JP5296675B2 - 耐久性疎水性表面を有する物品 - Google Patents
耐久性疎水性表面を有する物品 Download PDFInfo
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- JP5296675B2 JP5296675B2 JP2009516605A JP2009516605A JP5296675B2 JP 5296675 B2 JP5296675 B2 JP 5296675B2 JP 2009516605 A JP2009516605 A JP 2009516605A JP 2009516605 A JP2009516605 A JP 2009516605A JP 5296675 B2 JP5296675 B2 JP 5296675B2
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- hexafluoropropylene
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
- B05D7/04—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber to surfaces of films or sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/08—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2601/00—Inorganic fillers
- B05D2601/20—Inorganic fillers used for non-pigmentation effect
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
- Y10T428/24372—Particulate matter
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
- Y10T428/24372—Particulate matter
- Y10T428/24405—Polymer or resin [e.g., natural or synthetic rubber, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
- Y10T428/24372—Particulate matter
- Y10T428/24413—Metal or metal compound
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
- Y10T428/24372—Particulate matter
- Y10T428/24421—Silicon containing
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/251—Mica
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/256—Heavy metal or aluminum or compound thereof
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/256—Heavy metal or aluminum or compound thereof
- Y10T428/257—Iron oxide or aluminum oxide
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/258—Alkali metal or alkaline earth metal or compound thereof
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/259—Silicic material
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Description
a)起立部分、陥凹部分又はこれらの組み合わせを有するマイクロパターン化表面を有する基材を提供する工程と、
b)疎水性マイクロ粒子、疎水性ナノ粒子、又はこれらの混合物と結合剤とを含む粒子組成物を提供する工程と、
c)この基材の少なくとも一部上に粒子組成物を配置する工程と、
e)結合剤を乾燥又は別の方法で硬化する工程と、
を含む、コーティングされた耐久的な、高疎水性、最高疎水性、又は超疎水性物品の製造方法を提供する。
代表的な光重合可能な樹脂組成物は、サートマー6210{74%、サートマー社(ペンシルバニア州エクストン)}として入手したウレタンアクリレートオリゴマー、サートマー238(25%、サートマー社)として入手したジアクリレートモノマー、及びダロキュール1173として入手した反応開始剤からなる溶液を作ることにより調製した。この溶液を室温で30分間混合し、使用前にオーブン内で25℃に加温した。
TS−720、約5nm〜約200nmのヒュームドシリカ疎水性粒子を含む粉末(1.5/100部)を、メチルエチルケトン(95/100部)に分散させる。フルオロエラストマーFPO 3740(2.7/100部)をこの分散物に添加し、15分間混合し、続いてTMPTA(0.5/100部)、3−アミノプロピルトリエトキシシラン(0.25/100部)及びKB−1(0.05/100部)を添加し、得られる混合物を使用前に室温でさらに15分間攪拌する。
約3〜5μmの範囲のサイズのPTFE粉末(TF 2071)疎水性粒子(4.49/100部)を、メチルエチルケトン(95/100部)に分散した。次いで、ダイネオン2145として入手したフルオロポリマー(ヘキサフルオロプロピレン及びフッ化ビニリデンのコポリマー)(0.5/100部)を分散物に添加し、15分間混合し、続いて1,12−ジアミノドデカン(0.1/100部)を添加した。得られた混合物を使用前に室温でさらに15分間攪拌した。
比較例2の場合下塗剤溶液(1,6−ヘキサンジオールジアクリレート/ダロキュール1173、比99:1)、又は比較例3の場合3−アミノプロピルトリエトキシシラン(メタノール中に5重量%)、又は比較例4の場合光重合可能な樹脂組成物(上述のように調製)を、マイヤーバー(meyer bar)[#10、ポールNガードナー社(Paul N. Gardner Co., Inc.){フロリダ州ポンパノビーチ(Pompano Beach)}から入手可能]でPETフィルム上にコーティングして、厚さ5〜10μmのコーティングを得た。アミノシランで下塗りした基材を、使用前に100℃で10分間乾燥した。1,6−ヘキサンジオールジアクリレート(HDODA)下塗剤及び光重合可能な樹脂組成物を、下塗りした材料を毎分10.7メートル(m/分)で紫外線光(フュージョン「D」電球)下を2回通過させることにより硬化した。
ヒュームドシリカ粒子で作製した疎水性コーティング組成物(上記、番号1)を、マイヤーバー(#20)で、下塗りしていないPETフィルム上にコーティングして、1〜15μmの厚さのコーティングを得た。試料を120℃のオーブン内で10分間乾燥し、次いで、10.7m/分で紫外線光(フュージョン「D」電球)下で架橋又は硬化した。表1で規定したように、クロック試験(Crock test)での多数の試験サイクル後、接触角を測定することにより、試料を疎水性について評価した。
ヒュームドシリカ粒子で作製した疎水性コーティング組成物(上記、番号1)を、マイヤーバー(#20)で、1,6−ヘキサンジオールジアクリレートで下塗りしたPETフィルム上にコーティングし、1〜15μmの厚さのコーティングを得た。比較例1で記載したように、同じオーブン乾燥及び紫外線硬化処理により試料を処理した。接触角測定の結果を表1に示す。
ヒュームドシリカ粒子で作製した疎水性コーティング組成物(上記、番号1)を、マイヤーバー(#20)で、3−アミノプロピルトリエトキシシランで下塗りしたPETフィルム上にコーティングし、1〜15μmの厚さのコーティングを得た。比較例1で記載したように、同じオーブン乾燥及び紫外線硬化処理により試料を処理した。接触角測定の結果を表1に示す。
ヒュームドシリカ粒子で作製した疎水性コーティング組成物を、マイヤーバー(#20)で、PETフィルム(マイクロパターン化表面を作製するための上記光重合可能な組成物で下塗りした)上にコーティングし、1〜15μmの厚さのコーティングを得た。比較例1で記載したように、同じオーブン乾燥及び紫外線硬化処理により試料を処理した。接触角測定の結果を表1に示す。
疎水性コーティング組成物(上記番号1で指定した)を、マイヤーバー(#20)で、「V」溝(上記のように調製した)を備えるPET上にコーティングし、1〜8μmの厚さのコーティングを得た。試料を120℃のオーブン内で10分間乾燥し、次いで、10.7m/分で紫外線光(フュージョン「D」電球)下で架橋又は硬化した。表1で規定したような試験サイクル後、接触角を測定することにより試料を評価した。
疎水性コーティング組成物(番号1で指定した)を、マイヤーバー(#20)で、「V」溝(上記のように調製した)を備えるPET上にコーティングして、1〜25μmの厚さのコーティングを得た。実施例1で記載したように、オーブン乾燥及び紫外線硬化処理により試料を処理した。試料のデータを表1に報告する。
疎水性コーティング組成物(番号2で指定した)を、マイヤーバー(#20)で、「V」溝(「V」溝方向に)を備えるPET上にコーティングして、1〜25μmの厚さのコーティングを得た。試料を140℃のオーブン内で15分間乾燥し、組成物中のポリマーを熱的に架橋又は硬化する。表1で規定したような多数の試験サイクル後、接触角を測定することにより疎水性について試料を評価した。
表1のデータは、クロックメーター試験で繰り返し摩擦した後、超疎水性表面を示す、大きな接触角(150°)を優位に保持することにより、比較例と比較して、本発明の実施例は耐久性が実質的に改善されていることを示す。
Claims (2)
- 起立部分、陥凹部分又はこれらの組み合わせを含むマイクロパターン化表面を有する基材上に高疎水性又は超疎水性表面を提供するために十分な量の、ポリ−1,1−ジフルオロエチレン;1,1−ジフルオロエチレン及びヘキサフルオロプロピレンのコポリマー;テトラフルオロエチレン及びヘキサフルオロプロピレンのコポリマー;1,1−ジフルオロエチレン及びテトラフルオロエチレンのコポリマー;ヘキサフルオロプロピレン、テトラフルオロエチレン及びエチレンのターポリマー;並びに、テトラフルオロエチレン、ヘキサフルオロプロピレン及び1,1−ジフルオロエチレンのターポリマーからなる群から選択される架橋可能なフルオロポリマー結合剤、架橋剤及び疎水性マイクロ粒子、疎水性ナノ粒子、又はこれらの混合物を含む液体組成物を付着する工程と、
前記液体組成物を架橋させる工程と、を含み、
前記架橋した組成物が、前記マイクロパターン化表面の突出形状により遮断された不連続コーティングを形成する、高疎水性又は超疎水性表面の形成方法。 - 起立部分、陥凹部分又はこれらの組み合わせを含むマイクロパターン化表面を有する基材と;少なくとも起立部分間又は陥凹部分内の一部に位置し、ポリ−1,1−ジフルオロエチレン;1,1−ジフルオロエチレン及びヘキサフルオロプロピレンのコポリマー;テトラフルオロエチレン及びヘキサフルオロプロピレンのコポリマー;1,1−ジフルオロエチレン及びテトラフルオロエチレンのコポリマー;ヘキサフルオロプロピレン、テトラフルオロエチレン及びエチレンのターポリマー;並びに、テトラフルオロエチレン、ヘキサフルオロプロピレン及び1,1−ジフルオロエチレンのターポリマーからなる群から選択される架橋したフルオロポリマー結合剤、架橋剤及び疎水性マイクロ粒子、疎水性ナノ粒子、又はこれらの混合物を含む前記基材上のコーティング組成物とを高疎水性又は超疎水性表面を提供するために十分な量で含む物品。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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US11/426,122 | 2006-06-23 | ||
US11/426,122 US8354160B2 (en) | 2006-06-23 | 2006-06-23 | Articles having durable hydrophobic surfaces |
PCT/US2007/065628 WO2007149617A1 (en) | 2006-06-23 | 2007-03-30 | Articles having durable hydrophobic surfaces |
Publications (3)
Publication Number | Publication Date |
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JP2009541033A JP2009541033A (ja) | 2009-11-26 |
JP2009541033A5 JP2009541033A5 (ja) | 2010-02-25 |
JP5296675B2 true JP5296675B2 (ja) | 2013-09-25 |
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Application Number | Title | Priority Date | Filing Date |
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JP2009516605A Expired - Fee Related JP5296675B2 (ja) | 2006-06-23 | 2007-03-30 | 耐久性疎水性表面を有する物品 |
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Country | Link |
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US (1) | US8354160B2 (ja) |
EP (1) | EP2051821A4 (ja) |
JP (1) | JP5296675B2 (ja) |
CN (2) | CN101466481A (ja) |
WO (1) | WO2007149617A1 (ja) |
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EP2271490B1 (en) * | 2008-04-30 | 2019-10-09 | Nanosys, Inc. | Non-fouling surfaces for reflective spheres |
US8017234B2 (en) * | 2008-06-12 | 2011-09-13 | Dic Corporation | Structural object coated with superhydrophobic nanostructure composite and process for producing the same |
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CN101474896B (zh) * | 2009-01-21 | 2012-01-25 | 重庆大学 | 复合结构的超疏水膜 |
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AU2009355220B2 (en) | 2009-11-10 | 2013-02-14 | Unilever Plc | Frost free surfaces and method for manufacturing the same |
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CN102189071A (zh) * | 2010-03-07 | 2011-09-21 | 张镜 | 物体表面纳米粒子处理技术(间接法) |
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US8354160B2 (en) | 2013-01-15 |
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