 2011-08-30 | Chemtura Corporation | Liquid butylaryl phosphite compositions |
| US8008383B2 (en) | 2006-06-20 | 2011-08-30 | Chemtura Corporation | Liquid amylaryl phosphite compositions |
| US8183311B2 (en) * | 2006-06-20 | 2012-05-22 | Chemtura Corporation | Liquid phosphite composition derived from cresols |
| US8188170B2 (en) | 2006-06-20 | 2012-05-29 | Chemtura Corporation | Polymers with low gel content and enhanced gas-fading |
| US8049041B2 (en) | 2008-06-27 | 2011-11-01 | Chemtura Corporation | Phosphite stabilizer for lubricating base stocks and thermoplastic polymers |
| US8735628B2 (en) | 2009-07-31 | 2014-05-27 | Addivant Usa Llc | Processes for forming alkylated aryl phosphite compositions from complex hydrocarbon streams |
| RU2012107528A (ru) * | 2009-07-31 | 2013-09-10 | Кемтура Корпорейшн | Твердые алкиларилфосфитные композиции и способы их получения |
| EP2459577A1 (en) * | 2009-07-31 | 2012-06-06 | Chemtura Corporation | Liquid alkylated trisaryl phosphite compositions having two alkyl groups with different carbon number |
| US8309635B2 (en) * | 2009-07-31 | 2012-11-13 | Chemtura Corporation | Solid alkylaryl phosphite compositions and methods for manufacturing same |
| TW201109342A (en) * | 2009-07-31 | 2011-03-16 | Chemtura Corp | Processes for forming alkylated aryl phosphite compositions from complex hydrocarbon streams |
| US8258215B2 (en) | 2010-02-05 | 2012-09-04 | Dover Chemical Corporation | Mixed alkyl-alkylaryl-phenyl phosphite polymer additive |
| US8557946B1 (en) | 2011-02-28 | 2013-10-15 | Wm. T. Burnett Ip, Llc | Oxidation discoloration resistant polyurethane foam |
| WO2012145924A1 (en) * | 2011-04-29 | 2012-11-01 | Rhodia (China) Co., Ltd. | New coupling agents for elastomer compositions |
| US9127144B2 (en) * | 2012-01-20 | 2015-09-08 | Addivant Usa Llc | Polyolefin compositions for film, fiber and molded articles |
| CN104508031B (zh) * | 2012-08-02 | 2020-10-16 | 瑞士新集团有限公司 | 亚磷酸酯组合物 |
| WO2014056736A1 (de) | 2012-10-12 | 2014-04-17 | Evonik Degussa Gmbh | Gemisch von bisphosphiten und dessen verwendung als katalysatorgemisch in der hydroformylierung |
| AU2014326295B2 (en) | 2013-09-27 | 2017-11-30 | Basf Se | Polyolefin compositions for building materials |
| GB201403057D0 (en) | 2014-02-21 | 2014-04-09 | Addivant Switzerland Gmbh | Process |
| DE102015202722A1 (de) | 2014-05-20 | 2015-11-26 | Evonik Degussa Gmbh | Verfahren zur katalytischen Herstellung von Aldehyden aus Olefinen unter Einsatz von Monophosphit-Gemischen |
| JP6730428B2 (ja) * | 2016-02-26 | 2020-07-29 | シノケム ランティアン カンパニー リミテッドSinochem Lantian Co., Ltd. | フッ素含有ケトンを含む組成物 |
| WO2017184234A1 (en) | 2016-04-22 | 2017-10-26 | Exxonmobil Chemical Patents Inc. | Polyethylene sheets |
| WO2018017180A1 (en) | 2016-07-21 | 2018-01-25 | Exxonmobil Chemical Patents Inc. | Rotomolded compositions, articles, and processes for making the same |
| WO2018102091A1 (en) | 2016-12-02 | 2018-06-07 | Exxonmobil Chemical Patents Inc. | Polyethylene films |
| JP6909594B2 (ja) * | 2017-03-03 | 2021-07-28 | 株式会社Adeka | 安定化されたオレフィン系樹脂組成物の製造方法 |
| US20200108539A1 (en) | 2017-04-06 | 2020-04-09 | ExxonMobil Chemica Patents Inc. | Cast Films and Processes for Making the Same |
| WO2018226311A1 (en) | 2017-06-08 | 2018-12-13 | Exxonmobil Chemical Patents Inc. | Polyethylene blends and extrudates and methods of making the same |
| WO2019022801A1 (en) | 2017-07-24 | 2019-01-31 | Exxonmobil Chemical Patents Inc. | POLYETHYLENE FILMS AND METHODS OF PRODUCING THE SAME |
| RU2669934C1 (ru) * | 2018-04-06 | 2018-10-17 | Публичное акционерное общество "Нефтяная компания "Роснефть" (ПАО "НК "Роснефть") | Способ получения трифенилфосфата |
| US11441023B2 (en) | 2018-04-27 | 2022-09-13 | Exxonmobil Chemical Patents Inc. | Polyethylene films and methods of making the same |
| WO2020109870A2 (en) | 2018-06-28 | 2020-06-04 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions, wires and cables, and methods for making the same |
| AU2019326374B2 (en) | 2018-08-22 | 2025-07-24 | Basf Se | Stabilized rotomolded polyolefin |
| GB201907363D0 (en) * | 2019-05-24 | 2019-07-10 | Si Group Switzerland Chaa Gmbh | Stabilising composition |
| US20220282064A1 (en) | 2019-07-30 | 2022-09-08 | Basf Se | Stabilizer composition |
| GB2592952B (en) * | 2020-03-11 | 2023-12-13 | Si Group Switzerland Gmbh | Composition |
| US20230303803A1 (en) * | 2020-07-31 | 2023-09-28 | Shell Oil Company | Anti-ageing additives for bitumen |
| EP4019570A1 (en) | 2020-12-23 | 2022-06-29 | Ingenia Polymers International S.A. | High concentration polymer masterbatches of liquid phosphite antioxidants with improved resistance to hydrolysis |
| CN115947754B (zh) * | 2022-12-28 | 2023-07-25 | 江苏极易新材料有限公司 | 一种低酸值三(2,4-二叔丁基苯基)亚磷酸酯的合成方法 |
Family Cites Families (58)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2220845A (en) | 1938-08-12 | 1940-11-05 | Dow Chemical Co | Aromatic phosphites |
| US3056823A (en) | 1956-05-31 | 1962-10-02 | Hooker Chemical Corp | Transesterification process for making trialiphatic phosphite esters |
| US2834798A (en) | 1957-12-20 | 1958-05-13 | Shea Chemical Corp | Heterocyclic phosphorus compounds |
| NL278726A (OSRAM) | 1961-05-22 | |||
| US3412064A (en) | 1965-11-08 | 1968-11-19 | Uniroyal Inc | Olefin polymer composition |
| US3558554A (en) | 1966-06-09 | 1971-01-26 | Yoshitomi Pharmaceutical | Oxidatively stable polyolefin composition |
| US3644536A (en) | 1969-09-18 | 1972-02-22 | Pennwalt Corp | Process for 1 3 5-tris(alpha-hydroxy-isopropyl)benzene |
| CA971977A (en) | 1969-11-18 | 1975-07-29 | Richard A. Bafford | Preparation of tris peroxides and their use |
| GB1307281A (en) | 1970-02-13 | 1973-02-14 | Ici Ltd | Rubber-polyester compositions |
| FR2101275A5 (OSRAM) | 1970-07-17 | 1972-03-31 | Ugine Kuhlmann | |
| US3755200A (en) | 1972-02-14 | 1973-08-28 | Emery Industries Inc | Liquid stabilizer system for polyvinyl chloride |
| US3948801A (en) | 1972-09-14 | 1976-04-06 | Westvaco Corporation | Stabilizer composition of phosphite and lignin |
| US4011057A (en) * | 1974-04-16 | 1977-03-08 | E. I. Du Pont De Nemours And Company | Hindered phenol antioxidant composition containing an amino compound |
| BR7601007A (pt) † | 1975-02-20 | 1976-09-14 | Ciba Geigy Ag | Composicoes estabilizadoras e processo para estabilizar poliolefinas |
| CH626385A5 (OSRAM) * | 1976-02-05 | 1981-11-13 | Ciba Geigy Ag | |
| US4492661A (en) | 1977-08-08 | 1985-01-08 | Ciba-Geigy Corporation | Process for producing triarylphosphites |
| JPS5473842A (en) | 1977-11-25 | 1979-06-13 | Mitsubishi Petrochem Co Ltd | Polyolefin resin composition |
| GB2012279B (en) | 1978-01-10 | 1982-08-04 | Ciba Geigy Ag | Phosphite stabiliser |
| US4406842A (en) | 1978-04-20 | 1983-09-27 | Ciba-Geigy Corporation | Ortho-alkylated phenyl phosphonites |
| DE2929993A1 (de) | 1978-07-27 | 1980-02-07 | Ciba Geigy Ag | Neue stabilisatoren |
| US4276233A (en) | 1978-11-02 | 1981-06-30 | General Electric Company | Hindered phenol phosphites |
| DE2940548A1 (de) † | 1979-10-06 | 1981-04-16 | Hoechst Ag, 6000 Frankfurt | Kristallisiertes tris-(2-tert.-butylphenyl)-phosphit und verfahren zu seiner herstellung |
| DE2940620A1 (de) | 1979-10-06 | 1981-04-16 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von triarylphosphiten |
| DE3367237D1 (en) | 1982-03-26 | 1986-12-04 | Gen Electric | Thermal oxidation stabilizer composed of phosphite derivatives of an alcohol and ppe monomer still bottoms, and ppe compositions containing said phosphites |
| JPS5930842A (ja) | 1982-08-10 | 1984-02-18 | Sumitomo Chem Co Ltd | 安定化ポリオレフイン樹脂組成物 |
| JPH0759652B2 (ja) | 1985-08-07 | 1995-06-28 | 住友化学工業株式会社 | ポリオレフイン樹脂組成物 |
| US4724265A (en) | 1986-05-15 | 1988-02-09 | Stauffer Chemical Company | Process for preparing liquid triaryl thiophosphate mixtures |
| JP2571602B2 (ja) * | 1988-05-09 | 1997-01-16 | 五井化成株式会社 | 第三−アミルフェノール類の製造法 |
| GB8901517D0 (en) * | 1989-01-24 | 1989-03-15 | Sandoz Ltd | Improvements in or relating to organic compounds |
| CZ280072B6 (cs) | 1989-03-13 | 1995-10-18 | Polymer Institute Brno Spol. S R.O. | Stabilizovaný polypropylen a kopolymery propylenu |
| US5254709A (en) | 1989-12-08 | 1993-10-19 | Uniroyal Chemical Company, Inc. | Method for preparing stearically hindered aryl phosphites |
| DE4021712A1 (de) | 1990-07-07 | 1992-01-09 | Basf Ag | Verfahren zur herstellung von mischungen aus diphenylmethan-diisocyanaten und polyphenol-polymethylen-polyisocyanaten mit einer verminderten iodfarbzahl |
| RU2071478C1 (ru) † | 1991-03-26 | 1997-01-10 | Циба Гейги АГ | Несимметричные арилфосфиты, полимерная композиция и способ ее получения |
| US5254610A (en) | 1991-08-02 | 1993-10-19 | Eastman Kodak Company | Polyester/polycarbonate blends containing phosphites |
| FI94138C (fi) | 1992-01-10 | 1995-07-25 | Borealis Holding As | Säteilytyksellä tapahtuvan steriloinnin kestävä polymeerikoostumus ja sen valmistusmenetelmä |
| JPH05202236A (ja) | 1992-01-27 | 1993-08-10 | Asahi Denka Kogyo Kk | ポリオレフィン系樹脂の組成物 |
| RO112871B1 (ro) | 1994-04-11 | 1998-01-30 | Inst Cercetari Chim | FOSFITI DE (1-METIL-1-FENILETIL) FENOLI SI PROCEDEU DE OBȚINERE f A ACESTORA |
| JPH07309884A (ja) | 1994-05-18 | 1995-11-28 | Yotsukaichi Gosei Kk | トリスアルキルフェニルホスファイトの製造方法 |
| US5561181A (en) | 1994-11-16 | 1996-10-01 | General Electric Company | Ultra high ortho nonyl phenyl phosphite and resin compositions stabilized therewith |
| US5532401A (en) | 1995-01-19 | 1996-07-02 | Dover Chemical Corporation | Process for production of tris(nonylphenyl) phosphite |
| JPH08239337A (ja) * | 1995-03-03 | 1996-09-17 | Dainippon Ink & Chem Inc | 高純度ジアルキル化フェノールおよびその製造方法 |
| DE19817691A1 (de) | 1998-04-21 | 1999-10-28 | Basf Ag | Verfahren zur Herstellung von Mischungen aus Diphenylmehandiisocyanaten und Polyphenylen-polymethylen-polyisocyanaten mit vermindertem Gehalt an chlorierten Nebenprodukten und verminderter Jodfarbzahl |
| RU2140938C1 (ru) | 1998-12-15 | 1999-11-10 | Открытое акционерное общество "Органический синтез" | Композиция синергистов для стабилизации полиолефинов |
| US7176252B2 (en) | 1999-07-29 | 2007-02-13 | Dover Chemical Corporation | Solid melt blended phosphite composites |
| US7320764B2 (en) | 2001-03-02 | 2008-01-22 | Dover Chemical Corporation | Phosphite ester additive compositions |
| GB0004044D0 (en) | 2000-02-21 | 2000-04-12 | Borealis Polymers Oy | Polymer |
| GB0004043D0 (en) * | 2000-02-21 | 2000-04-12 | Borealis Polymers Oy | Polymer |
| JP2002241334A (ja) * | 2001-02-15 | 2002-08-28 | Sumitomo Chem Co Ltd | tert−ブチルフェノール類の製造方法 |
| WO2002070625A1 (en) | 2001-03-02 | 2002-09-12 | Dover Chemical, Inc. | Phosphite ester additive compositions |
| US6887926B1 (en) | 2001-11-16 | 2005-05-03 | Oatey Co. | Bonding compositions for chlorinated polymers and methods of using the same |
| US6846859B2 (en) | 2002-05-31 | 2005-01-25 | Fina Technology, Inc. | Polyolefin composition having reduced color bodies |
| US20040048958A1 (en) | 2002-09-06 | 2004-03-11 | Didier David A. | High temperature ultra high molecular weight polyethylene |
| US7157511B2 (en) | 2003-11-21 | 2007-01-02 | Chevron Phillipschemical Company Lp | Phosphite additives in polyolefins |
| EP1751223B1 (en) | 2004-05-13 | 2009-08-12 | Basf Se | Flame retardants |
| CA2464551C (en) | 2004-05-18 | 2012-01-03 | Nova Chemicals Corporation | Phenol free stabilization of polyethylene film |
| CN101228220B (zh) | 2005-07-21 | 2012-12-12 | 西巴特殊化学品控股有限公司 | 使用液体三(单烷基)苯基亚磷酸酯稳定聚烯烃 |
| WO2007050991A1 (en) | 2005-10-27 | 2007-05-03 | Polnox Corporation | Stabilized polyolefin compositions |
| US7888414B2 (en) | 2006-06-20 | 2011-02-15 | Chemtura Corporation | Liquid phosphite blends as stabilizers |
-
2007
- 2007-04-16 US US11/787,531 patent/US7888414B2/en active Active
- 2007-04-20 KR KR1020087029548A patent/KR101382690B1/ko active Active
- 2007-04-20 AU AU2007261715A patent/AU2007261715B2/en not_active Ceased
- 2007-04-20 JP JP2009516481A patent/JP5315238B2/ja not_active Expired - Fee Related
- 2007-04-20 CA CA2654157A patent/CA2654157C/en active Active
- 2007-04-20 WO PCT/US2007/009690 patent/WO2007149143A2/en not_active Ceased
- 2007-04-20 BR BRPI0713256A patent/BRPI0713256B1/pt active IP Right Grant
- 2007-04-20 EP EP07775879.5A patent/EP2057222B2/en active Active
- 2007-04-20 RU RU2009101471/04A patent/RU2455325C2/ru active
- 2007-04-20 PL PL387494A patent/PL216865B1/pl unknown
- 2007-04-20 PL PL07775879T patent/PL2057222T5/pl unknown
- 2007-04-20 MX MX2008016035A patent/MX2008016035A/es active IP Right Grant
- 2007-05-09 TW TW096116480A patent/TWI408166B/zh not_active IP Right Cessation
- 2007-06-09 SA SA7280306A patent/SA07280306B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0713256B1 (pt) | 2018-11-21 |
| US7888414B2 (en) | 2011-02-15 |
| BRPI0713256A2 (pt) | 2012-04-03 |
| AU2007261715A1 (en) | 2007-12-27 |
| WO2007149143A3 (en) | 2008-02-14 |
| TW200801094A (en) | 2008-01-01 |
| AU2007261715B2 (en) | 2012-12-06 |
| SA07280306B1 (ar) | 2011-05-04 |
| PL216865B1 (pl) | 2014-05-30 |
| RU2455325C2 (ru) | 2012-07-10 |
| KR20090031352A (ko) | 2009-03-25 |
| EP2057222B2 (en) | 2017-03-01 |
| CA2654157A1 (en) | 2007-12-27 |
| PL2057222T5 (pl) | 2017-10-31 |
| EP2057222B1 (en) | 2014-03-12 |
| PL2057222T3 (pl) | 2014-08-29 |
| US20100048782A1 (en) | 2010-02-25 |
| MX2008016035A (es) | 2009-01-16 |
| JP2009541526A (ja) | 2009-11-26 |
| PL387494A1 (pl) | 2009-07-20 |
| WO2007149143A2 (en) | 2007-12-27 |
| EP2057222A2 (en) | 2009-05-13 |
| RU2009101471A (ru) | 2010-07-27 |
| CA2654157C (en) | 2015-11-24 |
| TWI408166B (zh) | 2013-09-11 |
| KR101382690B1 (ko) | 2014-04-08 |
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