JP5139778B2 - 感光性樹脂組成物及びそれを用いたフレキシブルプリント配線板 - Google Patents
感光性樹脂組成物及びそれを用いたフレキシブルプリント配線板 Download PDFInfo
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- JP5139778B2 JP5139778B2 JP2007296124A JP2007296124A JP5139778B2 JP 5139778 B2 JP5139778 B2 JP 5139778B2 JP 2007296124 A JP2007296124 A JP 2007296124A JP 2007296124 A JP2007296124 A JP 2007296124A JP 5139778 B2 JP5139778 B2 JP 5139778B2
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Landscapes
- Non-Metallic Protective Coatings For Printed Circuits (AREA)
- Materials For Photolithography (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
本発明者は、ベース樹脂と、特定のリン酸エステル化合物、ホスフィンオキシド化合物、イソシアヌル酸環を有する化合物、及び前記樹脂以外のイミド基を1つ若しくは2つ含有するイミド化合物からなる群から選ばれた少なくとも一つの化合物と、キノンジアジド化合物と、を組み合わせて配合することにより、従来公知の技術では困難であった、ドライフィルム化時の反りがなくラミネート性を有し、難燃性を有するポジ型の感光性ドライフィルムを達成することに成功した。
本発明の感光性樹脂組成物に用いられる(A)成分は、有機溶剤に可溶である樹脂を用いる。このような樹脂として、可溶性ポリイミド又はポリイミド前駆体を用いる。これらの中でも製膜後、閉環反応の必要のない可溶性ポリイミドがより好ましい。
R7で示される2価の有機基としては、炭化水素基、芳香族基が挙げられる。炭化水素基は、エチレン基、プロピレン基、ブチレン基などである。芳香族基は、フェニレン基などである。
(B)成分は、リン酸エステル化合物、イソシアヌル酸環有する化合物、及び(A)成分以外のイミド基を1つ若しくは2つ含有するイミド化合物からなる群から選ばれた少なくとも一つの化合物である。
R3は1価の有機基である。1価の有機基とは、例えば、カルボキシル基を有する有機基やエステル基を有する有機基である。このような1価の有機基とは、例えば、式(15)で表される有機基である。また、樹脂やワニスに用いる溶媒との相溶性の観点より、エステル基を有する有機基が好ましい。
本発明に係る樹脂組成物においては、(C)成分のキノンジアジド化合物により感光性を発現する。さらに、(C)成分は、前記(B)成分と併用することで、本発明の感光性樹脂組成物は高い難燃性を発現できる。
本発明の感光性樹脂組成物に、(D)成分:ポリエーテル化合物を添加することによりドライフィルム化時の反りをさらに改善することができる。
[可溶性ポリイミド合成例1]
攪拌器を取り付けた1リットルのセパラブル3つ口フラスコに、水分定量計を備えた玉付冷却管を取り付けた。窒素気流下にて、γ−ブチロラクトン268.52g(和光純薬株式会社製)、オキシジフタル酸ニ無水物31.02g(100ミリモル)(マナック株式会社製)、1,3−ビス(3−アミノプロピル)ポリシロキサン68.55g(75ミリモル)(分子量914/信越化学工業株式会社製)、3,5−ジアミノ安息香酸7.61g(50ミリモル)(Aldrich社製)を仕込み室温で2時間攪拌した。
表1に示す組成の成分を表1に示す重量割合で配合した。なお、(C)成分のキノンジアジド化合物としては、式(24)に示す化合物(a)、若しくは式(26)に示す化合物(b)を用いた。化合物(a)は、α,α,α’−トリス(4−ヒドロキシフェニル)−1−エチル−4−イソプロピル−ベンゼン(1モル)と3−ジアゾ−3,4−ジヒドロ−4−オキソナフタレン−1−スルホン酸(2.3モル)とのエステルである。化合物(b)は、α,α,α’−トリス(4−ヒドロキシフェニル)−1−エチル−4イソプロピル−ベンゼン(1モル)と4−ジアゾ−4,5−ジヒドロ−5−オキソナフタレン−1−スルホン酸(2.8モル)とのエステルである。
[反り]
25μm厚のPETフィルム(T100−H25/三菱化学ポリエステルフィルム株式会社製)にブレードコーターで塗工後、95℃/30分間オーブンで乾燥し感光性ドライフィルムを得た。塗工部分を20cm×20cmの大きさに切り出し試験フィルムとし、反りを目視評価した。膜厚は24μmであった。反り発生なしの場合を◎とし、軽度の反り発生の場合を○とし、反り発生しフィルムがロール状に丸まる場合を×とした。
25μm厚のカプトンフィルム(カプトンEN−100/東レ・デュポン株式会社製)にブレードコーターで塗工後、95℃/30分間オーブンで乾燥。乾燥後、反対の面にも同様に塗工、乾燥を行った。得られたフィルムをオーブンにて120℃/1時間、200℃/1時間で加熱処理を行った。両面それぞれの膜厚は23μmであった。50mm×200mmに切り出し、UL94 VTM試験に準じた難燃性の評価を行った。難燃性ありの場合を○とし、難燃性なしの場合を×とした。
25μm厚のPETフィルム(T100−H25/三菱化学ポリエステルフィルム株式会社製)にブレードコーターで塗工後、95℃/30分間オーブンで乾燥し膜厚24μmの感光性ドライフィルムを得た。
ラミネート性評価で得た、感光性フィルムがラミネートされた銅箔を用い以下の評価をおこなった。尚、PETフィルムと感光性フィルムが剥離したサンプルについては評価が困難な為、銅箔にラミネートせずに感光性ドライフィルムのまま以下の評価を行った。
攪拌器を取り付けた1リットルのセパラブル3つ口フラスコに、水分定量計を備えた玉付冷却管を取り付けた。窒素気流下にて、γ−ブチロラクトン341.64g(和光純薬株式会社製)、オキシジフタル酸ニ無水物31.02g(100ミリモル)(マナック株式会社製)、1,3−ビス(3−アミノプロピル)ポリシロキサン68.55g(75ミリモル)(分子量914/信越化学工業株式会社製)、3,3’−ジカルボキシ−4,4’−ジアミノジフェニルメタン14.31g(50ミリモル)(和歌山精化株式会社製)を仕込み室温で2時間攪拌した。
Claims (11)
- (A)成分、(B)成分及び(C)成分を含有する感光性樹脂組成物であって、前記(A)成分は、可溶性ポリイミド又はポリイミド前駆体であり、前記(B)成分は、式(1)に示すリン酸エステル化合物、式(2)に示すリン酸エステル化合物、式(4)に示す有機基を含有するイソシアヌル酸環を有する化合物、及び、式(5)に示す有機基を含有する前記(A)成分以外のイミド基を1つ若しくは2つ含有するイミド化合物からなる群から選ばれた少なくとも一つの化合物であり、前記式(1)又は前記式(2)中のR 1 がメチル基、エチル基、ブチル基、2−エチルヘキシル基、ブトキシエチル基、フェニル基、クレジル基、キシレニル基及びアミノフェニル基からなる群より選ばれた有機基であり、前記式(5)中のmが1であり、R 4 が式(7)で示された有機基から選ばれたものであり、前記(C)成分は、キノンジアジド化合物であることを特徴とする感光性樹脂組成物。
- 前記(A)成分がシロキサン骨格を有することを特徴とする請求項1記載の感光性樹脂組成物。
- 前記(A)成分が可溶性ポリイミドであって、カルボキシル基及び/又は水酸基を有するポリイミド樹脂であることを特徴とする請求項1又は請求項2記載の感光性樹脂組成物。
- 前記式(10)で示されたいずれかの有機基を有する化合物が、フェノール性水酸基を有する化合物をスルホン酸でエステル化して得られる化合物であり、前記化合物1モル当たりの前記式(10)で示されたいずれかの有機基によるエステル化率が0.60以上0.98以下であることを特徴とする請求項4記載の感光性樹脂組成物。
- 前記(A)成分100重量部に対して、前記(B)成分が30重量部以下であることを特徴とする請求項1から請求項6のいずれかに記載の感光性樹脂組成物。
- 請求項1から請求項7のいずれかに記載の感光性樹脂組成物を含有することを特徴とするフィルム。
- キャリアフィルムと、前記キャリアフィルム上に設けられた請求項8記載のフィルムと、を具備することを特徴とする積層フィルム。
- 前記積層フィルム上に形成されたカバーフィルムを具備することを特徴とする請求項9記載の積層フィルム。
- 配線を有する基材と、前記配線を覆うように前記基材上に形成され、請求項8から請求項10のいずれかに記載のフィルムもしくは積層フィルムを露光・現像してなるカバーレイと、を具備することを特徴とするフレキシブルプリント配線板。
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