JP5171248B2 - 原子移動ラジカル重合法 - Google Patents
原子移動ラジカル重合法 Download PDFInfo
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- JP5171248B2 JP5171248B2 JP2007502066A JP2007502066A JP5171248B2 JP 5171248 B2 JP5171248 B2 JP 5171248B2 JP 2007502066 A JP2007502066 A JP 2007502066A JP 2007502066 A JP2007502066 A JP 2007502066A JP 5171248 B2 JP5171248 B2 JP 5171248B2
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- Prior art keywords
- polymerization
- reducing agent
- transition metal
- atrp
- reaction
- Prior art date
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- 238000010560 atom transfer radical polymerization reaction Methods 0.000 title claims description 256
- 238000006116 polymerization reaction Methods 0.000 claims description 345
- 238000006243 chemical reaction Methods 0.000 claims description 234
- 238000000034 method Methods 0.000 claims description 202
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- 239000003054 catalyst Substances 0.000 claims description 165
- 229910052723 transition metal Inorganic materials 0.000 claims description 130
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/40—Redox systems
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
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| WO2007025310A1 (en) * | 2005-08-26 | 2007-03-01 | Carnegie Mellon University | Polymerization process with catalyst reactivation |
| JP4543178B2 (ja) * | 2005-09-01 | 2010-09-15 | 国立大学法人京都大学 | 新規リビングラジカル重合法 |
| US20090171024A1 (en) * | 2005-12-21 | 2009-07-02 | Carnegie Mellon University | Preparation of block copolymers |
| DE102006037351A1 (de) * | 2006-08-09 | 2008-02-14 | Evonik Röhm Gmbh | Verfahren zur Herstellung von hydroxytelecheler ATRP-Produkten |
| WO2008021500A2 (en) | 2006-08-17 | 2008-02-21 | University Of Pittsburgh-Of The Commonwealth System Of Higher Education | Modification of surfaces with polymers |
| WO2008057163A2 (en) | 2006-10-09 | 2008-05-15 | Carnegie Mellon University | Preparation of functional gel particles with a dual crosslink network |
| GB2463198B (en) | 2007-05-23 | 2013-05-22 | Univ Carnegie Mellon | Hybrid particle composite structures with reduced scattering |
| WO2008148000A1 (en) * | 2007-05-23 | 2008-12-04 | Carnegie Mellon University | Atom transfer dispersion polymerization |
| JP2009013401A (ja) * | 2007-06-04 | 2009-01-22 | Kaneka Corp | 原子移動ラジカル重合法によるビニル系重合体の製造方法 |
| DE102007049859A1 (de) | 2007-10-18 | 2009-04-23 | Construction Research & Technology Gmbh | Verfahren zur Herstellung von silanmodifizierten Copolymeren |
| BRPI0816761A2 (pt) * | 2007-09-12 | 2015-03-24 | Constr Res & Tech Gmbh | Método para a fabricação de copolímeros silano modificados |
| DE102008009332A1 (de) * | 2008-02-14 | 2009-08-20 | Leibniz-Institut Für Neue Materialien Gemeinnützige Gmbh | Optische Elemente mit Gradientenstruktur |
| DE102008043666A1 (de) * | 2008-11-12 | 2010-05-20 | Evonik Röhm Gmbh | Verfahren zur Herstellung von AB-Diblockcopolymeren mit einem bimodalen verteilten A-Block |
| US8815971B2 (en) | 2008-12-22 | 2014-08-26 | ATRP Solutions, Inc. | Control over controlled radical polymerization processes |
| US8822610B2 (en) * | 2008-12-22 | 2014-09-02 | ATRP Solutions, Inc. | Control over controlled radical polymerization processes |
| US20100227162A1 (en) * | 2009-03-03 | 2010-09-09 | Abhimanyu Onkar Patil | Atom transfer radical polymerization (ATRP) based inorganic polymer structures |
| WO2010111708A1 (en) | 2009-03-27 | 2010-09-30 | Carnegie Mellon University | Preparation of functional star macromolecules |
| WO2010123575A1 (en) | 2009-04-23 | 2010-10-28 | Atrp Solutions Inc | Well defined stars with segmented arms |
| US9783628B2 (en) | 2009-04-23 | 2017-10-10 | ATRP Solutions, Inc. | Dual-mechanism thickening agents for hydraulic fracturing fluids |
| WO2012020545A1 (ja) * | 2010-08-10 | 2012-02-16 | 株式会社カネカ | （メタ）アクリル系重合体の製造方法 |
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| US9587064B2 (en) | 2010-12-08 | 2017-03-07 | ATRP Solutions, Inc. | Salt-tolerant star macromolecules |
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| EP2747753B1 (en) | 2011-08-22 | 2023-03-29 | Carnegie Mellon University | Atom transfer radical polymerization under biologically compatible conditions |
| US9790305B2 (en) | 2011-09-09 | 2017-10-17 | Franklin And Marshall College | Site specifically incorporated initiator for growth of polymers from proteins |
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| WO2013158183A2 (en) | 2012-01-27 | 2013-10-24 | Carnegie Mellon University | Processable self-organizing nanoparticles |
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| JP2013249437A (ja) * | 2012-06-04 | 2013-12-12 | Hitachi Chemical Co Ltd | 水及び水に不溶な有機溶媒の混合溶媒を用いた重合体の製造方法及び該製造方法にて製造された重合体 |
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| JP6294885B2 (ja) | 2012-08-30 | 2018-03-14 | エーティーアールピー ソリューションズ インコーポレイテッドＡＴＲＰ Ｓｏｌｕｔｉｏｎｓ，Ｉｎｃ． | 星形高分子、星形高分子組成物および星形高分子の製造方法 |
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| CN105263978B (zh) | 2013-02-04 | 2018-04-17 | Atrp解决方案公司 | 耐盐星形大分子 |
| WO2014136950A1 (ja) * | 2013-03-08 | 2014-09-12 | 横浜ゴム株式会社 | ビニルエーテル系ポリマーの製造方法 |
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| US20150368379A1 (en) * | 2013-06-21 | 2015-12-24 | The University Of Notre Dame Du Lac | Synthesizing hyperbranched polymers with uniform structure in confined space |
| WO2015003137A1 (en) * | 2013-07-03 | 2015-01-08 | University Of Connecticut | Polymerization of diene monomers |
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| CN106164109A (zh) * | 2014-04-07 | 2016-11-23 | 陶氏环球技术有限责任公司 | 通过光的丙烯酸酯的可控自由基聚合的调节 |
| JP6374696B2 (ja) * | 2014-05-01 | 2018-08-15 | 旭化成株式会社 | 表面改質無機酸化物粒子及び有機無機複合粒子の製造方法 |
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| US10486148B2 (en) | 2015-09-30 | 2019-11-26 | The Regents Of The University Of Michigan | Ni(0) catalysts |
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| US20070276101A1 (en) | 2007-11-29 |
| US7893174B2 (en) | 2011-02-22 |
| JP2007527463A (ja) | 2007-09-27 |
| EP1725590A4 (en) | 2013-08-07 |
| US20110218306A1 (en) | 2011-09-08 |
| EP1725590A1 (en) | 2006-11-29 |
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