JP4943612B2 - フェロモン又はその成分のメタセシス合成方法 - Google Patents

フェロモン又はその成分のメタセシス合成方法 Download PDF

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JP4943612B2
JP4943612B2 JP2001538323A JP2001538323A JP4943612B2 JP 4943612 B2 JP4943612 B2 JP 4943612B2 JP 2001538323 A JP2001538323 A JP 2001538323A JP 2001538323 A JP2001538323 A JP 2001538323A JP 4943612 B2 JP4943612 B2 JP 4943612B2
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acetate
metathesis
product
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omega
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JP2003531818A (ja
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エル ペダーソン リチャード
エイチ グラブス ロバート
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/505—Preparation; Separation; Purification; Stabilisation
    • C07F9/5086—Preparation; Separation; Purification; Stabilisation from phosphonium salts as starting materials
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/095—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of esters of organic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/44—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by addition reactions, i.e. reactions involving at least one carbon-to-carbon double or triple bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/511—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups
    • C07C45/515—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups the singly bound functional group being an acetalised, ketalised hemi-acetalised, or hemi-ketalised hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/12—Preparation of carboxylic acid esters from asymmetrical anhydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/293—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/297—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/475—Preparation of carboxylic acid esters by splitting of carbon-to-carbon bonds and redistribution, e.g. disproportionation or migration of groups between different molecules
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02—Boron compounds
    • C07F5/025—Boronic and borinic acid compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02—Boron compounds
    • C07F5/04—Esters of boric acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/09—Geometrical isomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Pyrane Compounds (AREA)
JP2001538323A 1999-11-18 2000-11-17 フェロモン又はその成分のメタセシス合成方法 Expired - Lifetime JP4943612B2 (ja)

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US16654399P 1999-11-18 1999-11-18
US60/166,543 1999-11-18
PCT/US2000/031549 WO2001036368A2 (en) 1999-11-18 2000-11-17 Metathesis syntheses of pheromones or their components

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JP2003531818A5 JP2003531818A5 (enExample) 2008-01-17
JP4943612B2 true JP4943612B2 (ja) 2012-05-30

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AT (1) ATE298318T1 (enExample)
AU (1) AU1921201A (enExample)
BR (1) BR0015712B1 (enExample)
CA (1) CA2392049C (enExample)
DE (1) DE60020987T2 (enExample)
IL (2) IL149720A0 (enExample)
WO (1) WO2001036368A2 (enExample)
ZA (1) ZA200204712B (enExample)

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WO2002079126A1 (en) 2001-03-30 2002-10-10 California Institute Of Technology Cross-metathesis reaction of functionalized and substituted olefins using group 8 transition metal carbene complexes as metathesis catalysts
BRPI0406756A (pt) 2003-01-13 2005-12-20 Cargill Inc Método para fabricação de agentes quìmicos industriais
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KR101269568B1 (ko) * 2005-07-04 2013-06-04 자난 사이텍 컴퍼니 리미티드 루테늄 착물 리간드, 루테늄 착물, 고정 루테늄 착물 촉매및 그의 제조방법과 용도
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CN102525829B (zh) 2006-03-07 2014-08-06 埃莱文斯可更新科学公司 含有复分解不饱和多元醇酯的组合物
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CN106083579A (zh) 2006-10-13 2016-11-09 埃莱文斯可更新科学公司 通过烯烃复分解由内烯烃合成末端烯烃的方法
WO2008048520A2 (en) 2006-10-13 2008-04-24 Elevance Renewable Sciences, Inc. Methods of making organic compounds by metathesis and hydrocyanation
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ATE519725T1 (de) 2006-10-13 2011-08-15 Elevance Renewable Sciences Metatheseverfahren mit hydrierung, und damit in zusammenhang stehende zusammensetzungen
BRPI0814994A2 (pt) * 2007-08-09 2015-02-03 Elevance Renewable Sciences Métodos químicos para tratamento de uma matéria-prima de metátese
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CN112782309B (zh) * 2020-12-29 2022-10-28 常州大学 一种稳定长链不饱和烯醛的方法
CN114507122B (zh) * 2022-01-28 2024-07-05 宜都市华阳化工有限责任公司 3-(4-甲基苯亚甲基)-樟脑合成副产物的回收利用方法
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CN115452991B (zh) * 2022-09-15 2024-07-12 江苏科技大学 十四碳烯酸和十六碳烯醛在检测检疫性害虫中的应用
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JPH11262667A (ja) * 1992-04-03 1999-09-28 California Inst Of Technol オレフィンメタセシス反応用高活性ルテニウムまたはオスミウム金属カルベン錯体の製造法
WO1999051344A1 (de) * 1998-04-06 1999-10-14 Aventis Research & Technologies Gmbh & Co. Kg Alkylidenkomplexe des rutheniums mit n-heterozyklischen carbenliganden; verwendung als hochaktive, selektive katalysatoren für die olefin-metathese
JP2002535297A (ja) * 1999-01-26 2002-10-22 カリフォルニア インスティチュート オブ テクノロジー 末端オレフィンのクロスメタセシスのための方法

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DE19907519A1 (de) * 1999-02-22 2000-08-31 Basf Ag Verfahren zur Herstellung von substituierten Olefinen
JP4410422B2 (ja) * 1999-05-24 2010-02-03 カリフォルニア インスティチュート オブ テクノロジー イミダゾリジンに基づく金属カルベンメタセシス触媒

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JPH11262667A (ja) * 1992-04-03 1999-09-28 California Inst Of Technol オレフィンメタセシス反応用高活性ルテニウムまたはオスミウム金属カルベン錯体の製造法
US5916983A (en) * 1997-05-27 1999-06-29 Bend Research, Inc. Biologically active compounds by catalytic olefin metathesis
WO1999051344A1 (de) * 1998-04-06 1999-10-14 Aventis Research & Technologies Gmbh & Co. Kg Alkylidenkomplexe des rutheniums mit n-heterozyklischen carbenliganden; verwendung als hochaktive, selektive katalysatoren für die olefin-metathese
JP2002535297A (ja) * 1999-01-26 2002-10-22 カリフォルニア インスティチュート オブ テクノロジー 末端オレフィンのクロスメタセシスのための方法

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BR0015712B1 (pt) 2011-01-25
CN1423629A (zh) 2003-06-11
ZA200204712B (en) 2004-04-08
BR0015712A (pt) 2004-04-27
JP2003531818A (ja) 2003-10-28
CN100528829C (zh) 2009-08-19
ATE298318T1 (de) 2005-07-15
JP2011178789A (ja) 2011-09-15
EP1230207A2 (en) 2002-08-14
JP5687114B2 (ja) 2015-03-18
CA2392049C (en) 2012-01-31
DE60020987D1 (de) 2005-07-28
IL149720A (en) 2008-03-20
EP1230207B1 (en) 2005-06-22
IL149720A0 (en) 2002-11-10
DE60020987T2 (de) 2006-05-11
WO2001036368A3 (en) 2002-01-10
AU1921201A (en) 2001-05-30
WO2001036368A2 (en) 2001-05-25
CA2392049A1 (en) 2001-05-25

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