JP4965068B2 - 電気化学的リチウム蓄電池の正極用電気化学的活物質 - Google Patents

電気化学的リチウム蓄電池の正極用電気化学的活物質 Download PDF

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JP4965068B2
JP4965068B2 JP2004295689A JP2004295689A JP4965068B2 JP 4965068 B2 JP4965068 B2 JP 4965068B2 JP 2004295689 A JP2004295689 A JP 2004295689A JP 2004295689 A JP2004295689 A JP 2004295689A JP 4965068 B2 JP4965068 B2 JP 4965068B2
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active material
electrochemical
lithium
positive electrode
storage battery
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JP2005150093A (ja
JP2005150093A5 (enExample
Inventor
クリスチヤン・ジヨルデイ
クローデツト・オードリー
ジヤン−ピエール・ブーブ
フイリツプ・ビヤンサン
アンドレ・ルセル
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SAFT Societe des Accumulateurs Fixes et de Traction SA
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/483—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides for non-aqueous cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0025—Organic electrolyte
    • H01M2300/0028—Organic electrolyte characterised by the solvent
    • H01M2300/0037—Mixture of solvents
    • H01M2300/004—Three solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
JP2004295689A 2003-10-10 2004-10-08 電気化学的リチウム蓄電池の正極用電気化学的活物質 Expired - Lifetime JP4965068B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0311866A FR2860922B1 (fr) 2003-10-10 2003-10-10 Matiere electrochimiquement active pour electrode positive de generateur electrochimique rechargeable au lithium
FR0311866 2003-10-10

Publications (3)

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JP2005150093A JP2005150093A (ja) 2005-06-09
JP2005150093A5 JP2005150093A5 (enExample) 2011-06-16
JP4965068B2 true JP4965068B2 (ja) 2012-07-04

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US (1) US7285357B2 (enExample)
EP (1) EP1523052B1 (enExample)
JP (1) JP4965068B2 (enExample)
FR (1) FR2860922B1 (enExample)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6623886B2 (en) * 1999-12-29 2003-09-23 Kimberly-Clark Worldwide, Inc. Nickel-rich quaternary metal oxide materials as cathodes for lithium-ion and lithium-ion polymer batteries
JP4625733B2 (ja) * 2005-07-26 2011-02-02 株式会社東芝 非水電解質二次電池及び電池パック
JP4625744B2 (ja) 2005-09-29 2011-02-02 株式会社東芝 非水電解質電池および電池パック
KR20080108222A (ko) 2006-04-07 2008-12-12 미쓰비시 가가꾸 가부시키가이샤 리튬 이차 전지 정극 재료용 리튬 천이 금속계 화합물분체, 그 제조 방법, 그 분무 건조체 및 그 소성 전구체,그리고, 그것을 사용한 리튬 이차 전지용 정극 및 리튬이차 전지
JP5013508B2 (ja) * 2006-07-05 2012-08-29 日立マクセルエナジー株式会社 非水電解液二次電池
US20080280205A1 (en) * 2007-05-07 2008-11-13 3M Innovative Properties Company Lithium mixed metal oxide cathode compositions and lithium-ion electrochemical cells incorporating same
CN102769130A (zh) 2007-09-04 2012-11-07 三菱化学株式会社 锂过渡金属类化合物粉末
KR20110076955A (ko) * 2008-09-30 2011-07-06 엔비아 시스템즈 인코포레이티드 비용량이 높은 불소 도핑된 리튬 풍부 금속 산화물 양극 배터리 재료 및 상당하는 배터리
US8389160B2 (en) * 2008-10-07 2013-03-05 Envia Systems, Inc. Positive electrode materials for lithium ion batteries having a high specific discharge capacity and processes for the synthesis of these materials
FR2937633B1 (fr) 2008-10-24 2010-11-19 Saft Groupe Sa Materiau d'electrode positive pour accumulateur lithium-ion
KR101190226B1 (ko) 2008-11-19 2012-10-11 코스모신소재 주식회사 리튬 이차전지용 양극활물질, 그의 제조방법 및 이를 포함한 리튬 이차전지
US8465873B2 (en) 2008-12-11 2013-06-18 Envia Systems, Inc. Positive electrode materials for high discharge capacity lithium ion batteries
JP2013503449A (ja) * 2009-08-27 2013-01-31 エンビア・システムズ・インコーポレイテッド 金属酸化物でコーティングされたリチウム系電池用正極材料
KR20120089845A (ko) 2009-08-27 2012-08-14 엔비아 시스템즈 인코포레이티드 높은 비용량과 우수한 사이클링을 갖는 층-층 리튬-리치 복합 금속 산화물
US9843041B2 (en) * 2009-11-11 2017-12-12 Zenlabs Energy, Inc. Coated positive electrode materials for lithium ion batteries
WO2011114534A1 (ja) * 2010-03-19 2011-09-22 トヨタ自動車株式会社 リチウム二次電池および該リチウム二次電池用正極活物質
CN104701525B (zh) * 2010-03-19 2017-04-26 丰田自动车株式会社 锂二次电池和该锂二次电池用正极活性物质
US8741484B2 (en) 2010-04-02 2014-06-03 Envia Systems, Inc. Doped positive electrode active materials and lithium ion secondary battery constructed therefrom
US8928286B2 (en) 2010-09-03 2015-01-06 Envia Systems, Inc. Very long cycling of lithium ion batteries with lithium rich cathode materials
US8663849B2 (en) 2010-09-22 2014-03-04 Envia Systems, Inc. Metal halide coatings on lithium ion battery positive electrode materials and corresponding batteries
CN102157733A (zh) * 2011-03-10 2011-08-17 江苏科捷锂电池有限公司 锰基层状晶体结构锂电池正极材料及其制备方法
WO2013090263A1 (en) 2011-12-12 2013-06-20 Envia Systems, Inc. Lithium metal oxides with multiple phases and stable high energy electrochemical cycling
US9070489B2 (en) 2012-02-07 2015-06-30 Envia Systems, Inc. Mixed phase lithium metal oxide compositions with desirable battery performance
CN102623688A (zh) * 2012-03-23 2012-08-01 江苏科捷锂电池有限公司 纳米层状富锂材料的制备方法及表面修饰方法
US9552901B2 (en) 2012-08-17 2017-01-24 Envia Systems, Inc. Lithium ion batteries with high energy density, excellent cycling capability and low internal impedance
US10115962B2 (en) 2012-12-20 2018-10-30 Envia Systems, Inc. High capacity cathode material with stabilizing nanocoatings
KR101785262B1 (ko) * 2013-07-08 2017-10-16 삼성에스디아이 주식회사 양극 활물질, 그 제조방법, 이를 채용한 양극 및 리튬이차전지
JP6406049B2 (ja) 2014-03-26 2018-10-17 株式会社デンソー 正極材料,非水電解質二次電池用正極及び非水電解質二次電池
KR102358438B1 (ko) * 2014-12-30 2022-02-04 삼성전자주식회사 복합 양극 활물질, 그 제조방법, 이를 포함하는 양극 및 리튬이차전지
GB2566473B (en) 2017-09-14 2020-03-04 Dyson Technology Ltd Magnesium salts
GB2566472B (en) 2017-09-14 2020-03-04 Dyson Technology Ltd Magnesium salts
GB2569387B (en) 2017-12-18 2022-02-02 Dyson Technology Ltd Electrode
GB2569388B (en) 2017-12-18 2022-02-02 Dyson Technology Ltd Compound
GB2569392B (en) 2017-12-18 2022-01-26 Dyson Technology Ltd Use of aluminium in a cathode material
GB2569390A (en) 2017-12-18 2019-06-19 Dyson Technology Ltd Compound
GB2569389B (en) * 2017-12-18 2022-02-09 Dyson Technology Ltd Compound
WO2021260900A1 (ja) * 2020-06-25 2021-12-30 TeraWatt Technology株式会社 リチウム2次電池、及びその使用方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0878009A (ja) * 1994-09-07 1996-03-22 Yuasa Corp リチウム二次電池
JP3624663B2 (ja) * 1996-12-24 2005-03-02 株式会社日立製作所 電池
JPH11307094A (ja) * 1998-04-20 1999-11-05 Chuo Denki Kogyo Co Ltd リチウム二次電池用正極活物質とリチウム二次電池
JP2002124261A (ja) * 1999-11-29 2002-04-26 Mitsui Chemicals Inc リチウム二次電池用正極活物質および電池
US6680143B2 (en) * 2000-06-22 2004-01-20 The University Of Chicago Lithium metal oxide electrodes for lithium cells and batteries
US6660432B2 (en) * 2000-09-14 2003-12-09 Ilion Technology Corporation Lithiated oxide materials and methods of manufacture
JP4635386B2 (ja) * 2001-07-13 2011-02-23 株式会社Gsユアサ 正極活物質およびこれを用いた非水電解質二次電池
JP4109847B2 (ja) * 2001-08-24 2008-07-02 Agcセイミケミカル株式会社 リチウム含有遷移金属複合酸化物およびその製造方法
KR100420034B1 (ko) * 2001-10-17 2004-02-25 삼성에스디아이 주식회사 리튬 이차 전지용 양극 활물질의 제조방법
EP2367224B1 (en) * 2002-03-25 2013-01-09 Sumitomo Chemical Company, Limited Method for preparing positive electrode active material for non-aqueous secondary battery

Also Published As

Publication number Publication date
US20050112466A1 (en) 2005-05-26
FR2860922B1 (fr) 2009-07-31
EP1523052B1 (fr) 2018-05-09
JP2005150093A (ja) 2005-06-09
EP1523052A2 (fr) 2005-04-13
US7285357B2 (en) 2007-10-23
FR2860922A1 (fr) 2005-04-15
EP1523052A3 (fr) 2009-01-07

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