JP5096751B2 - 物理的強度が改良されたアルキル芳香族化合物脱水素触媒およびその製造方法並びに脱水素化方法 - Google Patents

物理的強度が改良されたアルキル芳香族化合物脱水素触媒およびその製造方法並びに脱水素化方法 Download PDF

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JP5096751B2
JP5096751B2 JP2007017203A JP2007017203A JP5096751B2 JP 5096751 B2 JP5096751 B2 JP 5096751B2 JP 2007017203 A JP2007017203 A JP 2007017203A JP 2007017203 A JP2007017203 A JP 2007017203A JP 5096751 B2 JP5096751 B2 JP 5096751B2
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cerium
compound
catalyst
dehydrogenation
aromatic compound
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JP2007017203A
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JP2008183492A5 (enExample
JP2008183492A (ja
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雄二 三島
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Clariant Catalysts Japan KK
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Clariant Catalysts Japan KK
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Priority to JP2007017203A priority Critical patent/JP5096751B2/ja
Application filed by Clariant Catalysts Japan KK filed Critical Clariant Catalysts Japan KK
Priority to EP08703896A priority patent/EP2106852B1/en
Priority to US12/524,180 priority patent/US20100087694A1/en
Priority to CA2676383A priority patent/CA2676383C/en
Priority to PCT/JP2008/051069 priority patent/WO2008090974A1/ja
Priority to KR1020097017299A priority patent/KR101422878B1/ko
Priority to CN2008800030052A priority patent/CN101631612B/zh
Publication of JP2008183492A publication Critical patent/JP2008183492A/ja
Publication of JP2008183492A5 publication Critical patent/JP2008183492A5/ja
Priority to US13/659,401 priority patent/US20130053608A1/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/37—Crush or impact strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/38—Abrasion or attrition resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/04—Particle-shaped
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
    • B29C48/793—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling upstream of the plasticising zone, e.g. heating in the hopper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
    • B29C48/91—Heating, e.g. for cross linking
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/42—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
    • C07C15/44—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
    • C07C15/46—Styrene; Ring-alkylated styrenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/36—Mechanical strength
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
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    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with rare earths or actinides
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    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2007017203A 2007-01-26 2007-01-26 物理的強度が改良されたアルキル芳香族化合物脱水素触媒およびその製造方法並びに脱水素化方法 Expired - Fee Related JP5096751B2 (ja)

Priority Applications (8)

Application Number Priority Date Filing Date Title
JP2007017203A JP5096751B2 (ja) 2007-01-26 2007-01-26 物理的強度が改良されたアルキル芳香族化合物脱水素触媒およびその製造方法並びに脱水素化方法
US12/524,180 US20100087694A1 (en) 2007-01-26 2008-01-25 Catalyst for dehydrogenation of alkyl aromatic compound which has improved physical properties, method for production of the catalyst, and dehydrogenation method
CA2676383A CA2676383C (en) 2007-01-26 2008-01-25 Dehydrogenation catalyst of alkyl aromatic compounds having improved physical strength, process for producing same, and dehydrogenation method thereof
PCT/JP2008/051069 WO2008090974A1 (ja) 2007-01-26 2008-01-25 物理的強度が改良されたアルキル芳香族化合物脱水素触媒およびその製造方法並びに脱水素化方法
EP08703896A EP2106852B1 (en) 2007-01-26 2008-01-25 Catalyst for dehydrogenation of alkyl aromatic compound which has improved physical properties, method for production of the catalyst, and dehydrogenation method
KR1020097017299A KR101422878B1 (ko) 2007-01-26 2008-01-25 물리적 강도가 개량된 알킬 방향족 화합물 탈수소촉매 및 그 제조 방법 및 탈수소화 방법
CN2008800030052A CN101631612B (zh) 2007-01-26 2008-01-25 经物理强度改良的烷基芳香族化合物脱氢催化剂及其制造方法以及脱氢方法
US13/659,401 US20130053608A1 (en) 2007-01-26 2012-10-24 Dehydrogenation catalyst of alkyl aromatic compounds having improved physical strength, process for producing same, and dehydrogenation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2007017203A JP5096751B2 (ja) 2007-01-26 2007-01-26 物理的強度が改良されたアルキル芳香族化合物脱水素触媒およびその製造方法並びに脱水素化方法

Publications (3)

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JP2008183492A JP2008183492A (ja) 2008-08-14
JP2008183492A5 JP2008183492A5 (enExample) 2009-09-10
JP5096751B2 true JP5096751B2 (ja) 2012-12-12

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JP2007017203A Expired - Fee Related JP5096751B2 (ja) 2007-01-26 2007-01-26 物理的強度が改良されたアルキル芳香族化合物脱水素触媒およびその製造方法並びに脱水素化方法

Country Status (7)

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US (2) US20100087694A1 (enExample)
EP (1) EP2106852B1 (enExample)
JP (1) JP5096751B2 (enExample)
KR (1) KR101422878B1 (enExample)
CN (1) CN101631612B (enExample)
CA (1) CA2676383C (enExample)
WO (1) WO2008090974A1 (enExample)

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WO2017099161A1 (ja) 2015-12-11 2017-06-15 クラリアント触媒株式会社 アルキル芳香族化合物脱水素化触媒とその製造方法、及びそれを用いた脱水素化方法

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KR101218453B1 (ko) * 2008-12-30 2013-01-04 주식회사 효성 탈수소화 촉매
CN102728371A (zh) * 2011-04-15 2012-10-17 廖仕杰 一种高铈含量烷基芳烃脱氢催化剂及其制造方法
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RU2509604C1 (ru) * 2012-12-05 2014-03-20 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Ярославский государственный технический университет" Катализатор для дегидрирования алкилароматических углеводородов
PL3140039T3 (pl) 2014-05-09 2021-01-25 Basf Se Ulepszony katalizator do odwodorniania węglowodorów
US10315970B2 (en) 2014-05-09 2019-06-11 Basf Se Catalyst for dehydrogenating hydrocarbons
CN105289626B (zh) * 2014-07-24 2017-12-15 中国石油化工股份有限公司 苯乙烯催化剂和苯乙烯的制备方法
CN105312059B (zh) * 2014-07-24 2018-02-13 中国石油化工股份有限公司 乙苯脱氢生产苯乙烯的催化剂
EP3341126A1 (en) 2015-08-28 2018-07-04 Haldor Topsøe A/S Induction heating of endothermic reactions
CN106994353A (zh) 2017-04-24 2017-08-01 苏州拓瑞特新材料有限公司 一种不含粘结剂高强度低水比乙苯脱氢催化剂
KR101981886B1 (ko) * 2018-02-01 2019-05-23 효성화학 주식회사 탈수소화 촉매
CN112717970B (zh) * 2019-10-14 2023-08-08 中国石油化工股份有限公司 烷基芳烃脱氢的方法
CN113332976B (zh) * 2021-05-18 2022-06-07 贵州大学 一种CeCO3OH纳米球包裹MnCO3微米球复合材料制备方法及应用
CN115475624B (zh) * 2021-06-16 2024-01-30 中国石油化工股份有限公司 一种烷基芳烃脱氢催化剂及其制备方法和应用

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WO2017099161A1 (ja) 2015-12-11 2017-06-15 クラリアント触媒株式会社 アルキル芳香族化合物脱水素化触媒とその製造方法、及びそれを用いた脱水素化方法
KR20180092993A (ko) 2015-12-11 2018-08-20 쿠라리안토 쇼쿠바이 가부시키가이샤 알킬방향족 화합물 탈수소화 촉매 및 이를 제조하기 위한 공정, 및 이를 사용하는 탈수소화 공정

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CA2676383C (en) 2015-11-24
JP2008183492A (ja) 2008-08-14
EP2106852A1 (en) 2009-10-07
CN101631612B (zh) 2013-07-03
CN101631612A (zh) 2010-01-20
US20100087694A1 (en) 2010-04-08
CA2676383A1 (en) 2008-07-31
EP2106852B1 (en) 2012-10-31
US20130053608A1 (en) 2013-02-28
KR20100014807A (ko) 2010-02-11
WO2008090974A1 (ja) 2008-07-31
EP2106852A4 (en) 2011-06-22

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