WO2008090974A1 - 物理的強度が改良されたアルキル芳香族化合物脱水素触媒およびその製造方法並びに脱水素化方法 - Google Patents

物理的強度が改良されたアルキル芳香族化合物脱水素触媒およびその製造方法並びに脱水素化方法 Download PDF

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WO2008090974A1
WO2008090974A1 PCT/JP2008/051069 JP2008051069W WO2008090974A1 WO 2008090974 A1 WO2008090974 A1 WO 2008090974A1 JP 2008051069 W JP2008051069 W JP 2008051069W WO 2008090974 A1 WO2008090974 A1 WO 2008090974A1
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Prior art keywords
dehydrogenation
catalyst
cerium
pellet
production
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PCT/JP2008/051069
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English (en)
French (fr)
Inventor
Yuji Mishima
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Sued-Chemie Catalysts Japan, Inc.
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Application filed by Sued-Chemie Catalysts Japan, Inc. filed Critical Sued-Chemie Catalysts Japan, Inc.
Priority to KR1020097017299A priority Critical patent/KR101422878B1/ko
Priority to CN2008800030052A priority patent/CN101631612B/zh
Priority to EP08703896A priority patent/EP2106852B1/en
Priority to US12/524,180 priority patent/US20100087694A1/en
Priority to CA2676383A priority patent/CA2676383C/en
Publication of WO2008090974A1 publication Critical patent/WO2008090974A1/ja
Priority to US13/659,401 priority patent/US20130053608A1/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/04—Particle-shaped
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
    • B29C48/793—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling upstream of the plasticising zone, e.g. heating in the hopper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
    • B29C48/91—Heating, e.g. for cross linking
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/42—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
    • C07C15/44—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
    • C07C15/46—Styrene; Ring-alkylated styrenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
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    • C07—ORGANIC CHEMISTRY
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    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with rare earths or actinides

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

　工業規模で使用されるアルキル芳香族化合物脱水素用高セリウム含有酸化鉄・酸化カリウム系触媒ペレットの物理的強度を向上させた脱水素触媒およびその製造方法並びにそれを使用した脱水素化方法を提供する。酸化鉄・酸化カリウム系脱水素触媒で高セリウムを含有するペレットを製造する際に、セリウム源として水酸化炭酸セリウムを全部又は水酸化炭酸セリウムと他のセリウム化合物とを混合して使用することにより、物理的強度の高いペレットを製造する。
PCT/JP2008/051069 2007-01-26 2008-01-25 物理的強度が改良されたアルキル芳香族化合物脱水素触媒およびその製造方法並びに脱水素化方法 WO2008090974A1 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
KR1020097017299A KR101422878B1 (ko) 2007-01-26 2008-01-25 물리적 강도가 개량된 알킬 방향족 화합물 탈수소촉매 및 그 제조 방법 및 탈수소화 방법
CN2008800030052A CN101631612B (zh) 2007-01-26 2008-01-25 经物理强度改良的烷基芳香族化合物脱氢催化剂及其制造方法以及脱氢方法
EP08703896A EP2106852B1 (en) 2007-01-26 2008-01-25 Catalyst for dehydrogenation of alkyl aromatic compound which has improved physical properties, method for production of the catalyst, and dehydrogenation method
US12/524,180 US20100087694A1 (en) 2007-01-26 2008-01-25 Catalyst for dehydrogenation of alkyl aromatic compound which has improved physical properties, method for production of the catalyst, and dehydrogenation method
CA2676383A CA2676383C (en) 2007-01-26 2008-01-25 Dehydrogenation catalyst of alkyl aromatic compounds having improved physical strength, process for producing same, and dehydrogenation method thereof
US13/659,401 US20130053608A1 (en) 2007-01-26 2012-10-24 Dehydrogenation catalyst of alkyl aromatic compounds having improved physical strength, process for producing same, and dehydrogenation method thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-017203 2007-01-26
JP2007017203A JP5096751B2 (ja) 2007-01-26 2007-01-26 物理的強度が改良されたアルキル芳香族化合物脱水素触媒およびその製造方法並びに脱水素化方法

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US13/659,401 Division US20130053608A1 (en) 2007-01-26 2012-10-24 Dehydrogenation catalyst of alkyl aromatic compounds having improved physical strength, process for producing same, and dehydrogenation method thereof

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US (2) US20100087694A1 (ja)
EP (1) EP2106852B1 (ja)
JP (1) JP5096751B2 (ja)
KR (1) KR101422878B1 (ja)
CN (1) CN101631612B (ja)
CA (1) CA2676383C (ja)
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Cited By (3)

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EP2353712A1 (en) * 2008-11-07 2011-08-10 Sued-Chemie Catalysts Japan, Inc. Dehydrogenation catalyst for alkyl aromatic compound exhibiting high performance in the presence of high-concentration co2, method for producing the same, and dehydrogenation process using the same
CN105312059A (zh) * 2014-07-24 2016-02-10 中国石油化工股份有限公司 乙苯脱氢生产苯乙烯的催化剂
CN113332976A (zh) * 2021-05-18 2021-09-03 贵州大学 一种CeCO3OH纳米球包裹MnCO3微米球复合材料制备方法及应用

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KR20100017490A (ko) * 2007-05-03 2010-02-16 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 촉매, 이의 제조 및 용도
KR101218453B1 (ko) * 2008-12-30 2013-01-04 주식회사 효성 탈수소화 촉매
CN102728371A (zh) * 2011-04-15 2012-10-17 廖仕杰 一种高铈含量烷基芳烃脱氢催化剂及其制造方法
CN103769141B (zh) * 2012-10-25 2016-08-24 中国石油化工股份有限公司 乙苯脱氢催化剂、制备方法及其用途
RU2509604C1 (ru) * 2012-12-05 2014-03-20 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Ярославский государственный технический университет" Катализатор для дегидрирования алкилароматических углеводородов
EP3140267B1 (de) 2014-05-09 2021-03-31 Basf Se Katalysator für die dehydrierung von kohlenwasserstoffen
PL3140039T3 (pl) 2014-05-09 2021-01-25 Basf Se Ulepszony katalizator do odwodorniania węglowodorów
CN105289626B (zh) * 2014-07-24 2017-12-15 中国石油化工股份有限公司 苯乙烯催化剂和苯乙烯的制备方法
EP3341126A1 (en) 2015-08-28 2018-07-04 Haldor Topsøe A/S Induction heating of endothermic reactions
EA036822B1 (ru) 2015-12-11 2020-12-23 Клариант Каталистс (Джэпэн) К.К. Катализатор дегидрирования алкилароматического соединения, способ его получения и способ дегидрирования с его использованием
CN106994353A (zh) 2017-04-24 2017-08-01 苏州拓瑞特新材料有限公司 一种不含粘结剂高强度低水比乙苯脱氢催化剂
KR101981886B1 (ko) * 2018-02-01 2019-05-23 효성화학 주식회사 탈수소화 촉매
CN112717970B (zh) * 2019-10-14 2023-08-08 中国石油化工股份有限公司 烷基芳烃脱氢的方法
CN115475624B (zh) * 2021-06-16 2024-01-30 中国石油化工股份有限公司 一种烷基芳烃脱氢催化剂及其制备方法和应用

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EP0297657A1 (en) 1987-06-29 1989-01-04 Shell Internationale Researchmaatschappij B.V. Dehydrogenation catalyst
US4758543A (en) 1987-07-01 1988-07-19 The Dow Chemical Company Dehydrogenation catalyst
JPH0311812A (ja) 1989-06-08 1991-01-21 Kenwood Corp Ｓｓｂ変調装置及びｓｓｂ復調装置
JPH05105428A (ja) 1991-10-15 1993-04-27 Santoku Kinzoku Kogyo Kk 酸素吸収・放出能を有する酸化セリウム及びその製造法
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EP2353712A1 (en) * 2008-11-07 2011-08-10 Sued-Chemie Catalysts Japan, Inc. Dehydrogenation catalyst for alkyl aromatic compound exhibiting high performance in the presence of high-concentration co2, method for producing the same, and dehydrogenation process using the same
EP2353712A4 (en) * 2008-11-07 2012-08-01 Sued Chemie Catalysts Jp Inc DEHYDRATION CATALYST FOR ALKYLAROMATIC COMPOUNDS WITH HIGH PERFORMANCE IN THE PRESENCE OF HIGH-CONCENTRATED CO2, METHOD OF PREPARATION THEREOF AND DEHYDRATION METHOD THEREWITH
US8809609B2 (en) 2008-11-07 2014-08-19 Sued-Chemie Catalysts Japan, Inc. Dehydrogenation catalyst for alkyl aromatic compounds exhibiting high performance in the presence of high-concentration CO2
KR101501318B1 (ko) * 2008-11-07 2015-03-10 수드 케미 촉매주식회사 고농도의 ｃｏ₂ 존재하에 고성능의 알킬 방향족 화합물의 탈수소촉매 및 그의 제조방법 및 그것을 사용한 탈수소화 방법
EP3603802A1 (en) * 2008-11-07 2020-02-05 Clariant Catalysts (Japan) K.K. Dehydrogenation catalyst for alkyl aromatic compounds exhibiting high performance in the presence of high-concentration co2 and dehydrogenation process using the same
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CN113332976B (zh) * 2021-05-18 2022-06-07 贵州大学 一种CeCO3OH纳米球包裹MnCO3微米球复合材料制备方法及应用

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CA2676383C (en) 2015-11-24
EP2106852B1 (en) 2012-10-31
US20130053608A1 (en) 2013-02-28
JP5096751B2 (ja) 2012-12-12
JP2008183492A (ja) 2008-08-14
EP2106852A1 (en) 2009-10-07
EP2106852A4 (en) 2011-06-22
KR101422878B1 (ko) 2014-07-23
KR20100014807A (ko) 2010-02-11
CA2676383A1 (en) 2008-07-31
CN101631612A (zh) 2010-01-20
US20100087694A1 (en) 2010-04-08

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