JP5272337B2

JP5272337B2 - 長尺物固定治具用熱可塑性樹脂組成物およびその製造方法

長尺物固定治具用熱可塑性樹脂組成物およびその製造方法 Download PDF

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Publication number: JP5272337B2
Authority: JP; Japan
Prior art keywords: weight; resin; resin composition; thermoplastic resin; polylactic acid
Prior art date: 2006-06-22
Legal status : Expired - Fee Related

Application number

JP2007165673A

Other languages

English (en)

Japanese (ja)

Other versions

JP2008024923A (ja

JP2008024923A5 (enExample

Inventor

大秋田

美都繁濱口

英夫松岡

真希子斎藤

Current Assignee

Toray Industries Inc

Original Assignee

Toray Industries Inc

Priority date

2006-06-22

Filing date

2007-06-22

Publication date

2013-08-28

2007-06-22 Application filed by Toray Industries Inc filed Critical Toray Industries Inc

2007-06-22 Priority to JP2007165673A priority Critical patent/JP5272337B2/ja

2008-02-07 Publication of JP2008024923A publication Critical patent/JP2008024923A/ja

2010-08-05 Publication of JP2008024923A5 publication Critical patent/JP2008024923A5/ja

2013-08-28 Application granted granted Critical

2013-08-28 Publication of JP5272337B2 publication Critical patent/JP5272337B2/ja

Status Expired - Fee Related legal-status Critical Current

2027-06-22 Anticipated expiration legal-status Critical

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239000011342 resin composition Substances 0.000 title claims abstract description 83
229920005992 thermoplastic resin Polymers 0.000 title claims abstract description 77
238000004519 manufacturing process Methods 0.000 title claims abstract description 14
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239000011347 resin Substances 0.000 claims abstract description 153
229920000747 poly(lactic acid) Polymers 0.000 claims abstract description 85
239000004626 polylactic acid Substances 0.000 claims abstract description 85
238000005191 phase separation Methods 0.000 claims abstract description 20
229920003229 poly(methyl methacrylate) Polymers 0.000 claims abstract description 10
239000004926 polymethyl methacrylate Substances 0.000 claims abstract description 10
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238000004898 kneading Methods 0.000 claims description 40
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239000004014 plasticizer Substances 0.000 claims description 38
150000001875 compounds Chemical class 0.000 claims description 29
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 28
239000005977 Ethylene Substances 0.000 claims description 28
238000002156 mixing Methods 0.000 claims description 22
125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 19
239000004593 Epoxy Substances 0.000 claims description 15
239000002667 nucleating agent Substances 0.000 claims description 13
239000000314 lubricant Substances 0.000 claims description 11
HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 10
229920002292 Nylon 6 Polymers 0.000 claims description 9
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CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 6
239000000454 talc Substances 0.000 claims description 6
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235000013539 calcium stearate Nutrition 0.000 claims description 5
PFBWBEXCUGKYKO-UHFFFAOYSA-N ethene;n-octadecyloctadecan-1-amine Chemical compound C=C.CCCCCCCCCCCCCCCCCCNCCCCCCCCCCCCCCCCCC PFBWBEXCUGKYKO-UHFFFAOYSA-N 0.000 claims description 5
235000019359 magnesium stearate Nutrition 0.000 claims description 5
CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 claims description 4
229940063655 aluminum stearate Drugs 0.000 claims description 4
AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 claims description 4
XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 4
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ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 7
239000005749 Copper compound Substances 0.000 description 6
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KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
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GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
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OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 3
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102100028631 Testis-expressed protein 30 Human genes 0.000 description 3
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FIASKJZPIYCESA-UHFFFAOYSA-L calcium;octacosanoate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCCCCCCCCCCCC([O-])=O FIASKJZPIYCESA-UHFFFAOYSA-L 0.000 description 3
150000001735 carboxylic acids Chemical class 0.000 description 3
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KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
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VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
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NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 3
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